WO2007018015A1 - インドール化合物、光学フィルター及び光学記録材料 - Google Patents
インドール化合物、光学フィルター及び光学記録材料 Download PDFInfo
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- WO2007018015A1 WO2007018015A1 PCT/JP2006/314229 JP2006314229W WO2007018015A1 WO 2007018015 A1 WO2007018015 A1 WO 2007018015A1 JP 2006314229 W JP2006314229 W JP 2006314229W WO 2007018015 A1 WO2007018015 A1 WO 2007018015A1
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- -1 Indole compound Chemical class 0.000 title claims abstract description 140
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- PZOUSPYUWWUPPK-UHFFFAOYSA-N indole Natural products CC1=CC=CC2=C1C=CN2 PZOUSPYUWWUPPK-UHFFFAOYSA-N 0.000 title claims abstract description 36
- RKJUIXBNRJVNHR-UHFFFAOYSA-N indolenine Natural products C1=CC=C2CC=NC2=C1 RKJUIXBNRJVNHR-UHFFFAOYSA-N 0.000 title claims abstract description 36
- 230000003287 optical effect Effects 0.000 title claims description 126
- 239000000463 material Substances 0.000 title claims description 33
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- 125000000217 alkyl group Chemical group 0.000 claims abstract description 23
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- 125000004093 cyano group Chemical group *C#N 0.000 claims abstract description 5
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- 150000003053 piperidines Chemical class 0.000 description 1
- 125000003386 piperidinyl group Chemical group 0.000 description 1
- 238000009832 plasma treatment Methods 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920001084 poly(chloroprene) Polymers 0.000 description 1
- 229920001643 poly(ether ketone) Polymers 0.000 description 1
- 229920003207 poly(ethylene-2,6-naphthalate) Polymers 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
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- 239000011116 polymethylpentene Substances 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 150000008442 polyphenolic compounds Chemical class 0.000 description 1
- 235000013824 polyphenols Nutrition 0.000 description 1
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- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- GLGXXYFYZWQGEL-UHFFFAOYSA-M potassium;trifluoromethanesulfonate Chemical compound [K+].[O-]S(=O)(=O)C(F)(F)F GLGXXYFYZWQGEL-UHFFFAOYSA-M 0.000 description 1
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 description 1
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- 239000010948 rhodium Substances 0.000 description 1
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- 238000007761 roller coating Methods 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 239000012488 sample solution Substances 0.000 description 1
- 229910052706 scandium Inorganic materials 0.000 description 1
- SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 description 1
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- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- 229910052715 tantalum Inorganic materials 0.000 description 1
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- 150000003624 transition metals Chemical class 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- ITMCEJHCFYSIIV-UHFFFAOYSA-N triflic acid Chemical compound OS(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-N 0.000 description 1
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- 239000010937 tungsten Substances 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
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- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/20—Filters
- G02B5/22—Absorbing filters
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D209/02—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom condensed with one carbocyclic ring
- C07D209/04—Indoles; Hydrogenated indoles
- C07D209/10—Indoles; Hydrogenated indoles with substituted hydrocarbon radicals attached to carbon atoms of the hetero ring
- C07D209/14—Radicals substituted by nitrogen atoms, not forming part of a nitro radical
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
- C07D401/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
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- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
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- G11B7/2478—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing dyes methine or polymethine dyes oxonol
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- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
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- G11B7/248—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing dyes porphines; azaporphines, e.g. phthalocyanines
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- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
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- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
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- G11B7/256—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of layers improving adhesion between layers
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- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
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Definitions
- the present invention relates to novel indole compounds, optical filters and optical recording materials.
- the indole compound is useful as an optical element or the like.
- the indole compound is particularly useful as an ultraviolet light absorber to be contained in an optical filter for an image display device, and is high in wavelength by a low energy laser or the like having wavelengths in the visible and near infrared regions. It is useful for an optical recording material used for an optical recording medium capable of high density optical recording and reproduction.
- Optical recording media are in widespread use because they have excellent characteristics such as large recording capacity and non-contact recording or reproduction.
- WORM high definition optical disks
- CD-R compact disc-read-only optical disks
- DVD-R write-once optical disks
- the laser is focused to a minute area of the optical recording layer, the properties of the optical recording layer are changed, and recording is performed. Reproduction is performed according to the difference in light intensity.
- the wavelength of the semiconductor laser used for recording and reproduction is 750 to 830 nm for CD-R and 620 nm to 690 nm for DVD-R, but a further increase in capacity is realized.
- An optical disc using a very short wavelength laser is under study, for example, one using a light of 380 to 420 nm as a recording light is under consideration.
- an azo compound is reported in Patent Document 1
- a porphyrin compound is reported in Patent Document 2
- a metal complex of a triazole compound is reported in Patent Document 3.
- these compounds do not necessarily match the absorption wavelength characteristics as an optical recording material used to form an optical recording layer.
- an image display apparatus such as a liquid crystal display (LCD), a plasma display panel (PDP), an electroluminescent display (ELD), a cathode ray tube display (CRT), a fluorescent display tube, and a field emission display.
- LCD liquid crystal display
- PDP plasma display panel
- ELD electroluminescent display
- CRT cathode ray tube display
- fluorescent display tube a fluorescent display tube
- field emission display a field emission display.
- Optical filter for the wavelength of 300-390 nm Compounds that absorb light are used as ultraviolet light absorbers.
- Patent Document 4 reports a filter for an organic EL display element that contains an ultraviolet light absorber and blocks light of 200 to 410 nm.
- the UV absorber used in the filter for an organic EL display device is not necessarily suitable as an UV absorber for an optical filter, as to its absorption wavelength characteristics.
- Patent Document 1 Japanese Patent Application Laid-Open No. 2004-209771
- Patent Document 2 Japanese Patent Application Laid-Open No. 2004-58365
- Patent Document 3 Japanese Patent Application Laid-Open No. 2004-174838
- Patent Document 4 Japanese Patent Application Laid-Open No. 2004-102223
- an object of the present invention is, in particular, a compound having optical properties suitable for an optical filter for an image display device and an optical element used for an optical recording material for an optical recording medium for short wavelength laser light.
- the present invention has been made based on the above findings, and it is an indole compound represented by the following general formula (I), an optical filter comprising the indole compound, and a substrate Further, the present invention provides an optical recording material comprising the indole compound used for the optical recording layer of the optical recording medium having the optical recording layer formed thereon.
- R 1 and R 2 are each independently a hydrogen atom or a hydrocarbon group having 1 to 30 carbon atoms Or a substituent represented by the following general formula ( ⁇ ), wherein R 3 and R 4 are each independently an alkyl group having 1 to 10 carbon atoms, an alkoxy group having 1 to 10 carbon atoms, or the number of carbon atoms R 6 represents an aryl group of 6 to 30, and R 5 represents R 7 and R 8 each independently represent a hydrogen atom, a hydrocarbon group having 1 to 30 carbon atoms, a halogen atom, a hydroxyl group, a nitro group, a cyano group, NHR or NR′R ′ ′, R, R ′ and R ', Each independently represents an alkyl group having 1 to: carbon atom, and R' and R ', may combine with each other to form a ring; R 5 and R 6 , R 6 and R 7 , R 7 and R 8 may be linked to each other to form a ring An q
- R a to R ′ each independently represent a hydrogen atom or an alkyl group having 1 to 6 carbon atoms, and the methylene group in the alkyl group may be substituted with O 2 or —CO 2!
- Z represents a direct bond or an alkylene group having 1 to 8 carbon atoms which may have a substituent
- the methylene group in the alkylene group is one o-, one S-, one CO-, one coo- , One oco-, -so
- Examples of the hydrocarbon group having 1 to 30 carbon atoms represented by R 5 , R 6 , R 7 and R 8 include methyl, ethyl, propyl, isopropyl, butyl, sec-butyl, sec-butyl, tert-butyl, isobutyl and amyl , Isoamyl, tertiary amyl, hexyl, cyclohexyl, cyclohexylmethyl, 2-cyclohexyl Norechinole, Heptole Nore, Iso-Heptole Nore, Third-Heptole Nore, N-Octinole, Iso-Octinole, Third-Octyl, 2-Ethyl Hexyl, Noel, Isonoel, Decyl, Dodecyl, Tridecyl, Tetradecyl, Penta
- these groups may be substituted with one or more selected alkoxy, alkenyl, and cyano groups selected from alkoxy, alkenyl, nitro, cyano, halogen atoms and the like. In such a case, the total number of carbon atoms including these substituents is at most 30.
- alkyl group having 1 to: carbon atoms represented by R 4 , R, R ′ and R ′ ′ in the above general formula (I) methyl, ethyl, propyl, isopropyl, butyl, sec-butyl and the like can be mentioned.
- alkoxy group having 1 to 10 carbon atoms include methyloxy, ethyloxy, isopropyloxy, propyloxy and And the like.
- Examples of the aryl group having 6 to 30 carbon atoms include phenyl, naphthyl, 2-methylphenyl and the like. 3-methyl cellulose 4-methyl cellulose 4-butyl cellulose 3-isopropyl cellulose 4-isopropyl cellulose 4 butyl cellulose 4 butyl cellulose 4 isobutyl cellulose 4 tert-butyl ether -4-, 4-hydroxyphenyl, 4-alkoxyphenyl, 4- (2-ethylhexyl) phenyl, 4-stearyl gel, 2, 3-dimethylphenyl Le, 2,4 Dimethylphenyl, 2,5 Dimethylphenyl, 2,6 Dimethylphenyl, 3,4 Dimethylphenyl, 3,5 Dimethylphenyl, 2,4 Di-tert-butylphenyl, 2,5 Di-tert-butyl Hue Nil, 2,6 di-tert-butylphenyl, 2,4 di-tert-pentylphenyl, 2,5-di-tertiary
- Examples of the halogen atom represented by R 5 , R 6 , R 7 and R 8 in the above general formula (I) include fluorine, chlorine, bromine and iodine.
- the ring R 'and R are formed by linking in the general formula (I), the piperidine ring, piperidines Rajin ring, pyrrolidine ring, Morufuorin ring and the like, R 5 and the ring R 6, R 6 and R 7 and R 7 and R 8 are formed by connecting, cyclobutene ring, cyclopentene ring, cyclohexene ring cyclohexane, benzene ring, a pyridine ring, and the like.
- alkyl group having 1 to 4 carbon atoms represented by the above general formula (II) examples include methyl, ethyl, propyl, isopropyl, butyl, sec-butyl, tert-butyl, isobutyl, methoxy, Ethoxy, propyloxy, isopropyloxy, methoxymethyl, tetramethyl, 2-methoxyethyl, 2-acetyl, acetyl, 1-carbonylethyl, acetylmethyl, 1-carbonylpropyl, 2-oxobutyl, 2-acetylethyl, 1-carbonylisopropyl, etc.
- the optionally substituted alkylene group having 1 to 8 carbon atoms exemplified are methylene, ethylene, propylene, methylethylene, butylene, 1-methylpropylene, 2 methylpropylene, 1,2 dimethylpropylene , 1, 3 Dimethyl Lopylene, 1-Methylbutylene, 2-Methylbutylene, 3-Methylbutylene, 4-Methylbutylene, 2,4 Dimethylbutylene, 1,3 Dimethylbutylene, Pentylene, Hexylene, Heptylene, Heptylene, Otylene, Ethane 1, 1-Diyl, Propane 2, 2 —Diyl, ethenylene, propenylene, methyleneoxyl, ethyleneoxyl, oxymethylene, thiomethylene, carbonylmethylene, carbonyloxymethylene, methylenecarbonyloxyl, sulfolmethylene, aminomethylene, acetylethylated ethylene car
- examples of the a-on represented by An q — include, as monovalent, chlora-on, bromine-on, iodine-on and fluorine-on.
- Inorganics such as halogen halides such as perchlorate, chlorate, cyanocyanide, phosphorus hexafluoride, antimony hexafluoride, and boron tetrafluoride Benzenesulfonic acid, toluenesulfonic acid, trifluoromethanesulfonic acid, diphenylamine-1, 4-sulfonic acid, 2-amino-4-methyl-5-chlorobenzene Organic sulfonic acid ions such as sulfonic acid ions, 2-amino-5-thiobenzenesulfonic acid ions; octyl phosphate ions, octyl phosphate ions, dodecyl phosphate ions, octadec
- valence examples include benzenedisulfonic acid and naphthalenedisulfonic acid.
- valence has a function to de-excite (taunting) active molecules in the excited state.
- phenothiene having a carboxyl group, phosphonic acid group, sulfonic acid group or other anionic group in the chaer-one or cyclopentagel ring, meta-portane compound anion such as luteothene, etc. It can be used accordingly.
- quencher-on examples include the following general formulas (A) and (B) or the following formulas
- R 9 and R 1Q are each independently a halogen atom, an alkyl group having 1 to 8 carbon atoms, an aryl group having 6 to 30 carbon atoms, or SO 2
- G represents an alkyl group, an aryl group which may be substituted with a halogen atom, a dialkylamino group, a diallylamino group, a piperidino group or a morpholino group, and a and b each represent 0 to 4 Represent.
- R u , R 12 , R 13 and R 14 each independently represent an alkyl group, an alkyl phenyl group, an alkoxy phenyl group or a halogenated phenyl group.
- R 1 is a hydrocarbon group having 1 to 30 carbon atoms, particularly an alkyl group having 1 to 8 carbon atoms or 6 to 13 carbon atoms.
- R 2 is a hydrogen atom or a hydrocarbon group having 1 to 30 carbon atoms, particularly a hydrogen atom, an alkyl group having 1 to 8 carbon atoms or an aryl group having 6 to 13 carbon atoms
- R 3 is an alkyl group having 1 to 10 carbon atoms, particularly an alkyl group having 1 to 4 carbon atoms
- R 4 is an alkyl group having 1 to 10 carbon atoms, in particular 1 to 4 carbon atoms Alkyl groups are preferred because they are excellent in cost and optical properties.
- indole compound of the present invention include the following compound Nos. 1 to 24.
- the method for producing the indoleyl compound of the present invention represented by the above general formula (I) is not particularly limited, and the compound can be obtained by a method utilizing a well-known reaction. Examples of such a method include, in the case of obtaining an indoleyl compound having a monovalent a-ion, a synthesis method such as the route shown in the following [6].
- the indole compound of the present invention is useful as an optical element that exerts a function by absorbing light of a specific wavelength, particularly a wavelength of 320 to 420 nm.
- an optical element examples thereof include an ultraviolet absorber to be contained in an optical filter, and an optical recording agent used for forming an optical recording layer of an optical recording medium such as an optical disk.
- the indoleyl compound of the present invention can also be used as a synthetic intermediate for pharmaceuticals, agricultural chemicals, perfumes, dyes, etc., or as various functional materials.
- the optical filter according to the present invention contains the indoil compound according to the present invention. Since the indol compound of the present invention has an absorption maximum wavelength at 340 to 390 nm and can absorb and block ultraviolet light of 410 nm or less and a part of visible light, the indol compound of the present invention contains the indole compound of the present invention.
- the optical filter according to the invention is particularly suitable as an optical filter for an image display device used for high quality display images.
- the optical filter of the present invention can be used not only for image display devices, but also for various applications such as for analyzers, for manufacturing semiconductor devices, for astronomical observation, for optical communication, for ophthalmic lenses and the like.
- the optical filter of the present invention is usually disposed on the front of the display.
- an optical filter according to the present invention may be attached directly to the surface of the display, and a front plate may be provided in front of the display, in which case the front side (outside) or back side (display side) of the front plate You may paste it on
- each layer such as an undercoat layer, an antireflective layer, a hard coat layer, a lubricating layer, etc.
- a transparent support As a typical constitution of the optical filter of the present invention, one in which each layer such as an undercoat layer, an antireflective layer, a hard coat layer, a lubricating layer, etc. is provided on a transparent support, as needed.
- Examples of the method of incorporating an optional component such as the indole compound of the present invention, dye compounds other than the indole compound of the present invention, and various types of stabilizers into the optical filter of the present invention include: (1) transparent support or (2) a transparent support or an optional method of coating on each layer, (3) a transparent support and an adhesive layer between any two adjacent layers selected from any layer (4) a method of providing a light absorbing layer containing a light absorbing agent such as an indole compound of the present invention separately from each layer, and the like.
- the amount of use of the indoil compound of the present invention is usually 1 to: LOOOmg / m 2 , preferably 5 to: LOOmg Zm 2 per unit area of the optical filter, lmg Zm 2 If the amount used is less than 2 , the light absorption effect can not be fully exhibited, and if it is used beyond 1 OOOmg Zm 2 , the color of the filter becomes too strong, and the display item is displayed. There is a possibility that the quality etc. may be lowered, and furthermore, the brightness may be lowered.
- the indole compound of the present invention is usually used as follows in order to bring the amount used per unit area of the optical filter into the above-mentioned range.
- the indolyl compound of the present invention is preferably used per 100 parts by mass of the adhesive such as an acrylic adhesive.
- a varnish is prepared by adding 0.05 to 0.01 parts by mass of a solvent such as methyl ethyl ketone and preferably 40 to 500 parts by mass, and the varnish is subjected to easy adhesion treatment.
- a transparent support such as a PET film The composition is coated and cured to obtain an optical filter having an adhesive layer (cured film) with a thickness of 0.1 to 10 microns.
- the material of the transparent support examples include inorganic materials such as glass; diacetyl cellulose, triacetinolecenorulose (TAC), propio-norecenoreulose, butyrinoresenorellose, acetinole propio-norecenolose Polyphenols; Polycarbonate; polyethylene terephthalate, polyethylene naphthalate, polyethylene terephthalate, poly 1,4-dimethyl hexane dimethylene terephthalate, polyethylene 1,2 diphenoxetane 4,4 '-Dicarboxylate, polyesters such as polybutylene terephthalate; polystyrenes; polyolefins such as polyethylene, polypropylene and polymethylpentene; acrylic resins such as polymethylmetatalylate; polycarbonates; Sulfone; polyethersulfones; polyether ketone; polyetherimides; Porioki Shiechiren, and polymer materials such
- An infrared absorber, inorganic fine particles and the like can be added to these transparent supports, and the transparent supports can be subjected to various surface treatments.
- inorganic fine particles examples include layered clay mineral, silicon dioxide, titanium dioxide, and sulfur. Acid, calcium carbonate and the like.
- the various surface treatments described above include, for example, chemical treatment, mechanical treatment, corona discharge treatment, flame treatment, ultraviolet irradiation treatment, high frequency treatment, glow discharge treatment, active plasma treatment, laser one treatment, mixed acid treatment And ozone oxidation treatment.
- the subbing layer is a layer used between the transparent support and the light absorbing layer in the case of providing a light absorbing layer containing a light absorbing agent.
- the subbing layer is a layer containing a polymer having a glass transition temperature of ⁇ 60 to 60 ° C., a layer having a rough surface on the light absorbing layer side, or a layer containing a polymer having an affinity to the polymer of the light absorbing layer.
- the undercoat layer is provided on the surface of the transparent support on which the light absorption layer is not provided, and the adhesion between the transparent support and the layers (for example, the antireflective layer and the hard coat layer) provided thereon.
- the thickness of the undercoat layer is 2 ⁇ ! -20 m preferred 5 nm-5 ⁇ m more preferred 20 nm-2 ⁇ m even more preferred 50 nm-1 ⁇ m even more preferred 80 ⁇ ⁇ ! -300 nm is most preferred.
- a primer layer comprising a polymer having a glass transition temperature of ⁇ 60 to 60 ° C. adheres to the polymer and bonds the transparent support to the filter layer. Polymers having a glass transition temperature of ⁇ 60 to 60 ° C.
- the glass transition temperature is preferably 50 ° C. or less, more preferably 40 ° C. or less, still more preferably 30 ° C. or less, and further preferably 25 ° C. or less It is most preferable that the temperature be below 20 ° C. which is preferable.
- the modulus of elasticity of the subbing layer at 25 DEG C.
- the undercoat layer having a rough surface on the light absorption layer side bonds the transparent support to the light absorption layer by forming the light absorption layer on the rough surface.
- the subbing layer whose surface on the light absorbing layer side is rough can be easily formed by application of a polymer latex.
- the average particle diameter of the latex is preferably 0.2 to 3 / ⁇ ⁇ ⁇ ⁇ , and more preferably 0.05 to 1 / ⁇ ⁇ .
- acrylic resin, cellulose derivative, gelatin And casein, starch, polybutyl alcohol, soluble nylon, and polymer latex As a polymer having an affinity to the binder polymer of the light absorption layer, acrylic resin, cellulose derivative, gelatin And casein, starch, polybutyl alcohol, soluble nylon, and polymer latex.
- the optical filter of the present invention may be provided with two or more subbing layers.
- the undercoat layer may be added with a solvent for swelling the transparent support, a matting agent, a surfactant, an antistatic agent, a coating aid, a hardener and the like.
- a low refractive index layer is essential.
- the refractive index of the low refractive index layer is lower than the refractive index of the above-mentioned transparent support.
- the refractive index of the low refractive index layer is preferably 1.20 to L55, and more preferably 1.30 to L50.
- the thickness of the low refractive index layer is more preferably 50 to 400 nm, preferably 50 to 400 nm.
- the low refractive index layer is a layer comprising a fluorine-containing polymer having a low refractive index (JP-A-57-34526, JP-A-3-130103, JP-A-6-115023, JP-A-8-313702, JP-A-7- 16800 4, each layer obtained by a sol-gel method (as described in JP-A-5-208811, JP-A-6-299091, JP-A-7-168003), or a layer containing fine particles (Japanese Patent Publication No. No. 59250, JP-A-5-13021, JP-A-6-56478, JP-A-7-92306 and JP-A-9-288201).
- voids can be formed in the low refractive index layer as microvoids between the fine particles or in the fine particles.
- the layer containing fine particles further preferably has a porosity of 5 to 35% by volume, which preferably has a porosity of 3 to 50% by volume.
- a layer having a high refractive index may be laminated to the above-mentioned antireflective layer.
- the refractive index of the high refractive index layer is 1.65-2.40.
- the refractive index of the middle refractive index layer is adjusted to be an intermediate value between the refractive index of the low refractive index layer and the refractive index of the high refractive index layer.
- the refractive index of the middle refractive index layer is preferably 1. 50 to: L 90 and more preferably 1. 55 to: L 70.
- the thickness of the medium-high refractive index layer is preferably 5 10 ⁇ to 100 / ⁇ , more preferably 10 ⁇ to 10 / ⁇ m, and most preferably 30 ⁇ to 1 / ⁇ preferable. Most preferably, the haze of the medium-high refractive index layer is 1% or less, more preferably 3% or less, which is preferably 5% or less.
- the medium 'high refractive index layer can be formed using a polymer binder having a relatively high refractive index.
- polymers with high refractive index examples include polystyrene and styrene copolymerization And polycarbonate, melamine resin, phenol resin, epoxy resin, polyurethane obtained by the reaction of cyclic (alicyclic or aromatic) isocyanate and polyol, and the like.
- Polymers having other cyclic (aromatic, heterocyclic or alicyclic) groups and polymers having a halogen atom other than fluorine as a substituent also have a high refractive index. It is also possible to use a polymer formed by the polymerization reaction of monomers in which a double bond is introduced to enable radical curing.
- inorganic fine particles may be dispersed in the above-mentioned polymer binder.
- the refractive index of the inorganic fine particles is preferably 1.80 to 2.80.
- the inorganic fine particles are preferably formed of metal oxides or sulfides.
- metal oxides or sulfides titanium oxide (eg, mixed crystals of rutile, rutile Z anatase, anatase, amorphous structure), tin oxide, indium oxide, zinc oxide, zirconium oxide, sulfur oxide Lead and the like can be mentioned.
- titanium oxide, tin oxide and indium oxide are particularly preferable.
- the inorganic fine particles contain oxides or sulfides of these metals as main components, and can further contain other elements.
- the main component means a highest content (Weight 0/0) among the components constituting the particles.
- Other elements include Ti, Zr, Sn, Sb, Cu, Fe, Mn, Pb, Cd, As, Cr, Hg, Zn, Al, Mg, Si, P, S and the like.
- An inorganic material which is film-forming and dispersible in a solvent, or is itself a liquid such as alkoxides of various elements, salts of organic acids, coordination complexes bonded with coordination complexes (for example, It is also possible to form a medium-high refractive index layer by using a chelating agent, an active inorganic polymer.
- the surface of the antireflective layer can be provided with an antiglare function (a function of preventing incident light from being scattered on the surface to prevent a scene around the film from migrating to the film surface).
- an antiglare function a function of preventing incident light from being scattered on the surface to prevent a scene around the film from migrating to the film surface.
- an antiglare function a function of preventing incident light from being scattered on the surface to prevent a scene around the film from migrating to the film surface.
- an antiglare function a function of preventing incident light from being scattered on the surface to prevent a scene around the film from migrating to the film surface.
- the hard coat layer has a height higher than the hardness of the transparent support.
- the hard coat layer preferably comprises a crosslinked polymer.
- the hard coat layer is made of an acrylic, urethane, epoxy polymer, oligomer or monomer (eg, UV curable) It can be formed using a resin) or the like. Silica-based materials also form a hard coat layer.
- a lubricating layer may be formed on the surface of the above-mentioned antireflection layer (low refractive index layer).
- the lubricating layer has a function of imparting slipperiness to the surface of the low refractive index layer and improving scratch resistance.
- the lubricating layer can be formed using a polyorganosiloxane (eg, silicone oil), a natural wax, a petroleum wax, a metal salt of a higher fatty acid, a fluorine-based lubricant or a derivative thereof, or the like.
- the thickness of the lubricating layer is preferably 2 to 20 nm.
- the indole compound of the present invention can be used as it is, or a ndinder can be used.
- a binder for example, natural polymer materials such as gelatin, casein, starch, cellulose derivatives, alginic acid or polymethyl methacrylate, polybul butyral, polybul pyrrolidone, polyvinyl alcohol, polyvinyl chloride, styrene butadiene copolymer, Synthetic high molecular weight materials such as polystyrene, polycarbonate, polyamide, polyurethane, polyester, and polyurethane are used.
- the undercoat layer, the antireflective layer, the hard coat layer, the lubricating layer, the light absorbing layer, etc. can be formed by a general coating method.
- a coating method dip coating method, air knife coating method, curtain coating method, roller coating method, wire bar coating method, gravure coating method, estrudel coat method using a hopper (described in US Pat. No. 2,681,294) Etc.
- Two or more layers may be formed by simultaneous application. With respect to the simultaneous application method, for example, each specification of US Pat. No. 2761791, US Pat. No. 2941898, US Pat. No. 3508947, US Pat. No. 3,526,528 and Yuji Harasaki "Coating Engineering” p. 253 (1974 Asakura, Japan). Described in the bookstore issue).
- the optical recording material of the present invention contains the indole compound of the present invention and is used to form an optical recording layer of an optical recording medium, and various kinds of the optical recording material according to the light absorption characteristics of the contained indole compound. It can be applied to optical recording media.
- the optical recording materials of the present invention it is particularly suitable for an optical disc for short wavelength lasers with a wavelength of 380 nm to 420 nm that the indole compound contained has the maximum absorption wave in light absorption characteristics in solution state. It has a long max in the range of 320 to 420 nm.
- the absorption intensity if ⁇ at max is smaller than 1.
- OX 10 4 there is a possibility that the recording sensitivity may be lowered, therefore 1.0 ⁇ 10 4 or more is preferable.
- the measurement of ⁇ max and ⁇ in the solution state of the above-mentioned indole complex can be carried out by selecting the concentration of the sample solution, the solvent used for the measurement and the like according to a conventional method.
- the method for forming the optical recording layer of the optical recording medium using the optical recording material of the present invention containing the above-mentioned indole compound is not particularly limited.
- lower alcohols such as methanol and ethanol
- ether alcohols such as methyl seport sorb, ethyl seport sorb, butyl seport sorb and butyl diglycol
- acetone methyl ethyl ketone, methyl isobutyl ketone, cyclohexanone, diacetone Ketones
- alcohol, esters such as ethyl acetate, butyl acetate, methoxyethyl acetate, etc .
- acrylic esters such as ethyl acrylate, butyl acrylate etc., 2, 2, 3, 3-tetrafluoropropanoe
- Indole compounds of the present invention and various kinds of organic solvents such as fluorinated alcohols such as benzene; toluene; hydrocarbons such as
- the above optical recording layer is formed as a thin film, and the thickness thereof is usually 0.000 to 1: LO / z m, and preferably in the range of 0.01 to 5 ⁇ m.
- the content of the indole compound of the present invention in the optical recording material of the present invention is preferably 10% by mass to LOO% by mass in the solid content contained in the optical recording material of the present invention. It is preferable that the above optical recording layer is formed to contain 50 to 100% by mass of the indole compound represented by the above general formula (I) in the optical recording layer.
- the optical recording material of the present invention comprises the indole compound represented by the above general formula (I), based on the solid content contained in the optical recording material of the present invention. More preferably, containing 100% by mass.
- the optical recording material of the present invention may contain, in addition to the indole compound of the present invention, if necessary, a cyanine compound, an azo compound, a phthalocyanine compound, an oxanol compound, Squarylium compounds, styryl compounds, porphine compounds, azlenium compounds, croco-ttamethine compounds, pyrilium compounds, thiopyrylium compounds, triallylmethane compounds, diphenylmethane compounds, tetrahydrocholine compounds, indole choline compounds
- Compounds that can be used for ordinary optical recording layers such as anthracene compounds, naphthoquinone compounds, xanthene compounds, thiazine compounds, atalidine compounds, oxazine compounds, spiropyran compounds, fluorene compounds, rhodamine compounds, etc.
- the optical recording material of the present invention is an aromatic-trosoxy compound, an ammonium compound, an imidazole compound, a bisimidazole compound, a transition metal chelate as a quencher such as singlet oxygen. It may contain a compound or the like, or may use quan- teranion. In the optical recording material of the present invention, these various composites are preferably used in an amount of 0 to 50% by mass in the solid content contained in the optical recording material of the present invention. .
- the material of the above-mentioned base on which such an optical recording layer is formed is not particularly limited as long as it is substantially transparent to the writing (recording) light and the reading (reproducing) light.
- Chil metatalylate, resins such as polyethylene terephthalate and polycarbonate, glass and the like are used. Also, depending on the application, any shape such as tape, drum, belt, disk, etc. can be used.
- gold, silver, aluminum, copper or the like can be used to form a reflective film by a vapor deposition method or a sputtering method, or an acrylic resin or an ultraviolet curing property.
- the protective layer can also be formed by resin or the like.
- the reaction solution was cooled to room temperature, gradually added dropwise to a 500 ml aqueous solution of 23.5 g (127 mmol) of potassium hexafluorophosphate, and stirred at room temperature for 1 hour.
- the precipitate was separated by filtration and dried to obtain 16.2 g (yield 99.4%) of a brown solid. It was confirmed that the obtained brown solid was Compound No. 21, which is the target substance. Obtained
- the analysis results for Compound No. 21 are shown below.
- a UV varnish was prepared by the following composition, and the UV varnish was applied by means of a bar coater # 9 to a 188 ⁇ m-thick PET film which was treated to be easily adhered, and then dried at 100 ° C. for 10 minutes. After that, ultraviolet light was irradiated with lOOmJ with a high pressure mercury lamp with an infrared ray cut film filter to obtain an optical filter having a film layer (pressure-sensitive adhesive layer) having a cured film thickness of about 5 microns on a PET film. When this optical filter was measured by JASCO Corporation UV-visible near-infrared spectrophotometer V-570, ⁇ max was 353 nm.
- a UV varnish was prepared by the following composition, and the UV varnish was applied by means of a bar coater # 9 to a 188 ⁇ m-thick PET film which was treated to be easily adhered, and then dried at 100 ° C. for 10 minutes. After that, ultraviolet light was irradiated with 100 mOg with a high pressure mercury lamp with an infrared ray cut film filter to obtain an optical filter having a film layer with a cured film thickness of about 5 microns on a PET film. When this optical filter was measured using an ultraviolet visible near infrared spectrophotometer V-570 manufactured by JASCO Corporation, the max was 354 nm.
- Example 12 Production of Optical Recording Material and Optical Recording Medium, and Evaluation of Optical Recording Medium
- concentration of the compound No. 4 in the compound No. 4 obtained in the above production example 4 is 1.0 mass%.
- This material was dissolved to obtain an optical recording material as a 2, 2, 3, 3-teraphanolol propanol solution.
- a filter using the indole compound of the present invention has an absorption maximum at a specific wavelength (340 to 390 nm) (Examples 10 and 11), and is suitable as a UV absorber for an optical filter was confirmed.
- An optical recording medium having an optical recording layer formed of an optical recording material containing the indole compound of the present invention has an absorption maximum of reflected light at a specific wavelength (340 to 390 nm).
- Example 12 In the reproduction mode of the optical recording medium represented by the optical disc, the presence or absence of recording is detected from the difference in the light quantity of the laser wavelength for the reflected light that reflects the laser light to the optical recording medium. In the absorption spectrum of the above, it is more preferable to show a large absorption intensity in the vicinity of the wavelength of the laser light. Therefore, the optical recording material of the present invention containing the indole compound of the present invention is used for forming an optical recording layer of an optical recording medium using a 405 nm laser beam such as an optical disk for short wavelength laser. Is preferred.
- the light resistance evaluation was performed on the compounds No. 21, No. 23 and No. 24 obtained in Examples 7 to 9 and the comparative compound 1.
- a compound of the present invention is dissolved in 2, 2, 3, 3- tetrafluoropropanol to 1% by mass to prepare a 2, 2, 3, 3- tetrafluoropropanol solution,
- the obtained solution was applied on a polycarbonate plate of 20 2011 11 111 for 2000 ⁇ 111 in 60 seconds by spin coating to prepare a test piece.
- the evaluation was carried out by irradiating the test piece with light of 55000 lux, irradiating each for 24 hours and 150 hours, and then measuring the absorbance residual rate at ⁇ max of the UV absorption spectrum before irradiation.
- the present invention can provide a novel indole compound suitable as an optical element.
- an optical filter using the indoil compound is suitable as an optical filter for an image display device, and an optical recording material containing the indoli compound is a light of an optical recording medium. It is suitable for forming a magnetic recording layer.
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- Optics & Photonics (AREA)
- Optical Filters (AREA)
- Optical Record Carriers And Manufacture Thereof (AREA)
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Abstract
Description
Claims
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KR1020087002962A KR101354109B1 (ko) | 2005-08-11 | 2006-07-19 | 인돌화합물, 광학필터 및 광학기록 재료 |
DE602006016619T DE602006016619D1 (de) | 2005-08-11 | 2006-07-19 | Indolverbindung, optischer filter und material für optische aufzeichnung |
CN2006800292395A CN101238100B (zh) | 2005-08-11 | 2006-07-19 | 吲哚化合物、滤光器以及光学记录材料 |
JP2007529470A JP5046936B2 (ja) | 2005-08-11 | 2006-07-19 | インドール化合物、光学フィルター及び光学記録材料 |
EP06781236A EP1921063B1 (en) | 2005-08-11 | 2006-07-19 | Indole compound, optical filter and optical recording material |
US11/996,502 US7923091B2 (en) | 2005-08-11 | 2006-07-19 | Indole compound, optical filter and optical recording material |
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KR20210041568A (ko) * | 2018-08-09 | 2021-04-15 | 스미또모 가가꾸 가부시키가이샤 | 수지 및 점착제 조성물 |
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JP2002234259A (ja) * | 2001-02-14 | 2002-08-20 | Ricoh Co Ltd | 光記録媒体及びこれを用いる光記録方法 |
JP2003237233A (ja) | 2002-02-15 | 2003-08-27 | Mitsubishi Chemicals Corp | 光学記録媒体及び記録方法 |
JP2003313447A (ja) | 2002-04-19 | 2003-11-06 | Ind Technol Res Inst | インドールスチリル化合物およびこれを用いた高密度記録媒体 |
JP2004058365A (ja) | 2002-07-26 | 2004-02-26 | Matsushita Electric Ind Co Ltd | 光記録媒体および製造方法 |
JP2004102223A (ja) | 2002-07-15 | 2004-04-02 | Fuji Photo Film Co Ltd | 有機elディスプレイ素子用フィルター |
JP2004174838A (ja) | 2002-11-26 | 2004-06-24 | Fuji Photo Film Co Ltd | 光情報記録媒体および情報記録方法 |
JP2004209771A (ja) | 2002-12-27 | 2004-07-29 | Fuji Photo Film Co Ltd | 光情報記録媒体 |
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US6558768B2 (en) * | 2000-03-07 | 2003-05-06 | Ricoh Company, Ltd. | Optical recording medium and optical recording and reading method using the same |
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2006
- 2006-07-19 KR KR1020087002962A patent/KR101354109B1/ko not_active IP Right Cessation
- 2006-07-19 EP EP06781236A patent/EP1921063B1/en not_active Expired - Fee Related
- 2006-07-19 WO PCT/JP2006/314229 patent/WO2007018015A1/ja active Application Filing
- 2006-07-19 CN CN2006800292395A patent/CN101238100B/zh not_active Expired - Fee Related
- 2006-07-19 DE DE602006016619T patent/DE602006016619D1/de active Active
- 2006-07-19 US US11/996,502 patent/US7923091B2/en not_active Expired - Fee Related
- 2006-07-19 JP JP2007529470A patent/JP5046936B2/ja not_active Expired - Fee Related
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Also Published As
Publication number | Publication date |
---|---|
EP1921063A1 (en) | 2008-05-14 |
EP1921063B1 (en) | 2010-09-01 |
TWI376369B (ja) | 2012-11-11 |
JP5046936B2 (ja) | 2012-10-10 |
JPWO2007018015A1 (ja) | 2009-02-19 |
US7923091B2 (en) | 2011-04-12 |
CN101238100A (zh) | 2008-08-06 |
EP1921063A4 (en) | 2009-07-15 |
US20090092782A1 (en) | 2009-04-09 |
CN101238100B (zh) | 2011-06-22 |
KR20080042810A (ko) | 2008-05-15 |
KR101354109B1 (ko) | 2014-01-22 |
TW200720251A (en) | 2007-06-01 |
DE602006016619D1 (de) | 2010-10-14 |
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