WO2014086699A1 - Zonierter dieseloxidationskatalysator - Google Patents
Zonierter dieseloxidationskatalysator Download PDFInfo
- Publication number
- WO2014086699A1 WO2014086699A1 PCT/EP2013/075205 EP2013075205W WO2014086699A1 WO 2014086699 A1 WO2014086699 A1 WO 2014086699A1 EP 2013075205 W EP2013075205 W EP 2013075205W WO 2014086699 A1 WO2014086699 A1 WO 2014086699A1
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- WIPO (PCT)
- Prior art keywords
- catalytically active
- active zone
- oxidation catalyst
- diesel oxidation
- length
- Prior art date
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- 239000003054 catalyst Substances 0.000 title claims abstract description 54
- 230000003647 oxidation Effects 0.000 title claims abstract description 42
- 238000007254 oxidation reaction Methods 0.000 title claims abstract description 42
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract description 59
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims abstract description 55
- 229910052697 platinum Inorganic materials 0.000 claims abstract description 27
- 229910052763 palladium Inorganic materials 0.000 claims abstract description 26
- 239000007789 gas Substances 0.000 claims description 19
- 229910000510 noble metal Inorganic materials 0.000 claims description 15
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 claims description 12
- 238000000576 coating method Methods 0.000 claims description 10
- 239000011248 coating agent Substances 0.000 claims description 9
- 238000011068 loading method Methods 0.000 claims description 9
- 239000000919 ceramic Substances 0.000 claims description 7
- 239000000470 constituent Substances 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- 239000010970 precious metal Substances 0.000 claims description 5
- 238000010531 catalytic reduction reaction Methods 0.000 claims description 3
- 229910002091 carbon monoxide Inorganic materials 0.000 description 15
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 12
- 229930195733 hydrocarbon Natural products 0.000 description 12
- 239000004215 Carbon black (E152) Substances 0.000 description 9
- 150000002430 hydrocarbons Chemical class 0.000 description 7
- 239000000758 substrate Substances 0.000 description 5
- CSDREXVUYHZDNP-UHFFFAOYSA-N alumanylidynesilicon Chemical compound [Al].[Si] CSDREXVUYHZDNP-UHFFFAOYSA-N 0.000 description 4
- 239000000725 suspension Substances 0.000 description 4
- 230000032683 aging Effects 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 229910052878 cordierite Inorganic materials 0.000 description 3
- JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000010457 zeolite Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- -1 hydrocarbons HC Chemical class 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000010335 hydrothermal treatment Methods 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- GPNDARIEYHPYAY-UHFFFAOYSA-N palladium(ii) nitrate Chemical compound [Pd+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O GPNDARIEYHPYAY-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000006722 reduction reaction Methods 0.000 description 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical class [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/44—Palladium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/944—Simultaneously removing carbon monoxide, hydrocarbons or carbon making use of oxidation catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9459—Removing one or more of nitrogen oxides, carbon monoxide, or hydrocarbons by multiple successive catalytic functions; systems with more than one different function, e.g. zone coated catalysts
- B01D53/9477—Removing one or more of nitrogen oxides, carbon monoxide, or hydrocarbons by multiple successive catalytic functions; systems with more than one different function, e.g. zone coated catalysts with catalysts positioned on separate bricks, e.g. exhaust systems
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
- B01J29/068—Noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/19—Catalysts containing parts with different compositions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
- B01J35/56—Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional monoliths
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B01J37/0027—Powdering
- B01J37/0036—Grinding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/103—Oxidation catalysts for HC and CO only
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/10—Noble metals or compounds thereof
- B01D2255/102—Platinum group metals
- B01D2255/1021—Platinum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/10—Noble metals or compounds thereof
- B01D2255/102—Platinum group metals
- B01D2255/1023—Palladium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/90—Physical characteristics of catalysts
- B01D2255/903—Multi-zoned catalysts
- B01D2255/9032—Two zones
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/90—Physical characteristics of catalysts
- B01D2255/915—Catalyst supported on particulate filters
- B01D2255/9155—Wall flow filters
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2510/00—Surface coverings
- F01N2510/06—Surface coverings for exhaust purification, e.g. catalytic reaction
- F01N2510/068—Surface coverings for exhaust purification, e.g. catalytic reaction characterised by the distribution of the catalytic coatings
- F01N2510/0682—Surface coverings for exhaust purification, e.g. catalytic reaction characterised by the distribution of the catalytic coatings having a discontinuous, uneven or partially overlapping coating of catalytic material, e.g. higher amount of material upstream than downstream or vice versa
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2570/00—Exhaust treating apparatus eliminating, absorbing or adsorbing specific elements or compounds
- F01N2570/10—Carbon or carbon oxides
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2570/00—Exhaust treating apparatus eliminating, absorbing or adsorbing specific elements or compounds
- F01N2570/12—Hydrocarbons
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/24—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
- F01N3/28—Construction of catalytic reactors
- F01N3/2803—Construction of catalytic reactors characterised by structure, by material or by manufacturing of catalyst support
- F01N3/2807—Metal other than sintered metal
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/24—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
- F01N3/28—Construction of catalytic reactors
- F01N3/2803—Construction of catalytic reactors characterised by structure, by material or by manufacturing of catalyst support
- F01N3/2825—Ceramics
- F01N3/2828—Ceramic multi-channel monoliths, e.g. honeycombs
Definitions
- the present invention relates to a zoned oxidation catalyst for purifying the exhaust gases of diesel engines.
- the raw exhaust gas of diesel engines contains a relatively high oxygen content of up to 15% by volume.
- particulate emissions are contained, which consist predominantly of soot residues and optionally organic agglomerates and result from a partially incomplete fuel combustion in the cylinder.
- diesel particle filters with and without catalytically active coating are suitable for removing particulate emissions and nitrogen oxides can be converted to nitrogen by selective catalytic reduction (SCR) on a so-called SCR catalyst, for example, carbon monoxide and hydrocarbons are rendered harmless by oxidation to a suitable oxidation catalyst made.
- Oxidation catalysts are extensively described in the literature. These are, for example, so-called flow-through substrates made of ceramic or metal, which, as essential catalytically active constituents, carry noble metals, such as platinum and palladium, on high-surface-area, porous, high-melting oxides, for example aluminum oxide.
- Zoned oxidation catalysts are also described which, in the flow direction of the exhaust gas, have material zones of different composition with which the exhaust gas comes into contact one after the other.
- US2010 / 257843 describes a zoned oxidation catalyst containing platinum and palladium, wherein at least 50% of the total palladium content in the first zone and at least 50% of the total platinum content in the second zone.
- the first zone is the one with which the exhaust gas first comes in contact, that starts at the input side of the substrate.
- US2011 / 099975 and WO2012 / 079598 Al also describe a zoned oxidation catalyst containing platinum and palladium.
- the total amount of platinum and palladium in the first zone is high compared to the second zone and the platinum to palladium ratio is relatively low in the first zone and relatively high in the second zone.
- the first zone is the one with which the exhaust first comes into contact.
- WO 2011/057649 describes oxidation catalysts which can be used in linearized and zoned embodiments.
- the second zone i. the zone with which the effluent exhaust gas is in direct contact has a higher noble metal content than the front zone, which is in direct contact with the incoming exhaust gas.
- the oxidation catalysts according to WO2011 / 057649 have the particular task for a
- downstream SCR catalyst to set an optimal ratio of NO to NO2.
- Zoned platinum and palladium-containing oxidation catalysts are also described in US2011 / 206584.
- the present invention relates to a diesel oxidation catalyst comprising a support body of length L extending between a first end face and a second end face and one on the support body
- catalytically active coating comprising a first catalytically active zone and a second catalytically active zone, wherein
- the support body is a ceramic or metallic
- the first catalytically active zone and the second catalytically active zone have the same thermal masses
- the first catalytically active zone and the second catalytically active zone contain as the catalytically active constituents in each case platinum and palladium,
- the weight ratio of platinum to palladium in the first catalytically active zone and the second catalytically active zone is the same and is 1: 1, and
- the catalytically active zone is greater than in the second catalytically active zone.
- the length E of the first catalytically active zone is 20 to 70%, 40 to 60% or 45 to 50% of the total length L.
- the length Z of the second catalytically active zone is 20 to 70% in embodiments of the present invention. , 40 to 60% or 45 to 50% of the total length L.
- the lengths E and Z are both 50% of
- the sum of the length E of the first catalytically active zone and the length Z of the second catalytically active zone can correspond exactly to the total length L. In particular, for production reasons, however, it may be smaller than the total length L in embodiments of the present invention. In these cases, a certain length is the
- Total length L between the coated lengths E and Z uncoated For example, the sum of the length E of the first catalytically active zone and the length Z of the second catalytically active zone L x 0.8 to L x 0.999.
- the first end face of the support body is hereinafter also referred to as the entry end face, the second end face also as the exit end face.
- the first catalytically active zone and the second catalytically active zone have the same thermal masses.
- thermal mass is known in the art as heat capacity and can according to known in the
- Washcoat loading of the first and second catalytically active zone is the same. It can vary within wide limits depending on the application and is for example 50 to 400 g / l. Alternatively, the same thermal masses of the first and second catalytically active zones can be achieved at different washcoat loadings by the use of compacted washcoat constituents. In particular, carrier materials such as compacted alumina are suitable for this purpose.
- Precious metal content because negligible, is not included.
- the noble metal loading in the first and second catalytically active zones may each be 10 g / ft 3 (0.35315 g / L) to 220 g / ft 3 (7.76923 g / L). In other embodiments, the noble metal loading may also be at 15 g / ft 3 (0.52972 g / L) to 70 g / ft 3 (2.47203 g / L).
- the first catalytically active zone contains 1, 2 to 4 times as much platinum and palladium as the second catalytically active zone.
- the absolute noble metal content of the inventive diesel oxidation catalyst is, for example, 10 to 200 g / ft 3 (0.35315 to 7.063 g / L), 10 to 100 g / ft 3 (0.35315 to 3.5315 g / L) or at 15 to 50 g / ft 3 (0.52973 to 1.76575 g / L).
- platinum and palladium in both zones are on one or more
- Suitable carrier oxides are, for example, aluminum oxides, silicon oxides, zirconium oxide- and / or titanium-oxide-doped aluminum oxides and aluminum-silicon mixed oxides.
- the selected carrier oxides are suspended in water.
- Platinum and palladium are added with stirring in the form of suitable, water-soluble
- Precursor compounds such as palladium nitrate or hexa-hydroxoplatinic acid added to the suspension and optionally fixed by adjusting the pH and / or by adding an auxiliary reagent on the support material.
- the noble metal can also be applied to the substrate in analogy to the method described in EP 1 101 528 A2.
- the coated part is dried in a stream of hot air and optionally calcined.
- the diesel oxidation catalysts according to the invention are suitable for cleaning the exhaust gases of diesel engines, in particular with regard to
- the present invention thus also relates to a process for the treatment of diesel exhaust gases, characterized in that the diesel exhaust gas is passed over a diesel oxidation catalyst as described above and defined.
- diesel oxidation catalysts according to the invention are used in particular as constituents of exhaust gas purification systems.
- Corresponding emission control systems comprise, in addition to an inventive
- Diesel oxidation catalyst for example a diesel particulate filter and / or a catalyst for the selective catalytic reduction of nitrogen oxides, diesel particulate filter and SCR catalyst usually being connected downstream of the diesel oxidation catalyst according to the invention, So are arranged downstream.
- Diesel oxidation catalyst for example a diesel particulate filter and / or a catalyst for the selective catalytic reduction of nitrogen oxides, diesel particulate filter and SCR catalyst usually being connected downstream of the diesel oxidation catalyst according to the invention, So are arranged downstream.
- the SCR catalyst is disposed on the diesel particulate filter.
- the initial zone was carried out with a washcoat, which was prepared analogously to the process described under a), with the difference that the total concentration of the noble metals used (on the porous aluminum-silicon mixed oxide and on the platinum-coated zeolites) 2.6- was higher.
- a cordierite ceramic honeycomb was coated to 50% of its length as described in Example 1b). For coating the
- the exit zone was a washcoat made the same
- the diesel oxidation catalyst thus obtained is hereinafter called K3.
- the total noble metal loading is 22.5 g / ft 3 , with the
- Weight ratio of platinum and palladium in both zones is equal and each 1: 1.
- the thermal masses are the same in both zones. c)
- steps a) and b) were repeated, with the difference that in the entry zone 20 g / ft 3 Pt + 10 g / ft 3 Pd and in the exit zone 10 g / ft 3 Pt + 5 g / ft 3 Pd were used.
- the diesel oxidation catalyst thus obtained is hereinafter called VK2.
- the total noble metal loading is again 22.5 g / ft 3
- the weight ratio of platinum and palladium is again the same in both zones, but is in each case 2: 1.
- the thermal masses are the same in both zones. d)
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- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
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- Crystallography & Structural Chemistry (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Toxicology (AREA)
- Catalysts (AREA)
- Exhaust Gas After Treatment (AREA)
Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201380059983.XA CN104797334A (zh) | 2012-12-06 | 2013-12-02 | 分区的柴油氧化催化剂 |
EP13799516.3A EP2928595A1 (de) | 2012-12-06 | 2013-12-02 | Zonierter dieseloxidationskatalysator |
JP2015545756A JP2016500331A (ja) | 2012-12-06 | 2013-12-02 | ゾーン化ディーゼル酸化触媒 |
US14/442,300 US20160279610A1 (en) | 2012-12-06 | 2013-12-02 | Zoned diesel oxidation catalyst |
KR1020157017808A KR20150093203A (ko) | 2012-12-06 | 2013-12-02 | 구획화된 디젤 산화 촉매 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP12195774.0 | 2012-12-06 | ||
EP12195774 | 2012-12-06 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2014086699A1 true WO2014086699A1 (de) | 2014-06-12 |
Family
ID=47290763
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2013/075205 WO2014086699A1 (de) | 2012-12-06 | 2013-12-02 | Zonierter dieseloxidationskatalysator |
Country Status (6)
Country | Link |
---|---|
US (1) | US20160279610A1 (de) |
EP (1) | EP2928595A1 (de) |
JP (1) | JP2016500331A (de) |
KR (1) | KR20150093203A (de) |
CN (1) | CN104797334A (de) |
WO (1) | WO2014086699A1 (de) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3487617B1 (de) * | 2016-07-19 | 2021-09-08 | Umicore AG & Co. KG | Dieseloxidationskatalysator |
JP7245613B2 (ja) * | 2018-07-05 | 2023-03-24 | 株式会社キャタラー | 排ガス浄化触媒装置 |
CN115387886B (zh) * | 2022-09-23 | 2024-06-07 | 天津瑞合环保科技有限公司 | 带催化剂浆料涂层的内燃机车颗粒过滤器 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20110123421A1 (en) * | 2009-11-20 | 2011-05-26 | BASF Catalysts Germany GmbH | Zoned catalyzed soot filter |
US20110212008A1 (en) * | 2010-02-23 | 2011-09-01 | Alfred Helmut Punke | Catalyzed Soot Filter |
WO2012079598A1 (en) * | 2010-12-14 | 2012-06-21 | Umicore Ag & Co. Kg | Architectural diesel oxidation catalyst for enhanced no2 generator |
US20120288427A1 (en) * | 2011-05-13 | 2012-11-15 | Basf Corporation | Catalyzed Soot Filter With Layered Design |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB0600130D0 (en) * | 2006-01-06 | 2006-02-15 | Johnson Matthey Plc | Exhaust system comprising zoned oxidation catalyst |
US7534738B2 (en) * | 2006-11-27 | 2009-05-19 | Nanostellar, Inc. | Engine exhaust catalysts containing palladium-gold |
CN101683622B (zh) * | 2007-01-17 | 2013-03-06 | 纳米星公司 | 含有钯-金的发动机排气催化剂 |
US8557203B2 (en) * | 2009-11-03 | 2013-10-15 | Umicore Ag & Co. Kg | Architectural diesel oxidation catalyst for enhanced NO2 generator |
EP2623183B1 (de) * | 2012-02-03 | 2015-08-26 | Umicore AG & Co. KG | Katalytisch aktives partikelfilter und dessen verwendung |
-
2013
- 2013-12-02 WO PCT/EP2013/075205 patent/WO2014086699A1/de active Application Filing
- 2013-12-02 CN CN201380059983.XA patent/CN104797334A/zh active Pending
- 2013-12-02 JP JP2015545756A patent/JP2016500331A/ja active Pending
- 2013-12-02 US US14/442,300 patent/US20160279610A1/en not_active Abandoned
- 2013-12-02 KR KR1020157017808A patent/KR20150093203A/ko not_active Application Discontinuation
- 2013-12-02 EP EP13799516.3A patent/EP2928595A1/de not_active Withdrawn
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20110123421A1 (en) * | 2009-11-20 | 2011-05-26 | BASF Catalysts Germany GmbH | Zoned catalyzed soot filter |
US20110212008A1 (en) * | 2010-02-23 | 2011-09-01 | Alfred Helmut Punke | Catalyzed Soot Filter |
WO2012079598A1 (en) * | 2010-12-14 | 2012-06-21 | Umicore Ag & Co. Kg | Architectural diesel oxidation catalyst for enhanced no2 generator |
US20120288427A1 (en) * | 2011-05-13 | 2012-11-15 | Basf Corporation | Catalyzed Soot Filter With Layered Design |
Also Published As
Publication number | Publication date |
---|---|
US20160279610A1 (en) | 2016-09-29 |
CN104797334A (zh) | 2015-07-22 |
JP2016500331A (ja) | 2016-01-12 |
EP2928595A1 (de) | 2015-10-14 |
KR20150093203A (ko) | 2015-08-17 |
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