WO2006131138A1 - Method for making a sound-insulating load-bearing floor - Google Patents
Method for making a sound-insulating load-bearing floor Download PDFInfo
- Publication number
- WO2006131138A1 WO2006131138A1 PCT/EP2005/006260 EP2005006260W WO2006131138A1 WO 2006131138 A1 WO2006131138 A1 WO 2006131138A1 EP 2005006260 W EP2005006260 W EP 2005006260W WO 2006131138 A1 WO2006131138 A1 WO 2006131138A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- sound
- insulating material
- load
- bearing floor
- making
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D119/00—Coating compositions based on rubbers, not provided for in groups C09D107/00 - C09D117/00
- C09D119/003—Precrosslinked rubber; Scrap rubber; Used vulcanised rubber
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F15/00—Flooring
- E04F15/12—Flooring or floor layers made of masses in situ, e.g. seamless magnesite floors, terrazzo gypsum floors
- E04F15/14—Construction of joints, e.g. dividing strips
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F15/00—Flooring
- E04F15/18—Separately-laid insulating layers; Other additional insulating measures; Floating floors
- E04F15/20—Separately-laid insulating layers; Other additional insulating measures; Floating floors for sound insulation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C08L23/0853—Vinylacetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C08L23/0869—Acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
Definitions
- the present invention relates to a method for making a sound-insulating load-bearing floor.
- the present invention relates to a method for making a sound-insulating load-bearing floor, said method comprising the step of applying onto said load-bearing floor a sound-insulating material including at least one rubber in a subdivided form and at least one binding agent .
- the present invention also relates to a sound-insulating material including at least one rubber in a subdivided form and at least one binding agent .
- the present invention also relates to a building structure including at least one load-bearing floor, said load-bearing floor comprising a sound-insulating material including at least one rubber in a subdivided form and at least one binding agent.
- a sound-insulating material on the load-bearing floor of the upper floors.
- the sound-insulating material minimizes the pressure of sound generated into a room and traveling downward through the load-bearing floor. Sound- insulating material functions by reflecting sound waves, absorbing sound waves, and/or disrupting sound waves.
- Conventional sound-insulating materials comprise preformed sheets of cork, asphalt, or other materials such as, for example, foamed polyethylene or foamed polyurethane .
- said sound insulating materials may show some disadvantages .
- the asphalt typically comprises about 80% by weight of tar, the remainder including clay, solvents, and other fillers.
- One disadvantage of the asphalt is that upon aging, it tends to harden. It also hardens in cold weather. When asphalt hardens, it tends to crack if the floor expands or contracts (e.g. as a consequence of temperatures changes) .
- cork comprises a matrix of particles pressed together, the cork also tends to develop cracks if the floor expands or contracts (e.g. as a consequence of temperatures changes) .
- Other sound-insulating materials have been already suggested in the art .
- International Patent Application WO 02/48.478 relates to a light soundproof floor-filling structure for filling the space between a floor surface and the level of the laying plane of the walking-on floor covering.
- Said soundproof floor-filling structure consists of a mixture of concrete as air-hardening binder and a given amount of grains of resin materials which may be selected from polyvinyl resins, polyethylene, polypropylene, polyvinylchloride, caoutchouc, rubbers in general, polycarbons, silicon resins, plastics of different kinds.
- Metal elements such as copper and tin may be present as either pure metal or alloys.
- the abovementioned structure is said to have the following features: lightness, soundproofing, compactness, workability, mechanical strength and environmental compatibility.
- International Patent Application WO 00/26485 relates to an acustic insulating material with a filler which is mainly made of granules of a sound-deadening component, mixed with a binding agent , such that an almost coherent mass is formed.
- Said filler mainly contains rubber granules.
- Said binding agent is made on the basis of polyurethane and preferably consists of a polyurethane glue.
- a sound-insulating sprung floor provided with the abovementioned insulating material and resting on a load- bearing floor, and a method for making such a floor, are also disclosed.
- French Patent Application FR 2,221,465 relates to a material made from waste rubber particles, in particular waste rubber particles derived from tyres, and a synthetic elastomeric binding agent, preferably a moisture-hardening
- ⁇ isocyanate or polyisocyanate or a two-component polyurethane Said binding agent is of cellular structure and fills only partly the spaces between the rubber particles.
- the abovementioned material is said to be suitable as a floor underlay.
- International Patent Application WO 00/50707 relates to a solid paste which can be applied with a trowel to form regularly spaced striae, comprising an adhesive-type elastomeric resin forming 50%-70% of the volume of the paste, 30-90 mesh rubber granules forming 30%-50% of the volume of the paste, all of which is mixed with air to produce a foam.
- the adhesive is water-based.
- the rubber granules come from recycled tyres which are shredded into granules and ground.
- a method of application of said solid paste comprising the following steps: take a container with the adhesive-type elastomeric resin superposed on rubber granules in a suspension in the air, insert a mechanical mixer and agitate for two to five minutes in order to form a homogeneous emulsion containing air, rubber and resin, apply the product to a hard surface using an adhesive comb in order to form said striae and wedge tiles on top of the striae.
- the abovementioned solid paste is said to have sound-insulating properties.
- the sound-insulating materials as described above may have some disadvantages.
- the sound-insulating materials has low sound- insulating properties because of the stiffness of the concrete.
- the use of isocyanates or polyisocyanates as binding agents has to be avoided because of the toxicity of said substances which leads to risks for both the environment and the health of the operators.
- isocyanates, polyisocyanates or polyurethanes may release cyanidric acid.
- a water-based adhesive-type elastomeric resin when a water-based adhesive-type elastomeric resin is used, problems related to its stability may arise.
- the elastomeric resin may coagulate so forming a non-homogeneous adhesive mixture: the presence of coagulums may negatively affect the sound- insulating properties of said adhesive mixture.
- the Applicant has now found that it is possible to make a sound-insulating load-bearing floor by applying onto said load-bearing floor a sound-insulating material including at least one rubber in a subdivided form and at least one binding agent, said binding agent comprising at least one water-dispersible polymer.
- Said sound-insulating material has good sound-insulating properties. Furthermore, said sound-insulating material maintains its sound-insulating properties upon aging. Moreover, said sound-insulating material has a reduced dynamic stiffness, in particular, a dynamic stiffness, measured according to standard ISO 9052-1:1989, lower than 150 MN/m 3 . Said sound-insulating material also shows vibration damping properties. Furthermore, said sound-insulating material shows a good compression resistance after drying. Additionally, the binding agent used in said sound- insulating material does not contain harmful substances and does not release harmful substances in the case of fire.
- the present invention relates to a method for making a sound-insulating load- bearing floor, said method comprising the following steps: - providing a load-bearing floor; applying a sound-insulating material onto said load- bearing floor so as to form a substantially continuous coating layer; allowing said substantially continuous coating layer to dry; wherein said sound-insulating material includes: from 40% by weight to 95% by weight, preferably from 60% by weight to 90% by weight, with respect to the total weight of the sound-insulating material, of at least one rubber in a subdivided form; from 5% by weight to 60% by weight, preferably from 10% by weight to 40% by weight, with respect to the total weight of the sound-insulating material, of at least one binding agent comprising at least one water- dispersible polymer having a glass transition temperature (T 9 ) of from -50 0 C to +5O 0 C, preferably of from -40 0 C to + 10 0 C.
- T 9 glass transition temperature
- said step of applying a sound-insulating material further comprises the step of making pre-formed sheets of said sound insulating material .
- said sound- insulating material is applied directly in contact with said load-bearing floor.
- at least one intermediate layer is interposed between the load-bearing floor and the sound-insulating material.
- said method further comprises the step of applying a covering floor onto said load-bearing floor.
- said covering floor is applied onto said sound-insulating material .
- said sound-insulating material is applied onto said covering floor.
- said method further comprises the step of applying a protective foil onto said sound-insulating material.
- a protective foil may be selected, for example, from: polyethylene sheets, paper sheets, nylon sheets, woven- nonwoven sheets .
- the present invention also relates to a sound-insulating material including: from 40% by weight to 95% by weight, preferably from 60% by weight to 90% by weight, with respect to the total weight of the sound-insulating material, of at least one rubber in a subdivided form; from 5% by weight to 60% by weight, preferably from
- the present invention also relates to a building structure including at least one load-bearing floor, said load-bearing floor comprising a sound-insulating material including: from 40% by weight to 95% by weight, preferably from 60% by weight to 90% by weight, with respect to the total weight of the sound-insulating material, of at least one rubber in a subdivided form; from 5% by weight to 60% by weight, preferably from
- said sound insulating material has, in a dry form, a dynamic stiffness measured according to standard ISO 9052-1:1989, lower than 150 MN/m 3 , preferably lower than 100 MN/m 3 , more preferably of from 10 MN/m 3 to 80 MN/m 3 .
- said sound-insulating material has, in a dry form, a noise index (L) , which is a measure of its sound-insulating properties, measured according to standard ISO 140-8:1997, on a sample of said sound-insulating material having a 10 mm thickness, not higher than 65 dB, preferably not higher than 63 dB .
- L noise index
- said sound- insulating material form a substantially continuous coating layer having a thickness of from 5 mm to 50 mm, preferably of from 7 mm to 30 mm.
- Said sound-insulating material may be made according to different processes.
- the process for making a sound-insulating material is carried out by mixing, at a temperature of from -2O 0 C to +60 0 C, preferably of from +5°C to +40 0 C, for a time of from 10 seconds to 4 hours, preferably of from 60 seconds to 30 minutes, said at least one rubber in a subdivided form with said binding agent, obtaining a homogeneous sound- insulating material.
- the obtained homogeneous sound- insulating material may be collected in hermetic buckets or tanks and stored for further use .
- the above reported mixing step is carried out not more than 48 hours, preferably from 5 minutes to 24 hours, before the step of applying said sound-insulating material.
- Said mixing step may be carried out manually for example in a bucket, or in different mixing devices such as, for example, concrete mixer, cement mixer, concrete pump, cement pump, plaster sprayer.
- the step of applying a sound-insulating material may be carried according to different ways. According to one preferred embodiment, the step of applying a sound-insulating material is carried out by spreading (for example, by means of a trowel) said sound- insulating material onto said load-bearing floor. - a -
- the step of applying a sound-insulating material is carried out by spraying said sound-insulating material onto said load- bearing floor.
- said sound-insulating material is made and applied "in situ" by: spreading said at least one rubber in a subdivided form onto said load-bearing floor; - spraying the binding agent over said spreaded rubber in a subdivided form obtaining a sound-insulating material, said sound-insulating material forming a substantially continuous coating layer.
- said continuous coating layer has a drying time, at 23 0 C, of from 10 minutes to 72 hours, preferably of from 30 minutes to 24 hours .
- said sound-insulating material may be previuosly shaped as pre-formed sheets which will be subsequently applied onto said load-bearing floor.
- Said pre-formed sheets may be obtained by means of different processes.
- said pre-formed sheets may be obtained by means of a process comprising: - mixing said at least one rubber in a subdivided form and said at least one binding agent in a mixing device so as to obtain a homogeneous mixture; pouring the obtained homogeneous mixture into a die; keeping the homogeneous mixture into said die at a temperature and for a time sufficient to to obtain a substantially dry pre-formed sheets.
- the gaps optionally present between adjacent pre-formed sheets may be filled with suitable materials, e.g. with a binding agent or with a sound-insulating material, preferably the same used to make the pre-formed sheets according to the - y -
- the rubber in a subdivided form which may be used in the present invention is in the form of powder or granules having a particle size in the range of from 0.1 mm to 15 mm, preferably of from 1.0 mm to 10 mm.
- the rubber in a subdivided form may be selected, for example, from diene elastomeric polymers or copolymers which may be of natural origin or may be obtained by solution polymerization, emulsion polymerization or gas-phase polymerization of one or more conjugated diolefins, optionally blended with at least one comonomer selected from monovinylarenes and/or polar comonomers in an amount of not more than 60% by weight.
- the diene elastomeric polymers or copolymers may be selected, for example, from: cis-1,4- polyisoprene (natural or synthetic, preferably natural rubber), 3 , 4-polyisoprene, polybutadiene (in particular polybutadiene with a high 1,4-cis content), optionally halogenated isoprene/isobutene copolymers, 1,3- butadiene/acrylonitrile copolymers, styrene/1, 3 -butadiene copolymers, styrene/isoprene/l, 3 -butadiene copolymers, styrene/1 , 3 -butadiene/acrylonitrile copolymers, or mixtures thereof.
- the rubber in a subdivided form may be selected from elastomeric polymers of one or more monoolefins with olefinic comonomers or derivatives thereof.
- said elastomeric polymers may be selected, for example, from: ethylene/propylene copolymers
- said rubber in a subdivided form may be obtained from a waste rubber derived from the rubber manufacturing processes. More preferably, said rubber in a subdivided form is a vulcanized rubber which may be - ⁇ -
- the vulcanized rubber in a subdivided form may be obtained by mechanical grinding at ambient temperature or in the presence of a cryogenic coolant (i.e. liquid nitrogen) .
- a cryogenic coolant i.e. liquid nitrogen
- Said vulcanized rubber in a subdivided form may comprise at least one crosslinked diene elastomeric polymer or copolymer, said diene elastomeric polymer or copolymer being selected from those above reported; or at least one crosslinked elastomeric polymer of one or more monoolefins with an olefinic comonomer or derivatives thereof, said elastomeric polymer being selected from those above reported; or mixtures thereof.
- said water- dispersible polymer is used in the form of an aqueous dispersion.
- said aqueous dispersion comprises from 30% by weight to 90% by weight, preferably from 40% by weight to 70% by weight, with respect to the total weight of the aqueous dispersion, of at least one water- dispersible polymer.
- said aqueous dispersion has a Brookfield viscosity, measured at 23 0 C and at 250 rpm, of from 0.2 Pa. s to 60 Pa. s, preferably of from 0.5 Pa . s to 30 Pa. s.
- Brookfield viscosity is measured using a viscosimeter of Brookfield type, model DV3 , equipped with a RV6 spindle.
- said aqueous dispersion has a minimum film-forming temperature lower than or equal to 10 0 C, preferably of from -10 0 C to +5°C. Said mimimum film-forming temperature is measured according to standard ISO 2115:1996.
- said water- dispersible polymer may be selected from polymers having a main hydrocarbon chain to which hydrophilic groups are linked.
- polymers having a main hydrocarbon chain to which hydrophilic groups are linked it is meant a polymer wherein hydrophilic groups, either directly or through side groups, are linked to the main hydrocarbon chain, which may be either linear or branched.
- hydrophylic groups groups which are able to bind water molecules by means of hydrogen bonds .
- said polymers having a main hydrocarbon chain to which hydrophilic groups are linked may be selected from:
- At least one aliphatic vinyl ether monomer or copolymers obtained by the polymerization of an ethylenically unsaturated carboxylic acid monomer or a derivative thereof such as anhydrides, esters or salts, with at least one aliphatic vinyl ester monomer, or with at least one aliphatic vinyl ether monomer;
- terpolymers obtained by the polymerization of at least one aliphatic or aromatic olefinic monomer, with at least one ethylenically unsaturated carboxylic acids monomer or a derivative thereof such as anhydrides, esters or salts, and with at least one aliphatic vinyl ester monomer or with at leat one aliphatic vinyl ether monomer; or mixtures thereof.
- the ethylenically unsaturated carboxylic acid monomer or a derivative thereof may be selected, for example, from: (meth) acrylic acid, maleic acid, fumaric acid, itaconic acid, ethacrylic acid, crotonic acid, citraconic acid cinnamic acid, maleic anhydride, methyl hydrogen fumarate, benzyl hydrogen maleate, butyl hydrogen maleate, octyl hydrogen itaconate, dodecyl hydrogen citraconate, methyl (meth) acrylate, ethyl (meth) acrylate, propyl (meth) acrylate, • butyl (meth) acrylate, hexyl (meth) acrylate, 2-ethylhexyl (meth) acrylate, octyl
- (meth) acrylate benzyl (meth) acrylate, butyl fumarate, butyl maleate, octyl maleate, or mixtures thereof.
- Acrylic acid, methacrylic acid, or a derivative thereof, or mixtures thereof, are particularly preferred.
- (meth) acrylates which may be selected, for example, from: ethylene glycol monoester of (meth) acrylic acid, propylene glycol monoester of (meth) acrylic acid, glycidyl
- (meth) acrylate hexanediol di (meth) acrylate, methoxymethyl (meth) acrylate, ethoxymethyl (meth) acrylate, esters of (meth) acrylic acid with polyoxyethylene glycol or polyoxypropylene glycol , (meth) acryloyl compounds having a polyoxyalkylene structure, or mixtures thereof.
- the aliphatic vinyl ester monomer may be selected, for example, from: vinyl formate, vinyl acetate, vinyl propionate, vinyl butyrate, vinyl caproate, vinyl caprylate, vinyl laurate, vinyl stearate, vinyl octylate, vinyl heptanoate, vinyl pelargonate, vinyl-3,6- dioxaheptanoate, vinyl-3, 6, 9-trioxaundecanoate, vinyl ester of versatic. acid, or mixtures thereof.
- Vinyl acetate is particularly preferred.
- the aliphatic vinyl ether monomer may be selected, for example, from: methyl vinyl ether, ethyl vinyl ether, propyl vinyl ether, butyl vinyl ether, t-amyl vinyl ether, or mixtures thereof. Methyl vinyl ether is particularly preferred.
- the aliphatic or aromatic olefinic monomer may be selected, for example, from: - aliphatic olefins containing from 2 to 20 carbon atoms such as, for example, ethylene, propylene, 1,3- butadiene, 1-octene, or mixtures thereof; ethylene is particularly preferred; aromatic olefins containing from 8 to 20 carbon atoms such as, for example, styrene, p-acetoxystyrene, vinyltoluene, ⁇ -methylstyrene, vinyl benzoate, N-vinyl pyrrolidone, vinyl pyridine, or mixtures thereof; styrene is particularly preferred.
- comonomers which may optionally be used according to the present invention, may be selected from polar mononers such as, for example: vinyl chloride, vinyl sulfonate, vinyl silane, vinylidene chloride, nitriles or amides, such as, for example, acrylonitrile, acrylamide, or mixtures thereof.
- polar mononers such as, for example: vinyl chloride, vinyl sulfonate, vinyl silane, vinylidene chloride, nitriles or amides, such as, for example, acrylonitrile, acrylamide, or mixtures thereof.
- said comonomers are present in the polymer in an amount not higher than or equal to 5% by weight, with respect to the total weight of the polymer .
- homopolymers (i) which may be advantageously used according to the present invention are: poly (meth) acrylic acid, polyalkylacrylamide, polyhydroxyalkylate, polyalkylacrylate, polyvinylacetate, polyvinylalcohol, or mixtures thereof.
- copolymers (ii) which may be advantageously used according to the present invention are: vinylacetate/ethylene copolymers, vinylacetate/alkyl- acrylate copolymers, ethylene/alkylacrylate copolymers, vinylacetate/vinylversatate copolymers , vinylacetate/butylmaleate copolymers, styrene/acrylate copolymers, styrene/acrylic acid/ copolymers, or mixtures thereof .
- terpolymers (iii) which may be advantageously used according to the present invention are: vinylacetate/ethylene/acrylate terpolymers, vinylalcohol/ethylene/vinylacetate terpolymers, or mixtures thereof .
- the aqueous dispersion according to the present invention may be prepared by polymerization of monomers emulsified in water using conventional emulsion polymerization procedures.
- the aqueous dispersion according to the present invention may further comprise protective colloids such as, for example, polyvinyl alcohol, polyvinyl acetate, polyvinyl pirrolidone, polyethylene-glycol distearate, hydroxypropyl methylcellulose, hydroxyethyl cellulose, or mixtures thereof.
- protective colloids such as, for example, polyvinyl alcohol, polyvinyl acetate, polyvinyl pirrolidone, polyethylene-glycol distearate, hydroxypropyl methylcellulose, hydroxyethyl cellulose, or mixtures thereof.
- the polyvinyl alcohol which may be advantageously used according to the present invention, may be a modified polyvinylalcohol (such as, acetoacetylated polyvinyl alcohol) , a partially or completely saponified polyvinyl alcohol, or mixtures thereof .
- Said aqueous dispersion may further comprise surfactants.
- Suitable surfactants include non-ionic, anionic, cationic, surfactants, or mixtures thereof.
- Said surfactants may be selected, for example, from: octylphenoxy polyethoxy ethanol, polysiloxane copolymers, acetylenic alcohol or glycols or their ethoxylated derivatives; ethylene oxide/propylene oxide copolymers; or mixtures thereof .
- Said aqueous dispersion may comprise other commonly used additives which may be selected, for example, from: plasticizers such as, for example, polyethylene glycol, dibutyl phthalate, butyl benzyl phthalate, propylene glycol dibenzoate, triethylene glycol polyester of benzoic acid and phthalic acid, alkyd resin plasticizers; humectants such as, for example, glycerin, ethylene glycol, triethylene glycol, propylene glycol, urea, or mixtures thereof; filming aids and coalescing agents such as, for example, esters of lactic acid, 2-butoxy ethanol , esters of phthalic acid (for example, butyl octyl phathalate) , 2- (2-butoxy ethoxy) ethanol , ethylene glycol, dyethylene glycol, propylene glycol, diacetone alcohol, or mixtures thereof; or mixtures thereof.
- plasticizers such as, for example, polyethylene glycol
- Said aqueous dispersion may further comprise inorganic fillers such as, for example, sand, silica, calcium carbonate, calcium silicates, barium sulfates, talc, mica, carbon black, or mixtures thereof; pigments; dyes; antiseptic agents; antifoaming agents; or mixtures thereof .
- inorganic fillers such as, for example, sand, silica, calcium carbonate, calcium silicates, barium sulfates, talc, mica, carbon black, or mixtures thereof.
- solvents such as, for example, acetone, ethanol, or mixtures thereof, may be added.
- aqueous dispersions of homopolymers (i) , or copolymers (ii) , or terpolymers (iii) which may be used according to the present invention and which are commercialy available, are the products known as Vinavil , Ravemul " or Crilat " , from Vinavil, or Airflex from Air
- FIG. 1 represents a schematic cross section of a portion of a load-bearing floor comprising a coating layer made from the sound-insulating material according to an embodiment of the present invention.
- a sprung floor 1 is provided on top of a load-bearing floor 2 associated with the walls 5.
- Said sprung floor 1 comprises a covering floor 3 which rests on a coating layer 4 made from the sound-insulating material according to the present invention and which does not have any direct contact with said load-bearing floor 2 or with the walls 5.
- said coating layer 4 has a thickness of from 5 mm to 50 mm, more preferably of from 7 mm to 30 mm.
- the coating layer 4 is separated from the walls 5 by means of a stranding strip 6, said stranding strip 6 being usually made of a sound-insulating material such as, for example, polyethylene foam, polyurethane foam, rubber granules with a polyurthane glue as a binding agent.
- said stranding strip 6 may be made from the sound-insulating material according to the present invention.
- said coating layer 4 horizontally extends over the load-bearing floor 2 up against the surrounding walls 5 (not represented in Fig. 1) and the above-mentioned standing strip 6 rests on the edges of the coating layer 4 (not represented in Fig. 1) .
- the coating layer 4 extends both horizontally and vertically over the load-bearing floor 2 up against the surrounding walls 5 (not represented in Fig 1) .
- the stranding strip 6 vertically extends from the load-bearing floor 2 up to the covering floor 3 and it has a thickness of from 2 mm to 20 mm, preferably of from 3 mm to 10 mm.
- a protective foil 7 is provided over said coating layer 4 and it is folded up against the walls 5 on the edges of the sprung floor 1.
- the covering floor 3 is usually made from a hardened composition mainly comprising sand and cement, as is generally known for making fixed floors.
- a metal spot-welded wire netting (not represented in Fig. 1) is preferably inserted in the covering floor 3.
- Said covering floor 3 extends up to under the top edge of the above-mentioned standing strip 6 so that, consequently, there is no contact between the surrounding walls 5 and the covering floor 3.
- said covering floor has a thickness of from 2 cm to 10 cm, more preferably of from 4 cm to 6 cm. Depending on the expected load of the floor, this thickness may possibly be adjusted.
- the sprung-floor 1 comprises a covering floor 3 in the shape of a rigid plate whose perimeter is practically entirely enclosed by said standing strip 6 and a coating layer 4, whereby the whole rests on the fixed load-bearing floor 2.
- a layer of a finishing material 8 (such as, tiles, wood) , is placed.
- Preparation of the sound-insulating material 80% by weight (% by weight with respect to the total weight of the sound-insulating material) of a vulcanized rubber (ground waste rubber from scrap tyres having an average diameter of from 4 mm to 7 mm commercialized by Transeco s.r.l.) was mixed, under stirring, in a 5 liters becker, with 20% by weight (% by weight with respect to the total weight of the sound-insulating material) of the binding agent (the binding agent components are reported in Table 1 - the amounts are expressed in % by weight with respect to the total weight of the binding agent) , at room temperature (23 0 C), until a homogeneous dispersion was obtained.
- a vulcanized rubber ground waste rubber from scrap tyres having an average diameter of from 4 mm to 7 mm commercialized by Transeco s.r.l.
- Airflex EAF 60 (from Air Products) : aqueous dispersion comprising 60% of vinylacetate/ethylene/acrylate terpolymer having: a glass transition temperature (T 9 ) (referred to the terpolymer in a dry form) of -35°C; a Brookfield viscosity, measured at 23 0 C and at 250 rpm, of 9.4 Pa.
- T 9 glass transition temperature
- Brookfield viscosity measured at 23 0 C and at 250 rpm, of 9.4 Pa.
- Vinavil EVA 2615 M from Vinavil: aqueous dispersion comprising 52% of vinylacetate/ethylene copolymer having: a glass transition temperature (T 9 ) (referred to the copolymer in a dry form) of 19 0 C; a Brookfield viscosity, measured at 23 0 C and at 250 rpm, of 9.6 Pa. s; a minimum film-forming temperature of 2 0 C;
- Vinavil X 2428 (from Vinavil) : aqueous dispersion comprising 59% of vinylacrylate homopolymer having: a glass transition temperature (T 9 ) (referred to the homopolymer in a dry form) of -25 0 C; a Brookfield viscosity, measured at 23 0 C and at 250 rpm, of 10.5
- the Brookfield viscosity was measured at 23 0 C and at 250 rpm using a viscosimeter of Brookfield type, model DV3 , equipped with a RV6 spindle.
- the obtained data are the following:
- Example 2 13.6 Pa. s;
- Example 3 8.2 Pa. s. Minimum filming temperature
- the minimum filming temperature was measured according to standard ISO 2115:1996. The obtained data are the following:
- Example 2 2 0 C; - Example 3: 2 0 C.
- the mixture of Examples 2 and 3 were subjected to Differential Scanning Calorimetry (DSC) analysis in order to measure the glass transition temperatures.
- the DSC analysis was conducted as follows. First step: temperature scan: heating from -7O 0 C to +100 0 C with a heating rate of 20°C/min; temperature scan: cooling from +100 0 C to -70 0 C with a cooling rate of 20°C/min. Second step: temperature scan: heating from -100 0 C to +80 0 C with a heating rate of 20°C/min.
- the obtained data are the following: - Example 2: 19°C and -25 0 C (two peaks corresponding to the starting material) ;
- Example 3 19 0 C and -15°C (two peaks corresponding to the starting material) .
- the dynamic stiffness was measured according to standard ISO 9052-1:1989. To this aim, the so obtained sound-insulating material was spreaded over a polyethylene sheet and was allowed drying at room temperature (23 0 C), for 48 hours. A sample of the sound-insulating material having the following dimensions: 20 cm x 20 cm x 1 cm was removed from the above polyethylene sheet and was subjected to the dynamic stiffness measurement.
- the obtained sample was placed between two metal plates which were maintained at the following conditions: 23 0 C, 50% of humidity.
- the upper plate was a 8 kg load plate corresponding to a load of 200 kg/m 2 that is the typical weight of the load bearing floor.
- the plate was subjected to an impulse frequency of . from 50 Hz to 200 Hz: said impulse was generated by a generator and transferred to the upper plate by a shaker.
- the vibrational acceleration was measured by an accelerometer placed on the upper plate.
- the test was performed according to standard ISO 140- 8:1997.
Landscapes
- Engineering & Computer Science (AREA)
- Architecture (AREA)
- Chemical & Material Sciences (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Floor Finish (AREA)
- Mounting Of Bearings Or Others (AREA)
- Building Environments (AREA)
- Soundproofing, Sound Blocking, And Sound Damping (AREA)
- Laminated Bodies (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
Description
Claims
Priority Applications (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN200580050075XA CN101198756B (en) | 2005-06-10 | 2005-06-10 | Method for producing noise insulation material, bearing floor produced thereby and floor |
US11/921,862 US7861477B2 (en) | 2005-06-10 | 2005-06-10 | Method for making a sound-insulating load-bearing floor |
PCT/EP2005/006260 WO2006131138A1 (en) | 2005-06-10 | 2005-06-10 | Method for making a sound-insulating load-bearing floor |
AT05753112T ATE476569T1 (en) | 2005-06-10 | 2005-06-10 | METHOD FOR PRODUCING A SOUND-INSULATING LOAD-BEARING FLOOR AND SOUND-INSULATING MATERIAL |
DE602005022780T DE602005022780D1 (en) | 2005-06-10 | 2005-06-10 | METHOD FOR THE PRODUCTION OF A SOUND-INSULATING LOAD-BEARING SOIL AND SOUND-INSULATING MATERIAL |
JP2008515053A JP4757302B2 (en) | 2005-06-10 | 2005-06-10 | How to create a soundproof bearing floor |
CA002610963A CA2610963A1 (en) | 2005-06-10 | 2005-06-10 | Method for making a sound-insulating load-bearing floor |
ES05753112T ES2349939T3 (en) | 2005-06-10 | 2005-06-10 | PROCEDURE FOR MANUFACTURING A SOIL OF ACOUSTIC INSULATING LOAD SUPPORT AND ACOUSTIC INSULATING MATERIAL. |
EP05753112A EP1891285B9 (en) | 2005-06-10 | 2005-06-10 | Method for making a sound-insulating load-bearing floor and sound-insulating material |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/EP2005/006260 WO2006131138A1 (en) | 2005-06-10 | 2005-06-10 | Method for making a sound-insulating load-bearing floor |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2006131138A1 true WO2006131138A1 (en) | 2006-12-14 |
Family
ID=35911116
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2005/006260 WO2006131138A1 (en) | 2005-06-10 | 2005-06-10 | Method for making a sound-insulating load-bearing floor |
Country Status (9)
Country | Link |
---|---|
US (1) | US7861477B2 (en) |
EP (1) | EP1891285B9 (en) |
JP (1) | JP4757302B2 (en) |
CN (1) | CN101198756B (en) |
AT (1) | ATE476569T1 (en) |
CA (1) | CA2610963A1 (en) |
DE (1) | DE602005022780D1 (en) |
ES (1) | ES2349939T3 (en) |
WO (1) | WO2006131138A1 (en) |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2145797A3 (en) * | 2008-07-11 | 2010-12-08 | Maier, S. Coop. | Vehicle part provided with sound insulation comprising crumb rubber |
US8028800B2 (en) | 2009-04-10 | 2011-10-04 | Saint-Gobain Performance Plastics Rencol Limited | Acoustic damping compositions |
US8061478B2 (en) | 2008-05-06 | 2011-11-22 | Moderco Inc. | Acoustic face of polymer and embedded coarse aggregates and an acoustic panel assembly |
US8113495B2 (en) | 2005-05-02 | 2012-02-14 | Downey Paul C | Vibration damper |
US8240430B2 (en) | 2002-10-01 | 2012-08-14 | Downey Paul C | Noise and vibration mitigating mat |
WO2015051526A1 (en) | 2013-10-11 | 2015-04-16 | Dow Global Technologies Llc | Polymer mixture, multilayer article containing the same, and process of preparing the multilayer article |
US9637913B2 (en) | 2009-04-10 | 2017-05-02 | Saint-Gobain Performance Plastics Corporation | Acoustic damping compositions having elastomeric particulate |
EP3125233A4 (en) * | 2014-03-27 | 2017-10-25 | Mitsui Chemicals, Inc. | Sound insulator |
US9914011B2 (en) | 2015-06-25 | 2018-03-13 | Pliteq Inc. | Impact damping mat, equipment accessory and flooring system |
US10676920B2 (en) | 2015-06-25 | 2020-06-09 | Pliteq Inc | Impact damping mat, equipment accessory and flooring system |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2006105620A1 (en) * | 2004-06-25 | 2006-10-12 | Ferro (Belgium) S.P.R.L. | Acoustic sealant composition |
JP2011021451A (en) * | 2009-07-15 | 2011-02-03 | Kanazawa Seisakusho:Kk | Floor panel and floor panel assembly |
US8141321B2 (en) * | 2009-12-04 | 2012-03-27 | Young Robert H | Stair tread overlay and method |
TWI505930B (en) * | 2011-01-25 | 2015-11-01 | Ta Wei Chang | Multi-media acoustic material |
JP6313662B2 (en) * | 2014-05-30 | 2018-04-18 | 株式会社日本触媒 | Resin composition for vibration damping material |
US10933605B2 (en) * | 2016-07-22 | 2021-03-02 | The Gill Corporation | Vibration damping system |
CA2980564C (en) * | 2016-09-30 | 2024-05-07 | Pliteq Inc. | Sound control underlayment and floor construction incorporating the same |
CN106750700A (en) * | 2016-11-22 | 2017-05-31 | 深圳洛赛声学技术有限公司 | A kind of building floor preparation method of PU modified rubber particle cushion blockings |
US20190218795A1 (en) * | 2018-01-12 | 2019-07-18 | Hans-Erik Blomgren | Acoustically Absorptive Solid Volume Building Assembly |
KR102399896B1 (en) * | 2021-09-29 | 2022-05-18 | 차지연 | Versatile paint composition with improved thermal insulation and sound insulation properties |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2433617A1 (en) * | 1978-08-17 | 1980-03-14 | Caronor | Acoustic insulation of partitions - using layer of rubber particles bonded with phenolic resin |
DE4340478A1 (en) * | 1993-11-27 | 1995-06-01 | Dieter Arnds | Method and device for producing a sheet-like covering material and use as a floor and wall covering |
EP1001111A2 (en) * | 1998-11-10 | 2000-05-17 | Johannes Schulte | Impact sound-isolated floor |
US6200638B1 (en) * | 1997-04-08 | 2001-03-13 | William C. Ordway | Shock hardened flooring |
EP1375778A1 (en) * | 2002-06-21 | 2004-01-02 | Polynauve S.A.R.L. | Insulation material on the bases of recycled rubber and its use |
FR2852551A1 (en) * | 2003-03-21 | 2004-09-24 | Usines Gabriel Wattelez | Acoustic and/or vibration insulation material is made from a mixture of elastic particles and a plastomer resin, rolled into strips |
US20050050846A1 (en) * | 2003-09-08 | 2005-03-10 | Surace Kevin J. | Acoustical sound proofing material and methods for manufacturing same |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4010123A (en) * | 1972-04-06 | 1977-03-01 | Coal Industry (Patents) Limited | Cellular material |
DE2312666A1 (en) | 1973-03-14 | 1974-09-19 | Bayer Ag | MATERIAL FROM RUBBER WASTE, IN PARTICULAR FROM TIRE SCRAPS |
US4698249A (en) * | 1982-06-24 | 1987-10-06 | Brown John G | Modular-accessible-tiles providing accessibility to conductors and piping with improved sound isolation |
US4495240A (en) * | 1981-12-31 | 1985-01-22 | Usm Corporation | Heat-fusible-expandable mastic for automobile floor pans |
US4588634A (en) * | 1983-08-05 | 1986-05-13 | The Flintkote Company | Coating formulation for inorganic fiber mat based bituminous roofing shingles |
CA1322209C (en) * | 1988-05-18 | 1993-09-14 | Honda Giken Kogyo Kabushiki Kaisha (Also Trading As Honda Motor Co., Ltd .) | Automotive sound-proof materials and damping materials therefor |
US5093394A (en) * | 1988-09-27 | 1992-03-03 | Sheller-Globe Corporation | Thermoformable acoustical mat composition and method |
US5766754A (en) * | 1996-04-19 | 1998-06-16 | Badger Cork & Manufacturing Co. | Crack suppression and fracture resistant system |
BE1013514A6 (en) | 1998-11-04 | 2002-03-05 | Molenaers Ludovic | Acoustic insulation and suspended floor with such material. |
WO2000050707A1 (en) | 1999-02-25 | 2000-08-31 | Alain Verret | Acoustic adhesive for floors |
IT1315767B1 (en) | 2000-12-11 | 2003-03-18 | Isolcem Italia S R L | SOUNDPROOFING SCREED |
CN2498249Y (en) * | 2001-09-30 | 2002-07-03 | 郭文波 | Assembled elastic noise-absorption floor |
US6828020B2 (en) * | 2002-08-14 | 2004-12-07 | Adco Products, Inc. | Self-adhesive vibration damping tape and composition |
CN2658285Y (en) * | 2003-09-30 | 2004-11-24 | 张在东 | Building floor board with sound insulation device |
CN1560118A (en) * | 2004-03-10 | 2005-01-05 | 杰 郝 | Floor veneer board and manufacture method |
-
2005
- 2005-06-10 WO PCT/EP2005/006260 patent/WO2006131138A1/en active Application Filing
- 2005-06-10 CN CN200580050075XA patent/CN101198756B/en not_active Expired - Fee Related
- 2005-06-10 ES ES05753112T patent/ES2349939T3/en active Active
- 2005-06-10 JP JP2008515053A patent/JP4757302B2/en not_active Expired - Fee Related
- 2005-06-10 CA CA002610963A patent/CA2610963A1/en not_active Abandoned
- 2005-06-10 AT AT05753112T patent/ATE476569T1/en not_active IP Right Cessation
- 2005-06-10 EP EP05753112A patent/EP1891285B9/en not_active Not-in-force
- 2005-06-10 US US11/921,862 patent/US7861477B2/en not_active Expired - Fee Related
- 2005-06-10 DE DE602005022780T patent/DE602005022780D1/en active Active
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2433617A1 (en) * | 1978-08-17 | 1980-03-14 | Caronor | Acoustic insulation of partitions - using layer of rubber particles bonded with phenolic resin |
DE4340478A1 (en) * | 1993-11-27 | 1995-06-01 | Dieter Arnds | Method and device for producing a sheet-like covering material and use as a floor and wall covering |
US6200638B1 (en) * | 1997-04-08 | 2001-03-13 | William C. Ordway | Shock hardened flooring |
EP1001111A2 (en) * | 1998-11-10 | 2000-05-17 | Johannes Schulte | Impact sound-isolated floor |
EP1375778A1 (en) * | 2002-06-21 | 2004-01-02 | Polynauve S.A.R.L. | Insulation material on the bases of recycled rubber and its use |
FR2852551A1 (en) * | 2003-03-21 | 2004-09-24 | Usines Gabriel Wattelez | Acoustic and/or vibration insulation material is made from a mixture of elastic particles and a plastomer resin, rolled into strips |
US20050050846A1 (en) * | 2003-09-08 | 2005-03-10 | Surace Kevin J. | Acoustical sound proofing material and methods for manufacturing same |
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8240430B2 (en) | 2002-10-01 | 2012-08-14 | Downey Paul C | Noise and vibration mitigating mat |
US8556029B2 (en) | 2002-10-01 | 2013-10-15 | Paul C. Downey | Noise and vibration mitigating mat |
US8113495B2 (en) | 2005-05-02 | 2012-02-14 | Downey Paul C | Vibration damper |
US8061478B2 (en) | 2008-05-06 | 2011-11-22 | Moderco Inc. | Acoustic face of polymer and embedded coarse aggregates and an acoustic panel assembly |
EP2145797A3 (en) * | 2008-07-11 | 2010-12-08 | Maier, S. Coop. | Vehicle part provided with sound insulation comprising crumb rubber |
US9637913B2 (en) | 2009-04-10 | 2017-05-02 | Saint-Gobain Performance Plastics Corporation | Acoustic damping compositions having elastomeric particulate |
US8028800B2 (en) | 2009-04-10 | 2011-10-04 | Saint-Gobain Performance Plastics Rencol Limited | Acoustic damping compositions |
WO2015051526A1 (en) | 2013-10-11 | 2015-04-16 | Dow Global Technologies Llc | Polymer mixture, multilayer article containing the same, and process of preparing the multilayer article |
EP3030614A4 (en) * | 2013-10-11 | 2017-05-31 | Dow Global Technologies LLC | Polymer mixture, multilayer article containing the same, and process of preparing the multilayer article |
US10793709B2 (en) | 2013-10-11 | 2020-10-06 | Dow Global Technologies Llc | Polymer mixture, multilayer article containing the same, and process of preparing the multilayer article |
EP3125233A4 (en) * | 2014-03-27 | 2017-10-25 | Mitsui Chemicals, Inc. | Sound insulator |
US9914011B2 (en) | 2015-06-25 | 2018-03-13 | Pliteq Inc. | Impact damping mat, equipment accessory and flooring system |
US10676920B2 (en) | 2015-06-25 | 2020-06-09 | Pliteq Inc | Impact damping mat, equipment accessory and flooring system |
Also Published As
Publication number | Publication date |
---|---|
ES2349939T3 (en) | 2011-01-13 |
JP4757302B2 (en) | 2011-08-24 |
US20090293413A1 (en) | 2009-12-03 |
EP1891285B9 (en) | 2011-01-26 |
US7861477B2 (en) | 2011-01-04 |
JP2008545908A (en) | 2008-12-18 |
EP1891285B1 (en) | 2010-08-04 |
DE602005022780D1 (en) | 2010-09-16 |
CA2610963A1 (en) | 2006-12-14 |
EP1891285A1 (en) | 2008-02-27 |
ATE476569T1 (en) | 2010-08-15 |
CN101198756B (en) | 2010-10-06 |
CN101198756A (en) | 2008-06-11 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US7861477B2 (en) | Method for making a sound-insulating load-bearing floor | |
KR100883326B1 (en) | Polymer cement concrete composite and repairing method for concrete pavement using the concrete composite | |
KR101119237B1 (en) | Polymer cement concrete composite and overlay method of concrete structure using the composite | |
EP1853396B1 (en) | Method for making a sound-insulatiing load-bearing floor | |
US20080019773A1 (en) | Paving joint mortars | |
JP4902255B2 (en) | Modified asphalt composition for waterproof / waterproof material and method for producing the same | |
KR101005515B1 (en) | Self-reactive acryl-based resin composition, acryl-based polymer concrete, ultrathin overlay pavement structure and method of forming ultrathin overlay pavement using the same | |
KR101880455B1 (en) | Method for constructing embossing waterproof layer using mortar spray gun | |
KR20160087131A (en) | Crack repair construction method for concrete structure | |
KR101194555B1 (en) | Cement concrete composite and repairing method of concrete structure using the composite | |
EP0594321B1 (en) | Aqueous composition | |
JPH0471110B2 (en) | ||
JP2007131745A (en) | Adhesive composition | |
US10851025B2 (en) | Waterborne wet look coating composition | |
JP5869104B2 (en) | Improved polymer composition for cement-based substructures | |
US20240218167A1 (en) | Liquid applied sound damping mats for flooring and compositions for making them | |
JPH0598227A (en) | Adhesive composition which also serves as substrate elasticity regulator | |
JPH09208283A (en) | Resin-mortar composition and ruggedness regulating material using the same | |
Tsai et al. | Solid grade acrylic cement modifiers | |
US20230295478A1 (en) | Adhesive composition comprising lightened fillers | |
KR102284024B1 (en) | Filling composition for semi-rigid pavement and semi-rigid packing method using same | |
EP0649823B1 (en) | Bonding liquid dispersions | |
JP2576011B2 (en) | Paint for plywood | |
EP0442753A2 (en) | Low temperature acrylic latex compositions and methods for waterproofing structures | |
JPH0346417B2 (en) |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
WWE | Wipo information: entry into national phase |
Ref document number: 2005753112 Country of ref document: EP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2610963 Country of ref document: CA |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2008515053 Country of ref document: JP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 200580050075.X Country of ref document: CN |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
WWW | Wipo information: withdrawn in national office |
Country of ref document: DE |
|
WWP | Wipo information: published in national office |
Ref document number: 2005753112 Country of ref document: EP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 11921862 Country of ref document: US |