WO2020067408A1 - 眼鏡レンズ - Google Patents
眼鏡レンズ Download PDFInfo
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- WO2020067408A1 WO2020067408A1 PCT/JP2019/038102 JP2019038102W WO2020067408A1 WO 2020067408 A1 WO2020067408 A1 WO 2020067408A1 JP 2019038102 W JP2019038102 W JP 2019038102W WO 2020067408 A1 WO2020067408 A1 WO 2020067408A1
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- WIPO (PCT)
- Prior art keywords
- spectacle lens
- reflectance
- lens
- wavelength band
- less
- Prior art date
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Images
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02C—SPECTACLES; SUNGLASSES OR GOGGLES INSOFAR AS THEY HAVE THE SAME FEATURES AS SPECTACLES; CONTACT LENSES
- G02C7/00—Optical parts
- G02C7/02—Lenses; Lens systems ; Methods of designing lenses
- G02C7/024—Methods of designing ophthalmic lenses
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/20—Filters
- G02B5/28—Interference filters
- G02B5/285—Interference filters comprising deposited thin solid films
-
- G—PHYSICS
- G02—OPTICS
- G02C—SPECTACLES; SUNGLASSES OR GOGGLES INSOFAR AS THEY HAVE THE SAME FEATURES AS SPECTACLES; CONTACT LENSES
- G02C7/00—Optical parts
- G02C7/10—Filters, e.g. for facilitating adaptation of the eyes to the dark; Sunglasses
- G02C7/102—Photochromic filters
-
- G—PHYSICS
- G02—OPTICS
- G02C—SPECTACLES; SUNGLASSES OR GOGGLES INSOFAR AS THEY HAVE THE SAME FEATURES AS SPECTACLES; CONTACT LENSES
- G02C7/00—Optical parts
- G02C7/10—Filters, e.g. for facilitating adaptation of the eyes to the dark; Sunglasses
- G02C7/104—Filters, e.g. for facilitating adaptation of the eyes to the dark; Sunglasses having spectral characteristics for purposes other than sun-protection
-
- G—PHYSICS
- G02—OPTICS
- G02C—SPECTACLES; SUNGLASSES OR GOGGLES INSOFAR AS THEY HAVE THE SAME FEATURES AS SPECTACLES; CONTACT LENSES
- G02C7/00—Optical parts
- G02C7/10—Filters, e.g. for facilitating adaptation of the eyes to the dark; Sunglasses
- G02C7/107—Interference colour filters
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
- G02B1/18—Coatings for keeping optical surfaces clean, e.g. hydrophobic or photo-catalytic films
Definitions
- the present invention relates to spectacle lenses.
- Patent Document 1 discloses a spectacle lens that suppresses light in the blue region of visible light from entering the eyes of a spectacle lens wearer. According to Patent Document 1, the wavelength in the blue region to be cut off is described as 380 to 500 nm. Strictly speaking, the wavelength of violet is 380 to 450 nm, and the wavelength of blue is 450 to 500 nm.
- the spectacle lens described in Patent Literature 1 is an optical component including a plastic substrate and a multilayer film provided on at least a convex surface of both surfaces including a convex surface and a concave surface of the plastic substrate, wherein the multilayer film Has an average reflectance of 2 to 10% in a wavelength range of 400 to 500 nm ([0008] of Patent Document 1).
- the spectacle lens described in Patent Literature 1 In the spectacle lens described in Patent Literature 1, light in the blue region is blocked by increasing the reflectance with respect to the blue region. Therefore, the spectacle lens is also called a blue cut lens.
- the reflected light in the blue region that has been multiple-reflected within the lens is given to the wearer's eyes despite the fact that the blue-cut lens is named. It has been found that there is a risk of entry.
- An object of one embodiment of the present invention is to provide a blue-cut lens including reflected light.
- the present inventors have conducted intensive studies to solve the above-mentioned problems.
- the multilayer film on each side of the spectacle lens is provided with a blue cut function (reflectance), and the blue cut function having the same tendency in the relationship between the wavelength and the reflectivity is determined as the respective spectacle lens. It has been found that the above problem can be solved by providing a difference between the height of the blue cut function on one surface and the height of the blue cut function on the other surface while using the surface. .
- a first aspect of the present invention provides: A spectacle lens comprising a multilayer film on both surfaces of a lens substrate, The sum of the average reflectances in the wavelength band of 400 to 440 nm on each surface of the spectacle lens is 20.0% or more; The reflectance of each surface of the spectacle lens has at least one maximum value in the wavelength band, In the spectacle lens, in the wavelength band, there is a difference between the average reflectance on one surface of the spectacle lens and the average reflectance on the other surface.
- a second aspect of the present invention is an aspect according to the first aspect, wherein In the wavelength band, a ratio of an average reflectance on one surface to an average reflectance on one surface of the spectacle lens is more than 0 and 0.9 or less.
- a third aspect of the present invention is an aspect according to the first or second aspect, wherein In the wavelength band, the average reflectance on the object-side surface of the eyeglass lens is smaller than the average reflectance on the eyeball-side surface.
- a fourth aspect of the present invention is an aspect according to any one of the first to third aspects, wherein The sum of the average reflectances in the wavelength band of 500 to 570 nm on each surface of the spectacle lens is 1.0% or less.
- a fifth aspect of the present invention is an aspect according to any one of the first to fourth aspects, wherein The sum of the luminous reflectances on each surface of the spectacle lens is 2.0% or less.
- a sixth aspect of the present invention is the aspect according to the fifth aspect, wherein The maximum sum of the maximum values in the reflectance of each surface of the spectacle lens is 60.0% or less.
- a seventh aspect of the present invention is an aspect according to any one of the first to sixth aspects, wherein:
- Each multilayer film on each surface of the spectacle lens includes at least one high-refractive-index layer and at least one low-refractive-index layer, and the total number of layers is 10 or less.
- An eighth aspect of the present invention is an aspect according to any one of the first to seventh aspects, wherein:
- the sum of the average reflectances in the wavelength band of 500 to 570 nm on each surface of the spectacle lens is preferably less than 1.0%, more preferably 0.5% or less.
- a ninth aspect of the present invention is an aspect according to any one of the first to eighth aspects, wherein:
- the sum of the luminous reflectance on each surface of the spectacle lens is preferably less than 2.0%, more preferably 1.8% or less.
- a tenth aspect of the present invention is an aspect according to any one of the first to ninth aspects, wherein The moving average of the reflectance at 10 points before and after the predetermined point a in the plot of the relationship between the wavelength (horizontal axis) and the reflectance (vertical axis) (that is, 21 points including the point a in total) is calculated.
- the reflectance of each surface of the spectacle lens preferably has at least one maximum value in a wavelength band of 400 to 440 nm.
- An eleventh aspect of the present invention is the aspect described in any one of the first to tenth aspects,
- the maximum value in the wavelength band of 400 to 440 nm (the maximum value when there are a plurality of maximum values) is preferably also the maximum value in the wavelength band of 400 to 440 nm.
- a twelfth aspect of the present invention is an aspect according to any one of the first to eleventh aspects,
- Each multilayer film on each surface of the spectacle lens includes at least one high refractive index layer and at least one low refractive index layer, and the total number of layers is preferably 9 or less, more preferably 8 or less.
- a thirteenth aspect of the present invention is the aspect described in any one of the first to twelfth aspects,
- the sum of the average reflectances in the wavelength band of 400 to 440 nm on each surface of the spectacle lens is 20.0% or more, preferably more than 20.0%, and more preferably 25% or more.
- a fourteenth aspect of the present invention is an aspect according to any one of the first to thirteenth aspects,
- the sum of the average reflectances in the wavelength band of 360 to 400 nm on each surface of the spectacle lens is 6.0% or less, preferably less than 6.0%, and more preferably 5.0% or less.
- a fifteenth aspect of the present invention is an aspect according to any one of the first to fourteenth aspects,
- the sum of the average reflectances in the wavelength band of 480 to 680 nm on each surface of the spectacle lens is 2.0% or less, preferably less than 2.0%, and more preferably 1.5% or less.
- a sixteenth aspect of the present invention is an aspect according to any one of the first to fifteenth aspects, wherein In the wavelength band of 400 to 440 nm, the ratio of the average reflectance on one surface to the average reflectance on one surface of the spectacle lens is 0.3 (or 0.4) to 0.9.
- a seventeenth aspect of the present invention is an aspect according to any one of the first to sixteenth aspects, In the wavelength band of 400 to 440 nm, the ratio of the average reflectance on one surface to the average reflectance on one surface of the spectacle lens is more than 0 and less than 0.3 (or less than 0.4).
- An eighteenth aspect of the present invention is an aspect according to any one of the first to seventeenth aspects, wherein In a wavelength band of 400 to 440 nm, the ratio of the average reflectance on one surface to the average reflectance on one surface of the spectacle lens is more than 0.9 and less than 1.0.
- a blue-cut lens including reflected light can be provided.
- FIG. 1 is a diagram illustrating a spectral reflection spectrum obtained by measurement on the object-side surface and the eyeball-side surface of the spectacle lens of Example 1.
- the average reflectance in the present invention and in the present specification refers to an arithmetic average value of the normal incidence reflectance measured at an arbitrary wavelength (at an arbitrary pitch) in a wavelength range of a measurement object at an optical center of a surface of the measurement object.
- the measurement wavelength interval (pitch) can be arbitrarily set within a range of, for example, 1 to 5 nm.
- the reflection spectral characteristics such as the reflectance in the present invention and the present specification indicate direct incident reflection spectral characteristics.
- the “luminous reflectance” is measured in accordance with JIS T 7334: 2011.
- the "eyeball-side surface” refers to a surface arranged on the eyeball side when spectacles equipped with spectacle lenses are worn by a wearer
- an "object-side surface” Means a surface arranged on the object side.
- to indicates a value equal to or more than a predetermined value and equal to or less than a predetermined value.
- a spectacle lens according to one embodiment of the present invention A spectacle lens according to one embodiment of the present invention, A spectacle lens comprising a multilayer film on both surfaces of a lens substrate, The sum of the average reflectances in the wavelength band of 400 to 440 nm on each surface of the spectacle lens is 20.0% or more; The reflectance of each surface of the spectacle lens has at least one maximum value in the wavelength band, In the spectacle lens, in the wavelength band, there is a difference between the average reflectance on one surface of the spectacle lens and the average reflectance on the other surface.
- the reflectance of each surface of the spectacle lens has at least one maximum value in a wavelength band of 400 to 440 nm.
- This maximum value is also preferably the maximum value in the wavelength band of 400 to 440 nm.
- the definition of the maximum value is the same for the multilayer film on both surfaces in terms of the relationship between wavelength and reflectance (for example, both plots when the horizontal axis is wavelength (nm) and the vertical axis is reflectance (%)). Represents a blue cut function).
- the multilayer film on both surfaces effectively reflects light in the wavelength band of 400 to 440 nm, so that the effect of blocking light in the blue region is ensured.
- transmission of visible light can be ensured well.
- At least one is obtained by smoothing the plots in the wavelength band of 400 to 440 nm in the two plots.
- a moving average of the reflectance at 10 points before and after the predetermined point a of the plot (that is, a total of 21 points including the point a) is taken, and the moving average value is calculated as a new reflectance at the point a. May be performed. Accordingly, it is possible to exclude a case where a plurality of local maxima exist due to fine vibrations in the plot, and to define that both the plots are upwardly convex macroscopically.
- a blue cut lens including reflected light can be provided.
- the sum of the average reflectances in the wavelength band of 500 to 570 nm on each surface of the spectacle lens is 1.0% or less (preferably less than 1.0%, more preferably 0.5% or less). preferable.
- Light in the wavelength band of 500 to 570 nm is green light. According to the above definition, it is possible to suppress the reflection of green light that greatly contributes to the luminous reflectance.
- the sum of the luminous reflectances on each surface of the spectacle lens is preferably 2.0% or less (preferably less than 2.0%, more preferably 1.8% or less). According to the above definition, it is possible to suppress the occurrence of glare due to the reflected light on the spectacle lens.
- the sum of the local maximum values (the maximum local maximum value when there are a plurality of local maximum values) in the wavelength band of 400 to 440 nm in the reflectance of each surface of the spectacle lens is preferably 60.0% or less. According to this definition, as described in the section of the problem, it is possible to suppress a tendency that the reflectance for visible light other than the blue region also increases accompanying the increase in the reflectance for the blue region. As a result, transmission of visible light can be satisfactorily ensured.
- the following configuration is required. It is preferable to employ it. That is, in the wavelength band of 400 to 440 nm, the other surface (the average reflectance is equal to or lower than the average reflectance on one surface of the spectacle lens (the surface with the higher average reflectance, the surface on the eyeball side in Example 1 described later). It is preferable that the ratio of the average reflectance on the lower side, that is, on the object side in Example 1 described later) is 0.3 (preferably 0.4) to 0.9. As described above, of the light in the blue region, light in the violet region should be particularly blocked.
- the sum of the average reflectances of the respective surfaces is set to 20.0% or more. Accordingly, by setting the ratio of the average reflectance in the purple region on each surface to 0.3 to 0.9, it is possible to prevent one surface from affecting the transmission of visible light due to a particularly high reflectance. Can be suppressed in advance.
- the ratio of the average reflectance in the wavelength band of 400 to 440 nm is more than 0 and less than 0.3 (or less than 0.4), the multiple reflection light in the blue region is more reliably eliminated. Can be. With this range, the effect of blocking the light in the blue region is reduced on one surface of the spectacle lens.
- the one-sided multilayer film may be provided with a property of further reducing the luminous reflectance.
- the ratio of the average reflectance is more than 0.9 and less than 1.0, the color of the reflected light and the reflection intensity on both surfaces look the same, so that a sense of unity in appearance increases, Is good.
- the ratio of the average reflectance may be selected depending on which of the above listed advantages is adopted. In other words, in one embodiment of the present invention, there is a degree of freedom in which of the above-listed advantages is adopted.
- Example 1 in the wavelength band of 400 to 440 nm, the average reflectance of the surface on the object side is smaller than the average reflectance of the surface on the eyeball side.
- the average reflectance of the surface on the object side is smaller than the average reflectance of the surface on the eyeball side.
- Each multilayer film on each surface of the spectacle lens includes at least one high-refractive-index layer and at least one low-refractive-index layer, and has a total number of 10 or less (preferably 9 or less, more preferably 8 or less) The following is preferred.
- the sum of the average reflectances of the respective surfaces is 20.0% or more (preferably more than 20.0%) in the violet region (400 to 440 nm) to be cut off. , More preferably 25% or more). That is, the reflectance may be locally increased in the purple region.
- the sum of the average reflectances of the respective surfaces is set to 6.0% or less (preferably less than 6.0%, more preferably 5.0% or less). Is also good. That is, contrary to the case of the purple region (400 to 440 nm), the reflectance may be locally reduced.
- the sum of the average reflectances of the respective surfaces is 2.0% or less (preferably less than 2.0%, more preferably 1% or less). 0.5% or less).
- the reflectance may be locally reduced particularly in a main wavelength band of visible light.
- the multilayer films provided on the eyeball-side surface and the object-side surface of the lens substrate can impart the spectroscopic characteristics to the spectacle lens.
- the multilayer film is provided directly on the surface of the lens substrate or indirectly via one or more other layers.
- the lens substrate is not particularly limited, but may be glass or allyl carbonate resin such as styrene resin including (meth) acrylic resin, polycarbonate resin, allyl resin, diethylene glycol bisallyl carbonate resin (CR-39), vinyl resin A polyester resin, a polyether resin, a urethane resin obtained by reacting an isocyanate compound with a hydroxy compound such as diethylene glycol, a thiourethane resin obtained by reacting an isocyanate compound with a polythiol compound, and one or more disulfide bonds in the molecule. And a transparent resin obtained by curing a polymerizable composition containing a (thio) epoxy compound. Also, inorganic glass can be used.
- styrene resin including (meth) acrylic resin, polycarbonate resin, allyl resin, diethylene glycol bisallyl carbonate resin (CR-39), vinyl resin
- a polyester resin a polyether resin, a urethane resin obtained by reacting an isocyanate compound
- an unstained one colorless lens
- a dyed one dyed one
- the refractive index of the lens substrate is, for example, about 1.60 to 1.75.
- the refractive index of the lens substrate is not limited to this, and may be within the above range or may be vertically separated from the above range.
- the spectacle lens can be various lenses such as a single focus lens, a multifocal lens, and a progressive-power lens.
- the type of lens is determined by the surface shape of both surfaces of the lens substrate.
- the lens substrate surface may be any of a convex surface, a concave surface, and a flat surface.
- the surface on the object side is convex
- the surface on the eyeball side is concave.
- the present invention is not limited to this.
- the multilayer film for imparting the above-mentioned reflection spectral characteristics may be provided directly on the surface of the lens substrate, or may be provided indirectly via one or more other layers.
- the layer that can be formed between the lens substrate and the multilayer film include a hard coat layer (hereinafter, also referred to as “hard coat”).
- hard coat layer By providing the hard coat layer, the spectacle lens can be provided with scratch resistance (scratch resistance), and the durability (strength) of the spectacle lens can be increased.
- a primer layer for improving adhesion may be formed between the lens substrate and the coating.
- the primer layer refer to paragraphs 0029 to 0030 of JP-A-2012-128135, for example.
- the multilayer films provided on the eyeball-side surface and the object-side surface of the lens substrate are not particularly limited as long as the spectroscopic characteristics described above can be imparted to the surface of the spectacle lens having these multilayer films. is not.
- Such a multilayer film can be preferably formed by sequentially laminating a high refractive index layer and a low refractive index layer. More specifically, based on the refractive index of the film material for forming the high refractive index layer and the low refractive index layer, and the wavelength of light to be reflected or light to be reduced, each layer is subjected to optical simulation by a known method.
- the film-forming material may be an inorganic material, an organic material, or an organic-inorganic composite material, and is preferably an inorganic material from the viewpoint of film formation and availability.
- zirconium oxide for example, ZrO 2
- tantalum oxide Ta 2 O 5
- titanium oxide for example, TiO 2
- aluminum oxide Al 2 O 3
- yttrium oxide eg, Y 2 O 3
- hafnium oxide eg, HfO 2
- niobium oxide eg, Nb 2 O 5
- the low-refractive-index material for forming the low-refractive-index layer is an oxide selected from the group consisting of silicon oxide (eg, SiO 2 ), magnesium fluoride (eg, MgF 2 ), and barium fluoride (eg, BaF 2 ). Or a mixture of two or more kinds of compounds or fluorides.
- oxides and fluorides are represented by stoichiometric compositions, but those in which oxygen or fluorine is deficient or excessive from the stoichiometric composition are also high refractive index materials or low refractive index materials. It can be used as a material.
- the thickness of each layer included in the multilayer film can be determined by optical simulation.
- the layer configuration of the multilayer film for example, from the lens substrate side to the lens outermost surface side, First layer (low refractive index layer) / second layer (high refractive index layer) / third layer (low refractive index layer) / fourth layer (high refractive index layer) / fifth layer (low refractive index layer) / A configuration in which the sixth layer (high refractive index layer) / the seventh layer (low refractive index layer) are laminated in this order; First layer (high refractive index layer) / second layer (low refractive index layer) / third layer (high refractive index layer) / fourth layer (low refractive index layer) / fifth layer (high refractive index layer) / A configuration in which the sixth layer (low-refractive index layer) is laminated in this order; And the like.
- a combination of a film containing silicon oxide as a main component and a film containing zirconium oxide as a main component, and a film containing silicon oxide as a main component As an example of a preferred combination of a low refractive index layer and a high refractive index layer, a combination of a film containing silicon oxide as a main component and a film containing zirconium oxide as a main component, and a film containing silicon oxide as a main component.
- a combination with a film containing niobium oxide as a main component can be mentioned, and a multilayer film including at least one laminated structure in which these two-layer films are adjacent to each other can be exemplified as a preferable example of the multilayer film.
- each of the above-mentioned layers is a coating mainly composed of the above-mentioned high refractive index material or low refractive index material.
- the main component is a component that occupies the largest amount in the coating film, and is usually a component that occupies about 50% by mass to 100% by mass, and more preferably about 90% by mass to 100% by mass.
- Such a film can be formed by performing film formation using a film formation material (for example, an evaporation source) containing the above material as a main component.
- the main components of the film forming material are the same as above.
- Coatings and film-forming materials may contain trace amounts of impurities that are inevitably mixed, and also assist other components, such as other inorganic substances and film formation, within a range that does not impair the function of the main component.
- a known additive component that plays a role may be included.
- Film formation can be performed by a known film formation method, and is preferably performed by vapor deposition from the viewpoint of easy film formation.
- the vapor deposition in the present invention includes a dry method, for example, a vacuum vapor deposition method, an ion plating method, a sputtering method and the like. In the vacuum evaporation method, an ion beam assist method in which an ion beam is simultaneously irradiated during the evaporation may be used.
- the multilayer film is formed by a deposition using a conductive oxide-based coating, preferably a conductive oxide-based deposition source, in addition to the high refractive index layer and the low refractive index layer described above.
- a conductive oxide-based coating preferably a conductive oxide-based deposition source
- One or more conductive oxide layers to be formed can be included in any position of the multilayer film.
- the conductive oxide from the viewpoint of the transparency of the spectacle lens, generally known as a transparent conductive oxide, such as indium oxide, tin oxide, zinc oxide, titanium oxide, and composite oxides thereof. It is preferable to use various conductive oxides.
- Particularly preferred conductive oxides from the viewpoint of transparency and conductivity include tin oxide and indium-tin oxide (ITO).
- a further functional film on the multilayer film.
- a functional film examples include various functional films such as a water-repellent or hydrophilic antifouling film, an antifogging film, a polarizing film, and a light control film.
- Known techniques can be applied to these functional films without any restrictions.
- a further aspect of the present invention can also provide eyeglasses including the spectacle lens according to one embodiment of the present invention described above and a frame to which the eyeglass lens is attached.
- the spectacle lens is as described in detail above.
- Other configurations of the glasses are not particularly limited, and a known technique can be applied.
- a further aspect of the present invention can also provide a method for manufacturing a spectacle lens according to one aspect of the present invention described above.
- the refractive index is a refractive index at a wavelength of 500 nm.
- Example 1 A plastic lens substrate having a convex surface on the object side and a concave surface on the eyeball side (trade name: HL manufactured by HOYA CORPORATION, refractive index: 1.50, colorless)
- HL convex surface on the eyeball side
- N 2 nitrogen gas
- the multilayer vapor-deposited film is formed from the lens substrate side (hard coat side) toward the surface of the spectacle lens using the vapor deposition sources shown in Table 1 for the first and second layers.
- the outermost layer on the front side of the spectacle lens is the seventh layer.
- an evaporation source made of the following oxides was used except for impurities that might be inevitably mixed.
- the reflection spectral characteristics were controlled by changing the thickness of one or more of the following layers.
- a spectrophotometer F10-AR manufactured by Filmetrics Co., Ltd. was used in a wavelength range of 280 to 780 nm.
- the spectral reflection spectrum was measured (measuring pitch: 1 nm).
- the non-measurement surface was painted in glossless black as described in Section 5.2 of JIS T 7334.
- FIG. 1 is a diagram showing a spectral reflection spectrum obtained by measurement on the object-side surface and the eyeball-side surface of the spectacle lens of Example 1.
- Table 2 below summarizes the average reflectance on the object-side surface and the eyeball-side surface for each wavelength band, and the sum of the average reflectance on each surface.
- each condition of the average reflectance in the spectacle lens of one embodiment of the present invention is satisfied.
- the wearer did not recognize the multiple reflection light in the blue region.
- the present invention is useful in the field of manufacturing spectacle lenses and spectacles.
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- Health & Medical Sciences (AREA)
- Ophthalmology & Optometry (AREA)
- General Physics & Mathematics (AREA)
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- Spectroscopy & Molecular Physics (AREA)
- Eyeglasses (AREA)
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Abstract
Description
本発明の第1の態様は、
レンズ基材の両面に多層膜を備える眼鏡レンズであって、
前記眼鏡レンズの各面における400~440nmの波長帯域での平均反射率の和は20.0%以上であり、
前記眼鏡レンズの各面の反射率は前記波長帯域に少なくとも一つの極大値を有し、
前記波長帯域において、前記眼鏡レンズの一面における平均反射率と、もう一面における平均反射率とで差がある、眼鏡レンズである。
前記波長帯域において、前記眼鏡レンズの一面における平均反射率に対する、もう一面における平均反射率の割合は、0を超え且つ0.9以下である。
前記波長帯域において、前記眼鏡レンズの物体側の面における平均反射率は、眼球側の面における平均反射率よりも小さい。
前記眼鏡レンズの各面における500~570nmの波長帯域での平均反射率の和は1.0%以下である。
前記眼鏡レンズの各面における視感反射率の和は2.0%以下である。
前記眼鏡レンズの各面の反射率における最大の前記極大値の和は60.0%以下である。
前記眼鏡レンズの各面における各多層膜は、高屈折率層および低屈折率層をそれぞれ1層以上含み、且つ、層総数が10層以下である。
前記眼鏡レンズの各面における500~570nmの波長帯域での平均反射率の和は好適には1.0%未満、更に好適には0.5%以下である。
前記眼鏡レンズの各面における視感反射率の和は好適には2.0%未満、更に好適には1.8%以下である。
波長(横軸)と反射率(縦軸)との関係のプロットの所定の点aの前後10点(つまり点a含め合計21点)での反射率の移動平均をとり、その移動平均値を点aでの新たな反射率としてプロットの平滑化を行う場合、前記眼鏡レンズの各面の反射率は400~440nmの波長帯域に少なくとも一つの極大値を有するのが好ましい。
前記400~440nmの波長帯域の極大値(極大値が複数の場合は最大の極大値)は、好ましくは、前記400~440nmの波長帯域における最大値でもある。
前記眼鏡レンズの各面における各多層膜は、高屈折率層および低屈折率層をそれぞれ1層以上含み、且つ、層総数が好ましくは9層以下であり、更に好ましくは8層以下である。
前記眼鏡レンズの各面における400~440nmの波長帯域での平均反射率の和は20.0%以上、好適には20.0%を超え、更に好適には25%以上である。
前記眼鏡レンズの各面における360~400nmの波長帯域での平均反射率の和は6.0%以下、好適には6.0%未満、更に好適には5.0%以下である。
前記眼鏡レンズの各面における480~680nmの波長帯域での平均反射率の和は2.0%以下、好適には2.0%未満、更に好適には1.5%以下である。
400~440nmの波長帯域において、前記眼鏡レンズの一面における平均反射率に対する、もう一面における平均反射率の割合は、0.3(または0.4)~0.9である。
400~440nmの波長帯域において、前記眼鏡レンズの一面における平均反射率に対する、もう一面における平均反射率の割合は、0を超え且つ0.3未満(または0.4未満)である。
400~440nmの波長帯域において、前記眼鏡レンズの一面における平均反射率に対する、もう一面における平均反射率の割合は、0.9を超え且つ1.0未満である。
[本発明の一態様に係る眼鏡レンズ]
本発明の一態様に係る眼鏡レンズは、
レンズ基材の両面に多層膜を備える眼鏡レンズであって、
前記眼鏡レンズの各面における400~440nmの波長帯域での平均反射率の和は20.0%以上であり、
前記眼鏡レンズの各面の反射率は前記波長帯域に少なくとも一つの極大値を有し、
前記波長帯域において、前記眼鏡レンズの一面における平均反射率と、もう一面における平均反射率とで差がある、眼鏡レンズである。
以下、本発明の一態様の好適例について説明し、本発明の一態様に係る眼鏡レンズの構成の詳細について説明する。
上記眼鏡レンズにおいて、レンズ基材の眼球側の面および物体側の面にそれぞれ設けられた多層膜は、眼鏡レンズに上記の反射分光特性を付与することができる。上記多層膜は、レンズ基材の表面上に、直接または一層以上の他の層を介して間接的に設けられる。レンズ基材は、特に限定されないが、ガラス、または、(メタ)アクリル樹脂をはじめとするスチレン樹脂、ポリカーボネート樹脂、アリル樹脂、ジエチレングリコールビスアリルカーボネート樹脂(CR-39)等のアリルカーボネート樹脂、ビニル樹脂、ポリエステル樹脂、ポリエーテル樹脂、イソシアネート化合物とジエチレングリコールなどのヒドロキシ化合物との反応で得られたウレタン樹脂、イソシアネート化合物とポリチオール化合物とを反応させたチオウレタン樹脂、分子内に1つ以上のジスルフィド結合を有する(チオ)エポキシ化合物を含有する重合性組成物を硬化して得られる透明樹脂等を挙げることができる。また、無機ガラスも使用可能である。なおレンズ基材としては、染色されていないもの(無色レンズ)を用いてもよく、染色されているもの(染色レンズ)を用いてもよい。レンズ基材の屈折率は、例えば、1.60~1.75程度である。ただしレンズ基材の屈折率は、これに限定されるものではなく、上記の範囲内でも、上記の範囲から上下に離れていてもよい。
第一層(低屈折率層)/第二層(高屈折率層)/第三層(低屈折率層)/第四層(高屈折率層)/第五層(低屈折率層)/第六層(高屈折率層)/第七層(低屈折率層)の順に積層された構成;
第一層(高屈折率層)/第二層(低屈折率層)/第三層(高屈折率層)/第四層(低屈折率層)/第五層(高屈折率層)/第六層(低屈折率層)の順に積層された構成、
等を挙げることができる。好ましい低屈折率層と高屈折率層の組み合わせの一例としては、ケイ素酸化物を主成分とする被膜とジルコニウム酸化物を主成分とする被膜との組み合わせ、ケイ素酸化物を主成分とする被膜とニオブ酸化物を主成分とする被膜との組み合わせを挙げることができ、これら二層の被膜が隣接する積層構造を少なくとも1つ含む多層膜を、多層膜の好ましい一例として例示することができる。
本発明の更なる態様は、上記の本発明の一態様に係る眼鏡レンズと、この眼鏡レンズを取り付けたフレームとを有する眼鏡を提供することもできる。眼鏡レンズについては、先に詳述した通りである。その他の眼鏡の構成については、特に制限はなく、公知技術を適用することができる。
本発明の更なる態様は、上記の本発明の一態様に係る眼鏡レンズの製造方法を提供することもできる。
両面が光学的に仕上げられ予めハードコートが施された、物体側の面が凸面、眼球側の面が凹面であるプラスチックレンズ基材(HOYA株式会社製商品名HL、屈折率1.50、無色レンズ)の凸面側(物体側)のハードコート表面に、アシストガスとして酸素ガス(O2)および窒素ガス(N2)を用いて、イオンアシスト蒸着により合計7層の多層蒸着膜を順次形成した。
Claims (7)
- レンズ基材の両面に多層膜を備える眼鏡レンズであって、
前記眼鏡レンズの各面における400~440nmの波長帯域での平均反射率の和は20.0%以上であり、
前記眼鏡レンズの各面の反射率は前記波長帯域に少なくとも一つの極大値を有し、
前記波長帯域において、前記眼鏡レンズの一面における平均反射率と、もう一面における平均反射率とで差がある、眼鏡レンズ。 - 前記波長帯域において、前記眼鏡レンズの一面における平均反射率に対する、もう一面における平均反射率の割合は、0を超え且つ0.9以下である、請求項1に記載の眼鏡レンズ。
- 前記波長帯域において、前記眼鏡レンズの物体側の面における平均反射率は、眼球側の面における平均反射率よりも小さい、請求項1または2に記載の眼鏡レンズ。
- 前記眼鏡レンズの各面における500~570nmの波長帯域での平均反射率の和は1.0%以下である、請求項1~3のいずれかに記載の眼鏡レンズ。
- 前記眼鏡レンズの各面における視感反射率の和は2.0%以下である、請求項1~4のいずれかに記載の眼鏡レンズ。
- 前記眼鏡レンズの各面の反射率における前記極大値の和は60.0%以下である、請求項5に記載の眼鏡レンズ。
- 前記眼鏡レンズの各面における各多層膜は、高屈折率層および低屈折率層をそれぞれ1層以上含み、且つ、層総数が10層以下である、請求項1~6のいずれかに記載の眼鏡レンズ。
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JP2020549425A JP7136908B2 (ja) | 2018-09-28 | 2019-09-27 | 眼鏡レンズ |
CN201980063269.5A CN112840264B (zh) | 2018-09-28 | 2019-09-27 | 眼镜镜片 |
KR1020237042820A KR20230172041A (ko) | 2018-09-28 | 2019-09-27 | 안경 렌즈 |
EP19864195.3A EP3859435A4 (en) | 2018-09-28 | 2019-09-27 | Spectacle lens |
US17/279,906 US11835800B2 (en) | 2018-09-28 | 2019-09-27 | Spectacle lens |
KR1020217011750A KR102685727B1 (ko) | 2018-09-28 | 2019-09-27 | 안경 렌즈 |
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JP5586017B2 (ja) * | 2010-08-20 | 2014-09-10 | 東海光学株式会社 | 光学製品及び眼鏡プラスチックレンズ |
EP2602654B1 (en) * | 2011-12-08 | 2023-04-19 | Essilor International | Ophthalmic filter |
US10330953B2 (en) * | 2012-05-16 | 2019-06-25 | Essilor International | Ophthalmic lens |
EP2916148A4 (en) * | 2012-11-05 | 2016-10-05 | Nikon Essilor Co Ltd | OPTICAL COMPONENT, PROCESS FOR PREPARING THE OPTICAL COMPONENT AND METHOD FOR THE QUANTIFIED DETERMINATION OF IRRICHTILES |
CN108474966A (zh) * | 2016-03-31 | 2018-08-31 | 豪雅镜片泰国有限公司 | 眼镜镜片及眼镜 |
EP3859435A4 (en) | 2018-09-28 | 2022-06-29 | Hoya Lens Thailand Ltd. | Spectacle lens |
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JP2012093639A (ja) | 2010-10-28 | 2012-05-17 | Fuji Xerox Co Ltd | 画像形成装置 |
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