WO2015018280A1 - 橡胶母炼胶的连续式制造方法及该方法制备的橡胶母炼胶 - Google Patents
橡胶母炼胶的连续式制造方法及该方法制备的橡胶母炼胶 Download PDFInfo
- Publication number
- WO2015018280A1 WO2015018280A1 PCT/CN2014/082712 CN2014082712W WO2015018280A1 WO 2015018280 A1 WO2015018280 A1 WO 2015018280A1 CN 2014082712 W CN2014082712 W CN 2014082712W WO 2015018280 A1 WO2015018280 A1 WO 2015018280A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- rubber
- drying
- filler
- masterbatch
- mixture
- Prior art date
Links
- 229920001971 elastomer Polymers 0.000 title claims abstract description 89
- 239000005060 rubber Substances 0.000 title claims abstract description 89
- 239000004594 Masterbatch (MB) Substances 0.000 title claims abstract description 35
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 15
- 239000000945 filler Substances 0.000 claims abstract description 58
- 239000000203 mixture Substances 0.000 claims abstract description 40
- 239000002904 solvent Substances 0.000 claims abstract description 32
- 238000000034 method Methods 0.000 claims abstract description 24
- 239000006185 dispersion Substances 0.000 claims abstract description 18
- 238000003756 stirring Methods 0.000 claims abstract description 7
- 239000011877 solvent mixture Substances 0.000 claims abstract description 5
- 238000001035 drying Methods 0.000 claims description 35
- 238000010438 heat treatment Methods 0.000 claims description 20
- 239000000654 additive Substances 0.000 claims description 18
- 239000003795 chemical substances by application Substances 0.000 claims description 14
- 239000000178 monomer Substances 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- 239000003963 antioxidant agent Substances 0.000 claims description 10
- 230000015572 biosynthetic process Effects 0.000 claims description 8
- 239000007822 coupling agent Substances 0.000 claims description 8
- 239000011261 inert gas Substances 0.000 claims description 8
- 238000011084 recovery Methods 0.000 claims description 8
- 238000003786 synthesis reaction Methods 0.000 claims description 8
- 239000003292 glue Substances 0.000 claims description 7
- 230000003712 anti-aging effect Effects 0.000 claims description 6
- 230000003078 antioxidant effect Effects 0.000 claims description 6
- 239000003921 oil Substances 0.000 claims description 6
- 238000007605 air drying Methods 0.000 claims description 5
- 239000000049 pigment Substances 0.000 claims description 5
- 239000013543 active substance Substances 0.000 claims description 4
- 239000000975 dye Substances 0.000 claims description 4
- 238000001125 extrusion Methods 0.000 claims description 4
- 239000003063 flame retardant Substances 0.000 claims description 4
- 239000012760 heat stabilizer Substances 0.000 claims description 4
- 239000004611 light stabiliser Substances 0.000 claims description 4
- 238000001291 vacuum drying Methods 0.000 claims description 4
- 238000005194 fractionation Methods 0.000 claims description 3
- 239000008247 solid mixture Substances 0.000 claims description 3
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 2
- 238000000643 oven drying Methods 0.000 claims 2
- 238000001704 evaporation Methods 0.000 claims 1
- 230000014759 maintenance of location Effects 0.000 claims 1
- 238000001694 spray drying Methods 0.000 claims 1
- 238000002156 mixing Methods 0.000 abstract description 7
- 150000001875 compounds Chemical class 0.000 abstract description 6
- 230000008569 process Effects 0.000 abstract description 6
- 238000005265 energy consumption Methods 0.000 abstract description 3
- 238000005516 engineering process Methods 0.000 abstract description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 18
- 230000000996 additive effect Effects 0.000 description 16
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 14
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 239000006229 carbon black Substances 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- 238000000227 grinding Methods 0.000 description 7
- 239000000377 silicon dioxide Substances 0.000 description 7
- 239000011787 zinc oxide Substances 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- 239000003607 modifier Substances 0.000 description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 239000006087 Silane Coupling Agent Substances 0.000 description 5
- 235000021355 Stearic acid Nutrition 0.000 description 5
- 230000004048 modification Effects 0.000 description 5
- 238000012986 modification Methods 0.000 description 5
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 5
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 5
- 229920001195 polyisoprene Polymers 0.000 description 5
- 239000008117 stearic acid Substances 0.000 description 5
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 4
- 238000013019 agitation Methods 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 239000012071 phase Substances 0.000 description 4
- 229910052717 sulfur Inorganic materials 0.000 description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- 238000005054 agglomeration Methods 0.000 description 3
- 230000002776 aggregation Effects 0.000 description 3
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- -1 ethylene, propylene, butene Chemical class 0.000 description 3
- 125000000524 functional group Chemical group 0.000 description 3
- 239000000499 gel Substances 0.000 description 3
- 230000020169 heat generation Effects 0.000 description 3
- 238000004898 kneading Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- OWRCNXZUPFZXOS-UHFFFAOYSA-N 1,3-diphenylguanidine Chemical compound C=1C=CC=CC=1NC(=N)NC1=CC=CC=C1 OWRCNXZUPFZXOS-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 239000005062 Polybutadiene Substances 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- 150000001721 carbon Chemical group 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 150000001924 cycloalkanes Chemical class 0.000 description 2
- 125000004185 ester group Chemical group 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N methylene hexane Natural products CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 2
- DEQZTKGFXNUBJL-UHFFFAOYSA-N n-(1,3-benzothiazol-2-ylsulfanyl)cyclohexanamine Chemical compound C1CCCCC1NSC1=NC2=CC=CC=C2S1 DEQZTKGFXNUBJL-UHFFFAOYSA-N 0.000 description 2
- 229920005615 natural polymer Polymers 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229920002857 polybutadiene Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000010092 rubber production Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229920001059 synthetic polymer Polymers 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- 238000004073 vulcanization Methods 0.000 description 2
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 1
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
- HKMVWLQFAYGKSI-UHFFFAOYSA-N 3-triethoxysilylpropyl thiocyanate Chemical compound CCO[Si](OCC)(OCC)CCCSC#N HKMVWLQFAYGKSI-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- 235000007516 Chrysanthemum Nutrition 0.000 description 1
- 244000189548 Chrysanthemum x morifolium Species 0.000 description 1
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229920000181 Ethylene propylene rubber Polymers 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- 239000000899 Gutta-Percha Substances 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- 229920000459 Nitrile rubber Polymers 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 240000000342 Palaquium gutta Species 0.000 description 1
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 229920006311 Urethane elastomer Polymers 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- KCXMKQUNVWSEMD-UHFFFAOYSA-N benzyl chloride Chemical compound ClCC1=CC=CC=C1 KCXMKQUNVWSEMD-UHFFFAOYSA-N 0.000 description 1
- 229910052810 boron oxide Inorganic materials 0.000 description 1
- 229920005549 butyl rubber Polymers 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 125000004093 cyano group Chemical group *C#N 0.000 description 1
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 1
- 150000001993 dienes Chemical group 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- JBTWLSYIZRCDFO-UHFFFAOYSA-N ethyl methyl carbonate Chemical compound CCOC(=O)OC JBTWLSYIZRCDFO-UHFFFAOYSA-N 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 229920000588 gutta-percha Polymers 0.000 description 1
- 150000002430 hydrocarbons Chemical group 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 229920002681 hypalon Polymers 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- WORCCYVLMMTGFR-UHFFFAOYSA-M loxoprofen sodium Chemical compound [Na+].C1=CC(C(C([O-])=O)C)=CC=C1CC1C(=O)CCC1 WORCCYVLMMTGFR-UHFFFAOYSA-M 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 150000001282 organosilanes Chemical class 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920001084 poly(chloroprene) Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 239000012763 reinforcing filler Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000004945 silicone rubber Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 229950011008 tetrachloroethylene Drugs 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 150000005671 trienes Chemical class 0.000 description 1
- NBXZNTLFQLUFES-UHFFFAOYSA-N triethoxy(propyl)silane Chemical compound CCC[Si](OCC)(OCC)OCC NBXZNTLFQLUFES-UHFFFAOYSA-N 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/30—Mixing; Kneading continuous, with mechanical mixing or kneading devices
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/30—Mixing; Kneading continuous, with mechanical mixing or kneading devices
- B29B7/58—Component parts, details or accessories; Auxiliary operations
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/74—Mixing; Kneading using other mixers or combinations of mixers, e.g. of dissimilar mixers ; Plant
- B29B7/7476—Systems, i.e. flow charts or diagrams; Plants
- B29B7/7495—Systems, i.e. flow charts or diagrams; Plants for mixing rubber
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/80—Component parts, details or accessories; Auxiliary operations
- B29B7/88—Adding charges, i.e. additives
- B29B7/90—Fillers or reinforcements, e.g. fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
- B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/12—Powdering or granulating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/12—Powdering or granulating
- C08J3/122—Pulverisation by spraying
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/205—Compounding polymers with additives, e.g. colouring in the presence of a continuous liquid phase
- C08J3/21—Compounding polymers with additives, e.g. colouring in the presence of a continuous liquid phase the polymer being premixed with a liquid phase
- C08J3/212—Compounding polymers with additives, e.g. colouring in the presence of a continuous liquid phase the polymer being premixed with a liquid phase and solid additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2309/00—Characterised by the use of homopolymers or copolymers of conjugated diene hydrocarbons
Definitions
- the invention relates to the field of rubber, in particular to a continuous manufacturing method of rubber masterbatch and a rubber masterbatch prepared by the method.
- the rubber/filler/additive is included in the solvent.
- the process described in W098/58985 is carried out in a large, bladed worm gear dryer at 400/1200 rpm, which results in slower agglomeration, long process life and high energy consumption.
- the present invention omits the agglomeration step, simplifies the process, and reduces costs.
- Another object of the present invention is to provide a continuous manufacturing method of a rubber master batch and a t-size masterbatch prepared by the method. Another object of the present invention is to provide a rubber article prepared using the t-size masterbatch of the present invention.
- the present invention has no requirements for rubber and filler, and the invention has a wide application range for the types and contents of rubber, fillers and additives;
- a continuous manufacturing method of a rubber masterbatch comprising the following steps:
- the drying in the step 2) means transferring the mixture obtained in the step 1) into a heated conveyor belt dryer, Heating and drying under vacuum or inert gas, the solvent and the unreacted monomer in the rubber synthesis are recycled into the condenser and the fractionation column for recovery; or the drying in step 2) means the step 1)
- the mixture is spray dried or flashed.
- the heating medium used is an inert gas or water vapor, and the volatilized solvent and unreacted monomers in the rubber synthesis enter the condenser and the column for recovery.
- step 1) wherein one or more selected from the group consisting of oils, antioxidants, antioxidants, coupling agents, active agents, flame retardants, heat stabilizers, light stabilizers, dyes, pigments are optionally added in step 1) , vulcanizing agents and additives for the agent.
- step 1) specifically adds a filler to the rubber solution, forms a rubber/filler/solvent mixture by stirring, and further finely disperses and finely disperses the rubber/filler/solvent mixture to increase the filler in the rubber solution. The degree of dispersion in the middle.
- the heating medium described in the step 2) is water vapor
- the solid mixture in the dry state has water therein, and then dried under vacuum, heated and dried, and heated to remove water to obtain a rubber/filler masterbatch. gum. More preferably, wherein the heat drying is drying or air drying.
- the extrusion heat drying is performed by first removing the heating medium and then drying it. More preferably, the drying step is air drying, drying or mechanical drying.
- the mechanical drying is carried out using an open mill, a kneader, an internal mixer, a continuous internal mixer, a single screw extruder, and twin screw extrusion.
- the invention also provides a t-size masterbatch prepared according to the above method.
- the present invention provides a rubber article prepared using a rubber masterbatch.
- the continuous manufacturing method of the rubber master batch of the present invention comprises the following steps:
- the drying in the step 2) means transferring the mixture obtained in the step 1) into a heated conveyor belt dryer, Heating and drying under vacuum or inert gas, the solvent and the unreacted monomer in the rubber synthesis are recycled into the condenser and the fractionation column for recovery; or the drying in step 2) means the step 1)
- the mixture is spray dried or flashed.
- the heating medium used is an inert gas or water vapor, and the volatilized solvent and unreacted monomers in the rubber synthesis enter the condenser and the column for recovery.
- the continuous manufacturing process of the rubber masterbatch of the present invention optionally further comprises the step of recovering the solvent removed in step 2) for recycling. Further, in step 1), one or more selected from the group consisting of oils, antioxidants, coupling agents, active agents, antioxidants, dyes, light stabilizers, flame retardants, heat stabilizers, pigments, and vulcanizing agents are optionally added. And ⁇ leg additive.
- Step 1) can be carried out using methods well known in the art.
- the agitation described in the step 1) can be carried out using a general agitator, including but not limited to a vane type agitation type agitation type planetary mixer, a zigzag type mixer, and the like.
- Step 1) may further comprise a fine dispersion step, the fine dispersion of the ruthenium may be carried out as follows: The mixture obtained by the above agitation is sprayed through a nozzle under high pressure and high shear to improve the filler and/or the additive. Dispersing; causing the above-mentioned effluent to pass through a multi-bend tube to cause the mixture to collide with the tube wall in the tube to increase the dispersibility of the filler and/or the additive; or to cause the effluent to pass through a tube having a plurality of tubes To shift the shear stress to increase the dispersion of the filler and/or additive.
- the pressure used ranges from 0.1 MPa to 60 MPa, preferably 10 MPa to 0 MPa.
- the mixture formed after the fine dispersion can further improve the filler and/or addition by the following fine dispersion.
- Dispersion of the agent in the rubber solution is a mixture formed after the fine dispersion of the agent in the rubber solution:
- the finely dispersed mixture is continuously added to a grinder for grinding to sufficiently disperse the filler and/or the additive in the rubber solution, the grinder having one or more sets of high-speed rotating flat grinding discs and fixed in the grinding A fixing pin or plate on the casing and between the flat grinding discs.
- the pressure used ranges from 0.1 MPa to 60 MPa, preferably 10 MPa to 40 MPa.
- the mixture after finely dispersing the legs is continuously added to the multi-layer high-pressure slit disperser, and the mixture is extruded under high pressure from the slit between the two layers, and the strong shear force generated at this time can increase the filler and / or the degree of dispersion of the additive in the rubber solution.
- the pressure used ranges from 0.1 MPa to 60 MPa, preferably 10 MPa to 0 MPa.
- the household; M finely dispersed mixture is continuously added to the power disperser for dispersion, the high-speed rotating rotor of the M-power disperser has a plurality of radially distributed slits or holes, and the mixture hits at a high speed.
- the surface of the stator is such that the filler and/or additive are uniformly dispersed in the gum solution.
- Two or more of the above five fine dispersion methods may be used in series with each other.
- the rubber solution of M can be directly obtained from the preparation of the solution rubber production line, and any type of dry glue can be prepared by dissolving in the solvent of the glue.
- the dry glue may be any kind of rubber used in the art, such as a natural polymer or a synthetic polymer.
- the natural polymer includes, but is not limited to, natural rubber, gutta percha, silver chrysanthemum, etc.; synthetic polymers including, but not limited to, monomers obtained by polymerization in a solution (ie, a solution rubber), and polymerization of monomers in an emulsion ( That is, the latex rubber) and the monomer body are obtained by polymerization.
- the M-soluble rubber is a diene using ethylene, propylene, butene, pentene, hexene, heptene, 4-7 carbon atoms.
- a homopolymer or copolymer of a triene of 6 to 7 carbon atoms or an ethylenic monomer having other atoms or functional groups, and other atoms or functional groups of the leg are silicon atoms, fluorine atoms, chlorine atoms, nitrogen atoms, oxygen atoms.
- sulfur atom, ester group, amino ester group, cyano group also includes homopolymers and copolymers containing the above monomers, including but not limited to polybutadiene, polyisoprene, styrene-butadiene rubber , Ethylene-propylene rubber, butyl rubber, nitrile rubber, neoprene, silicone rubber, fluorine rubber, urethane rubber, chlorosulfonated polyethylene rubber, acrylate rubber, etc.
- the amount of rubber is from 1 to 40 million, preferably from 5,000 to 30 million, more preferably from 10,000 to 8,000,000.
- the solvent in the Mt solution is a good solvent for various t-gels.
- the solvent may specifically be an aliphatic hydrocarbon solvent, an aromatic hydrocarbon solvent, a chlorinated hydrocarbon solvent, a ketone solvent, an ether solvent, and an ester solvent, and the aliphatic hydrocarbon solvent includes, but is not limited to, various solvents such as gasoline, cycloalkane, and substituted cycloalkane.
- M aromatic hydrocarbon solvent including but not limited to benzene, A Benzene, xylene, styrene, the chlorinated hydrocarbon solvent includes, but is not limited to, dichloromethane, chloroform, carbon tetrachloride, dichloroethane, chlorobenzene, tetrachloroethylene, chlorotoluene.
- concentration of the rubber in the solution ranges from 1% by weight to 60% by weight, preferably from 5% by weight to 0% by weight, more preferably from 10% by weight to 30% by weight.
- the fillers include, but are not limited to, various solid powdered reinforcing agents and fillers used in rubber, such as various types of carbon black, silica, metal oxides, salts, different resins, and nanoscale materials of the above fillers.
- the metal oxides include, but are not limited to, alumina, magnesia, zinc oxide, etc.
- the salts include, but are not limited to, carbonic acid, clay, and nanoscale materials of the above fillers.
- the specific surface area of the filler is 0.1 to 800m 2 / g, preferably from 1 to 500m 2 / g, more preferably 5 to 300 m 2 / g.
- the oil absorption value is from 20 to 250 ml / 100 g, preferably from 25 to 200 ml / 100 g, more preferably from 30 to 150 ml / 100 g, wherein the filler comprises a mixture thereof,
- multiphase fillers including but not limited to carbon black, silica, alumina, magnesia, zinc oxide, oxidized titanium oxide, boron oxide, etc., for two-phase or multi-phase fillers, for two-phase or multi-phase
- the oil absorption value is from 20 to 250 ml/100 g, preferably from 25 to 200 ml/100 g, more preferably from 30 to 150 ml/100 g.
- the filler is used in an amount of 5 to 300 parts by weight (based on 100 parts by weight of the rubber), preferably 10 to 200 parts by weight, more preferably 30 to 150 parts by weight.
- the filler also includes a combination of two or more of the above fillers.
- the filler of the legs also includes their surface modifying fillers.
- the surface modification of the leg may be a ship chemical reaction in which a certain functional group is attached to the surface of the filler or the modifier is physically bonded to the surface of the filler by mixing or adsorption.
- the modifier can be dissolved in a solvent and mixed with a filler, such as Wang W, Nanse G, Vidal A, et al. K. GK [J], 1994, 47:493 In the middle of the household; 3 ⁇ 4, the modifier and the filler may also be mixed and heated for solid phase modification, as described in Wang MJ, Wolff. SRCT [J], 1992, 65:715.
- the surface modification may also be carried out before the filler is added to the rubber solution, or the modifier may be added to the mixture of the rubber solution and the filler for surface modification.
- the modifier is a conventional modifier in the art, such as an organosilane coupling agent represented by the following formula: ( n- ( O ) 3- constructiveSi- (Alk) m - ( Ar) p ) q ( A) (I)
- A is -SCN, -SH, -CI, -NH 2 ;
- R and R' are a branched or linear alkyl or phenol group having from 1 to 4 carbon atoms, and R and R' may be the same or different;
- n 0, 1 or 2;
- Alk is a linear or branched hydrocarbon group having 1 to 1 carbon atom
- ⁇ 13 ⁇ 4 ⁇ 1 is a linear or branched alkenyl group having 1 to 1 carbon atom
- n 0 or 1;
- Ar is an aryl group having 6 to 12 carbon atoms;
- p is 0 or 1, p and n cannot be 0 at the same time;
- X is 2 to 8;
- the most commonly used are bis(triethoxypropylsilane) tetrasulfide and disulfide, 3-thiocyanopropyl-triethoxysilane, ⁇ -mercapto-trimethoxysilane, zirconate a coupling agent, a phthalate coupling agent, a nitro coupling agent, an alcohol compound, including but not limited to a unit alcohol, a glycol, a polyol, and a compound such as, but not limited to, propanol , butanol, ethylene glycol, polyethylene glycol and its derivatives.
- Step 1) of the present invention may directly add the filler and/or the additive to the rubber solution, or may first add the filler and/or the additive to the same or different solvent as the t-gel solution to form a uniform suspension, and then add and Mix into the rubber solution by stirring.
- the additive may optionally include one or more of an oil, an antioxidant, a coupling agent, an active agent, an antioxidant, a heat stabilizer, a light stabilizer, a flame retardant, a dye, a pigment, a vulcanizing agent, or an additive for an accelerator. .
- the amount of the additive used is a conventional amount or adjusted according to actual conditions.
- Drying in step 2) means transferring the mixture obtained in step 1) into a heated conveyor belt dryer, heating and drying under vacuum or an inert gas (for example, nitrogen), and the solvent and the rubber compound are not reacted in the synthesis.
- the monomer is charged into the condenser and the column for recovery; or the mixture obtained in step 1) is spray dried or flashed, and the heating medium used is an inert gas (such as nitrogen) or water vapor, and the solvent and rubber are volatilized.
- the unreacted monomer in the synthesis enters the condenser and the column for recovery.
- water vapor is used as the heating medium, the dried solid mixture may contain water, and then dried under vacuum, dried by heating or extruded and heated to obtain a rubber/filler masterbatch.
- the vacuum drying includes vacuum drying at room temperature, freeze vacuum drying, and heating under vacuum.
- the heat drying may be a general drying method such as drying or air drying.
- the extrusion heating and drying is performed by first removing and removing the heating medium, and then further drying, wherein the household is further dried to be air-dried, dried or mechanically dried, and the household is operated by using an open mill, a kneader, an internal mixer. , continuous mixer, single screw extruder, twin screw extruder for drying.
- the method of recovering the solvent can be recovered by any method known in the art, such as by vaporizing the solvent by surface condensation or direct contact condensation.
- the coolant may be water when the direct condensation contact method is used.
- the invention is further described by the following examples, but the scope of the invention is not limited by the examples. (1) The examples were determined using the following apparatus and measuring methods:
- Butadiene rubber BR9000, Sinopec Qilu Co., Ltd.;
- Antioxidant 020 Jiangsu Shengao Chemical Co., Ltd.;
- Antioxidant 264 Zhejiang Huangyan Zhedong Rubber Additive Co., Ltd.;
- Antioxidant RD chemical plant of Sinopec Nanjing Chemical Industry Co., Ltd.
- Silane coupling agent Si69 Nanjing Shuguang Chemical Group Co., Ltd.
- silica and silane coupling agent are added to 100 parts of cis-polyisoprene for kneading, mixing for a certain period of time, and 3.5 parts of zinc oxide are added.
- the masterbatch 2 is added to the internal mixer by adding 2 parts of stearic acid, 2 parts of the antioxidant 020, and then kneading 2, discharging from the internal mixer, and the rubber is passed through the roll on the open mill and the lower piece. After mixing for 8 hours, add 2 parts of CZ, 1 part of D and 1.6 parts of sulfur in the mixer and mix again 1.5 ⁇ ! Discharged from the mixer. After being placed in the open mill for 8 hours, it was vulcanized to a positive pressure in a 15 CTC flat vulcanizer to obtain a wet vulcanizate 2 .
- Table 3 shows the physical properties of the vulcanizate obtained from the examples of the wet master batch and the dry mix in different formulations and processes. It can be seen that in the same formulation, the wet masterbatch Compared with the dry masterbatch, the dispersion of the filler in the rubber is greatly improved, the hardness of the vulcanizate is lower, the tensile strength and the elongation at break are higher, the elasticity is high, the dynamic compression heat generation is low, and the wear resistance is low. better.
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Priority Applications (5)
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EP14834055.7A EP3031590B1 (en) | 2013-08-05 | 2014-07-22 | Continuous manufacturing process for rubber masterbatch and rubber masterbatch prepared therefrom |
US14/910,221 US10125229B2 (en) | 2013-08-05 | 2014-07-22 | Continuous manufacturing process for rubber masterbatch and rubber masterbatch prepared therefrom |
ES14834055T ES2861825T3 (es) | 2013-08-05 | 2014-07-22 | Proceso de fabricación continuo de mezcla madre de caucho y mezcla madre de caucho preparada a partir del mismo |
JP2016532219A JP6397021B2 (ja) | 2013-08-05 | 2014-07-22 | ゴムマスターバッチの連続的製造方法 |
KR1020157034587A KR101795203B1 (ko) | 2013-08-05 | 2014-07-22 | 고무 마스터배치 연속식 제조 방법 및 그 방법으로 제조된 고무 마스터배치 |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115926207A (zh) * | 2022-11-23 | 2023-04-07 | 辽宁维航基业科技有限公司 | 一种软质耐磨胶的制备方法 |
Families Citing this family (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103419293B (zh) | 2013-08-05 | 2016-04-27 | 怡维怡橡胶研究院有限公司 | 橡胶母炼胶的连续式制造方法及该方法制备的橡胶母炼胶 |
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CO2021001306A1 (es) * | 2021-02-09 | 2022-08-09 | Greiff Palacio Mauricio De | Método para la producción de premezclas de caucho natural particulado vía húmeda |
FR3129942A1 (fr) | 2021-12-08 | 2023-06-09 | Beyond Lotus Llc | Méthodes de préparation d’un composite comportant des résines |
CN114213730A (zh) * | 2022-01-08 | 2022-03-22 | 威海君道新材料科技有限公司 | 一种橡胶纳米复合材料及其制备方法 |
CN115572418B (zh) * | 2022-11-25 | 2023-04-25 | 广东粤港澳大湾区黄埔材料研究院 | 一种适用于轮胎胎面胶的含白炭黑湿法混炼母胶及其制备方法与橡胶组合物 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1998058985A1 (en) | 1997-06-23 | 1998-12-30 | Vomm Impianti E Processi S.R.L. | A method of producing synthetic rubbers |
CN103113597A (zh) * | 2013-01-30 | 2013-05-22 | 怡维怡材料研究院有限公司 | 橡胶母炼胶的连续式制造方法及该方法制备的橡胶母炼胶 |
CN103203810A (zh) * | 2013-01-10 | 2013-07-17 | 怡维怡材料研究院有限公司 | 橡胶母炼胶的连续式制造方法及该方法制备的橡胶母炼胶与橡胶制品 |
CN103419293A (zh) * | 2013-08-05 | 2013-12-04 | 怡维怡材料研究院有限公司 | 橡胶母炼胶的连续式制造方法及该方法制备的橡胶母炼胶 |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3663666A (en) * | 1970-05-22 | 1972-05-16 | Bird J Vincent | Method of forming silicone rubber articles |
DE2260340A1 (de) * | 1972-12-09 | 1974-06-20 | Huels Chemische Werke Ag | Verfahren zur herstellung pulverfoermiger, fuellstoffhaltiger kautschukmischungen sowie deren verwendung zur herstellung von reifenlaufflaechen |
US4048062A (en) * | 1976-04-22 | 1977-09-13 | Uop Inc. | Aromatic extraction with solvent recovery and regeneration |
TW360585B (en) * | 1996-04-01 | 1999-06-11 | Cabot Corp | Elastomeric compositions and methods and apparatus for producing same |
DE19808746A1 (de) * | 1997-07-10 | 1999-01-21 | Bayer Ag | Verfahren zur Herstellung von füllstoffhaltigen Kautschukmischungen |
JP2000230013A (ja) * | 1999-02-10 | 2000-08-22 | Daicel Chem Ind Ltd | エポキシ化ブロック共重合体の製造方法 |
WO2002059193A1 (en) * | 2001-01-25 | 2002-08-01 | The Yokohama Rubber Co., Ltd. | Rubber composition |
WO2008087114A1 (en) * | 2007-01-16 | 2008-07-24 | Basf Se | Production of superabsorbent polymers |
CN101463149B (zh) * | 2007-12-19 | 2011-11-09 | 北京化工大学 | 一种耐磨橡胶复合材料的制备方法 |
BRPI1014615A2 (pt) * | 2009-04-28 | 2019-09-24 | Bridgestone Corp | dispersão líquida de produto químico para borrachas,método para produzir a mesma, batelada de borracha úmida contendo produto químico para borrachas,composição de borracha e pneu". |
JP5651062B2 (ja) * | 2011-03-31 | 2015-01-07 | 東洋ゴム工業株式会社 | ゴム組成物およびその製造方法、ならびに空気入りタイヤ |
WO2013066329A1 (en) * | 2011-11-03 | 2013-05-10 | Lanxess Deutschland Gmbh | NdBR WET MASTERBATCH |
CN103159990B (zh) * | 2011-12-08 | 2014-12-31 | 中国石油化工股份有限公司 | 一种母炼胶及其制备方法和硫化橡胶及其应用 |
CN103600435B (zh) * | 2013-08-05 | 2016-04-27 | 怡维怡橡胶研究院有限公司 | 橡胶母炼胶的连续式制造方法及该方法制备的橡胶母炼胶 |
US9914884B2 (en) * | 2013-12-17 | 2018-03-13 | Uop Llc | Process and apparatus for recovering oligomerate |
-
2013
- 2013-08-05 CN CN201310337779.1A patent/CN103419293B/zh active Active
-
2014
- 2014-07-22 US US14/910,221 patent/US10125229B2/en active Active
- 2014-07-22 KR KR1020157034587A patent/KR101795203B1/ko active IP Right Grant
- 2014-07-22 JP JP2016532219A patent/JP6397021B2/ja active Active
- 2014-07-22 WO PCT/CN2014/082712 patent/WO2015018280A1/zh active Application Filing
- 2014-07-22 EP EP14834055.7A patent/EP3031590B1/en active Active
- 2014-07-22 ES ES14834055T patent/ES2861825T3/es active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1998058985A1 (en) | 1997-06-23 | 1998-12-30 | Vomm Impianti E Processi S.R.L. | A method of producing synthetic rubbers |
CN103203810A (zh) * | 2013-01-10 | 2013-07-17 | 怡维怡材料研究院有限公司 | 橡胶母炼胶的连续式制造方法及该方法制备的橡胶母炼胶与橡胶制品 |
CN103113597A (zh) * | 2013-01-30 | 2013-05-22 | 怡维怡材料研究院有限公司 | 橡胶母炼胶的连续式制造方法及该方法制备的橡胶母炼胶 |
CN103419293A (zh) * | 2013-08-05 | 2013-12-04 | 怡维怡材料研究院有限公司 | 橡胶母炼胶的连续式制造方法及该方法制备的橡胶母炼胶 |
Non-Patent Citations (1)
Title |
---|
See also references of EP3031590A4 |
Cited By (1)
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EP3031590A1 (en) | 2016-06-15 |
JP6397021B2 (ja) | 2018-09-26 |
ES2861825T3 (es) | 2021-10-06 |
KR101795203B1 (ko) | 2017-11-07 |
JP2016538394A (ja) | 2016-12-08 |
US10125229B2 (en) | 2018-11-13 |
US20160185921A1 (en) | 2016-06-30 |
CN103419293A (zh) | 2013-12-04 |
EP3031590B1 (en) | 2021-01-13 |
CN103419293B (zh) | 2016-04-27 |
EP3031590A4 (en) | 2017-04-12 |
KR20160009588A (ko) | 2016-01-26 |
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