WO2012024153A1 - Improving terephthalic acid purge filtration rate by controlling % water in filter feed slurry - Google Patents
Improving terephthalic acid purge filtration rate by controlling % water in filter feed slurry Download PDFInfo
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- WO2012024153A1 WO2012024153A1 PCT/US2011/047373 US2011047373W WO2012024153A1 WO 2012024153 A1 WO2012024153 A1 WO 2012024153A1 US 2011047373 W US2011047373 W US 2011047373W WO 2012024153 A1 WO2012024153 A1 WO 2012024153A1
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- water
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/47—Separation; Purification; Stabilisation; Use of additives by solid-liquid treatment; by chemisorption
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C63/00—Compounds having carboxyl groups bound to a carbon atoms of six-membered aromatic rings
- C07C63/14—Monocyclic dicarboxylic acids
- C07C63/15—Monocyclic dicarboxylic acids all carboxyl groups bound to carbon atoms of the six-membered aromatic ring
- C07C63/26—1,4 - Benzenedicarboxylic acid
Definitions
- This invention relates improving terephthalic acid purge filtration rate by controlling weight percent water in filter feed slurry and to the recovery of a metal catalyst from an oxidizer purge stream produced in the synthesis of carboxylic acid, typically terephthalic acid, while utilizing pressure filtration.
- Terephthalic acid is commercially produced by oxidation of paraxylene in the presence of a catalyst, such as, for example, Co, Mn, Br and a solvent.
- a catalyst such as, for example, Co, Mn, Br and a solvent.
- Terephthalic acid used in the production of polyester fibers, films, and resins must be further treated to remove impurities formed as a result of the oxidation of paraxylene.
- TPA Terephthalic acid
- p-xylene p-xylene
- a bromide promoter in an acetic acid solvent. Due to the limited solubility of TPA in acetic acid under practical oxidation conditions, a slurry of TPA crystals is usually formed in the oxidation reactor.
- the TPA oxidizer slurry is withdrawn from the reactor and TPA solids are separated from the oxidizer mother liquor using conventional solid-liquid separation techniques. The oxidizer mother liquor, which contains most of the catalyst and promoter used in the process, is recycled to the oxidation reactor.
- the oxidizer mother liquor stream also contains dissolved TPA and many by-products and impurities. These by-products and impurities arise partially from minor impurities present in the p-xylene feed stream. Other impurities arise due to the incomplete oxidation of p- xylene resulting in partially oxidized products. Still other by-products result from competing side reactions formed as a result of the oxidation of p-xylene to terephthalic acid.
- Patents disclosing the production of terephthalic acid such as U.S patent #4, 158,738 and #3,996,271 are hereby incorporated by reference in their entirety to the extent that they do not contradict statements herein.
- the TPA solids undergo a solid-liquid separation wherein fresh solvent is utilitized to displace a major portion of the liquid component of the oxidizer mother liquor.
- impurities in the oxidizer mother liquor stream that are recycled are relatively inert to further oxidation.
- impurities include, for example, isophthalic acid, phthalic acid and trimellitic acid.
- Impurities, which may undergo further oxidation are also present, such as, for example, 4-carboxybenzaldehyde, p-toluic acid and p- tolualdehyde.
- Oxidation inert impurities tend to accumulate in the oxidizer mother liquor upon recycle. The concentration of these inert impurities will increase in the oxidizer mother liquor until an equilibrium is reached whereby the rate of removal of each impurity via the TPA product balances with the rate of formation and the rate of addition to the oxidation process.
- the normal level of impurities in commercial crude TPA makes it unsuitable for direct use in most polymer applications.
- One technique for impurity removal from a recycle stream commonly used in the chemical processing industry is to draw out or "purge" some portion of the recycle stream.
- the purge stream is simply disposed of or, if economically justified, subjected to various treatments to remove undesired impurities while recovering valuable components.
- U.S. # 4,939,297 herein incorporated by reference in their entirety to the extent that they do not contradict statements herein.
- the amount of purge required for control of impurities is process-dependent; however, a purge amount equal to 10-40% of the total oxidizer mother liquor stream is usually sufficient to produce TPA adequate as feedstock for commercial polymer manufacture.
- the percentage purge of the oxidizer mother liquor stream purge necessary to maintain acceptable impurity concentrations coupled with the economic value of the metal catalyst and solvent components in the oxidizer purge stream, make simple disposal of the oxidizer purge stream economically unattractive.
- the metal catalyst can be recovered in an active form suitable for reuse by direct recycling to the p-xylene oxidation step.
- a number patents teach a terephthalic acid process comprising a purge process comprising concentration, filtration, followed by
- Evaporative concentration of a purge feed comprising acetic acid and water results in a super concentrated purge slurry with lower % weight water content relative to the purge fed because water has a lower boiling point that acetic acid.
- a purge slurry feed comprising acetic acid and water
- the filtration rate of said super concentrated purge slurry in a terephthalic acid purge process can vary greatly depending upon the % water in said super concentrated purge slurry.
- Variability in the super concentrated purge slurry filtration rate is an attribute of the slurry and is related to the particle size distribution of the solids in the slurry.
- disclosure methods for controlling the % water in the super concentrated purge slurry that improves the filtration rate of said super concentrated purge slurry.
- This invention relates to removal of impurities and the recovery of a metal catalyst from an oxidizer purge stream produced in the synthesis of carboxylic acids, typically terephthalic acid, the process comprising:
- terephthalic acid process comprising a carboxylic acid, a metal catalyst, impurities, water and a solvent comprising acetic acid to evaporation in a 1st evaporator zone to produce a 1 st vapor stream and a concentrated purge stream;
- Figure 1 illustrates an embodiment of the invention wherein a method for removing impurities from an oxidizer purge stream formed in a terephthalic acid process comprising acetic acid, water, a metal catalyst, and oxidation impurities by (a) evaporating a portion of an oxidizer purge stream in a first evaporator zone to produce a
- Ranges may be expressed herein as from “about” one particular value, and/or to "about” another particular value. When such a range is expressed, another embodiment includes from the one particular value and/or to the other particular value. Similarly, when values are expressed as approximations, by use of the antecedent "about,” it will be understood that the particular value forms another embodiment. It will be further understood that the endpoints of each of the ranges are significant both in relation to the other endpoint, and independently of the other endpoint.
- a process to remove oxidation by-product impurities from an oxidizer purge stream 101 is provided as shown in FIG. 1.
- the process comprises the following steps.
- Step (a) comprises subjecting an oxidizer purge stream 101 to evaporation in a first evaporator zone 120 to produce a 1 st vapor stream 121 and a concentrated purge stream 122.
- the oxidizer purge stream 101 is withdrawn from a carboxylic acid oxidative synthesis process comprising terephthalic acid.
- One method for generating oxidizer purge stream 101 is to filter terephthalic acid oxidizer slurry and collect a portion of the mother liquor exiting the filter and routing it to the purge process.
- Yet another method for generating oxidizer purge stream 101 is to conduct a solvent swap on terephthalic acid oxidation slurry displacing a portion of the oxidation mother liquor and routing it to the purge process.
- the oxidation mother liquor obtained from a terephthalic acid process can be cooled to a
- a clarification pressure filter such as a candle filter to remove any solids present before routing it to the 1 st evaporator in the purge process.
- the oxidizer purge stream 101 serves as the feed stream to the present terephthalic acid purge process.
- the oxidizer purge stream 101 serves as the feed stream to the present terephthalic acid purge process.
- the impurities comprise organic bromides, corrosion metals, p-xylene oxidation by-products, and impurities derived as a result of impurities in the p-xylene.
- the organic bromides may be used as promoters in the oxidation reaction. Examples of corrosion metals are iron and chromium compounds, which inhibit, reduce or entirely destroy the activity of the metal catalyst.
- the oxidizer mother liquor stream also contains by-products and impurities. These by-products and impurities arise partially from minor impurities present in the p-xylene feed stream. Other impurities arise due to the incomplete oxidation of p-xylene resulting in partially oxidized products. Still other by-products result from competing side reactions in the oxidation of p-xylene to terephthalic acid.
- Carboxylic acids include aromatic carboxylic acids produced via controlled oxidation of an organic substrate.
- aromatic carboxylic acids include compounds with at least one carboxylic acid group attached to a carbon atom that is part of an aromatic ring, preferably having at least 6 carbon atoms, even more preferably having only carbon atoms.
- Suitable examples of such aromatic rings include, but are not limited to, benzene, biphenyl, terphenyl, naphthalene, and other carbon-based fused aromatic rings.
- carboxylic acids include, but are not limited to, terephthalic acid, benzoic acid, p- toluic acid, isophthalic acid, trimellitic acid, naphthalene dicarboxylic acid, 2,5-diphenyl-terephthalic acid and mixtures thereof.
- Suitable solvents include, but are not limited to, aliphatic mono- carboxylic acids, preferably containing 2 to 6 carbon atoms, or benzoic acid and mixtures thereof and mixtures of these compounds with water.
- the solvent is acetic acid mixed with water, in a ratio of about 5:1 to about 25:1 , preferably between about 8:1 and about 20:1 , and most preferably between about 11 :1 and 20:1.
- acetic acid will be referred to as the solvent.
- suitable solvents such as those disclosed previously, may also be utilized.
- the oxidizer purge stream 101 is concentrated by conventional means in a first evaporator zone 120 comprising an evaporator to produce a 1 st vapor stream 121 and concentrated purge stream 122.
- the evaporator is operated at atmospheric or slightly super atmospheric conditions, generally from about 1 atmosphere to about 10 atmospheres.
- the vapor stream 121 comprises a majority of the water and solvent
- the concentrated purge stream 122 comprises the remainder of the water and solvent not removed from the oxidizer purge stream 101.
- the evaporation removes about 50 wt % to about 85 wt % of the solvent mass present in the oxidizer purge stream 101.
- Step (b) subjecting the concentrated purge stream 122 and stream 131 comprising water to mix zone 130 to produce a water rich concentrated purge stream 132.
- the water rich concentrated purge stream 132 is enriched in water in that the % water in the water rich concentrated purge stream 132 is greater the concentrated purge stream 122.
- Any equipment know in the art for mixing two liquid streams can be utilized including mixing the two streams in a pipe equipped with an internal static mixer.
- (mass/time) of stream 131 added in mix zone 130 is manipulated to control the weight percent(wt%) water contained in the downstream super concentrated purge slurry stream 142 from about 5.0 wt% to about 25.0 wt% water.
- Another range to control the water content of stream 142 is from about 8.0 wt% water to about 23.0 1% water.
- Yet another range to control the water content of stream 142 is from about 11.0 wt% water to about 21.0 wt% water.
- the conduit between the 1 st evaporator 120 and mix zone 130 should be maintained at a temperature at or above 90°C to prevent solids from coming out of solution in the conduit.
- Step (c) subjecting said water rich concentrated purge stream 132 to evaporation in a second evaporator zone 140 to produce a 2 nd vapor stream 141 and said super concentrated purge slurry stream 142.
- the conduit between mix zone 130 and the second evaporator 140 should be maintained at a temperature at or above 80°C to minimize the amount of solids coming out of solution in the conduit.
- the second evaporator zone 140 comprises at least one evaporator operated at vacuum conditions.
- the evaporation can be conducted at a temperature from about 20°C to about 70°C; another range is from about 30°C to about 60°C.
- the combination of evaporators 120 and 140 are operated so as to concentrate the oxidizer purge stream 101 to a condition wherein about 75 wt. % to about 97 wt % of mass of stream 101 is removed by evaporation.
- condition of the super concentrated purge slurry 142 can be as a solid-liquid mixture with only enough solvent to provide pump ability.
- Step (d) comprises filtering a super concentrated purge slurry 142 in a filtration zone 160 to form a filter cake 164 and a mother liquor 163;
- the wash stream 166 comprises water.
- the filtration zone 160 comprises at least one solid liquid separation device.
- the filtration zone 160 and the wash zone 161 and optionally the dewater zone 162 can be accomplished in one solid liquid separation device or in multiple devices in a solid liquid separation zone 200.
- Example of such devices include but are not limited to continuous pressure filters, continuous vacuum filters, batch pressure filters, centrifuges, and like devices.
- the solid liquid separation zone and the wash zone and the optional dewatering zone can be accomplished in one device.
- Example of such devices include but are not limited to continuous pressure filters, continuous vacuum filters, batch pressure filters, centrifuges, and like devices
- a suitable pressure filter which can be adapted to the requirements of the instant invented process is a BHS-FEST.TM, rotary drum pressure filter, although other pressure filters which can accomplish the required operation can be used.
- Other devices that can used in the filtration zone include 160, but are not limited to; vacuum belt filters, filter presses, centrifuges, pressure leaf filters, pressure drum filters , and vacuum drum filters.
- the pressure filter can be operated at temperature and pressure sufficient to obtain at least 80% recovery of the metal catalyst from the solute of the mother liquor 163.
- the pressure filter can be operated at a temperature of about 25°C to about 80°C, and a pressure of 2 bar to 6 bar gauge.
- Step (f) comprises mixing in 2 nd mixing zone 170 a water stream 171 with mother liquor stream 163 and optionally a portion of the wash liquor stream 167 to form an aqueous mixture 172.
- the mixing zone 170 comprises a conventional mixer. If necessary, the water 171 can be added to the mixing zone 170 in sufficient quantity to dissolve the metal catalyst in the aqueous mixture stream 172.
- the water stream 171 is added to in mixing zone 170 in sufficient quantity to dissolve catalyst resulting in an aqueous mixture 172 where in the ratio of acetic acid to water ranges from about 0.7:1 to 1.4:1 , preferably from about 0.8:1 to 1.3:1 , and most preferably from about 0.9:1 to 1.2:1. It is desirable to keep the aqueous mixture 172 circulating with an external circulation loop.
- a small amount of extraction solvent 181 generally about 1 to about 10% by weight, preferably less than 5% by weight may be added to the mixing zone 170 to enhance slurry handling by reducing adherence of solids to the side of vessels. This is represented by the dashed arrow from stream 181 in FIG. 1.
- aqueous mixture 172 prior to extraction, to a heat treatment at about 60°C to about 95°C, another range is about 80°C about 90°C for about 0.5 to about 4 hours, preferably about 1 to about 2 hours.
- organic bromides are reacted to yield inorganic bromides which are preferentially retained in the raffinate stream 183.
- the quantity of bromine-containing compounds purged from the system along with the unwanted impurities is thereby minimized.
- the heat treatment conserves bromides and simplifies disposal of the organic impurities.
- Step (g) comprises contacting an extraction solvent 181 with the aqueous mixture 172 in an extraction zone 180 to form an extract stream 182 and the raffinate stream 183.
- the aqueous mixture 172 is fed to an extraction zone 180 wherein the aqueous mixture 172 and the extraction solvent 181 are contacted in the extraction zone 180.
- the aqueous mixture 172 and the extraction solvent 181 are mixed to form an extract stream 182 comprising solvent, water, organic impurities, and extraction solvent which forms a lighter phase, and the raffinate stream 183 comprising a metal catalyst, corrosion metals, and water.
- the extract stream 182 is withdrawn as an overhead stream and the raffinate stream 183 is withdrawn from the bottom of extractor in extraction zone 180.
- one embodiment of the extraction zone 180 is a single stage extractor.
- the extraction solvent 181 used in the extractor should be substantially water-immiscible to minimize the amount of organic solvent dissolved in the aqueous fraction. Additionally, the extraction solvent 181 is preferably an azeotropic agent which serves to assist solvent recovery from the organic extract. Solvents which have proven to be particularly useful are C1 to C6 alkyl acetates, particularly n-propyl acetate, isopropyl acetate, isobutyl acetate, sec-butyl acetate, ethyl acetate and n-butyl acetate, although other substantially water-inmiscible organic solvents having an appropriate density and a sufficiently low boiling point may also be used, such as p-xylene. N-propyl acetate and isopropyl acetate are particularly preferred due to their relatively low water miscibility and excellent azeotropic behavior.
- the extraction can be effected using solvent ratios from about 1 -4 parts by weight extraction solvent per part aqueous mixture.
- the extraction can be operated at ambient temperature and pressure, heating the solvent and extractor to about 30°C to about 70°C, another range of about 40°C to about 60°C can be used.
- the extract stream 109 comprises small amounts of the metal catalyst and corrosion metals, essentially all of the metal catalyst and the majority of the remaining corrosion metals are contained in the heavier phase, raffinate stream 183.
- Step (h) comprises separating the extract stream 182 in a separation zone 190 to form a high boiling point organic impurities stream 192 and a recovered extraction solvent stream 191.
- the extract stream 182 comprises organic solvent and organic impurities.
- the extract stream 182 can further comprises acetic acid and water, often in minor amounts.
- the extract stream 182 may be distilled in a separation zone 190 comprising conventional distillation equipment.
- Convention distillation equipment includes, for example, a distillation column.
- the organic impurities are extracted by the organic solvent in the extraction zone, 180. This occurs because the organic impurities show a high degree of solubility for the organic solvent and to a lesser extent for acetic acid.
- the recovered extraction solvent stream 191 may be recycled to the extractor in the extraction zone 180.
- the high-boiling organic impurities stream 192 are removed as sludge from the base of the distillation column for disposal.
- evaporation zone 120 and 140 are operated in a continuous fashion as oppesed to batch operation.
- the purge process is operated in a continuous fashion as opposed to batch operation.
- Example 1 The data for Examples 1 through 9 is outlined in Table 1 and Figure 2 was generated in a laboratory. An objective of these examples is to illustrate the relationship between the % water in the super concentrated purge slurry stream 142 and the filtration rate of the super concentrated purge slurry stream 142 in a pressure filter. It is also an objective of these examples to illustrate how to generate super concentrated purge slurry stream 142 with a range of water contents.
- the % water in the super concentrated purge slurry stream 142 ranges from 2.5% to 25% and the filtration rate of the super concentrated purge slurry stream 142 ranges from 30 kg filtrate/minute square meter to 1110 kg filtrate/minute square meter respectively.
- oxidizer purge feed 101 was obtained from a commercial plant comprising about 6% water and 94% acetic acid. 75% of the mass of oxidizer purge feed was removed by evaporation at 120°C in a 1 st evaporator zone resulting in a concentrated purge stream 122 comprising about 4.6% water.
- the concentrated purge stream 122 was subjected to additional evaporative concentration at a final temperature of at about 55°C resulting in a super concentrated purge slurry 142 comprising water of about 2.5% and a total evaporative loss of about 92% of the original oxidizer purge feed.
- the resulting super concentrated purge slurry was filtered in a lab scale pressure filter operated at 3 bar pressure gauge with filtration area of 20 cm 2 , washed with water, and dewatered with N 2 .
- the filtration rate was calculated by dividing the total liquid mass (mother liquor + wash liquor) by the filtration area of 20cm 2 and the sum of the filtration time and wash time.
- 120°C concentrated purge stream 122 was mixed continuously in a mix zone with varying amounts of ambient temperature water and then subjected to additional evaporative concentration at a final temperature of about 55°C resulting in super concentrated purge stream 142 comprising water ranging from about 8 weight percent(wt%) to 25wt%. About 92wt% of the original mass of the oxidizer purge feed is lost during evaporative concentration.
- the resulting super concentrated purge stream 142 were filtered in a lab scale pressure filter operated at 3 bar pressure gauge with filtration area of 20 cm 2 , washed with water, and dewatered with N 2 .
- the addition of water must occur at a point in the purge process prior to the final evaporative concentration zone.
- the water addition step can occur after the 1 st evaporative concentration zone in a purge process with two evaporative concentration zones.
- the water addition can also occur prior to the 1 st evaporator zone but is not desirable due to the higher energy costs associated with evaporative concentration prior to the filtration zone 200.
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Priority Applications (10)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EA201390259A EA027100B1 (en) | 2010-08-20 | 2011-08-11 | Improving terephthalic acid purge filtration rate by controlling water percentage in filter fed slurry |
CN201180050950.XA CN103168021B (en) | 2010-08-20 | 2011-08-11 | Terephthalic acid cleaning and filtering speed is improved by the percentage ratio of water in controlling filter feed slurry |
JP2013524875A JP5973437B2 (en) | 2010-08-20 | 2011-08-11 | Increasing terephthalic acid purge filtration rate by controlling the percentage of water in the filter feed slurry |
EP11818582.6A EP2606024B1 (en) | 2010-08-20 | 2011-08-11 | Improving terephthalic acid purge filtration rate by controlling % water in filter feed slurry |
ES11818582.6T ES2566500T3 (en) | 2010-08-20 | 2011-08-11 | Improved filtration rate of terephthalic acid purge by controlling the percentage of water in a filter feed suspension |
CA2808087A CA2808087C (en) | 2010-08-20 | 2011-08-11 | Improving terephthalic acid purge filtration rate by controlling % water in filter feed slurry |
MX2013001961A MX343485B (en) | 2010-08-20 | 2011-08-11 | Improving terephthalic acid purge filtration rate by controlling % water in filter feed slurry. |
KR1020137006910A KR101943116B1 (en) | 2010-08-20 | 2011-08-11 | Improving terephthalic acid purge filtration rate by controlling % water in filter feed slurry |
BR112013003894-2A BR112013003894B1 (en) | 2010-08-20 | 2011-08-11 | Terephthalic Acid Purge Process |
UAA201303398A UA110491C2 (en) | 2010-08-20 | 2011-11-08 | Process of terephthalic acid purge filtration |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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US12/860,131 | 2010-08-20 | ||
US12/860,131 US9963413B2 (en) | 2010-08-20 | 2010-08-20 | Terephthalic acid purge filtration rate by controlling % water in filter feed slurry |
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WO2012024153A1 true WO2012024153A1 (en) | 2012-02-23 |
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PCT/US2011/047373 WO2012024153A1 (en) | 2010-08-20 | 2011-08-11 | Improving terephthalic acid purge filtration rate by controlling % water in filter feed slurry |
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US (1) | US9963413B2 (en) |
EP (1) | EP2606024B1 (en) |
JP (1) | JP5973437B2 (en) |
KR (1) | KR101943116B1 (en) |
CN (1) | CN103168021B (en) |
AR (1) | AR082486A1 (en) |
BR (1) | BR112013003894B1 (en) |
CA (1) | CA2808087C (en) |
EA (1) | EA027100B1 (en) |
ES (1) | ES2566500T3 (en) |
MX (1) | MX343485B (en) |
MY (1) | MY162469A (en) |
PL (1) | PL2606024T3 (en) |
TW (1) | TWI551585B (en) |
UA (1) | UA110491C2 (en) |
WO (1) | WO2012024153A1 (en) |
Cited By (1)
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US9963413B2 (en) | 2010-08-20 | 2018-05-08 | Grupo Petrotemex, S.A. De C.V. | Terephthalic acid purge filtration rate by controlling % water in filter feed slurry |
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US8466312B2 (en) * | 2010-08-20 | 2013-06-18 | Grupo Petrotemex, S.A. De C.V. | Terephthalic acid purge filtration rate by controlling % water in filter feed slurry |
JP2015140342A (en) * | 2014-01-30 | 2015-08-03 | 株式会社日立製作所 | Method for manufacturing refined terephthalic acid |
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US9963413B2 (en) | 2010-08-20 | 2018-05-08 | Grupo Petrotemex, S.A. De C.V. | Terephthalic acid purge filtration rate by controlling % water in filter feed slurry |
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2010
- 2010-08-20 US US12/860,131 patent/US9963413B2/en active Active
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2011
- 2011-08-11 MX MX2013001961A patent/MX343485B/en active IP Right Grant
- 2011-08-11 KR KR1020137006910A patent/KR101943116B1/en active IP Right Grant
- 2011-08-11 PL PL11818582.6T patent/PL2606024T3/en unknown
- 2011-08-11 MY MYPI2013000467A patent/MY162469A/en unknown
- 2011-08-11 BR BR112013003894-2A patent/BR112013003894B1/en active IP Right Grant
- 2011-08-11 EA EA201390259A patent/EA027100B1/en not_active IP Right Cessation
- 2011-08-11 JP JP2013524875A patent/JP5973437B2/en active Active
- 2011-08-11 WO PCT/US2011/047373 patent/WO2012024153A1/en active Application Filing
- 2011-08-11 CA CA2808087A patent/CA2808087C/en active Active
- 2011-08-11 CN CN201180050950.XA patent/CN103168021B/en active Active
- 2011-08-11 EP EP11818582.6A patent/EP2606024B1/en active Active
- 2011-08-11 ES ES11818582.6T patent/ES2566500T3/en active Active
- 2011-08-18 AR ARP110103006A patent/AR082486A1/en active IP Right Grant
- 2011-08-19 TW TW100129862A patent/TWI551585B/en active
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Also Published As
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UA110491C2 (en) | 2016-01-12 |
CN103168021A (en) | 2013-06-19 |
CA2808087C (en) | 2018-11-20 |
EP2606024A1 (en) | 2013-06-26 |
JP5973437B2 (en) | 2016-08-23 |
BR112013003894A2 (en) | 2016-07-12 |
CA2808087A1 (en) | 2012-02-23 |
US9963413B2 (en) | 2018-05-08 |
MX2013001961A (en) | 2013-05-09 |
TW201219367A (en) | 2012-05-16 |
AR082486A1 (en) | 2012-12-12 |
EP2606024B1 (en) | 2016-02-24 |
EA027100B1 (en) | 2017-06-30 |
KR20130099061A (en) | 2013-09-05 |
EA201390259A1 (en) | 2013-11-29 |
CN103168021B (en) | 2015-11-25 |
JP2013536197A (en) | 2013-09-19 |
KR101943116B1 (en) | 2019-01-28 |
PL2606024T3 (en) | 2016-09-30 |
ES2566500T3 (en) | 2016-04-13 |
TWI551585B (en) | 2016-10-01 |
MY162469A (en) | 2017-06-15 |
BR112013003894B1 (en) | 2019-03-26 |
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