WO2012044313A1 - Lead-free piezoelectric materials with enhanced fatigue resistance - Google Patents
Lead-free piezoelectric materials with enhanced fatigue resistance Download PDFInfo
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- WO2012044313A1 WO2012044313A1 PCT/US2010/050965 US2010050965W WO2012044313A1 WO 2012044313 A1 WO2012044313 A1 WO 2012044313A1 US 2010050965 W US2010050965 W US 2010050965W WO 2012044313 A1 WO2012044313 A1 WO 2012044313A1
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- 239000000463 material Substances 0.000 title claims description 26
- 229910010293 ceramic material Inorganic materials 0.000 claims abstract description 49
- 239000000126 substance Substances 0.000 claims abstract description 10
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 5
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 5
- 229910052451 lead zirconate titanate Inorganic materials 0.000 claims description 25
- HFGPZNIAWCZYJU-UHFFFAOYSA-N lead zirconate titanate Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ti+4].[Zr+4].[Pb+2] HFGPZNIAWCZYJU-UHFFFAOYSA-N 0.000 claims description 7
- 239000006104 solid solution Substances 0.000 claims description 2
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- 101100453572 Arabidopsis thaliana KCO3 gene Proteins 0.000 description 3
- 101100453573 Oryza sativa subsp. japonica TPKC gene Proteins 0.000 description 3
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- VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
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- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- YPQJHZKJHIBJAP-UHFFFAOYSA-N [K].[Bi] Chemical compound [K].[Bi] YPQJHZKJHIBJAP-UHFFFAOYSA-N 0.000 description 1
- PMVFCJGPQOWMTE-UHFFFAOYSA-N bismuth calcium Chemical compound [Ca].[Bi] PMVFCJGPQOWMTE-UHFFFAOYSA-N 0.000 description 1
- SKKNACBBJGLYJD-UHFFFAOYSA-N bismuth magnesium Chemical compound [Mg].[Bi] SKKNACBBJGLYJD-UHFFFAOYSA-N 0.000 description 1
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/46—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on titanium oxides or titanates
- C04B35/462—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on titanium oxides or titanates based on titanates
- C04B35/475—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on titanium oxides or titanates based on titanates based on bismuth titanates
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- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
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- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/62605—Treating the starting powders individually or as mixtures
- C04B35/62625—Wet mixtures
- C04B35/6263—Wet mixtures characterised by their solids loadings, i.e. the percentage of solids
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- H10N30/00—Piezoelectric or electrostrictive devices
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- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
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- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
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- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
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- C04B2235/768—Perovskite structure ABO3
Definitions
- the present disclosure generally relates to piezoelectric ceramic materials, more particularly to lead-free piezoelectric ceramic materials based on binary and ternary compositions containing bismuth magnesium titanate or bismuth calcium titanate, together with bismuth potassium titanate-bismuth sodium titanate.
- Piezoelectric ceramic materials also referred to as piezoelectric ceramics or piezoceramics
- piezoelectric ceramics have been widely used in applications such as actuators, transducers, resonators, sensors, and random access memories.
- PZT lead zirconate titanate
- PZT piezoceramics have been widely used due to their excellent piezoelectric properties and the ease with which modifications by doping can be made during manufacturing.
- PZT lead zirconate titanate
- PZT piezoceramics is the strong fatigue behavior associated with PZT. Fatigue is a phenomenon in which a piezoelectric material loses its switchable polarization and electromechanical strain during electrical cyclic loading.
- Fig. 1 is a ternary compositional/phase diagram illustrating the compositional range of Ni-based piezoelectric materials according to certain embodiments.
- Fig. 2 is a graph of polarization values at applied electrical field of 50 kV/cm of three BNiT-BKT-BNT compositions according to embodiments of the disclosed compositions.
- Fig. 3 is a graph showing electromechanical strain values at applied electrical field of 60 kV/cm of a BNiT-BKT-BNT composition according to an embodiment of the disclosed compositions.
- Fig. 4 is a graph of electromechanical strain values at applied electrical fields ranging from -60 kV/cm to 60 kV/cm of a 10 mol% BNiT- 90 mol% BNT composition according to an embodiment of the disclosed compositions.
- Fig. 5 is a graph of polarization values at applied electrical fields ranging from -60 kV/cm to 60 kV/cm of three BNiT-BKT-BNT compositions according to embodiments of the disclosed compositions.
- Fig. 6 is a ternary compositional/phase diagram illustrating the compositional range of Mg-based piezoelectric materials according to certain embodiments.
- Fig. 7 is a graph of polarization values at an applied electrical field of 50 kV/cm of three BMgT-BKT-BNT compositions according to embodiments of the disclosed compositions.
- Fig. 8 is a graph showing electromechanical strain values over electrical fields ranging from -60 kV/cm to 60 kV/cm of a BMgT-BNT composition according to an embodiment of the disclosed compositions.
- Fig. 9 is a graph of polarization values at applied electrical fields ranging from -60 kV/cm to 60 kV/cm of three BMgT-BKT-BNT compositions according to embodiments of the disclosed compositions.
- Fig. 10 is a graph showing electromechanical strain values at an applied electrical fields of -60 kV/cm to 60 kV/cm of a BMgT-BKT-BNT composition according to an embodiment of the disclosed compositions.
- the term “Curie temperature” refers to the temperature above which a piezoelectric material loses its spontaneous polarization and piezoelectric characteristics.
- polarization hysteresis refers to lead-free piezoelectric ceramic materials that display non-linear polarization characteristics indicative of a polar state.
- electromechanical strain refers to an electric field induced strain and is commonly expressed in terms of one or more piezoelectric coefficients (d33 and d3i , for example), where d (units pm/V) is the tensor property that relates the strain to the applied electric field (V/m).
- the d33 coefficient can be measured in many different ways, such a piezoelectric resonance, the direct piezoelectric effect, the indirect piezoelectric effect, and others.
- d33 units pm/V
- fatigue refers to the observed loss of polarization and electromechanical strain after the application of a cyclic electric field.
- polarization remanence refers to the polarization measured at zero field during a polarization hysteresis measurement. It is a unique characteristic of polar, non-linear dielectrics.
- morphotropic region refers to compositions where multiple perovskite phases co-exist
- morphotropic phase boundary refers to a specific composition where two or more perovskite phases co-exist.
- a temperature range of about 100°C to about 500°C should be interpreted to include not only the explicitly recited limits of 100°C and 500°C, but also to include every intervening temperature such as 250°C, 300°C, 350°C and 400°C, and all sub-ranges such as 300°C to 400°C, and so forth.
- a ternary composition/phase diagram illustrates the entire range of lead-free piezoelectric ceramic materials based on the binary systems Bi(Ni 0 .5Tio.5)O3-(Bi 0 .5Ko.5)TiO3 and Bi(Ni 0 .5Tio.5)O3-(Bio.5Na 0 .5)TiO3 and on ternary compositions in the Bi(Nio.5Tio.5)O3-(Bi 0 .5Ko.5)TiO3-(Bi 0 .5Nao.5)TiO3 system.
- binary and ternary systems are sometimes referred to herein as BNiT- BKT, BNiT-BNT, and BNiT-BKT-BNT, respectively, or are referred to as simply Ni-based binary and ternary compositions.
- Exemplary compositions B-E (defined in Table 1 ) are in the first region, and exemplary compositions G-J are in the second region. In Table 1 and Fig.
- composition A the unary perovskite compositions BNT (composition A) and BKT (composition F) are included for comparison purposes only.
- a third region shown in Fig. 1 is in the vicinity of MPB at 80 mol% BNT-20 mol % BKT. It was discovered that with the addition of up to 20 mol% BNiT to the MPB composition, a single phase perovskite with high piezoelectric coefficients is obtained.
- Representative compositions K-N are included in this single phase perovskite region adjacent to the BNT-BKT MPB (indicated by a dashed oval).
- Fig. 1 Also shown in Fig. 1 is a central region (indicated by a dashed trapezoid), including a group of ternary stoichiometries that are also single-phase perovskites with excellent piezoelectric coefficients. Representative compositions O-Q are included in this region and are also identified in Table 1 . The stoichiometries of some representative BNiT-BKT, BNiT-BNT and BNiT-BKT- BNT materials with single phase stable perovskite structures shown in Fig. 1 are also identified in Table 1 .
- BNiT concentrations greater than 20 mole percent, and greater than 10 mole percent of BKT and BNT contain stable single phase perovskites with high strain values. In many cases, this material has a maximum electromechanical strain coefficient (d 33 ) in the range of about 200 pm/V to about 700 pm/V. In some embodiments, a BNiT-BNT, BNiT-BKT or BNiT-BNT-BKT composition has a d 33 coefficient in the range of about 400 pm/V to about 650 pm/V.
- the representative compositions identified as B-E and G-Q in Table 1 and Fig. 1 demonstrated the highest strain values of the Ni-based stable single phase perovskites tested.
- a lead- free piezoelectric ceramic material has one of the following general chemical formulas:
- These compositions represent the basic range of stability of the binary compositions with a stable perovskite phase.
- the Curie temperature (T c ) of most Ni-based binary and ternary compositions is in the range of about 100°C to about 500°C. In some cases the T c of a composition is between about 300°C and about 400°C.
- the relative proportions of the components of the Ni-based binary and ternary compositions may be varied during production of the ternary composition so that the product will have a specified Curie temperature range.
- the operating temperature of the ceramic product may differ from the Tc of the Ni-based binary or ternary composition. For example, in some situations the operating temperature will be about 100°C-150°C lower than the T c .
- maximum operating temperature of a Ni- based binary or ternary composition ceramic product is its depolarization temperature.
- Polarization hysteresis data for representative compositions indicate ferroelectric behavior, and a plot of the electric field induced strain appears as butterfly loops, consistent with other ferroelectric materials. Many of these Ni- based binary and ternary compositions demonstrate or are predicted to have properties similar to or exceeding those of PZT.
- BNiT-BNT, BNiT-BKT or BNiT-BNT-BKT composition materials may be evaluated by piezoelectric resonance measurements following the customary IEEE standard, poling studies to measure the low-field electromechanical strain coefficient d33, fatigue measurements, and studies of the temperature dependence of these piezoelectric properties.
- Polarization hysteresis data for representative compositions indicate ferroelectric behavior and the electric field induced strain appears as the expected butterfly loops.
- Excellent fatigue resistance is predicted for many of the BNiT-BNT, BNiT-BKT and BNiT-BNT-BKT piezoelectric ceramics, with losses of ⁇ 1 percent of the maximum polarization after 1 million cycles in some cases.
- the piezoelectric strain coefficients (d33 and d3i) of the Ni-based binary and ternary compositions are generally below those of PZT.
- conventional PZT piezoelectric ceramics typically demonstrate the following properties of piezoelectric resonance, low-field d33, fatigue and temperature dependence of piezoelectric properties: ⁇ ⁇ about 1000 - 3400; d33 about 200 pm/V - 600 pm/V; k 33 about 0.64 - 0.75; and T c about 195°C - 365°C.
- a disclosed Ni-based binary and ternary piezoelectric ceramic material demonstrates a piezoelectric strain coefficient (d 33 ) equal to or exceeding that of a lead zirconate titanate perovskite (PZT).
- the ceramic material demonstrates a maximum electromechanical strain value of about 0.30 percent elongation under electric field.
- a disclosed lead-free piezoelectric ceramic material demonstrates fatigue resistance exceeding that of a lead zirconate titanate perovskite.
- a Ni-based binary or ternary piezoelectric ceramic material demonstrates a maximum high-field piezoelectric d33 value in the range of about 200 pm/V to about 700 pm/V, and in some cases is in the range of about 400 pm/V to about 650 pm/V.
- a ternary composition/phase diagram illustrates the entire range of lead-free piezoelectric ceramic materials based on the binary systems Bi(Mg 0 .5Tio.5)03-(Bi 0 .5Ko.5)Ti03 and Bi(Mg 0 .5Tio.5)03-(Bio.5Na 0 .5)Ti03 and on ternary compositions in the Bi(Mg 0. 5Tio.5)0 3 -(Bio.5K 0 .5)Ti0 3 -(Bio.5Nao.5)Ti0 3 system.
- the binary systems are sometimes referred to herein as BMgT-BNT or BMgT-BKT.
- BMgT- BNT-BKT binary and ternary systems
- Mg-based binary and ternary compositions Similar to the above- described Ni-based compositions, there are two regions containing exemplary binary compositions BMgT-BNT and BMgT-BKT, respectively, wherein Mg ranges from about 1 mol% to about 5 mol%, consist of single-phase perovskite with large piezoelectric coefficients.
- Exemplary compositions B-E (defined in Table 2) are in the first region, and exemplary compositions G-J are in the second region. In Table 2 and Fig.
- composition A the unary perovskite compositions BNT (composition A) and BKT (composition F) are included for comparison purposes only.
- a third region shown in Fig. 6 is in the vicinity of MPB at 80 mol% BNT-20 mol% BKT. It was discovered that with the addition of up to 20 mol% BMgT to the MPB composition, a single phase perovskite with high piezoelectric coefficient is obtained.
- Representative compositions K-N are included in this single phase perovskite region adjacent to the BNT-BKT MPB (indicated by a dashed oval).
- Fig. 6 Also shown in Fig. 6 is a central region (dashed trapezoid) including a group of ternary stoichiometries that are also single-phase perovskites with excellent piezoelectric coefficients. Representative compositions O-Q are included in this region and are also identified in Table 2. The stoichiometries of some representative BMgT-BKT, BMgT-BNT, and BMgT-BKT-BNT materials with single phase stable perovskite structures shown in Fig. 6 are also identified in Table 2.
- BMgT concentrations greater than 20 mole percent, and greater than 10 mole percent of BKT and BNT contain stable single phase perovskites with high strain values. In many cases, this material has a maximum electromechanical strain coefficient (d 33 ) in the range of about 200 pm/V to about 700 pm/V. In some embodiments, a BMgT-BNT, BMgT-BKT or BMgT-BNT-BKT composition has a d 33 coefficient in the range of about 400 pm/V to about 650 pm/V.
- the representative compositions identified as B-E and G-Q in Table 2 and Fig. 6 demonstrated the highest strain values of the Mg-based stable single phase perovskites tested.
- the electromechanical strain behavior of this material shows large strain values (in the range of 0.20% to about 0.35%) and large strain hysteresis (loss).
- BMgT is not stable in it's pure state, like BNiT, it exhibits a remarkably large range of solubility with BNT and BKT.
- the Mg-based binary compositions exhibit approximately 20 mole percent solid solubility. However, for the ternary compositions the solubility is greater than 50 mole percent. Without being limited to any particular theory, it is thought that this surprisingly large solubility of BMgT in the ternary compositions may be due, in part, to complex interactions between the B-cations in the octahedral network in the perovskite structure.
- a lead-free piezoelectric ceramic material has one of the following general chemical formulas:
- These compositions represent the basic range of stability of the binary compositions with a stable perovskite phase.
- the Curie temperature (T c ) of most Mg-based binary and ternary compositions is in the range of about 100°C and 500°C. In some cases the T c of a composition is between about 300°C and about 400°C.
- the relative proportions of the components of the Mg-based binary and ternary compositions may be varied during production of the ternary composition so that the product will have a specified Curie temperature range.
- the operating temperature of the ceramic product may differ from the Tc of the Mg-based binary or ternary composition. For example, in some situations the operating temperature will be about 100°C-150°C lower than the T c . s a practical matter, maximum operating temperature of a Mg- based binary or ternary composition ceramic product is its depolarization temperature.
- Polarization hysteresis data for representative compositions indicate ferroelectric behavior, and a plot of the electric field induced strain appears as butterfly loops, consistent with other ferroelectric materials. Many of these Mg- based binary and ternary compositions demonstrate or are predicted to have properties similar to or exceeding those of PZT.
- BMgT-BNT, BMgT-BKT or BMgT-BNT-BKT composition materials may be evaluated by piezoelectric resonance measurements following the customary IEEE standard, poling studies to measure the low-field electromechanical strain coefficient d33, fatigue measurements, and studies of the temperature dependence of these piezoelectric properties.
- Polarization hysteresis data for representative compositions indicate ferroelectric behavior and the electric field induced strain appears as the expected butterfly loops.
- Excellent fatigue resistance is predicted for many of the BMgT-BNT, BMgT-BKT and BMgT-BNT-BKT piezoelectric ceramics, with losses of ⁇ 1 percent of the maximum polarization after 1 million cycles in some cases.
- the piezoelectric strain coefficients (d33 and d3i ) of the Mg-based binary and ternary compositions are generally below those of PZT.
- a disclosed Mg-based binary and ternary piezoelectric ceramic material demonstrates a piezoelectric strain coefficient (d33) equal to or exceeding that of a lead zirconate titanate perovskite (PZT).
- the Mg-based binary and ternary piezoelectric ceramic material demonstrates a maximum electromechanical strain value of about 0.30 percent elongation under electric field.
- a disclosed lead-free piezoelectric ceramic material demonstrates fatigue resistance exceeding that of a lead zirconate titanate perovskite.
- a Mg-based binary or ternary piezoelectric ceramic material demonstrates a maximum high-field piezoelectric d 33 value in the range of about 200 pm/V to about 700 pm/V, and in some cases is in the range of about 400 pm/V to about 650 pm/V.
- Ni- or Mg-based binary and ternary ceramic material may be advantageous. It is predicted that many of the Ni- and Mg-based binary and ternary compositions will meet or exceed the piezoelectric properties of doped PZT materials, and will provide a constant strain with minimal or no degradation over the life of a device employing such material.
- Ni-, and Mg-based binary and ternary ceramic materials with improved piezoelectric properties are predicted to be substantially equivalent or superior to conventional PZT-based piezoelectric ceramics and are predicted to have similar potential uses, including but not limited to actuators, transducers, resonators, sensors, and random access memories. Some of these applications will further benefit from the absence of lead in the piezoelectric ceramics.
- All lead-free Ni- and Mg-based binary and ternary ceramic materials described herein may be produced by any suitable solid-state synthesis method, using B12O3, NaC03, KCO3 and ⁇ 2 starting powders, and either NiO or MgO starting powders.
- the starting powders are preferably at least 99% purity.
- the Curie temperature (T c ) of the resulting product is generally between about 100°C and about 500°C.
- the T c of a piezoelectric ceramic may be increased or decreased by varying the relative amounts of the starting powders.
- the relative amounts of BNiT/BMgT, BNT and BKT may be adjusted so that the product will have a T c in a specified range.
- the powders are milled, shaped and calcined to produce the desired ceramic product.
- Milling can be either wet or dry type milling, as is known in the art.
- High energy vibratory milling may be used, for instance, to mix starting powders and for post-calcination grinding.
- the powders are mixed with a suitable liquid (e.g., ethanol or water, or a combination of liquids) and wet milled with a suitable high density milling media (e.g., yttria stabilized zirconia (YSZ) beads).
- a suitable liquid e.g., ethanol or water, or a combination of liquids
- a suitable high density milling media e.g., yttria stabilized zirconia (YSZ) beads.
- the milled powders are calcined, then mixed with a binder, formed into the desired shape (e.g., pellets) and sintered to produce a ceramic product with high sintered density.
- a binder formed into the desired shape (e.g., pellets) and sintered to produce a ceramic product with high sintered density.
- the ceramic disc may be polished to a suitable thickness (e.g., 0.9 mm), and a silver paste (e.g., Heraeus C1000) is applied to both sides of the discs.
- a high- density ceramic disc or pellet containing Ni- or Mg-based binary or ternary material may be polished to a thickness in the range of about 0.5 ⁇ to about 1 ⁇ , suitable for use as a piezoelectric actuator, for example.
- the production method may be modified to include chemical solution deposition using chemical precursors such bismuth nitrate, titanium isopropoxide, etc., or sputtering using solid state sintered or hot- pressed ceramic targets. Any suitable sputtering or chemical deposition method may be used for this purpose.
- the resulting thin film ceramic may have a thickness in the range of about 50 nm to about 10 ⁇ , in some cases.
- the above-described sintered Ni- or Mg-based binary or ternary ceramic material can be modified for this purpose.
- the ceramic powder is ground or milled to the desired particle size and loaded into polymer matrix to create a 0-3 piezoelectric composite.
- the ceramic powder can be formed into sintered rods or fibers using injection molding or similar technique and loaded into a polymer matrix to create a 1-3 piezoelectric composite.
- the polymer may be piezoelectric, such as PVDF, or non-piezoelectric such as epoxy depending on the final application.
- Example 1 Production of Ni-containing Binary and Ternary
- Lead-free binary or ternary compositions were produced via solid-state synthesis methods, using either NiO or MgO, B12O3 and T1O2, and either or both NaC0 3 and KCO3 starting powders of at least 99% purity. Appropriate amounts of those powders were combined to yield BNiT-BKT, BNiT-BNT or BNiT-BKT- BNT. In one case, the resulting composition had the relative proportions (mole percent) 5Bi(Nii 2Tii 2)03-72.5(Bii 2Nai 2)Ti03-22.5(Bii 2Ki 2)Ti0 3 . Six hours of high energy vibratory milling was used for mixing starting powders and for post- calcination grinding.
- Ethanol mixtures containing 15 vol.% powder were milled with high density YSZ beads approximately 3/8 inch in diameter. After removal of YSZ, calcination was performed on the milled powder in covered crucibles at 900°C for 6 hours. The calcined powders were mixed with a 3 wt.% solution of Polyvinyl Butyral (PVB) binder, and the powders were uniaxially cold pressed into 12.7 mm pellets at a pressure of 150 MPa. Following a 400°C binder burnout, the pellets were sintered in covered crucibles at 1 100°C for 2 hours. Prior to electrical measurements, the ceramics discs were polished to thickness of 0.9 mm with smooth and parallel surfaces. Silver paste (Heraeus C1000) was fired on both sides in air at 650°C for 30 minutes.
- Silver paste (Heraeus C1000) was fired on both sides in air at 650°C for 30 minutes.
- Ni-containing compositions prepared as described in Example 1 were subjected to x-ray diffraction analysis which confirmed that the material consisted of a single-phase perovskite structure. The resulting x-ray diffraction pattern showed no evidence of any secondary phases in these compositions or any of the compositions listed in Tables I and 3.
- Fig. 2 shows polarization values at an applied electrical field of 50 kV/cm of three BNiT-BKT-BNT compositions (compositions L, M, and N) having the relative proportions shown in Table 3 and Fig. 2.
- the polarization was measured using a Radiant Premier II Ferroelectric Test System which utilizes a Sawyer- Tower circuit.
- the electromechanical strain of a specimen of composition K was measured at an applied electrical field of 60 kV/cm using an optical interferometer directly integrated with the Radiant instrument. Direct measurement of coefficient d33 of a ceramic material may also be performed by dual-beam laser interferometer.
- the results shown in Figs. 2 and 3 and in Table 3 demonstrate large electromechanical strains with an approximate d33* value as high as 540 pm/V.
- electromechanical strain values of a 10 ⁇ - 90BNT composition were measured at applied electrical fields ranging from -60 kV/cm to 60 kV/cm, and the results show large electromechanical strains of as much as 0.08%.
- the measured values for these and other representative binary and ternary Ni-based ceramics are comparable to many known Pb-free compositions (d33 about 300 pm/V to about 400 pm/V), and are comparable to doped PZT ceramics (d33 about 400 pm/V to about 600 pm/V).
- the depolarization temperature of the 5Bi(Ni 0 .5Tio.5)03-22.5(Bi 0 .5Ko.5)Ti03- 72.5(Bi 0 .5Nao.5)Ti0 3 ceramic, and that of other representative BNiT-BKT-BNT ceramics, is 200°C or higher, or at least equal to doped PZT materials.
- Ni-based ternary ceramic compositions corresponding to "O", "P” and “Q”, in Table 1 and Fig. 1 were prepared as described in Example 1 , to produce a single phase perovskite structure in each case. These compositions were subjected to x-ray diffraction analysis which confirmed that the material consisted of a single-phase perovskite structure, without any evidence of secondary phases. Their polarization values at applied electrical fields ranging from -60 kV/cm to 60 kV/cm were measured as described in Example 2. The results shown in Fig. 5 indicate that these compositions exhibit a significant degree of hysteresis in the dielectric response.
- Example 3 Production of Mg-containing Binary and Ternary
- Lead-free binary or ternary Mg-containing compositions were produced via solid-state synthesis methods, using B12O3, MgO and T1O2, and either or both NaC03 and KCO3 starting powders of at least 99% purity. Appropriate amounts of those powders were combined to yield BMgT-BKT, BMgT-BNT or BMgT-BKT- BNT compositions. The ceramic materials were formed from these compositions substantially as described in Example 1 , above.
- Fig. 7 shows polarization values at an applied electrical field of 50 kV/cm of three BMgT-BKT-BNT compositions having the relative proportions shown in Table 4 and Fig. 7. Polarization was measured as described above with respect to these Ni-containing piezoelectric compositions (Fig. 7).
- the electromechanical strain was measured at applied electric fields ranging from -60 kV/cm to 60 kV/cm using an optical interferometer directly integrated with the Radiant instrument. Direct measurement of coefficient d33 of a ceramic material may also be performed by dual-beam laser interferometer. These results show large electromechanical strains of representative binary and ternary Mg-based piezoelectric materials with an approximate d33* value as high as 540 pm/V.
- Mg-containing ternary compositions having the relative proportions (mol%) shown in Table 4 were prepared as described in Example 3 and their polarization and electromechanical strain values were measured at applied electrical fields ranging from -60 kV/cm to 60 kV/cm, as described in Example 2.
- Fig. 8 shows electromechanical strain values at applied electrical fields ranging from -60 kV/cm to 60 kV/cm of a BMgT-BKT-BNT composition indicated by K on Table 2.
- Fig. 9 shows polarization values at applied electrical fields ranging from -60 kV/cm to 60 kV/cm of three BMgT-BKT-BNT compositions indicated as O, P, and Q in Table 2.
- Fig. 10 shows electromechanical strain values at applied electrical fields ranging from -60 kV/cm to 60 kV/cm of a 50BMgT-25BKT-25BNT (composition Q). The results shown in Figs. 9 and 10, indicate that large electromechanical strain values can be obtained for these compositions.
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JP5802274B2 (en) | 2015-10-28 |
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