WO2014198742A1 - Thermally conductive screed - Google Patents
Thermally conductive screed Download PDFInfo
- Publication number
- WO2014198742A1 WO2014198742A1 PCT/EP2014/062062 EP2014062062W WO2014198742A1 WO 2014198742 A1 WO2014198742 A1 WO 2014198742A1 EP 2014062062 W EP2014062062 W EP 2014062062W WO 2014198742 A1 WO2014198742 A1 WO 2014198742A1
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- WO
- WIPO (PCT)
- Prior art keywords
- expanded graphite
- floor screed
- hydraulic binder
- weight
- floor
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/14—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/14—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
- C04B28/16—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements containing anhydrite, e.g. Keene's cement
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/60—Flooring materials
- C04B2111/62—Self-levelling compositions
Definitions
- the present invention relates to compositions suitable for use as floor screed, the compositions being based on hydraulic binders.
- a floor screed is used in buildings to level and flatten the underlying concrete layer and in which pipes and cables can be housed. It should have a good thermal conductivity in case it houses ducts for floor heating,
- a self-leveling screed is a liquid mortar mainly formed from a hydraulic binder such as cement or calcium sulphate, aggregates and different additives; it is supplied on the job site by truck mixer or directly via a transmix distribution system.
- compositions suitable for thermally conductive screeds based hydraulic binders, and thermally conductive floor screeds are provided.
- the invention further relates to floor screeds and floor heating systems obtained by using compositions according to the invention.
- the invention also relates to the use of compositions according to the invention for floor screeds and floor heating systems.
- a floor screed composition is provided, the composition comprising a hydraulic binder and expanded graphite, the amount of expanded graphite being less than 12 %w, the %w being based upon the weight of said hydraulic binder .
- the weight percentage "X %w" of the expanded graphite means that X gram of expanded graphite is used per 100 gram of hydraulic binder .
- Hydraulic binder By the term “hydraulic binder”, reference is made to what is usually understood as hydraulic binders, i.e. compounds having the property to hydrate in the presence of water and moisture to get a solid mechanical property. Hydraulic Binder in particular may comprise Portland cement in accordance with the standard EN 197-1 or aluminous cement. The hydraulic binder may also comprise calcium sulfate. This calcium sulfate can be beta calcium sulfate and/or alpha calcium sulfate from natural or synthetic origin, or anhydrous calcium sulfate, e.g. anhydrite il or anhydrite III, obtained from sources of synthesis (for example fluoro anhydrite) or natural sources, e.g.
- gypsum natural or synthetic gypsum
- suitable calcining processes are classic calcination process or process RocalTM.
- the screed the invention generally meets the requirements of the European standards EN 13454-1 (binder) and EN 13813 (mortar) for calcium sulphate for fluid screed mortars and binders
- Calcium suplhate usually as anhydride, may comprise at least 50% by weight of calcium sulphate, preferably at least 85% or even significantly 100%.
- the screed may further comprise fillers of various kinds (calcareous, siliceous, Silica fume, fly ash can be used in addition to the calcium sulfate.
- the hydraulic binder may be calcium sulphate.
- the used calcium sulphate preferably is anhydride.
- a thermal conductivity increase is obtained and thermal conductivity values, as measured according to NF EN 993-15, of at least 1.8 W/m.K, even of 2 W/m.K or more, or 2.2 W/m.K or more, e.g. 2.5 W/m.K or more, or even 2.8 W/m.K or more may be obtained .
- the low amounts of expanded graphite in the composition according to the present invention offers further advantages such as low additional dust generation and the ease of incorporation said graphite without excessive floating in aqueous medium.
- the composition may comprise expanded graphite in an amount of at least 0.01 %w, the %w being based upon the weight of said hydraulic binder.
- the composition may comprise expanded graphite in an amount of at least 0.4%w, the %w being based upon the weight of said hydraulic binder.
- the floor screed composition according to the present invention comprises expanded graphite preferably in an amount of from 0.4 to 6 weight% with respect to the weight of hydraulic binder.
- Compositions comprising expanded graphite in an amount of from 0.4 to 4 weight% with respect to the weight of hydraulic binder are particularly preferred.
- the expanded graphite may have a specific BET surface ranging from 5 to 50m 2 /g, e.g. about 25 m 2 /g
- the expanded graphite may have a bulk density (scott density) ranging from 0.01 to 0.1 g/cm 3 , about 0.04 g/cm 3 , measured by ASTM n° E 153-59 T.
- the expanded graphite may have a mean particle size D50, as measured by laser diffraction, ranging from 1 to 100 ⁇ .
- the expanded graphite may have a mean particle size D50, as measured by laser diffraction, ranging from 20 to 60 ⁇ .
- the floor screed composition usually comprises aggregate, e.g. sand, and may comprise other additives such as piasticizers, anti foaming agents, fluidizers, superplasticizers and dispersants, SiC, B 4 C and/or AI2O3.
- aggregate e.g. sand
- additives such as piasticizers, anti foaming agents, fluidizers, superplasticizers and dispersants, SiC, B 4 C and/or AI2O3.
- the expanded graphite may be present in an amount less than 2.5 %w, the %w being based upon the weight of said floor screed composition.
- This weight percentage "X %w" of the expanded graphite means that X gram of expanded graphite is used per 100 gram of the floor screed composition in pourable form, i.e. ready to be used to provide the floor screed on the job site.
- the floor screed composition according to the present invention comprises expanded graphite preferably in an amount less than 1.5 %w, the %w being based upon the weight of said floor screed composition.
- Floor screed comprising expanded graphite in an amount of from 0.001 to 2,5 weight%, such as in the range of 0.001%w to 1.5%w with said %w being based upon the weight of said floor screed composition are particularly preferred.
- the floor screed composition may further comprise an anti foaming agent.
- the anti foaming agent may be selected from silicone-based antifoaming agents, fatty acids, esters, polypropylene glycols, and combinations thereof.
- the amount of anti foaming agent is preferably between 0.01 and 2%w, and more preferred between 0.01 and 0.5%w, the %w based upon the weight of said hydraulic binder.
- the floor screed composition may further comprise fluidizing agents and/or dispersants and/or plasticizers and/ or superplasticizers.
- the fluidizing agents and/or dispersants and/or plasticizers and/ or superplasticizers may be selected from sulfonated condensation products of formaldehyde and napthalene, sulfonated condensation products of formaldehyde and melamine, comb-branched copolymers having a backbone of acrylic and metacrylic acid, esterified with polycabroxylates or polyoxyalkylenes, such as polyoxyethylenes and combinations thereof.
- the total amount of fluidizing agents and/or dispersants and/or plasticizers and/ or superplasticizers are is preferably between 0.01 and 2%w, and more preferred between 0.02 and 1 %w, the %w based upon the weight of said hydraulic binder.
- the weight ratio anti foaming agent over fluidizing agents and/or dispersants and/or piasticizers and/ or superplasticizers is between 0.005 and 200, preferably between 0.05 and 20.
- the floor screed composition is combined and mixed with water to form a suitable floor screed in wet state. After applying the wet floor screed, the screed cures and evaporates part of the water. The floor screed so obtained is in dry state .
- the weight ration of water/calcium sulphate is preferably between 0.27 and 0.70, and more preferred between 0.35 and 0.55 such as between 0.35 and 0.45 .
- a floor screed composition according to the first aspect of the invention is used for the manufacture of a floor screed.
- the floor screed being provided may have a thermal conductivity measured according to NF EN 993-15 of at least 1 ,8 W/mK.
- the floor screed composition may further comprise aggregates.
- a method to provide a floor screed composition is provided, the method comprises
- the addition of hydraulic binder and the expanded graphite may be performed in the presence of water.
- At least part of the expanded graphite may be added to the hydraulic binder packed in a water soluble container.
- This container can e.g. be a water soluble bag, e.g. a polyvinyl alcohol based bag.
- At least part of the expanded graphite may be provided together with the water. According to some embodiments, at least part of the expanded graphite may be provided together with the hydraulic binder.
- -Silicon carbide(SiC) as commercialized under the name F600 by LAMPLAN
- -Boron carbide (B 4 C) as commercialized under the name F120 by LAMPLAN -Aluminium oxide (AI2O3) : as commercialized under the name F1200 by
- Table 1 summarizes the compositions of the mortars which have been prepared and tested as follows :
- the binder (CaSC1 ⁇ 4) and the additive are weighted and mixed for 5min with a turbula mixer.
- the sand is weighted, and the volume of water is defined and weighted as well.
- the water is introduced in the mixer.
- the binder premixed with the additive is added and mixed for 30s at 140rpm, after which the sand is added.
- the test results are also added in the table 1.
- the amount of the additives which have been tested as thermal conductivity enhancers i.e. expanded graphite, natural unexpended graphite, silicon carbide, boron carbide and aluminium oxide
- the thermal conductivity ( ⁇ ) has been measured on test specimens of 14x16x4 cm according to standard NF EN 993-15.
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- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
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- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
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- Compositions Of Macromolecular Compounds (AREA)
Abstract
A composition suitable for use as floor screed is provided, which composition comprises hydraulic binder and expanded graphite, characterized in that the amount of expanded graphite is less than 12 %w, the %w being based upon the weight of said hydraulic binder.
Description
THERMALLY CONDUCTIVE SCREED
Field of the invention
The present invention relates to compositions suitable for use as floor screed, the compositions being based on hydraulic binders.
Background of the invention
A floor screed is used in buildings to level and flatten the underlying concrete layer and in which pipes and cables can be housed. It should have a good thermal conductivity in case it houses ducts for floor heating, A self-leveling screed is a liquid mortar mainly formed from a hydraulic binder such as cement or calcium sulphate, aggregates and different additives; it is supplied on the job site by truck mixer or directly via a transmix distribution system.
Floor screeds based on cement and/or calcium sulphate binders are well known in the art.
Attempts have been made to improve the thermal conductivity of floor screeds by adding expanded graphite, as described in DE10049230. According to DE10049230, an amount of expanded graphite of 5%w to 35%w, based upon the dry weight of the floor screed is added to change the thermal conductivity, the size of the expanded graphite particles being in the range of 0.001 to 1 mm.
Summary of the invention It is an object of the present invention to provide compositions suitable for thermally conductive screeds based hydraulic binders, and thermally conductive floor screeds.
The invention further relates to floor screeds and floor heating systems obtained by using compositions according to the invention.
The invention also relates to the use of compositions according to the invention for floor screeds and floor heating systems. According to a first aspect of the present invention, a floor screed composition is provided, the composition comprising a hydraulic binder and expanded graphite, the amount of expanded graphite being less than 12 %w, the %w being based upon the weight of said hydraulic binder . The weight percentage "X %w" of the expanded graphite means that X gram of expanded graphite is used per 100 gram of hydraulic binder .
By the term "hydraulic binder", reference is made to what is usually understood as hydraulic binders, i.e. compounds having the property to hydrate in the presence of water and moisture to get a solid mechanical property. Hydraulic Binder in particular may comprise Portland cement in accordance with the standard EN 197-1 or aluminous cement. The hydraulic binder may also comprise calcium sulfate. This calcium sulfate can be beta calcium sulfate and/or alpha calcium sulfate from natural or synthetic origin, or anhydrous calcium sulfate, e.g. anhydrite il or anhydrite III, obtained from sources of synthesis (for example fluoro anhydrite) or natural sources, e.g. by calcining natural or synthetic gypsum (e.g. from the desulfurization FGD gypsum). Examples of suitable calcining processes are classic calcination process or process RocalTM. One may use mixtures of different sources of calcium sulphate. The screed the invention generally meets the requirements of the European standards EN 13454-1 (binder) and EN 13813 (mortar) for calcium sulphate for fluid screed mortars and binders
Calcium suplhate, usually as anhydride, may comprise at least 50% by weight of calcium sulphate, preferably at least 85% or even significantly 100%.
The screed may further comprise fillers of various kinds (calcareous, siliceous, Silica fume, fly ash can be used in addition to the calcium sulfate.
According to some embodiments, the hydraulic binder may be calcium sulphate. The used calcium sulphate preferably is anhydride.
The use of expanded graphite leads to higher values of thermal conductivity compared to unexpanded graphite.
If the amount of expanded graphite is above 12 weight % with respect to the weight of hydraulic binder, the cost of the formulation for use as a screed is too high, the further addition may not necessarily bring much additional increase of thermal conductivity, and there may be a potential reduction of mechanical performance.
Despite the low dosage of expanded graphite in the composition according to the invention, a thermal conductivity increase is obtained and thermal conductivity values, as measured according to NF EN 993-15, of at least 1.8 W/m.K, even of 2 W/m.K or more, or 2.2 W/m.K or more, e.g. 2.5 W/m.K or more, or even 2.8 W/m.K or more may be obtained . The low amounts of expanded graphite in the composition according to the present invention offers further advantages such as low additional dust generation and the ease of incorporation said graphite without excessive floating in aqueous medium.
According to some embodiments, the composition may comprise expanded graphite in an amount of at least 0.01 %w, the %w being based upon the weight of said hydraulic binder.
According to some embodiments, the composition may comprise expanded graphite in an amount of at least 0.4%w, the %w being based upon the weight of said hydraulic binder.
The floor screed composition according to the present invention comprises expanded graphite preferably in an amount of from 0.4 to 6 weight% with respect to the weight of hydraulic binder. Compositions comprising expanded graphite in an amount of from 0.4 to 4 weight% with respect to the weight of hydraulic binder are particularly preferred.
The expanded graphite may have a specific BET surface ranging from 5 to 50m2/g, e.g. about 25 m2/g
The expanded graphite may have a bulk density (scott density) ranging from 0.01 to 0.1 g/cm3, about 0.04 g/cm3, measured by ASTM n° E 153-59 T.
According to some embodiments, the expanded graphite may have a mean particle size D50, as measured by laser diffraction, ranging from 1 to 100μιτι.
The expanded graphite may have a mean particle size D50, as measured by laser diffraction, ranging from 20 to 60μιη .
The floor screed composition usually comprises aggregate, e.g. sand, and may comprise other additives such as piasticizers, anti foaming agents, fluidizers, superplasticizers and dispersants, SiC, B4C and/or AI2O3.
According to some embodiments, the expanded graphite may be present in an amount less than 2.5 %w, the %w being based upon the weight of said floor screed composition.
This weight percentage "X %w" of the expanded graphite means that X gram of expanded graphite is used per 100 gram of the floor screed composition in pourable form, i.e. ready to be used to provide the floor screed on the job site.
The floor screed composition according to the present invention comprises expanded graphite preferably in an amount less than 1.5 %w, the %w being based upon the weight of said floor screed composition. Floor screed comprising expanded graphite in an amount of from 0.001 to 2,5 weight%, such as in the range of 0.001%w to 1.5%w with said %w being based upon the weight of said floor screed composition are particularly preferred.
According to some embodiments, the floor screed composition may further comprise an anti foaming agent.
According to some embodiments, the anti foaming agent may be selected from silicone-based antifoaming agents, fatty acids, esters, polypropylene glycols, and combinations thereof.
The amount of anti foaming agent is preferably between 0.01 and 2%w, and more preferred between 0.01 and 0.5%w, the %w based upon the weight of said hydraulic binder.
According to some embodiments, the floor screed composition may further comprise fluidizing agents and/or dispersants and/or plasticizers and/ or superplasticizers.
The fluidizing agents and/or dispersants and/or plasticizers and/ or superplasticizers may be selected from sulfonated condensation products of formaldehyde and napthalene, sulfonated condensation products of formaldehyde and melamine, comb-branched copolymers having a backbone of acrylic and metacrylic acid, esterified with polycabroxylates or polyoxyalkylenes, such as polyoxyethylenes and combinations thereof.
The total amount of fluidizing agents and/or dispersants and/or plasticizers and/ or superplasticizers are is preferably between 0.01 and 2%w, and more preferred between 0.02 and 1 %w, the %w based upon the weight of said hydraulic binder.
When fluidizing agents and/or dispersants and/or piasticizers and/ or superplasticizers are used, and an antifoaming agent is used, the weight ratio anti foaming agent over fluidizing agents and/or dispersants and/or piasticizers and/ or superplasticizers is between 0.005 and 200, preferably between 0.05 and 20.
The floor screed composition is combined and mixed with water to form a suitable floor screed in wet state. After applying the wet floor screed, the screed cures and evaporates part of the water. The floor screed so obtained is in dry state . The weight ration of water/calcium sulphate is preferably between 0.27 and 0.70, and more preferred between 0.35 and 0.55 such as between 0.35 and 0.45 . According to a second aspect of the present invention, a floor screed composition according to the first aspect of the invention is used for the manufacture of a floor screed.
According to some embodiments, the floor screed being provided may have a thermal conductivity measured according to NF EN 993-15 of at least 1 ,8 W/mK.
According to some embodiments, the floor screed composition may further comprise aggregates. According to a third aspect of the invention, a method to provide a floor screed composition is provided, the method comprises
- providing a hydraulic binder
- providing expanded graphite such that the amount of expanded graphite is less than 12 %w, the %w being based upon the weight of the hydraulic binder
- adding the expanded graphite to the hydraulic binder to provide a floor screed composition .
According to some embodiments, the addition of hydraulic binder and the expanded graphite may be performed in the presence of water.
According to some embodiments, at least part of the expanded graphite may be added to the hydraulic binder packed in a water soluble container. This container can e.g. be a water soluble bag, e.g. a polyvinyl alcohol based bag.
According to some embodiments, at least part of the expanded graphite may be provided together with the water. According to some embodiments, at least part of the expanded graphite may be provided together with the hydraulic binder.
The independent and dependent claims set out particular and preferred features of the invention. Features from the dependent claims may be combined with features of the independent or other dependent claims, and/or with features set out in the description above and/or hereinafter as appropriate.
The above and other characteristics, features and advantages of the present invention will become apparent from the following detailed description, which illustrate, by way of example, the principles of the invention. This description is given for the sake of example only, without limiting the scope of the invention.
Description of illustrative embodiments The present invention will be described with respect to particular embodiments.
it is to be noticed that the term "comprising", used in the claims, should not be interpreted as being restricted to the means listed thereafter; it does not exclude other elements or steps. It is thus to be interpreted as specifying the presence of the stated features, steps or components as referred to, but does not preclude the presence or addition of one or more other features, steps or components, or groups thereof. Thus, the scope of the expression "a device comprising means A and B" should not be limited to devices consisting only of components A and B. It means that with respect to the present invention, the only relevant components of the device are A and B.
Throughout this specification, reference to "one embodiment" or "an
embodiment" are made. Such references indicate that a particular feature, described in relation to the embodiment is included in at least one embodiment of the present invention. Thus, appearances of the phrases "in one embodiment" or "in an embodiment" in various places throughout this specification are not necessarily all referring to the same embodiment, though they could.
Furthermore, the particular features or characteristics may be combined in any suitable manner in one or more embodiments, as would be apparent to one of ordinary skill in the art. EXAMPLES
The following products were used for the preparation of the compositions in the examples :
-Calcium sulphate (CaS04) being binder named CAp and obtainable from La Chape liquide;
-Sand being 0/4 Perrin (Dmax 4mm)
-Expanded graphite (Exp. C): Timrex® C-Therm™ 012 commercialised by Timcal; -Natural graphite (Nat. C) : Timrex® 50x100 commercialized by Timcal;
-Silicon carbide(SiC) as commercialized under the name F600 by LAMPLAN; -Boron carbide (B4C) as commercialized under the name F120 by LAMPLAN
-Aluminium oxide (AI2O3) : as commercialized under the name F1200 by
LAMPLAN
Table 1 summarizes the compositions of the mortars which have been prepared and tested as follows :
1 : mortar preparation
The binder (CaSC¼) and the additive are weighted and mixed for 5min with a turbula mixer. The sand is weighted, and the volume of water is defined and weighted as well.
First, the water is introduced in the mixer. The binder premixed with the additive is added and mixed for 30s at 140rpm, after which the sand is added.
The mixing procedure is continued according to the norm EN 196-1
2 : test specimen
After mixing the mortar is poured into two 14x16x4cm moulds
Let it dry for 28 days {at 20 °C /65%HR) before testing
The test results are also added in the table 1. The amount of the additives which have been tested as thermal conductivity enhancers (i.e. expanded graphite, natural unexpended graphite, silicon carbide, boron carbide and aluminium oxide) are expressed in weight % with respect to the weight of the calcium sulphate. The thermal conductivity (λ) has been measured on test specimens of 14x16x4 cm according to standard NF EN 993-15.
The results in table 1 show that compositions comprising the expanded graphite at the same dosage level expressed in weight % with respect to the binder, give higher thermal conductivities.
Claims
Floor screed composition, said composition comprising a hydraulic binder and expanded graphite, characterized in that the amount of expanded graphite is less than 12 %w, the %w being based upon the weight of said hydraulic binder .
Floor screed composition according to claim 1 wherein said hydraulic binder is calcium sulphate.
Floor screed composition according to claim 1 or 2 comprising expanded graphite in an amount of at least 0.01 %w, the %w being based upon the weight of said hydraulic binder.
Floor screed composition according to any one of the claims 1 to 3 comprising expanded graphite in an amount of at least 0.4%w, the %w being based upon the weight of said hydraulic binder.
Floor screed composition according to any of the preceding claims wherein the expanded graphite has a mean particle size D50, as measured by laser diffraction, ranging from 1 to 100μιτι.
Floor screed composition according to any of the preceding claims, wherein the expanded graphite being present in an amount less than 2.5 %w , the %w being based upon the weight of said floor screed composition.
7.- Floor screed composition according to any one of the preceding claims, wherein the floor screed composition further comprises an anti foaming agent. 8.- Floor screed composition according to any one of the preceding claims, wherein the floor screed composition further comprises fluidizing agents and/or dispersants and/or plasticizers and/ or superp!asticizers.
The use of a floor screed composition according to any of the claims 1 to 8 for the manufacture of a floor screed.
A method to provide a floor screed composition, said method comprises
- providing a hydraulic binder
- providing expanded graphite such that the amount of expanded
graphite is less than 12 %w, the %w being based upon the weight of said hydraulic binder
- adding said expanded graphite to said hydraulic binder to provide a floor screed composition .
Floor screed composition according claim 10 wherein the floor screed composition further comprises aggregates.
A method according to claim 10 or 1 1 , wherein the addition of hydraulic binder and the expanded graphite being performed in the presence of water.
A method according to claim 12, wherein at least part of the expanded graphite is added to the hydraulic binder packed in a water soluble container.
14. - A method according to claim 10 to 13, wherein at least part of the expanded graphite is provided together with the water.
15. - A method according to claim 10 to 14, wherein at least part of the expanded graphite is provided together with the hydraulic binder.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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EP14729330.2A EP3008032A1 (en) | 2013-06-12 | 2014-06-11 | Thermally conductive screed |
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Application Number | Priority Date | Filing Date | Title |
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EP13290143.0 | 2013-06-12 | ||
EP13290143 | 2013-06-12 |
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WO2014198742A1 true WO2014198742A1 (en) | 2014-12-18 |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES2545303A1 (en) * | 2015-05-12 | 2015-09-09 | Alfonso Javier MORAÑO RODRÍGUEZ | Addition to obtain structural concretes and thermal conductive mortars (Machine-translation by Google Translate, not legally binding) |
WO2023281136A1 (en) | 2021-07-09 | 2023-01-12 | Sunthalpy Engineering, S.L | Heat exchanger |
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DE10049230A1 (en) | 2000-09-28 | 2002-04-18 | Anneliese Zementwerke Ag | Floor heating system comprises pipes and/or tubes made from composite material and/or plastic placed in the flooring having a graphite additive and injected with a heating medium |
DE10341299A1 (en) * | 2003-09-04 | 2005-03-31 | Fagerdala Deutschland Gmbh | Light concrete used in building and road construction contains polymer particles, cement and expanded graphite |
DE102004039107A1 (en) * | 2003-08-21 | 2005-06-30 | Anneliese Zementwerke Ag | Filling material for the gap between a probe and the surrounding earth in a bore hole, comprises mineral clay, a binding agent, powder or granulate, and water |
CN101376583A (en) * | 2008-09-24 | 2009-03-04 | 东南大学 | Hidden heat energy storage type gypsum-based construction material |
WO2011095634A1 (en) * | 2010-02-08 | 2011-08-11 | Knauf Gips Kg | Gypsum plaster board and a method for producing a gypsum plaster board |
EP2476658A1 (en) * | 2011-01-17 | 2012-07-18 | Cugini S.p.A. | Binding mixture for making highly thermally conductive screeds |
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2014
- 2014-06-11 EP EP14729330.2A patent/EP3008032A1/en active Pending
- 2014-06-11 WO PCT/EP2014/062062 patent/WO2014198742A1/en active Application Filing
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DE10049230A1 (en) | 2000-09-28 | 2002-04-18 | Anneliese Zementwerke Ag | Floor heating system comprises pipes and/or tubes made from composite material and/or plastic placed in the flooring having a graphite additive and injected with a heating medium |
DE102004039107A1 (en) * | 2003-08-21 | 2005-06-30 | Anneliese Zementwerke Ag | Filling material for the gap between a probe and the surrounding earth in a bore hole, comprises mineral clay, a binding agent, powder or granulate, and water |
DE10341299A1 (en) * | 2003-09-04 | 2005-03-31 | Fagerdala Deutschland Gmbh | Light concrete used in building and road construction contains polymer particles, cement and expanded graphite |
CN101376583A (en) * | 2008-09-24 | 2009-03-04 | 东南大学 | Hidden heat energy storage type gypsum-based construction material |
WO2011095634A1 (en) * | 2010-02-08 | 2011-08-11 | Knauf Gips Kg | Gypsum plaster board and a method for producing a gypsum plaster board |
EP2476658A1 (en) * | 2011-01-17 | 2012-07-18 | Cugini S.p.A. | Binding mixture for making highly thermally conductive screeds |
Cited By (5)
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ES2545303A1 (en) * | 2015-05-12 | 2015-09-09 | Alfonso Javier MORAÑO RODRÍGUEZ | Addition to obtain structural concretes and thermal conductive mortars (Machine-translation by Google Translate, not legally binding) |
WO2016180999A1 (en) * | 2015-05-12 | 2016-11-17 | Moraño Rodríguez Alfonso Javier | Addition for producing thermally conductive mortars and structural concrete |
EP3312149A4 (en) * | 2015-05-12 | 2018-11-21 | Moraño Rodríguez, Alfonso Javier | Addition for producing thermally conductive mortars and structural concrete |
US10611685B2 (en) | 2015-05-12 | 2020-04-07 | Alfonso Javier MORANO RODRIGUEZ | Addition for producing thermally conductive mortars and structural concrete |
WO2023281136A1 (en) | 2021-07-09 | 2023-01-12 | Sunthalpy Engineering, S.L | Heat exchanger |
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