WO2013166614A2 - Systemisches pflanzenschutz-verfahren zur kontrolle von mykosen, bakteriosen und virosen mittels injektor-technologie und neutralem elektrolysierten mineralwasser als biozid - Google Patents
Systemisches pflanzenschutz-verfahren zur kontrolle von mykosen, bakteriosen und virosen mittels injektor-technologie und neutralem elektrolysierten mineralwasser als biozid Download PDFInfo
- Publication number
- WO2013166614A2 WO2013166614A2 PCT/CH2013/000079 CH2013000079W WO2013166614A2 WO 2013166614 A2 WO2013166614 A2 WO 2013166614A2 CH 2013000079 W CH2013000079 W CH 2013000079W WO 2013166614 A2 WO2013166614 A2 WO 2013166614A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- injection
- electrolysis
- water
- systemic
- oxidative radicals
- Prior art date
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G7/00—Botany in general
- A01G7/06—Treatment of growing trees or plants, e.g. for preventing decay of wood, for tingeing flowers or wood, for prolonging the life of plants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- C25B1/04—Hydrogen or oxygen by electrolysis of water
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/13—Ozone
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/042—Electrodes formed of a single material
- C25B11/043—Carbon, e.g. diamond or graphene
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
- C25B9/19—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/70—Assemblies comprising two or more cells
- C25B9/73—Assemblies comprising two or more cells of the filter-press type
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/133—Renewable energy sources, e.g. sunlight
Definitions
- the invention relates to a novel plant protection experience, with mineral-salt-containing water, electrolytically generated, oxidative radicals as a systemic biocide, filled in a pressurized spray ampoule or in a hand-injection apparatus, or in other syringe types specially integrated technology used to carry out injection molding.
- Electrolytically produced oxidative radicals can be all types of mycoses, bacterioses, viruses and levorioses in plants,
- Phloem injections are used to systemically control shrubs and trees without the need for the use of toxic, environment-damaging and resis- tant-forming antibiotic substances with residual effects.
- the new crop protection technology is clean, significantly cheaper, efficient and, above all, environment friendly and can also be used preventively in organic and organic farming.
- this new technology allows a better systemic effect against pathogens than external spraying applications on leaves etc.
- the object of the invention is to provide a new, efficient, and cost-effective, environmentally friendly and biological
- Electrolysis water is against the bacterium Envinia amylovora
- Electrolysis water is very efficient against the apple scab (Venturia inaequalis) in orchards.
- the fungicide Dclan WG has an efficiency of 95.6% in the long-term average at this experimental setting.
- Electrolytic oxidative water (EOW) or chemically active water does not chemically destroy germs, fungi, bacteria, viruses, yeasts, phages and insects by oxidative radicals
- the pathogen is compromised, resulting in osmotic or hydrogen overload inside the cell.
- the damaged cell membranes allow for increased
- the voltage source causes an electron deficiency in the electrode connected to the positive pole (anode) and a
- Electron overshoots in the other electrode connected to the negative pole (cathode).
- the aqueous solution between the cathode and anode contains electrolytes, which are positively or negatively charged ions.
- the positively charged cations in an electrolytic cell migrate by applying a voltage to the negatively charged cathode (attraction of opposite charges). At the cathode, they absorb one or more electrons and are thereby reduced.
- the opposite process takes place.
- the negatively charged anions emit electrons, that is, they are oxidized.
- the number of electrons consumed by the reduction at the cathode corresponds to the electrons picked up by the anode.
- the electrolysis of aqueous saline solution the same volume is produced
- Hydrogen gas such as chlorine gas.
- oxygen gas In the electrolysis of water twice as much hydrogen gas as oxygen gas, since the two positively charged protons of a water molecule migrate to the cathode and there each have to take an electron so that hydrogen forms, while the doubly negatively charged oxygen anion at the anode must deliver two electrons to join the
- the voltage which must at least be applied to the electrolysis is called the deposition potential, in the electrolysis of water or in aqueous salt solutions, one speaks of the decomposition voltage. This voltage (or a higher voltage) must be applied so that the electrolysis takes place at all. For every substance, for every conversion of ions to two or more
- Separation potential can be determined based on the redox potential. From the redox potential one receives many other important indications for the electrolysis, for example for the electrolytic decomposition of metal electrodes in acid or for the reduction of
- a galvanic element acts at the same time, the voltage of which counteracts the electrolysis. This voltage is also called the polarization voltage.
- Mercury cathodes (0.80 V) show a significant overpotential of hydrogen protons and the formation of hydrogen occurs only at a much higher voltage.
- the electrolysis of water consists of two partial reactions, which take place at the two electrodes.
- the electrodes are immersed in water, which is rendered more conductive by the addition of some common salt, which then produces chlorine instead of oxygen.
- H 3 O 4 Positively charged hydronium ions migrate in the electric field to the negatively charged electrode (cathode), where they each receive an electron. Hydrogen atoms are formed, which combine with another H atom formed by reduction to form a hydrogen molecule. Remain water molecules.
- the negatively charged hydroxide ions migrate to the positively charged electrode (anode).
- Each hydroxide ion releases an electron to the plus pole, so that oxygen atoms are formed which combine to form oxygen molecules.
- NaCl addition to chlorine molecules
- the remaining tF ions are immediately neutralized by hydroxide ions to water molecules.
- hydronium and hydroxide ions on the left originate from the autoprotolysis of the water:
- the electrolysis equation can therefore also be written as follows: 8 H 2 Q -> 2 H 2 + 0 2 + 6 H 2 0 or after shortening of the water: 2 H 2 0 - 2 H 2 + 0 2 hydroxide ion
- the hydroxide ion is a negatively charged ion that forms when bases react with water. Its chemical formula is OH-.
- a general base B reacts with water according to the following scheme:
- Hydroxide ions are also in pure water at 20 ° C in one
- Electrolyzed oxidative water received FDA (USA Food and
- the inventor holds with the electrolysis product HYDROSEPT the rights to a biocide entry at the Federal Office of Public Health in Bern, Switzerland.
- the new systemic crop protection method achieved 92.6% efficiency in statistically relevant field trials in the apple tree against apple scab.
- Crop protection has been published by means of in water, with the addition of ion-forming mineral salts, electrolytically produced oxidative radicals (electrolysis water), and with the help of electrochemically separated water molecule clusters of only 2-3 molecules, resulting from the bottom of the smaller molecular structure Cell membranes can penetrate and with the help of the new injector technology can ensure an effective systemic biocidal crop protection.
- Salt concentration and salt composition for an efficient systemic injection-injection process via pressurized injection vials on.
- the method also shows the
- the invention forms an integrated system in which the
- the injection technology are integrated into the phloem of plants, shrubs and trees with the corresponding injection applicators in the form of pressurized injection vials or hand-held injectors or other types of syringes.
- Bacteria, viruses, pike, and yeasts have.
- Oxidative radical concentrations are essential for the successful use of electrolytic oxidative radicals in water and fulfill all the parameters for the optimal mode of action of the new systemic pest control method.
- the invention is innovative with respect to the production of oxidative radicals by means of two processes, the electrolysis in an electrolytic cell with full-diamond electrodes and the cylinder electrolysis with platinum electrodes, which in the electrolysis of mineral nutrients in the water with Na + and CL- ions, especially Cl- produce ions and not H + ions.
- This fact makes it possible to produce organically degradable hypochlorite compounds (HOCL) or hypochlorite acid H2CLO, which are not toxic to plants.
- the cylinder produces electrolysis, thanks to its special construction and the
- the invention of the new systemic plant protection method consists essentially in the combination of the electrolytic production of oxidative radicals in water in 2 different possible production processes (biocide), their mixing and intermediate storage in the tank and the subsequent application of the biocides by means of the various injection applications, injection -Ampoule, Hand injector, etc. as biocide injector leads to a systemic ultrafast super-oxidation of the pathogens.
- Plant protection with electrolytic oxidative radicals and with the help of specially designed injectors consists of the following technical components:
- Pressurized injector ampoules or hand syringe injector or other syringe types.
- electrolysis - cells with solid diamond electrodes, each with 1-3 or more electrolysis - chambers, as required, with volume flow meter and flow probe and corresponding control unit with manual and automatic cathode and anode - load reversal, built-in ammeter and voltmeter and
- Lamp function control with automatic shutdown without volume flow, including, pressure regulating and return stop valve, lines and connections and KontroUhahn and sampling point (220 or 340 V).
- No volume flow shutdown including piping and fittings and control and sampling points.
- (22 () or 340 V) including redox anodic and cathodic electrolyte fluid meter, including electronic mixer tap, used to set the desired pH of the Electrolytic Oxidative Water (EOW) serves.
- EOW Electrolytic Oxidative Water
- the innovative application method of the invention includes 6 essential steps: preparation of biocidal oxidative radicals and separation of water-molecule clusters to 2-3 molecules in aqueous,
- Minerals salt-containing nutrient solution by means of electrolysis. 2. Pressure wastes of injection ampoules, hand injectors, etc. with electrolyzed plant-physiological nutrient solution and biocidal oxidative radicals with compressed gases, nitrogen, CO 2 and / or argon on the filling station.
- the preparation of the biocidal oxidative radicals in aqueous, mineral salt-containing solution is done by 2 different, but complementary electrolysis.
- the first method is implemented with the electrolysis using full diamond electrodes.
- the result is a cocktail of oxidative radicals close to the "neutral" region with a pH of 7.6 to 8.2.
- free chlorine (CI-) are formed at the anode, which together with the hydroxyl groups lead to the formation of hypochlorite HOCL and hypochlorite acid H 2 OCl, which are decomposed organically very rapidly.
- hypochlorite HOCL and hypochlorite acid H 2 OCl which are decomposed organically very rapidly.
- the water because of the improved electroconductivity and improved nutrient supply of plants and trees various nutrient salts and inorganic oligo elements are added, which are approved in organic farming.
- oxidizing reducing peroxide-di-sulfate, peroxide-di-phosphate and percarbonate are also formed.
- nutrient salts are, for example, per liter of injection fluid: (for young plants)
- This salt solution must after the successful electrolysis a concentration of min. 35 ppm or 35 mg per liter of oxidative radicals as total total or contain about 17 ppm or 17 mg per liter of free chlorine compounds.
- salts are, for example, per liter of injection fluid: (for growing and adult plants):
- This salt solution must after the successful electrolysis a concentration of min. 90 ppm or 90 mg per liter of oxidative radicals as total total or contain about 45 ppm or 45 mg per liter of free chlorine compounds.
- salt compositions can also be different, depending on the type of plant and the purpose of use, both as salts and in their salts
- the second method is implemented with cylinder electrolysis with diaphragm, where the electrolysis cells are separated from each other, consisting of an anode chamber and a cathode chamber.
- the electrolysis cells are separated from each other, consisting of an anode chamber and a cathode chamber.
- the electrolytic water solution also contains ozone 03 and H202, a gene-elicited triggering of a systemic acquired immune response (SAR), a systemic immune protection reaction in the plant, is triggered simultaneously in the plants.
- SAR systemic acquired immune response
- the catalytic function of ozone and hydrogen peroxide causes in the plant or in a tree the same Abreeh rresureen as in an attack of an insect or a bacterium or virus.
- the plant or the tree forms internal, systemic substances for their protection. This intensifies with every treatment
- Pressurized injection vials inject electrolyzed water with nutrients as bactericide, virucide or fungicides into the phloem of the tree trunk.
- the biocidal fluid slowly spreads in all parts of the tree.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Biodiversity & Conservation Biology (AREA)
- Ecology (AREA)
- Forests & Forestry (AREA)
- Wood Science & Technology (AREA)
- Environmental Sciences (AREA)
- Botany (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Zoology (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Abstract
Description
Claims
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US14/399,711 US20150208591A1 (en) | 2012-05-08 | 2013-05-07 | Systemic crop protection method for controlling mycoses, bacterioses and viroses using injector technology and neutral electrolyzed mineral water as a biocide |
BR112014027888A BR112014027888A2 (pt) | 2012-05-08 | 2013-05-07 | processo de proteção vegetal sistêmica para controlar e eliminar a infestação patogênica de fungos, leveduras, bactérias ou vírus em plantas por meio de água eletrolisada, utilização da água eletrolisada, e equipamento para a execução do processo |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH00639/12A CH706484A2 (de) | 2012-05-08 | 2012-05-08 | Systemisches Pflanzenschutz-Verfahren zur Kontrolle von Mykosen, Bakteriosen und Virosen mittels Injektor-Technologie und neutralem elektrolysiertem Mineralwasser als Biozid. |
CH639/12 | 2012-05-08 |
Publications (3)
Publication Number | Publication Date |
---|---|
WO2013166614A2 true WO2013166614A2 (de) | 2013-11-14 |
WO2013166614A3 WO2013166614A3 (de) | 2014-01-03 |
WO2013166614A4 WO2013166614A4 (de) | 2014-03-06 |
Family
ID=48672308
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/CH2013/000079 WO2013166614A2 (de) | 2012-05-08 | 2013-05-07 | Systemisches pflanzenschutz-verfahren zur kontrolle von mykosen, bakteriosen und virosen mittels injektor-technologie und neutralem elektrolysierten mineralwasser als biozid |
Country Status (4)
Country | Link |
---|---|
US (1) | US20150208591A1 (de) |
BR (1) | BR112014027888A2 (de) |
CH (1) | CH706484A2 (de) |
WO (1) | WO2013166614A2 (de) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AT515551B1 (de) * | 2014-07-24 | 2015-10-15 | Pro Aqua Diamantelektroden Produktion Gmbh & Co Kg | Verfahren zur Herstellung eines auf das Bakterium Erwinia amylovora bakterizid wirkenden Pflanzenschutzmittels |
WO2016092273A1 (en) * | 2014-12-09 | 2016-06-16 | Ozo Innovations Ltd | Electrolyzed water composition |
EP3190893A4 (de) * | 2014-09-12 | 2018-04-25 | K10 Technologies, Inc. | Zusammensetzungen und verfahren zur behandlung und vorbeugung von bakteriellen infektionen |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103987664B (zh) | 2011-12-06 | 2017-03-08 | 德尔塔阀门公司 | 龙头中的臭氧分配 |
CN105265204B (zh) * | 2015-11-03 | 2018-02-09 | 吉首大学 | 气水直喷式打花装置 |
CA3007437C (en) | 2015-12-21 | 2021-09-28 | Delta Faucet Company | Fluid delivery system including a disinfectant device |
CN108770529A (zh) * | 2018-03-29 | 2018-11-09 | 四川省合亩农业开发有限公司 | 一种果树微创伤补给方法 |
CN111937622B (zh) * | 2020-08-18 | 2022-08-02 | 广西特色作物研究院 | 一种柑橘溃疡病病菌的接种方法 |
WO2024108164A1 (en) * | 2022-11-18 | 2024-05-23 | Zymtronix Catalytic Systems, Inc. | Enzymatically produced biopesticides |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
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US5622848A (en) * | 1990-05-23 | 1997-04-22 | Medical Discoveries, Inc. | Electrically hydrolyzed salines as microbiocides for in vitro treatment of contaminated fluids containing blood |
US5239773A (en) * | 1992-06-22 | 1993-08-31 | Doolittle Jr Glayne D | Tree injection system |
US5901498A (en) * | 1996-01-05 | 1999-05-11 | Simcro Tech Limited | Tree injector |
US6024986A (en) * | 1999-05-24 | 2000-02-15 | Ecolab Inc. | Method of protecting growing plants from the effects of plant pathogens |
US20060099274A1 (en) * | 2004-11-10 | 2006-05-11 | Hoshizaki Denki Kabushiki Kaisha | Expulsive liquid for exterminating disease injury of plants |
DE502007001688D1 (de) * | 2006-05-02 | 2009-11-19 | Nanosys Gmbh | Verfahren zur bekämpfung von erwinia amylovora |
CH704641B1 (de) * | 2007-02-20 | 2012-09-28 | Aonsys Technologies Ltd | Pflanzenschutz-Spritzverfahren und Vorrichtung zur Elimination von schädlichen Mikroorganismen und Insekten mittels in Wasser, unter Zugabe von Ionen bildenden Salzen, elektrolytisch hergestellten oxidativen Radikalen, UV-C-Licht, und mit Hilfe luftunterstützter elektrostatischer Sprühtechnologie. |
ITMI20071863A1 (it) * | 2007-09-28 | 2009-03-29 | Industrie De Nora Spa | Dispositivo elettrochimico per trattamento biocida in applicazioni agricole |
-
2012
- 2012-05-08 CH CH00639/12A patent/CH706484A2/de not_active Application Discontinuation
-
2013
- 2013-05-07 WO PCT/CH2013/000079 patent/WO2013166614A2/de active Application Filing
- 2013-05-07 US US14/399,711 patent/US20150208591A1/en not_active Abandoned
- 2013-05-07 BR BR112014027888A patent/BR112014027888A2/pt not_active IP Right Cessation
Non-Patent Citations (1)
Title |
---|
None |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AT515551B1 (de) * | 2014-07-24 | 2015-10-15 | Pro Aqua Diamantelektroden Produktion Gmbh & Co Kg | Verfahren zur Herstellung eines auf das Bakterium Erwinia amylovora bakterizid wirkenden Pflanzenschutzmittels |
AT515551A4 (de) * | 2014-07-24 | 2015-10-15 | Pro Aqua Diamantelektroden Produktion Gmbh & Co Kg | Verfahren zur Herstellung eines auf das Bakterium Erwinia amylovora bakterizid wirkenden Pflanzenschutzmittels |
EP3190893A4 (de) * | 2014-09-12 | 2018-04-25 | K10 Technologies, Inc. | Zusammensetzungen und verfahren zur behandlung und vorbeugung von bakteriellen infektionen |
WO2016092273A1 (en) * | 2014-12-09 | 2016-06-16 | Ozo Innovations Ltd | Electrolyzed water composition |
EP3598896A1 (de) * | 2014-12-09 | 2020-01-29 | Ozo Innovations Ltd | Zusammensetzung mit elektrolysiertem wasser |
Also Published As
Publication number | Publication date |
---|---|
WO2013166614A4 (de) | 2014-03-06 |
US20150208591A1 (en) | 2015-07-30 |
BR112014027888A2 (pt) | 2017-06-27 |
WO2013166614A3 (de) | 2014-01-03 |
CH706484A2 (de) | 2013-11-15 |
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