WO2006077779A1 - アルミニウム合金板及びその製造方法 - Google Patents
アルミニウム合金板及びその製造方法 Download PDFInfo
- Publication number
- WO2006077779A1 WO2006077779A1 PCT/JP2006/300380 JP2006300380W WO2006077779A1 WO 2006077779 A1 WO2006077779 A1 WO 2006077779A1 JP 2006300380 W JP2006300380 W JP 2006300380W WO 2006077779 A1 WO2006077779 A1 WO 2006077779A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- aluminum alloy
- less
- plate
- temperature
- alloy sheet
- Prior art date
Links
- 229910000838 Al alloy Inorganic materials 0.000 title claims abstract description 75
- 238000000034 method Methods 0.000 title claims abstract description 71
- 238000005097 cold rolling Methods 0.000 claims abstract description 39
- 229910052742 iron Inorganic materials 0.000 claims abstract description 13
- 239000000463 material Substances 0.000 claims abstract description 13
- 239000012535 impurity Substances 0.000 claims abstract description 5
- 238000001816 cooling Methods 0.000 claims description 81
- 238000005242 forging Methods 0.000 claims description 60
- 238000004519 manufacturing process Methods 0.000 claims description 37
- 238000000137 annealing Methods 0.000 claims description 34
- 238000010438 heat treatment Methods 0.000 claims description 29
- 239000000314 lubricant Substances 0.000 claims description 14
- 238000000265 homogenisation Methods 0.000 claims description 13
- 229910052751 metal Inorganic materials 0.000 claims description 8
- 239000002184 metal Substances 0.000 claims description 8
- 229910052802 copper Inorganic materials 0.000 claims description 6
- 229910052804 chromium Inorganic materials 0.000 claims description 5
- 229910052719 titanium Inorganic materials 0.000 claims description 5
- 229910052720 vanadium Inorganic materials 0.000 claims description 5
- 229910052726 zirconium Inorganic materials 0.000 claims description 5
- 229910052748 manganese Inorganic materials 0.000 claims description 4
- 230000001105 regulatory effect Effects 0.000 claims description 4
- 239000000956 alloy Substances 0.000 abstract description 81
- 229910045601 alloy Inorganic materials 0.000 abstract description 79
- 229910052782 aluminium Inorganic materials 0.000 abstract description 4
- 238000005266 casting Methods 0.000 abstract description 3
- 238000009749 continuous casting Methods 0.000 abstract description 3
- 229910000765 intermetallic Inorganic materials 0.000 description 53
- 238000012360 testing method Methods 0.000 description 40
- 230000000052 comparative effect Effects 0.000 description 35
- 229910018134 Al-Mg Inorganic materials 0.000 description 28
- 229910018467 Al—Mg Inorganic materials 0.000 description 28
- 238000005452 bending Methods 0.000 description 27
- 229910000861 Mg alloy Inorganic materials 0.000 description 23
- 239000013078 crystal Substances 0.000 description 23
- 238000005096 rolling process Methods 0.000 description 18
- 239000000203 mixture Substances 0.000 description 17
- 238000000465 moulding Methods 0.000 description 12
- 238000005259 measurement Methods 0.000 description 11
- 238000001556 precipitation Methods 0.000 description 11
- 230000000694 effects Effects 0.000 description 10
- 150000001875 compounds Chemical class 0.000 description 7
- 238000005461 lubrication Methods 0.000 description 7
- 239000002245 particle Substances 0.000 description 7
- 230000002093 peripheral effect Effects 0.000 description 7
- 239000000843 powder Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 239000010949 copper Substances 0.000 description 5
- 230000007423 decrease Effects 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 238000005336 cracking Methods 0.000 description 4
- 230000007547 defect Effects 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 238000005098 hot rolling Methods 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 238000007711 solidification Methods 0.000 description 4
- 230000008023 solidification Effects 0.000 description 4
- 239000011701 zinc Substances 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 229910052796 boron Inorganic materials 0.000 description 3
- 210000001787 dendrite Anatomy 0.000 description 3
- 238000013461 design Methods 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- 238000007670 refining Methods 0.000 description 3
- 238000005204 segregation Methods 0.000 description 3
- 238000002791 soaking Methods 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 229910052725 zinc Inorganic materials 0.000 description 3
- 229910018084 Al-Fe Inorganic materials 0.000 description 2
- 229910018192 Al—Fe Inorganic materials 0.000 description 2
- 238000012935 Averaging Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000011362 coarse particle Substances 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 230000001050 lubricating effect Effects 0.000 description 2
- 239000010687 lubricating oil Substances 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000009864 tensile test Methods 0.000 description 2
- 230000037303 wrinkles Effects 0.000 description 2
- 229910018125 Al-Si Inorganic materials 0.000 description 1
- 229910018520 Al—Si Inorganic materials 0.000 description 1
- 108010053481 Antifreeze Proteins Proteins 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910019064 Mg-Si Inorganic materials 0.000 description 1
- 229910019406 Mg—Si Inorganic materials 0.000 description 1
- 241001024304 Mino Species 0.000 description 1
- 229910001199 N alloy Inorganic materials 0.000 description 1
- 229910001080 W alloy Inorganic materials 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000010960 cold rolled steel Substances 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000004512 die casting Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 238000009957 hemming Methods 0.000 description 1
- 238000010191 image analysis Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 239000006060 molten glass Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000007788 roughening Methods 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 238000005482 strain hardening Methods 0.000 description 1
- 238000003887 surface segregation Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/001—Continuous casting of metals, i.e. casting in indefinite lengths of specific alloys
- B22D11/003—Aluminium alloys
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/06—Continuous casting of metals, i.e. casting in indefinite lengths into moulds with travelling walls, e.g. with rolls, plates, belts, caterpillars
- B22D11/0622—Continuous casting of metals, i.e. casting in indefinite lengths into moulds with travelling walls, e.g. with rolls, plates, belts, caterpillars formed by two casting wheels
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/06—Continuous casting of metals, i.e. casting in indefinite lengths into moulds with travelling walls, e.g. with rolls, plates, belts, caterpillars
- B22D11/0637—Accessories therefor
- B22D11/068—Accessories therefor for cooling the cast product during its passage through the mould surfaces
- B22D11/0682—Accessories therefor for cooling the cast product during its passage through the mould surfaces by cooling the casting wheel
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/06—Alloys based on aluminium with magnesium as the next major constituent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/06—Alloys based on aluminium with magnesium as the next major constituent
- C22C21/08—Alloys based on aluminium with magnesium as the next major constituent with silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/04—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
- C22F1/047—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys with magnesium as the next major constituent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B3/00—Rolling materials of special alloys so far as the composition of the alloy requires or permits special rolling methods or sequences ; Rolling of aluminium, copper, zinc or other non-ferrous metals
- B21B2003/001—Aluminium or its alloys
Definitions
- the present invention provides a high Mg content A ⁇ Mg-based aluminum alloy plate obtained by continuous forging, an aluminum alloy plate having an excellent balance of strength and ductility and excellent formability, and a method for producing the same. It is.
- automotive body panels such as automobile hoods, fenders, doors, roofs, trunk lids, etc.
- panels such as water panels (outer plates) and inner panels (inner plates) are made of Al-Mg.
- Aluminum alloy or JIS 5000 series hereinafter simply referred to as 5000 or A ⁇ Mg aluminum alloy plate or A ⁇ Mg-Si aluminum alloy or JIS 6000 series aluminum alloy plate,
- the aluminum alloy plate for an automobile body panel (hereinafter, aluminum is also referred to as A1) is required to have high press formability. From the viewpoint of formability, among the A1 alloys, an A ⁇ Mg-based A1 alloy having an excellent balance between strength and ductility is advantageous.
- twin-roll molten aluminum alloy is poured from a refractory hot water supply nozzle between a pair of rotating water-cooled copper molds (twin rolls) and solidified.
- twin rolls rotating water-cooled copper molds
- the aluminum alloy sheet is rolled down immediately after solidification and rapidly cooled.
- This twin-roll continuous fabrication method is known as the Hunter's method or the 3C method!
- the cooling rate of the twin roll type continuous forging method is 1 to 3 orders of magnitude higher than that of the conventional DC forging method or belt type continuous forging method.
- the obtained aluminum alloy sheet has a very fine structure and is excellent in workability such as press formability.
- the aluminum alloy plate with a relatively thin thickness of 1 to 13 mm can be obtained by forging. For this reason, steps such as hot rough rolling and hot finish rolling can be omitted as in the case of conventional DC ingots (thickness 200 to 600 mm). In addition, the homogenization process of the lump may be omitted.
- Patent Document 1 Japanese Patent Laid-Open No. 7-252571 (Claims, pages 1 to 2)
- Patent Document 2 JP-A-8-165538 (Claims 1 to 2)
- the Mg-based intermetallic compound that crystallizes during forging tends to be a starting point of fracture during press molding. Therefore, in order to improve the press formability of the high Mg A ⁇ Mg alloy plate produced using the twin roll type continuous forging method, these A1 -Mg intermetallic compounds (also called Al-Mg compounds) As described in Patent Documents 1 and 2, it is effective to reduce the size or the size of coarse particles. It is also effective to improve press formability by making the crystal grains of the plate finer.
- Patent Document 1 As shown in Fig. 2, refinement of crystal grains, and further Al-Mg intermetallic compound It is not enough to make things finer or less coarse.
- the present invention has been made to solve such problems, and a first object thereof is a high Mg content A ⁇ Mg-based aluminum alloy plate obtained by continuous forging, and has a strength.
- the object is to provide an aluminum alloy sheet having an excellent ductility balance, excellent formability and in-plate uniformity.
- cooling rate (forging rate) in the twin-roll continuous forging method is increased to suppress the A ⁇ Mg-based intermetallic compound that crystallizes during forging, in the subsequent steps.
- 400 mm ingots or thin plates such as homogenization heat treatment before cold rolling, intermediate annealing during cold rolling, solution treatment after cold rolling, etc.
- the process of heating to a temperature of more than ° C or cooling the heated plate-shaped lump or sheet is selectively included in the design. In these thermal history processes, Al-Mg intermetallic compounds are likely to be generated.
- the present invention has been made to solve such problems, and a second object of the present invention is to provide an A ⁇ Mg-based intermetallic compound generated in a thermal history process after twin roll type continuous casting. This is to provide a method for producing a high Mg A-Mg alloy sheet with improved press formability.
- the gist of the aluminum alloy sheet of the present invention is that an A-Mg-based alloy having a thickness of 0.5 to 3 mm that has been forged and cold-rolled by a twin-roll continuous forging method.
- the strength and ductility balance (tensile strength x total elongation) is 11000 (MPa%) or more as the material properties of aluminum alloy sheets.
- the aluminum alloy sheet contains, in mass%, Mg: 8 to 14%, Fe: 1.0% or less, Si: 0.5% or less, and 97% or more of the balance is A1
- a powerful aluminum alloy melt is poured into a pair of rotating twin rolls, and the cooling rate of the twin rolls is set to 100 ° C / s or more, and the steel is continuously manufactured in a thickness range of 1 to 13 mm. It is preferable that
- the surface of the twin roll is lubricated during continuous production.
- the average conductivity referred to in the present invention means an average value of the respective conductivity at five measurement points at arbitrary measurement positions with a space of 100 mm or more between the parts where the plate is formed.
- the gist of the manufacturing method of the aluminum alloy sheet of the present invention is that, by the twin roll type continuous forging method, the mass% is more than 8% and not more than 14%, Fe: 1.0% or less, Si: 0.5% or less, the balance consisting of A1 and unavoidable impurities, with an aluminum alloy plate-shaped ingot having a thickness of 1 to 13 mm, which is cold-rolled
- the steel sheet is forged at an average cooling rate of 50 ° C / s or more until the center of the plate-shaped ingot lump is solidified after pouring into the twin rolls.
- the temperature of the central portion of the plate-like lump or sheet is in the range of 200 ° C to 400 ° C.
- the average cooling rate up to a temperature of 200 ° C should be 5 ° C / s or more.
- such a heat history process is a process in which cooling is performed immediately after the plate-shaped ingot is formed. Homogenization heat treatment at a temperature range of up to 0 ° C, 400 ° C or more before the cold rolling and below the liquidus temperature, and cooling performed on the plate-shaped ingots at a temperature of 300 ° C or more after forming. Examples include cold rolling, final annealing at 400 ° C. or higher and liquidus temperature or lower after cold rolling. These thermal history processes are used to improve the formability of the plate and to improve the manufacturing efficiency and yield in the manufacturing method of high Mg A ⁇ Mg-based alloy plates by the twin roll type continuous forging method. Selectively comes in.
- the average conductivity of the aluminum alloy plate in the structure of A-Mg alloy plate with a high Mg content exceeding 8% after the final annealing is 20IA CS%.
- Al-Fe and A-Si intermetallic compounds are not included in the high Mg A-Mg alloy structure.
- the overall intermetallic compounds are controlled in general, including their precipitation state and amount.
- the plate-like ingot or thin plate is heated to a temperature of 400 ° C or higher in the heat history step after the twin roll type continuous forging. Do not increase or decrease the average rate of temperature increase from 5 ° C / s to 5 ° C / s or more in the temperature range from 200 ° C to 400 ° C.
- the strength ductility balance can be improved uniformly over the aluminum alloy plate as the material property of the high Mg A-Mg alloy plate exceeding 8%. Then, press formability such as bulging, drawing, bending, or a combination of these can be improved by pressing.
- the average conductivity of the aluminum alloy plate is set in the range of 20IACS% or more and less than 26IACS%.
- the average conductivity of the aluminum alloy sheet correlates unequivocally with the amount of precipitation of these intermetallic compounds and the overall state of precipitation, in other words, with the strength-ductility balance of the sheet. Defined and controlled by rate.
- the material of each part of the plate used for forming the (product) forming aluminum alloy plate is defined and controlled by the average conductivity of the aluminum alloy plate. As uniform properties, it is ensured that the strength ductility balance (tensile strength X total elongation) is 11000 (MPa%) or more.
- the strength and ductility balance in other portions of the plate used for forming is low. If there are variations in material, it cannot be used as an aluminum alloy sheet for molding. In order to be able to be used as an aluminum alloy sheet for forming, the material of each part of the obtained (product) forming aluminum alloy sheet is uniform, and the balance of strength and ductility (tensile strength X total elongation) is It must be 11000 (MPa%) or higher.
- the strength ductility balance and each part of the plate used for forming Ensures a uniform balance of strength and ductility.
- the conductivity of each part used for forming of the high Mg A-Mg alloy plate exceeding 8% is required.
- it is preferably in the range of 15 to 29 IACS%.
- the average conductivity of the aluminum alloy plate is set to a range of 20 to 26 IACS%. It is preferable to do.
- the conductivity can be measured on the surface of the aluminum alloy plate with a commercially available eddy current conductivity measuring device. In this way, the electrical conductivities are measured at arbitrary measurement locations and 5 locations at intervals of 100 mm or more at the site where the plate is to be formed, and averaged to obtain the average electrical conductivity.
- the aluminum alloy sheet to be measured is forged and cold-rolled by the double-hole type continuous forging method and finally annealed. A mini-alloy sheet.
- the average crystal grain size on the surface of the A1 alloy plate is reduced to 100 m or less as a prerequisite for satisfying the above-described strength-ductility balance.
- press formability is ensured or improved.
- the crystal grain size becomes larger than 100 m, the press formability is remarkably deteriorated, and defects such as cracks and rough skin during forming tend to occur.
- SS stretch yarn strain
- the crystal grain size referred to in the present invention is the maximum diameter of crystal grains in the longitudinal (L) direction of the plate.
- the crystal grain size is measured by a line intercept method in the above-mentioned direction by observing the surface of the A1 alloy plate that has been mechanically polished by 0.05 to 0.1 mm and then electrolytically etched using a 100 ⁇ optical microscope.
- the length of one measurement line is 0.95mm, and the total measurement line length is 0.95 x 15mm by observing a total of five fields with three lines per field.
- composition of the A1 alloy plate of the present invention that is, the A1 alloy plate-like ingot (or the molten metal supplied to the twin roll) manufactured by the twin roll type continuous forging method is, by mass, Mg: more than 8% and not more than 14% Fe: 1.0% or less, Si: 0.5% or less chemical composition
- Mg is an important alloying element that improves the balance of strength, ductility, and strength and ductility of A1 alloy sheets.
- content of Mg is 8% or less, strength and ductility are insufficient, and the characteristics of the high Mg A ⁇ Mg-based A1 alloy do not appear, and the press formability to automotive panels, which is particularly intended by the present invention, is insufficient.
- Mg is contained in excess of 14%, the Al-Mg compound can be controlled even if the manufacturing method and conditions are controlled, such as increasing the cooling rate during continuous casting or increasing the cooling rate after annealing. The crystal precipitation increases. As a result, press formability is significantly reduced. In addition, the work hardening amount increases and the cold rollability also decreases. Therefore, Mg is more than 8% and less than 14% And
- Fe and Si inevitably contain the melting raw material power of the molten metal, and are impurities that should be regulated to the smallest possible amount.
- Fe and Si are produced in large amounts with the amount of A ⁇ Mg compounds composed of Al-Mg- (Fe, Si) and the like and the amount of compounds other than A Mg such as A ⁇ Fe and Al-Si. If the Fe content exceeds 1.0% and the Si content exceeds 0.5%, the amount of these compounds becomes excessive, and fracture toughness greatly inhibits formability. As a result, press formability is significantly reduced. Therefore, Fe is regulated to 1.0% or less, preferably 0.5% or less, and Si is regulated to 0.5% or less, preferably 0.3% or less.
- Mn, Cu, Cr, Zr, Zn, V, Ti, B, and the like are also impurity elements that are likely to be contained from the melting raw material of the molten metal, and it is better that the content is small.
- Mn, Cr, Zr, and V have the effect of refining the rolled plate structure
- Ti and B have the effect of refining the forged plate (bulb) structure
- Cu and Zn also have the effect of improving strength. For this reason, it may be intentionally included for these effects, and it is allowed to contain one or more of these elements within a range that does not impair the formability, which is a characteristic of the plate of the present invention.
- Mn 0.3% or less
- Cr 0.3% or less
- Zr 0.3% or less
- V 0.3% or less
- Ti 0.1% or less
- B 0.05% or less
- Cu 1.0% or less
- Zn 1.0% or less.
- the high Mg A ⁇ Mg-based A1 alloy plate of the present invention is, as described above, a slab ingot formed by DC forging. It is difficult to manufacture industrially by a normal manufacturing method in which hot rolling is performed after soaking. Therefore, the high Mg A ⁇ Mg-based A1 alloy sheet of the present invention is manufactured by combining continuous forging such as a twin roll type, cold rolling and annealing without hot rolling.
- twin roll method there are belt caster type, propelzi type, block caster type, etc. as the continuous forging method of A1 alloy thin plate.
- a twin roll type is adopted.
- this twin-roll continuous forging is performed by pouring the molten A1 alloy having the above composition from a refractory hot-water supply nozzle between a pair of rotating water-cooled copper-plated twin rolls. It is solidified, and between these twin rolls, it is reduced immediately after the solidification and rapidly cooled to obtain an A1 alloy sheet.
- the twin roll it is desirable to use a roll whose surface is not lubricated by a lubricant.
- oxide powder alumina powder, zinc oxide powder, etc.
- SiC powder silicon carbide
- graphite to prevent cracking of the solidified shell formed on the twin roll surface when the molten metal comes into contact with the roll surface and is rapidly cooled.
- lubricants release agents
- these lubricants are used, the required cooling rate cannot be obtained because the cooling rate is slow. For this reason, there is a high possibility that the average conductivity of a high Mg A-Mg alloy plate exceeding 8% will be out of the specified range.
- the surface of the roll is continuously lubricated by a lubricant in the double roll continuous forging of an A ⁇ Mg-based alloy plate containing 3.5% or more of Mg. It is disclosed that the surface quality is improved by preventing blemish defects (surface segregation) due to uneven cooling.
- the amount of Mg up to 5% is the amount of Mg up to 5%, and there is no disclosure of an A-Mg alloy sheet with a high amount of Mg exceeding 8% as in the present invention.
- this twin roll The cooling rate for forging must be as fast as possible at 50 ° C / s or more.
- the actual or actual cooling rate tends to be substantially less than 50 ° C / s.
- the average crystal grains grow larger than 50 ⁇ m, and all of the intermetallic compounds such as Al-Mg are crystallized in large quantities.
- the strength-elongation balance is lowered, and the possibility that the press formability is significantly lowered is increased.
- the uniformity of the plate is also reduced.
- the thickness of the thin plate continuously produced by twin rolls shall be in the range of 1 to 13 mm. And preferably, it should be a thin plate thickness of lmm or more and less than 5mm. Continuous forging with a thickness of less than lmm is difficult due to casting limitations such as pouring between the twin holes and controlling the roll gap between the two rolls. On the other hand, if the plate thickness is 13 mm, or more strictly, the plate thickness is thicker than 5 mm, the cooling rate of the forging becomes extremely slow, and the overall intermetallic compounds such as Al-Mg system become coarse or a large amount of crystallization occurs. Tend to. As a result, the electrical conductivity is likely to be out of the range force. For this reason, the strength-elongation balance is lowered, and the possibility that the press formability is significantly lowered is increased.
- the pouring temperature when pouring the molten A1 alloy into the twin rolls is preferably set to the liquidus temperature + 30 ° C or lower. If the pouring temperature exceeds the liquidus temperature + 30 ° C, the forging cooling rate described later will be reduced, and all intermetallic compounds such as Al-Mg will become coarse or crystallize in large quantities. The conductivity may be out of the range. As a result, the strength-elongation balance is lowered, and the press formability may be significantly lowered. In addition, the rolling effect of the twin rolls is reduced, and the number of center defects increases, which may degrade the basic mechanical properties of the A1 alloy sheet.
- the peripheral speed of the pair of rotating twin rolls is preferably lm / min or more. If the peripheral speed of the twin roll is less than lm / min, the contact time between the molten metal and the mold (twist roll) becomes long, and the surface quality of the forged sheet may deteriorate. In this respect, the higher the peripheral speed of the twin rolls, the better.
- the preferable peripheral speed is 30 m / min or more.
- the forged A1 alloy sheet is not hot-rolled online or offline, but is cold-rolled to a thickness of 0.5 to 3 mm for product panels for automobile panels, and the forged structure is processed into a textured structure. .
- the degree of this processed structure is allowed depending on the amount of cold rolling reduction, but the structure may remain, but it is allowed as long as the press formability and mechanical properties are not impaired.
- intermediate annealing may be performed under normal conditions prior to cold rolling or during cold rolling.
- the A1 alloy cold-rolled sheet is preferably finally annealed at 400 ° C. to the liquidus temperature. If the annealing temperature force is less than S400 ° C, there is a high possibility that the solution effect will not be obtained. In addition, after this final annealing, it is necessary to cool at a temperature range of 500 to 300 ° C at the fastest possible average cooling rate of 5 ° C / s or more.
- the plate-shaped lump or thin plate when the plate-shaped lump or thin plate is heated to a temperature of 400 ° C or higher, or when the high-temperature force plate-shaped lump or thin plate exceeding 200 ° C is cooled. As described above, this means a thermal history process in which there is a sufficient possibility that an Al—Mg intermetallic compound is generated.
- these thermal history processes are performed in order to improve the formability of the plate in the manufacturing method of the high Mg A-Mg alloy plate by the twin roll type continuous forging method. It comes in selectively for process design such as efficiency and yield improvement. Therefore, when these thermal history processes enter the manufacturing process selectively or in combination, it is performed for each of these thermal history processes under conditions that suppress the generation of Al-Mg intermetallic compounds. .
- the conditions for suppressing the generation of Al-Mg intermetallic compounds for each such heat history process will be described below.
- the plate-shaped lumps produced by the twin-roll continuous forging method are subjected to cold rolling.
- the temperature range where A1-Mg intermetallic compounds are highly likely to be generated ranges from 200 ° C to 400 ° C at the center of the agglomerate when the temperature rises, and from the homogenization heat treatment temperature when cooling. The range is up to 100.
- cold rolling may be continuously performed without cooling to room temperature immediately after the plate-like ingot is formed by the twin-roll continuous forging method.
- the cold rolling (or warm rolling) start temperature is 300 ° C. or higher, there is a sufficient possibility that an Al—Mg intermetallic compound is generated during the cold rolling.
- the average cooling rate of the sheet (during rolling) should be 50 ° C / s or more, or the plate after cold rolling (or after warm rolling) should be cooled at an average cooling rate of 5 ° C / s or more.
- the temperature of the plate is increased during both the temperature rising and cooling. If the temperature and cooling rates are slow, there is a good chance that an Al-Mg intermetallic compound will be generated.
- the temperature range where Al-Mg intermetallic compounds are likely to be generated is the range where the temperature at the center of the plate is from 200 ° C to 400 ° C when the temperature is raised to the final annealing temperature, and the final temperature is during cooling. It ranges from annealing temperature to 100 ° C.
- the temperature at the center of the plate during the heating to the final annealing temperature is suppressed in order to suppress the generation of the A ⁇ Mg-based intermetallic compound.
- the average heating rate in the range from 200 to 400 ° C is 5 ° C / s or more.
- the average cooling rate in the range from the final annealing temperature to 100 ° C should be 5 ° C / s or more.
- the A1 alloy cold-rolled sheet is preferably subjected to final annealing at 400 ° C to the liquidus temperature. If the annealing temperature is less than 400 ° C, there is a high possibility that the solution effect cannot be obtained. [0074] (Cold rolling)
- Ordinary cold rolling that is, the force immediately after forming the plate-shaped ingots described above is not cold-rolled to room temperature, but the cold rolling performed after cooling to room temperature is not performed. Rolling to a thickness of 0.5 to 3 mm for product panels for automobile panels without hot rolling both online and offline, and forming a forged structure. Depending on the amount of cold rolling reduction, a forged structure may remain, but this degree of work structure is allowed within a range that does not impair press formability and mechanical properties.
- intermediate annealing may be performed under normal conditions. In that case, when intermediate annealing is performed at a temperature of 400 ° C or higher, A ⁇ Mg-based intermetallic compound In order to suppress the generation, the temperature raising and cooling processes are performed under the same conditions as in the final annealing.
- the average crystal grain size on the surface of the A1 alloy sheet is reduced to 100 m or less as a precondition for satisfying the strength ductility balance.
- press formability can be ensured or improved.
- the crystal grain size exceeds 100 / zm, the press formability is remarkably deteriorated, and defects such as cracks and rough skin during forming tend to occur.
- the SS (stretch yarn strain) mark which is peculiar to 5000 series A1 alloy sheets, is generated during press forming. From this viewpoint, the average grain size is 20 It is preferable to set it to m or more.
- the crystal grain size referred to in the present invention is the maximum diameter of crystal grains in the longitudinal (L) direction of the plate.
- the crystal grain size is measured by a line intercept method in the above-mentioned direction by observing the surface of the A1 alloy plate that has been mechanically polished by 0.05 to 0.1 mm and then electrolytically etched using a 100 ⁇ optical microscope.
- One measurement line length is 0.95mm, and the total measurement line length is 0.95 x 15mm by observing a total of five fields per field.
- Example 1 of the present invention will be described below.
- Each of the A-Mg based A1 alloy melts (Invention Examples A to M, Comparative Examples N to X) having various chemical composition shown in Table 1 was prepared under the conditions shown in Table 2 by the twin roll continuous forging method described above. Forged to a plate thickness (3-5mm). These A1 alloy forged sheets were cold-rolled to a thickness of 1.5 mm. In addition, these cold-rolled plates are connected under the conditions shown in Table 2. Final annealing and cooling were performed in a secondary annealing furnace. In both the inventive examples and the comparative examples, the average crystal grain size on the surface of the obtained A1 alloy plate was in the range of 30 to 60 / zm.
- the tensile test was performed according to JIS Z 2201, and the shape of the test piece was a JIS No. 5 test piece, and the test piece was prepared so that the longitudinal direction of the test piece coincided with the rolling direction.
- the crosshead speed was 5 mm / min, and the test piece was run at a constant speed until the test piece broke.
- the sampled specimen was subjected to 10% stretch at room temperature by simulating a flat hem process after press molding using an automobile outer panel. Thereafter, a bending test was performed for evaluation.
- the sample specimen was prepared using a No. 3 specimen (width 30 mm x length 200 mm) defined in JIS Z 2204 so that the longitudinal direction of the specimen coincided with the rolling direction.
- the bending test was performed by simulating flat hem processing using the V-block method specified in JIS Z 2248, bending it to 60 degrees with a clamp with a tip radius of 0.3 mm and a bending angle of 60 degrees, and then bending to 180 degrees. It was.
- the A1 alloy plate was bent at 180 ° without being sandwiched in order to tighten the force condition that the inner panel was sandwiched in the bent part.
- Examples of high Mg A ⁇ Mg-based A1 alloy plates having compositions within the scope of the present invention of A to M in Table 1 are provided under the conditions within the scope of the present invention.
- Inventive Examples 1 to 14 which were continuously forged, cold-rolled, and finally annealed, had a conductivity within the range of the present invention, a variation in conductivity, a small ⁇ conductivity, a high strength ductility balance, and a uniform Therefore, it is excellent in press formability and uniformity in each part of the plate.
- Comparative Examples 15 and 16 are examples of high Mg Mg-based A1 alloy examples having a composition within the scope of the present invention of A and B in Table 1.
- the cooling rate is less than 100 ° C / s, and it is manufactured outside the range of preferable manufacturing conditions.
- Comparative Examples 15 and 16 are inferior in bending workability and press formability in which the electrical conductivity is out of the scope of the present invention and the strength and ductility balance is low. Moreover, it is inferior to the homogeneity of the plate with high ⁇ conductivity.
- Comparative Example 17 is an example of a high Mg A ⁇ Mg-based A1 alloy having a composition within the scope of the present invention of B in Table 1. However, the cooling rate during the final annealing is slow. For this reason, Comparative Example 17 is inferior in bending workability and press formability in which the electrical conductivity falls outside the range of the present invention and the strength and ductility balance is low. Moreover, it is inferior to the homogeneity of the plate with high ⁇ conductivity.
- Comparative Examples 18 to 28 using alloys having compositions outside the invention range N to X in Table 1 were subjected to twin-roll continuous fabrication, cold rolling, and final annealing within the range of preferable conditions. in spite of
- the press formability is significantly inferior to that of the inventive examples.
- Comparative Example 18 uses an N alloy whose Mg content is too low below the lower limit, so that the conductivity falls slightly lower. As a result, the strength ductility balance is low and the bending workability and press formability are poor.
- Comparative Example 19 uses an alloy whose Mg content exceeds the upper limit and is too high, the conductivity is significantly higher. As a result, bending workability and press formability are inferior due to a low strength ductility balance. Therefore, these show the critical significance of the Mg content for strength, ductility, strength-ductility balance, and formability.
- Comparative Example 20 uses an alloy of P in which the Fe content exceeds the upper limit and is too high.
- Comparative Example 21 uses an alloy of Q whose Si content is too much above the upper limit. Comparative Example 22 uses an R alloy whose Mn content exceeds the upper limit and is too high.
- Comparative Example 23 uses an alloy of S in which the Cr content exceeds the upper limit and is too high.
- Comparative Example 24 uses an alloy of T whose Zr content exceeds the upper limit and is too high.
- Comparative Example 25 uses an alloy of U in which the V content exceeds the upper limit and is too high.
- Comparative Example 26 uses an alloy of V whose Ti content exceeds the upper limit and is too high.
- Comparative Example 27 uses a W alloy whose Cu content exceeds the upper limit and is too high.
- Comparative Example 28 uses an alloy of X whose Zn content is too much above the upper limit.
- K 10. 5 0. 25 0. 21 0. 01 0. 002 80 and 10.5 0. 25 0. 21 0. 01 0. 002
- Example 2 of the present invention will be described below.
- A1 Mg-based A1 alloy melts with various chemical composition shown in Table 1 (Invention example AI, comparative ⁇ 3 ⁇ 4 ⁇ ⁇ ) were formed into plate-like lumps (each plate thickness: 35 mm) by the twin roll continuous forging method described above. did.
- cold-rolled plates (each plate thickness: 1.5 mm) were manufactured from each plate-shaped ingot (A1 alloy forged sheet) according to the specific process conditions shown in Table 3 using the manufacturing method types shown in Table 2.
- the average crystal on the surface of the obtained A1 alloy plate The particle size was in the range of 30-60 ⁇ m except for Comparative Example 13.
- the peripheral speed of the twin roll during twin roll continuous fabrication is 70 m / min, and the pouring temperature when pouring the A1 alloy melt into the twin roll is the liquidus
- the temperature was constant at + 20 ° C in each example.
- Lubricating the twin roll surface with a lubricant in which SiC and alumina powders are suspended in water is performed only in Comparative Examples 15 and 16 in Table 2, and all other examples are without lubrication of the twin roll surface (no lubrication). Continuously forged.
- each specimen structure was observed with a 250x scanning electron microscope, and the average particle size (zm) and average area ratio (%) of the A1-Mg intermetallic compound in the field of view were measured. And averaged.
- the A ⁇ Mg-based intermetallic compound (precipitate) existing in the structure (? Mino) is identified and identified by X-ray diffraction, and the maximum amount of each A ⁇ Mg-based intermetallic compound observed is observed.
- the average particle diameter was determined by measuring the particle diameter and then averaging between the above test pieces.
- the area ratio the area occupied by all the observed A ⁇ Mg intermetallic compounds in the field of view was obtained by image analysis, and the average area ratio was obtained by averaging the above test pieces.
- the tensile test was performed in accordance with JIS Z 2201 in the same manner as in Example 1, the test piece shape was a J IS No. 5 test piece, and the test piece was manufactured so that the longitudinal direction of the test piece coincided with the rolling direction.
- the crosshead speed was 5 mm / min, and the test was performed at a constant speed until the test piece broke.
- each of the obtained high Mg A-Mg-based A1 alloy sheets was press-formed and bent.
- the press-molding test was performed in the same manner as in Example 1. Five of the sampled specimens (square blanks with a side of 200 mm) were projected in the shape of a square tube with a side of 60 mm and a height of 30 mm. And a hat-shaped panel having flat flanges around the four sides of the overhanging portion, and stretched by a mechanical press. The wrinkle holding force was 49 kN, the lubricating oil was a general fender, and the molding speed was 20 mm / min.
- the bending workability is the same as in Example 1, with the sampled test piece being used as an automobile outer panel, simulating flat hem processing after press molding, and 10% stretch on the test piece at room temperature. Then, a bending test was performed and evaluated.
- the sample specimen was prepared using a No. 3 specimen (width 30 mm x length 200 mm) defined in JIS Z 2204 so that the longitudinal direction of the specimen coincided with the rolling direction.
- the bending test was performed by simulating flat hem processing using the V-block method specified in JIS Z 2248, bending it to 60 degrees with a clamp with a tip radius of 0.3 mm and a bending angle of 60 degrees, and then bending to 180 degrees. It was. At this time, for example, in Hemkaroe, the water panel, the inner panel was bent at 180 degrees without squeezing the A1 alloy plate in order to tighten the force condition for the inner panel to be sandwiched in the bent part.
- Invention Examples 1 to 12 having compositions within the scope of the present invention of A to 1 in Table 3 are examples of high Mg A-Mg-based A1 alloy plates, After casting, the average cooling rate until the center of the plate-shaped lump is solidified is set to 50 ° C / s or more, and further, the plate-shaped lump or thin plate is 400 ° C or more in the subsequent thermal hysteresis process. When heating to a temperature of 5 ° C / s or more, the average temperature rise rate in the range from 200 ° C to 400 ° C is higher than 200 ° C.
- Comparative Example 13 is an example of an alloy having a composition within the range of the present invention shown in Table 3B.
- twin roll lubrication was performed, and the cooling rate during forging was 50 ° C / Less than s and too low.
- the average particle size (m) and average area ratio (%) of the Al—Mg intermetallic compound are larger than those of the inventive examples.
- the average crystal grain size was as large as 300 m.
- Comparative Example 13 is inferior in bending strength and press formability with a low strength-ductility balance. In addition, the uniformity of the plate is inferior.
- Comparative Examples 14 to 18 are the average heating rate or cooling rate in any one of the heat history steps after forging within the scope of the present invention shown in B of Table 1. Too late. Therefore, in Comparative Examples 14 to 18, the average particle size (m) and average area ratio (%) of the A ⁇ Mg intermetallic compound are larger than those of Invention Examples 1 to 14, and the strength ductility balance is low. The bending calorie is inferior in press formability. In addition, the uniformity of the plate is inferior.
- Comparative Examples 19 to 22 using alloys having compositions outside the invention range of J to M in Table 3 show that although the heat history process after forging was produced within the range of the present invention conditions.
- the bending workability and press formability are significantly inferior to those of the inventive examples.
- Comparative Example 19 uses an alloy of J in which the Mg content is too low below the lower limit, the strength-ductility balance is low and the bending strength and press formability are poor.
- Comparative Example 20 uses an alloy of K whose Mg content exceeds the upper limit and is inferior in bending strength and press formability with a low strength-ductility balance. Therefore, these show the critical significance of the Mg content for strength, ductility, strength-ductility balance, and formability.
- Comparative Example 21 uses an alloy of L in which the Fe content exceeds the upper limit and is too high.
- Comparative Example 22 uses an M alloy whose Si content exceeds the upper limit and is too high.
- these comparative examples are inferior in bending strength and press formability with a low strength ductility balance. Therefore, from these, the criticality for the strength, ductility, strength-ductility balance, and formability of each element I understand the significance.
- Example K 1 None 800 10 3 None--- ⁇ 1. 5 450 10 10. 0
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Continuous Casting (AREA)
- Metal Rolling (AREA)
Abstract
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP06711665.7A EP1842935B1 (en) | 2005-01-19 | 2006-01-13 | Aluminum alloy plate and process for producing the same |
KR1020077016378A KR100933385B1 (ko) | 2005-01-19 | 2006-01-13 | 알루미늄 합금판 및 그의 제조방법 |
US11/814,124 US8420011B2 (en) | 2005-01-19 | 2006-01-13 | Aluminum alloy plate and process for producing the same |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2005-011812 | 2005-01-19 | ||
JP2005011812A JP4224463B2 (ja) | 2005-01-19 | 2005-01-19 | 成形用アルミニウム合金板 |
JP2005017236A JP4224464B2 (ja) | 2005-01-25 | 2005-01-25 | 成形用アルミニウム合金板の製造方法 |
JP2005-017236 | 2005-01-25 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2006077779A1 true WO2006077779A1 (ja) | 2006-07-27 |
Family
ID=36692169
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2006/300380 WO2006077779A1 (ja) | 2005-01-19 | 2006-01-13 | アルミニウム合金板及びその製造方法 |
Country Status (4)
Country | Link |
---|---|
US (1) | US8420011B2 (ja) |
EP (1) | EP1842935B1 (ja) |
KR (1) | KR100933385B1 (ja) |
WO (1) | WO2006077779A1 (ja) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2113576A4 (en) * | 2007-01-24 | 2017-11-29 | Advanced Alloys GmbH | Method for producing a structural material made of magnesium-containing aluminium-based alloy |
CN114107768A (zh) * | 2020-08-26 | 2022-03-01 | 宝山钢铁股份有限公司 | 一种喷射铸轧高性能新型7xxx铝合金薄带的制备方法 |
CN115094282A (zh) * | 2015-06-05 | 2022-09-23 | 诺维尔里斯公司 | 高强度5xxx铝合金以及其制造方法 |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2006077779A1 (ja) | 2005-01-19 | 2006-07-27 | Kabushiki Kaisha Kobe Seiko Sho | アルミニウム合金板及びその製造方法 |
JP4203508B2 (ja) * | 2006-03-08 | 2009-01-07 | 株式会社神戸製鋼所 | アルミニウム合金鋳造板の製造方法 |
US8956472B2 (en) * | 2008-11-07 | 2015-02-17 | Alcoa Inc. | Corrosion resistant aluminum alloys having high amounts of magnesium and methods of making the same |
US20100164677A1 (en) * | 2008-12-29 | 2010-07-01 | Chin-Chi Yang | Fuse |
JP5715062B2 (ja) * | 2009-10-16 | 2015-05-07 | 昭和電工株式会社 | ブレーキピストンの製造方法 |
KR101232221B1 (ko) * | 2011-01-10 | 2013-02-12 | 한국기계연구원 | 쌍롤주조법을 이용한 마그네슘 합금 주편의 제조방법 및 이에 따라 제조되는 마그네슘 합금 주편 |
JP5920723B2 (ja) * | 2011-11-21 | 2016-05-18 | 株式会社神戸製鋼所 | アルミニウム−マグネシウム合金およびその合金板 |
FR2995322B1 (fr) * | 2012-09-10 | 2015-04-17 | Peugeot Citroen Automobiles Sa | Piece de carrosserie de vehicule emboutie a partir de tole d'aluminium a haute deformabilite. |
KR20150047246A (ko) | 2013-10-24 | 2015-05-04 | 한국기계연구원 | 결정립이 미세화된 알루미늄-아연-마그네슘-구리 합금 판재의 제조방법 |
JP6258108B2 (ja) * | 2014-04-09 | 2018-01-10 | 株式会社神戸製鋼所 | 車輌用フード |
KR102506754B1 (ko) | 2016-12-15 | 2023-03-07 | 현대자동차주식회사 | 고강도 알루미늄 합금 판재 부품 및 그 제조방법 |
CN108330420B (zh) * | 2018-03-23 | 2020-01-14 | 武汉理工大学 | 超高Mg含量的变形Al-Mg合金的制备方法 |
KR20220087210A (ko) * | 2020-12-17 | 2022-06-24 | 현대자동차주식회사 | 연료전지의 분리판용 알루미늄 박판재 및 그 제조방법 |
CN114054695B (zh) * | 2021-11-18 | 2023-07-21 | 青海桥头铝电有限责任公司 | 一种超薄宽幅铝合金铸轧板生产方法 |
KR102566987B1 (ko) | 2023-04-24 | 2023-08-14 | 한국재료연구원 | 고강도 알루미늄-아연-마그네슘-구리 합금 후판 및 그 제조방법 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH01202345A (ja) * | 1988-02-05 | 1989-08-15 | Kobe Steel Ltd | 双ロールによるAl―Mg合金の鋳造方法 |
JPH07252571A (ja) * | 1994-03-17 | 1995-10-03 | Nippon Steel Corp | 自動車用アルミニウム合金板とその製造方法 |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4626294A (en) * | 1985-05-28 | 1986-12-02 | Aluminum Company Of America | Lightweight armor plate and method |
JPH07145441A (ja) * | 1993-01-27 | 1995-06-06 | Toyota Motor Corp | 超塑性アルミニウム合金およびその製造方法 |
JPH08165538A (ja) | 1994-12-12 | 1996-06-25 | Sky Alum Co Ltd | リサイクル性の高い自動車ボディシート用アルミニウム合金圧延板及びその製造方法 |
JP3145904B2 (ja) * | 1995-08-23 | 2001-03-12 | 住友軽金属工業株式会社 | 高速超塑性成形に優れたアルミニウム合金板およびその成形方法 |
RU2111826C1 (ru) * | 1996-07-24 | 1998-05-27 | Виктор Макарьевич Живодеров | Способ литья алюминиевых сплавов, алюминиевый сплав и способ производства из него промежуточных изделий |
JPH10259441A (ja) * | 1997-03-19 | 1998-09-29 | Sumitomo Light Metal Ind Ltd | 高速超塑性成形性に優れ且つ成形後のキャビティの少ないアルミニウム合金板およびその製造方法 |
JP2001032031A (ja) | 1999-07-22 | 2001-02-06 | Kobe Steel Ltd | 耐応力腐食割れ性に優れた構造材用アルミニウム合金板 |
EP1440177A1 (en) | 2001-09-25 | 2004-07-28 | Assan Demir VE SAC Sanayi A.S. | Process of producing 5xxx series aluminum alloys with high mechanical properties through twin-roll casting |
WO2006077779A1 (ja) | 2005-01-19 | 2006-07-27 | Kabushiki Kaisha Kobe Seiko Sho | アルミニウム合金板及びその製造方法 |
-
2006
- 2006-01-13 WO PCT/JP2006/300380 patent/WO2006077779A1/ja active Application Filing
- 2006-01-13 EP EP06711665.7A patent/EP1842935B1/en active Active
- 2006-01-13 KR KR1020077016378A patent/KR100933385B1/ko active IP Right Grant
- 2006-01-13 US US11/814,124 patent/US8420011B2/en not_active Expired - Fee Related
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH01202345A (ja) * | 1988-02-05 | 1989-08-15 | Kobe Steel Ltd | 双ロールによるAl―Mg合金の鋳造方法 |
JPH07252571A (ja) * | 1994-03-17 | 1995-10-03 | Nippon Steel Corp | 自動車用アルミニウム合金板とその製造方法 |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2113576A4 (en) * | 2007-01-24 | 2017-11-29 | Advanced Alloys GmbH | Method for producing a structural material made of magnesium-containing aluminium-based alloy |
CN115094282A (zh) * | 2015-06-05 | 2022-09-23 | 诺维尔里斯公司 | 高强度5xxx铝合金以及其制造方法 |
CN114107768A (zh) * | 2020-08-26 | 2022-03-01 | 宝山钢铁股份有限公司 | 一种喷射铸轧高性能新型7xxx铝合金薄带的制备方法 |
Also Published As
Publication number | Publication date |
---|---|
KR100933385B1 (ko) | 2009-12-22 |
US20090071576A1 (en) | 2009-03-19 |
EP1842935A1 (en) | 2007-10-10 |
US8420011B2 (en) | 2013-04-16 |
EP1842935A4 (en) | 2011-07-06 |
EP1842935B1 (en) | 2014-10-29 |
KR20070087137A (ko) | 2007-08-27 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
WO2006077779A1 (ja) | アルミニウム合金板及びその製造方法 | |
JP4224463B2 (ja) | 成形用アルミニウム合金板 | |
JP4555183B2 (ja) | 成形用アルミニウム合金板の製造方法および成形用アルミニウム合金の連続鋳造装置 | |
JP4203508B2 (ja) | アルミニウム合金鋳造板の製造方法 | |
JP4542016B2 (ja) | 成形用アルミニウム合金板の製造方法 | |
JP4541934B2 (ja) | 成形用アルミニウム合金板の製造方法 | |
JP4914098B2 (ja) | アルミニウム合金鋳造板の製造方法 | |
JP4224464B2 (ja) | 成形用アルミニウム合金板の製造方法 | |
JP5059353B2 (ja) | 耐応力腐食割れ性に優れたアルミニウム合金板 | |
JP4955969B2 (ja) | 成形用アルミニウム合金板の製造方法 | |
JP5416795B2 (ja) | 成形用アルミニウム合金板 | |
JP5059505B2 (ja) | 高強度で成形が可能なアルミニウム合金冷延板 | |
JP4550598B2 (ja) | 成形用アルミニウム合金板 | |
JP4427020B2 (ja) | 成形用アルミニウム合金板の製造方法 | |
JP6589443B2 (ja) | Al−Si−Mg系アルミニウム合金板、該合金板の製造方法及び合金板を用いた自動車用部品 | |
JP4456505B2 (ja) | 成形用アルミニウム合金板の製造方法 | |
JP4542004B2 (ja) | 成形用アルミニウム合金板 | |
JP4542017B2 (ja) | 冷間圧延用アルミニウム合金板状鋳塊 | |
JP4550597B2 (ja) | 成形用アルミニウム合金板 | |
JP4224435B2 (ja) | 自動車用アルミニウム合金板およびその製造方法 | |
JP5406600B2 (ja) | 伸びフランジ性に優れたアルミニウム合金板およびその製造方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
WWE | Wipo information: entry into national phase |
Ref document number: 2006711665 Country of ref document: EP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 200680002585.4 Country of ref document: CN Ref document number: 1020077016378 Country of ref document: KR |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
WWP | Wipo information: published in national office |
Ref document number: 2006711665 Country of ref document: EP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 11814124 Country of ref document: US |