WO2008004939A1 - Injection moulding mechanism - Google Patents
Injection moulding mechanism Download PDFInfo
- Publication number
- WO2008004939A1 WO2008004939A1 PCT/SE2007/000638 SE2007000638W WO2008004939A1 WO 2008004939 A1 WO2008004939 A1 WO 2008004939A1 SE 2007000638 W SE2007000638 W SE 2007000638W WO 2008004939 A1 WO2008004939 A1 WO 2008004939A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- mould
- injection moulding
- mould part
- servo
- motor
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/17—Component parts, details or accessories; Auxiliary operations
- B29C45/64—Mould opening, closing or clamping devices
- B29C45/66—Mould opening, closing or clamping devices mechanical
- B29C45/661—Mould opening, closing or clamping devices mechanical using a toggle mechanism for mould clamping
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
- B29C45/14467—Joining articles or parts of a single article
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/17—Component parts, details or accessories; Auxiliary operations
- B29C45/46—Means for plasticising or homogenising the moulding material or forcing it into the mould
- B29C45/56—Means for plasticising or homogenising the moulding material or forcing it into the mould using mould parts movable during or after injection, e.g. injection-compression moulding
- B29C45/561—Injection-compression moulding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/17—Component parts, details or accessories; Auxiliary operations
- B29C2045/1784—Component parts, details or accessories not otherwise provided for; Auxiliary operations not otherwise provided for
- B29C2045/1792—Machine parts driven by an electric motor, e.g. electric servomotor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/17—Component parts, details or accessories; Auxiliary operations
- B29C45/46—Means for plasticising or homogenising the moulding material or forcing it into the mould
- B29C45/56—Means for plasticising or homogenising the moulding material or forcing it into the mould using mould parts movable during or after injection, e.g. injection-compression moulding
- B29C45/561—Injection-compression moulding
- B29C2045/564—Compression drive means acting independently from the mould closing and clamping means
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/17—Component parts, details or accessories; Auxiliary operations
- B29C45/64—Mould opening, closing or clamping devices
- B29C45/66—Mould opening, closing or clamping devices mechanical
- B29C2045/667—Cam drive for mould closing or clamping
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/712—Containers; Packaging elements or accessories, Packages
Definitions
- the present invention concerns an injection moulding mechanism.
- the injection moulding mechanism has been developed for moulding of a thermoplastic top on the edge of a sleeve of paper laminate.
- Prior Art is developed for use with the injection moulding technique known as injection compression.
- injection compression a partly closed mould is partly filled in a first step. Then the mould is completely closed giving a compression force on the material inside the mould, which material will fill up the mould due to the compression. Movements to close the mould and to give the compression force are often given by means of a hydraulic cylinder and some kind of link mechanism.
- the second step, giving the compression force is accomplished in that a link system is given a straight orientation.
- the previously used mechanisms have been difficult to control in an exact manner and in some cases there has been registered a potential risk for deformations instead of a suitable compression.
- One object of the present invention is to have a simple and yet reliable mechanism, giving a partly closed mould in a first step and a closed mould and compression force in a second step. Furthermore, the mechanism should be possible to control in a precise manner. A further object is to have a process that is repeatable in giving the same result. Still a further object is that the cycle time to produce one component should be relatively short.
- an injection moulding mechanism comprising an extruder, an inner mould part and an outer mould part. It further comprises a first mechanism to partly close the mould and a second mechanism to close the mould and compress the extruded material inside the mould.
- One of the mould parts is arranged moveable towards the other mould part to form a mould cavity.
- At least one of the mould parts has a channel, opening into the mould cavity and connected to the extruder.
- the first mechanism to partly close the mould, has a knee mechanism driven by a servo-motor.
- the second mechanism to close and compress the extruded material inside the mould, has an eccentric being a part of the shaft of a second servo-motor.
- Fig. 1 is a sectional view of a mould used in a mechanism according to the present invention and indicating a position during one step of a working cycle
- Fig. 2 is a side view of an injection moulding mechanism, according to the present invention, in a step of starting closing of the mould
- Fig. 3 is a view according to Fig. 2 but showing a step of finishing closing of the mould
- Fig. 4 is a view according to Fig. 2 but showing a step of compressing the mould with the second mechanism of the invention
- Fig. 5 is a view according to Fig. 2, but showing a different embodiment of the injection compression mechanism according to the present invention. Detailed Description of Preferred Embodiments
- the mechanism shown in the Figs has a mould, having an inner mould part 1 and an outer mould part 2.
- the outer mould part 2 has one or more channels 3 for receiving extruded plastic material and is arranged movable in relation to the inner mould part 1.
- the inner mould part 1 has the form of a mandrel placed on a mandrel wheel 4, having five mandrels. In other embodiments other numbers of mandrels may be placed on the mandrel wheel.
- the mandrels are placed projecting radially outwards on the mandrel wheel 4.
- the mandrel wheel 4 is provided to rotate intermittently on a shaft, in such away that the mandrels are placed one at the time in a correct position opposite the outer mould part 2.
- a sleeve 5 of paper laminate is placed together with a cap 6 on a mandrel in successive steps, which mandrel forms the inner mould part 1.
- the inner mould part 1 is then placed in-line with the outer mould part 2.
- a mould cavity 7 is formed between them.
- the channel(s) 3 of the outer mould part 2 opens into the mould cavity 7.
- the outer mould part 2 is mounted on a moveable frame having a lower plate 8 and an upper plate 9, which lower and upper plates 8, 9 are held together a by means of a number of rods 10.
- the plates 8, 9 are arranged at a distance from each other to give room for parts of the injection moulding mechanism.
- the outer mould part 2 is mounted on the lower plate 8.
- the frame, formed of the lower and upper plates 8, 9 and the rods 10, is arranged movable on rails 11. On top of the rails 11 a support 12 is fixed, which support 12 holds a first servo-motor 13 and a second servo-motor 14.
- a first pivotable arm 15 is connected to the servo-motor by means of a first pivot axle 16, arranged eccentric on a disc 17, in that it is placed at a distances from the rotation axis of the disc 17.
- the disc 17 is rotated by the first servo-motor 13.
- the first pivotable arm 15 is connected to a second pivotable arm 18 by means of a second pivot axle 19.
- the second pivotable arm 18 is connected to the upper plate 9 of the frame for the outer mould part 2 by means of a third pivot axle 20.
- a third pivotable arm 21 is connected at one end to the same pivot axle 19 as the first and second pivotable arms 15, 18. The other end of the third pivotable arm 21 is received at the second servo-motor 14.
- the second pivotable arm 18 In the starting position for the first servo-motor 13, i.e. before rotation of the first servo-motor 13, the second pivotable arm 18 is inclined in relation to an imaginary line 22, see Fig. 2.
- the imaginary line 22 goes through the centre of the mould, crossing the pivot axle 20 between the second pivotable arm 18 and the upper plate 9 of the frame, crossing the shaft and eccentric of the second servo-motor 14 and through the centre of the mandrel wheel 4.
- the second pivotable arm 18 has been moved to a position in-line with the imaginary line 22, due to the arrangement of the first, second and third pivotal arms 15, 18, 21 and the first, second and third pivot axles 16, 19, 20.
- the third pivotable arm 21 is arranged in such a way that it also will be in-line with the second pivotable arm 18 and the imaginary line 22, when the first servo-motor 13 has reached its end position.
- the second servo-motor 14 is furnished with an eccentric, which is to act on the third pivotable arm 21.
- the eccentric is formed on the rotating shaft of the second servo-motor 14 and the third pivotable arm 21 is received journalled in a roller bearing.
- the eccentric of the second servo-motor 14 will act on a straight link mechanism.
- the first servo-motor 13 co-operates with a knee-mechanism, in the form of the first, second and third pivotable arms 15, 18, 21 , to partly close the mould.
- the second servo-motor 14 co-operates with an eccentric and the second and third pivotable arms 18, 21 to close and lock the mould with a high clamping force, compressing the plastic material inside the mould.
- An extruder 23 is placed at the injection compression mechanism.
- a pipe 24 is arranged to lead plastic material from the extruder, via the channel(s) 3 of the outer mould part 2 and into the mould cavity 7 formed between the outer and inner mould parts 2, 1.
- the embodiment as shown in the enclosed Figs, has the following work cycle.
- the mandrel wheel 4 has five equally spaced mandrels, each forming an inner mould part 1.
- the mandrel wheel 4 will be rotated or indexed a fifth of a full turn during each work cycle. Thus, each mandrel will subsequently occupy five different positions.
- a sleeve 5 is placed on the mandrel.
- a cap 6 is placed on the mandrel.
- a plastic top is moulded between the sleeve 5 and the cap 6.
- the plastic top and the cap 6 form one unit.
- the formed unit In a fourth position of the mandrel the formed unit is allowed to cool. In the fifth and last position the formed unit is released from the mandrel.
- the placement of parts on the mandrels and removing of the finished products are normally done in an automatic fashion. However, a person skilled in the art realises that it may also be performed at least partly manually. As this part does not have any importance for the present invention as such it will not be described further here.
- one mandrel i.e. inner mould part 1
- the inner mould part 1 holds a sleeve 5 and a cap 6.
- the first servo-motor 13 closes the mould, in that the outer mould part 2 is moved down towards the inner mould part 1 , whereby the mould cavity 7 is formed.
- the movement of the first servo-motor 13 rotates the disc 17 holding a pivot axle 16 to which the first pivotable arm 15 is connected.
- the second and third moveable arms 18, 21 will be moved.
- the first servo motor 13 will move the second and third arms 18, 21 to a position in which said arms 18, 21 will form a straight line in-line with the imaginary line 22. In that position the first servo-motor 13 is stopped, giving the end position of the first servo-motor 13, see Fig. 3.
- the next step of the work cycle is that the extruder 23 will inject plastic material into the mould cavity 7, via the pipe 24 and the channel 3 of the outer mould part 2. The injected plastic material will not fill the mould cavity 7 completely.
- the second servo-motor 14 will be rotated, whereby the eccentric connected to the second servo-motor 14 will act on the third pivotable arm 21 in such a way that the outer mould part 2 will be moved further towards the inner mould part 1 , closing the mould, see Fig. 4.
- the second servo-motor 14 will be rotated about one third to one half of a full turn.
- This relatively long movement of the second servo-motor 14 translates to a movement of the outer mould part of only 1-2 mm, by means of the eccentric.
- This further movement of the outer mould part 2 will compress the injected plastic material in such a way that the material will fill out the mould cavity 7.
- both servo-motors 13, 14 in the end positions the injected material is cooled. Thus, the cooling is performed under compression and is normally done from the inside of the mould.
- Fig. 5 another embodiment of the present invention is shown, where the injection moulding mechanism is movably mounted on rails 11 , which rails 11 are fastened at a base 25. This base 25 is located close to the mandrel wheel, which is mounted at a central hub.
- the injection moulding mechanism is attached to the support 12, at an upper end as seen in Fig.
- the rails are relatively long, in the order of 100-120 cm, and are formed to be slightly flexible. During normal operation, the force on the rails from the knee-mechanism is about 50 to 100 kN. At these loads, the rails should be designed to flex about 0.05 to 0.1 percent, which for a 100 cm long rail translates into 0.5 mm to 1 mm. This means that in order to compress the mould about 1 mm, the knee-mechanism must be extended about 1.5 to 2.0 mm, due to the flex of the rails. The flex of the rails 11 makes the setup of the injection moulding mechanism much easier, since overfilling of the mould will be compensated by said flexing.
- the rails 11 are at an outer end rigidly attached to the support 12 and are at an inner end rigidly attached to the base 25.
- a further advantage of the flexing of the rails 11 appears when the injected plastic material in the mould 1 , 2 is cooled. The plastic material will then shrink and will separate from the walls of a traditional moulding mechanism. The flexing of the rails 11 will, however, ensure that the mould 1 , 2 is always in contact with the injected plastic material during cooling. This will also increase the speed of cooling, since the mould transfers heat from the plastic material more efficiently if being in contact with the entire plastic detail.
- the long and relatively slender rails 11 will give the injection moulding mechanism another advantage.
- the outer mould part 2 is slightly movable in a lateral direction, in addition to the longitudinal direction given by the longitudinal flexing of the rails 11. This lateral movement is possible due to bending of the rails 11.
- the sideways movement will make the outer mould 2 self-aligning, since it will adjust to a force balance in the mould 1 , 2.
- compression moulding where the injected plastic material enters the substantially open mould 1 , 2 at two or more locations on the jacket 26 of the mould, see Fig. 1 , the compression of the mould will create a force balance which will strive to ensure that the thickness of the finished plastic part is more or less uniform, despite of differences in injected amounts at different locations.
- the mould parts 1 , 2 are arranged such that they can move slightly in a lateral direction, and adjust to said force balance.
- the outer mould part 2 By arranging the outer mould part 2 in a mechanism that is suspended on flexible rails 11 , this is possible.
- the inner mould part 1 is connected to the mandrel wheel 4 and is more or less stationary.
- the maximum possible lateral movement of the injection moulding mechanism and hence the outer mould should be in the order of 0.5 to 1 mm (corresponding to 0.05 to 0.1 percent of the length of the rails 11 described above), when the injection moulding mechanism is subjected to normal forces of injection compression moulding.
- the above flexing refers to a location where the outer mould part 2 is mounted on the injection moulding mechanism, which is suspended on the rails 11 , such that the outer mould part 2 can move a distance of about 0.5 to 1 mm in a lateral direction.
- Both the longitudinal flexing and the lateral flexing should be adapted to the specific application. In the above cases, the flexing is about half the distance compared to the movement given by a second eccentric mechanism, i.e. if a movement given by the eccentric mechanism 14 in the longitudinal direction is about 1 mm, the flexing in the longitudinal direction will be about 0.5 mm.
- Other relationships between the movement in the longitudinal direction of the injection compression mechanism and the flexing of the rails 11 in the same direction are possible. The same applies for the lateral flexing of the rails 11.
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
- Moulds For Moulding Plastics Or The Like (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
- Transmission Devices (AREA)
Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ES07748297.4T ES2488917T3 (en) | 2006-07-05 | 2007-07-02 | Injection molding mechanism |
JP2009518047A JP4914920B2 (en) | 2006-07-05 | 2007-07-02 | Injection molding mechanism |
EP07748297.4A EP2040901B1 (en) | 2006-07-05 | 2007-07-02 | Injection moulding mechanism |
BRPI0713271A BRPI0713271B1 (en) | 2006-07-05 | 2007-07-02 | injection molding mechanism |
MX2008016421A MX2008016421A (en) | 2006-07-05 | 2007-07-02 | Injection moulding mechanism. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SE0601470-8 | 2006-07-05 | ||
SE0601470 | 2006-07-05 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2008004939A1 true WO2008004939A1 (en) | 2008-01-10 |
Family
ID=38894818
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/SE2007/000638 WO2008004939A1 (en) | 2006-07-05 | 2007-07-02 | Injection moulding mechanism |
Country Status (8)
Country | Link |
---|---|
EP (1) | EP2040901B1 (en) |
JP (1) | JP4914920B2 (en) |
BR (1) | BRPI0713271B1 (en) |
ES (1) | ES2488917T3 (en) |
MX (1) | MX2008016421A (en) |
RU (1) | RU2429125C2 (en) |
TW (1) | TWI411514B (en) |
WO (1) | WO2008004939A1 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2011073105A1 (en) | 2009-12-14 | 2011-06-23 | Tetra Laval Holdings & Finance S.A. | Opening device and method for manufacturing the same, and a packaging material provided with said opening device |
WO2011073104A1 (en) | 2009-12-14 | 2011-06-23 | Tetra Laval Holdings & Finance S.A. | Opening device and method for manufacturing the same, and a packaging container provided with said opening device |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3830614A (en) * | 1972-12-01 | 1974-08-20 | A Kurtz | Injection molding machine |
US4900242A (en) * | 1986-05-05 | 1990-02-13 | Maus Steven M | Apparatus for injection molding articles |
US20020018826A1 (en) * | 2000-06-29 | 2002-02-14 | Yuji Abe | Die clamping apparatus |
WO2002055283A1 (en) * | 2001-01-09 | 2002-07-18 | Hongguan Technologies (S) Pte Ltd. | Apparatus for and a method used in compressing a workpiece |
US20050109229A1 (en) * | 2002-09-20 | 2005-05-26 | Bionics Corporation | Press mechanism, clamp mechanism, and molding machine using this clamp mechanism |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3731083B2 (en) * | 2000-10-05 | 2006-01-05 | 有限会社 テクノクリエイト | Resin sealing device |
TWI280166B (en) * | 2002-12-26 | 2007-05-01 | Toshiba Machine Co Ltd | Liquid material feed apparatus of die casting machine, liquid material feed method, and ladle |
US20090004314A1 (en) * | 2004-07-26 | 2009-01-01 | Noritsugu Hiraga | Injection Apparatus |
-
2007
- 2007-07-02 RU RU2009103778/05A patent/RU2429125C2/en active
- 2007-07-02 MX MX2008016421A patent/MX2008016421A/en active IP Right Grant
- 2007-07-02 BR BRPI0713271A patent/BRPI0713271B1/en not_active IP Right Cessation
- 2007-07-02 ES ES07748297.4T patent/ES2488917T3/en active Active
- 2007-07-02 JP JP2009518047A patent/JP4914920B2/en active Active
- 2007-07-02 WO PCT/SE2007/000638 patent/WO2008004939A1/en active Application Filing
- 2007-07-02 EP EP07748297.4A patent/EP2040901B1/en active Active
- 2007-07-05 TW TW096124405A patent/TWI411514B/en active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3830614A (en) * | 1972-12-01 | 1974-08-20 | A Kurtz | Injection molding machine |
US4900242A (en) * | 1986-05-05 | 1990-02-13 | Maus Steven M | Apparatus for injection molding articles |
US20020018826A1 (en) * | 2000-06-29 | 2002-02-14 | Yuji Abe | Die clamping apparatus |
WO2002055283A1 (en) * | 2001-01-09 | 2002-07-18 | Hongguan Technologies (S) Pte Ltd. | Apparatus for and a method used in compressing a workpiece |
US20050109229A1 (en) * | 2002-09-20 | 2005-05-26 | Bionics Corporation | Press mechanism, clamp mechanism, and molding machine using this clamp mechanism |
Non-Patent Citations (1)
Title |
---|
See also references of EP2040901A4 * |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2011073105A1 (en) | 2009-12-14 | 2011-06-23 | Tetra Laval Holdings & Finance S.A. | Opening device and method for manufacturing the same, and a packaging material provided with said opening device |
WO2011073104A1 (en) | 2009-12-14 | 2011-06-23 | Tetra Laval Holdings & Finance S.A. | Opening device and method for manufacturing the same, and a packaging container provided with said opening device |
US8616400B2 (en) | 2009-12-14 | 2013-12-31 | Tetra Laval Holdings & Finance S.A. | Opening device and method for manufacturing the same, and a packaging container provided with said opening device |
US9505519B2 (en) | 2009-12-14 | 2016-11-29 | Tetra Laval Holdings & Finance S.A. | Opening device and method for manufacturing the same, and a packaging material provided with said opening device |
US10399738B2 (en) | 2009-12-14 | 2019-09-03 | Tetra Laval Holdings & Finance S.A. | Opening device and method for manufacturing the same, and a packaging material provided with said opening device |
Also Published As
Publication number | Publication date |
---|---|
TW200819276A (en) | 2008-05-01 |
ES2488917T3 (en) | 2014-09-01 |
RU2009103778A (en) | 2010-08-10 |
MX2008016421A (en) | 2009-01-21 |
EP2040901B1 (en) | 2014-06-18 |
RU2429125C2 (en) | 2011-09-20 |
BRPI0713271A2 (en) | 2012-04-10 |
BRPI0713271B1 (en) | 2018-05-08 |
JP2009542469A (en) | 2009-12-03 |
JP4914920B2 (en) | 2012-04-11 |
EP2040901A4 (en) | 2013-02-27 |
EP2040901A1 (en) | 2009-04-01 |
TWI411514B (en) | 2013-10-11 |
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