WO2018095693A1 - Verfahren zur herstellung einer gebogenen verbundglasscheibe mit einer dünnen glasscheibe - Google Patents
Verfahren zur herstellung einer gebogenen verbundglasscheibe mit einer dünnen glasscheibe Download PDFInfo
- Publication number
- WO2018095693A1 WO2018095693A1 PCT/EP2017/077562 EP2017077562W WO2018095693A1 WO 2018095693 A1 WO2018095693 A1 WO 2018095693A1 EP 2017077562 W EP2017077562 W EP 2017077562W WO 2018095693 A1 WO2018095693 A1 WO 2018095693A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- glass
- glass pane
- support
- pane
- glass sheet
- Prior art date
Links
- 239000011521 glass Substances 0.000 title claims abstract description 136
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 10
- 239000002131 composite material Substances 0.000 title claims abstract 4
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 29
- 239000004416 thermosoftening plastic Substances 0.000 claims abstract description 29
- 238000003475 lamination Methods 0.000 claims abstract description 13
- 239000005340 laminated glass Substances 0.000 claims description 36
- 238000000034 method Methods 0.000 claims description 29
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 claims description 6
- BFMKFCLXZSUVPI-UHFFFAOYSA-N ethyl but-3-enoate Chemical compound CCOC(=O)CC=C BFMKFCLXZSUVPI-UHFFFAOYSA-N 0.000 claims description 4
- 239000005361 soda-lime glass Substances 0.000 claims description 4
- 239000005354 aluminosilicate glass Substances 0.000 claims description 3
- 239000004814 polyurethane Substances 0.000 claims description 2
- 238000005452 bending Methods 0.000 description 18
- 230000000694 effects Effects 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 230000003287 optical effect Effects 0.000 description 4
- 238000013003 hot bending Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 230000032798 delamination Effects 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 238000005496 tempering Methods 0.000 description 2
- 238000013022 venting Methods 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000005358 alkali aluminosilicate glass Substances 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000005357 flat glass Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229910001414 potassium ion Inorganic materials 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- -1 steel or aluminum Chemical class 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
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- B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
- B32B17/10036—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheets
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- B32B17/10082—Properties of the bulk of a glass sheet
- B32B17/10119—Properties of the bulk of a glass sheet having a composition deviating from the basic composition of soda-lime glass, e.g. borosilicate
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- B32B17/10761—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing vinyl acetal
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- B32B37/18—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with all layers existing as coherent layers before laminating involving the assembly of discrete sheets or panels only
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- B60J1/00—Windows; Windscreens; Accessories therefor
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- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B29C51/00—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor
- B29C51/26—Component parts, details or accessories; Auxiliary operations
- B29C51/42—Heating or cooling
- B29C51/421—Heating or cooling of preforms, specially adapted for thermoforming
- B29C51/425—Heating or cooling of preforms, specially adapted for thermoforming using movable heating devices
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B29C65/48—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding
- B29C65/4805—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding characterised by the type of adhesives
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- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29C65/48—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding
- B29C65/486—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding characterised by their physical form being non-liquid, e.g. in the form of granules or powders
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- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/01—General aspects dealing with the joint area or with the area to be joined
- B29C66/05—Particular design of joint configurations
- B29C66/301—Three-dimensional joints, i.e. the joined area being substantially non-flat
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29C66/733—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the optical properties of the material of the parts to be joined, e.g. fluorescence, phosphorescence
- B29C66/7336—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the optical properties of the material of the parts to be joined, e.g. fluorescence, phosphorescence at least one of the parts to be joined being opaque, transparent or translucent to visible light
- B29C66/73365—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the optical properties of the material of the parts to be joined, e.g. fluorescence, phosphorescence at least one of the parts to be joined being opaque, transparent or translucent to visible light at least one of the parts to be joined being transparent or translucent to visible light
- B29C66/73366—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the optical properties of the material of the parts to be joined, e.g. fluorescence, phosphorescence at least one of the parts to be joined being opaque, transparent or translucent to visible light at least one of the parts to be joined being transparent or translucent to visible light both parts to be joined being transparent or translucent to visible light
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- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29C67/0011—Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00 for shaping plates or sheets
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- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
- B32B17/1077—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing polyurethane
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- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
- B32B17/10788—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing ethylene vinylacetate
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10807—Making laminated safety glass or glazing; Apparatus therefor
- B32B17/10889—Making laminated safety glass or glazing; Apparatus therefor shaping the sheets, e.g. by using a mould
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2605/00—Vehicles
- B32B2605/006—Transparent parts other than made from inorganic glass, e.g. polycarbonate glazings
Definitions
- the invention relates to a method for producing a curved laminated glass pane, a laminated glass pane produced therewith and their use.
- Laminated glass panes are common as vehicle glazing, especially as windscreens or roof windows. They consist of two glass panes, which are connected to each other via a thermoplastic intermediate layer. Typical thicknesses of glass sheets in conventional laminated glass are about 2 mm. Glazing in the vehicle area are often bent. The relatively thick individual glass panes of conventional laminated glass panes are first heated to the softening temperature and bent. After solidification, they exhibit a dimensionally stable bend and are then laminated to the laminated glass pane. In order to optimally match the shape of the two glass panes to be joined, they can be bent together in pairs, simultaneously congruent. Such bending methods are known, for example, from EP 1 836 136 A1, EP 1 358 131 A1, EP 2 463 247 A1 and EP 2 463 248 A1.
- laminated glass panes which have a thin glass pane with a thickness of less than 1, 5 mm or even less than 1 mm.
- the thin glass sheets may be chemically tempered.
- thin glass panes require customized manufacturing processes. Classic bending of the thin glass panes is often difficult. On the one hand, the thin glass sheets are susceptible to breakage during handling, on the other hand they often have chemical compositions with high softening temperatures, which makes bending energy-intensive. If a thin and a thick glass sheet are to be laminated together, then they generally also have different compositions, with the widespread and favorable soda-lime glass being used for the thick glass pane and a thin glass pane being used for the thin glass pane Glass compositions selected for chemical tempering ability. The associated different softening temperatures of the two discs make a pairwise bending difficult or impossible.
- thin glass panes are so flexible even at room temperature that they can be cold-bent directly during lamination and the previous bending into a dimensionally stable form can be dispensed with. If, however, the glass sheets and the intermediate layer are simply stacked on top of each other, the unsconciled shape of the sheets and the restoring force of the cold-bent thin glass sheet result in a constant contact pressure which is not constant over the entire surface. This reduces the quality of the laminated glasses which are prone to optical defects and delamination.
- the present invention has for its object to provide an improved method for producing curved laminated glass with a thin glass sheet. It should be dispensed with a hot bending of the thin glass and still be guaranteed a high optical quality and mechanical bond stability.
- the object of the present invention is achieved by a method for producing a laminated glass according to the independent claim 1. Preferred embodiments will become apparent from the dependent claims.
- the laminated glass pane to be produced is intended to separate an interior, in particular a vehicle interior, from an external environment. So it is a window that is intended to be inserted into a window opening, in particular a window opening of a vehicle body. It is bent and comprises a first pane of glass and a second pane of glass, which are connected to one another via a thermoplastic intermediate layer.
- the first glass pane is a thin glass pane with a thickness of up to 1 mm.
- the second glass sheet has a thickness of greater than or equal to 1, 5 mm, as is common for conventional laminated glass.
- the thicker second pane of glass is traditionally pre-bent to its final shape. For this purpose, it is heated to at least its softening temperature and then deformed, that is, hot-bent.
- the thin first glass pane is not pre-bent (in the sense of hot bending), but rather when arranging the laminate to be laminated Layer stack clearly below its softening temperature brought from its initial plane state by mechanical pressure in the desired curved shape, that is cold bent.
- the defined shape and a uniform contact pressure within the layer stack are ensured by the use of a support mold according to the invention.
- the support form provides the desired flexure and counteracts restoring forces of the thin, resilient glass sheet, allowing the stack to be handled safely and laminated with high optical and mechanical quality.
- the process according to the invention comprises at least the following process steps:
- thermoplastic film which is larger than the glass sheets and projects beyond this, and to cut off the projecting parts of the film after lamination.
- the process steps are preferably carried out in the order given. But there are also variations conceivable. It is thus possible first to place the thermoplastic film on the first glass pane and then to place both together with the first glass pane facing down onto the supporting mold. It is also possible to place the second glass sheet on the thermoplastic intermediate layer and then to deposit both with downwardly facing thermoplastic film on the first glass sheet located on the support mold. Of course, the entire layer stack of first glass sheet, thermoplastic film and second glass sheet must be placed on the support mold before it is further handled and ultimately laminated.
- the support mold according to the invention provides the desired final shape of the laminated glass pane. It has a curved contact surface or contact points, which span a curved surface, wherein the bend of the contact surface or the clamped surface corresponds to the desired bending of the laminated glass pane.
- the first glass sheet and the thermoplastic film are applied to the contact surface or the contact points and are thus brought into the desired shape. Since this bending of the first glass sheet takes place well below its softening temperature and preferably at ambient temperature without active heating, the bending process is referred to as cold bending. Cold bending is possible due to the flexibility and elasticity of the thin glass sheet without glass breakage.
- the support form may basically be concave or convex, but is preferably convex. This means that the contact surface of the support mold or the surface spanned by the contact points is convex so that the surface of the first glass pane facing the support mold is concave and the surface of the first glass pane facing away from the support form is convexly bent. Accordingly, a laminated glass pane is produced with a convex support form in which the surface of the thin first glass pane facing away from the intermediate layer is concave and the surface of the thicker second glass pane facing away from the intermediate layer is convexly shaped.
- the convex support form allows laminated glass panes where the thin first glass sheet is the inner pane and the thicker second glass pane the outer pane, which is usually preferred for reasons of stone chip and scratch resistance.
- outer pane is referred to in the context of the invention that glass pane, which is intended to be facing in installation position of the external environment.
- inner pane that glass pane is referred to, which is intended to be facing the interior in the installed position.
- the designations on the outside and on the inside are also to be understood.
- the second glass pane When placed on the support form, the second glass pane already has essentially its final curved shape.
- the second glass sheet is previously heated in its original plan initial state at least to softening temperature, bent and cooled to solidify. Suitable for this purpose are all common glass bending processes, for example gravity, compression or suction bending.
- the bend of the second glass sheet substantially corresponds to the bending of the contact surface of the support mold.
- the application of the first glass sheet to the support mold can be done solely under pressure, either only by the weight of the second glass or in addition by mechanical pressure exerted from above.
- the first glass sheet is sucked by applying a negative pressure to the support mold and thereby bent.
- the support form must be equipped with a means for generating a negative pressure or suitable connectable.
- negative pressure is meant a pressure which is lower than the ambient pressure. This can be advantageous in terms of handling or processing speed.
- the support form can be designed in various ways.
- the support form has a bearing surface for the first glass pane.
- the first glass pane When the first glass pane is placed on the support mold, it is essentially in contact with the entire surface of the support surface. Areas of the disc may be excluded from the contact with the support surface, for example, an over the support surface protruding edge region or areas of the disc, which are arranged over interruptions of the support surface. Such interruptions may arise, for example, through openings, holes or passages in the support surface, over which the support form preferably has, in order to exert a suction effect on the first glass pane and to suck it to the curved support surface for cold bending.
- the holes are connected to a means for generating a negative pressure, by which the suction effect is generated.
- a means for generating a negative pressure by which the suction effect is generated.
- at least 80% or even at least 90% of the disk surface is in contact with the support surface.
- the support surface may be padded, for example by a cover or a support made of a fabric.
- the support form has a plurality of support pins, on which the first glass pane rests substantially punctiform.
- the support form then has no contact surface in the true sense, but a plurality of contact points, which span a curved surface corresponding to the shape of the cold-bent glass sheet.
- the contact points are formed by the contact of the glass sheet with the upwardly facing ends of the contact pins.
- they are not points in the strictly mathematical sense, but have a finite one Extension so that each pin has a small contact area, which is preferably at most 10 cm 2 , more preferably at most 4 cm 2 .
- the totality of all contact surfaces is much smaller than the extent of the glass pane.
- the proportion of the glass pane surface which is in direct contact with the support pins is for example less than 10%.
- the support pins may have openings through which a suction effect can be transmitted to the glass to suck it to the support pins.
- the number and the distances of the support pins can be suitably selected by the person skilled in the art according to the complexity of the disc bending.
- the support form should have at least five support pins, wherein four support pins are assigned to the corner regions of the glass and a support pin is assigned to the center of the disk.
- the number of support pins depends on the size and geometry of the disc in each case and can be selected accordingly by the expert. Sufficient support pins should be used so that there is no local bending of the glass.
- At least two of the support pins are actively heated, preferably a plurality of support pins particularly preferably at least three support pins and most preferably at least 5 support pins.
- the support pins can be equipped with heating coils for example. Due to the heatable support pins, the applied layer stack can be heated in the area of the contact points. At a suitable temperature, a point bonding of the two glass panes over the thermoplastic film can thus be achieved. By gluing at two points, the layer stack is secured against slipping. A larger number of heatable support pins further increases the stability of the layer stack. It may be advantageous to exert an additional mechanical contact pressure from above. Thus, a precompound is produced which fixes the shape of the layer stack reached on the support form.
- the layer stack can then be removed from the support mold and be laminated to the laminated glass regardless of the support form, optionally after additional processing steps.
- An advantage of the support pins over a support surface is that the same support form can be adapted to different disc shapes and therefore more versatile.
- the support pins are movable independently of one another along their extension direction. This allows their height to be changed. It is likewise advantageous to make at least a part of the support pins or all support pins movable in the plane perpendicular to their extension direction. As a result, their relative position on the disc is changed and adapted to the geometry of the laminated glass to be produced.
- the support pins are therefore movable independently of each other in a preferred embodiment, in their extension direction and / or perpendicular to their extension direction.
- the support mold is preferably provided with means for moving the support pins, for example with threaded spindles or servomotors for moving the support pins or mechanical, hydraulic or pneumatic means for raising and lowering the support pins.
- the support mold can be adjusted to a disk shape by moving the support pins so that their contact points span a surface corresponding to the disk shape.
- the movement of the support pins can be done manually or automatically. So it is conceivable that in the context of an industrial mass production, the geometric values of the disc are read into a software, which in turn controls the support pins and adapts the support form to the disc geometry.
- the material of the support form in particular the contact surface or the support pins, there are no restrictions as long as the support form is stable enough to support the layer stack. Since there is no hot bend on the support form, it also does not have to be heat resistant.
- the materials can therefore be chosen freely by the skilled person in individual cases. Suitable materials include metals or alloys such as steel or aluminum, but also wood or plastics.
- the thin first glass pane preferably has a thickness of 0.2 mm to 1, 0 mm, more preferably 0.4 mm to 0.7 mm. Such thin glass panes are easy to cold bend.
- the first pane of glass may be cured to increase its breaking strength, making handling during cold bending easier. Since glass sheets with these small thicknesses can not or only with great difficulty be thermally prestressed, the first glass sheet is preferably chemically tempered.
- the first glass pane preferably consists of a glass type, which can be well chemically biased.
- the first glass pane is therefore preferably made of aluminosilicate glass, in particular of alkali aluminosilicate glass. Chemical tempering is accomplished by replacing smaller ones with larger alkali ions (eg, sodium versus potassium ions) to produce depth-dependent compressive stresses. In addition, this type of glass is characterized by high scratch resistance and hardness.
- the second glass sheet is preferably made of soda-lime glass, which is common as window glass and therefore widely used and relatively inexpensive.
- the second glass pane can also be made of other types of glass.
- the thickness of the second glass pane is preferably from 1, 5 mm to 5 mm. A second pane with these thicknesses results in the thin first glass pane a laminated glass, which is suitable in terms of its stability and overall thickness as vehicle glazing.
- the thermoplastic film preferably contains polyvinyl butyral (PVB), ethyl vinyl acetate (EVA) or polyurethane (PU), more preferably PVB. It preferably has a thickness of 0.2 to 2 mm, in particular 0.5 mm to 1, 6 mm.
- PVB polyvinyl butyral
- EVA ethyl vinyl acetate
- PU polyurethane
- the bonding of the glass panes over the thermoplastic intermediate layer can be carried out by all common lamination methods.
- Lamination typically occurs under the action of temperature, pressure and / or vacuum.
- the lamination comprises venting the layer stack, applying a vacuum to remove air from the gap between the glass sheets and the thermoplastic films, and heating the layer stack, wherein the thermoplastic film softens and forms the adhesive bond to the disk surface.
- vacuum bag methods can be used, in which the layer stack is arranged in a bag in which a negative pressure is then generated.
- vacuum ring methods can be used in which the side edge is provided with a circulating hose in which a negative pressure is generated.
- the production of the final adhesive compound can be carried out in an autoclave in which the vented layer stack is preferably heated and subjected to overpressure.
- the lamination can be done on the support mold where the bent shape is stabilized.
- the disc can also be removed from the support mold for lamination, provided that the curved shape is stabilized by other measures, for example by the above-described local bonding by heated support pins.
- the invention also encompasses a laminated glass pane produced or producible by the process according to the invention, comprising a first glass pane having a thickness of less than or equal to 1 mm and a second glass pane having a thickness greater than or equal to 1.5 mm and connected via at least one thermoplastic film are.
- the invention also includes an apparatus for producing a laminated glass sheet according to the invention, comprising a support mold defining the desired final shape of the laminated glass pane, and means for laminating the laminated glass pane.
- the invention also encompasses the use of a laminated glass pane produced by the method according to the invention as a window pane of a vehicle, for example as a windshield, side window, rear window or roof window.
- the thin first glass pane preferably forms the inner pane of the laminated glass pane and faces the vehicle interior, while the thicker second glass pane faces the outer environment.
- FIG. 1 is a plan view of an embodiment of the support mold according to the invention with the applied first glass sheet
- FIG. 3 is a plan view of a further embodiment of the support mold according to the invention with the first glass pane
- FIG. 4 shows a cross section through the support form according to FIG. 3,
- FIG. 5 shows a cross section through the support form according to FIG. 3 with the entire layer stack applied before lamination, FIG.
- Fig. 6 shows an embodiment of the method according to the invention with reference to a
- FIGS. 1 and 2 each show a detail of an embodiment of the support form 4 according to the invention.
- the support form 4 has a substantially full-area contact surface which is interrupted only by small openings 5.
- a first glass pane 1 is arranged on the contact surface of the support mold 4.
- the first glass pane 1 is, for example, a 0.6 mm thick, chemically tempered pane of aluminosilicate glass.
- the convex contact surface of the support mold 4 has a curvature which corresponds to the desired curvature of the laminated glass pane.
- the first glass pane 1 is flat in the initial state, adapts to the contact surface due to its small thickness and the associated flexibility and is bent (cold bent) at ambient temperature without active heating.
- the openings 5 may be connected to a means for generating a negative pressure, for example a fan or a vacuum pump. Thereby, a suction effect can be generated by which the first glass pane 1 is sucked to the contact surface of the support mold 4.
- a means for generating a negative pressure for example a fan or a vacuum pump.
- FIGS. 3 and 4 each show a detail of a further embodiment of the support form 4 according to the invention.
- the support form 4 has no large-area contact surface but a plurality of support pins 6.
- the upper ends of the support pins 6 clamp a curved surface whose curvature corresponds to the desired curvature of the laminated glass pane.
- a first glass pane 1 rests substantially punctually on each support pin 6, a large-area direct contact between the support form and the glass pane 1 is avoided.
- the layer stack can be adhesively bonded locally in the area of the support points. As a result, a local bond can be produced, so that a kind of pre-bond is formed and the layer stack is stabilized in its curved shape and can be removed from the support mold 4.
- the same support form 4 can be used to produce various types of laminated glass.
- the layer stack comprises a thermoplastic film 3 on the first glass pane 1 and a second glass pane 2 on the thermoplastic film 3.
- the thermoplastic film 3 is, for example, a 0.76 mm thick PVB film.
- the second glass pane 2 is for example a 2.1 mm thick slice of soda-lime glass. Due to its thickness, the second glass pane 2 is not sufficiently flexible to be cold-bent and is therefore already pre-bent into the final shape by means of conventional hot-bending processes, for example by means of press bending.
- FIG. 6 shows an exemplary embodiment of the method according to the invention for producing a laminated glass pane on the basis of a flow chart.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Fluid Mechanics (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Joining Of Glass To Other Materials (AREA)
- Laminated Bodies (AREA)
Abstract
Description
Claims
Priority Applications (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US16/463,745 US11192341B2 (en) | 2016-11-24 | 2017-10-27 | Method for producing a curved composite glass pane having a thin glass pane |
CA3042439A CA3042439C (en) | 2016-11-24 | 2017-10-27 | Method for producing a curved composite glass pane having a thin glass pane |
MX2019006016A MX2019006016A (es) | 2016-11-24 | 2017-10-27 | Metodo para producir un cristal de vidrio compuesto curvo que tiene un cristal de vidrio delgado. |
RU2019105061A RU2720685C1 (ru) | 2016-11-24 | 2017-10-27 | Способ получения гнутого многослойного оконного стекла, содержащего тонкий стеклянный лист |
CN201780003130.2A CN108602324B (zh) | 2016-11-24 | 2017-10-27 | 制造具有薄玻璃质玻璃板的弯曲的复合玻璃质玻璃板的方法 |
EP17791087.4A EP3544809B1 (de) | 2016-11-24 | 2017-10-27 | Verfahren zur herstellung einer gebogenen verbundglasscheibe mit einer dünnen glasscheibe |
KR1020197017778A KR102244653B1 (ko) | 2016-11-24 | 2017-10-27 | 얇은 유리판을 갖는 구부러진 복합유리판을 제조하는 방법 |
JP2019528115A JP6898446B2 (ja) | 2016-11-24 | 2017-10-27 | 薄いガラスペインを有する湾曲複合ガラスペインの製造方法 |
BR112019000952A BR112019000952A2 (pt) | 2016-11-24 | 2017-10-27 | método para produzir um painel de vidro compósito curvo com um painel de vidro fino |
Applications Claiming Priority (2)
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EP16200376.8 | 2016-11-24 | ||
EP16200376 | 2016-11-24 |
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PCT/EP2017/077562 WO2018095693A1 (de) | 2016-11-24 | 2017-10-27 | Verfahren zur herstellung einer gebogenen verbundglasscheibe mit einer dünnen glasscheibe |
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US (1) | US11192341B2 (de) |
EP (1) | EP3544809B1 (de) |
JP (1) | JP6898446B2 (de) |
KR (1) | KR102244653B1 (de) |
CN (1) | CN108602324B (de) |
BR (1) | BR112019000952A2 (de) |
CA (1) | CA3042439C (de) |
MA (1) | MA46872A (de) |
MX (1) | MX2019006016A (de) |
RU (1) | RU2720685C1 (de) |
WO (1) | WO2018095693A1 (de) |
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WO2019008470A1 (en) * | 2017-07-02 | 2019-01-10 | Agp America S.A. | METHOD OF THIN GLASS STRATIFICATION WITH PRESSURE PLATE |
US10450215B2 (en) | 2017-02-20 | 2019-10-22 | Corning Incorporated | Shaped glass laminates and methods for forming the same |
DE102019208638A1 (de) | 2018-06-20 | 2019-12-24 | Haverkamp Gmbh | Vorrichtung zum flächigen Abstützen einer gekrümmten Glasscheibe beim Herstellen einer gekrümmten Verbundglasscheibe sowie Verbundglasscheibe |
US11236003B2 (en) | 2017-10-18 | 2022-02-01 | Corning Incorporated | Methods for controlling separation between glasses during co-sagging to reduce final shape mismatch therebetween |
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2017
- 2017-10-27 CN CN201780003130.2A patent/CN108602324B/zh active Active
- 2017-10-27 MA MA046872A patent/MA46872A/fr unknown
- 2017-10-27 EP EP17791087.4A patent/EP3544809B1/de active Active
- 2017-10-27 KR KR1020197017778A patent/KR102244653B1/ko active IP Right Grant
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- 2017-10-27 US US16/463,745 patent/US11192341B2/en active Active
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US10450215B2 (en) | 2017-02-20 | 2019-10-22 | Corning Incorporated | Shaped glass laminates and methods for forming the same |
US10773988B2 (en) | 2017-02-20 | 2020-09-15 | Corning Incorporated | Shaped glass laminates |
US10954154B2 (en) | 2017-02-20 | 2021-03-23 | Corning Incorporated | Shaped glass laminates and methods for forming the same |
US11465927B2 (en) | 2017-02-20 | 2022-10-11 | Corning Incorporated | Shaped glass laminates |
US11987516B2 (en) | 2017-02-20 | 2024-05-21 | Corning Incorporated | Shaped glass laminates |
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US11236003B2 (en) | 2017-10-18 | 2022-02-01 | Corning Incorporated | Methods for controlling separation between glasses during co-sagging to reduce final shape mismatch therebetween |
DE102019208638A1 (de) | 2018-06-20 | 2019-12-24 | Haverkamp Gmbh | Vorrichtung zum flächigen Abstützen einer gekrümmten Glasscheibe beim Herstellen einer gekrümmten Verbundglasscheibe sowie Verbundglasscheibe |
EP3593994A2 (de) | 2018-06-20 | 2020-01-15 | Haverkamp GmbH | Vorrichtung zum flächigen abstützen einer gekrümmten glasscheibe beim herstellen einer gekrümmten verbundglasscheibe sowie verbundglasscheibe |
EP3593994A3 (de) * | 2018-06-20 | 2020-02-19 | Haverkamp GmbH | Vorrichtung zum flächigen abstützen einer gekrümmten glasscheibe beim herstellen einer gekrümmten verbundglasscheibe sowie verbundglasscheibe |
Also Published As
Publication number | Publication date |
---|---|
EP3544809A1 (de) | 2019-10-02 |
CA3042439A1 (en) | 2018-05-31 |
US11192341B2 (en) | 2021-12-07 |
JP2020513389A (ja) | 2020-05-14 |
RU2720685C1 (ru) | 2020-05-12 |
MX2019006016A (es) | 2019-08-01 |
EP3544809B1 (de) | 2023-06-14 |
KR20190082946A (ko) | 2019-07-10 |
CA3042439C (en) | 2021-02-16 |
KR102244653B1 (ko) | 2021-04-26 |
BR112019000952A2 (pt) | 2019-06-11 |
US20190389180A1 (en) | 2019-12-26 |
JP6898446B2 (ja) | 2021-07-07 |
CN108602324A (zh) | 2018-09-28 |
CN108602324B (zh) | 2021-09-10 |
MA46872A (fr) | 2019-10-02 |
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