WO2008100325A3 - Method of producing carbon nanotubes - Google Patents

Method of producing carbon nanotubes Download PDF

Info

Publication number
WO2008100325A3
WO2008100325A3 PCT/US2007/072098 US2007072098W WO2008100325A3 WO 2008100325 A3 WO2008100325 A3 WO 2008100325A3 US 2007072098 W US2007072098 W US 2007072098W WO 2008100325 A3 WO2008100325 A3 WO 2008100325A3
Authority
WO
WIPO (PCT)
Prior art keywords
carbon
chirality
component
catalyst component
cylindrical
Prior art date
Application number
PCT/US2007/072098
Other languages
French (fr)
Other versions
WO2008100325A2 (en
Inventor
Avetik Harutyunyan
Original Assignee
Honda Motor Co Ltd
Avetik Harutyunyan
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Honda Motor Co Ltd, Avetik Harutyunyan filed Critical Honda Motor Co Ltd
Priority to JP2009518504A priority Critical patent/JP5358045B2/en
Publication of WO2008100325A2 publication Critical patent/WO2008100325A2/en
Publication of WO2008100325A3 publication Critical patent/WO2008100325A3/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/745—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/881—Molybdenum and iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90—Regeneration or reactivation
    • B01J23/94—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/12—Treating with free oxygen-containing gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y40/00—Manufacture or treatment of nanostructures
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • C01B32/158—Carbon nanotubes
    • C01B32/16—Preparation
    • C01B32/162—Preparation characterised by catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/462—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0203—Impregnation the impregnation liquid containing organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0234—Impregnation and coating simultaneously
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2202/00—Structure or properties of carbon nanotubes
    • C01B2202/02—Single-walled nanotubes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2202/00—Structure or properties of carbon nanotubes
    • C01B2202/04—Nanotubes with a specific amount of walls
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2202/00—Structure or properties of carbon nanotubes
    • C01B2202/06—Multi-walled nanotubes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/10—Particle morphology extending in one dimension, e.g. needle-like
    • C01P2004/13—Nanotubes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Abstract

The present teachings are directed to methods of preparing cylindrical carbon structures, specifically single-walled carbon nanotubes, with a desired chirality. The methods include the steps of providing a catalyst component on a substrate and a carbon component, contacting the catalyst component and the carbon component to produce a cylindrical carbon structure. Then, no longer providing the carbon component and determining the chirality of the cylindrical carbon structure. The catalyst component is then cleaned and the process is repeated until the cylindrical carbon structure fulfills a desired characteristic, such as, length. The chirality of the single-walled carbon nanotube grown, after cleaning of the catalyst component, has the same chirality as the initially produced nanotube.
PCT/US2007/072098 2006-06-28 2007-06-26 Method of producing carbon nanotubes WO2008100325A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2009518504A JP5358045B2 (en) 2006-06-28 2007-06-26 Method for producing carbon nanotube

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11/475,919 2006-06-28
US11/475,919 US20100239491A1 (en) 2006-06-28 2006-06-28 Method of producing carbon nanotubes

Publications (2)

Publication Number Publication Date
WO2008100325A2 WO2008100325A2 (en) 2008-08-21
WO2008100325A3 true WO2008100325A3 (en) 2008-10-30

Family

ID=39661384

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2007/072098 WO2008100325A2 (en) 2006-06-28 2007-06-26 Method of producing carbon nanotubes

Country Status (3)

Country Link
US (1) US20100239491A1 (en)
JP (1) JP5358045B2 (en)
WO (1) WO2008100325A2 (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100081568A1 (en) * 2008-04-21 2010-04-01 Lockheed Martin Corporation Methods for producing carbon nanotubes with controlled chirality and diameter and products therefrom
US8591858B2 (en) * 2008-05-01 2013-11-26 Honda Motor Co., Ltd. Effect of hydrocarbon and transport gas feedstock on efficiency and quality of grown single-walled nanotubes
US9174847B2 (en) * 2008-05-01 2015-11-03 Honda Motor Co., Ltd. Synthesis of high quality carbon single-walled nanotubes
US8257678B2 (en) 2009-07-31 2012-09-04 Massachusetts Institute Of Technology Systems and methods related to the formation of carbon-based nanostructures
FR2949075B1 (en) 2009-08-17 2013-02-01 Arkema France FE / MO SUPPORTED CATALYST, PROCESS FOR PREPARING THE SAME, AND USE IN THE MANUFACTURE OF NANOTUBES
US20110162957A1 (en) * 2009-11-25 2011-07-07 Massachusetts Institute Of Technology Systems and methods for enhancing growth of carbon-based nanostructures
US9663368B2 (en) 2010-10-28 2017-05-30 Massachusetts Institute Of Technology Carbon-based nanostructure formation using large scale active growth structures
US10195797B2 (en) 2013-02-28 2019-02-05 N12 Technologies, Inc. Cartridge-based dispensing of nanostructure films
JP6039534B2 (en) 2013-11-13 2016-12-07 東京エレクトロン株式会社 Carbon nanotube generation method and wiring formation method

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5037785A (en) * 1989-11-17 1991-08-06 Her Majesty The Queen In Right Of Canada, As Represented By The Minister Of Energy, Mines And Resources Catalyst regeneration process using laser radiation
WO2000063115A1 (en) * 1999-04-16 2000-10-26 Commonwealth Scientific And Industrial Research Organisation Multilayer carbon nanotube films

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000516708A (en) * 1996-08-08 2000-12-12 ウィリアム・マーシュ・ライス・ユニバーシティ Macroscopically operable nanoscale devices fabricated from nanotube assemblies
JP3441923B2 (en) * 1997-06-18 2003-09-02 キヤノン株式会社 Manufacturing method of carbon nanotube
US6835366B1 (en) * 1998-09-18 2004-12-28 William Marsh Rice University Chemical derivatization of single-wall carbon nanotubes to facilitate solvation thereof, and use of derivatized nanotubes
EP1112224B1 (en) * 1998-09-18 2009-08-19 William Marsh Rice University Chemical derivatization of single-wall carbon nanotubes to facilitate solvation thereof; and use of derivatized nanotubes
US6869583B2 (en) * 2001-04-12 2005-03-22 The Penn State Research Foundation Purification of carbon filaments and their use in storing hydrogen
WO2003040446A2 (en) * 2001-06-15 2003-05-15 The Pennsylvania State Research Foundation Method of purifying nanotubes and nanofibers using electromagnetic radiation
US20030124717A1 (en) * 2001-11-26 2003-07-03 Yuji Awano Method of manufacturing carbon cylindrical structures and biopolymer detection device
US7214361B2 (en) * 2002-11-26 2007-05-08 Honda Giken Kogyo Kabushiki Kaisha Method for synthesis of carbon nanotubes
JP2007504086A (en) * 2003-09-03 2007-03-01 本田技研工業株式会社 Method for producing one-dimensional carbon nanostructure
JP2005343744A (en) * 2004-06-03 2005-12-15 Matsushita Electric Ind Co Ltd Method for producing carbon nanotube semiconductor and carbon nanotube semiconductor
US20060057388A1 (en) * 2004-09-10 2006-03-16 Sungho Jin Aligned and open-ended nanotube structure and method for making the same
JP4868726B2 (en) * 2004-09-14 2012-02-01 富士通株式会社 Method for controlling the structure of carbon nanotubes
JP4780546B2 (en) * 2004-11-08 2011-09-28 学校法人 名城大学 Method for producing carbon nanotube and method for producing current control element
WO2006060476A2 (en) * 2004-12-01 2006-06-08 William Marsh Rice University Fibers comprised of epitaxially grown single-wall carbon nanotubes, and a method for added catalyst and continuous growth at the tip

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5037785A (en) * 1989-11-17 1991-08-06 Her Majesty The Queen In Right Of Canada, As Represented By The Minister Of Energy, Mines And Resources Catalyst regeneration process using laser radiation
WO2000063115A1 (en) * 1999-04-16 2000-10-26 Commonwealth Scientific And Industrial Research Organisation Multilayer carbon nanotube films

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
HATA K ET AL: "Water-Assisted Highly Efficient Synthesis of Impurity-Free Single-Walled Carbon Nanotubes", SCIENCE, WASHINGTON, DC, vol. 306, 19 November 2004 (2004-11-19), pages 1362 - 1364, XP002993037, ISSN: 0036-8075 *
HE MAOSHUAI ET AL: "Iron catalysts reactivation for efficient CVD growth of SWNT with base-growth mode on surface", J PHYS CHEM B; JOURNAL OF PHYSICAL CHEMISTRY B AUG 26 2004, vol. 108, no. 34, 26 August 2004 (2004-08-26), pages 12665 - 12668, XP002491259 *
WANG Y ET AL: "Continued growth of Single-Walled Carbon Naontubes", NANO LETTERS, ACS, WASHINGTON, DC, US, vol. 5, no. 6, 1 June 2005 (2005-06-01), pages 997 - 1002, XP002379119, ISSN: 1530-6984 *

Also Published As

Publication number Publication date
JP2010503595A (en) 2010-02-04
US20100239491A1 (en) 2010-09-23
JP5358045B2 (en) 2013-12-04
WO2008100325A2 (en) 2008-08-21

Similar Documents

Publication Publication Date Title
WO2008100325A3 (en) Method of producing carbon nanotubes
WO2010014650A3 (en) Preferential growth of single-walled carbon nanotubes with metallic conductivity
WO2007044614A3 (en) Carbon nanostructures manufactured from catalytic templating nanoparticles
WO2006065431A3 (en) Method for preparing catalyst supports and supported catalysts from single walled carbon nanotubes
WO2008060654A3 (en) Method for preparing uniform single walled carbon nanotubes
WO2008115753A3 (en) Method of preparing carbon nanotube containing electrodes
JP2005521563A5 (en)
WO2007086909A3 (en) Nanotube composite materials and methods of manufacturing the same
WO2008136347A1 (en) Single-walled carbon nanotube dispersion liquid and method for producing single-walled carbon nanotube dispersion liquid
WO2009036877A8 (en) Carbon nanotube powder, carbon nanotube, and method for the production thereof
WO2006135439A3 (en) Improved ozonolysis of carbon nanotubes
WO2008054839A3 (en) Carbon nanotube diameter selection by pretreatment of metal catalysts on surfaces
WO2010056933A3 (en) Hydrophobic surface coating systems and methods for metals
WO2008152221A8 (en) Composite consisting of nanotubes or nanofibres on a β-sic film
WO2005019104A3 (en) Controlled nanotube fabrication and uses
EP1977997A4 (en) Process for producing carbon nanotube and catalyst for carbon nanotube production
WO2006060168A3 (en) Method for preparing supported catalysts from metal loaded carbon nanotubes
WO2010066990A3 (en) Method for the synthesis of carbon nanotubes on long particulate micrometric materials
WO2010123534A3 (en) Enzyme-based nanoscale decontaminating composites
WO2008140649A3 (en) Boron-doped single-walled nanotubes (swcnt)
WO2010052704A3 (en) Tubular nanostructures, processes of preparing same and devices made therefrom
WO2011127207A3 (en) Simple method for producing superhydrophobic carbon nanotube array
WO2009060009A3 (en) Expanded graphite and method for producing the same
EP2179791A4 (en) Method for production of metal-supporting carbon, method for production of crystal composed of fullerene molecule and fullerene nanowhisker/nanofiber nanotube, and apparatus for production of fullerene molecule and fullerene nanowhisker/nanofiber nanotube
WO2008032071A8 (en) Polymer - carbon nanotube composites

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 07873307

Country of ref document: EP

Kind code of ref document: A2

WWE Wipo information: entry into national phase

Ref document number: 2009518504

Country of ref document: JP

NENP Non-entry into the national phase

Ref country code: DE

NENP Non-entry into the national phase

Ref country code: RU

122 Ep: pct application non-entry in european phase

Ref document number: 07873307

Country of ref document: EP

Kind code of ref document: A2