WO2004105482A2 - Herbicidal compositions for paddy field - Google Patents
Herbicidal compositions for paddy field Download PDFInfo
- Publication number
- WO2004105482A2 WO2004105482A2 PCT/EP2004/005254 EP2004005254W WO2004105482A2 WO 2004105482 A2 WO2004105482 A2 WO 2004105482A2 EP 2004005254 W EP2004005254 W EP 2004005254W WO 2004105482 A2 WO2004105482 A2 WO 2004105482A2
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- alkyl
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Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
- A01N43/08—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings with oxygen as the ring hetero atom
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
- A01N41/10—Sulfones; Sulfoxides
Definitions
- the present invention relates to herbicidal compositions for paddy field. More specifically the present invention relates to herbicidal compositions for paddy field containing herbicidal benzoylcyclohexadiones and certain known herbicidal compounds as effective components.
- Herbicidal benzoylcyclohexadiones are known from WO 98/29406; WO 00/21924; WO 01/07422.
- WO 98/29406 Herbicidal benzoylcyclohexadiones are known from WO 98/29406; WO 00/21924; WO 01/07422.
- Several compounds disclosed in these references show good controlling effect against paddy weeds
- the activity of herbicides depends, inter alia, on the type of the herbicide employed, its application rate, the preparation, the harmful plants to be controlled, the climatic conditions and soil conditions and the like. Another criterion is the duration of action or degradation rate of the herbicide. Where appropriate, changes in the sensitivity of harmful plants to an active ingredient, which may occur upon prolonged use or within a geographically defined area, may also have to be taken into account. Such changes manifest themselves as more or less pronounced losses of action and can only be compensated for to a certain extent by increasing the application rates of the herbicides.
- a method which is frequently used for improving the use characteristics of a herbicide is to combine the active ingredient with one or more other active ingredients which contribute the desired additional properties.
- phenomena of physical and biological incompatibility are frequently observed when several active ingredients are used as a combination, for example lack of stability of a coformulation, degradation of an active ingredient, or antagonism of the active ingredients.
- combinations of active ingredients with an advantageous spectrum of action, high stability and the highest possible synergistically enhanced action, which allows the application rate to be reduced in comparison with the individual application of the active ingredients to be combined, are desired.
- R 1 represents
- R 2 represents O-R 6 , SO m -R 7 , cyanato, cyano, thiocyanato or halogen,
- R 3 and R 4 each independently represents hydrogen, halogen, C 1- alkyl, halo- ⁇ 4 alkyl, cyano, nitro or SO m -R 7 ,
- R 5 represents O-(CH 2 ) p -O-(CH 2 ) q -OR 7 , alkoxy, 2-tetrahydrofuranylmethoxy, 3-tetrahydrofuranylmethoxy, 2- tetrahydro-2H-pyranylmethoxy, 2-tetrahydrothienylmethoxy, 2- furanylmethoxy or 2-thienylmethoxy,
- R 6 represents hydrogen, C 1-4 alkyl or halo-C ⁇ alkyl
- R 7 represents C 1-4 alkyl, C ⁇ alkenyl, C 2-4 alkynyl, halo-C 1-4 alkyl, halo-C 2-4 alkenyl or halo-C ⁇ alkynyl,
- n 0,1 or 2
- p 2, 3 or 4
- q 2, 3 or 4
- compositions of the present invention By means of the above-mentioned compositions of the present invention, surprisingly, a substantially higher herbicidal effect, in comparison with the case that each active compound is singly used, than the sum of the individual effect of each of them, is shown. Consequently, it becomes possible, in conducting the weed control, to substantially reduce the concentration of each chemical that has been conventionally used.
- a broad herbicidal spectrum can be obtained and the application period can be broadened to a long period of time. For example, in the paddy rice cultivation, they show excellent herbicidal effect in any time of use from the early period of weed-emergence just after transplantation to growing period. Moreover, such an excellent herbicidal effect as durability of effect for a long time, excellent residual effect without phytotoxicity against rice is obtained.
- Preferred herbicidal compositions comprise as component a, compound of the formula (I) where:
- R 1 represents C 1-4 alkyl
- R 2 represents O-R 6 , SO m -R 7 , cyanato, cyano, thiocyanato or halogen,
- R 3 and R 4 each independently represents hydrogen, halogen, C 1-4 alkyl, halo-C h alky!, cyano, nitro or SOm-R 7 ,
- R 5 represents O-(CH 2 ) p -O-(CH 2 ) q -OR 7 , C 3-8 cycloalkyloxy, C 3 ⁇ cycloalkyl-C 1-4 alkoxy or 2-tetrahydrofuranylmethoxy, R 6 represents hydrogen, C 1-4 alkyl or halo-C 1-4 alkyl,
- R 7 represents C ⁇ alkyl, C 2-4 alkenyl, C 2-4 alkynyl, halo-C 1-4 alkyl, halo-C 2-4 alkenyl or halo-C 2-4 alkynyl,
- n 0. 1 , 2, 3, 4, 5 or 6,
- n 0,1 or 2
- p 2, 3 or 4
- q 2, 3 or 4
- compositions comprise as component (a), a compound of the formula (I) where:
- R 1 represents methyl
- R 2 represents O-R 6 .
- R 3 and R 4 each independently represents hydrogen, chloro, fluoro, methyl, trifluoromethyl, cyano, nitro or SO 2 -R 7 ,
- R 5 represents O-(CH 2 ) p -O-(CH 2 ) q -OR 7 , C 3-8 cycloalkyloxy, C 3-8 cycloalkyl-C 1-4 alkoxy, 2- tetrahydrofuranylmethoxy, 3-tetrahydrofuranylmethoxy, 2-tetrahydro-2H- pyranylmethoxy, 2-tetrahydrothienylmethoxy, 2-furanylmethoxy or 2- thienylmethoxy,
- R 6 represents hydrogen
- R 7 represents methyl or ethyl
- n 0. 1 or 2
- herbicidal compositions that comprise, as component (a), a compound of the formula (la) with the meanings stated hereinbelow: Table 1
- Preferred as components (b) are (b-1) pyraclonil, (b-2) HOK201 , (b-3) naproanilide, (b-4) pyrazolate, (b-5) pyrazoxifen, (b-6) clomeprop, (b-7) cumyluron, (b-8) dimepiperate, (b-9) quinoclamine, (b-10) bensulide, (b-11) simetryn, (b-12) butamifos, (b-13) MCPB and (b- 14) bentazone.
- compositions which are of particular interest in this context are those with a synergistically active content of one or more of the following combinations of two compounds (A) + (B):
- the herbicidal compounds as components (b) mentioned above can be used each singly or can be used in combination of 2 kinds or more.
- the mixing ratio of component (a) and component (b) can be varied in a relatively wide range according to the time of application, region of application, method of application, etc. of said compositions. They can be used in the range of generally 1/200 - 200 parts by weight, preferably 1/20 - 20 parts by weight of at least 1 kind of the herbicidal compounds as (b) components for 1 part by weight of a compound of the formula (I) as component (a) or its agriculturally customary salt. More specifically the ratio of use of individual compound of component (b) for 1 part by weight of a compound of the formula (I) as component (a) or its salt can be as follows.
- compositions of the present invention show strong herbicidal effect against paddy weeds. Said compositions can, therefore, be used as herbicidal compositions for paddy field, particularly as selective herbicides for paddy rice
- compositions of the present invention can be used against various weeds that develop in the paddy field.
- Dicotyledonous plants of the following Genera Polygonum, Rorippa, Rotala, Lindernia, Bidens, Dopatrium, Eclipta, Elatine, Gratiola, Lindernia, Ludwigia, Oenanthe, Ranunculus, Deinostema, etc.
- Monocotyledonous plants of the following Genera Echinochloa, Panicum, Poa, Cyperus, Monochoria, Fimbristylis, Sagittaria, Eleocharis, Scirpus, Alisma, Aneilema, Blyxa, Eriocaulon, Potamogeton, etc.
- compositions of the present invention can be used, concretely for example, in relation to the following typical paddy weeds.
- Dicotyledonous plants Rotala indica Koehne, Lindernia procumbens Philcox, Ludwigia prostrate, Roxburgh, Potamogeton distinctus A. Benn, Elatine triandra Schk, Oenanthe javanica
- Monocotyledonous plants Echinochloa oryzicola Vasing, Monochoria vaginalis Presl, Eleocharis, acicularis L, Eleocharis Kuroguwai Ohwi, Cyperus difformis L., Cyperus serotinus, Rottboel, Sagittaria pygmaea Miq, Alisma canaliculatum A. Br. et Bouche, Scirpus juncoides Roxburgh
- compositions of the present invention should not be restricted to these weeds in any way, but can be applied against other weeds in the same manner.
- compositions of the present invention can be made into customary formulations in case of using for control of the paddy weeds.
- Formulations are, for example, solutions, emulsions, wettable powders, suspensions, powders, soluble powders, granules, suspo- emulsion concentrates, solid formulations (jumbo formulations), floating granules, microcapsules in polymer substance, etc.
- the formulation auxiliaries required are likewise known and are described, for example, in: Watkins, "Handbook of Insecticide Dust Diluents and Carriers", 2nd Ed., Darland Books, Caldwell N.J.; H.v. Olphen, "Introduction to Clay Colloid Chemistry”; 2nd Ed., J. Wiley & Sons, N.Y. Marsden, “Solvents Guide”, 2nd Ed., Interscience, N.Y. 1950; McCutcheon's, “Detergents and Emulsifiers Annual", MC Publ.
- combinations with other pesticidally active substances such as other herbicides, fungicides or insecticides, and with safeners, fertilizers and/or growth regulators, may also be prepared, for example in the form of a readymix or a tank mix.
- formulations can be prepared according to per se known methods.
- the formulations according to the present invention can be prepared, for example, by mixing the aforementioned component (a) and component (b) with extenders, namely liquid diluents and/or solid diluents, and optionally with surfactants, namely emulsifiers and/or dispersants and/or foam-forming agents.
- organic solvents can be used as auxiliary solvent.
- liquid diluents there can be mentioned, for example, organic solvents such as aromatic hydrocarbons (for example, xylene, toluene, alkylnaphthalene, etc.), chlorinated aromatic or chlorinated aliphatic hydrocarbons (for example, chlorobenzenes, ethylene chlorides, methylene chloride, etc.), aliphatic hydrocarbons [for example, cyclohexane etc.
- paraffins for example, mineral oil fractions, mineral and vegetable oils, etc.
- alcohols for example, butanol, glycol and their ethers, esters, etc.
- ketones for example, acetone, methyl ethyl ketone, methyl isobutyl ketone, cyclohexanone, etc.
- strongly polar solvents for example, dimethylformamide, dimethyl sulfoxide, etc.
- Solid diluents are, for example, ammonium salts and ground natural minerals (for example, kaolin, clay, talc, chalk, quartz, attapulgite, montmorillonite, diatomaceous earth, etc.), ground synthetic minerals (for example, highly dispersed silicic acid, alumina, silicates, etc.) etc.
- ground natural minerals for example, kaolin, clay, talc, chalk, quartz, attapulgite, montmorillonite, diatomaceous earth, etc.
- ground synthetic minerals for example, highly dispersed silicic acid, alumina, silicates, etc.
- solid carriers for granules there can be used, for example, crushed and fractionated rocks (for example, calcite, marble, pumice, sepiolite, dolomite, etc.) synthetic granules of inorganic and organic meals, particles of organic materials (for example, saw dust, coconut shells, maize cobs, tobacco stalks, etc.) etc.
- Emulsifiers and/or foam-forming agents are, for example, nonionic and anionic emulsifiers [for example, polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol ethers (for example, alkylaryl polyglycol ethers, alkylsulfonat.es, alkylsulfates, arylsulfonates, etc.)], albumin hydrolysis products, etc.
- Dispersants are, for example, lignin sulfite waste liquor and methyl cellulose are adequate.
- Tackifiers can also be used in formulations (powders, granules, emulsifiable concentrates).
- Tackifiers are, for example, carboxymethyl cellulose, natural and synthetic polymers (for example, gum Arabic, polyvinyl alcohol, polyvinyl acetates, etc.) natural phospholipids (for example, cephalins and recithins), synthetic phospholipids, etc.
- mineral oils and vegetable oils can be used.
- Colorants can also be used. Colorants are, for example, inorganic pigments (for example, iron oxide, titanium oxide, Prussian Blue, etc,), organic dyestuffs such as alizarin dyestuffs, azo dyestuffs or metal phthalocyanine dyestuffs, and further traces nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc.
- inorganic pigments for example, iron oxide, titanium oxide, Prussian Blue, etc.
- organic dyestuffs such as alizarin dyestuffs, azo dyestuffs or metal phthalocyanine dyestuffs
- nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc.
- the formulations can contain the total of component (a) and component (b) in the range of concentration of generally 0.1-95 % by weight, preferably 0.5-90 % by weight.
- compositions of the present invention can be used for weed control as themselves or in their formulation forms. It is possible to do tank mixing when they are used, and further to mix with other known active compounds, particularly active compounds generally used for paddy field, for example, fungicides, insecticides, plant growth regulators, plant nutrients, soil improving agents, safeners and other herbicides.
- active compounds particularly active compounds generally used for paddy field, for example, fungicides, insecticides, plant growth regulators, plant nutrients, soil improving agents, safeners and other herbicides.
- 1-( ⁇ , ⁇ -dimethylbenzyl)-3-p-tolylurea as a safener can be added at an amount in the range of 1-200 parts by weight, preferably 2-100 parts by weight for 1 part by weight of a compound (a) of the formula (I) in the compositions of the present invention.
- compositions of the present invention can be directly used as such or in their formulation forms or in application forms prepared by further diluting said formulations, for example, in the forms of ready-to-use solutions, emulsifiable concentrates, suspensions, powders, wettable powders or granules.
- Formulations of these forms can be applied to paddy field by usual methods, for example, watering, spraying, atomizing, dusting, granule application, etc.
- compositions of the present invention can be applied to paddy field before, during or after transplantation.
- the applicable amount of said compositions can be varied in a substantial range.
- the application amount can be, as the total amount of the component (a) and component (b), for example, in the range of 0.01-5 kg/ha, preferably 0.06- 4.5 kg/ha.
- a prescribed amount of the test solution is prepared by diluting with water the formulation obtained by mixing the above-mentioned carrier and surfactant with 1 part by weight of the active compounds (component (a) or component (b)).
- Test Example 1 Test of effect of herbicidal compositions against paddy weeds
- Formulation Example 1 To a mixture of 3 parts by weight of the active compound (a-1), 4 parts by weight of the active compound (b-1), 32 parts by weight of bentonite (montmorillonite), 58 parts by weight of talc and 3 parts by weight of ligninsulfonate salt, 25 parts by weight of water were added, well kneaded, made into granules of 10-40 mesh by an extrusion granulator and dried at 40-50°C to obtain granules.
- bentonite montmorillonite
- talc 58 parts by weight of talc
- ligninsulfonate salt 25 parts by weight of water were added, well kneaded, made into granules of 10-40 mesh by an extrusion granulator and dried at 40-50°C to obtain granules.
- Formulation Example 2 96 Parts by weight of clay mineral particles having particle diameter distribution in the range of 0.2-2mm are put in a rotary mixer. While rotating it, 2 parts by weight of the active compound (a-1) and 2 parts by weight of the active compound (b-2) are sprayed together with a liquid diluent, wetted the particles uniformly and dried at 40-50°C to obtain granules.
- Formulation Example 3 A mixture of 4 parts by weight of the active compound (a-1), 4 parts by weight of the active compound (b-12), 10 parts by weight of ethylene glycol, 3 parts by weight of polyoxyalkylene tristyrylphenyl ether, 10 parts by weight of xanthan gum, 0.5 parts by weight of 14% silicone oil emulsion and 68.5 parts by weight of water was well stirred and then crushed with a crusher (Dyno-Mill Type KDL) to obtain water suspension formulation.
- a crusher Denso-Mill Type KDL
- Formulation Example 4 5 Parts by weight of the active compound (a-1), 15 parts by weight of the active compound (b-11), 30 parts by weight of sodium ligninsulfonate, 15 parts by weight of bentonite and 35 parts by weight of calcined diatomaceous earth powder were sufficiently mixed and, after addition of water, well kneaded, extruded with 0.3 mm screen and dried to obtain water-dispersible granules.
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
Claims
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020057022828A KR101180152B1 (en) | 2003-05-29 | 2004-05-15 | Herbicidal compositions for paddy field |
JP2006529842A JP4708349B2 (en) | 2003-05-29 | 2004-05-15 | Herbicide composition for paddy field |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2003152242A JP2004352657A (en) | 2003-05-29 | 2003-05-29 | Herbicide composition for paddy field |
JP2003-152242 | 2003-05-29 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2004105482A2 true WO2004105482A2 (en) | 2004-12-09 |
WO2004105482A3 WO2004105482A3 (en) | 2005-04-07 |
Family
ID=33487253
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2004/005254 WO2004105482A2 (en) | 2003-05-29 | 2004-05-15 | Herbicidal compositions for paddy field |
Country Status (4)
Country | Link |
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JP (2) | JP2004352657A (en) |
KR (1) | KR101180152B1 (en) |
CN (1) | CN100388885C (en) |
WO (1) | WO2004105482A2 (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2008155027A2 (en) * | 2007-06-19 | 2008-12-24 | Bayer Cropscience Ag | Synergistic crop-tolerated combinations of herbicides from the benzoylcyclohexandione group for application in rice growing |
WO2011101321A1 (en) | 2010-02-19 | 2011-08-25 | Bayer Cropscience Ag | 3-aminocarbonyl-substituted benzoylcyclohexanediones and their use as herbicides |
WO2010136165A3 (en) * | 2009-05-27 | 2011-12-29 | Bayer Cropscience Ag | Herbicide combinations comprising tefuryltrione for use in rice cultures |
EP2848125A1 (en) * | 2008-09-15 | 2015-03-18 | Syngenta Limited | Herbicidal compositions |
EP3679794A1 (en) | 2019-11-27 | 2020-07-15 | Bayer AG | Herbicidal compositions |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2001028341A2 (en) * | 1999-10-22 | 2001-04-26 | Aventis Cropscience Gmbh | Hydroxyphenylpyruvate dioxygenase inhibitors used in synergistic mixtures |
WO2002089582A1 (en) * | 2001-04-21 | 2002-11-14 | Bayer Cropscience Gmbh | Synergistic herbicide comprising benzoylcyclohexanediones for application in rice cultivation |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19846792A1 (en) * | 1998-10-10 | 2000-04-13 | Hoechst Schering Agrevo Gmbh | New benzoyl-cycloalkanone and benzoyl-cycloalkanedione derivatives useful as herbicides, especially for selective weed control in crops, and plant growth regulators |
DE10119721A1 (en) * | 2001-04-21 | 2002-10-31 | Bayer Cropscience Gmbh | Herbicidal compositions containing benzoylcyclohexanediones and safeners |
-
2003
- 2003-05-29 JP JP2003152242A patent/JP2004352657A/en active Pending
-
2004
- 2004-05-15 JP JP2006529842A patent/JP4708349B2/en not_active Expired - Lifetime
- 2004-05-15 CN CNB2004800146826A patent/CN100388885C/en not_active Expired - Lifetime
- 2004-05-15 KR KR1020057022828A patent/KR101180152B1/en active IP Right Grant
- 2004-05-15 WO PCT/EP2004/005254 patent/WO2004105482A2/en active Application Filing
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2001028341A2 (en) * | 1999-10-22 | 2001-04-26 | Aventis Cropscience Gmbh | Hydroxyphenylpyruvate dioxygenase inhibitors used in synergistic mixtures |
WO2002089582A1 (en) * | 2001-04-21 | 2002-11-14 | Bayer Cropscience Gmbh | Synergistic herbicide comprising benzoylcyclohexanediones for application in rice cultivation |
Non-Patent Citations (1)
Title |
---|
ANONYMOUS: "New synergistic and selective herbicide compositions" RESEARCH DISCLOSURE, KENNETH MASON PUBLICATIONS, HAMPSHIRE, GB, vol. 452, no. 61, December 2001 (2001-12), XP007129416 ISSN: 0374-4353 * |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2008155027A2 (en) * | 2007-06-19 | 2008-12-24 | Bayer Cropscience Ag | Synergistic crop-tolerated combinations of herbicides from the benzoylcyclohexandione group for application in rice growing |
WO2008155027A3 (en) * | 2007-06-19 | 2009-10-22 | Bayer Cropscience Ag | Synergistic crop-tolerated combinations of herbicides from the benzoylcyclohexandione group for application in rice growing |
EP2232992A1 (en) * | 2007-06-19 | 2010-09-29 | Bayer CropScience AG | Cultivated plant compatible synergistic herbicidal compositions comprising tembotrione and pyrazolynate for application in rice cultures |
US8673814B2 (en) | 2007-06-19 | 2014-03-18 | Bayer Cropscience Ag | Synergistic combinations which are compatible with cultivated plants and which comprise herbicides selected from the group consisting of benzoylcyclohexanediones for use in rice crops |
EP2848125A1 (en) * | 2008-09-15 | 2015-03-18 | Syngenta Limited | Herbicidal compositions |
WO2010136165A3 (en) * | 2009-05-27 | 2011-12-29 | Bayer Cropscience Ag | Herbicide combinations comprising tefuryltrione for use in rice cultures |
US8728977B2 (en) | 2009-05-27 | 2014-05-20 | Bayer Cropscience Ag | Herbicidal combinations comprising tefuryltrione for use in rice crops |
WO2011101321A1 (en) | 2010-02-19 | 2011-08-25 | Bayer Cropscience Ag | 3-aminocarbonyl-substituted benzoylcyclohexanediones and their use as herbicides |
CN102781235A (en) * | 2010-02-19 | 2012-11-14 | 拜耳知识产权有限责任公司 | 3-aminocarbonyl-substituted benzoylcyclohexanediones and their use as herbicides |
US8557741B2 (en) | 2010-02-19 | 2013-10-15 | Bayer Cropscience Ag | 3-aminocarbonyl-substituted benzoylcyclohexanediones and their use as herbicides |
CN102781235B (en) * | 2010-02-19 | 2015-04-22 | 拜耳知识产权有限责任公司 | 3-aminocarbonyl-substituted benzoylcyclohexanediones and their use as herbicides |
EP3679794A1 (en) | 2019-11-27 | 2020-07-15 | Bayer AG | Herbicidal compositions |
Also Published As
Publication number | Publication date |
---|---|
CN1794912A (en) | 2006-06-28 |
JP2007502849A (en) | 2007-02-15 |
KR20060015323A (en) | 2006-02-16 |
JP2004352657A (en) | 2004-12-16 |
CN100388885C (en) | 2008-05-21 |
JP4708349B2 (en) | 2011-06-22 |
WO2004105482A3 (en) | 2005-04-07 |
KR101180152B1 (en) | 2012-09-05 |
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