WO2004046078A1 - Hydrogenation of benzene polycarboxylic acids or derivatives thereof - Google Patents
Hydrogenation of benzene polycarboxylic acids or derivatives thereof Download PDFInfo
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- WO2004046078A1 WO2004046078A1 PCT/EP2003/012881 EP0312881W WO2004046078A1 WO 2004046078 A1 WO2004046078 A1 WO 2004046078A1 EP 0312881 W EP0312881 W EP 0312881W WO 2004046078 A1 WO2004046078 A1 WO 2004046078A1
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- pyromelhtate
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- hemimellitate
- trimesate
- trimellitate
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/03—Catalysts comprising molecular sieves not having base-exchange properties
- B01J29/0308—Mesoporous materials not having base exchange properties, e.g. Si-MCM-41
- B01J29/0316—Mesoporous materials not having base exchange properties, e.g. Si-MCM-41 containing iron group metals, noble metals or copper
- B01J29/0325—Noble metals
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/03—Catalysts comprising molecular sieves not having base-exchange properties
- B01J29/0308—Mesoporous materials not having base exchange properties, e.g. Si-MCM-41
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/041—Mesoporous materials having base exchange properties, e.g. Si/Al-MCM-41
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/041—Mesoporous materials having base exchange properties, e.g. Si/Al-MCM-41
- B01J29/042—Mesoporous materials having base exchange properties, e.g. Si/Al-MCM-41 containing iron group metals, noble metals or copper
- B01J29/043—Noble metals
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0203—Impregnation the impregnation liquid containing organic compounds
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
- C07C51/36—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by hydrogenation of carbon-to-carbon unsaturated bonds
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
- C07C67/303—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by hydrogenation of unsaturated carbon-to-carbon bonds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
- B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/46—Ruthenium, rhodium, osmium or iridium
- B01J23/462—Ruthenium
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated
Definitions
- the present invention relates to a process for the hydrogenation of benzenepolycarboxylic acids or derivatives thereof, such as esters and/or anhydrides, and in particular to a hydrogenation process, which utilizes a catalyst based on the combination of one or more catalytically active metals with one or more ordered mesoporous materials as support.
- Hydrogenation is an established process both in the chemical and petroleum refining industries. Hydrogenation is conventionally carried out in the presence of a catalyst, which usually comprises a metal hydrogenation component deposited on a porous support material.
- the metal hydrogenation component is often nickel or one or more metals such as platinum, palladium, rhodium or ruthenium.
- dimethylterephthalate is hydrogenated at ⁇ - 40° C and a pressure of from 50 to 170 bar over supported Pd catalysts, which are treated with Ni, Pt and/or Ru to give the corresponding dimethylhexahydroterephthalate.
- the supports used are alumina of crystalline phase alpha or theta or delta or gamma or beta or mixtures thereof.
- aromatic carboxylic esters are hydrogenated at from 70 to 250° C and from 30 to 200 bar over supported Ni, Ru, Rh and/or Pd catalysts to give the corresponding cycloaliphatic carboxylic esters.
- the support used is an aluminium oxide of which at least 20% has been converted into lithium-aluminium spinel.
- U.S. Pat. No. 3,027,398 describes the hydrogenation of dimethylterephthalate over supported Ru catalysts at from 110 to 140° C and from 35 to 105 bar.
- the Ru is deposited on charcoal or kieselguhr.
- EP-A 0 603 825 relates to a process for the preparation of 1,4- cycylohexanedicarboxylic acid by hydrogenating terephthalic acid by using a supported palladium catalyst, wherein as support alumina, silica or active charcoal is used.
- U.S. Pat. No. 3,334,149 describes a multistage process for the hydrogenation of dialkylterephthalate using a Pd catalyst followed by use of a copper chromite catalyst.
- U.S. Pat. No. 5,936,126 describes a process for the hydrogenation of an aromatic compound.
- the catalyst used contains ruthenium as active metal alone or optionally with one or more other Group IB, NUB or NIHB metals on a macroporous support.
- the macroporous support exhibits an average pore diameter of at least 50 nm and a BET surface area of not more than about 30 m 2 /g.
- U.S. Pat. No. 6,248,924 describes a process for reacting organic compounds.
- the catalyst used contains ruthenium as active metal alone or optionally with one or more other Group IB, VHB or NIHB metals on a support.
- the support may be a material having macropores (50 to 10000 nm pore diameter) and mesopores (2 to 50 nm pore diameter). In the support 10 -50% of the pores are macropores and 50 to 90% of the pores are mesopores.
- Alumina of surface area (BET) 238 m /g is specifically exemplified.
- the catalyst used comprises ruthenium as an active metal which is deposited alone or together with at least one other metal of subgroups I, NH or VIE of the periodic table on a support.
- One of three separate types of support may be used.
- the first support is macroporous having a mean pore diameter of at least about 50 nm and a BET surface area of at most 30m 2 /g.
- the second support is a material, which has both macropores and mesopores (2 to 50 nm pore diameter), and in which 5-50%) of the pores are macropores, 50 to 95% of the pores are mesopores and the surface area of the support is preferably from 50 to about 500 m 2 /g.
- the third type of support is a material, which is macroporous and has a mean pore diameter of at least 0.1 lm and a surface area of at most 15m 2 /g.
- the present invention accordingly provides a process for hydrogenating one or more benzenepolycarboxylic acids or one or more derivatives thereof, or a mixture of one or more benzenepolycarboxylic acids or one or more derivatives thereof by bringing the benzenepolycarboxylic acid or the derivative thereof or the mixture into contact with a hydrogen-containing gas in the presence of a catalyst, the catalyst comprising one or more catalytically active metals applied to a catalyst support comprising one or more ordered mesoporous materials.
- the catalyst support comprises one or more macroporous materials combined in admixture with the one or more ordered mesoporous materials.
- the catalyst support comprises one or more mixed porosity materials combined in admixture with the one or more ordered mesoporous materials.
- the catalyst comprises as active metal at least one metal of transition group N ⁇ i of the Periodic Table either alone or together with at least one metal of transition group I or Nil of the Periodic Table.
- benzenepolycarboxylic acids or derivatives thereof are hydrogenated to the corresponding cyclohexyl derivative in the presence of hydrogen and a catalyst comprising an active hydrogenation metal component deposited on one or more ordered mesoporous materials.
- a catalyst comprising an active hydrogenation metal component deposited on one or more ordered mesoporous materials.
- a certain class of support materials namely ordered mesoporous materials, which have high pore volume, high surface area and controlled pore openings of at least 2 nm, are particularly suitable for the hydrogenation of benzenepolycarboxylic acids or derivatives thereof.
- benzenepolycarboxylic acid or a derivative thereof used for the purposes of the present invention encompasses all benzenepolycarboxylic acids as such, e.g. phthalic acid, isophthalic acid, terephthalic acid, trimellitic acid, trimesic acid, hemimellitic acid and pyromellitic acid, and derivatives thereof, particularly monoesters, diesters and possibly triesters and tetraesters, in particular alkyl esters, and anhydrides such as phthalic anhydride or trimellitic anhydride or their esters.
- phthalic acid isophthalic acid
- terephthalic acid trimellitic acid
- trimesic acid trimesic acid
- hemimellitic acid and pyromellitic acid and derivatives thereof, particularly monoesters, diesters and possibly triesters and tetraesters, in particular alkyl esters, and anhydrides such as phthalic anhydride or trimellitic anhydride or
- esters used are alkyl, cycloalkyl and alkoxyalkyl esters, where the alkyl, cycloalkyl and alkoxyalkyl groups generally have from 1 to 30, preferably from 2 to 20 and particularly preferably from 3 to 18, carbon atoms and can be branched or linear.
- alkyl terephthalates such as monomethyl terephthalate, dimethyl terephthalate, diethyl terephthalate, di-n-propyl terephthalate, di-n-butyl terephthalate, di-tert-butyl terephthalate, diisobutyl terephthalate, monoglycol esters of terephthalic acid, diglycol esters of terephthalic acid, di-n-octyl terephthalate, diisooctyl terephthalate, mono-2-ethylhexyl terephthalate, di-2-ethylhexyl terephthalate, di-n-nonyl terephthalate, diisononyl terephthalate, di-n-decyl terephthalate, di-n-undecyl
- alkyl phthalates such as monomethyl phthalate, dimethyl phthalate, diethyl phthalate, di-n-propyl phthalate, di-n-butyl phthalate, di- tert-butyl phthalate, diisobutyl phthalate, monoglycol esters of phthalic acid, diglycol esters of phthalic acid, di-n-octyl phthalate, diisooctyl phthalate, di-2-ethylhexyl phthalate, di-n-nonyl phthalate, diisononyl phthalate, di-n-decyl phthalate, diisodecyl phthalate, di-n-undecyl phthalate, di-isoundecyl phthalate, diisododecyl phthalate, di- n-octadecyl phthalate, diisooctadecyl phthalate, diiso
- alkyl trimellitates such as monomethyl trimellitate, dimethyl trimellitate, diethyl trimellitate, di-n-propyl trimellitate, di-n- butyl trimellitate, di-tert-butyl trimellitate, diisobutyl trimellitate, the monoglycol ester of trimellitic acid, diglycol esters of trimellitic acid, di-n-octyl trimellitate, diisooctyl trimellitate, di-2-ethylhexyl trimellitate, di-n-nonyl trimellitate, diisononyl trimellitate, di-n-decyl trimellitate, diisodecyl trimellitate, di-n-undecyl trimellitate, di-isoundecyl trimellitate, diisododecyl trimellitate, di-n-octadecyl trimellitate, diisooctadecyl trimellitate, diiso
- alkyl trimesates such as monomethyl trimesate, dimethyl trimesate, diethyl trimesate, di-n-propyl trimesate, di-n-butyl trimesate, di-tert-butyl trimesate, diisobutyl trimesate, monoglycol esters of trimesic acid, diglycol esters of trimesic acid, di-n-octyl trimesate, diisooctyl trimesate, di-2-ethylhexyl trimesate, di- n-nonyl trimesate, diisononyl trimesate, di-n-decyl trimesate, diisodecyl trimesate, di- n-undecyl trimesate, di-isoundecyl trimesate, diisododecyl trimesate, di-n-oct
- a further suitable class are the alkyl hemimellitates such as monomethyl hemimellitate, dimethyl hemimellitate, diethyl hemimellitate, di-n-propyl hemimellitate, di-n-butyl hemimellitate, di-tert-butyl hemimellitate, diisobutyl hemimellitate, monoglycol esters of hemimellitic acid, diglycol esters of hemimellitic acid, di-n-octyl hemimellitate, diisooctyl hemimellitate, di-2-ethylhexyl hemimellitate, di-n-nonyl hemimellitate, diisononyl hemimellitate, di-n-decyl hemimellitate, diisodecyl hemimellitate, di-n-undecyl hemimellitate, di-isoundecyl hemimellitate, di
- alkyl pyromellitates such as monomethyl pyromelhtate, dimethyl pyromelhtate, diethyl pyromelhtate, di-n-propyl pyromelhtate, di-n-butyl pyromelhtate, di-tert-butyl pyromelhtate, diisobutyl pyromelhtate, monoglycol esters of pyromellitic acid, diglycol esters of pyromellitic acid, di-n-octyl pyromelhtate, diisooctyl pyromelhtate, di-2-ethylhexyl pyromelhtate, di-n-nonyl pyromelhtate, diisononyl pyromelhtate, di-n-decyl pyromelhtate, diisodecyl pyromelhtate, di-n-undecyl pyromelhtate
- anhydrides of phthalic acid trimellitic acid, hemimellitic acid and pyromellitic acid.
- alkyl terephthalates alkyl phthalates, alkyl isophthalates, dialkyl or trialkyl trimellitates, dialkyl or trialkyl trimesates, dialkyl or trialkyl hemimellitates and dialkyl, trialkyl or tetraalkyl pyromellitates in which one or more of the alkyl groups contain 5, 6 or 7 carbon atoms (e.g.
- alkyl groups include; n-pentyl, 1 -methylbutyl terephthalate, 2-methylbutyl, 3- methylbutyl, 2,2-dimethylpropyl, 1,1-dimethylpropyl, n-hexyl, 1-methylpentyl, 2- methylpentyl, 3-methylpentyl, 4-methylpentyl, 1,1-dimethylbutyl, 2,2-dimethylbutyl, 3,3-dimethylbutyl, 1,2-dimethylbutyl, 1,3-dimethylbutyl, 2,3-dimethylbutyl, 1- methyl-2-ethylpropyl, l-ethyl-2-methylpropyl, 1-ethylbutyl, 2-ethylbutyl, n-heptyl, 1- methylhexyl, 2-methylhexyl, 3-methylhexyl, 4-methylhexyl, 5-methylhexyl,
- alkyl groups are not identical such as for example in butylpropyl terephthalate or where one of the alkyl groups is replaced by a benzyl group such as for example in butylbenzyl terephthalate.
- mixtures of one or more of the benzenepolycarboxylic acid or a derivative thereof described herein When the derivatives are esters the mixture may be derived through use of a two or more alcohols in admixture or in sequence to esterify the same sample of a benzenepolycarboxylic acid derivative or a mixture of two or more benzenepolycarboxylic acids or a derivatives.
- the alcohols may be used to form, in separate syntheses, two different esterified derivatives, which may then be mixed together to form a mixture of two or more esterified derivatives.
- the mixture may comprise a mixture of esters derived from branched or linear alcohols, for example the mixture may comprise ester derivatives prepared from C7, C9, C8, CIO andCl 1 linear or branched alcohols, preferably linear alcohols, with the alcohols being used in the same synthesis of a mixture of derivatives or in separate syntheses of the derivative where the resultant derivative products in each synthesis are combined to form a mixed derivative.
- the preferred products are those derived from phthalates and in particular the following: cyclohexane-l,2-dicarboxylic acid di(isopentyl) ester, obtainable by hydrogenation of a di(isopentyl) phthalate having the Chemical Abstracts registry number (in the following: CAS No.) 84777- 06-0; cyclohexane-l,2-dicarboxylic acid di(isoheptyl) ester, obtainable by hydrogenating the di(isoheptyl) phthalate having the CAS No.
- cyclohexane-l,2-dicarboxylic acid di(isononyl) ester obtainable by hydrogenating the di(isononyl)phthalate having the CAS No. 68515-48-0; cyclohexane-1,2- dicarboxylic acid di(isononyl) ester, obtainable by hydrogenating the di(isononyl)phthalate having the CAS No. 28553-12-0, which is based on n-butene; cyclohexane-l,2-dicarboxylic acid di(isononyl) ester, obtainable by hydrogenating the di(isononyl)phthalate having the CAS No.
- 28553-12-0 which is based on isobutene; a l,2-di-C 9 -ester of cyclohexanedicarboxylic acid, obtainable by hydrogenating the di(nonyl)phthalate having the CAS No. 68515-46-8; cyclohexane- 1,2-dicarboxylic acid di(isodecyl) ester, obtainable by hydrogenating a di(isodecyl)phthalate having the CAS No. 68515-49-1; l,2-C 7 - ⁇ -ester of cyclohexanedicarboxylic acid, obtainable by hydrogenating the corresponding phthalic acid ester having the CAS No.
- l,2-di-C - ⁇ -ester of cyclohexanedicarboxylic acid obtainable by hydrogenating the di- C 7 - ⁇ -phthalates having the following CAS Nos.:l 11381-89-6, 111381-90-9, 111381-91-0, 68515-44- 6, 68515-45-7 and 3648-20-7; a 1,2-di- C 9 -n -ester of cyclohexanedicarboxylic acid, obtainable by hydrogenating a di- C 9 -n -phthalate having the CAS No.
- a l,2-di(isodecyl)cyclohexanedicarboxylic acid ester obtainable by hydrogenating a di(isodecyl)phthalate, consisting essentially of di-(2-propylheptyl)phthalate; 1,2-di- C 7 . 9 -cyclohexanedicarboxylic acid ester, obtainable by hydrogenating the corresponding phthalic acid ester, which comprises branched and linear C 7 . 9 - alkylester groups; respective phthalic acid esters which may be e.g. used as starting materials have the following CAS Nos.: di- C 7 . -alkylphthalate having the CAS No. Ill 381-89-6; di- C 7 -alkylphthalate having the CAS No. 68515-44-6; and di- C 9 - alkylphthalate having the CAS No. 68515-45-7.
- Cio, C 7 - ⁇ , C 9 - ⁇ and C 7 - 9 esters of 1,2 -cyclohexanedicarboxylic acids are preferably the hydrogenation products of the commercially available benzenepolycarboxylic acid esters with the trade names Jayflex ® DINP (CAS No. 68515-48-0), Jayflex ® DIDP (CAS No. 68515- 49-1), Jayflex ® DIUP (CAS No. 85507-79-5), Jayflex ® DTDP (CAS No. 68515-47- 9), Palatinol ® 91 IP, Vestinol ® 9 (CAS No.
- benzenepolycarboxylic acid esters suitable for use in the present invention include phthalates such as: Palatinol® AH (Di-(2-ethylhexyl) phthalate; Palatinol® AH L (Di-(2-ethylhexyl) phthalate); Palatinol® C (Dibutyl phthalate); Palatinol® IC (Diisobutyl phthalate); Palatinol® N (Diisononyl phthalate); Palatinol® Z (Diisodecyl phthalate) Palatinol® 10-P (Di-(2- Propylheptyl) phthalate); Palatinol® 71 IP (
- adipates such as: PlastomoU® DOA (Di-(2- ethylhexyl) adipate) and PlastomoU® DNA (Diisononyl adipate).
- suitable commercially available materials are Vestinol® C (DBP), Vestinol® IB (DBP), Vestinol® AH (DEHP), Witamol® 110 (61 OP) and Witamol® 118 (81 OP).
- mesopores are used as they are defined in Pure Appl. Chem., 45 (1976), 79, namely as pores whose diameter is above 50 nm (macropores) or whose diameter is from 2 nm and 50 nm (mesopores).
- the one or more catalytically active metals are deposited on a specific catalyst support.
- This catalyst support is prepared from one or more ordered mesoporous materials.
- Preferred ordered mesoporous materials that may be used in the present invention are those ordered mesoporous materials that may be synthesized using amphiphilic compounds as directing agents. Examples of such materials are described in U.S. Patent No. 5 250 282, the whole contents of which are hereby incorporated by reference. Examples of amphiphilic compounds are also provided in Winsor, Chemical Reviews, 68(1), 1968. Other suitable ordered mesoporous materials of this type are also described in "Review of Ordered Mesoporous Materials", U. Ciesla and F. Schuth, Microporous and Mesoporous Materials, 27, (1999), 131-49.
- Such materials include but are not limited to materials designated as SB A (Santa Barbara) such as SBA-2, SBA-15 and SBA-16, materials designated as FSM (Folding Sheet Mechanism) such as FSM-16 and KSW-2, materials designated as MSU (Michigan State) such as MSU-S and MSU-X, materials designated as TMS or Transition Metal Sieves, materials designated as FMMS or functionalized monolayers on mesoporous supports and materials designated as APM or Acid Prepared Mesostructure.
- Particularly preferred ordered mesoporous materials are the silicate or aluminosilicate ordered mesoporous materials designated as M41S such as MCM-41, MCM-48 and MCM-50.
- MCM-41 and MCM-48 are the mesoporous silicas designated as MCM-41 and MCM-48.
- MCM-41 is particularly preferred and has a hexagonal arrangement of uniformly sized mesopores.
- MCM-41 molecular sieve materials are described in detail in US 5 098 684, the whole contents of which are hereby incorporated by reference.
- the MCM-41 molecular sieves generally have a SiO 2 /Al 2 O 3 molar ratio when alumina is present that is greater than 100, preferably greater than 200, and most preferably greater than 300.
- the hydrogenation process utilizes a catalyst, which comprises a hydrogenation function in the form of a metal on a support material comprising one or more ordered mesoporous materials with a unique structure and pore geometry as described below.
- Preferred ordered mesoporous materials are inorganic, porous, non-layered materials which, in their calcined forms exhibit an X- ray diffraction pattern with at least one peak at a d-spacing greater than about 18 Angstrom Units (A). They also have a benzene adsorption capacity of greater than 15 grams of benzene per 100 grams of the material at 50 torr and 25° C.
- the support material is characterized by a substantially uniform hexagonal honeycomb microstructure with uniform pores having a cell diameter greater than 2 nm and typically in the range of 2 to 50 nm, preferably 3 to 30 nm and most preferably from 3 to 20 nm.
- MCM-41 an ordered mesoporous material identified as MCM-41, which is usually synthesized as a metallosilicate with Broensted acid sites by incorporating a tetrahedrally coordinated trivalent element such as Al, Ga, B, or Fe within the silicate framework.
- MCM-41 ordered mesoporous material identified as MCM-41, which is usually synthesized as a metallosilicate with Broensted acid sites by incorporating a tetrahedrally coordinated trivalent element such as Al, Ga, B, or Fe within the silicate framework.
- the preferred forms of these materials are the aluminosilicates although other metallosilicates may also be utilized.
- MCM-41 is characterized by a microstructure with a uniform, hexagonal arrangement of pores with diameters of at least about 2 nm: after calcination it exhibits an X-ray diffraction pattern with at least one d- spacing greater than about 18 A and a hexagonal electron diffraction pattern that can be indexed with a dioo value of greater than about 18 A, which corresponds to the d- spacing of the peak in the X-ray diffraction pattern.
- This material is described below and in detail in Ser. No. 07/625,245, now U.S. Pat. No. 5,098,684 (Kresge et al) and U.S. Patent No. 5,102,643 to Kresge et al., both of which are incorporated by reference herein in their entirety.
- the ordered mesoporous materials may be crystalline, that is having sufficient order to provide a diffraction pattern such as, for example, by X-ray, electron or neutron diffraction, following calcination, with at least one peak.
- a diffraction pattern such as, for example, by X-ray, electron or neutron diffraction, following calcination, with at least one peak.
- These mesoporous materials may be characterized by their structure, which includes large pore windows as well as high sorption capacities.
- Ordered mesoporous materials as used in the present invention can be distinguished from other porous inorganic solids by the regularity of their large open pores, whose pore size more nearly resembles that of amorphous or paracrystalline materials, but whose regular arrangement and uniformity of size (pore size distribution within a single phase of, for example, +/-25%, usually +/- 15% or less of the average pore size of that phase) resemble more those of crystalline framework materials such as zeolites.
- the term "hexagonal” is intended to encompass not only materials that exhibit mathematically perfect hexagonal symmetry within the limits of experimental measurement, but also those with significant observable deviations from that ideal state.
- a working definition as applied to the microstructure of the present invention would be that most channels in the material would be surrounded by six nearest neighbor channels at roughly the same distance. Defects and imperfections will cause significant numbers of channels to violate this criterion to varying degrees, depending on the quality of the material's preparation. Samples which exhibit as much as +/- 25% random deviation from the average repeat distance between adjacent channels still clearly give recognizable images of the present ordered mesoporous materials.
- the ordered mesoporous materials as used for preparation of the catalyst support preferably have the following composition:
- W is a divalent element, such as a divalent first row transition metal, e.g. manganese, cobalt and iron, and/or magnesium, preferably cobalt;
- X is a trivalent element, such as aluminium, boron, iron and/or gallium, preferably aluminium;
- Y is a tetravalent element such as silicon and/or germanium, preferably silicon;
- Z is a pentavalent element, such as phosphorus;
- M is one or more ions, such as, for example, ammonium, Group IA, DA and VJIB ions, usually hydrogen, sodium and/or fluoride ions;
- n is the charge of the composition excluding M expressed as oxides;
- q is the weighted molar 1 average valence of M;
- n/q is the number of moles or mole fraction of M;
- a, b, c, and d are mole fractions of W, X, Y and 1
- R is the total organic material not included in M as an ion
- r is the coefficient for R, i.e. the number of moles or mole fraction of R.
- the M and R components are associated with the material as a result of their presence during synthesis of the material and are easily removed or, in the case of M, replaced by post-synthesis methods hereinafter more particularly described.
- the original M e.g. ammonium, sodium or chloride
- ions of the as-synthesised material can be replaced in accordance with techniques well known in the art, at least in part, by ion exchange with other ions.
- Preferred replacing ions include metal ions, hydrogen ions, hydrogen precursor, e.g.
- ammonium, ions and mixtures thereof Other ions rare earth metals and metals of Groups IA (e.g. K), UA (e.g. Ca), NUA (e.g. Mn), NJJLA (e.g. ⁇ i),IB (e.g. Cu), D-B (e.g. Zn), ⁇ iB (e.g. In), 1NB (e.g. Sn), and VUB (e.g. F) of the Periodic Table of the Elements (Sargent- Welch Co. Cat. No. S-18806, 1979) and mixtures thereof.
- IA e.g. K
- UA e.g. Ca
- NUA e.g. Mn
- NJJLA e.g. ⁇ i
- IB e.g. Cu
- D-B e.g. Zn
- ⁇ iB e.g. In
- 1NB e.g. Sn
- VUB e.g. F
- the preferred ordered mesoporous materials for use in the process of the present invention are ordered mesoporous silicas.
- the most preferred ordered mesoporous silicas are those designated as M41S, with the most preferred being MCM-41.
- the catalyst may consist solely of one or more active hydrogenation metals deposited on the surfaces of one or more ordered mesoporous materials, h this embodiment the catalyst is free of added inorganic binder.
- the ordered mesoporous material with or without active metal deposited thereon may be shaped into a wide variety of particle sizes.
- the particles can be in the form of a powder, a granule, or a molded product, such as an extrudate having particle size sufficient to pass through a 2 mesh (Tyler) screen and be retained on a 400 mesh (Tyler) screen.
- the ordered mesoporous materials may be formed into composites with matrix materials resistant to the temperatures and other conditions employed in the hydrogenation process.
- Such materials include active and inactive materials and synthetic or naturally occurring zeolites as well as inorganic materials such as clays and/or oxides such as alumina, silica or silica-alumina. The latter may be either naturally occurring or in the form of gelatinous precipitates or gels including mixtures of silica and metal oxides.
- a material in conjunction with the zeolite i.e., combined therewith or present during its synthesis, which itself is catalytically active may change the conversion and/or selectivity of the catalyst.
- These materials may be incorporated into naturally occurring clays, e.g., bentonite and kaolin, to improve the crush strength of the catalyst under commercial operating conditions and function as binders or matrices for the catalyst.
- the ordered mesoporous material may be composited with the matrix material in amounts from 99:01 to 05:95 by weight, preferably from 99:01 to 10:90, more preferably from 99:01 to 20:80, and most preferably from 99:01 to 50:50 ordered mesoporous material: matrix material.
- the additional matrix material is kept to a minimum typically less than 50 wt % of the combined weight of ordered mesoporous material and matrix material, ideally less than 40 wt%, preferably less than 30 wt%, more preferably less than 20 wt%, more preferably less than 15 wt%, most preferably less than 10 wt% and in a most preferred embodiment less than 5 wt%.
- Formation of the composition may be achieved by conventional means including mulling the materials together followed by extrusion of pelletizing into the desired finished catalyst particles.
- the additional matrix material is macroporous or is a material of mixed porosity i.e. both macroporous and mesoporous.
- the materials of mixed porosity may have a pore distribution in which from about 5 to about 50%, preferably from about 10 to about 45%, more preferably from about 10 to about 30 and in particular from about 15 to about 25%, of the pore volume is formed by macropores having pore diameters in the range from about 50 nm to about 10,000 nm and from about 50 to about 95%, preferably from about 55 to about 90%, more preferably from about 70 to about 90% and in particular from about 75 to about 85%, of the pore volume is formed by mesopores having a pore diameter of from about 2 to about 50 nm where in each case the sum of the pore volumes adds up to 100%.
- the total pore volume of the mixed porosity material is from about 0.05 to 1.5 cm 3 /g, preferably from 0.1 to 1.2 cm 3 /g and in particular from about 0.3 to 1.0 cm 3 /g.
- the mean pore diameter of the mixed porosity material is preferably from about 5 to 20 nm, preferably from about 8 to about 15 nm and in particular from about 9 to about 12 nm.
- the surface area of the mixed porosity material is preferably from about 50 to about 500 m /g, more preferably from about 200 to about 350 m /g and in particular from about 250 to about 300 m 2 /g of the support.
- the surface area of the macroporous materials and mixed porosity materials may be determined by the BET method using N 2 adsorption, in particular in accordance with DIN 66131.
- the mean pore diameter and the size distribution may be determined by Hg porosimetry, in particular in accordance with DIN 66133.
- the macroporous materials and mixed porosity materials that may be used are, for example, macropore containing activated carbon, silicon carbide, aluminum oxide, silicon dioxide, titanium dioxide, zirconium dioxide, magnesium oxide, zinc oxide or mixtures of two or more thereof, with preference being given to using macropore containing alumina.
- the finished catalyst may be a composition comprising a support matrix of from 90 to 10% by weight MCM-41 and 10 to 90% by weight alumina, preferably 80 to 20%) by weight MCM-41 and 20 to 80% by weight alumina, more preferably 80 to 40% by weight MCM-41 and 20 to 60% by weight of alumina, and as active metal component from 0.01 to 5 wt % Pt, preferably from 0.05 to 1 wt % Pt, more preferably from 0.1 to 0.5 wt % Pt and most preferably 0.15 to 0.4 wt % Pt either alone or in combination with 0.01 to 5 wt % Pd, preferably from 0.05 to 2 wt % Pd, more preferably from 0.1 to 1.5 wt % Pd and most preferably 0.15 to 1.0 wt % Pd.
- a particularly preferred composition comprises a support matrix of 70 to 60 %, ideally 65% by weight MCM-41 and 30 to 40%, ideally 35% by weight alumina, and as active metal component, 0.1 to 0.4, ideally 0.3 wt % Pt alone or in combination with 0.4 to 1.5, ideally 0.9 wt % Pd.
- the catalyst used in the present invention comprises one or more active hydrogenation metals deposited on one or more ordered mesoporous support materials free of added inorganic binder material.
- the hydrogenation catalyst includes an active metal as the hydrogenation- dehydrogenation component.
- the hydrogenation-dehydrogenation component is provided by a metal or combination of metals.
- Active metals that may be used are preferably one or more metals of transition group Vi ⁇ of the Periodic Table. Preference is given to using platinum, rhodium, palladium, cobalt, nickel or ruthenium or a mixture of two or more thereof as active metal. A particular preference is given to using ruthenium, platinum, palladium or mixtures of two or more thereof. A particularly preferred active metal is ruthenium.
- the content of the metal component will vary according to its catalytic activity.
- the highly active noble metals may be used in smaller amounts than the less active base metals. For example, about 1 wt. percent or less palladium or platinum will be effective.
- the present support materials are, however, notable in that they are capable of including a greater proportion of metal than previous support materials because of their extraordinarily large surface area.
- the metal component may exceed about 30 percent in a monolayer.
- the hydrogenation component can be exchanged onto the support material, impregnated into it or physically admixed with it.
- the active metal content is generally from about 0.01 to about 30% by weight, preferably from about 0.01 to about 5% by weight and in particular from about 0.1 to about 5% by weight, in each case based on the total weight of the catalyst used.
- a preferred catalyst is one that comprises ruthenium alone or in combination with one or more additional active metals at a total content of less than 5% by weight of active metal and preferably at a total content of less than 2% by weight of active metal.
- the content of ruthenium is from about 0.01 to 2%, more preferably 0.1 to 1% by weight of the total catalyst.
- the catalysts according to the present invention may be produced industrially by application of the one or more catalytically active metals to the desired support.
- the application may be achieved by steeping the support in aqueous metal salt solutions, for example ruthenium or palladium or platinum salt solutions, by spraying appropriate metal salt solutions onto the support or by other suitable methods.
- Suitable metal salts for preparing the metal salt solutions are the nitrates, nitrosyl nitrates, halides, carbonates, carboxylates, acetylacetonates, chloro complexes, nitrito complexes or ammine complexes of the corresponding metals, with preference being given to the nitrates and nitrosyl nitrates and most preferably the nitrosyl nitrates.
- the metal salts or metal salt solutions can be applied simultaneously or in succession.
- the ordered mesoporous material is used in combination with a matrix material it is preferred that the active hydrogenation metal is applied to the ordered mesoporous material before it is combined with the matrix material.
- the ordered mesoporous materials either with or without matrix material, which have been coated or impregnated with the metal salt solution, may subsequently be dried, preferably at from 100 to 150° C. If desired, these supports can be calcined at from 200 to 600° C, preferably from 350 to 450° C.
- the dried and/or calcined ordered mesoporous materials either with or without matrix material are subsequently activated by treatment in a gas stream comprising free hydrogen at from 30 to 600° C, preferably from 100 to 450° C, and in particular from 100 to 300° C.
- the gas stream preferably consists of from 50 to 100% by volume of H 2 and from 0 to 50% by volume of N 2 .
- the support can be dried at from 100 to 150° C and, if desired, calcined at from 200 to 600° C after each application or impregnation.
- % dispersion (% of metal atoms that populate the surface of the metal particles) can be estimated since a properly chosen titrant used in the chemisorption measurements adsorbs only on metal atoms populating the surface. Consequently higher dispersion values indicate smaller particles with more of the metal atoms populating the surface. For many hydrogenation reactions, activity correlates with dispersion.
- the preferred method for determining metal dispersion is by using hydrogen as the chemisorption probe molecule under high vacuum static conditions as follows.
- the sample is held at a temperature of 40°C and an 8-point isotherm (with pressures between 80 and 400 torr) is obtained using H 2 as the chemisorption probe molecule.
- the linear portion of this isotherm is extrapolated to zero pressure to obtain the total quantity of hydrogen chemisorbed; this is the combined dispersion.
- the sample is then evacuated at 40°C to remove any weakly adsorbed hydrogen and the titration repeated to determine what is referred to as weak adsorption isotherm.
- the linear portion of this weak adsorption isotherm is extrapolated to zero pressure to obtain the quantity of weakly chemisorbed hydrogen. Subtraction of these two values for combined dispersion and weak dispersion yields the strongly held chemisorbed quantity.
- this method provides values for the total metal dispersion, the dispersion due to weakly chemisorbed hydrogen and dispersion due to strongly chemisorbed hydrogen.
- the value for the strongly chemisorbed hydrogen is an accurate indication of metal dispersion.
- the metal dispersion figures provided are based on the total chemisorbed probe and are not split into strong and weak components.
- the hydrogenation catalyst used have dispersion values relating to the strongly chemisorbed component in excess of 20% more preferably in excess of 25% and most preferably in excess of 30%.
- total dispersion values in excess of 45% preferably in excess of 50%, more preferably in excess of 55%, and most preferably in excess of 60% are achieved.
- 40% or more of the total metal dispersion relates to the strongly chemisorbed component, more preferably 45 % or more and most preferably 50% or more.
- the hydrogenation metal salt solutions used may be combined with one or more amines to form a mixture with the solution and this mixture is applied to the ordered mesoporous support.
- Preferred amines include alkanolamines such as triethanolamine or amino acids such as L-arginine.
- the hydrogenation is generally carried out at from about 50 to 250° C, preferably from about 70 to 220° C, most preferably 75 to 160 ° C.
- the pressures used here are generally above 10 bar, more preferably from about 20 to about 300 bar, and most preferably 50 to 300 bar, especially 80 to 300 bar.
- the pressure is greater than 100 bar and more preferably greater than 130 bar.
- the process of the present invention may be carried out either continuously or batchwise, with preference being given to carrying out the process continuously.
- the amount of the benzenepolycarboxylic acid or ester to be hydrogenated or of the mixture of two or more thereof is from about 0.05 to about 3 kg per liter of catalyst per hour, preferably from about 0.1 to about 2 kg per liter of catalyst per hour, more preferably from 0.2 to 1.5 kg per liter of catalyst per hour and most preferably from 0.2 to about 1 kg per liter of catalyst per hour.
- hydrogenation gases it is possible to use any gases which comprise free hydrogen and do not contain harmful amounts of catalyst poisons such as CO, CO , COS, H S and amines.
- catalyst poisons such as CO, CO , COS, H S and amines.
- waste gases from a reformer can be used. Preference is given to using pure hydrogen as the hydrogenation gas.
- the hydrogenation of the present invention can be carried out in the presence or absence of a solvent or diluent, i.e. it is not necessary to carry out the hydrogenation in solution.
- a solvent or diluent preference is given to using a solvent or diluent. Any suitable solvent or diluent may be used. The choice is not critical as long as the solvent or diluent used is able to form a homogeneous solution with the benzenepolycarboxylic acid or ester to be hydrogenated.
- the solvents or diluents may also comprise water although it is preferred that they are free of water.
- suitable solvents or diluents include the following: straight-chain or cyclic ethers such as tetrahydrofuran or dioxane, and also aliphatic alcohols in which the alkyl radical preferably has from 1 to 10 carbon atoms, in particular from 3 to 6 carbon atoms.
- alkyl radical preferably has from 1 to 10 carbon atoms, in particular from 3 to 6 carbon atoms.
- alcohols which are preferably used, are i-propanol, n-butanol, i- butanol and n-hexanol. Mixtures of these or other solvents or diluents can likewise be used.
- the amount of solvent or diluent used is not restricted in any particular way and can be selected freely depending on requirements. However, preference is given to amounts which lead to a 10-70% strength by weight solution of the benzenepolycarboxylic acid or ester to be hydrogenated.
- the process of the present invention it is also possible to use one or more derivates of benzenepolycarboxylic acids in the unpurified state that is in the presence of one or more starting materials for their manufacture such as for example alcohol in the case of ester derivatives. Also present may be traces of monoester derivatives, un-reacted acid such as phthalic acid, sodium monoester derivatives and sodium salts of the acids, hi this aspect the benzenecarboxylic acid derivative is hydrogenated prior to purification and after hydrogenation is then sent to process finishing for stripping, drying and polishing filtration.
- the benzenecarboxylic acid derivative may be an intermediate feed containing high levels of alcohol in the case of ester derivatives. There maybe present 5 to 30% excess alcohol than that required to achieve complete esterification of the acid, hi one embodiment there may be an intermediate feed containing 8 to 10 wt% isononyl alcohol in di-isononyl phthalate.
- the desired products are one or more cyclohexyl materials derived from the hydrogenation of the corresponding benzenepolycarboxylic acid or derivatives thereof.
- the benzenepolycarboxylic acid or derivatives thereof are converted to the desired product with a high degree of selectivity and with the maximum conversion possible of the benzenepolycarboxylic acid or derivatives thereof. Hydrogenations of this type often result in undesirable by-products of relatively low molecular weight and low boiling point; these by-products are referred to as "lights".
- lights are defined as materials in the as hydrogenated reaction product that are eluted before the object cyclohexyl materials when the as hydrogenated reaction product is analyzed by Gas Liquid Chromatography. Details for one suitable method for determining the "lights” content of a product obtained by the process of the present invention is provided in the specific examples. When using the process of the present invention it is possible to obtain greater than 95% conversion of the starting material (one or more benzenepolycarboxylic acid or derivatives thereof), whilst at he same time producing less than 1.5 % by weight based on the total weight of reaction product of "lights".
- the product obtained directly from the hydrogenation reaction ideally contains the object cyclohexyl derivative(s) in an amount that equates to 97 or greater mole % conversion of the starting material, preferably 98.5 or greater mole% conversion, more preferably 99 or greater mole% conversion, and most preferably 99.9 or greater mole % conversion.
- the product obtained directly from the hydrogenation reaction ideally contains 1.3% or less, preferably 1.0% or less, more preferably 0.75 % or less, even more preferably 0.5 % or less, and in the most preferable embodiment less than 0.3 % by weight based on the total weight of the reaction product of "lights".
- CMA Cetyltrimethylammonium hydroxide prepared by contacting a 29 wt. % N,N,N- trimethyl- 1-hexadecylammonium chloride solution with a hydroxide- for halide exchange resin, 1.7 pbw sodium aluminate, 41.1 pbw tetramethylammonium silicate (10% aqueous solution), and 10.5 pbw precipitated hydrated silica (HiSil)
- the product was identified as MCM-41 with an X-ray diffraction pattern that included a very strong relative intensity line at 38.4 +/- 2.0 A, and weak lines at 22.6 +/- 1.0, 20.0 +/- 1.0, and 15.2+/- A.
- the mixture was crystallized at 150°C for 20 hours with stirring under autogeneous pressure.
- the resulting product was recovered by filtration and dried in air at ambient temperature.
- the product was then calcined at 540°C for one hour in nitrogen, followed by six hours in air.
- the product was identified as MCM-41.
- the calcined product has a surface area of 903 m 2 /g and a pore size (determined by nitrogen adsorption) of 3.8 nm.
- the analyses are as follows:
- a solution was prepared by combining with stirring 16.6 grams of ruthenium (in) nitrosyl nitrate aqueous solution with 25.7 grams of triethanolamine and 25.7 grams of distilled water. This solution was added slowly to 25 grams of MCM-41 of Example 2 and dried overnight at 100°C. The catalyst was then calcined to 400°C for three hours in flowing air. The ruthenium content was a nominal 0.5%.
- a solution was prepared by combining with stirring 16.6 grams of ruthenium (III) nitrosyl nitrate aqueous solution with 10.7 grams of DI water and 10.7 grams of triethanolamine. This solution was added slowly to 25 grams of 1/16-inch MCM-41 (Example 2) bound with gamma alumina extrudates (65/35 weight % MCM- 41/gamma alumina) and dried overnight at 100°C. The catalyst was then calcined to 400°C for three hours in flowing air. The ruthenium content was a nominal 0.5%.
- a solution was prepared by combining with stirring 16.6 grams of ruthenium (III) nitrosyl nitrate aqueous solution with 9.0 grams of DI water. This solution was added slowly to 25 grams of 1/16-inch gamma alumina extrudates and dried overnight at 100°C. The catalyst was then calcined to 400°C for three hours in flowing air. The ruthenium content was a nominal 0.5%.
- a solution was prepared by combining with stirring 16.6 grams of ruthenium (in) nitrosyl nitrate aqueous solution with 4.2 grams of DI water and 4.2 grams of triethanolamine. This solution was added slowly to 25 grams of 1/16-inch gamma alumina extrudates and dried overnight at 100°C. The catalyst was then calcined to 400°C for three hours in flowing air. The ruthenium content was a nominal 0.5%.
- Example 8 The catalysts used in the hydrogenation of Example 8 were activated under two sets of conditions a) and b) as follows: a) Catalyst particles (10/20 mesh) were loaded into a stainless-steel catalyst basket then installed in a 300 cm autoclave. Metal reduction was conducted under a continuous atmospheric hydrogen flow of ⁇ 100 cm 3 min "1 at 200° C for 18 hours, b) Catalyst particles (10/20 mesh) were loaded into a stainless-steel catalyst basket then installed in a 300 cm autoclave. Metal reduction was conducted under a static hydrogen pressure of 1250 psig (approx 86 bar) at 200° C for 14 hours.
- Example 8 - Hydrogenation of Di-isononyl phthalate fDINP Di-isononyl phthalate fDINP
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Abstract
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AU2003292041A AU2003292041A1 (en) | 2002-11-20 | 2003-11-18 | Hydrogenation of benzene polycarboxylic acids or derivatives thereof |
EP03767568.3A EP1567470B1 (en) | 2002-11-20 | 2003-11-18 | Hydrogenation of benzene polycarboxylic acids or derivatives thereof |
US10/535,531 US7595420B2 (en) | 2002-11-20 | 2003-11-18 | Hydrogenation of benzene polycarboxylic acids or derivatives thereof |
US13/006,006 US8203017B2 (en) | 2002-11-20 | 2011-01-13 | Hydrogenation of benzene polycarboxylic acids or derivatives thereof |
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GB0227087.4 | 2002-11-20 |
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US12/426,704 Continuation US7893295B2 (en) | 2002-11-20 | 2009-04-20 | Hydrogenation of benzene polycarboxylic acids or derivatives thereof |
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Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5098684A (en) | 1990-01-25 | 1992-03-24 | Mobil Oil Corp. | Synthetic mesoporous crystaline material |
US5250282A (en) | 1990-01-25 | 1993-10-05 | Mobil Oil Corp. | Use of amphiphilic compounds to produce novel classes of crystalline oxide materials |
US5286898A (en) | 1993-06-15 | 1994-02-15 | Eastman Kodak Company | Low pressure process for the hydrogenation of dimethyl benzenedicarboxylates to the corresponding dimethyl cyclohexanedicarboxlates |
US5319129A (en) | 1993-06-15 | 1994-06-07 | Eastman Kodak Company | Preparation of dimethyl cyclohexanedicarboxylates |
US5837639A (en) | 1990-01-25 | 1998-11-17 | Mobil Oil Corporation | Hydroprocessing catalyst |
WO1999032427A1 (en) | 1997-12-19 | 1999-07-01 | Basf Aktiengesellschaft | Method for hydrogenating benzene polycarboxylic acids or derivatives thereof by using a catalyst containing macropores |
US5951962A (en) | 1996-09-23 | 1999-09-14 | Basf Aktiengesellschaft | Mesoporous silica, its preparation and its use |
US6248924B1 (en) * | 1996-06-19 | 2001-06-19 | Basf Aktiengesellschaft | Process for reacting an organic compound in the presence of a supported ruthenium catalyst |
WO2003103830A1 (en) * | 2002-06-10 | 2003-12-18 | Oxeno Olefinchemie Gmbh | Catalyst and method for hydrogenating aromatic compounds |
US7625245B1 (en) | 2008-07-24 | 2009-12-01 | Lotes Co., Ltd. | Low-profile electrical connector and device thereof |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3027398A (en) * | 1960-02-01 | 1962-03-27 | Du Pont | Process for preparing dimethyl 1, 4-cyclohexanedicarboxylate |
US3334149A (en) * | 1964-07-21 | 1967-08-01 | Eastman Kodak Co | Plural stage hydrogenation of dialkyl terephthalate using palladium and then copper chromite |
DE2823165A1 (en) | 1978-05-26 | 1979-11-29 | Bayer Ag | PROCESS FOR MANUFACTURING CYCLOALIPHATIC CARBONIC ACID ESTERS |
JP3106411B2 (en) | 1992-12-21 | 2000-11-06 | 東和化成工業株式会社 | Method for producing 1,4-cyclohexanedicarboxylic acid |
EP0813906A3 (en) * | 1996-06-19 | 1998-11-18 | Basf Aktiengesellschaft | Process for converting an organic compound in presence of a supported ruthenium catalyst |
KR100634254B1 (en) * | 2001-02-16 | 2006-10-16 | 바스프 악티엔게젤샤프트 | Method for producing cyclohexane dicarboxylic acids and the derivatives thereof |
DE10147776A1 (en) | 2001-09-27 | 2003-07-03 | Oxeno Olefinchemie Gmbh | Process for the preparation of alicyclic polycarboxylic acid esters from partial esters of aromatic polycarboxylic acids |
GB0227087D0 (en) * | 2002-11-20 | 2002-12-24 | Exxonmobil Chem Patents Inc | Hydrogenation of benzene polycarboxylic acids or derivatives thereof |
GB0227086D0 (en) | 2002-11-20 | 2002-12-24 | Exxonmobil Res & Eng Co | Hydrogenation processes |
US7285512B2 (en) | 2004-08-31 | 2007-10-23 | Exxonmobile Research And Engineering Company | Selective hydrodesulfurization catalyst |
-
2002
- 2002-11-20 GB GBGB0227087.4A patent/GB0227087D0/en not_active Ceased
-
2003
- 2003-11-18 AU AU2003292041A patent/AU2003292041A1/en not_active Abandoned
- 2003-11-18 CN CNB2003801063046A patent/CN100363323C/en not_active Expired - Fee Related
- 2003-11-18 WO PCT/EP2003/012881 patent/WO2004046078A1/en active Search and Examination
- 2003-11-18 US US10/535,531 patent/US7595420B2/en not_active Expired - Fee Related
- 2003-11-18 EP EP03767568.3A patent/EP1567470B1/en not_active Expired - Lifetime
-
2009
- 2009-04-20 US US12/426,704 patent/US7893295B2/en not_active Expired - Fee Related
-
2011
- 2011-01-13 US US13/006,006 patent/US8203017B2/en not_active Expired - Fee Related
Patent Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5098684A (en) | 1990-01-25 | 1992-03-24 | Mobil Oil Corp. | Synthetic mesoporous crystaline material |
US5102643A (en) | 1990-01-25 | 1992-04-07 | Mobil Oil Corp. | Composition of synthetic porous crystalline material, its synthesis |
US5250282A (en) | 1990-01-25 | 1993-10-05 | Mobil Oil Corp. | Use of amphiphilic compounds to produce novel classes of crystalline oxide materials |
US5837639A (en) | 1990-01-25 | 1998-11-17 | Mobil Oil Corporation | Hydroprocessing catalyst |
US5286898A (en) | 1993-06-15 | 1994-02-15 | Eastman Kodak Company | Low pressure process for the hydrogenation of dimethyl benzenedicarboxylates to the corresponding dimethyl cyclohexanedicarboxlates |
US5319129A (en) | 1993-06-15 | 1994-06-07 | Eastman Kodak Company | Preparation of dimethyl cyclohexanedicarboxylates |
US6248924B1 (en) * | 1996-06-19 | 2001-06-19 | Basf Aktiengesellschaft | Process for reacting an organic compound in the presence of a supported ruthenium catalyst |
US5951962A (en) | 1996-09-23 | 1999-09-14 | Basf Aktiengesellschaft | Mesoporous silica, its preparation and its use |
WO1999032427A1 (en) | 1997-12-19 | 1999-07-01 | Basf Aktiengesellschaft | Method for hydrogenating benzene polycarboxylic acids or derivatives thereof by using a catalyst containing macropores |
US6284917B1 (en) * | 1997-12-19 | 2001-09-04 | Basf Aktiengesellschaft | Method for hydrogenating benzene polycarboxylic acids or derivatives thereof by using a catalyst containing macropores |
WO2003103830A1 (en) * | 2002-06-10 | 2003-12-18 | Oxeno Olefinchemie Gmbh | Catalyst and method for hydrogenating aromatic compounds |
US7625245B1 (en) | 2008-07-24 | 2009-12-01 | Lotes Co., Ltd. | Low-profile electrical connector and device thereof |
Non-Patent Citations (4)
Title |
---|
PURE APPL. CHEM., vol. 45, 1976, pages 79 |
SARGENT-WELCH, VIIB (E.G. F) OF THE PERIODIC TABLE OF THE ELEMENTS, vol. S, 1979, pages 18806 |
U. CIESLA; F. SCHUTH: "Review of Ordered Mesoporous Materials", MICROPOROUS AND MESOPOROUS MATERIALS, vol. 27, 1999, pages 131 - 49 |
WINSOR, CHEMICAL REVIEWS, vol. 68, no. 1, 1968 |
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Also Published As
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US20090234152A1 (en) | 2009-09-17 |
AU2003292041A1 (en) | 2004-06-15 |
US7595420B2 (en) | 2009-09-29 |
CN1726179A (en) | 2006-01-25 |
US20110112322A1 (en) | 2011-05-12 |
EP1567470B1 (en) | 2013-06-05 |
GB0227087D0 (en) | 2002-12-24 |
US20060247461A1 (en) | 2006-11-02 |
US8203017B2 (en) | 2012-06-19 |
US7893295B2 (en) | 2011-02-22 |
EP1567470A1 (en) | 2005-08-31 |
CN100363323C (en) | 2008-01-23 |
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