WO2009053147A1 - High-voltage outdoor bushing - Google Patents
High-voltage outdoor bushing Download PDFInfo
- Publication number
- WO2009053147A1 WO2009053147A1 PCT/EP2008/061867 EP2008061867W WO2009053147A1 WO 2009053147 A1 WO2009053147 A1 WO 2009053147A1 EP 2008061867 W EP2008061867 W EP 2008061867W WO 2009053147 A1 WO2009053147 A1 WO 2009053147A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- bushing
- tape
- particles
- fraction
- condenser core
- Prior art date
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B17/00—Insulators or insulating bodies characterised by their form
- H01B17/26—Lead-in insulators; Lead-through insulators
- H01B17/28—Capacitor type
Definitions
- the invention relates to the field of high-voltage technology and concerns a high- voltage outdoor bushing comprising a conductor extended along an axis, a condenser core and an electrically insulating polymeric weather protection housing moulded on the condenser core.
- the condenser core contains an electrically insulating tape which is wound in spiral form around the conductor, capacitance grading insertions arranged between successive windings of the tape and a cured polymeric insulating matrix embedding the wound tape and the capacitive grading insertions.
- Such a bushing is used in high voltage technology, in particular in switchgear installations or in high-voltage machines, like generators or transformers, for voltages up to several hundred kV, typically for voltages between 24 and 800 kV.
- a high-voltage outdoor bushing is a component that is usually used to carry current at high potential from an encapsulated active part of a high-voltage component, like a transformer or a circuit breaker, through a grounded barrier, like a transformer tank or a circuit breaker housing, to a high-voltage outdoor line.
- the outdoor bushing comprises a condenser core which facilitates the electrical stress control through floating capacitance grading insertions, which are incorporated in the condenser core.
- the condenser core decreases the electric field gradient and distributes the electric field homogeneously along the length of the bushing.
- the condenser core of the bushing is typically wound from kraft paper or creped kraft paper as a spacer.
- the capacitance grading insertions are executed as either metallic (typically aluminium) sheets or non-metallic (typically ink, graphite paste) patches.
- the insertions are located coaxially so as to achieve an optimal balance between external flashover and internal puncture strength.
- the paper spacer ensures a defined position of the insertions and the mechanical stability of the condenser core.
- the condenser core is impregnated with resin (RIP, resin impregnated paper). The resin is then introduced during a heating and vacuum process of the core.
- RIP outdoor bushing has the advantage that it is dry (oil free).
- the outdoor bushing comprises an outdoor side with an insulator made of either porcelain or a weather-resistant polymeric material, typically on the basis of silicone or of epoxide, having sheds which ensure the necessary creepage distance for withstand voltages under all operation conditions.
- the porcelain is traditionally used as insulation material, however, there is a continuously growing demand for polymeric insulation.
- the demand for polymeric insulation is mainly based on the fact that polymeric insulators have the additional benefit of being hydrophobic (water repellent) which leads to a self cleaning property, and which thus extends service life and lowers significantly substation maintenance costs.
- the silicone intrinsic hydrophobic property helps to break up water films and to create separate droplets which reduce leakage currents, prevent flashover and elevate the voltage withstand capability in wet and highly contaminated conditions, which are typical for coastal or highly polluted environments.
- a bushing with polymeric insulation is lightweight and resistant against vandalism and earthquake. Besides such a bushing is explosion proof. Thus a scattering of a rigid insulating housing, in particular of a porcelain insulator, and a damage of secondary equipment is mostly excluded.
- a high-voltage outdoor bushing with a conductor extended along an axis, a condenser core coaxially surrounding the conductor and with an electrically insulating polymeric weather protection housing is described in EP 1 284 483 A1.
- the weather protection housing is manufactured from a silicone and is directly moulded on the outer surface and the high-voltage front face of the condenser core and is extended to a part of the surface of the conductor, which is not covered from the condenser core.
- a bushing cap which protects the high-voltage side against the weather becomes no longer necessary and thus the bushing can be manufactured with low costs.
- directly moulded outdoor bushings have shown to generate significant problems during storage and operation. Particularly, the dissipation factor tan ⁇ has increased considerably during extended periods of storage and operation.
- Such bushings which respectively comprise a conductor extended along an axis and a condenser core coaxially surrounding the conductor are disclosed in EP 1 622 173 A1 , EP 1 798 740 A1 and WO 2006/131011 A1. These bushings respectively comprise a composite insulator as weather protection housing which is designed as a prefabricated rigid housing. The rigid housing receives the prefabricated condenser core and the conductor and is closed by means of a cap and a mounting flange.
- the production of the condenser core comprises the steps of winding an insulating tape onto the conductor, adding capacitance grading insertions during winding between successive layers of the tape, placing the wound tape into a mould, applying a vacuum to a mould and impregnating the evacuated wound tape with an insulating material consisting of a polymer which is loaded with an inorganic filler powder. Afterwards the impregnated wound tape is cured. The resulting condenser core is cooled down and machined if necessary.
- At least one of the layers of the tape (EP 1 622 173 A1 ) and/or one of the capacitance grading insertions (EP 1 798 740 A1 ) comprises holes and/or the tape contains the inorganic filler particles which are pre-filled into the tape before execution of the impregnation process with the unfilled polymer (WO 2006/131011 A19).
- High-voltage outdoor bushings are expensive since the composite insulators must be manufactured separately and need a bushing cap. Furthermore, electrically insulating material is necessary for filling gaps and pores within the bushing housings and for preventing electrical discharges and failures in the bushings.
- High-voltage outdoor bushings with a condenser core of a moisture absorbing resp. hygroscopic material are known from WO 2005/006355 A and GB 537 268 A. In these bushings the moisture uptake in the condenser core is prevented by means of a diffusion barrier which is applied to the surface of the core and which comprises a film having low water permeability resp. a solid moisture-proof skin.
- the high-voltage outdoor bushing according to the invention comprises a moisture diffusion barrier which is incorporated inside the condenser core prior to moulding a polymeric weather protection housing.
- a moisture diffusion barrier which is incorporated inside the condenser core prior to moulding a polymeric weather protection housing.
- Such a bushing is distinguished by an excellent storage and operation stability under hot and wet weather conditions. This is due to the fact that the moisture diffusion barrier limits moisture to enter deeply into the condenser core. Otherwise the moisture after having migrated through the polymeric weather protection housing by way of diffusion can migrate deeply into the condenser core and can then affect the electrical properties of the bushing, in particular the dissipation factor, strongly.
- the moisture diffusion barrier comprises at least a part of the insulating matrix which is loaded with an inorganic filler powder.
- the particles of the filler power significantly reduce the diffusion coefficient of the condenser core since the filler particles of the inorganic filler powder reduce the effective length of the diffusion path of water molecules.
- moisture is remarkably prevented from entering the condenser core.
- the bushing can be manufactured easily and at the same time the storage and operation stability of the bushing even under hot and wet environmental conditions can be significantly enhanced.
- a bushing with a comparatively high operation and storage life time under moderate weather conditions is achieved when the filler comprises at least 20%, preferably at least 30% by volume of the material of the matrix before curing.
- a bushing with a high operation and storage life time even under severe weather conditions is achieved when the filler comprises between 40 and 50% by volume of the material of the matrix before curing.
- the filler powder has two fractions of particles with different average sizes, of which the particles in the first fraction have a larger average diameter than the particles in the second fraction and are arranged essentially in the form of close sphere packing and the particles in the second fraction fill the interstices formed by the sphere packing.
- a tight filling is achieved if the average diameter of the particles in the second fraction is from about 10 to about 50% of the average diameter of the particles in the first fraction and if the quantity of the second fraction is from about 5 to about 30% by volume of the amount of the first fraction.
- the density and thus the efficiency of the moisture diffusion barrier can be further improved if a further fraction of predominantly spherically formed particles of the filler is present, whose average diameter is from about 10 to about 50% of the diameter of the particles in the second fraction.
- Water vapour which has passed the polymeric weather protection housing by means of diffusion is prevented from penetrating into the condenser core to a large extent if the moisture diffusion barrier comprises a layer which frequently already exists and which causes a strong adhesive force between the condenser core and the weather protection housing. It is to recommend to make such a layer in the form of an adhesion promoter on the basis of an adhesive polymer comprising a diffusion-constraining material.
- the conductor typically is executed as a rod, a tube or a wire.
- the tape is typically wound in spiral form, thus forming a multitude of neighbouring layers and is manufactured from fibres which are arranged in form of a paper or a net.
- Appropriate fibres are organic or inorganic.
- Organic fibres typically include natural fibres, like cellulose, polymeric fibres on the basis of a thermosetting, like polyester, or on the basis of a thermoplastic, like aramide (NOMEX ®), polyamide, polyolefine, for instance PE, polybenzimidazole (PBI), polybenzobisoxazole (PBO), polyphenylene sulphide (PPS), melamine and polyimide.
- Inorganic fibres typically include glass, lava, basalt and alumina.
- the paper preferably is a crepe paper or a paper comprising holes.
- the matrix material then can be distributed very fast und homogeneous in the condenser core. A fast and homogeneous distribution of the matrix material is also achieved, when the tape contains filler powder particles which are pre-filled into the tape or the insulating matrix before impregnating the wound tape with an uncured polymer.
- the capacitance grading insertions are inserted into the core after certain numbers of windings, so that the capacitance grading insertions are arranged in a well- defined, radial distance to the axis.
- the capacitance grading insertions can be interspersed with openings, which facilitate and accelerate the penetration of the wound tape with the matrix material.
- spacer and capacitance grading insertions facilitates and accelerates the impregnation of the wound tape with matrix material considerably.
- the polymer can for example be a resin on the basis of a silicone, an epoxy, in particular a hydrophobic epoxy, an unsaturated polyester, a vinylester, a polyurethane or a phenol.
- the filler particles are electrically insulating or semiconducting.
- the filler particles can be particles of SiO 2 , AI 2 O 3 , BN, AIn, BeO, TiB 2 , TiO 2 , SiC, SisN 4 , B 4 C, ZnO or the like, or mixtures thereof. It is also possible to have a mixture of various such particles in the polymer.
- the bushing shown in the figure is substantially rotationally symmetric with respect to a symmetry axis 1.
- a columnar supporting body 2 which is executed as solid metallic rod or a metallic tube.
- the metallic rod is an electric conductor 2 which connects an active part of an encapsulated device, for instance a transformer or a switch, with an outdoor component, for instance a power line. If the supporting body 2 is executed as metallic tube this tube can also be used as electric conductor 2, but can also receive an end of a cable, which is guided from below into the tube and the current conductor of which is electrically connected to part 2.
- the conductor 2 is partially surrounded by a core 3, which also is substantially rotationally symmetric with respect to the symmetry axis 1.
- the core 3 comprises an insulating tape 4 (shown on the right of the figure), which is wound around the conductor 2 and which is impregnated with a cured matrix material on the base of a polymer filled with an inorganic filler powder.
- the filler powder comprises approximately 45% by volume of the matrix material before curing.
- Capacitance grading insertions 5 (shown on the right of the figure) are arranged between adjacent windings of the tape 4.
- a foot flange On the outside of the core 3, a foot flange
- the weather protection housing 7 is manufactured from a polymer on the basis of a silicone or a hydrophobic epoxy resin.
- the housing 7 comprises sheds and is moulded on the condenser core 3 such that it extends from the top of the foot flange 6 along the adjoining outer surface of the condenser core 3 to the upper end 8 of the conductor 2.
- An adhesive layer which is deposited on covered surfaces of the parts 2, 3 and 6 improves adhesion of the housing 7.
- the housing protects the condenser core 3 from ageing caused by radiation (UV) and by weather and maintains good electrical insulating properties during the entire life of the bushing.
- the shape of the sheds is designed such, that it has a self- cleaning surface when it is exposed to rain. This avoids dust or pollution accumulation on the surface of the sheds, which could affect the insulating properties and lead to electrical flashover.
- the tape 4 is executed as a net on the basis of a polyester.
- the matrix material comprises as polymer an epoxy resin which was cured with an anhydride and as filler powder fused silica.
- the sizes of the fused silica particles are up to 64 ⁇ m and comprise three fractions with an average particle sizes of 2, 12 and 40 ⁇ m respectively.
- the bushing according to the figure and a reference bushing were stored in tap water at 25 ⁇ 3°C. Both bushings were totally immersed in the tap water.
- the reference bushing differed from the inventive bushing in the material of the tape and in the material of the matrix.
- the tape of the reference bushing was as crepe paper.
- the matrix of the reference bushing had the same polymer as the matrix of the bushing according to the invention, but without a filler powder. From time to time the bushings were removed from the water, blown with compressed air and dried in air for 2 or 3 hours. Afterwards the dissipation factor tan ⁇ of the two bushing was measured in accordance with IEC 60137 at a frequency of 50 Hz.
- the table shows that the bushing according to the invention even after a storage period of more than a hundred days under severe storage conditions had a dissipation factor smaller 1 %. Furthermore, the dissipation factor reached this small value already after a few weeks and remained nearly constant until this time. On the other side the dissipation factor of the reference bushing after a few weeks reached a value which was a factor 100 higher than the corresponding value of the bushing according to the invention and which still increased considerably with time.
- the matrix material of the condenser core of the bushing according to invention acts as a moisture diffusion barrier which limits the diffusion of water molecules into the interior of the condenser core to a large extent and which is responsible that the bushing according to the invention maintains to a large extent a low dissipation factor even under strong external conditions.
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- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Insulators (AREA)
- Insulating Bodies (AREA)
- Cable Accessories (AREA)
Abstract
Description
Claims
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT08803835T ATE532186T1 (en) | 2007-10-26 | 2008-09-08 | OUTDOOR HIGH VOLTAGE FEEDTHROUGH |
BRPI0817773A BRPI0817773B8 (en) | 2007-10-26 | 2008-09-08 | HIGH VOLTAGE EXTERNAL BUSHING |
RU2010121171/07A RU2473997C2 (en) | 2007-10-26 | 2008-09-08 | High-voltage bushing insulator for outdoor installation |
JP2010530370A JP2011501868A (en) | 2007-10-26 | 2008-09-08 | High voltage outdoor bushing |
CN2008801131440A CN101836269B (en) | 2007-10-26 | 2008-09-08 | High-voltage outdoor bushing |
CA2701361A CA2701361C (en) | 2007-10-26 | 2008-09-08 | High-voltage outdoor bushing with a moisture diffusion barrier |
EP08803835A EP2203922B1 (en) | 2007-10-26 | 2008-09-08 | High-voltage outdoor bushing |
US12/766,158 US8003891B2 (en) | 2007-10-26 | 2010-04-23 | High-voltage outdoor bushing |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP07119369.2 | 2007-10-26 | ||
EP07119369A EP2053616A1 (en) | 2007-10-26 | 2007-10-26 | High-voltage outdoor bushing |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US12/766,158 Continuation US8003891B2 (en) | 2007-10-26 | 2010-04-23 | High-voltage outdoor bushing |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2009053147A1 true WO2009053147A1 (en) | 2009-04-30 |
Family
ID=39199389
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2008/061867 WO2009053147A1 (en) | 2007-10-26 | 2008-09-08 | High-voltage outdoor bushing |
Country Status (9)
Country | Link |
---|---|
US (1) | US8003891B2 (en) |
EP (2) | EP2053616A1 (en) |
JP (1) | JP2011501868A (en) |
CN (1) | CN101836269B (en) |
AT (1) | ATE532186T1 (en) |
BR (1) | BRPI0817773B8 (en) |
CA (1) | CA2701361C (en) |
RU (1) | RU2473997C2 (en) |
WO (1) | WO2009053147A1 (en) |
Cited By (6)
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EP2431983A1 (en) * | 2010-09-21 | 2012-03-21 | ABB Technology AG | High voltage bushing and method for manufacturing same |
EP2515313A1 (en) | 2011-04-21 | 2012-10-24 | ABB Technology AG | High voltage feed-through |
WO2012163561A1 (en) | 2011-05-27 | 2012-12-06 | Abb Technology Ag | Electric component for a high-voltage system |
RU2613686C2 (en) * | 2012-12-13 | 2017-03-21 | Абб Текнолоджи Лтд | High-voltage device and method of producing high-voltage device |
RU179607U1 (en) * | 2017-10-26 | 2018-05-21 | Алексей Давидович Резников | High voltage insulator |
RU2790632C1 (en) * | 2022-06-09 | 2023-02-28 | Общество с ограниченной ответственностью "Индастриал Восток Инжиниринг" | High voltage input device |
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EP1939897A1 (en) * | 2006-12-28 | 2008-07-02 | ABB Research Ltd. | An insulating structure with screens shaping an electric field |
US20100078198A1 (en) * | 2008-08-13 | 2010-04-01 | John Richardson Harris | High Gradient Multilayer Vacuum Insulator |
DE102010005086B4 (en) * | 2010-01-15 | 2018-05-24 | Siemens Aktiengesellschaft | High-voltage bushing |
EP2431982B1 (en) | 2010-09-21 | 2014-11-26 | ABB Technology AG | Plugable feedthrough and high voltage assembly with such a feedthrough |
EP2482290B1 (en) * | 2011-01-28 | 2017-07-19 | ABB Schweiz AG | Temperature compensated bushing design |
WO2013104983A1 (en) * | 2012-01-13 | 2013-07-18 | Trench Limited | Method of manufacture of porcelain insulator structures and method and assembly for affixing metal flanges to porcelain insulators |
EP2777905B1 (en) * | 2013-03-14 | 2017-07-12 | ABB Schweiz AG | Mold for impregnating a prefabricated condenser core of a high-voltage bushing and device for forming a condenser core of a high-voltage bushing |
WO2015117823A1 (en) * | 2014-02-05 | 2015-08-13 | Abb Technology Ltd | Condenser core |
CN106463217B (en) * | 2014-04-14 | 2018-07-06 | Abb瑞士股份有限公司 | Manufacture the method for High-Voltage Insulation spacer of high voltage component and the high voltage component of the spacer including being manufactured according to this method |
JP6502674B2 (en) * | 2014-10-15 | 2019-04-17 | 日本碍子株式会社 | Polymer bushing |
JP6014180B2 (en) * | 2015-01-28 | 2016-10-25 | 昭和電線ケーブルシステム株式会社 | Polymer sleeve |
CN105139978A (en) * | 2015-08-11 | 2015-12-09 | 江苏神马电力股份有限公司 | Insulating tube and insulation sleeve with same |
DK3148027T3 (en) * | 2015-09-25 | 2020-03-23 | Abb Schweiz Ag | CABLE SCREWING FOR CONNECTING A HIGH VOLTAGE CABLE TO A HIGH VOLTAGE COMPONENT |
US9649797B1 (en) * | 2015-11-09 | 2017-05-16 | Marmon Utility, Llc | Electrical insulator apparatus and method of manufacturing the same |
JP6593219B2 (en) * | 2016-02-19 | 2019-10-23 | 株式会社オートネットワーク技術研究所 | Conductive member |
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US11289243B2 (en) * | 2017-07-12 | 2022-03-29 | Siemens Energy Global GmbH & Co. KG | Pluggable high-voltage bushing and electrical device having a pluggable high-voltage bushing |
EP3561819B1 (en) * | 2018-04-26 | 2022-01-26 | Hitachi Energy Switzerland AG | Bushing equipped with an optical fibre |
RU183608U1 (en) * | 2018-06-26 | 2018-09-27 | Юрий Вячеславович Лакиза | Sealed device with current lead |
US11348705B2 (en) * | 2018-10-19 | 2022-05-31 | Rolls-Royce Corporation | Coaxial cable system for gas turbine engine |
US11227708B2 (en) | 2019-07-25 | 2022-01-18 | Marmon Utility Llc | Moisture seal for high voltage insulator |
EP3869525B1 (en) * | 2020-02-24 | 2024-04-03 | Hitachi Energy Ltd | Bushing with electrically conductive head mounted on condenser core |
CN112435889A (en) * | 2020-12-01 | 2021-03-02 | 郑州大学 | High-voltage integrated static and dynamic self-voltage-sharing vacuum arc extinguish chamber |
CN117132787B (en) * | 2023-09-04 | 2024-05-31 | 北京闪电侠科技有限公司 | Locomotive roof insulator hydrophobicity evaluation method and device based on image recognition |
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GB537268A (en) * | 1939-12-13 | 1941-06-16 | Reyrolle A & Co Ltd | Improvements in or relating to electrically insulating bushings or sleeves |
WO2005006355A1 (en) * | 2003-07-11 | 2005-01-20 | Abb Research Ltd. | Bushing |
EP1798740A1 (en) * | 2005-12-14 | 2007-06-20 | Abb Research Ltd. | High voltage bushing |
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CN101253582B (en) * | 2005-06-07 | 2011-06-29 | Abb研究有限公司 | Bushing, high voltage/medium voltage equipment using same, and method for manufacturing the bushing |
DK1811626T3 (en) * | 2006-01-24 | 2016-08-01 | Nexans | Electrical bushing |
CN2911891Y (en) * | 2006-06-08 | 2007-06-13 | 南京智达电气有限公司 | Oiled paper capacitor type sleeve |
-
2007
- 2007-10-26 EP EP07119369A patent/EP2053616A1/en not_active Withdrawn
-
2008
- 2008-09-08 AT AT08803835T patent/ATE532186T1/en active
- 2008-09-08 EP EP08803835A patent/EP2203922B1/en active Active
- 2008-09-08 CA CA2701361A patent/CA2701361C/en active Active
- 2008-09-08 WO PCT/EP2008/061867 patent/WO2009053147A1/en active Application Filing
- 2008-09-08 BR BRPI0817773A patent/BRPI0817773B8/en active IP Right Grant
- 2008-09-08 CN CN2008801131440A patent/CN101836269B/en active Active
- 2008-09-08 JP JP2010530370A patent/JP2011501868A/en not_active Withdrawn
- 2008-09-08 RU RU2010121171/07A patent/RU2473997C2/en active
-
2010
- 2010-04-23 US US12/766,158 patent/US8003891B2/en active Active
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GB537268A (en) * | 1939-12-13 | 1941-06-16 | Reyrolle A & Co Ltd | Improvements in or relating to electrically insulating bushings or sleeves |
WO2005006355A1 (en) * | 2003-07-11 | 2005-01-20 | Abb Research Ltd. | Bushing |
EP1798740A1 (en) * | 2005-12-14 | 2007-06-20 | Abb Research Ltd. | High voltage bushing |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2431983A1 (en) * | 2010-09-21 | 2012-03-21 | ABB Technology AG | High voltage bushing and method for manufacturing same |
EP2515313A1 (en) | 2011-04-21 | 2012-10-24 | ABB Technology AG | High voltage feed-through |
WO2012163561A1 (en) | 2011-05-27 | 2012-12-06 | Abb Technology Ag | Electric component for a high-voltage system |
RU2613686C2 (en) * | 2012-12-13 | 2017-03-21 | Абб Текнолоджи Лтд | High-voltage device and method of producing high-voltage device |
RU179607U1 (en) * | 2017-10-26 | 2018-05-21 | Алексей Давидович Резников | High voltage insulator |
RU2790632C1 (en) * | 2022-06-09 | 2023-02-28 | Общество с ограниченной ответственностью "Индастриал Восток Инжиниринг" | High voltage input device |
Also Published As
Publication number | Publication date |
---|---|
CA2701361A1 (en) | 2009-04-30 |
CN101836269B (en) | 2012-10-03 |
US8003891B2 (en) | 2011-08-23 |
CA2701361C (en) | 2016-04-12 |
EP2203922B1 (en) | 2011-11-02 |
BRPI0817773B8 (en) | 2022-11-22 |
US20100206604A1 (en) | 2010-08-19 |
EP2053616A1 (en) | 2009-04-29 |
RU2473997C2 (en) | 2013-01-27 |
CN101836269A (en) | 2010-09-15 |
BRPI0817773B1 (en) | 2018-10-23 |
ATE532186T1 (en) | 2011-11-15 |
BRPI0817773A2 (en) | 2015-03-24 |
RU2010121171A (en) | 2011-12-10 |
JP2011501868A (en) | 2011-01-13 |
EP2203922A1 (en) | 2010-07-07 |
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