WO2005002350A1 - A method for modifying the texture of a dairy product - Google Patents
A method for modifying the texture of a dairy product Download PDFInfo
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- WO2005002350A1 WO2005002350A1 PCT/NZ2004/000142 NZ2004000142W WO2005002350A1 WO 2005002350 A1 WO2005002350 A1 WO 2005002350A1 NZ 2004000142 W NZ2004000142 W NZ 2004000142W WO 2005002350 A1 WO2005002350 A1 WO 2005002350A1
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23C—DAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING THEREOF
- A23C19/00—Cheese; Cheese preparations; Making thereof
- A23C19/06—Treating cheese curd after whey separation; Products obtained thereby
- A23C19/068—Particular types of cheese
- A23C19/08—Process cheese preparations; Making thereof, e.g. melting, emulsifying, sterilizing
- A23C19/082—Adding substances to the curd before or during melting; Melting salts
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23J—PROTEIN COMPOSITIONS FOR FOODSTUFFS; WORKING-UP PROTEINS FOR FOODSTUFFS; PHOSPHATIDE COMPOSITIONS FOR FOODSTUFFS
- A23J3/00—Working-up of proteins for foodstuffs
- A23J3/04—Animal proteins
- A23J3/08—Dairy proteins
Definitions
- the present invention relates to processes for preparing dairy products and products produced.
- the processes involve manipulation of the texture of dairy gels using whey protein and adjustment of pH.
- a longstanding problem with the production of cheese and cheese-like products, including processed cheese is that the ability to vary the texture of the product is often relatively limited. This is particularly a problem where an all-dairy recipe is used or when a specified fat or protein content is required.
- the texture of foods is a complex combination of science and art.
- the literature and art disclose many ways of manipulating the texture of cheese and cheese-like products. Texture in this context relates to instrumental/rheological methods used to determine stress-strain relationships at defined temperatures and deformation rates and fracture behaviour at defined temperatures and deformation rates.
- the texture of food products may also be evaluated by consumers or by using trained taste panellists by describing the mouth-feel attributes of the mastication process.
- the texture of foods may be manipulated over a wide range by a wide variety of methods, including but not limited to moisture content, fat content and composition, acidity, polymer structure, particle size, incorporation of multiple phases, shear rate and temperature.
- non-dairy ingredients are gel-forming polysaccharides such as hydrocoUoids and gums. This often necessitates labelling the products as "analogue” or "imitation” and the price has to be discounted to match consumer expectation.
- analogue or "imitation”
- the price has to be discounted to match consumer expectation.
- approaches have been used. These include manipulation of moisture, fat, incorporation of whey proteins, microparticulation, use of the enzyme transglutaminase, use of salts and pH variation.
- US Patent 6,303,160 discloses a process whereby the texture of cream cheese was able to be significantly varied by controlling the incorporation of water at key stages of the manufacturing process.
- US Patent 3,929,892 discloses a method whereby fat in cream cheese is replaced using a mixture incorporating heat denatured casein and whey proteins.
- the heat denaturated protein is mixed with cheese curd, acidified to attain the final pH required and then homogenised and packed. This process does not teach the in-situ denaturation at a controlled cooking pH of the protein.
- the process requires at least one homogenisation step and does not teach how to vary the texture by varying both cooking time and pH.
- Distinguishing attributes of these processes are heat treatment, pH adjustment and homogenisation steps so that the protein particles emerge with a carefully controlled particle size distribution (typically ⁇ 10 ⁇ m) i.e. micro particulation. See for instance EP patent application 1,201,134 and PCT published application WO 91/17665.
- Lov & L ⁇ v (WO 98/08396) extend this process to the micro particulation of denatured casein- whey protein aggregates.
- a further method of incorporating whey proteins into cheese and cheese-like products is to enzymatically crosslink the whey and casein proteins using an enzyme such as transglutaminase.
- Processes where salt interactions are used include that of US Patent 4,166,142. This describes a method of preparing processed cheese where whey protein was denatured in conjunction with salts of phosphate and citrate along with the usual processed cheese ingredients including blends of young and old cheese.
- NZ Patent 254127 discloses a process where salts of phosphate and citrate in conjunction with pH and heat modifies whey protein concentrate solutions, that are then dried and used as an ingredient in process cheese manufacture.
- the incorporated whey protein enables a significant reduction in cheese requirements in the process cheese formulation.
- skim milk powder Up to 5% skim milk powder may be added to the mixture.
- the thermal denaturation of the proteins is conducted at a pH range of 6.8-7.0 to mit imise protein deposition on the heat exchanger surfaces.
- the mixture is acidified to pH 5.4-5.6 and allowed to coagulate while still hot before draining and packing.
- the Modler & Emmons process is directed towards a continuous process using whey or mixtures of whey and milk that may be fortified with skim milk powder to produce ricotta and they speculate that it has the 'potential to produce casein, Paneer and Queso Blanco'. Their process requires a curd draining step and does not produce processed cheese directly, if at all.
- the Modler & Emmons process does not use melting salts and related agents to sequester calcium.
- Modler & Emmons made no attempt to vary the cooking pH in any way (beyond the range pH 6.8-7.0) and did not discover that it was possible to vary the texture of cheese-like products over a wide range by selecting combinations of casein to whey protein, pH and cooking conditions. They did not teach of a method capable of producing process cheese.
- the invention provides a process for preparing a cheese, a cheese-like product, a yoghurt or a dairy dessert without removing whey comprising:
- the product is a cheese or cheese-like product.
- the dairy starting material may take the form of any type of dairy product containing both casein and whey proteins. Suitable materials for use as the starting product include cheese, skim milk, whole milk, milk protein concentrates and mixtures and any of these. Also suitable are mixtures of a casein source and a whey protein source. For example a mixture of whey protein concentrate and casein.
- the ratio of whey protein to casein may be varied within the range of 0.05-3, preferably 0.1- 0.75.
- concentration is in the range 1-30% (w/w), more preferably 3-20% (w/w). Concentrations in the range 5-15% (w/w) are particularly preferred.
- the invention provides a process for preparing a cheese, a cheeselike product, a yoghurt or a dairy dessert comprising:
- chee-like product is a product which on being consumed by consumer imparts the sensation of consuming cheese.
- the products of the process include processed cheese and processed cheese spread, cottage cheese and petit suisse.
- Particularly preferred products include processed cheese and processed cheese spread.
- the term "comprising” means “consisting of or “including”.
- the processes of the invention may have additional steps and ingredients. For example salt, flavouring, colouring etc maybe added.
- the inventors have discovered that the texture of cheese, cheese-like products and related products can be varied over a surprisingly wide range by varying the casein to whey protein ratio while controlling the cooking pH in the range 5.0 to 8.0 preferably 5.8-7.5, more preferably 6.0-7.0, most preferably 6.3-7.0.
- the final product pH may be attained by adding acid (or alkali) to achieve typically a pH of 4.5 -7.5 preferably 5.0-6.3, more preferably 5.0-6.0.
- the range of product textures may be further varied using this controlled pH-cooking regime, by varying the fat or edible oil content, the heat treatment and the shear conditions.
- the cooking pH is 6.0-7.0 preferably 6.3-7.0 and the pH is adjusted to 5.0-6.3 preferably 5.0-6.0 after cooking.
- casein any source of casein may be used - including but not limited to casein, fresh casein curd, young cheese and milk protein concentrate powders (MPC) (retentate powders) or fresh retentate (including modified retentates and retentate powders).
- MPC milk protein concentrate powders
- retentate powders retentate powders
- fresh retentate including modified retentates and retentate powders.
- Ingredients containing casein that have been pre-treated with an agent to produce para ⁇ -casein are preferred.
- Preferred fats are milkfat, butter and butter oil (anhydrous milkfat). Any ratio of fat to protein as desired may be used but ratios between zero and 200% are preferred.
- whey protein sources may be used depending on the desired lactose and mineral concentrations in the finished product.
- Dried whey protein concentrates or concentrated whey protein retentates may be used.
- the process may be conducted using a mixture of fresh dairy ingredients in the liquid state and optionally fortified with the addition of dry ingredients containing either casein or whey protein containing powders.
- dry ingredients may be used and preferred sources of such dry ingredients are casein or MPC and whey protein concentrates.
- Preferred dry ingredients are blends of casein and whey protein containing powders, or MPC and whey protein containing powders.
- the casein rich powder and the whey protein rich powders may be pre-blended in a preferred ratio.
- the casein and whey protein containing powders may be combined at the point of filling the cooking device.
- a mixture of wet and dry starting materials may be used.
- Preferred cooking temperatures are in the range 50°C and up to the boiling point of the mixture.
- the preferred cooking time varies according to temperature used and the nature of the starting material. Generally times in the range 1 second to 30 minutes are used. Preferred cooking times may be chosen on the basis that they are times sufficient for modification of the casein whey interaction. Casein whey interactions provided by the cooking step provide increased strength of the texture of products produced from the casein whey mixture relative to uncooked controls or controls cooked at apH of approximately 5.7.
- the mixture of casein and whey protein, and any fat, is cooked with an initial pH (cooking pH) in the range pH 5.0 to 8.0.
- Any suitable agent may be used to attain the cooking pH.
- the pH adjustment either before or after the cooking step is carried out by direct addition of an alkali or acidulant.
- Preferred agents may be selected as allowed by Codex Alimentarius Standard 221-2001 (Codex group standard for unripened cheese including fresh cheese). This may be found at http://www.codexalimentarius.net/standard_list.asp or its updates.
- suitable monovalent cationic salts of phosphate and citrate may be used in conjunction with the alkali or acid.
- some of the monovalent cationic salts of phosphate and citrate added may substitute for some of the alkali or acid required.
- Preferred salts are widely known as melting salts and a preferred alkali is sodium hydroxide, and a preferred acids are lactic acid or citric acid or a mixture of the two.
- the acidity of the mixture may be increased further to the final desired level by the addition of suitable food-grade acid.
- Preferred acids are lactic acid, an acid precursor such as gfucono-delta-lactone (GDL), citric acid .and acetic acid, or the pH may be manipulated by the addition of melting salts.
- Any suitable ingredients such as, but not limited to, flavourings, colouring, common salt and water may also be added.
- a consequence of the invention is that a wide range of 'all dairy' cheese products can be made with desired textures and good flavours but at lower cost.
- the manufacture of processed cheese and processed cheese spread are preferred products. For some products such as cream cheese, traditional product texture characteristics such as firmness can be attained at an overall reduction in protein content. This offers the consumer the prospect of a more competitive product. Alternatively, increasing the whey protein to casein ratio may make a firmer product having the same overall protein content.
- Figure 1 is a flow diagram showing a preferred embodiment.
- Figure 2 shows a graph of gel firmness (Elastic Modulus G' (Pa) against cooking pH (rennet casein squares, cheese triangles)
- Figure 3 shows a surface plot of G vs pH and Hold.
- Example 1 A gel formulation made from cheese with the texture of the product being varied depending on the cook pH
- the processed cheeses were prepared using a 2L capacity Vorwerk Thermomix TM 21 blender cooker (Vorwerk & Co. Thermomix GmbH, Wuppertal, Germany).
- Cheddar cheese [matured for > 12 months] (NZMP, Wellington, New Zealand), tri-sodium citrate (BHD Laboratory Supplies, Poole, England), sodium chloride (BHD Laboratory
- the mixture was cooked at a temperature setting of 90 for 2 min at speed 4 (2000 rpm), after which the temperature was lowered to a temperature setting of 80 for 7 min. At the end of each minute, the speed was set to "Turbo" (12,000 rpm) for 3 s to thoroughly mix the emulsion as well as to prevent burning and sticking of the emulsion to the wall of the cooker.
- the final pH of the product was attained by the addition of 1.332 g of citric acid (BHD Laboratory Supplies, Poole) dissolved in 20 g of water, together with 2.3 mL of 3 M hydrochlorid acid, at the end of the 7 th minute.
- the final temperature of the processed cheese melt was 82°C.
- the molten processed cheese was poured into plastic screwed cap containers, inverted then stored at 4°C.
- the final pH of the processed cheese was about 5.7 at 20°C. Varying the cook pH and adjusting final pH back to 5.7
- the pH of the gel samples was measured with a Schott Gerate N 48EE "stab" electrode (Schott Gerate GmbH, Hafheim, Germany) and a Radiometer pH82 meter (Radiometer, Copenhagen, Denmark).
- composition of the gel samples The product had 53.8% moisture, 29.5% fat, 11.2% protein and balance 5.5% salts etc.
- Method of measurement of elastic modulus, G' The elastic modulus, G' was obtained at 0.1 Hz using a Carri-Med CSL100 rheometer (TA Instruments - Waters LLC, New Castle, USA) at 20°C as described by S. K. Lee & H. Kleinmeyer (2001). A description of elastic modulus is detailed in Ferry (1980). Gel firmness observations at the same pH were replicate determinations taken from the same gel sample.
- Example 2 Gel formulations using rennet casein with texture varied according to cook pH
- WPC (ALACEN 392, NZMP, Wellington, New Zealand) was dispersed in 67.64 g water and stored at 4°C overnight.
- 192 g sunflower oil (Sunfield Oils, Tasti Products Ltd., Auckland, New Zealand) was heated in the cooker for 1 min with the temperature setting at 100 and speed setting 1 (100 rpm). This brought the oil temperature to around 60°C.
- the hydrated rennet casein, WPC and water 48.7 g were added to the sunflower oil.
- the hydrated mixture had a [cook] pH of 6.7.
- the mixture was cooked at a temperature setting of 90 for 2 min at speed 4 (2000 rpm), after which the temperature was lowered to a temperature setting of 80 for 7 min. At the end of each minute, the speed was set to "Turbo" (12,000 rpm) for 3 s to thoroughly mix the emulsion as well as to prevent burning and sticking of the emulsion to the wall of the cooker.
- the pH of the final product was obtained by the addition of 1.91 g of citric acid (dissolved in 20 g of cold water) at the end of the 7 th min. The temperature of the mixture during the final 2 minutes was 82°C. At the end of the 9 th min, the molten processed cheese was poured into plastic screwed cap containers, inverted then stored at 4°C. After allowing to cool to room temperature, the final pH of the gel was about 5.1, at 20°C.
- the product had a composition of 52.1% moisture, 33.2% fat, 10% protein and remainder 4.7% minerals and other.
- the cook pH was varied by altering the proportion of the citric acid added for the cooking phase and the balance added post cooking to attain a constant final product pH and composition.
- the total citric acid added was 3.57 g.
- the cooking pH was varied by altering the proportion of the tri-sodium citrate added for the cooking phase and the balance to attain the final product pH.
- the total tri-sodium citrate added was 11.43 g.
- the rheology was examined using the same instrument and procedure as above and the textures are summarised in Table 4.
- the gels varied in texture from a soft pourable spread to that of a stiff gel.
- the model cream cheese was prepared using a 2L capacity Vorwerk Thermomix TM 21 blender cooker (Vorwerk Australia Pty. Ltd., Granville, N.S.W., Australia ).
- the rennet casein (ALAREN 799, 90 mesh, NZMP, Wellington, New Zealand) was hydrated with sodium chloride, tri-sodium citrate (Jungbunzlauer GmbH, Perhofen, Austria) and 3.0 g citric acid (Jungbunzlauer GmbH, Perhofen, Austria) and 100 g of water and held overnight at 4 ° C.
- the WPC (ALACEN 392, NZMP Wellington, New Zealand) was hydrated in 60 g of water for half an hour at room temperature. Frozen anhydrous milk fat, NZMP, Wellington, New Zealand after thawing at room temperature was heated for 1 min at temperature setting of 100 and speed 1 (100 rpm).
- the hydrated rennet casein, hydrated WPC and water (141.2 g) were added to the AMF.
- the mixture was cooked at a temperature setting of 90 for 2 min at speed setting 5 (3500 rpm), after which the temperature was lowered to a temperature setting of 80 for 7 min at speed 5.
- the speed was set to "Turbo" (12,000 rpm) for 3 s to thoroughly mix the emulsion as well as to prevent burning and sticking of the emulsion to the wall of the cooker.
- the mixture had a whey protein/casein ratio of 0.56.
- the cooking pH was about 5.7.
- the pH of the final product was obtained by the addition of 2.861 g of citric acid at the end of the 8 min.
- the final temperature of the processed cheese melt was 82°C.
- the molten product was poured into plastic screwed cap containers, inverted then stored at 4°C.
- the final pH of the product was 4.98.
- the cream cheese gel had a composition of 51.0 % water, 33.6% fat, 10.1% protein, 5.6% salts and minerals (balance).
- the cream cheese like composite gel had an elastic modulus, G' of between 42.1 kPa to 54.4 kPa measured at 0.1 Hz at 20°C.
- Example 4 Gel formation using using rennet casein and pre-denatured whey proteins
- Denatured WPC of 15 g protein in 100 g water was prepared using the method of Huss & Spiegel (2000) of controlled temperature, time and limited shear.
- the hydrated rennet casein, denatured WPC and water 48.7 g were added to the sunflower oil.
- the mixture was cooked at a temperature setting of 90 for 2 min at speed setting 4 (2000 rpm), after which the temperature was lowered to a temperature setting of 80 for 7 min.
- the speed was set to "Turbo" (12,000 rpm) for 3 s to thoroughly mix the emulsion as well as to prevent burning and sticking of the emulsion to the wall of the cooker.
- the processed cheese had 52.1% moisture, 33.2% fat, 10% protein and remainder 4.7% minerals and others.
- the processed cheese cooked was a soft and "runny" emulsion which flowed without support. Its elastic modulus, G' was 64.5 Pa measured at 0.1 Hz at 20°C and should be compared with the elastic modulus shown in Table 4 of a sample cooked at pH 5.71 using un-denatured whey protein. Comparison between these two samples demonstrated that un-denatured whey protein present during the cooking stage is required to increase the elastic modulus of the resulting gel.
- Example 5 Gel formation using rennet casein alone (no whey protein) Ingredient Weight (g)
- the hydrated rennet casein and 114.8 mL water were added to the sunflower oil.
- the mixture was cooked at a temperature setting of 90 for 2 min at speed 4 (2000 rpm), after which the temperature was lowered to a temperature setting of 80 for 7 min.
- the speed was set to "Turbo" (12,000 rpm) for 3 s to thoroughly mix the emulsion as well as to prevent burning and sticking of the emulsion to the wall of the cooker. 20 mL water was added at the end of the 7 th min.
- the final temperature of the processed cheese melt was 82 °C.
- the molten processed cheese was poured into plastic screwed cap containers, inverted then stored at 4°C.
- the final pH of the processed cheese was about 5.7.
- the processed cheese had 52.0 % moisture, 33.2 % fat, 10.1 % protein and remainder 4.6 % minerals and others.
- the processed cheese cooked was a soft emulsion. Its elastic modulus, G' was 113.5, 122.9 and 176.9 Pa measured at 0.1 Hz at 20°C.
- the processed cheese had 52.0 % moisture, 33.2 % fat, 10.1 % protein and remainder 4.6 % minerals and others.
- the model processed cheeses were prepared using a 2L capacity Vorwerk Thermomix TM 21 blender cooker (Vorwerk & Co. Thermomix GmbH, Wuppertal, Germany).
- MPC 85 (ALAPLEX 4850, N.Z. Milk Protein Concentrate, NZMP, Rellingen, Germany) was hydrated in a salt solution of 11.32 g tri-sodium citrate (BHD Laboratory Supplies, Poole,
- the hydrated MPC 85 and 92.5 mL water were added to the sunflower oil.
- the mixture was cooked at a temperature setting of 90 for 2 min at speed setting 4 (2000 rpm), after which the temperature was lowered to a setting of 80 for 7 min.
- the speed was set to "Turbo" (12,000 rpm) for 3 s to thoroughly mix the emulsion as well as to prevent burning and sticking of the emulsion to the wall of the cooker.
- 20 mL water was added at the end of the 7 th min.
- the final temperature of the processed cheese melt was 82°C.
- the molten processed cheese was poured into plastic screwed cap containers, inverted then stored at 4°C.
- the final pH of the processed cheese was about 5.7.
- the processed cheese had 52.0 % moisture, 33.0 % fat, 10.0 % protein and remainder 4.7 % minerals and others.
- MPC 85 was hydrated in salt solution (11.32 g tri-sodium citrate (BHD Laboratory Supplies, Poole, England), 1.07 g citric acid (BHD Laboratory Supplies, Poole, England), 6 g sodium chloride (BHD Laboratory Supplies, Poole) and 200 g water). The mixture was hydrated overnight at 4°C. This provided a cook pH of 6.1.
- the processed cheese cooked was a thick emulsion of elastic modulus, G' of 1118 Pa measured at 0.1 Hz at 20°C.
- This gel prepared at a cook pH close to the maximum of the curve disclosed in Figure 2, had an elastic modulus almost 20 times than that of the sample cooked at pH 5.1 (close to the minimum in the curve shown in Figure 2.)
- This comparison demonstrated that the whey protein (in an un-denatured form) can be applied along with the casein and does not have to be added as a separate ingredient to the process.
- Example 7 Experiments examining the effect of varying both the cooking pH and cooking time
- the cheese spread samples were prepared using a 2L capacity Vorwerk Thermomix TM 21 blender cooker (Vorwerk Australia Pty. Ltd., Granville, N.S.W., Australia).
- rennet casein (ALAREN 799, 90 mesh, NZMP, Wellington, New Zealand) was hydrated in salt solution (12.311 g tri-sodium citrate (Jungbunzlauer GmbH, Perhofen, Austria), 3.439 g citric acid (Jungbunzlauer GmbH, Perhofen, Austria), 6.3 g sodium chloride (Pacific Salt, Wales, New Zealand) and 170 g water). The mixture was hydrated overnight at 4°C. To provide the various cooking pHs of the samples produced in Table 7, the amounts of tri-sodium citrate and citric acid were adjusted according to the quantities in Table 5 for the selected experiment.
- Sunflower oil (Sunfield Oils, Tasti Products Ltd, Auckland, New Zealand) was heated for 1 minute at a temperature setting of 100 and speed setting 1 (this brought the temperature of the oil to 60°C).
- the hydrated rennet casein, WPC (dispersed in 50 g water) and water (56.5 g) were added to the sunflower oil.
- the mixture was cooked at a temperature setting of 90 for 2 minutes at speed 4 (2000 rpm), after which the temperature was lowered to a temperature setting of 80 for a set cooking time (see Table 6).
- the speed was set to "Turbo" (12,000 rpm) for 3 s to thoroughly mix the emulsion as well as to prevent burning and sticking of the emulsion to the wall of the cooker.
- 20 g of water and 3.161 g TSC was added at the end of the cooking time and held for a further 2 minutes at the same temperature and speed.
- the quantities of TSC or CA from Table 5 were added in substitution of the 3.161 g TSC to give the required final pH in Table 7.
- the hot processed cheese spread was transferred into plastic screwed cap
- the processed cheese spread had a composition of 51.0% moisture, 33.2% fat, 11% protein and remainder 4.8% minerals and others. Table 5. Amounts of tri-sodium citrate (TSC) and citric acid (CA) required to achieved different cooking pH (columns 2 and 3) and to achieve final product pH of 5.75 (columns 4 and 5)
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Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
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AU2004254141A AU2004254141B2 (en) | 2003-07-04 | 2004-07-05 | A method for modifying the texture of a dairy product |
BRPI0412319-0A BRPI0412319A (en) | 2003-07-04 | 2004-07-05 | Method for Modifying the Texture of a Dairy Product |
US10/563,314 US20070065560A1 (en) | 2003-07-04 | 2004-07-05 | Method for modifying the texture of a dairy product |
EP04748837A EP1648239A4 (en) | 2003-07-04 | 2004-07-05 | A method for modifying the texture of a dairy product |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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NZ526878A NZ526878A (en) | 2003-07-04 | 2003-07-04 | A method for varying the texture of cheese or cheese-like products by varying the casein to whey protein ratio while controlling the pH in the range of 5.0 to 8.0 |
NZ526878 | 2003-07-04 |
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WO2005002350A1 true WO2005002350A1 (en) | 2005-01-13 |
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US (1) | US20070065560A1 (en) |
EP (1) | EP1648239A4 (en) |
AU (1) | AU2004254141B2 (en) |
BR (1) | BRPI0412319A (en) |
NZ (1) | NZ526878A (en) |
TW (1) | TW200513190A (en) |
WO (1) | WO2005002350A1 (en) |
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- 2004-07-05 BR BRPI0412319-0A patent/BRPI0412319A/en not_active IP Right Cessation
- 2004-07-05 AU AU2004254141A patent/AU2004254141B2/en not_active Ceased
- 2004-07-05 TW TW093120168A patent/TW200513190A/en unknown
- 2004-07-05 EP EP04748837A patent/EP1648239A4/en not_active Withdrawn
- 2004-07-05 WO PCT/NZ2004/000142 patent/WO2005002350A1/en active Application Filing
- 2004-07-05 US US10/563,314 patent/US20070065560A1/en not_active Abandoned
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EP1677613A1 (en) * | 2003-10-30 | 2006-07-12 | Arla Foods amba | Stabilisers useful in low fat spread production |
AU2004284866B2 (en) * | 2003-10-30 | 2007-07-26 | Arla Foods Amba | Stabilisers useful in low fat spread production |
WO2005041677A1 (en) | 2003-10-30 | 2005-05-12 | Arla Foods Amba | Stabilisers useful in low fat spread production |
EP2274988A3 (en) * | 2003-10-30 | 2011-03-30 | Arla Foods Amba | Stabilisers useful in low fat spread production |
EP1677613B1 (en) * | 2003-10-30 | 2012-05-30 | Arla Foods Amba | Stabilisers useful in low fat spread production |
US8182856B2 (en) | 2003-10-30 | 2012-05-22 | Arla Foods Amba | Stabilizers useful in low fat spread production |
AU2004325988B2 (en) * | 2004-12-24 | 2012-01-19 | Fonterra Co-Operative Group Limited | Dairy ingredient - preparation and use |
WO2006068505A1 (en) * | 2004-12-24 | 2006-06-29 | Fonterra Co-Operative Group Limited | Dairy ingredient - preparation and use |
US7687095B2 (en) | 2005-09-30 | 2010-03-30 | Kraft Foods Global Brands Llc | High moisture, low fat cream cheese with maintained product quality and method for making same |
WO2007108708A1 (en) * | 2006-03-23 | 2007-09-27 | Fonterra Co-Operative Group Limited | Processed cheese comprising non-denatured and denatured whey protein |
US8192780B2 (en) | 2006-03-23 | 2012-06-05 | Fonterra Co-Operative Group Limited | Dairy product and process |
WO2009108074A1 (en) * | 2008-02-29 | 2009-09-03 | Christina June Coker | Dairy protein gel |
CN102164497A (en) * | 2008-02-29 | 2011-08-24 | 方塔拉合作集团有限公司 | Dairy protein gel |
JP2011512816A (en) * | 2008-02-29 | 2011-04-28 | フォンテラ コ−オペレイティブ グループ リミティド | Milk protein gel |
EP2262375A1 (en) * | 2008-02-29 | 2010-12-22 | Fonterra Co-Operative Group Limited | Dairy protein gel |
EP2262375A4 (en) * | 2008-02-29 | 2014-03-19 | Fonterra Co Operative Group | Dairy protein gel |
WO2011099876A1 (en) * | 2010-02-15 | 2011-08-18 | Fonterra Co-Operative Group Limited | Dairy product and process |
EP2649884B1 (en) | 2012-04-10 | 2016-02-03 | Kraft Foods R & D, Inc. | Process for producing cream cheese |
US9775366B2 (en) | 2012-04-10 | 2017-10-03 | Kraft Foods R & D, Inc. | Process for producing cream cheese |
CN103392831A (en) * | 2013-08-15 | 2013-11-20 | 光明乳业股份有限公司 | Lactalbumin food and preparation method thereof |
WO2015197496A1 (en) * | 2014-06-25 | 2015-12-30 | Nestec S.A. | Liquid dairy blend for culinary food products |
US10709147B2 (en) | 2014-06-25 | 2020-07-14 | Societe Des Produits Nestle S.A. | Liquid dairy blend for culinary food products |
Also Published As
Publication number | Publication date |
---|---|
AU2004254141A1 (en) | 2005-01-13 |
US20070065560A1 (en) | 2007-03-22 |
EP1648239A4 (en) | 2011-06-22 |
BRPI0412319A (en) | 2006-08-22 |
TW200513190A (en) | 2005-04-16 |
AU2004254141B2 (en) | 2009-10-29 |
EP1648239A1 (en) | 2006-04-26 |
NZ526878A (en) | 2007-01-26 |
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