WO2010003853A1 - Method and apparatus for packaging a liquid food product - Google Patents
Method and apparatus for packaging a liquid food product Download PDFInfo
- Publication number
- WO2010003853A1 WO2010003853A1 PCT/EP2009/058236 EP2009058236W WO2010003853A1 WO 2010003853 A1 WO2010003853 A1 WO 2010003853A1 EP 2009058236 W EP2009058236 W EP 2009058236W WO 2010003853 A1 WO2010003853 A1 WO 2010003853A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- volume
- beverage component
- beverage
- stretch rod
- preform
- Prior art date
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/42—Component parts, details or accessories; Auxiliary operations
- B29C49/46—Component parts, details or accessories; Auxiliary operations characterised by using particular environment or blow fluids other than air
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/08—Biaxial stretching during blow-moulding
- B29C49/10—Biaxial stretching during blow-moulding using mechanical means for prestretching
- B29C49/12—Stretching rods
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65B—MACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
- B65B3/00—Packaging plastic material, semiliquids, liquids or mixed solids and liquids, in individual containers or receptacles, e.g. bags, sacks, boxes, cartons, cans, or jars
- B65B3/02—Machines characterised by the incorporation of means for making the containers or receptacles
- B65B3/022—Making containers by moulding of a thermoplastic material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65B—MACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
- B65B3/00—Packaging plastic material, semiliquids, liquids or mixed solids and liquids, in individual containers or receptacles, e.g. bags, sacks, boxes, cartons, cans, or jars
- B65B3/04—Methods of, or means for, filling the material into the containers or receptacles
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65B—MACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
- B65B3/00—Packaging plastic material, semiliquids, liquids or mixed solids and liquids, in individual containers or receptacles, e.g. bags, sacks, boxes, cartons, cans, or jars
- B65B3/04—Methods of, or means for, filling the material into the containers or receptacles
- B65B3/10—Methods of, or means for, filling the material into the containers or receptacles by application of pressure to material
- B65B3/12—Methods of, or means for, filling the material into the containers or receptacles by application of pressure to material mechanically, e.g. by pistons or pumps
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/42—Component parts, details or accessories; Auxiliary operations
- B29C49/46—Component parts, details or accessories; Auxiliary operations characterised by using particular environment or blow fluids other than air
- B29C2049/4602—Blowing fluids
- B29C2049/465—Blowing fluids being incompressible
- B29C2049/4655—Blowing fluids being incompressible water
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/42—Component parts, details or accessories; Auxiliary operations
- B29C49/46—Component parts, details or accessories; Auxiliary operations characterised by using particular environment or blow fluids other than air
- B29C2049/4602—Blowing fluids
- B29C2049/465—Blowing fluids being incompressible
- B29C2049/4664—Blowing fluids being incompressible staying in the final article
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/42—Component parts, details or accessories; Auxiliary operations
- B29C49/78—Measuring, controlling or regulating
- B29C49/786—Temperature
- B29C2049/7861—Temperature of the preform
- B29C2049/7862—Temperature of the preform characterised by temperature values or ranges
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/42—Component parts, details or accessories; Auxiliary operations
- B29C49/78—Measuring, controlling or regulating
- B29C49/786—Temperature
- B29C2049/7864—Temperature of the mould
- B29C2049/78645—Temperature of the mould characterised by temperature values or ranges
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/42—Component parts, details or accessories; Auxiliary operations
- B29C49/78—Measuring, controlling or regulating
- B29C49/786—Temperature
- B29C2049/7866—Temperature of the blowing medium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/42—Component parts, details or accessories; Auxiliary operations
- B29C49/78—Measuring, controlling or regulating
- B29C2049/7879—Stretching, e.g. stretch rod
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2949/00—Indexing scheme relating to blow-moulding
- B29C2949/07—Preforms or parisons characterised by their configuration
- B29C2949/0715—Preforms or parisons characterised by their configuration the preform having one end closed
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/02—Combined blow-moulding and manufacture of the preform or the parison
- B29C49/06—Injection blow-moulding
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/08—Biaxial stretching during blow-moulding
- B29C49/087—Means for providing controlled or limited stretch ratio
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/08—Biaxial stretching during blow-moulding
- B29C49/10—Biaxial stretching during blow-moulding using mechanical means for prestretching
- B29C49/122—Drive means therefor
- B29C49/1222—Pneumatic
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/08—Biaxial stretching during blow-moulding
- B29C49/10—Biaxial stretching during blow-moulding using mechanical means for prestretching
- B29C49/122—Drive means therefor
- B29C49/1229—Drive means therefor being a cam mechanism
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/42—Component parts, details or accessories; Auxiliary operations
- B29C49/78—Measuring, controlling or regulating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
- B29K2023/04—Polymers of ethylene
- B29K2023/06—PE, i.e. polyethylene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
- B29K2023/10—Polymers of propylene
- B29K2023/12—PP, i.e. polypropylene
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2025/00—Use of polymers of vinyl-aromatic compounds or derivatives thereof as moulding material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2027/00—Use of polyvinylhalogenides or derivatives thereof as moulding material
- B29K2027/06—PVC, i.e. polyvinylchloride
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2067/00—Use of polyesters or derivatives thereof, as moulding material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2067/00—Use of polyesters or derivatives thereof, as moulding material
- B29K2067/003—PET, i.e. poylethylene terephthalate
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2067/00—Use of polyesters or derivatives thereof, as moulding material
- B29K2067/04—Polyesters derived from hydroxycarboxylic acids
- B29K2067/046—PLA, i.e. polylactic acid or polylactide
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2069/00—Use of PC, i.e. polycarbonates or derivatives thereof, as moulding material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/25—Solid
- B29K2105/253—Preform
- B29K2105/258—Tubular
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/712—Containers; Packaging elements or accessories, Packages
- B29L2031/7158—Bottles
Definitions
- the present invention relates to the field of manufacturing containers made of a polymer material, especially a polyester. More particularly, it relates to the field of manufacturing polyester bottles, preferably polyethylene terephthalate (PET) bottles containing a liquid, preferably water and especially mineral water.
- PET polyethylene terephthalate
- PET bottles usually found on the market have been manufactured by the blow moulding or stretch-blow moulding of PET preforms using compressed air.
- a preform usually takes the form of a cylindrical tube closed at one of its ends and open at its opposite end.
- the open head of the preform corresponds to the neck of the container.
- the preforms are slipped onto the cylindrical mounts of a continuous conveyor chain, which thus transports the preforms through an oven, essentially formed by a straight section bordered on each side by radiative heating means, so as to temperature-condition the plastic for the subsequent stretch-blow moulding step.
- the hot preform is then taken off and transported into a mould of a blow moulding machine.
- the transport movement performed for example by a transfer arm, is coordinated with that of the blow moulding machine, which is generally produced in the form of a rotary carousel that rotates continuously about its vertical axis and carries, on its periphery, a series of identical moulds.
- the blow moulding machine which is generally produced in the form of a rotary carousel that rotates continuously about its vertical axis and carries, on its periphery, a series of identical moulds.
- the preform is heated beforehand so as to be in the mould at a temperature above the glass transition temperature (about 100 0 C) so as to enable it to be formed by stretch-blow moulding.
- the temperature of the preform at the end of the heating step is slightly above that required inside the mould of the blow moulding machine, so as to take into account the cooling that takes place over the distance that exists between the heating site and the blow- moulding site. Thanks to the simultaneous presence of several moulds, such a blow moulding machine can produce containers at very high rates, of around 1000 to 2000 bottles per hour per mould, i.e. around several tens of thousands of units per hour.
- the stretch-blow moulding takes place by stretching using a metal rod and by injecting air at pressures ranging from 3 to 40 bar (3.10 5 Pa to 4.10 6 Pa).
- the air is injected through a nozzle, the end of which is introduced through the opening in the head of the preform.
- the pressures then exerted on the injected beverage are high, since the industrial process requires high rates.
- the usual practice is for the volume of beverage introduced into the containers to be above the displayed volume for the container, in so far as it is possible to finalize the contents with a volume greater than the stipulated volume, whereas the reverse is not possible.
- the technical problem solved by the present invention is to devise an industrial process that guarantees the stipulated volume for the type of filling, in a simple and economically acceptable manner.
- the Applicant proposes a method of delivering a predetermined volume of a beverage component into a thermoplastic container formed from a heated preform (for example an approximately cylindrical preform) positioned in a mould, the method including a step of injecting at least some beverage component into a recess in the preform so as to promote expansion of the preform inside the mould, the mould defining the shape of the container, a volume of beverage component introduced during the injection step being at least equal to said predetermined volume, and, in addition, the method includes a step of sucking out a fraction of said volume of beverage component introduced until the volume of beverage component remaining in the container is approximately equal to said predetermined volume.
- a heated preform for example an approximately cylindrical preform
- the method thus defined makes it possible to guarantee the intended volume for the type of container defined by the mould within the context of an integrated industrial process.
- the suction step is preferably carried out by means of a suction pump and a volumetric sensor.
- the injection step is preferably carried out by means of a pressurizing actuator and a volumetric sensor.
- the injection step includes a substep of longitudinally stretching the preform by a stretch rod, said stretch rod being hollow, and the suction step comprises sucking out some of the beverage via said hollow stretch rod.
- the method includes a step of recirculating at least part of the beverage sucked out during the suction step.
- the recirculation may be performed in the injection circuit, thereby minimizing beverage losses.
- the suction step comprises suction by means of a vacuum pump.
- the injection step includes a substep of injecting at least some beverage via a hollow stretch rod that is designed to stretch a thermoplastic preform and is connected to a beverage inlet.
- the same stretch rod serves for injecting beverage and for sucking out a fraction of said volume of beverage.
- the hollow stretch rod has an adapted profile in order to minimize the turbulence in the beverage during the step of injecting at least some beverage via the hollowing stretch rod.
- Said profile may include an internal profile, an external profile or a combination of an internal profile and an external profile.
- the beverage is injected in amounts of about 500 ml in 0.2 s.
- the adapted profile minimizes the turbulence, thereby making it possible to obtain a more stable process, with wider operational windows.
- the injection is carried out by means of a bell-shaped filling head.
- thermoplastic container necks rupturing since they are subjected to high pressures during the injection step.
- the stretch rod is designed in such a way that its internal volume is optimized so that said fraction of the beverage volume is reduced.
- the fraction of the beverage volume is reduced to the internal volume of the neck.
- the injection step includes a step of injecting at least some beverage through the inside of the stretch rod and through an orifice around the stretch rod.
- the injection step comprises a step of injecting a first beverage component and a step of injecting a second beverage component.
- the injection of the first beverage component comprises injection through the inside of the stretch rod and the injection of the second beverage component comprises injection through an orifice around the stretch rod.
- the invention also relates to a device for delivering a predetermined volume of beverage into a thermoplastic container formed from an approximately cylindrical heated preform positioned in a mould, characterized in that the device comprises means for injecting at least some beverage into a recess in the preform so as to promote expansion of the preform inside the mould, the mould defining the shape of the container, a volume of beverage introduced during the injection step being at least equal to said predetermined volume and the device comprising, in addition, means for sucking out a fraction of said volume of beverage component introduced until the volume of beverage remaining in the container is approximately equal to said predetermined volume.
- this device may include means suitable for carrying out the respective intended steps of the method, taken separately or in combination.
- Figure 1 shows a general diagram of an installation suitable for operating with the invention.
- Figure 2 shows an important aspect of the invention.
- Figure 3 shows a bell-shaped nozzle end-piece used within the context of the invention.
- Figure 4 shows the monitoring of the formation of a mineral water bottle according to one example of the use of the invention.
- the embodiment given here by way of example relates to a process for manufacturing PET mineral water bottles from a heated preform.
- the preform has the shape of a cylindrical tube closed at its lower end.
- the open head of the preform corresponds to the throat or neck of the bottle, onto which a closure cap is screwed.
- a stretch rod 10 is inserted into a compressed- air actuator 15.
- the stretch rod 10 is generally controlled by an air actuator associated with a cam, which gives it a longitudinal movement (represented by an arrow). It is also possible to use a stretch motor.
- the compressed-air actuator 15 comprises a cylinder 17 controlling an injection head 18, through which the stretch rod 10 passes.
- the injection head 18 is connected to the neck 20 of a PET preform placed in a mould (not shown), which preform, after being expanded, takes on the shape of a mineral water bottle, this shape being determined by the wall of the mould.
- the actuator comprises three chambers, the upper two chambers 15a and 15b being filled with compressed air. Between these upper two chambers, a piston wall 19 slides in a direction parallel to the stretch rod (the displacement being represented by an arrow). The stretch rod 10 passes through the centre of this wall 19.
- the compressed-air actuator also includes a lateral inlet 30 for the beverage, here mineral water, connected to the third chamber 15c of the actuator, this being the bottom chamber.
- the beverage is fed in via a line 32.
- An external mineral water inlet feeds the liquid via the remote end of this line 32 into a first valve 34, which is connected to the opening of a single- chamber filling cylinder 40 comprising a piston 42 controlled by a filling motor (movement of which is represented by an arrow). This motor imparts a longitudinal movement on the piston in the single chamber of the filling cylinder 40.
- the bottom chamber 15c of the compressed-air actuator is penetrated by the cylinder 17 for controlling the filling head 18, the internal volume of which emerges through the lower outlet of the compressed-air actuator 15 into the filling head 18.
- the control cylinder has a lateral opening 25 allowing the beverage to circulate between the bottom chamber of the actuator and the inside of the control cylinder.
- the stretch rod 10 itself passes through the control cylinder 17 as far as the filling head 18 and the neck 20 of the bottle preform.
- a pressurizing actuator 100 increases the pressure of the beverage in the beverage feed line 110.
- a volumetric sensor 120 allows the volume injected through the line 110 to be monitored.
- the beverage is introduced into the nozzle 130.
- the stretch rod 140 is introduced along the axis of the nozzle 130.
- a suction pump 150 is attached to a line 170 connected via a volumetric sensor to the nozzle 130.
- the nozzle 130 is positioned facing the mould (not shown) in which the PET preform, to be expanded and filled with beverage, here mineral water, is positioned.
- a PET water bottle 180 is formed. Referring to Figure 3, a bell-shaped nozzle end-piece 500 according to a preferred embodiment is shown.
- the internal and external pressures on either side of the circumference of the neck of the preform i.e.
- a nozzle end-piece holds the external surfaces 510 of the neck of the preform in such a way that when a pressurized fluid is injected via the top of the nozzle into the recess of the preform, the pressure exerted on the internal walls 520 of the neck of the preform by the fluid is compensated for by the holding by the walls of the bell- shaped nozzle end-piece.
- the neck of the preform therefore does not deform, despite the high pressure.
- Figure 4 shows the variation over time of the position 101 of the stretch rod and the position 102 of the filling actuator controlling the inflow of the mineral water into the expanded preform.
- the horizontal axis represents the time
- the left-hand vertical axis represents the position of the stretch rod
- the right-hand vertical axis represents the volume of water introduced into the expanded preform, this being proportional to the position of the filling actuator.
- the stretch rod advances at an essentially constant rate, according to a preferred embodiment.
- the stretch rod advances at an increasing speed due to a positive acceleration.
- the stretch rod advances with a negative acceleration, the speed decreasing until it becomes zero at 250 ms.
- the changes in speed must be sufficiently gentle to ensure regular and reliable stretching of the thermoplastic. 250 ms after the start of the process (reference 103), the stretch rod has reached its final position P f , from which it no longer moves.
- the filling actuator has introduced a volume V 1 of mineral water into the expanded preform.
- the volume introduced from the start of the process (therefore between 0 ms and 250 ms) has progressively increased, with a progressive increase in the flow rate (filling actuator displacement acceleration).
- the total volume of water introduced is constant, the flow rate being invariant.
- the volume suddenly decreases by a small fraction (around 4%) over a period of 40 ms.
- the total volume introduced stabilizes around the value V 2 , which is finally reached after a few oscillations, the flow rate of liquid being introduced being zero.
- the filling actuator has reached a final position, from which it no longer moves. At this moment, it has introduced a volume V 2 of mineral water into the expanded preform.
- the volume V 2 is greater than V-i, but less than twice the volume V 1 .
- the temperature of the preform is brought beforehand to a value between 50 0 C and 130 0 C, or even between 75°C and 100 0 C. In the preferred embodiment, this value is 95°C, the plastic used being PET.
- the rod has a speed of between 0.5 and 3.0 m/s "1 , or even between 1.0 and 5 m/s "1 . In the preferred embodiment, this value is 1.6 m/s "1 .
- the temperature of the beverage is brought beforehand to a value between 1°C and 120°C, preferably between 10°C and 90°C. In the preferred embodiment, this value is 30 0 C.
- the longitudinal stretch ratio of the thermoplastic is between 2 and 5 or even between 2.5 and 4. In the preferred embodiment, this value is 3.5.
- the radial stretch ratio of the thermoplastic is between 2 and 7, or even between 3 and 4.5. In the preferred embodiment, this value is 4.
- the thermoplastic is chosen from the group consisting of polyethylene terephthalates, polypropylenes, polyethylenes, polycarbonates, polystyrenes, polylactic acids, polyvinyl chlorides and combinations thereof. In the preferred embodiment, it is PET.
- the temperature of the mould is at least 50 0 C below the melting point of the thermoplastic, which in the case of PET is 230°C. Preferably, this temperature is maintained below 100 0 C. In the preferred embodiment, the temperature of the mould is equal to the ambient temperature.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
- Basic Packing Technique (AREA)
- Filling Of Jars Or Cans And Processes For Cleaning And Sealing Jars (AREA)
Abstract
Description
Claims
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN200980126279.5A CN102089142B (en) | 2008-07-07 | 2009-07-01 | Method and apparatus for packaging a liquid food product |
BRPI0915468-0A BRPI0915468B1 (en) | 2008-07-07 | 2009-07-01 | METHOD AND DEVICE FOR DISTRIBUTION OF A PREDIMINED VOLUME OF A DRINKING COMPONENT INSIDE A THERMOPLASTIC CONTAINER |
US13/002,199 US9573314B2 (en) | 2008-07-07 | 2009-07-01 | Method and apparatus for packaging a liquid food product |
RU2011104089/05A RU2500534C2 (en) | 2008-07-07 | 2009-07-01 | Method and device for fluid food product packing |
EP09793919.3A EP2313247B1 (en) | 2008-07-07 | 2009-07-01 | Method and apparatus for packaging a liquid food product |
JP2011517091A JP5694154B2 (en) | 2008-07-07 | 2009-07-01 | Method and apparatus for packaging liquid food |
MX2011000207A MX346757B (en) | 2008-07-07 | 2009-07-01 | Method and apparatus for packaging a liquid food product. |
US15/399,346 US10369737B2 (en) | 2008-07-07 | 2017-01-05 | Method and apparatus for packaging a liquid food product |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP08159852A EP2143542A1 (en) | 2008-07-07 | 2008-07-07 | Method and apparatus for packaging a liquid food product |
EP08159852.6 | 2008-07-07 |
Related Child Applications (2)
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US13/002,199 A-371-Of-International US9573314B2 (en) | 2008-07-07 | 2009-07-01 | Method and apparatus for packaging a liquid food product |
US15/399,346 Division US10369737B2 (en) | 2008-07-07 | 2017-01-05 | Method and apparatus for packaging a liquid food product |
Publications (1)
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WO2010003853A1 true WO2010003853A1 (en) | 2010-01-14 |
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Application Number | Title | Priority Date | Filing Date |
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PCT/EP2009/058236 WO2010003853A1 (en) | 2008-07-07 | 2009-07-01 | Method and apparatus for packaging a liquid food product |
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US (2) | US9573314B2 (en) |
EP (2) | EP2143542A1 (en) |
JP (1) | JP5694154B2 (en) |
CN (1) | CN102089142B (en) |
BR (1) | BRPI0915468B1 (en) |
MX (1) | MX346757B (en) |
RU (1) | RU2500534C2 (en) |
WO (1) | WO2010003853A1 (en) |
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2839277A1 (en) * | 2002-05-03 | 2003-11-07 | Nestle Waters Man & Technology | PROCESS FOR PRODUCING A POLYESTER RESIN CONTAINER AND DEVICE FOR IMPLEMENTING SAME |
EP1529620A1 (en) * | 2003-11-06 | 2005-05-11 | Nestlé Waters Management & Technology | Container made of polyester resin, process and apparatus for manufacturing it |
WO2006096916A1 (en) * | 2005-03-15 | 2006-09-21 | Invoplas Pty Ltd | Stretch blow moulding method and apparatus |
WO2007120807A2 (en) * | 2006-04-13 | 2007-10-25 | Amcor Limited | Liquid or hydraulic blow molding |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH388173A (en) * | 1961-10-25 | 1965-02-15 | Bonatex Ets | Method and device for the manufacture of filled and closed containers |
JPH06345191A (en) * | 1993-06-01 | 1994-12-20 | Mitsubishi Heavy Ind Ltd | Filling apparatus |
JP2000043129A (en) * | 1998-07-29 | 2000-02-15 | Ishikawajima Harima Heavy Ind Co Ltd | Molding of plastic container |
FR2830277B1 (en) | 2001-10-01 | 2003-11-14 | Renault | METHOD FOR CONTROLLING A COMBUSTION ENGINE DURING A COLD START |
FR2850899B1 (en) * | 2003-02-07 | 2007-01-19 | Eurofeu Sa | METHOD FOR MANUFACTURING A HOLLOW BODY BY EXTRUSION AND BLOWING A THERMOPLASTIC RESIN |
CN101130274A (en) * | 2006-08-22 | 2008-02-27 | 东莞佳鸿机械制造有限公司 | Device of blow molding machine for drawing and air-blowing for bottle perform |
-
2008
- 2008-07-07 EP EP08159852A patent/EP2143542A1/en not_active Withdrawn
-
2009
- 2009-07-01 EP EP09793919.3A patent/EP2313247B1/en active Active
- 2009-07-01 JP JP2011517091A patent/JP5694154B2/en active Active
- 2009-07-01 WO PCT/EP2009/058236 patent/WO2010003853A1/en active Application Filing
- 2009-07-01 MX MX2011000207A patent/MX346757B/en active IP Right Grant
- 2009-07-01 BR BRPI0915468-0A patent/BRPI0915468B1/en active IP Right Grant
- 2009-07-01 CN CN200980126279.5A patent/CN102089142B/en active Active
- 2009-07-01 US US13/002,199 patent/US9573314B2/en active Active
- 2009-07-01 RU RU2011104089/05A patent/RU2500534C2/en active
-
2017
- 2017-01-05 US US15/399,346 patent/US10369737B2/en active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2839277A1 (en) * | 2002-05-03 | 2003-11-07 | Nestle Waters Man & Technology | PROCESS FOR PRODUCING A POLYESTER RESIN CONTAINER AND DEVICE FOR IMPLEMENTING SAME |
EP1529620A1 (en) * | 2003-11-06 | 2005-05-11 | Nestlé Waters Management & Technology | Container made of polyester resin, process and apparatus for manufacturing it |
WO2006096916A1 (en) * | 2005-03-15 | 2006-09-21 | Invoplas Pty Ltd | Stretch blow moulding method and apparatus |
WO2007120807A2 (en) * | 2006-04-13 | 2007-10-25 | Amcor Limited | Liquid or hydraulic blow molding |
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Also Published As
Publication number | Publication date |
---|---|
RU2500534C2 (en) | 2013-12-10 |
CN102089142B (en) | 2015-06-24 |
CN102089142A (en) | 2011-06-08 |
JP5694154B2 (en) | 2015-04-01 |
US10369737B2 (en) | 2019-08-06 |
BRPI0915468B1 (en) | 2019-09-17 |
JP2011526852A (en) | 2011-10-20 |
MX2011000207A (en) | 2011-02-25 |
EP2313247A1 (en) | 2011-04-27 |
MX346757B (en) | 2017-03-30 |
EP2143542A1 (en) | 2010-01-13 |
BRPI0915468A2 (en) | 2015-11-10 |
US20110268855A1 (en) | 2011-11-03 |
US9573314B2 (en) | 2017-02-21 |
US20170113396A1 (en) | 2017-04-27 |
RU2011104089A (en) | 2012-08-20 |
EP2313247B1 (en) | 2014-06-25 |
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