WO2007022243A3 - Bidentate catalyst for olefin polymerization, methods of forming such and products therefrom - Google Patents

Bidentate catalyst for olefin polymerization, methods of forming such and products therefrom Download PDF

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Publication number
WO2007022243A3
WO2007022243A3 PCT/US2006/031949 US2006031949W WO2007022243A3 WO 2007022243 A3 WO2007022243 A3 WO 2007022243A3 US 2006031949 W US2006031949 W US 2006031949W WO 2007022243 A3 WO2007022243 A3 WO 2007022243A3
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WO
WIPO (PCT)
Prior art keywords
methods
forming
olefin polymerization
products therefrom
groups
Prior art date
Application number
PCT/US2006/031949
Other languages
French (fr)
Other versions
WO2007022243A2 (en
Inventor
Abbas Razavi
Vladimir Marin
Margarito Lopez
Original Assignee
Fina Technology
Abbas Razavi
Vladimir Marin
Margarito Lopez
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fina Technology, Abbas Razavi, Vladimir Marin, Margarito Lopez filed Critical Fina Technology
Priority to EP06801604A priority Critical patent/EP1915383A2/en
Publication of WO2007022243A2 publication Critical patent/WO2007022243A2/en
Publication of WO2007022243A3 publication Critical patent/WO2007022243A3/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1825—Ligands comprising condensed ring systems, e.g. acridine, carbazole
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/12—Olefin polymerisation or copolymerisation
    • B01J2231/122—Cationic (co)polymerisation, e.g. single-site or Ziegler-Natta type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/46—Titanium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/48—Zirconium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/49—Hafnium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

Bidentate catalyst systems and the methods or forming such are described herein. The catalyst systems generally are compounds having the general formula: where R, R1, R2 and R3 are optional and independently selected from hydrogen, C1 to C20 alkyl groups or C6 to C20 aryl groups, A' and A' are independently selected from coordination groups, M is a Group 4 or 5 transition metal, X is selected from halogens, alkyl groups, aromatic groups or combinations thereof and n is less than 4.
PCT/US2006/031949 2005-08-18 2006-08-16 Bidentate catalyst for olefin polymerization, methods of forming such and products therefrom WO2007022243A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP06801604A EP1915383A2 (en) 2005-08-18 2006-08-16 Bidentate catalyst for olefin polymerization, methods of forming such and products therefrom

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11/206,895 2005-08-18
US11/206,895 US7301040B2 (en) 2005-08-18 2005-08-18 Bidentate catalyst for olefin polymerization, methods of forming such and products therefrom

Publications (2)

Publication Number Publication Date
WO2007022243A2 WO2007022243A2 (en) 2007-02-22
WO2007022243A3 true WO2007022243A3 (en) 2007-12-13

Family

ID=37758332

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2006/031949 WO2007022243A2 (en) 2005-08-18 2006-08-16 Bidentate catalyst for olefin polymerization, methods of forming such and products therefrom

Country Status (3)

Country Link
US (1) US7301040B2 (en)
EP (1) EP1915383A2 (en)
WO (1) WO2007022243A2 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2536735B1 (en) * 2010-02-19 2018-08-01 Dow Global Technologies LLC Metal-ligand complexes and catalysts

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6800774B2 (en) * 2000-12-25 2004-10-05 Changchun Institute Of Applied Chemistry Chinese Academy Of Science Catalysts used for olefine polymerization and the preparation thereof

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6096676A (en) 1997-07-02 2000-08-01 Union Carbide Chemicals & Plastics Technology Corporation Catalyst for the production of olefin polymers
US6103657A (en) 1997-07-02 2000-08-15 Union Carbide Chemicals & Plastics Technology Corporation Catalyst for the production of olefin polymers
DE10107045A1 (en) 2001-02-13 2002-08-14 Basf Ag Process for the polymerization of olefins
KR100440480B1 (en) 2001-08-31 2004-07-14 주식회사 엘지화학 Catalyst for olefin polymerization and method for preparing polyolefins
US6562930B2 (en) 2001-09-18 2003-05-13 Cornell Research Foundation, Inc. Bis(salicylaldiminato)titanium complex catalysts, highly syndiotactic polypropylene by a chain-end control mechanism, block copolymers containing this
US6831187B2 (en) 2001-12-18 2004-12-14 Univation Technologies, Llc Multimetallic catalyst compositions for the polymerization of olefins
JP4481820B2 (en) 2002-08-19 2010-06-16 ザ ユニバーシティ オブ ホンコン Polyolefin catalyst components utilizing non-covalent interactions
WO2004069881A1 (en) 2003-02-07 2004-08-19 Basell Polyolefine Gmbh Polymerization catalysts, organic transition metal compounds, process for preparing polyolefins and polyolefins

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6800774B2 (en) * 2000-12-25 2004-10-05 Changchun Institute Of Applied Chemistry Chinese Academy Of Science Catalysts used for olefine polymerization and the preparation thereof

Also Published As

Publication number Publication date
WO2007022243A2 (en) 2007-02-22
US7301040B2 (en) 2007-11-27
US20070043184A1 (en) 2007-02-22
EP1915383A2 (en) 2008-04-30

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