WO2004067664A1 - Hitze-aktivierbare klebemasse für fpcb-verklebungen - Google Patents
Hitze-aktivierbare klebemasse für fpcb-verklebungen Download PDFInfo
- Publication number
- WO2004067664A1 WO2004067664A1 PCT/EP2004/000679 EP2004000679W WO2004067664A1 WO 2004067664 A1 WO2004067664 A1 WO 2004067664A1 EP 2004000679 W EP2004000679 W EP 2004000679W WO 2004067664 A1 WO2004067664 A1 WO 2004067664A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- adhesive film
- adhesive
- concrete
- fpcb
- film according
- Prior art date
Links
- 239000000853 adhesive Substances 0.000 title description 21
- 230000001070 adhesive effect Effects 0.000 title description 21
- 239000000463 material Substances 0.000 title description 3
- 230000004520 agglutination Effects 0.000 title 1
- 239000002313 adhesive film Substances 0.000 claims abstract description 41
- 229920005989 resin Polymers 0.000 claims abstract description 17
- 239000011347 resin Substances 0.000 claims abstract description 17
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 10
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229920002725 thermoplastic elastomer Polymers 0.000 claims abstract description 4
- 229920001721 polyimide Polymers 0.000 claims description 20
- 239000003822 epoxy resin Substances 0.000 claims description 14
- 229920000647 polyepoxide Polymers 0.000 claims description 14
- 239000004642 Polyimide Substances 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 13
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 claims description 10
- 229920001971 elastomer Polymers 0.000 claims description 9
- 239000000806 elastomer Substances 0.000 claims description 7
- 229920001568 phenolic resin Polymers 0.000 claims description 7
- 239000004848 polyfunctional curative Substances 0.000 claims description 7
- 150000004760 silicates Chemical class 0.000 claims description 7
- 239000000126 substance Substances 0.000 claims description 6
- 239000005011 phenolic resin Substances 0.000 claims description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 3
- 238000010943 off-gassing Methods 0.000 claims description 3
- 239000005060 rubber Substances 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 239000000975 dye Substances 0.000 claims description 2
- 239000005007 epoxy-phenolic resin Substances 0.000 claims description 2
- 239000000945 filler Substances 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims description 2
- 238000004026 adhesive bonding Methods 0.000 claims 1
- 239000000470 constituent Substances 0.000 claims 1
- 239000004033 plastic Substances 0.000 claims 1
- 101001045744 Sus scrofa Hepatocyte nuclear factor 1-beta Proteins 0.000 description 20
- 229910000679 solder Inorganic materials 0.000 description 11
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 9
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 8
- 239000002131 composite material Substances 0.000 description 7
- 229910052802 copper Inorganic materials 0.000 description 7
- 239000010949 copper Substances 0.000 description 7
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
- 229920000459 Nitrile rubber Polymers 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- 239000000758 substrate Substances 0.000 description 6
- 238000010998 test method Methods 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 5
- 239000010410 layer Substances 0.000 description 5
- 229920000728 polyester Polymers 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 229920001342 Bakelite® Polymers 0.000 description 4
- 239000012790 adhesive layer Substances 0.000 description 4
- 239000002390 adhesive tape Substances 0.000 description 4
- 239000004637 bakelite Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 239000004416 thermosoftening plastic Substances 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- IANQTJSKSUMEQM-UHFFFAOYSA-N 1-benzofuran Chemical compound C1=CC=C2OC=CC2=C1 IANQTJSKSUMEQM-UHFFFAOYSA-N 0.000 description 2
- QZFAGHFGBLEISM-DBQHITQZSA-N 3-[(1r)-1-hydroxy-2-(methylamino)ethyl]phenol;4-[1-hydroxy-2-(propan-2-ylamino)butyl]benzene-1,2-diol;dihydrochloride Chemical compound Cl.Cl.CNC[C@H](O)C1=CC=CC(O)=C1.CC(C)NC(CC)C(O)C1=CC=C(O)C(O)=C1 QZFAGHFGBLEISM-DBQHITQZSA-N 0.000 description 2
- PLIKAWJENQZMHA-UHFFFAOYSA-N 4-aminophenol Chemical compound NC1=CC=C(O)C=C1 PLIKAWJENQZMHA-UHFFFAOYSA-N 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- 239000004820 Pressure-sensitive adhesive Substances 0.000 description 2
- 239000004433 Thermoplastic polyurethane Substances 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- -1 cycloaliphatic Chemical group 0.000 description 2
- 125000003700 epoxy group Chemical group 0.000 description 2
- 150000002460 imidazoles Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- ROGIWVXWXZRRMZ-UHFFFAOYSA-N 2-methylbuta-1,3-diene;styrene Chemical compound CC(=C)C=C.C=CC1=CC=CC=C1 ROGIWVXWXZRRMZ-UHFFFAOYSA-N 0.000 description 1
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 1
- OECTYKWYRCHAKR-UHFFFAOYSA-N 4-vinylcyclohexene dioxide Chemical compound C1OC1C1CC2OC2CC1 OECTYKWYRCHAKR-UHFFFAOYSA-N 0.000 description 1
- YXALYBMHAYZKAP-UHFFFAOYSA-N 7-oxabicyclo[4.1.0]heptan-4-ylmethyl 7-oxabicyclo[4.1.0]heptane-4-carboxylate Chemical compound C1CC2OC2CC1C(=O)OCC1CC2OC2CC1 YXALYBMHAYZKAP-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- 229920003319 Araldite® Polymers 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 239000004971 Cross linker Substances 0.000 description 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004831 Hot glue Substances 0.000 description 1
- 229920013646 Hycar Polymers 0.000 description 1
- 101100346764 Mus musculus Mtln gene Proteins 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000004844 aliphatic epoxy resin Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 238000010382 chemical cross-linking Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 239000011889 copper foil Substances 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 125000005442 diisocyanate group Chemical group 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- LDLDYFCCDKENPD-UHFFFAOYSA-N ethenylcyclohexane Chemical compound C=CC1CCCCC1 LDLDYFCCDKENPD-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 150000002357 guanidines Chemical class 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229920003986 novolac Polymers 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 239000011112 polyethylene naphthalate Substances 0.000 description 1
- 229920001228 polyisocyanate Polymers 0.000 description 1
- 239000005056 polyisocyanate Substances 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 238000011417 postcuring Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000011115 styrene butadiene Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/38—Improvement of the adhesion between the insulating substrate and the metal
- H05K3/386—Improvement of the adhesion between the insulating substrate and the metal by the use of an organic polymeric bonding layer, e.g. adhesive
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J5/00—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers
- C09J5/06—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers involving heating of the applied adhesive
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/10—Adhesives in the form of films or foils without carriers
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/03—Use of materials for the substrate
- H05K1/0393—Flexible materials
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2203/00—Applications of adhesives in processes or use of adhesives in the form of films or foils
- C09J2203/326—Applications of adhesives in processes or use of adhesives in the form of films or foils for bonding electronic components such as wafers, chips or semiconductors
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2463/00—Presence of epoxy resin
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2479/00—Presence of polyamine or polyimide
- C09J2479/08—Presence of polyamine or polyimide polyimide
- C09J2479/086—Presence of polyamine or polyimide polyimide in the substrate
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2201/00—Indexing scheme relating to printed circuits covered by H05K1/00
- H05K2201/01—Dielectrics
- H05K2201/0104—Properties and characteristics in general
- H05K2201/0129—Thermoplastic polymer, e.g. auto-adhesive layer; Shaping of thermoplastic polymer
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2201/00—Indexing scheme relating to printed circuits covered by H05K1/00
- H05K2201/01—Dielectrics
- H05K2201/0104—Properties and characteristics in general
- H05K2201/0133—Elastomeric or compliant polymer
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2201/00—Indexing scheme relating to printed circuits covered by H05K1/00
- H05K2201/02—Fillers; Particles; Fibers; Reinforcement materials
- H05K2201/0203—Fillers and particles
- H05K2201/0206—Materials
- H05K2201/0209—Inorganic, non-metallic particles
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
Definitions
- the invention relates to a heat-activatable adhesive with low flow at high temperatures for bonding flexible printed circuit board laminates.
- Adhesive tapes are widespread processing aids in many technical fields. Adhesive tapes are subject to very high requirements, particularly for use in the electronic industry.
- FPCBs flexible printed circuit boards
- FPCBs Flexible printed circuit boards are used in a variety of electronic devices such as Cell phones, car radios, computers, etc. represented.
- FPCBs consist of layers of copper and polyimide, where appropriate polyimide is glued to the copper foil.
- FPCBs For the use of the FPCBs, they are glued to substrates or to one another. In the latter case, polyimide films are bonded to one another.
- heat-activated adhesives are generally used that do not release any volatile components and can also be used in a high temperature range.
- the heat-activatable adhesive must be self-crosslinking after temperature activation, since the bonded FPCBs generally also have to be solder bath-resistant.
- Pure thermoplastics which are used as heat-activated adhesives for a number of bonds, become soft again at high temperatures and therefore have no resistance to solder baths. Pure thermoplastics are therefore unsuitable as the basis for the adhesive compositions for the abovementioned application. Thermoplastic adhesives would, however, be preferred for the bonding process as such, since they can be activated in a few seconds and the adhesive connection could accordingly be set up quickly.
- Phenolic resin-based heat-activated adhesive tapes are generally excluded because they release volatile components during curing and thus lead to the formation of bubbles.
- the object of the invention was therefore to meet the need for a heat-activatable adhesive system which is self-crosslinking and solder bath-resistant, has a low flow behavior at temperatures above 120 ° C. and has good adhesion to polyimide.
- This object is surprisingly achieved by an adhesive film, as is characterized in the main claim.
- the subclaims relate to advantageous developments of the subject matter of the invention.
- the invention relates to an adhesive film comprising (i) at least one thermoplastic polymer or a thermoplastic elastomer, (ii) at least one (tackifying) resin and (iii) at least one organically modified layered silicate and / or concreteite.
- adheresive film encompasses all flat structures, such as extended films, film sections and cutouts, tapes (extended length, limited width), tape sections, labels, die-cuts and the like, with the structures can have regular or irregular shapes.
- % By weight ii) one or more tackifying phenolic resins with a proportion of 0-30% by weight iii) epoxy resins, advantageously with hardeners, optionally also with accelerators, with a proportion of 5-60% by weight iv) organically modified Layered silicates or concrete with a share of 1 - 15% by weight
- the reactive film is advantageously a mixture containing reactive resins which crosslink at room temperature and form a three-dimensional, high-strength polymer network, and containing thermoplastic compounds, in particular permanently elastic elastomers, which counteract embrittlement of the product.
- the elastomer can preferably originate from the group of polyolefins, polyesters, polyurethanes or polyamides or can be a modified rubber, e.g. Nitrile rubber.
- thermoplastic polyurethanes are reaction products of polyester or polyether polyols and organic diisocyanates such as Diphenylmethane diisocyanate, known. They are made up of predominantly linear marrow molecules. Such products are usually commercially available in the form of elastic granules, for example from Bayer AG under the trade name "Desmocoll”.
- Synthetically produced nitrile rubbers can also be used as elastomers.
- nitrile rubbers can also be used as elastomers.
- Hycar TM types used by BF Goodrich.
- Suitable nitrile rubbers are also available under the trade name Nipol TM from Nippon Zeon.
- Amorphous types are particularly preferably used as polyester.
- the adhesive film further comprises substances which, in particular under elevated pressure and / or elevated temperature, serve as hardeners for at least one of the resins present.
- the softening temperature of the adhesive film can be sufficiently reduced by combining elastomers with selected compatible resins. At the same time, there is an increase in adhesion. Rosin, hydrocarbon and coumarone resins, for example, have proven to be suitable resins.
- Epoxy resins are usually understood to mean both oligomeric compounds with more than one epoxy group per mole and the thermosets produced from such compounds. In the sense of the invention, the entire group of epoxy compounds should be understood.
- the corresponding monomers, oligomers or polymers can be used which have at least two epoxy groups.
- Polymeric epoxy resins can be aliphatic, cycloaliphatic, aromatic or heterocyclic in nature.
- the molecular weight M n of the added epoxy resins is preferably chosen between 100 and 25,000 g / mol.
- Epoxy resins which can advantageously be used according to the invention include, for example, glycid esters and / or the reaction products epichlorohydrin and at least one of the following compounds: Bisphenol A, the reaction product of phenol and formaldehyde (novolak resins), p-amino phenol.
- Preferred commercial examples are e.g. Araldite TM 6010, CY-281 TM, ECN TM 1273, ECN TM 1280, MY 720, RD-2 from Ciba Geigy, DER TM 331, DER TM 732, DER TM 736, DEN TM 432, DEN TM 438, DEN TM 485 from Dow Chemical, Epon TM 812, 825, 826, 828, 830, 834, 836, 871, 872, 1001, 1004, 1031 etc. from Shell Chemical and HPT TM 1071, HPT TM 1079 also from Shell Chemical.
- Examples of commercial aliphatic epoxy resins are e.g. Vinyl cyclohexane dioxides such as ERL-4206, ERL-4221, ERL 4201, ERL-4289 or ERL-0400 from Union Carbide Corp.
- Hardeners are substances that are added to crosslinkable resins (prepolymers) to cause them to harden (crosslink).
- all of the hardeners known to the person skilled in the art can advantageously be used as hardening systems for epoxy resins and / or phenolic resins and / or other added resins in the adhesive film.
- All formaldehyde donors such as hexamethylenetretraamine, fall into this category.
- Acid anhydrides, cationic crosslinking agents, guanidines such as dicyandiamide or peroxides can also be used. Combinations of these crosslinkers can also be used.
- accelerators can also be used, such as imidazoles.
- Suitable accelerators are, for example, imidazoles, commercially available from 2M7, 2E4MN, 2PZ-CN, 2PZ-CNS, P0505, L07N from Shikoku Chem. Corp. or Curezol 2MZ from Air Products. Furthermore, amines, especially tertiary amines, can also be used for acceleration.
- Another component of the inventive PSA are organically modified layered silicates or concrete.
- Silicates which are available under the trade name Bentone TM (company Elementis Specialties) are particularly preferred for use. Bentone are preferably used TM types, low outgassing at 200 C C - preferably less than 200 micrograms volatiles at a temperature of 200 ° C over a period of 1 h - as well as a low chloride content - preferably less than 0, 2% by weight, particularly preferably less than 0.1% by weight
- High levels of chloride can negatively affect the electrical conductivity of the copper conductor tracks.
- High outgassing components lead to deformation of the FPCB laminates after curing and reduce the resistance to the solder bath.
- phenolic resins such as e.g. Use YP 50 (Toto Kasei), PKHC (Union Carbide Corp.) and / or BKR 2620 (Showa Union Gosei Corp.).
- Polyisocyanates such as e.g. Coronate TM L (from Nippon Polyurethane Ind.), Desmodur TM N3300 or Mondur TM 489 (from Bayer) can be used in addition or as an alternative to the phenolic resins.
- the composition for the adhesive film can be varied within a wide range by changing the type and proportion of raw material. Likewise, further product properties such as color, thermal or electrical conductivity can be achieved through the targeted addition of dyes, fillers and / or carbon or metal powders.
- the adhesive film preferably has a thickness of 5 to 100 ⁇ m, preferably 10 and 50 ⁇ m.
- the mass forming the film is coated as a solution or from the melt onto a flexible substrate (release film, release paper) and countered. if necessary dried so that the mass can be easily removed from the substrate. After appropriate assembly, die cuts, sections of a roll or other shaped bodies can be glued from this adhesive film to the substrate (polyimide) to be bonded at room temperature or at a slightly elevated temperature.
- the adhesive is coated on a polyimide carrier. Such adhesive films can then be used to cover copper interconnects for FPCBs.
- the admixed reactive resins should preferably not yet undergo any chemical reaction at the slightly elevated temperature. It is not necessary for the adhesive to be carried out as a one-step process, but for the sake of simplicity, as in the case of bonding with commercially available pressure-sensitive adhesive tapes, the adhesive film can first be tacked onto one of the two substrates by laminating in the heat. During the actual hot glue process with the second substrate (second polyimide film of the second FPCB), the resin cures in whole or in part and the adhesive joint achieves the high bond strength, which is significantly higher than that of known pressure sensitive adhesive systems. Accordingly, the adhesive film is particularly suitable for a hot pressing process at temperatures above 80 ° C., preferably above 100 ° C., particularly preferably above 120 ° C.
- the adhesive film according to the invention has a high elastic component due to the high elastomer component (rubber component). Due to this tough elastic behavior, the flexible movements of the FPCB's can be compensated particularly well, so that even high loads and peeling movements can be withstood well.
- the adhesive film has an advantage over other heat-activated materials due to the high viscoelastic content. Holes are often drilled through the adhesive film for contacting.
- One problem here is that existing heat-activated adhesives flow into the holes and thus interfere with the contact. With the inventive use of the adhesive films described above, this problem does not occur at all or only to a greatly reduced extent.
- FPCBs based on polyimide FPCBs based on polyethylene naphthalate (PEN)) and polyethylene terephthalate (PET) can also be bonded. In these cases, too, the adhesive film achieves a high bond strength.
- a mixture of 50 g nitrile rubber (Breon® 41, Zeon), 50 g epoxy resin (Rüapox TM 166, Bakelite AG), 5 g organic layered silicate (Bentone 38®, Elementis Specialties) and 3.4 g of dicyandiamide is dissolved in methyl ethyl ketone and coated from solution onto a release paper siliconized with 1.5 g / m 2 and dried at 90 ° C. for 10 minutes at this temperature.
- the thickness of the adhesive layer was 25 ⁇ m.
- a mixture of 60 g nitrile rubber (Breon® 41, Zeon), 40 g epoxy resin (Rüapox TM 166, Bakelite AG), 5 g organic layered silicate (Bentone 38®, Elementis Specialties) and 3 g of dicyandiamide is dissolved in methyl ethyl ketone and coated from solution onto a release paper siliconized with 1.5 g / m 2 and dried at 90 ° C. for 10 minutes at this temperature.
- the thickness of the adhesive layer was 25 ⁇ m.
- Two FPCB's were each bonded with the adhesive films produced according to Examples 1 to 4 and with the reference film (R) (Pyralux® LF001, DuPont).
- the adhesive film was laminated onto the polyimide film of the FPCB laminate made of polyimide / copper film / polyimide at 100 ° C.
- This process was then repeated with a second polyimide film from a further FPCB, and an adhesive joint was thus produced between two polyimide / copper film / polyimide laminates, the polyimide films in each case being bonded to one another.
- the composite was pressed in a heated press from Bürkle at 170 ° C. for 30 minutes at a pressure of 50 N / cm z .
- connections produced in this way had the structure shown in FIG. 1, (a) denoting a polyimide layer, (b) denoting a copper layer and (c) the adhesive film.
- a composite (a-b-a) of a copper layer (b) with a polyimide layer (a) on each side represents an FPCB unit.
- the FPCB composites (FIG.) Bonded by the process described above were completely immersed in a 288 ° C. hot solder bath for 10 seconds. The bond was rated as resistant to the solder bath if no air bubbles were formed which caused the FPCB's polyimide film to inflate. The test was assessed as failed if there was already a slight blistering.
- the bond strength was measured in accordance with DIN EN 1465. The measured values were given in N / mm 2 .
- Table 1 shows that with Examples 1 to 4 very high bond strengths were achieved after just 30 minutes of curing.
- Reference example R shows lower adhesive strengths.
- Test method B was therefore carried out with all the examples. The results are summarized in Table 2.
- Table 2 shows that Examples 1 to 4 mixed with Bentone TM have only a very low flow behavior and can therefore withstand high loads at high temperatures.
- test method C Another criterion for the use of adhesive films for the bonding of FPCB's is the resistance to the solder bath (test method C).
- Table 3 lists the results of the solder bath resistance.
- Table 4 shows that the adhesive films 1 to 4 according to the invention have a significantly higher bond strength than the reference example R.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Adhesive Tapes (AREA)
- Laminated Bodies (AREA)
Abstract
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP04705391A EP1590415A1 (de) | 2003-01-29 | 2004-01-27 | Hitze-aktivierbare klebemasse für fpcb-verklebungen |
JP2006501617A JP2006517604A (ja) | 2003-01-29 | 2004-01-27 | フレキシブルプリント基板接合のための熱活性化しうる接着剤 |
US10/543,795 US20060121272A1 (en) | 2003-01-29 | 2004-01-27 | Thermo-activated adhesive material for fpcb agglutinations |
Applications Claiming Priority (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10303518 | 2003-01-29 | ||
DE10303518.4 | 2003-01-29 | ||
DE10324737.8 | 2003-05-30 | ||
DE10317403A DE10317403A1 (de) | 2003-01-29 | 2003-05-30 | Verfahren zur Verklebung von FPCB's |
DE10317403.6 | 2003-05-30 | ||
DE2003124737 DE10324737A1 (de) | 2003-05-30 | 2003-05-30 | Hitze-aktivierbare Klebemass für FPCB-Verklebungen |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2004067664A1 true WO2004067664A1 (de) | 2004-08-12 |
WO2004067664A8 WO2004067664A8 (de) | 2005-07-28 |
Family
ID=32830168
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2004/000679 WO2004067664A1 (de) | 2003-01-29 | 2004-01-27 | Hitze-aktivierbare klebemasse für fpcb-verklebungen |
Country Status (5)
Country | Link |
---|---|
US (1) | US20060121272A1 (de) |
EP (1) | EP1590415A1 (de) |
JP (1) | JP2006517604A (de) |
KR (1) | KR20050094048A (de) |
WO (1) | WO2004067664A1 (de) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2005063908A1 (de) * | 2003-12-23 | 2005-07-14 | Tesa Ag | Schmelzkleber |
WO2005063907A1 (de) * | 2003-12-23 | 2005-07-14 | Tesa Ag | Schmelzkleber |
WO2010028950A1 (de) * | 2008-09-11 | 2010-03-18 | Tesa Se | Verfahren zur verklebung zweier konststoffoberflächen |
EP2700683B1 (de) | 2012-08-23 | 2016-06-08 | 3M Innovative Properties Company | Haftstrukturfolie |
EP3741803A1 (de) * | 2019-05-23 | 2020-11-25 | tesa SE | Verfahren zur herstellung haftklebriger reaktivklebebänder |
EP3760686A1 (de) | 2019-07-03 | 2021-01-06 | tesa SE | Thermisch härtender klebstoff und daraus hergestelltes klebeband |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102006055093A1 (de) * | 2006-11-21 | 2008-06-19 | Tesa Ag | Hitze-aktiviert verklebbares Flächenelement |
JP2009029843A (ja) * | 2007-07-24 | 2009-02-12 | Sekisui Chem Co Ltd | 半導体用接着剤及び半導体用接着テープ |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS52152585A (en) * | 1976-06-10 | 1977-12-19 | Katsuhiko Kanbayashi | Method of producing oily resist printing material |
US4465542A (en) * | 1982-02-19 | 1984-08-14 | Mitsui Petrochemical Industries, Ltd. | Adhesive composition |
JPH01221236A (ja) * | 1988-03-01 | 1989-09-04 | Nitto Denko Corp | 薄板補強用の接着性シート |
EP1234857A1 (de) * | 1999-11-30 | 2002-08-28 | Otsuka Chemical Company, Limited | Harzzusammensetzung und flexible leiterplattenanordung |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5026752A (en) * | 1987-04-03 | 1991-06-25 | Minnesota Mining And Manufacturing Company | Amorphous-polypropylene-based hot melt adhesive |
DE69229262T2 (de) * | 1992-03-16 | 2000-01-20 | Raytheon Co., Lexington | Wärmetransferklebstoff |
US5478885A (en) * | 1994-04-15 | 1995-12-26 | Shell Oil Company | Composition of epoxy resin, epoxidized block polydiene and curing agent |
ATE267237T1 (de) * | 2000-04-10 | 2004-06-15 | Henkel Kgaa | Schlagfeste epoxidharz-zusammensetzungen |
DE10163859A1 (de) * | 2001-12-22 | 2003-07-10 | Henkel Kgaa | Mehrphasige Strukturklebstoffe |
-
2004
- 2004-01-27 WO PCT/EP2004/000679 patent/WO2004067664A1/de not_active Application Discontinuation
- 2004-01-27 US US10/543,795 patent/US20060121272A1/en not_active Abandoned
- 2004-01-27 EP EP04705391A patent/EP1590415A1/de not_active Withdrawn
- 2004-01-27 KR KR1020057014079A patent/KR20050094048A/ko not_active Application Discontinuation
- 2004-01-27 JP JP2006501617A patent/JP2006517604A/ja active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS52152585A (en) * | 1976-06-10 | 1977-12-19 | Katsuhiko Kanbayashi | Method of producing oily resist printing material |
US4465542A (en) * | 1982-02-19 | 1984-08-14 | Mitsui Petrochemical Industries, Ltd. | Adhesive composition |
JPH01221236A (ja) * | 1988-03-01 | 1989-09-04 | Nitto Denko Corp | 薄板補強用の接着性シート |
EP1234857A1 (de) * | 1999-11-30 | 2002-08-28 | Otsuka Chemical Company, Limited | Harzzusammensetzung und flexible leiterplattenanordung |
Non-Patent Citations (2)
Title |
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DATABASE WPI Section Ch Week 197805, Derwent World Patents Index; Class A87, AN 1978-09494A, XP002278050 * |
DATABASE WPI Section Ch Week 198941, Derwent World Patents Index; Class A28, AN 1989-297752, XP002278049 * |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2005063908A1 (de) * | 2003-12-23 | 2005-07-14 | Tesa Ag | Schmelzkleber |
WO2005063907A1 (de) * | 2003-12-23 | 2005-07-14 | Tesa Ag | Schmelzkleber |
WO2010028950A1 (de) * | 2008-09-11 | 2010-03-18 | Tesa Se | Verfahren zur verklebung zweier konststoffoberflächen |
EP2700683B1 (de) | 2012-08-23 | 2016-06-08 | 3M Innovative Properties Company | Haftstrukturfolie |
EP3741803A1 (de) * | 2019-05-23 | 2020-11-25 | tesa SE | Verfahren zur herstellung haftklebriger reaktivklebebänder |
EP3760686A1 (de) | 2019-07-03 | 2021-01-06 | tesa SE | Thermisch härtender klebstoff und daraus hergestelltes klebeband |
Also Published As
Publication number | Publication date |
---|---|
JP2006517604A (ja) | 2006-07-27 |
EP1590415A1 (de) | 2005-11-02 |
KR20050094048A (ko) | 2005-09-26 |
US20060121272A1 (en) | 2006-06-08 |
WO2004067664A8 (de) | 2005-07-28 |
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