WO2003074608A3 - Weatherable styrenic blends with improved translucency - Google Patents

Weatherable styrenic blends with improved translucency Download PDF

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Publication number
WO2003074608A3
WO2003074608A3 PCT/US2003/006066 US0306066W WO03074608A3 WO 2003074608 A3 WO2003074608 A3 WO 2003074608A3 US 0306066 W US0306066 W US 0306066W WO 03074608 A3 WO03074608 A3 WO 03074608A3
Authority
WO
WIPO (PCT)
Prior art keywords
vinyl
poly
blends
weatherable
styrenic blends
Prior art date
Application number
PCT/US2003/006066
Other languages
French (fr)
Other versions
WO2003074608A2 (en
Inventor
Satish Kumar Gaggar
Kwan Hongladarom
Original Assignee
Gen Electric
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Gen Electric filed Critical Gen Electric
Priority to AU2003212456A priority Critical patent/AU2003212456A1/en
Priority to MXPA04008376A priority patent/MXPA04008376A/en
Priority to JP2003573067A priority patent/JP4921695B2/en
Priority to EP03709396A priority patent/EP1481026B1/en
Priority to DE60307797T priority patent/DE60307797T2/en
Publication of WO2003074608A2 publication Critical patent/WO2003074608A2/en
Publication of WO2003074608A3 publication Critical patent/WO2003074608A3/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/18—Homopolymers or copolymers of nitriles
    • C08L33/20—Homopolymers or copolymers of acrylonitrile
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Laminated Bodies (AREA)
  • Graft Or Block Polymers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Rubber modified weatherable styrenic blends with improved transparency and colorability are disclosed. A matrix phase of poly(alkyl alkylacrylate) and vinyl carboxylic acid ester-vinyl aromatic-vinyl cyanide is combined with a rubbery graft phase of a poly(alkyl acrylate) rubber substrate grafted with a vinyl aromatic-vinyl cyanide superstrate copolymer to provide acrylate-styrene-acrylonitrile type (ASA) compositions.
PCT/US2003/006066 2002-02-28 2003-02-27 Weatherable styrenic blends with improved translucency WO2003074608A2 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
AU2003212456A AU2003212456A1 (en) 2002-02-28 2003-02-27 Weatherable styrenic blends with improved translucency
MXPA04008376A MXPA04008376A (en) 2002-02-28 2003-02-27 Weatherable styrenic blends with improved translucency.
JP2003573067A JP4921695B2 (en) 2002-02-28 2003-02-27 Acrylate-styrene-acrylonitrile (ASA) type composition with improved translucency and method for producing the same
EP03709396A EP1481026B1 (en) 2002-02-28 2003-02-27 Weatherable styrenic blends with improved translucency
DE60307797T DE60307797T2 (en) 2002-02-28 2003-02-27 WEATHER-RESISTANT STYRENE POLYMER COMPOSITIONS WITH IMPROVED LIGHT THERAPY

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/084,963 US6720386B2 (en) 2002-02-28 2002-02-28 Weatherable styrenic blends with improved translucency
US10/084,963 2002-02-28

Publications (2)

Publication Number Publication Date
WO2003074608A2 WO2003074608A2 (en) 2003-09-12
WO2003074608A3 true WO2003074608A3 (en) 2003-11-13

Family

ID=27753559

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2003/006066 WO2003074608A2 (en) 2002-02-28 2003-02-27 Weatherable styrenic blends with improved translucency

Country Status (9)

Country Link
US (1) US6720386B2 (en)
EP (1) EP1481026B1 (en)
JP (1) JP4921695B2 (en)
CN (1) CN100393799C (en)
AT (1) ATE337368T1 (en)
AU (1) AU2003212456A1 (en)
DE (1) DE60307797T2 (en)
MX (1) MXPA04008376A (en)
WO (1) WO2003074608A2 (en)

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US8969476B2 (en) * 2002-06-21 2015-03-03 Sabic Global Technologies B.V. Impact-modified compositions
US7514147B2 (en) * 2003-01-14 2009-04-07 Sabic Innovative Plastics Ip B.V. Formable thermoplastic multi-layer laminate, a formed multi-layer laminate, an article, and a method of making an article
KR20050106447A (en) * 2003-02-21 2005-11-09 제너럴 일렉트릭 캄파니 Weatherable multilayer articles and method for their preparation
US7270882B2 (en) * 2003-02-21 2007-09-18 General Electric Company Weatherable multilayer articles and method for their preparation
EP1625172B1 (en) * 2003-05-09 2006-09-06 General Electric Company Impact-modified compositions and method
US20040225034A1 (en) * 2003-05-09 2004-11-11 General Electric Company Impact-modified compositions and method
US7135233B2 (en) * 2003-10-20 2006-11-14 General Electric Company Multi-layer composites
US20050144309A1 (en) * 2003-12-16 2005-06-30 Intel Corporation, A Delaware Corporation Systems and methods for controlling congestion using a time-stamp
US20050171297A1 (en) * 2004-02-04 2005-08-04 General Electric Company Impact-modified compositions and method
US20050282000A1 (en) * 2004-06-16 2005-12-22 General Electric Company Multilayer composites with special visual effects
US20060069208A1 (en) * 2004-09-29 2006-03-30 General Electric Company Weatherable resinous composition with improved heat resistance
JP4699031B2 (en) * 2005-01-13 2011-06-08 日東電工株式会社 Adhesive products and substrates for adhesive products
DE102005022635B4 (en) 2005-05-11 2018-05-30 Ineos Styrolution Europe Gmbh Thermoplastic molding compounds with improved dyeability
KR100645065B1 (en) * 2005-06-23 2006-11-10 삼성전자주식회사 Fin fet and non-volatile memory device having the same and method of forming the same
KR100771355B1 (en) * 2005-08-29 2007-10-29 주식회사 엘지화학 Thermoplastic resin composition
US20070077405A1 (en) * 2005-09-30 2007-04-05 Basf Corporation Inorganic/organic-filled styrenic thermoplastic door skins
KR100994976B1 (en) * 2007-10-02 2010-11-18 주식회사 엘지화학 Optical films and method for fabricating the same
US20090269531A1 (en) * 2007-10-26 2009-10-29 Dominique Arnould Resinous compositions, articles made therefrom and process
CN101225211B (en) * 2007-12-17 2010-06-16 胡大忠 ASA modified material
JP5476581B2 (en) * 2008-06-30 2014-04-23 独立行政法人産業技術総合研究所 Thermochromic fine particles, dispersion thereof, production method thereof, and light control paint, light control film and light control ink
US20100009207A1 (en) * 2008-07-10 2010-01-14 Sabic Innovative Plastics Ip B.V. Formable thermoplastic multi-layer article, a formed multi-layer article, an article, and a method of making an article
US20100160190A1 (en) * 2008-12-19 2010-06-24 Kuvshinnikova Olga I Weatherable colored resinous composition and method
US8344043B2 (en) * 2009-12-23 2013-01-01 Cheil Industries Inc. Thermoplastic resin composition having good scratch resistance and molded article made therefrom
CN102363642B (en) * 2011-07-01 2013-06-05 深圳市科聚新材料有限公司 Graft acrylonitile-styrene-acrylate (ASA) material and preparation method
KR101531613B1 (en) * 2011-11-24 2015-06-25 제일모직 주식회사 Thermoplastic resin composition and molded product using the same
CN104672737B (en) * 2015-02-12 2017-12-19 深圳毅彩鸿翔新材料科技有限公司 Weatherability ASA based composites, coextrusion mold plastic products and plastic products
KR101788375B1 (en) * 2015-05-27 2017-11-16 삼성에스디아이 주식회사 Epoxy resin composition for encapsulating semiconductor device and semiconductor device encapsulated by the same
KR101949371B1 (en) 2015-10-07 2019-02-18 주식회사 엘지화학 Weather-resistant thermoplastic resin, thermoplastic resine composition containing the same and methd for preparing the composition
KR20210036945A (en) * 2018-07-24 2021-04-05 이네오스 스티롤루션 그룹 게엠베하 Polyacrylate Graft Rubber Copolymer and Thermoplastic Molding Composition
CN109337272A (en) * 2018-09-13 2019-02-15 广东锦湖日丽高分子材料有限公司 A kind of PMMA/ASA alloy resin composition and preparation method thereof
KR102332344B1 (en) * 2018-11-13 2021-11-30 주식회사 엘지화학 Thermoplastic resin composition
KR102465681B1 (en) * 2019-09-06 2022-11-11 주식회사 엘지화학 Thermoplastic resin composition and product comprising the resin composition
JP2022528145A (en) * 2019-10-07 2022-06-08 エルジー・ケム・リミテッド ASA-based resin composition, molded product containing it, and method for manufacturing the molded product.
KR102547327B1 (en) * 2019-10-07 2023-06-26 주식회사 엘지화학 Acrylate-styrene-acrylonitrile based resin composition, article comprising the same and method for manufacturing the article
WO2023041510A1 (en) 2021-09-14 2023-03-23 Ineos Styrolution Group Gmbh Asa-copolymer compositions with increased transmittance and process for the preparation thereof

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DE3134103A1 (en) * 1981-08-28 1983-03-17 Basf Ag, 6700 Ludwigshafen Thermoplastic moulding composition
US4393164A (en) * 1981-04-04 1983-07-12 Basf Aktiengesellschaft Transparent impact-resistant molding material
JPS6032811A (en) * 1983-08-02 1985-02-20 Mitsubishi Monsanto Chem Co Weatherable styrene graft copolymer
US4579909A (en) * 1984-12-18 1986-04-01 General Electric Company Ternary combination of acrylate-styrene-acrylonitrile terpolymer, poly methyl methacrylate and polycarbonate
US4666980A (en) * 1984-07-06 1987-05-19 Bayer Aktiengesellschaft Transparent moulding compositions
US4753988A (en) * 1987-02-18 1988-06-28 The Dow Chemical Company High gloss acrylate rubber-modified weatherable resins
EP0337187A2 (en) * 1988-04-09 1989-10-18 Bayer Ag Polymer blend for flexible sheets
US5104935A (en) * 1988-12-10 1992-04-14 Bayer Aktiengesellschaft Polymer mixture

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Publication number Priority date Publication date Assignee Title
US4393164A (en) * 1981-04-04 1983-07-12 Basf Aktiengesellschaft Transparent impact-resistant molding material
DE3134103A1 (en) * 1981-08-28 1983-03-17 Basf Ag, 6700 Ludwigshafen Thermoplastic moulding composition
JPS6032811A (en) * 1983-08-02 1985-02-20 Mitsubishi Monsanto Chem Co Weatherable styrene graft copolymer
US4666980A (en) * 1984-07-06 1987-05-19 Bayer Aktiengesellschaft Transparent moulding compositions
US4579909A (en) * 1984-12-18 1986-04-01 General Electric Company Ternary combination of acrylate-styrene-acrylonitrile terpolymer, poly methyl methacrylate and polycarbonate
US4753988A (en) * 1987-02-18 1988-06-28 The Dow Chemical Company High gloss acrylate rubber-modified weatherable resins
EP0337187A2 (en) * 1988-04-09 1989-10-18 Bayer Ag Polymer blend for flexible sheets
US5104935A (en) * 1988-12-10 1992-04-14 Bayer Aktiengesellschaft Polymer mixture

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Title
DATABASE WPI Section Ch Week 198514, Derwent World Patents Index; Class A13, AN 1985-083255, XP002251874 *

Also Published As

Publication number Publication date
JP2006509048A (en) 2006-03-16
ATE337368T1 (en) 2006-09-15
JP4921695B2 (en) 2012-04-25
US6720386B2 (en) 2004-04-13
MXPA04008376A (en) 2004-11-26
EP1481026A2 (en) 2004-12-01
CN1777646A (en) 2006-05-24
AU2003212456A8 (en) 2003-09-16
WO2003074608A2 (en) 2003-09-12
CN100393799C (en) 2008-06-11
EP1481026B1 (en) 2006-08-23
DE60307797D1 (en) 2006-10-05
DE60307797T2 (en) 2007-08-16
AU2003212456A1 (en) 2003-09-16
US20030162895A1 (en) 2003-08-28

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