WO2011043623A2 - 다층 광학 필름 및 이의 제조방법 - Google Patents
다층 광학 필름 및 이의 제조방법 Download PDFInfo
- Publication number
- WO2011043623A2 WO2011043623A2 PCT/KR2010/006902 KR2010006902W WO2011043623A2 WO 2011043623 A2 WO2011043623 A2 WO 2011043623A2 KR 2010006902 W KR2010006902 W KR 2010006902W WO 2011043623 A2 WO2011043623 A2 WO 2011043623A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- optical film
- resin
- resin layer
- diol
- multilayer optical
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/02—Physical, chemical or physicochemical properties
- B32B7/023—Optical properties
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/08—Mirrors
- G02B5/0816—Multilayer mirrors, i.e. having two or more reflecting layers
- G02B5/0825—Multilayer mirrors, i.e. having two or more reflecting layers the reflecting layers comprising dielectric materials only
- G02B5/0841—Multilayer mirrors, i.e. having two or more reflecting layers the reflecting layers comprising dielectric materials only comprising organic materials, e.g. polymers
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/20—Filters
- G02B5/28—Interference filters
- G02B5/285—Interference filters comprising deposited thin solid films
- G02B5/287—Interference filters comprising deposited thin solid films comprising at least one layer of organic material
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/30—Polarising elements
- G02B5/3025—Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state
- G02B5/3033—Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state in the form of a thin sheet or foil, e.g. Polaroid
- G02B5/3041—Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state in the form of a thin sheet or foil, e.g. Polaroid comprising multiple thin layers, e.g. multilayer stacks
- G02B5/305—Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state in the form of a thin sheet or foil, e.g. Polaroid comprising multiple thin layers, e.g. multilayer stacks including organic materials, e.g. polymeric layers
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/30—Polarising elements
- G02B5/3083—Birefringent or phase retarding elements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/24—All layers being polymeric
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/42—Alternating layers, e.g. ABAB(C), AABBAABB(C)
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/306—Resistant to heat
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
- B32B2307/42—Polarizing, birefringent, filtering
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/514—Oriented
- B32B2307/516—Oriented mono-axially
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/514—Oriented
- B32B2307/518—Oriented bi-axially
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/702—Amorphous
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/704—Crystalline
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2457/00—Electrical equipment
- B32B2457/20—Displays, e.g. liquid crystal displays, plasma displays
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
- Y10T428/2495—Thickness [relative or absolute]
- Y10T428/24967—Absolute thicknesses specified
- Y10T428/24975—No layer or component greater than 5 mils thick
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31909—Next to second addition polymer from unsaturated monomers
- Y10T428/31913—Monoolefin polymer
- Y10T428/31917—Next to polyene polymer
Definitions
- the present invention relates to a multilayer optical film used for a color filter, a packaging material, and the like.
- Background Art A conventional multilayer film uses a method of simultaneously extruding and stretching two or more kinds of polymers using a composite feedbrick, as described in US Patent No. 5,122,905 to Whirler et al. have.
- such a multilayer technology has been used in various fields such as a polarizing reflective film, a girdle film, a color shift film, and a color filter to improve the brightness of a display.
- an object of the present invention is to provide excellent heat resistance and fairness while maintaining transparency.
- the present invention provides a multilayer optical film and a method of manufacturing the same, which have a high optical efficiency.
- the present invention is a first resin layer containing polyethylene naphthalate (PEN); And it provides a multilayer optical film having a structure in which a series of two resin layer comprising a heterocyclic polyalcohol copolymerized polyethylene terephthalate (PET) is laminated alternately.
- PEN polyethylene naphthalate
- PET heterocyclic polyalcohol copolymerized polyethylene terephthalate
- the present invention is ( a ) melt extrusion of the first resin containing polyethylene naphthalate (PEN) and the crater 2 resin containing polyethylene terephthalate (PET) co-condensed with a heterocyclic polyalcohol Alternately laminating; And (b) stretching the laminated sheet in at least one of longitudinal and transverse directions and then heat setting the laminated sheet.
- PEN polyethylene naphthalate
- PET polyethylene terephthalate
- FIG. 1 is a schematic view showing a laminated structure of a multilayer optical film of the present invention.
- 3 is a graph showing a change in refractive index for each resin content.
- FIG. 4 is a graph showing the change in viscosity of each resin content.
- 5 is a spectral result of the multilayer optical film prepared in Example 1.
- FIG. 6 is a spectral result of the multilayer optical film prepared in Comparative Example 1.
- FIG. 7 is a spectral result of the multilayer optical film prepared in Comparative Example 2.
- the multilayer optical film according to the present invention has a structure in which two resin layers having different refractive indices are alternately stacked in order to reflect specific wavelengths (see FIG. 1).
- the two resin layers must be made of different materials that can maintain each layer without mixing in order to maintain their unique refraction.
- the refractive index difference between the first resin layer and the second resin layer is preferably at least 0.2 at 632.8 nm, and more preferably, the refractive index difference is 0.25 to
- the multilayer optical film of the present invention is preferably designed such that the first resin layer is provided at both outermost layers, and the sum of the thicknesses of both outermost layers is preferably 10% to 40% of the total thickness of the multilayer optical film.
- heterocyclic polyalcohol refers to a polyhydric alcohol having a heterocycle including one or more heteroatoms such as 0, N, S, and P, wherein the heteroatom is oxygen, nitrogen or It is preferably sulfur.
- the heterocycle is preferably a 5 to 14 membered ring because the heterocyclic polyalcohol is more stable and easier to produce when in the above range.
- the number of OH groups in the heterocyclic polyalcohol is preferably two or three, and the more OH groups, the higher the heat resistance, but crosslinking may cause problems in the processing process.
- Preferred heterocyclic polyalcohols include di having a single hetero ring (formulas 3, 5, 6, 7, 8); diols having a spiro structure and two heterocycles (Formula 2); And diols having two or more rings connected to each other including heterocycles (Formulas 1, 4, 9, 10 and 11), and triols having one or more heterocycles and three OH groups (Formulas 12 and 13).
- heterocyclic polyhydric alcohol examples include isosorbide of formula (1), spiroglycol of formula (2), tetrahydrofuran diol of formula (3), and coraylactone di of formula (4).
- (Corey lactone diol) pyrimidine-2,4-diol of formula (5), 1,2-dithiane-3,6 ⁇ diol (l, 2-dithiane-) of formula (6) 3,6-diol), p-dithiane-2,5-diol of formula 7, 2-methylpyridine-3,5-diol of formula 8 (2-methylpyridine- 3,5-diol), puro [3,2-pypyrimidine-2,4-diol of formula (9), 7H-pyrrolo [2, 3-d] pyrimidine — 2,4 ⁇ di (7H-pyrrolo [2,3-dbyrimidine-2,4: -diol), 1,2,3,9—tetrahydropyrrolo [2, 1— b] quinazol
- the light irradiated on the laminated film forms reflected wavelengths of 1 / 2 ⁇ and 1 / 3 ⁇ by optical properties. These reflected wavelengths are UV region (200 ⁇ 4Q0nm), visible region (400 ⁇ 700nm), infrared
- the area (700 nm ⁇ ) can be adjusted by the stack thickness or the refractive index difference, and the reflectance of the secondary reflected wavelength can be changed by the stacking ratio value.
- the lamination ratio represented by the following formula (1) is preferably laminated in a range of 0.01 to 0.99, more preferably 0.50 to 0.54.
- dl and d2 are average thicknesses of the first and second resin layers, respectively.
- the lamination ratio represents the ratio of the first resin layer between the two layers.
- the lamination ratio is 0.50 to 0.54 because the lamination thickness of the first resin layer and the second resin layer is similar, the reflectance of the secondary reflection wavelength is increased.
- the intensity of the secondary reflected wavelengths is reduced to around 10%, but beyond this range, the reflection of the secondary reflected wavelengths may increase. Therefore, in order to further increase the desired effect of the present invention, the lamination ratio is laminated so that the range of 0.01 to 0.99, so that as close as possible to 0.50 to 0.54 value It is desirable to tune the process. However, even if the second reflected wavelength is minimized, the problem with the nth reflected wavelength remains, but it is impossible to match all the nth reflected wavelengths at the same time.
- the average thickness of the individual layers of the multilayer optical film according to the present invention is preferably from 30nm to 300nm, it is possible to further increase the optical efficiency in the above range.
- the number of laminated layers of the multilayer optical film of the present invention is not particularly limited, but preferably 50 to 1000 layers.
- the 1st resin layer has PEN which is a crystalline polyester as a main component, and heat resistance can be improved by using PEN which copolymerized a small amount of heterocyclic polyhydric alcohol as needed.
- PEN copolymerized with aimol% to 20.0 mol% of heterocyclic polyalcohol may be used, and the birefringence is hardly reduced when the heterocyclic polyhydric alcohol is within the above range. It can increase.
- the first resin layer preferably has a refractive index of 1.80 to 1.88 at 632.8 nm, and preferably has a birefringence of 0.15 to 3.0. 2nd resin layer
- the second resin layer is mainly composed of amorphous PET copolymerized with heterocyclic polyhydric alcohol.
- PET contained in the second resin layer is preferably a copolymer of heterocyclic polyhydric alcohols 10mol% to 60mol%.
- the copolymerization ratio of the heterocyclic polyhydric alcohol is within the above range, the difference between the refraction with the first resin layer (PEN) can be maximized, so that not only the optical effect is better, but also the heat resistance is high, and the flow during lamination is almost It does not occur and can be excellent in appearance.
- the second resin layer has a refractive index of 1.55 to 1.65 at 632.8 nm. It is preferable that the birefringence is 0.1 or less.
- the second resin layer preferably has a haze of 1.0 or less.
- the first resin mainly contains PEN, a crystalline polyester, and may be one prepared by polycondensation of naphthalate dicarboxylate and ethylene glycol.
- the difference in viscosity between the first resin and the second resin is not large, for example, the viscosity of the first resin is second. It is good not to exceed twice the viscosity of resin.
- the intrinsic viscosity of the first resin and the second resin is preferably 0.6dl / g to 0.8dl / g.
- first resin and the second resin known additives such as a polycondensation catalyst, a dispersant, an electrostatic agent, an antistatic agent, a sunscreen, an antiblocking agent, and other inorganic lubricants do not impair the effects of the present invention. It may be added.
- the system 1 resin has a refractive index of 632.8 nm of 1.80 to 1.88, and a birefringence of 0.15 to 3.0.
- total 2 resin has a refractive index of 632.8 nm of 1.80 to 1.88, and a birefringence of 0.15 to 3.0.
- the refractive index at 632.8 nm is preferably 1.55 to 1.65, and the birefringence is preferably 0.1 or less.
- the second resin is an isotropic polymer resin that is amorphous and maintains a low refractive index after extrusion and stretching.
- the main component of the second resin is preferably a copolymer of a heterocyclic polyhydric alcohol at 10 mol% to 60 mol%.
- the proportion of the heterocyclic polyhydric alcohol is within the above range, the mixture has a viscosity and Tg similar to that of the first resin layer, so that it may have excellent fairness, and the birefringence of the first resin layer may be maximum.
- the stretching process is possible in the stretching temperature range.
- the first resin and the second resin is melt-extruded at the same time through the extruder.
- the melt extrusion temperature is preferably at least 280 ° C, more preferably 280 ° C to 30 CTC.
- the first resin and the second resin to be melt-extruded are laminated through a multilayer feed block. It is preferable that the temperature of the feedable force does not deviate significantly from the melt extrusion temperature, and it is preferable to carry out at 280 ° C or higher.
- the number of laminations is adjusted according to the position of the wavelength, the reflectance, or the thickness of the film, and can be laminated at least 50 or more and 1000 or more. As the number of stacks increases, the reflectance for a particular wavelength increases, and the range of reflection wavelengths can be widened if the layer enjoys a gradient. It is also possible to change the position of the wavelength in accordance with the thickness of each layer, and the thickness of the outermost layer can be adjusted as necessary. In particular, maintaining the flow rate ratio well through the extrusion ratio helps to produce a film having an appearance that does not flow. Drawing process
- the laminate formed through the multilayer feed block is stretched in at least one of the longitudinal direction and the transverse direction after casting, thereby increasing the difference in refraction. If the uniaxial stretching in the transverse or longitudinal direction is performed, the manufactured optical filter may have a characteristic of expressing only part of the birefringence to separate and transmit / reflect the light.
- the air knife, etc. When casting, it is preferable to use the air knife, etc., to quickly invert the first resin layer, which helps to maintain the unique refraction of each of the first resin layer and the second resin layer.
- PEN's glass transition temperature (Tg) + 30 ° C or less, preferably Tg + 10 ° C or less It is good to carry out.
- the stretching process of the multilayer film of the present invention can be carried out at a stretching temperature of 12C C to 13C C.
- the multilayer optical film of the present invention prepared as described above can be used in various applications, such as a mirror film, a color filter, a packaging material, an optical window.
- a color filter a desired color is reflected semi-permanently by reflecting a desired light and can be used for interiors.
- PET polyethylene terephthalate
- PEN polyethylene naphthalate
- EG ethylene glycol
- NDC dimethyl-2,6-naphthalene dicarboxylate
- CHDM 1,4-cyclonucleic acid dimethane
- Preparation Example Preparation of Second Resin
- the second resin of various contents was prepared as follows.
- Preparation Example 1 Copolymerized PET (Iso carbide Copolymerization mol%: 20, 30, 45, 60) With respect to 1 mol of DMT which is a dicarboxylic acid, a mixture of EG, which is a polyhydric alcohol, and isosorbide (isosorbate content: 20 , 30, 45, 60 mol%)) was added at a rate of 2 to 4 moles, and the catalyst was added thereto, followed by expansion and condensation reaction while raising to 160-220 ° C. at normal pressure. The reaction was completed after 4-6 hours while removing methanol generated during reaction.
- Comparative Production Example 2 Copolymerization PEN (NDC Co-Condensation Mole%: 20, 30, 45, 60) A polymer was obtained by the same procedure as in Preparation Example 1, except that a mixture of DMT and NDC (NDC content: 20, 30, 45, 60 mol%) was used as the dicarboxylic acid. Comparative Production Example 3: Copolymerized PET (CHDM Copolymer mol%: 20, 30, 45, 60)
- PETXPCTG, SkyGreen TM, SK Chemical Co., Ltd. in which 1,4-cyclonucleodimethanol (CHDM) was copolymerized at 20, 30, 45, and 60 mol%, respectively, was used.
- Comparative Production Example 4 Co-Condensed PET (mol of PDO Copolymer: 20, 30, 45, 60) Except for using a mixture of EG and PDO (PDO content: 20, 30, 45, 60 mol%) as a polyhydric alcohol was carried out in the same procedure as in Production Example 1 to obtain a polymer.
- Test Examples 1 to 3 Evaluation of Characteristics by Contents of Second Resin In the following, evaluation was performed on various amounts of copolymerized resins.
- Test Example 1 Glass Transition Temperature Measurement The glass transition for each resin was measured using a differential scanning calorimeter (DSC-Q100, TA Instrument) while heating at a rate of l C C / min. Applied. The results are shown in Table 1 below and in FIG. 2. Table 1
- Test Example 3 Viscosity Evaluation For each resin, the ultimate viscosity value of the polymer was obtained by dissolving in orthochlorophenol (OCP) solution and measuring the drop time in a right-valid tube at a temperature of 3C C. The results are shown in the following table. 3 and the accompanying FIG. 4. TABLE 3
- the PET resin copolymerized with isosorbide or spiroglycol has a large change in viscosity with increasing content, which is advantageous for coextrusion with a high viscosity polymer, but is copolymerized with CHDM or PDO. It can be seen that since the change in viscosity is not large, it is blunted by co-extrusion with PEN, which is a high viscosity polymer.
- Examples and Comparative Examples: Preparation of Multilayer Reflective Film Hereinafter, various examples of the multilayer reflective film according to the present invention and the prior art are described.
- Example 1 PENXSKC) was used as the first resin
- isosorbide was used as the second resin.
- PET (SK Chemicals) copolymerized at 10 mol% was used.
- the first resin and the second resin were melt extruded at 28 CTC using two extruders, and then alternately laminated in the multilayer feed block, and the inner layer was increased by 1% in thickness. It has a gradient form to be added, the lamination ratio represented by the formula (1) is 0.01 to 0.99, it was configured so that the first resin layer is in the outermost layer.
- the laminated sheet was brought into close contact with the corner angle angled by 2CTC to obtain an unstretched laminated sheet.
- the unstretched laminated sheet was stretched four times in the longitudinal and transverse directions at about 120 ° C. using a biaxial stretching machine (Toyoseki Co., Japan), and then heat-set in 23 CTC and biaxially stretched to a total thickness of 18.7 jt ⁇ .
- Example 2 A biaxially stretched 131-layer optical film having a total thickness of 18.7 was subjected to the same procedure as in Example 1, except that PET (Mitsubish Gas Chemical Co., Ltd.) copolymerized with 40 mol 93 ⁇ 4 of spiroglycol was used as the second resin. was prepared.
- Comparative Example 1 A biaxially stretched 131-layer optical film having a total thickness of 18.7 was prepared in the same manner as in Example 1, except that unpolymerized pure PET (SKC) was used as the second resin. Comparative Example 2 The same procedure as in Example 1 was carried out, except that PEN (coPEN5545, SKC Co., Ltd.), in which T / NDC was copolymerized at a molar ratio of 55:45, was used as a second resin. A stretched 131 layer optical film was prepared.
- Comparative Example 3 The same procedure as in Example 1 was carried out, except that 1,4—cyclohexanedimethane (CHDM) was copolymerized with 6011101 ⁇ 3 ⁇ 4 as a second resin, and SK Chemicals Co., Ltd. was used. A biaxially stretched 131 layer optical film of was prepared. Comparative Example 4 A biaxially stretched 131 layer having a total thickness of 18.7 was subjected to the same procedure as in Example 1, except that PET (SKC Co., Ltd.) co-condensed with 40 mol% propanedi (PDO) was used as the second resin. An optical film was prepared.
- CHDM 1,4—cyclohexanedimethane
- PDO propanedi
- Comparative Example 5 Example 1, except that polycarbonate (PC) and polyester (PCTG) were alloyed as a second resin (Xilex 720Q, SABIC Innovation Plastics Co., Ltd.). A biaxially stretched 131 layer optical film having a total thickness of 18.7 was prepared by following the same procedure as described above.
- Test Example 4 Spectral Analysis of Multi-layer Optical Films The multi-layer optical films obtained in Example 1 and Comparative Examples 1 and 2 were observed by using a spectrum analyzer (Ultrascan TM Pro, Hunter Lab) to observe reflected wavelengths. Attached to FIGS. 5-7.
- Test Example 5 Refractive Index Measurement
- the single-layer film of the first resin layer or the second resin layer obtained above was measured using a Abbe refractometer to measure the refraction in the longitudinal direction and the transverse direction at 632.8 nm. The average value of was calculated and the result was put together in following Table 4.
- Table 4 the multilayer optical film of Examples 1 and 2 according to the present invention through the stretching, the difference in refractive index between the first resin layer and the second resin layer is further increased, and as a result the inter-layer refractive index by the difference It can be seen that the effect of constructive interference is also increased, so that the optical effect, that is, the reflectance of light, can be increased.
- Test Example 6 Evaluation of long-term heat resistance (without fine wrinkles) The second resin layer monolayer film obtained above was exposed to 500 hours at 85 ° C., and then magnified 200 times through a microscope to confirm the occurrence of fine wrinkles. , The results are summarized in Table 4 below.
- the multilayer optical films of Examples 1 and 2 according to the present invention were excellently evaluated in heat resistance, stretchability, optical properties, and the like, compared to the multilayer optical films of Comparative Examples 1 to 4 according to the prior art.
- the multilayer optical film of Comparative Example 5 it is excellent in heat resistance, but lacks in elongation and high haze, so that it is inferior in efficiency for optical use.
- the present invention has been described with reference to the above embodiments, which are only examples, and the present invention includes various modifications and other equivalent embodiments which are obvious to those skilled in the art. It should be understood that they can be performed within the scope of the appended claims.
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Laminated Bodies (AREA)
- Optical Filters (AREA)
- Polyesters Or Polycarbonates (AREA)
Abstract
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2012533087A JP5776088B2 (ja) | 2009-10-09 | 2010-10-08 | 多層光学フィルム及びその製造方法 |
EP10822268.8A EP2487036B1 (en) | 2009-10-09 | 2010-10-08 | Multilayered optical film, and preparation method thereof |
US13/500,820 US20120207993A1 (en) | 2009-10-09 | 2010-10-08 | Multilayered optical film, and preparation method thereof |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR20090096273 | 2009-10-09 | ||
KR10-2009-0096273 | 2009-10-09 | ||
KR1020100093448A KR101775077B1 (ko) | 2009-10-09 | 2010-09-27 | 다층 광학 필름 및 이의 제조방법 |
KR10-2010-0093448 | 2010-09-27 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2011043623A2 true WO2011043623A2 (ko) | 2011-04-14 |
WO2011043623A3 WO2011043623A3 (ko) | 2011-11-03 |
Family
ID=44046017
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/KR2010/006902 WO2011043623A2 (ko) | 2009-10-09 | 2010-10-08 | 다층 광학 필름 및 이의 제조방법 |
Country Status (5)
Country | Link |
---|---|
US (1) | US20120207993A1 (ko) |
EP (1) | EP2487036B1 (ko) |
JP (1) | JP5776088B2 (ko) |
KR (1) | KR101775077B1 (ko) |
WO (1) | WO2011043623A2 (ko) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20140287211A1 (en) * | 2011-10-20 | 2014-09-25 | Teijin Dupont Films Japan Limited | Uniaxially stretched multi-layer laminate film |
US20150064428A1 (en) * | 2012-03-16 | 2015-03-05 | Toray Industries, Inc. | Multi-layer laminated film |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101417250B1 (ko) * | 2012-02-20 | 2014-07-08 | (주)엘지하우시스 | 고내열성 다층 광학필름 및 그의 제조방법 |
JP6210473B2 (ja) * | 2012-08-03 | 2017-10-11 | 国立大学法人山形大学 | 有機光学デバイス及びこれを用いた有機電子デバイス |
JP6139266B2 (ja) * | 2013-05-27 | 2017-05-31 | 帝人フィルムソリューション株式会社 | 二軸延伸積層ポリエステルフィルム |
JPWO2015016111A1 (ja) * | 2013-08-02 | 2017-03-02 | 東レ株式会社 | ポリエステルシート、ポリエステルシートから得られる成形体およびカード |
KR102251210B1 (ko) * | 2014-04-11 | 2021-05-11 | 에스케이케미칼 주식회사 | 다층 폴리에스테르 시트 및 그 성형품 |
WO2018221944A1 (ko) | 2017-05-31 | 2018-12-06 | 에스케이케미칼 주식회사 | 폴리에스테르 수지, 이의 제조 방법 및 이로부터 형성된 수지 성형품 |
KR102568694B1 (ko) | 2017-06-22 | 2023-08-22 | 에스케이케미칼 주식회사 | 폴리에스테르 용기, 이의 제조 방법 |
KR102684863B1 (ko) | 2017-06-26 | 2024-07-15 | 에스케이케미칼 주식회사 | 폴리에스테르 필름 및 이의 제조 방법 |
JP7388271B2 (ja) * | 2020-03-30 | 2023-11-29 | 住友ベークライト株式会社 | 反射偏光板 |
KR102404447B1 (ko) * | 2022-01-06 | 2022-06-02 | 주식회사 크라텍 | 반사율의 향상으로 보다 선명한 상을 제공하며 개선된 내충격성을 갖는 필름형 안전거울 및 이의 제조방법 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5122905A (en) | 1989-06-20 | 1992-06-16 | The Dow Chemical Company | Relective polymeric body |
Family Cites Families (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5939189A (en) * | 1995-05-09 | 1999-08-17 | Flex Products, Inc. | Flexible plastic substrate with anti-reflection coating having low reflective color and method |
CA2222511A1 (en) * | 1995-06-26 | 1997-01-16 | Minnesota Mining And Manufacturing Company | Multilayer polymer film with additional coatings or layers |
US6045894A (en) * | 1998-01-13 | 2000-04-04 | 3M Innovative Properties Company | Clear to colored security film |
AU2314899A (en) * | 1998-01-13 | 1999-08-02 | Minnesota Mining And Manufacturing Company | Modified copolyesters and improved multilayer reflective films |
US6531230B1 (en) * | 1998-01-13 | 2003-03-11 | 3M Innovative Properties Company | Color shifting film |
US6063464A (en) * | 1998-04-23 | 2000-05-16 | Hna Holdings, Inc. | Isosorbide containing polyesters and methods for making same |
CN1192255C (zh) * | 1998-07-31 | 2005-03-09 | 美国3M公司 | 可后成形的多层光学薄膜及其成形方法 |
JP2002069165A (ja) * | 2000-06-13 | 2002-03-08 | Mitsubishi Gas Chem Co Inc | ポリエステル樹脂 |
US6673425B1 (en) * | 2000-10-27 | 2004-01-06 | 3M Innovative Properties Company | Method and materials for preventing warping in optical films |
WO2002061469A2 (en) * | 2001-01-15 | 2002-08-08 | 3M Innovative Properties Company | Multilayer infrared reflecting film with high and smooth transmission in visible wavelength region and laminate articles made therefrom |
KR101134334B1 (ko) * | 2004-03-09 | 2012-04-09 | 가부시키가이샤 구라레 | 광학 소자 |
US7345137B2 (en) * | 2004-10-18 | 2008-03-18 | 3M Innovative Properties Company | Modified copolyesters and optical films including modified copolyesters |
KR100670613B1 (ko) * | 2005-02-25 | 2007-01-17 | 에스케이씨 주식회사 | 광특성이 우수한 폴리에스터 필름 |
EP1938966B1 (en) * | 2005-08-18 | 2013-02-27 | Toray Industries, Inc. | Laminate film and molded article |
KR101310587B1 (ko) * | 2006-09-06 | 2013-09-23 | 도레이 카부시키가이샤 | 폴리에스테르 수지 조성물, 그의 제조 방법 및 적층 폴리에스테르 필름 |
US8530054B2 (en) * | 2006-09-27 | 2013-09-10 | 3M Innovative Properties Company | Solar control multilayer film |
JP5553468B2 (ja) * | 2006-10-05 | 2014-07-16 | 日東電工株式会社 | 偏光板および液晶表示装置 |
KR101492306B1 (ko) * | 2008-02-01 | 2015-02-11 | 도레이 카부시키가이샤 | 적층 필름 및 성형체, 반사체 |
-
2010
- 2010-09-27 KR KR1020100093448A patent/KR101775077B1/ko active IP Right Grant
- 2010-10-08 WO PCT/KR2010/006902 patent/WO2011043623A2/ko active Application Filing
- 2010-10-08 JP JP2012533087A patent/JP5776088B2/ja active Active
- 2010-10-08 US US13/500,820 patent/US20120207993A1/en not_active Abandoned
- 2010-10-08 EP EP10822268.8A patent/EP2487036B1/en active Active
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5122905A (en) | 1989-06-20 | 1992-06-16 | The Dow Chemical Company | Relective polymeric body |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20140287211A1 (en) * | 2011-10-20 | 2014-09-25 | Teijin Dupont Films Japan Limited | Uniaxially stretched multi-layer laminate film |
US9366792B2 (en) * | 2011-10-20 | 2016-06-14 | Teijin Dupont Films Japan Limited | Uniaxially stretched multi-layer laminate film |
US20150064428A1 (en) * | 2012-03-16 | 2015-03-05 | Toray Industries, Inc. | Multi-layer laminated film |
US9527266B2 (en) * | 2012-03-16 | 2016-12-27 | Toray Industries, Inc. | Multi-layer laminated film |
Also Published As
Publication number | Publication date |
---|---|
EP2487036A2 (en) | 2012-08-15 |
KR101775077B1 (ko) | 2017-09-06 |
JP5776088B2 (ja) | 2015-09-09 |
US20120207993A1 (en) | 2012-08-16 |
JP2013506883A (ja) | 2013-02-28 |
EP2487036A4 (en) | 2014-01-29 |
WO2011043623A3 (ko) | 2011-11-03 |
KR20110039185A (ko) | 2011-04-15 |
EP2487036B1 (en) | 2017-08-23 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
WO2011043623A2 (ko) | 다층 광학 필름 및 이의 제조방법 | |
US20200217989A1 (en) | Multilayer optical film, method of making the same, and transaction card having the same | |
JP5508390B2 (ja) | 光学物品用ポリエステル厚膜及び光学物品 | |
KR20140041611A (ko) | 반사 편광 필름, 그것으로 이루어지는 액정 표시 장치용 광학 부재 및 액정 표시 장치 | |
WO2012003123A1 (en) | Multilayer optical film | |
JP5950368B2 (ja) | 高耐熱性多層光学フィルム及びその製造方法 | |
JP7400723B2 (ja) | 多層積層フィルム | |
JP7400724B2 (ja) | 多層積層フィルム | |
CN112805601B (zh) | 多层层叠膜 | |
CN111741845B (zh) | 多层层叠膜 | |
WO2015093764A1 (ko) | 다층 연신 필름 | |
CN112771417B (zh) | 光源单元、显示装置和膜 | |
KR20200027968A (ko) | 다층 적층 필름 | |
CN117897638A (zh) | 多层叠层膜及投影图像显示构件 | |
KR20200064058A (ko) | 적층 필름 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 10822268 Country of ref document: EP Kind code of ref document: A1 |
|
WWE | Wipo information: entry into national phase |
Ref document number: 13500820 Country of ref document: US Ref document number: 2012533087 Country of ref document: JP |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
REEP | Request for entry into the european phase |
Ref document number: 2010822268 Country of ref document: EP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2010822268 Country of ref document: EP |