WO2011112643A2 - Cationic uv-crosslinkable acrylic polymers for pressure sensitive adhesives - Google Patents
Cationic uv-crosslinkable acrylic polymers for pressure sensitive adhesives Download PDFInfo
- Publication number
- WO2011112643A2 WO2011112643A2 PCT/US2011/027632 US2011027632W WO2011112643A2 WO 2011112643 A2 WO2011112643 A2 WO 2011112643A2 US 2011027632 W US2011027632 W US 2011027632W WO 2011112643 A2 WO2011112643 A2 WO 2011112643A2
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- WO
- WIPO (PCT)
- Prior art keywords
- pressure sensitive
- adhesive
- sensitive adhesive
- ultra
- monomer
- Prior art date
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- 0 *C1C(*)*C2OC2C1 Chemical compound *C1C(*)*C2OC2C1 0.000 description 1
- AZTFWMLQRNZIQN-UHFFFAOYSA-N CC(C)(COC(C)(C)c(cc1)ccc1C(C)=O)OC(NC(C)(C)c1cc(C(C)=C)ccc1)=O Chemical compound CC(C)(COC(C)(C)c(cc1)ccc1C(C)=O)OC(NC(C)(C)c1cc(C(C)=C)ccc1)=O AZTFWMLQRNZIQN-UHFFFAOYSA-N 0.000 description 1
- ACNQGCISLKLMDO-UHFFFAOYSA-N CC(C)(c1cccc(C(C)=C)c1)NC(OCCCS(C)(C)O[Si](C)(C)CCCOc(cc1)ccc1C(c1ccccc1)=O)=O Chemical compound CC(C)(c1cccc(C(C)=C)c1)NC(OCCCS(C)(C)O[Si](C)(C)CCCOc(cc1)ccc1C(c1ccccc1)=O)=O ACNQGCISLKLMDO-UHFFFAOYSA-N 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J137/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a heterocyclic ring containing oxygen; Adhesives based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J143/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Adhesives based on derivatives of such polymers
- C09J143/04—Homopolymers or copolymers of monomers containing silicon
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/22—Plastics; Metallised plastics
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
- C09J7/38—Pressure-sensitive adhesives [PSA]
- C09J7/381—Pressure-sensitive adhesives [PSA] based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C09J7/385—Acrylic polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1808—C8-(meth)acrylate, e.g. isooctyl (meth)acrylate or 2-ethylhexyl (meth)acrylate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
- C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
- C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
- C08F220/281—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing only one oxygen, e.g. furfuryl (meth)acrylate or 2-methoxyethyl (meth)acrylate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2312/00—Crosslinking
- C08L2312/06—Crosslinking by radiation
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
- C09J2301/416—Additional features of adhesives in the form of films or foils characterized by the presence of essential components use of irradiation
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2423/00—Presence of polyolefin
- C09J2423/10—Presence of homo or copolymers of propene
- C09J2423/106—Presence of homo or copolymers of propene in the substrate
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2467/00—Presence of polyester
- C09J2467/006—Presence of polyester in the substrate
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
- Y10T428/2809—Web or sheet containing structurally defined element or component and having an adhesive outermost layer including irradiated or wave energy treated component
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
- Y10T428/2813—Heat or solvent activated or sealable
- Y10T428/2817—Heat sealable
- Y10T428/2826—Synthetic resin or polymer
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y10T428/2852—Adhesive compositions
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- Y10T428/287—Adhesive compositions including epoxy group or epoxy polymer
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- Y10T428/2878—Adhesive compositions including addition polymer from unsaturated monomer
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- Y10T428/2878—Adhesive compositions including addition polymer from unsaturated monomer
- Y10T428/2891—Adhesive compositions including addition polymer from unsaturated monomer including addition polymer from alpha-beta unsaturated carboxylic acid [e.g., acrylic acid, methacrylic acid, etc.] Or derivative thereof
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- Y10T428/31511—Of epoxy ether
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Definitions
- the invention relates to an ultra-violet curable pressure sensitive adhesive comprising an acrylic polymer with pendant reactive functional groups.
- PSAs Pressure sensitive adhesives
- PSA compositions are commonly applied to various substrates, such as paper, fabric, metal, and plastic films that are then converted into a large number of different products, especially pressure sensitive adhesive tapes and labels.
- These pressure sensitive adhesive products have a broad field of application in the automobile industry, e.g., for fastening or sealing, in the pharmaceutical industry, e.g., for bandages or transdermal drug delivery systems, or in the packaging industry, e.g., for sealing, bonding or labeling.
- PSAs can be formulated for application as a solvent borne or a molten adhesive.
- Hot melt pressure sensitive adhesives are compositions that combine the properties of hot melt adhesives with those of pressure sensitive adhesives. Hot melt adhesives are solids at room
- HMPSA high cohesive strength at room temperature, low shrinkage on substrates, retention of pressure sensitive properties during storage and use, and a relatively fluid viscosity at typical coating temperatures (e.g., between 80°C and 180°C). Although very low molecular weight polymers will yield hot melt adhesives with sufficient fluidity, the resulting adhesives lack cohesive strength. Very high molecular weight polymers give better cohesive strength, but are too viscous at the common application temperatures to be easily coatable on substrates.
- Acrylic polymers with epoxy functional groups have been known in prior art.
- An example of such polymers are described in JP1186876, however, these polymers fail to crosslink under UV radiation and/or heat.
- JP2008-208149 is directed to acrylic copolymers with non free radical polymerizable oxetane compounds as a polymerization medium and reactive diluent.
- the polymerization is completed with heat and/or x-ray irradiation to form an adhesive for a flat panel display.
- JP19940816 and 1996060127 describe UV-curable acrylic polymers but require the addition of multifunctional polyol and other hydroxy-functional groups for crosslinking the polymers.
- JP2003147311 is directed to the use of photopolymerizable diacrylate . Due to the difunctional acrylate which crosslinks upon radical polymerization, it is less desirable for use in an adhesive, and especially unsuitable for a solvent borne or hot melt adhesive, because it is necessary to polymerize the acrylate monomers following application onto the final coated substrate.
- the invention provides cationic ultra-violet-curable pressure sensitive adhesive comprising (a) crosslinkable acrylic polymers which comprise pendant reactive functional groups and (b) a cationic photoinitiator.
- the crosslinkable acrylic polymer (a) of the adhesive comprises (i) an acrylic monomer which is an acrylic or methacrylic acid derivative of the formula
- Ri is H or CH 3 and R 2 is C1.20 alkyl chain and (ii) a monomer with a pendant reactive functional group selected from cycloaliphatic epoxide, oxetane or mixtures thereof, and the amount of the monomer (ii) is from about 0.001 to about 0.015 equivalent per lOOg of the acrylic polymer.
- the acrylic polymer is essentially free of multi-(meth)acrylate, polyol or OH- functional groups and the polymer remains substantially linear after polymerization.
- the crosslinkable acrylic polymer (a) of the adhesive comprises
- CH2 CH(Ri)(COOR 2 ), wherein R ⁇ is H or C3 ⁇ 4 and R 2 is Ci. 2 o alkyl chain and (ii) a monomer with a combination of pendant reactive functional groups selected from (1) cycloaliphatic epoxide, oxetane, benzophenone or mixtures thereof, and (2) mono-substituted oxirane; and the amount of the monomer
- (ii) is the amount of about 0.001 to about 0.015 equivalent per lOOg of the acrylic polymer.
- the acrylic polymer is essentially free of multi-(meth)acrylate, polyol or OH-functional groups and the polymer remains substantially linear after polymerization.
- the cationic photoinitiator (b) the adhesive has the structure of
- R is C 3 H 7 , C i2 H 2 5, W is S, SO, S0 2 or CO.
- the cationic ultra-violet-curable pressure sensitive adhesive further comprises a polyethylene copolymer additive, plasticizer, fillers, inhibitors, antioxidants, accelerators, tackifier and/or solvent.
- a further embodiment is directed to a method of preparing a crosslinkable acrylic polymer which comprises pendant reactive functional groups.
- the adhesive is in a form of a solvent borne acrylic pressure sensitive adhesive or an acrylic hot melt pressure sensitive adhesive.
- the adhesive article further comprises a backing which is a polyester, polypropylene, metal or glass.
- the adhesives are particularly advantageous as a tape, an adhesive transfer film, a decorative or protective film, decal or label.
- Figure 1 is a graph of viscosity over time at 130°C, measured by Brookfield viscometer. DETAILED DESCRIPTION OF THE INVENTION
- the invention provides the art with acrylic polymers comprising UV-reactive pendant functional groups bound to the polymer chain. Depending upon the bound functional groups, the acrylic polymer undergoes fast UV-crosslinking reaction and provides green strength and/or undergoes post-UV crosslinking in the presence of a cationic photoinitiator to results in adhesives with high cohesive strength and high temperature holding strength.
- the acrylic polymers are those having the following composition or those that can be prepared by polymerizing (i) an acrylic monomer which is an acrylic or methacrylic acid derivative (e.g. methacrylic acid ester) of the formula
- CH 2 CH(R')(COOR 2 ), where R 1 is H or CH 3 and R 2 is a Ci. 20 , preferably C
- the monomers are chosen such that the resulting polymers can be used to prepare adhesives, especially such that the resulting polymers possess pressure sensitive adhesive properties in accordance with the "Handbook of Pressure Sensitive Adhesive Technology" by Donatas Satas (van Nostrand, N.Y. 1989).
- Examples of acrylates and or methacrylates useful as components of monomer mixture (i) include methyl acrylate, ethyl acrylate, ethyl methacrylate, methyl methacrylate, n-butyl acrylate, n- butyl methacrylate, n-pentyl acrylate, n-hexyl acrylate, n-heptyl acrylate, and n-octyl acrylate, n-nonyl acrylate, lauryl methacrylate, cyclohexyl acrylate, and branched (meth)acrylic isomers, such as i-butyl acrylate, i-butyl methacrylate, n-butyl methacrylate, 2-ethylhexyl acrylate, stearyl methacrylate., and isooctyl acrylate.
- the exemplary acrylates and/or methacrylates are mono-acrylic monomers, and do not include any di or multi-acrylate monomers.
- the exemplary acrylic monomer mixture (i) has a Tg value less than 0°C and a weight average molecular weight from about 10,000 to about 2,000,000 g/mol more preferably between 50,000 and 1,000,000 g mol and most preferably between 100,000 and 700,000 g/mol.
- the mixture (i) may be a single monomer provided that its homopolymer Tg is less than 0°C.
- Suitable monomer (ii) of the polymer is capable of undergoing cationic UV-activated crosslinking reaction and providing green strength to the adhesive films, include cycloaliphatic epoxide monomers M100 and A400 (Daicel), oxetane monomer OXE-10 ( owa Company), dicyclopentadienyl methacrylate (CD535, Sartomer Co., PA) epoxide, 4-vinyl-l-cyclohexene-l,2- epoxide (Dow).
- Other exemplary monomers (ii) include vinyl or acrylic compounds containing cationic UV-reactive functional groups with the formula (1):
- X is acrylate, methacrylate or comprises a -W-Y group, where
- W is O, S, amide, carbonate, urethane, urea, siloxane or a combination thereof, and
- a preferred vinyl or acrylic compound for use as monomer (ii) is represented by the formula
- R 6 H or CH 3 .
- the acrylic polymers are capable of undergoing post-UV cationic activated reaction and thus, provide high temperature holding strength to the adhesive films.
- the amount of the monomer (ii) is the amount of about 0.001 to about 0.015 equivalent per lOOg of the acrylic polymer.
- the acrylic polymer is essentially free of multi-(meth)acrylate, polyol or OH- functional groups and the polymer remains substantially linear after polymerization.
- the amount of the monomer (ii) is from about 0.002 to about 0.01 equivalent per lOOg of the acrylic polymer.
- Suitable monomer (ii) with benzophenone pendant reactive function groups ( 1 ) include the compounds of the following formula (2), (3), and (4):
- Z is S, 0, C3 ⁇ 4, or NH
- R' '8 are independently H, CI, Br, I, F, , or aryl; and wherein at least one of R 1-8
- W is a C].j2 alkylene or Ci-12 oxyalkylene
- X is carbonate, urethane, urea, tetramethyldisiloxane or a combination thereof, and
- a preferred vinyl or acrylic compound for use as monomer (ii) is represented by the structural formula (3A):
- Exemplary mono-substituted oxirane (2) of monomer(ii) include glycidyl methacrylate
- GMA l,2-epoxy-5-hexene
- cycloaliphatic epoxide monomer M100 and A400 OXE-10
- CD535 epoxide 4-vinyl-l-cyclohexene-1.2-epoxide.
- the invention also provides the art with UV-crosslinkable adhesives comprising the acrylic polymers herein and a cationic photoinitiator.
- the primary function of a photoinitiator is to initiate crosslinking reaction when the photoinitiator is irradiated with UV radiation.
- photoinitiators There are two main types of photoinitiators that can be used in this invention to initiate the crosslinking upon irradiation: radical photoinitiators and cationic photoimtiators.
- the most frequently used cationic photoinitiators are either organic iodonium or sulfonium salts.
- the mechanism of a cationic photoinitiator, when irradiated, is that it forms an excited state which then breaks down to release a radical cation.
- This radical cation reacts with the solvent, or other hydrogen atom donors, and generates a protonic acid, which is the active species that initiates the crosslinking reaction.
- any of the many compounds known to initiate polymerization by a cationic mechanism may be used for the crosslinking reaction in this invention. These include, for example,
- diaryliodonium salts triarylsulfonium salts, dialkylphenylsulfonium salts,
- dialkyl(hydroxydialkylphenyl)sulfonium salts and ferrocenium salts generally possess low nucleophilic character and include SbFe " PFe " AsF 6 ⁇ BF 4 ⁇ B ⁇ Fs ⁇ - or Ga(C 6 Fs) 4 ⁇ Specific examples include Cyracure UVI-6976 (Dow Chemical).
- Particularly useful cationic initiators are soluble and red-shifted sulfonium salt photoinitiators, which have increased solubility in UV-crosslinkable compositions, promote efficient thick film UV curing, and exhibit increased thermal stability in UV crosslinkable compositions before cure, exhibit increased curing rates, and have a reduced dark cure time, having the structural formula (6A) and (7 A):
- R is C 3 H 7 , C l2 H 25 , W is S, SO, SO 2 or CO.
- R 1 and R 2 are independently H, CH 3 , C 2 H 5 , C 3 H 7 , C12H25, OCH 3 , OC 2 H 5 , OC3H7, or OCi 2 H 25 .
- the adhesive may also comprise various other additives, such as plasticizers, tackifiers, and fillers, all of which are conventionally used in the preparation of PSAs.
- tackifier or tackifying resins to be added it is possible to use any known tackifying resins described in the literature. Non- limiting examples include pinene resins, indene resins, and their disproportionated, hydrogenated, polymerized, and esterified derivatives and salts, the aliphatic and aromatic hydrocarbon resins, terpene resins, terpene-phenolic resins, C5 resins, C9 resins, and other hydrocarbon resins. Any desired combinations of these or other resins may be used in order to adjust the properties of the resultant adhesive in accordance with the desired final properties.
- any resin which is compatible with the corresponding acrylic polymers reference may be made in particular to all aliphatic, aromatic, alkylaromatic hydrocarbon resins, hydrocarbon resins based on hydrocarbon resins, hydrogenated hydrocarbon resins, functional hydrocarbon resins, and natural resins. Explicit reference may be made to the depiction of the state of the art in the "Handbook of Pressure Sensitive Adhesive Technology" by Donatas Satas (van Nostrand, 1989).
- one or more plasticizers such as low molecular weight acrylic polymers, phthalates, benzoates, adipates, or plasticizer resins, are added to the acrylic HMPSAs.
- the acrylic PSAs may further be blended with one or more additives such as aging inhibitors, antioxidants, light stabilizers, compounding agents, and/or accelerators.
- additives such as aging inhibitors, antioxidants, light stabilizers, compounding agents, and/or accelerators.
- the adhesive may further be mixed with one or more fillers such as fibers, carbon black, zinc oxide, titanium dioxide, solid or hollow glass microbeads, microbeads of other materials, silica, silicates, and chalk.
- fillers such as fibers, carbon black, zinc oxide, titanium dioxide, solid or hollow glass microbeads, microbeads of other materials, silica, silicates, and chalk.
- the copolymers may optionally be blended with crosslinkers.
- suitable crosslinkers are functional acrylates.
- Preferred substances in accordance with the inventive process in which crosslinking occurs under radiation are, for example, difunctional or trifunctional acrylates, difunctional or polyfunctional urethane acrylates, difunctional or trifunctional or multi-functional acrylic epoxy resins such as Lumicryl 1000 and 1100 (Estron Chemical). It is, however, also possible here to use any further difunctional or polyfunctional compounds which are familiar to the skilled worker and are capable of crosslinking acrylic polymers. For optional thermal or moisture crosslinking it is possible to use blocked difunctional or
- hot melt PSAs are produced by all additives. All additives are either blended to the molten, solvent-free acrylic polymers, or more efficiently, added into the solutions of the copolymers at the end of the polymerization reactions. Upon the removal of the solvent, the mixtures are concentrated to give hot melt PSAs.
- the preparation of acrylic polymers can be carried out by solution, emulsion, or bulk polymerization procedures using well-known polymerization techniques, such as free radical techniques.
- the copolymers can then be formed into hot melt adhesives by removal of the solvent, coagulation of the latex, or melt-processing of the neat polymers.
- the polymerization may be conducted in the presence of one or more organic solvents and/or in the presence of water.
- Suitable organic solvents or mixtures of solvents are alkanes, such as hexane, heptane, octane, isooctane, and cyclohexane; aromatic hydrocarbons, such as benzene, toluene, and xylene; esters, such as ethyl, propyl, butyl and heptyl acetate; halogenated hydrocarbons, such as chlorobenzene; alkanols, such as methanol, ethanol, iso-propanol, ethylene glycol, and ethylene glycol monomethyl ether; ethers, such as diethyl ether and dibutyl ether; or mixtures thereof.
- the polymerization reactions proceed in an ethyl acetate solvent, thermally initiated by, for example, azobisisobutyronitrile (AIBN).
- AIBN azobisisobutyronitrile
- the acrylic polymers prepared will generally have a weight averaged average molecular weight (M w ) of from 10,000 to 2,000,000 g/mol, more preferably between 50,000 and 1,000,000 g/mol and most preferably between 100,000 and 700,000 g mol.
- M w is determined by gel permeation chromatography (GPC) or matrix-assisted laser desorption/ionization mass
- the acrylic polymers can be prepared by polymerizing monomer mixtures of (i) and (ii).
- preparation of the UV-crosslinkable acrylic polymers may comprise a two step reaction: (1) preparing acrylic polymers that have pendant isocyanate functionality by using w- ⁇ ® ( 3- isopropenyl-a,a-dimethylbenzyl isocyanate, Cytec) or MOI (2-methacryloyloxyethyl isocyanate, Showa Denko) as a co-monomer in polymerization reactions; and then (2) reacting the pendant isocyanate groups with hydroxyl-functionalized epoxide, oxetane, or benzophenone.
- the acrylic polymer does not contain any multi-functional acrylate and is substantially linear in its structure before UV crosslinking reaction. Therefore, the acrylic polymer, before crosslinking, is completely soluble in many organic solvents, and can also be easily applied on substrates in solvent-free form as a hot melt adhesive.
- the adhesives can be formulated as a solvent borne adhesive and used by coating films or paper with polymer solutions or suspensions and subsequently removing the solvent by drying.
- the acrylic polymers must be free of the solvent.
- the copolymers prepared as described above are concentrated to a solvent content of less than 2% by weight, preferably less than 0.2 % by weight. This process takes place preferably in a reaction tank, or vacuum mixer, concentration extruder, such as vent extruder, ring extruder, single-screw extruder, or twin-screw extruder, which are known to the skilled worker.
- Non-limiting examples of substrate are films, tapes, sheets, panels, foam, and the like; and can be made of materials such as paper, fabric, plastic (polyesters, PE, PP, BOPP, and PVC), nonwoven fiber, metal, foil, glass, natural rubber, synthetic rubber, wood, or plywood. If a coated substrate is to be used in the form of a self-wound roll, the back of the substrate is usually coated with a release coating to prevent the adhesive from adhering to the reverse side of the substrate.
- a substrate is to be coated with the adhesive on both sides and rolled, a strippable paper or other protective means is laid over the adhesive on one side to prevent that adhesive from adhering to the adhesives on the other.
- a second substrate may be applied directly to the adhesive.
- a hot melt adhesive is applied to a backing or substrate before crosslinking.
- the adhesive is formulated preferably to provide a composition that can be heated to render a coatable fluid on the substrate.
- Commonly used industrial coating temperatures are in the range of 80-180°C.
- the hot melt PSAs of this invention have melt viscosities between 1000-500,000 mPa.s, preferably between 5000-100,000 mPa.s at those application temperatures.
- a pressure sensitive adhesive film may be formed by applying the hot melt to a release liner, such as silicone coated paper or plastic film, and then after irradiation, the adhesive may be stripped from the release liner and used as a film.
- the adhesive can be coated onto a release liner, laminated and transferred to a substrate.
- the hot melt PSAs of the invention can be crosslinked in air by irradiation with UV light in the range from 200 to 500 nm, preferably 280 to 400 nm. Irradiation may be done
- Adhesive composition is irradiated for a period of time sufficient to transform the low cohesion composition into a viscoelastic adhesive of higher modulus.
- the exact length of the exposure is dependent upon the nature and intensity of the radiation, the amount of cationic photoinitiator, the polymer composition, adhesive formulation, the thickness of the adhesive film, environmental factors, and the distance between the radiation source and the adhesive film.
- the dosage or the length of exposure is conveniently controlled by the belt speed. It may be appropriate to adapt the lamp output to the belt speed or to shade off the belt partly, in order to reduce its thermal load.
- Actinic light from any source may be used on the adhesive, provided the source furnishes an effective amount of UV radiation.
- Suitable sources of radiation are carbon arcs, mercury- vapor arcs, fluorescent lamps with special ultraviolet light emitting phosphors, electronic flash lamps and the like, lasers of specific wavelengths, UV LED, or combinations of those.
- Preferred lamps are the electrodeless microwave powered lamps from Fusion Systems, or commercially customary high or medium pressure mercury lamps with an output of, for example, from 80 to 240 W/cm.
- the adhesive compositions of the invention generally exhibit their maximum sensitivity to wavelengths in the ultraviolet range.
- acrylic hot melt PSAs described in accordance with the invention may be crosslinked with electron beams. This type of crosslinking can also take place in addition to the UV crosslinking.
- the adhesives of the present invention may be used to bond one substrate to a second substrate.
- Substrates include but are not limited to plastic, glass or plastic-coated glass, wood, metal, etc.
- the adhesive may be applied by a variety of methods including coating or spraying in an amount sufficient to cause the substrates to be bonded together to adhere.
- the adhesive coated substrate may be irradiated before or after bonding. Since cure begins immediately upon irradiation, but may not be completed for several days, there is time immediately after irradiation, but before gelation for bonding to take place.
- the pressure sensitive adhesives of the invention may advantageously be used in the manufacture of adhesive articles including, but not limited to, industrial tapes and transfer films.
- the adhesive article comprises an adhesive coated on at least one major surface of a backing having a first and second major surface.
- Useful backing substrates include, but are not limited to foam, metal, paper, fabric, and various polymers such as polypropylene, polyamide, polyester, polyethylene terephthalate, and mixtures thereof.
- the adhesive may be present on one or both surfaces of the backing. When the adhesive is coated on both surfaces of the backing, the adhesive coatings can be the same or different.
- Adhesive samples were tested according to the following test methods for pressure sensitive tapes, some of which were developed by the Pressure Sensitive Tape Council (PSTC) or by FINAT (Federation INtemationale des solids et transformateurs d'Adhesifs et Thermocollants sur papier et herb supports).
- PSTC Pressure Sensitive Tape Council
- FINAT Federation INtemationale des
- a sample of UV-irradiated acrylic polymer (or formulated adhesive) was separated from the silicone release liner and weighed to the nearest 0.1 mg. The sample was then placed in a glass jar and immersed in toluene for 24 to 48 hours. The ratio of the sample mass after toluene extraction to the initial mass gave the gel fraction expressed as a percentage. If the sample was a formulated adhesive, the mass of any toluene-soluble component such as a tackifying resin was subtracted from the initial weight.
- a lab coater with two heatable rolls was used to apply the adhesive.
- the adhesive was heated to 150°C and coated onto a 2 mil (51 ⁇ ) thick silicone-coated PET release liner.
- the adhesive on the liner was irradiated at a line speed of 15 meters per minutes under H-bulb (Fusion Systems) with a dosage of UV C 257 mJ/cm 2 .
- the film was then laminated and transferred to a polyethylene terephthalate substrate (Mylar ® , DuPont) and conditioned at 23 °C and 50% relative humidity. Unless otherwise indicated, the adhesive film thickness was 3.5 mil (89 ⁇ ).
- Adhesive films were cured using medium pressure mercury arc lamps (using an 1ST UV curing laboratory unit).
- the UV C dose was measured and recorded using an EIT Power Puck. UV C is the region between 200 and 280 nm.
- Loop Tack was measured according to Test Method B, PSTC- 16, adapted as follows. A loop tack tester was used for the measurement. All test samples of the acrylic polymers were UV- irradiated according to the procedure described above. The adhesive was coated on 50 ⁇ PET film backing and the size of a specimen strip was 125 mm x 24 mm.
- Adhesives were cast in a range of coating weights (from 20-100 g/m 2 ) film onto a silicone liner using a Chemsultants ® hot melt laminator coater then cured (as noted above). The cured free film was transferred to 50 ⁇ PET backing film.
- Peel adhesion was measured as the force required to remove a pressure sensitive tape from a standard stainless steel panel at a specified angle and speed according to FINAT Test Method no. 1 adapted as follows.
- Equipment used to measure this value included a standard FINAT 2kg rubber-covered roller, and a standard Instron ® tensile testing machine.
- a stainless steel panel (AFERA steel from Rocholl GmbH) was cleaned as per standard FINAT method. Before the stainless steel panel was used it was abraded along the length of the test panel with a 400-grit waterproof wet and dry sanding paper under the tap, until water flowed smoothly over the steel plate. After this it was rinsed with water and dried, cleaned with ethyl acetate, and conditioned in a controlled climate room maintained at 23 °C and 50% relative humidity (RH), for at least 1 hour.
- RH relative humidity
- the coating to be tested was conditioned for 24 hours at 23°C + 2°C and 50% + 5% RH. Test strips were cut to 25 mm X 175 mm.
- the backing paper was removed from each strip and placed, adhesive side down, onto a clean test plate using light finger pressure, and then rolled twice in each direction with the standard 2kg FINAT test roller, at a speed of approximately 10mm per second. After applying the strips to the test plate at a rate of one per 2 minutes the strips were left until the first test piece had either 20 minutes or 24 hours elapsed time (dwell).
- the tensile tester was set with a crosshead speed of 300 mm/minute. The free end of the tape was doubled back at an angle of 180° and clamped to the upper jaw of the machine. The end of the panel was clamped to the lower jaw. The test strip was then peeled from the panel and the peel force was recorded in Newtons/25 mm width of tape.
- Adhesion Failure test piece separated from test plate without leaving any residue
- Cohesive Failure adheresive film split cohesively and residue left on test piece and test plate
- SAFT Shear Adhesion Failure Temperature
- Samples were adhered to the steel panel overlapping up to an engraved line so that a square 25 x 25mm of adhesive was in contact with the test panel.
- the test area was rubbed using a straight edged wooden applicator to ensure good contact between the panel and test sample.
- Samples were placed into the test oven at room temperature. The heating program was started and 1kg shear load applied when the temperature reached 40°C. The oven temperature was ramped at 0.5°C/ minute up to 200°C and the failure temperature (SAFT) was recorded.
- SAFT failure temperature
- Shear Resistance from a stainless steel surface was measured according to FINAT Test Method no.8 adapted as follows. Three samples, 25 mm x 100 mm in dimensions, were cut from each cured coating in the machine direction. Shear panels (pregritted steel) were cleaned with ethyl acetate. Samples were adhered to the steel panel up to the engraved line so that a square 25 x 25mm of adhesive was in contact with the test panel. The test area was rubbed using a straight edged wooden applicator to ensure good contact between the panel and test sample. The test specimens were conditioned for 15 minutes at 23 °C ⁇ 2°C and 50% ⁇ 5% RH. They were then mounted in the test fixture and a 1 or 2 kg weight applied. The time to failure was recorded.
- test specimens were placed into a preheated oven at 70°C, and left to acclimatize for 10 minutes. A 1 kg weight was applied and the time to failure recorded.
- Viscosity was measured by Brookfield DV-I Viscometer at 135°C, as shown in Figure 1. A 10 g sample was used with a spindle No 27 at a speed setting of 4 rpm.
- a 500 mL three-necked round bottom flask was equipped with a reflux condenser, addition funnel and magnetic stirrer, and placed under gentle nitrogen flow.
- the flask was charged with 1,1,3,3-tetramethyldisiloxane (TMDS, 364 mL, 2.06 mol).
- the addition funnel was charged with allyl alcohol (20.0 g, 0.34 mol). Approximately 2 mL of allyl alcohol was added to the reaction flask.
- the heating bath temperature was raised to 50°C, at which point chlorotris(triphenylphosphine) rhodium (40 ppm or 18.7 mg) was added to the reaction flask.
- the internal reaction temperature was then raised to 70°C.
- the acrylate version of this monomer can be prepared by the same procedure.
- a four-neck 1 L round-bottom polymerization flask was equipped with a thermometer connected to a temperature control device, a condenser, an overhead mechanical stirrer, two addition funnels, and nitrogen inlet/outlet. The set-up was purged with nitrogen gas for 15 min.
- a mixture of the following monomers was prepared: 2-ethylhexyacrylate (2-EHA, 99.8 g), methyl acrylate (MA, 96.2 g), glycidyl methacrylate (GMA, 3.0 g), l-acrylomethyl-3,4-cyclohexene epoxide (Ml 00, 1.0 g).
- 2-EHA 2-ethylhexyacrylate
- MA methyl acrylate
- GMA glycidyl methacrylate
- MME l-acrylomethyl-3,4-cyclohexene epoxide
- the initiator solution in the funnel was added continuously over 3 hr at a constant rate. Upon complete addition of initiator solution, the mixture was stirred for an additional 2 hr at reflux. A short half-life initiator (0.75 g) and ethyl acetate (25 mL) were charged into the initiator funnel and then added into the polymerization flask over 1 hr to reduce residual monomers. The polymerization solution was cooled to 60°C and cationic photoinitiator Cyracure UVI-6976 (1.0 g, 50% in propylene carbonate) was added and mixed thoroughly for 15 minutes.
- cationic photoinitiator Cyracure UVI-6976 1.0 g, 50% in propylene carbonate
- acrylic polymer (I) was obtained with M w of approximately 97,000 determined by GPC.
- the viscosity (Brookfield) of the polymer was about 40,000 mPa.s at 135°C.
- the properties of the adhesive film were as follows: shear resistance (2kg weight, 25mmx25mm area) >168 hr at 21°C on stainless steel panel, peel strength 19 N/25mm on stainless steel panel, loop tack 23 N/25mm on stainless steel panel, SAFT 171 °C on PET film and 160°C on an aluminum foil backing.
- Polymers XII and XIII were prepared in the same manner as Example 4. Besides the cationic photoninitators, Cyacure UVI-6976, Polymers XII and XIII were synthesized using a mono- substituted oxirane monomer, and their compositions are shown in Table 3.
- peel adhesion values indicate that the cationic formulation can be cured at a variety of dose levels and coat weights typically used in the tapes and labels industry.
- SAFT experiments were conducted from 40 to 200°C at 1 kg load, bond area 25 by 25mm, on mirrored stainless steel, and the failure temperatures are shown in Table 5. Hot shear resistance results are also shown in Table 5.
- a first set of adhesive films having compositions according to the examples listed in Table 6 were coated at 25°C, 50% RH, on release liner, dried, UV cured and then laminated to PET film backing in the usual manner in preparation for peel adhesion testing.
- a second set of adhesive films following coating and drying were placed in a chamber set to a controlled environment of 25°C, 50% RH, for 72 hours, with one adhesive surface exposed to the air. After conditioning for 72 hours, the films were then UV cured and laminated. Adhesive properties for the two sets of adhesive films are compared in Table 6.
- a formulation was made of Polymer VIII (80 wt%), Foral 85E ( 10 wt%) and Licocene ® PP 1302, Clariant (10 wt%) and the adhesive properties are summarized in Table 8.
- Figure 1 shows the viscosity over time for Polymer VIII and Polymer IX.
- the viscosity of each sample was measured by a Brookfield viscometer at 130°C.
- Polymer VIII, according to this Figure 1 had a stable viscosity around 45,000 mPa.s for about 300 minutes.
- the formulated adhesive, Examples 9, also exhibited stable viscosity, even up to 140°C, which indicates a long usable pot life.
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Abstract
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CN201180012600.4A CN102782072B (en) | 2010-03-09 | 2011-03-09 | Cationic UV-crosslinkable acrylic polymers for pressure sensitive adhesives |
EP11753966.8A EP2545132B1 (en) | 2010-03-09 | 2011-03-09 | Cationic uv-crosslinkable acrylic polymers for pressure sensitive adhesives |
KR1020127026328A KR101650693B1 (en) | 2010-03-09 | 2011-03-09 | Cationic uvcrosslinkable acrylic polymers for pressure sensitive adhesives |
JP2012557186A JP5711767B2 (en) | 2010-03-09 | 2011-03-09 | Cationic UV cross-linked acrylic polymer for pressure sensitive adhesives |
BR112012022560A BR112012022560B1 (en) | 2010-03-09 | 2011-03-09 | pressure sensitive adhesive curable by ultraviolet and manufactured article |
US13/606,066 US8796350B2 (en) | 2010-03-09 | 2012-09-07 | Cationic UV-crosslinkable acrylic polymers for pressure sensitive adhesives |
US14/309,420 US9469794B2 (en) | 2010-03-09 | 2014-06-19 | Cationic UV-crosslinkable acrylic polymers for pressure sensitive adhesives |
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Also Published As
Publication number | Publication date |
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JP2013522394A (en) | 2013-06-13 |
US20120329900A1 (en) | 2012-12-27 |
CN102782072B (en) | 2015-06-03 |
EP2545132A4 (en) | 2013-11-06 |
US8796350B2 (en) | 2014-08-05 |
CN102782072A (en) | 2012-11-14 |
WO2011112643A3 (en) | 2012-03-01 |
JP5711767B2 (en) | 2015-05-07 |
EP2985330A1 (en) | 2016-02-17 |
EP2985330B1 (en) | 2017-05-03 |
CN104893626B (en) | 2017-08-08 |
US9469794B2 (en) | 2016-10-18 |
KR20130053397A (en) | 2013-05-23 |
US20140303274A1 (en) | 2014-10-09 |
EP2545132A2 (en) | 2013-01-16 |
KR101650693B1 (en) | 2016-08-25 |
EP2545132B1 (en) | 2015-11-04 |
BR112012022560A2 (en) | 2016-08-30 |
BR112012022560B1 (en) | 2020-01-28 |
CN104893626A (en) | 2015-09-09 |
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