WO2008003243A1 - Fibre de viscose contenant de la calamine, son procédé de préparation et d'utilisation - Google Patents

Fibre de viscose contenant de la calamine, son procédé de préparation et d'utilisation Download PDF

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Publication number
WO2008003243A1
WO2008003243A1 PCT/CN2007/002027 CN2007002027W WO2008003243A1 WO 2008003243 A1 WO2008003243 A1 WO 2008003243A1 CN 2007002027 W CN2007002027 W CN 2007002027W WO 2008003243 A1 WO2008003243 A1 WO 2008003243A1
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WO
WIPO (PCT)
Prior art keywords
calamine
viscose
fiber
powder
preparing
Prior art date
Application number
PCT/CN2007/002027
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English (en)
Chinese (zh)
Inventor
Bingsheng Gao
Mulin 351100 Xu
Yi Xu
Jitao Liu
Original Assignee
Fu Jian Zhonghe Co., Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fu Jian Zhonghe Co., Ltd filed Critical Fu Jian Zhonghe Co., Ltd
Publication of WO2008003243A1 publication Critical patent/WO2008003243A1/fr

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Classifications

    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
    • D01F2/06—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from viscose
    • D01F2/08—Composition of the spinning solution or the bath
    • D01F2/10—Addition to the spinning solution or spinning bath of substances which exert their effect equally well in either
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/10—Other agents for modifying properties

Definitions

  • BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to the field of textile industry, and relates to a calamine viscose fiber, and to a method for preparing calamine viscose fiber and a use thereof.
  • BACKGROUND OF THE INVENTION Viscose fiber is a regenerated cellulose fiber, and has a molecular formula of (C e H 1() C n, n is a degree of polymerization. It is based on natural cellulose such as wood, reed, and cotton linters in nature. The process of alkalization, aging, yellowing, etc.
  • Viscose fiber is made into soluble cellulose xanthate, which is dissolved in dilute alkali solution to make viscose and made by wet spinning. It is the first chemical fiber in the world to be industrially produced. 1. Viscose fiber is divided into two types: filament and short fiber. Viscose filament is also called rayon or viscose; and viscose staple fiber is cotton (also called rayon), wool type (called artificial wool). ) and medium and long fiber. Because the properties of viscose fiber are close to natural fiber, it has good hygroscopicity and moisture content which meets the physiological requirements of human skin. It has smooth, breathable, antistatic, dyed and beautiful characteristics, and is soft and comfortable to wear.
  • Calamine has a high medicinal and health value, and the medicinal function of calamine is recorded in many ancient books of ancient medicine and modern pharmacopoeia.
  • Calamine is a natural medicinal material, drug name: calamine, English name: luganshi, taste: Gan, Ping. Go to the liver, stomach.
  • the main components of calamine are zinc carbonate (ZnCO 3 ), aqueous zinc carbonate (ZnC0 3 ⁇ 2 ⁇ (OH) 2 ⁇ 2 0 ), and zinc oxide (Zn0).
  • Calamine effect Detoxification eyesight, to remove phlegm, use the treatment of red swelling and pain, eye deciduous film, bad string wind eye; Humidity and itching, sore muscle sore, use eczema wet sore, ulcers are not concentrated . It can be used clinically for the treatment of a variety of contact dermatitis-skin conditions, especially for the treatment of ulcers, pus, wet sores, itchy skin and other diseases.
  • viscose and calamine have their own characteristics, so far, no one has combined viscose fiber with calamine, so that one product has the advantages of two substances at the same time.
  • the inventors After understanding and mastering the characteristics of viscose fiber and calamine, the inventors have worked hard to combine the viscose fiber textiles with the health care function of calamine, and the present invention has been produced.
  • SUMMARY OF THE INVENTION It is an object of the present invention to provide a calamine viscose fiber which has a viscose fiber.
  • Another object of the invention is a method of preparing a calamine viscose fiber and its use.
  • the solution of the present invention is:
  • the calamine viscose fiber contains 1% to 6% of calamine powder in the fiber based on the total dry basis weight of the fiber, and the calamine powder is uniformly dispersed inside and on the surface of the fiber.
  • the above viscose fiber is a viscose filament or a viscose staple fiber.
  • the calamine powder described above is a micron-sized particle having an average particle diameter of 1 ⁇ m.
  • the method for preparing the calamine viscose fiber the calamine powder is blended with the dissolved viscose in an amount of 1% to 6% based on the total weight of the fiber dry basis, and the mixture is thoroughly stirred, filtered, and vacuum defoamed.
  • the calamine powder is directly blended with the spinning viscose by a pre-spinning syringe device in an amount of 1% to 6% based on the total weight of the fiber dry basis, and then passed through a filament production line. , that is, a calamine viscose filament obtained; or a calamine viscose staple fiber obtained by a short fiber production line.
  • the above calamine dissolution formula is: calamine 5% - 15%, water 85% - 95%.
  • calamine viscose fiber can be directly spun, or interlaced with cotton and chemical fiber, and short fiber can be blended with short fibers of cotton, acrylic, polyester, etc. Used in underwear, t-shirts, pajamas, shirts, dresses, bedding, etc.
  • the calamine powder particles are uniformly dispersed in the fibers, the powder is firmly integrated with the fibers in the inside and the surface of the fibers.
  • Calamine powder has good compatibility and dispersibility, is resistant to washing, light, and high temperature, and has good dyeability and spinnability of viscose fiber.
  • the calamine viscose fiber is obtained by the above method, and has broad-spectrum antibacterial and antibacterial long-lasting effects. It has significant anti-bacterial effects against Staphylococcus aureus, Escherichia coli, and Candida albicans. It provides health and auxiliary medical care for the treatment of patients with various contact dermatitis-skin disorders.
  • This calamine viscose fiber is a functional fiber added. In addition to the natural, degradable, soft, and excellent dyeing properties of viscose fiber, it also imparts medicinal and health-care functions and has various physiological functions. The activity helps to enhance the vitality of the cells, and can regulate the skin and the body to maintain health. Moreover, the calamine viscose fiber also has remarkable anti-ultraviolet properties and improves the material quality.
  • the quality of the calamine viscose filament of the invention conforms to the standard of GB/T13758-92-; the quality of the calamine viscose staple fiber conforms to the standard of GB/T14463-93-.
  • the calamine viscose fiber has a wide range of applications, and the following examples are not limiting of the invention. System.
  • the above mother liquor is continuously blended with the spinning viscose in a pre-spinning syringe, and the blending ratio is the weight ratio of ⁇ -Cell (the cellulose) in the total weight of the fiber to the weight of the calamine powder in the mother liquor.
  • 1 : 0. 04 simultaneously enter the R535A spinning machine (or R535, R535A semi-continuous spinning machine and continuous spinning machine) for spinning.
  • the falling silk cake is subjected to pressure washing (or rinsing) and then subjected to desulfurization, water washing, pickling, bleaching, water washing, oiling, dehydration, drying, and forming into a cylinder, thereby obtaining the above-mentioned furnace.
  • Glycine viscose filaments are simultaneously enter the R535A spinning machine (or R535, R535A semi-continuous spinning machine and continuous spinning machine) for spinning.
  • pressure washing or rinsing
  • desulfurization water washing, pickling, bleaching, water washing
  • the above mother liquor is blended with the dissolved viscose in a dissolving machine, and the blending ratio is a weight ratio of the weight of the a-cell (the cellulose) to the calcined powder in the mother liquor of the total weight of the fiber: 1: 0. 04, the blend is stirred, filtered, vacuum defoamed, matured, and then spun into a viscose staple fiber spinning machine.
  • the spun-formed tow is subjected to short fiber post-treatment for desulfurization, water washing, pickling, bleaching, water washing, oiling, cutting, drying, and packaging to obtain the above-mentioned calamine viscose staple fiber.
  • the calamine varnish viscose fiber with 4% calamine content has remarkable anti-ultraviolet effect, and the UV protection factor UPF can be more than doubled compared with ordinary viscose fiber.
  • the antibacterial rate is not less than 90%, and the antipruritic effect on the skin is good.
  • Preparation method of calamine containing 10. 0wt% mother liquor In the stainless steel kettle, add 20Kg of calamine, add 180Kg of water, stir, mix, and set aside.
  • the above mother liquor is continuously blended with the spinning viscose in a pre-spinning syringe, and the blending ratio is the weight ratio of a-cell (the cellulose) and the weight of the calamine powder in the mother liquor according to the total weight of the fiber.
  • 1 : 0. 02 simultaneously enter the R535A spinning machine (or R535, R535A semi-continuous spinning machine and continuous spinning machine) for spinning.
  • the falling silk cake is then subjected to pressure washing (or rinsing) post-treatment for desulfurization, water washing, pickling, bleaching, water washing, oiling, dehydration, drying, into a cylinder, that is, the above-mentioned calamine viscose filaments are obtained.
  • the above mother liquor is blended with the dissolved viscose in a dissolving machine, and the blending ratio is 1:0 by weight of the total weight of the fiber in the weight of the ⁇ -Cell (the cellulose) and the weight of the calamine powder in the mother liquor.
  • the blend is stirred, filtered, vacuum defoamed, matured, and spun into a viscose staple fiber spinning machine.
  • the spun-formed tow is subjected to short fiber post-treatment for desulfurization, water washing, pickling, bleaching, water washing, oiling, cutting, drying, and packaging to obtain the above-mentioned calamine viscose staple fiber.
  • the fiber of the invention has soft hand feeling and delicate skin, and can play the functions of antibacterial, anti-mildew, anti-odor, conditioning skin and body health.
  • the invention combines the health care function of calamine with the use of textiles and has broad development prospects.

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Artificial Filaments (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)

Abstract

La présente invention concerne une fibre de viscose contenant de la calamine, son procédé de préparation et d'utilisation. La fibre de viscose contient 1% à 6% de poudre de calamine sous forme de matière sèche. La fibre de viscose contenant de la calamine procure non seulement l'avantage de présenter la nature, la dégradabité, la flexibilité et la grande qualité de teinture de la viscose, mais présente également une fonction médicinale et hygiénique, de multiples activités biologiques, et sert à améliorer la vitalité cellulaire, peut éliminer le voile et la rougeur, peut restreindre l'humidité et la tuméfaction, et présente simultanément deseffets comprenant la résistance aux rayons ultraviolets, l'inhibition bactérienne et les soins de la peau.
PCT/CN2007/002027 2006-06-29 2007-06-28 Fibre de viscose contenant de la calamine, son procédé de préparation et d'utilisation WO2008003243A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN200610036344.3 2006-06-29
CNB2006100363443A CN100507100C (zh) 2006-06-29 2006-06-29 炉甘石粘胶纤维及其制备方法和应用

Publications (1)

Publication Number Publication Date
WO2008003243A1 true WO2008003243A1 (fr) 2008-01-10

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10072050B2 (en) 2008-12-24 2018-09-11 Emd Millipore Corporation Caustic stable chromatography ligands
CN116602820A (zh) * 2023-05-23 2023-08-18 江苏宝姿实业有限公司 一种柔软透气成人护理垫及其制备工艺

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100507100C (zh) * 2006-06-29 2009-07-01 福建众和股份有限公司 炉甘石粘胶纤维及其制备方法和应用
CN101280471B (zh) * 2008-04-23 2011-09-28 华东理工大学 一种含有超细炉甘石微粒的纤维
CN101851803B (zh) * 2010-05-28 2012-08-08 新乡化纤股份有限公司 一种保健功能粘胶纤维及其制备方法
CN101985781B (zh) * 2010-10-19 2012-03-28 山东海龙股份有限公司 炉甘石纤维素纤维的制备方法
CN102383223B (zh) * 2011-09-22 2014-05-07 福建众和股份有限公司 高强力炉甘石海藻纤维及其制备方法和应用
CN102828298A (zh) * 2012-08-20 2012-12-19 肖晖 一种和田玉纱线及其制备方法
CN115969740A (zh) * 2023-02-07 2023-04-18 珠海朗祺生物科技有限公司 一种含有炉甘石的防护隔离霜及其制备方法

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JPH09170110A (ja) * 1995-10-09 1997-06-30 Nobuhide Maeda 抗菌性、脱臭性および防虫性を有すると共に、遠赤外線放射特性を有するレーヨンの製造方法
JPH09209225A (ja) * 1995-11-27 1997-08-12 Nobuhide Maeda 抗菌性、脱臭性および防虫性を有すると共に、遠赤外線放射特性を有する複合レーヨンと牛乳蛋白繊維とを混紡または交撚して紡糸する加工糸の製造方法
JPH09310235A (ja) * 1996-03-18 1997-12-02 Nobuhide Maeda 抗菌性、脱臭性、防カビ性および防虫性を有すると共に、遠赤外線放射特性を有する複合レーヨンと絹繊維とを混紡または交撚して紡糸する加工糸の製造方法
CN1401831A (zh) * 2001-08-27 2003-03-12 武汉纳宝新技术有限责任公司 含有纳米粉末材料的功能性人造棉
CN1804158A (zh) * 2005-12-26 2006-07-19 天津市赛远保健品有限公司 炉甘石功能纤维及其制造方法
CN1876905A (zh) * 2006-06-29 2006-12-13 福建众和股份有限公司 炉甘石粘胶纤维及其制备方法和应用

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JPH0465510A (ja) * 1990-07-02 1992-03-02 Bio Giken:Kk 抗菌性レーヨン材の製造方法
JPH0860431A (ja) * 1994-08-22 1996-03-05 Nobuhide Maeda 抗菌性および脱臭性を有すると共に、遠赤外線放射特性を有するレーヨンの製造方法
JPH09170110A (ja) * 1995-10-09 1997-06-30 Nobuhide Maeda 抗菌性、脱臭性および防虫性を有すると共に、遠赤外線放射特性を有するレーヨンの製造方法
JPH09209225A (ja) * 1995-11-27 1997-08-12 Nobuhide Maeda 抗菌性、脱臭性および防虫性を有すると共に、遠赤外線放射特性を有する複合レーヨンと牛乳蛋白繊維とを混紡または交撚して紡糸する加工糸の製造方法
JPH09310235A (ja) * 1996-03-18 1997-12-02 Nobuhide Maeda 抗菌性、脱臭性、防カビ性および防虫性を有すると共に、遠赤外線放射特性を有する複合レーヨンと絹繊維とを混紡または交撚して紡糸する加工糸の製造方法
CN1401831A (zh) * 2001-08-27 2003-03-12 武汉纳宝新技术有限责任公司 含有纳米粉末材料的功能性人造棉
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CN1876905A (zh) * 2006-06-29 2006-12-13 福建众和股份有限公司 炉甘石粘胶纤维及其制备方法和应用

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10072050B2 (en) 2008-12-24 2018-09-11 Emd Millipore Corporation Caustic stable chromatography ligands
CN116602820A (zh) * 2023-05-23 2023-08-18 江苏宝姿实业有限公司 一种柔软透气成人护理垫及其制备工艺
CN116602820B (zh) * 2023-05-23 2023-10-13 江苏宝姿实业有限公司 一种柔软透气成人护理垫及其制备工艺

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CN1876905A (zh) 2006-12-13
CN100507100C (zh) 2009-07-01

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