WO1998016665A1 - Method of making cemented carbide with binder phase enriched surface zone - Google Patents
Method of making cemented carbide with binder phase enriched surface zone Download PDFInfo
- Publication number
- WO1998016665A1 WO1998016665A1 PCT/SE1997/001690 SE9701690W WO9816665A1 WO 1998016665 A1 WO1998016665 A1 WO 1998016665A1 SE 9701690 W SE9701690 W SE 9701690W WO 9816665 A1 WO9816665 A1 WO 9816665A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- binder phase
- atom
- nitrogen
- phase
- surface zone
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C29/00—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
- C22C29/02—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides
- C22C29/06—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds
- C22C29/08—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds based on tungsten carbide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/10—Sintering only
- B22F3/1003—Use of special medium during sintering, e.g. sintering aid
- B22F3/1007—Atmosphere
- B22F3/101—Changing atmosphere
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2201/00—Treatment under specific atmosphere
- B22F2201/02—Nitrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
- B22F2998/10—Processes characterised by the sequence of their steps
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12014—All metal or with adjacent metals having metal particles
- Y10T428/12028—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, etc.]
- Y10T428/12049—Nonmetal component
- Y10T428/12056—Entirely inorganic
Definitions
- the present invention relates to coated cemented carbide inserts with unique edge security in sticky work piece materials such as stainless steel, achieved with a binder phase enriched surface zone extending over the edge.
- Coated cemented carbide inserts with binder phase enriched surface zone are today used to a great extent for machining of steel and stainless materials. Thanks to the binder phase enriched surface zone, an extension of the application area for the cutting material has been obtained.
- Methods or processes to make cemented carbide containing WC, cubic phase (gamma-phase) and binder phase with binder phase enriched surface zones are known through a number of patents and patent application. According to e.g. US Patents 4,277,283 and 4,610,931 nitrogen containing additions are used and sintering takes place in vacuum whereas according to US Patent 4,548,786 the nitrogen is added in gas phase. Hereby in both cases a binder phase enriched surface zone essentially free of cubic phase is obtained. US Patent 4,830,930 describes a binder phase enrichment obtained through decarburization after the sintering whereby a binder phase enrichment is obtained which also contains cubic phase.
- the thickness of the binder phase enriched zone decreases towards sharp corners, such as the cutting edge of a cutting insert, and that a brittle binder phase depleted zone, enriched in cubic phase, is present in the edge area and often limits the use of binder phase enriched cemented carbides especially in work piece materials with high demands on edge toughness .
- edges of a cutting insert has to be edge rounded to a certain radius of the order of 50-100 ⁇ or less in order to be useful.
- the edge rounding is generally made after sintering by an edge rounding operation. In this operation the thin outermost binder phase enriched zone is completely removed and the hard, brittle area is exposed. As a result a hard but brittle edge is obtained resulting in an increased risk for problems with brittleness in the edge particularly in applications demanding high edge toughness.
- EP-A-0569696 A method of maintaining the binder phase enriched zone in the edge portion of a cemented carbide insert is disclosed in EP-A-0569696. According to this application this effect is obtained if Zr and/or Hf is present in the cemented carbide .
- the thickness of the binder phase enriched surface zone can be maintained over the edge also in cemented carbide free of Hf and Zr if certain conditions are fulfilled particularly with regard to the titanium and nitrogen content within the cubic phase as well as the overall carbon content.
- a favourable influence on the edge toughness in sticky materials such as austenitic stainless steel can thereby be obtained.
- the binder phase enriched zones according to this application often becomes to deep and difficult to control. It is an therefore an object of the present invention to provide a method of making a cemented carbide insert allowing a better control of the thickness of the binder phase enriched zone.
- a cemented carbide insert comprising a cemented carbide substrate and a coating.
- the substrate contains WC and cubic carbonitride phase in a binder phase based of Co and/or Ni and has a binder phase enriched surface zone essentially free of cubic phase.
- the binder phase enriched surface zone prevails over the edge.
- an insert according to the invention has improved edge toughness and is particularly useful for machining of sticky work piece materials such as stainless steel. (Although the cubic phase is essentially a carbonitride phase the material is herein referred to as a cemented carbide . )
- Fig. 1 shows in 80OX the binder phase enriched zone under a cutting edge rounded to a 50 ⁇ m radius in a coated cemented carbide according to the invention. It has now surprisingly been found that by performing part of the sintering under nitrogen pressure the thickness of the binder phase enriched surface zone can be controlled with gradient prevailing in the vicinity of the edge.
- the invention thus, relates to a method of making cutting inserts comprising a cemented carbide substrate consisting of a binder phase of Co and/or Ni , WC and a cubic carbonitride phase with a binder phase enriched surface zone essentially free of cubic phase and a coating.
- Ta and/or Nb is/are added as carbides whereas Ti is added as TiC, TiCN and/or TiN in such proportions that the nitrogen content of the carbonitride phase expressed as x in the formula, (Ti,Nb,Ta) (N ⁇ C _ x ) shall be >0.2, preferably 0.3-0.4.
- the powder mixture is mixed with pressing agent and possibly carbon such that the carbon content is 0-0.15, preferably 0.05-0.15, weight-%, above the stoichiometric content and the mixture is milled and dried to obtain a powder material. Next, the powder material is compacted and sintered.
- nitrogen gas may be supplied to the furnace at 0-500 mbar, preferably 10-40 mbar, in order to prevent denitrification prior to pore closure at temperatures above 1200°C.
- Sintering is performed at a temperature of 1380-1520°C, in a protective atmosphere consisting essentially of nitrogen, the nitrogen pressure adjusted to impede gradient growth, with a period of sintering in an atmosphere without nitrogen, the time of this period adjusted to obtain the gradient zone depth desired.
- the nitrogen pressure required to impede gradient growth depends on composition of the carbide body, sintering temperature and on the furnace used.
- the time required in atmosphere without nitrogen addition depends on sintering temperature and furnace used.
- Cooling can be performed according to standard practice or as disclosed in US 5,484,468. After conventional post sintering treatments including edgerounding a hard, wear resistant coating according to above is applied by CVD- , PVD- or MT-CVD-technique .
- the present invention also relates to a cutting insert comprising a cemented carbide substrate with a binder phase enriched surface zone and a coating, said substrate consisting of a binder phase of Co and/or Ni , WC and a cubic carbonitride of W , Ti and at least one of the metals Ta, Nb, Mo, V, or Cr with a binder phase enriched surface zone being essentially free of cubic phase .
- the cemented carbide contains 6-14 atom- %, most preferably 8-11 atom-%, binder phase, 3-8 atom- %, most preferably 4-6 atom-%, of Ti and at least one of Ta and Nb and rest WC .
- the average WC grain size shall be between 1.0 and 4 ⁇ m, preferably between 1.5 and 3 ⁇ m.
- the Ti/ (Ta+Nb) atomic ratio in the carbonitride phase shall be >2 , preferably >3 , with a nitrogen content expressed as x in the formula, (Ti,Nb,Ta) (N x ,C ⁇ _ x ) shall be >0.2, preferably between 0.3 and 0.4.
- the depth of the binder phase enriched surface zone close to the edge increases with increased titanium and nitrogen content within the cubic phase and with increased overall carbon content.
- the maximum nitrogen content that can be used in practice is mainly limited by the increased tendency for A and B type of porosity with increased nitrogen content. However, the maximum nitrogen content can be extended over the above stated limit if the sintering is performed in an inert atmosphere under high pressure.
- the maximum carbon content that can be used in practice is mainly limited by an increased tendency for carbon precipitation in the binder phase enriched surface zone, reduced coating adhesion and reduced deformation resistance.
- the carbon content shall correspond to a C-porosity better than CO8, preferably COO just below carbon saturation.
- the thickness of the binder phase enriched surface zone shall be 1. below a flat surface 15-45 ⁇ m, preferably 25-35 ⁇ m
- the gradient zone depth close to the edge depends on the geometry, a blunt, 90 degrees or more, geometry giving deeper gradient zones .
- Inserts according to the invention shall preferably have a coating of TiC, TiCN and/or TiN with a total coating thickness of 3-10 ⁇ m, most preferably 4-8 ⁇ m, possibly in combination with an AI2O3 coating with a thickness of 1-4 ⁇ m, most preferably 1.5-3 ⁇ m.
- Other coatings known in the art can also be used such as single or multiple layers of at least one carbide, nitride, carbonitride, oxide or boride of at least one metal of the groups I b, VB and VIB of the periodic table and/or aluminium oxide by known CVD- , PVD- or MT- CVD-methods .
- the structure in the surface of the cutting inserts consisted of a 30 ⁇ m thick binder phase enriched zone below the flat flank face with a minimum if 25 ⁇ m close to the edge .
- the structure in the surface of the cutting inserts consisted of a 33 ⁇ m thick binder phase enriched zone below the flat flank face with a minimum if 23 ⁇ m close to the edge .
- CNMG120408 were pressed.
- the inserts were sintered with H2 up to 450°C for dewaxing, further in vacuum to 1200°C, and after that with a protective gas of 40 mbar nitrogen up to 1380°C the furnace was then evacuated and filled with argon to 40 mbar heated to sintering temperature, 1450°C, and held there for 1 hour and then cooled.
- the structure in the surface of the cutting inserts consisted of a 46 ⁇ m thick binder phase enriched zone below the flat flank face with a minimum if 30 ⁇ m close to the edge .
- the structure in the surface of the cutting inserts consisted of a 40 ⁇ m thick binder phase enriched zone below the flat flank face with a minimum if 26 ⁇ m close to the edge .
- Examples 1 and 2 show that it is possible to control the depth of the gradient zone without loosing the desired gradient in the vicinity of the edge as in example 5.
- Examples 3 and 4 show that the gradient zone may grow excessively without nitrogen addition under a part of the sintering.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Cutting Tools, Boring Holders, And Turrets (AREA)
- Powder Metallurgy (AREA)
- Ceramic Products (AREA)
- Chemical Vapour Deposition (AREA)
Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/242,683 US6299992B1 (en) | 1996-10-11 | 1997-10-09 | Method of making cemented carbide with binder phase enriched surface zone |
AT97945149T ATE231930T1 (en) | 1996-10-11 | 1997-10-09 | METHOD FOR PRODUCING SINTERED CARBIDE WITH A BINDER PHASE-ENRICHED SURFACE ZONE |
DE69718805T DE69718805T2 (en) | 1996-10-11 | 1997-10-09 | METHOD FOR PRODUCING SINTER CARBIDE WITH BIN PHASE ENRICHED SURFACE ZONE |
EP97945149A EP0931171B1 (en) | 1996-10-11 | 1997-10-09 | Method of making cemented carbide with binder phase enriched surface zone |
JP51825998A JP3934160B2 (en) | 1996-10-11 | 1997-10-09 | Method for producing cemented carbide with surface area enriched in binder phase |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SE9603758A SE517474C2 (en) | 1996-10-11 | 1996-10-11 | Way to manufacture cemented carbide with binder phase enriched surface zone |
SE9603758-5 | 1996-10-11 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1998016665A1 true WO1998016665A1 (en) | 1998-04-23 |
Family
ID=20404245
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/SE1997/001690 WO1998016665A1 (en) | 1996-10-11 | 1997-10-09 | Method of making cemented carbide with binder phase enriched surface zone |
Country Status (7)
Country | Link |
---|---|
US (1) | US6299992B1 (en) |
EP (1) | EP0931171B1 (en) |
JP (1) | JP3934160B2 (en) |
AT (1) | ATE231930T1 (en) |
DE (1) | DE69718805T2 (en) |
SE (1) | SE517474C2 (en) |
WO (1) | WO1998016665A1 (en) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1026271A1 (en) * | 1999-02-05 | 2000-08-09 | Sandvik Aktiebolag | Cemented carbide insert |
JP2002520484A (en) * | 1998-07-09 | 2002-07-09 | サンドビック アクティエボラーグ(プブル) | Cemented carbide insert with bonded phase enriched surface zone |
WO2002077312A2 (en) * | 2001-03-27 | 2002-10-03 | Widia Gmbh | Method for increasing compression stress or reducing internal tension stress of a layer |
JP2003528743A (en) * | 2000-03-24 | 2003-09-30 | ケンナメタル インコーポレイテッド | Cemented carbide tool and method of making the same |
US6998173B2 (en) | 2000-03-24 | 2006-02-14 | Kennametal Inc. | Cemented carbide tool and method of making |
US8101291B2 (en) | 2006-12-27 | 2012-01-24 | Sandvik Intellectual Property Ab | Coated cemented carbide insert particularly useful for heavy duty operations |
US11858049B2 (en) | 2022-01-19 | 2024-01-02 | Sumitomo Electric Industries, Ltd. | Cemented carbide and tool containing the same |
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SE522730C2 (en) * | 2000-11-23 | 2004-03-02 | Sandvik Ab | Method for manufacturing a coated cemented carbide body intended for cutting machining |
US6666753B2 (en) * | 2001-02-02 | 2003-12-23 | General Electric Company | Silver-coated abrasives, tools containing silver-coated abrasives, and applications of these tools |
SE523826C2 (en) * | 2002-03-20 | 2004-05-25 | Seco Tools Ab | Cutter coated with TiAIN for high speed machining of alloy steels, ways of making a cutter and use of the cutter |
SE527173C2 (en) * | 2003-07-25 | 2006-01-17 | Sandvik Intellectual Property | Ways to manufacture a fine-grained cemented carbide |
JP4446469B2 (en) * | 2004-03-12 | 2010-04-07 | 住友電工ハードメタル株式会社 | Coated cutting tool |
SE529302C2 (en) * | 2005-04-20 | 2007-06-26 | Sandvik Intellectual Property | Ways to manufacture a coated submicron cemented carbide with binder phase oriented surface zone |
SE529590C2 (en) * | 2005-06-27 | 2007-09-25 | Sandvik Intellectual Property | Fine-grained sintered cemented carbides containing a gradient zone |
JP4936761B2 (en) * | 2006-03-28 | 2012-05-23 | 京セラ株式会社 | Cutting tools |
SE532044C2 (en) * | 2007-12-27 | 2009-10-06 | Seco Tools Ab | Use of a CVD coated cutter when milling |
EP2316790A4 (en) * | 2008-07-16 | 2012-08-22 | Japan Fine Ceramics Ct | Hard powder, method for producing hard powder and sintered hard alloy |
JP5559575B2 (en) | 2009-03-10 | 2014-07-23 | 株式会社タンガロイ | Cermet and coated cermet |
EP2446987B1 (en) | 2009-06-22 | 2018-09-26 | Tungaloy Corporation | Tool having coated cubic boron nitride sintered body |
JPWO2011002008A1 (en) * | 2009-06-30 | 2012-12-13 | 株式会社タンガロイ | Cermet and coated cermet |
US8999531B2 (en) | 2010-04-16 | 2015-04-07 | Tungaloy Corporation | Coated CBN sintered body |
WO2012005275A1 (en) | 2010-07-06 | 2012-01-12 | 株式会社タンガロイ | Coated polycrystalline cbn tool |
GB201100966D0 (en) * | 2011-01-20 | 2011-03-02 | Element Six Holding Gmbh | Cemented carbide article |
EP2725111B1 (en) * | 2011-06-27 | 2019-10-02 | Kyocera Corporation | Hard alloy and cutting tool |
US9764523B2 (en) * | 2011-11-29 | 2017-09-19 | Smith International, Inc. | High pressure carbide component with surfaces incorporating gradient structures |
KR101675649B1 (en) | 2014-12-24 | 2016-11-11 | 한국야금 주식회사 | Cutting tool |
CN110284038B (en) * | 2019-04-26 | 2020-07-28 | 中南大学 | PVD coating with strong (111) texture and preparation method thereof |
WO2023166900A1 (en) * | 2022-03-03 | 2023-09-07 | 京セラ株式会社 | Cemented carbide, and coated tool and cutting tool using same |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
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US4277283A (en) * | 1977-12-23 | 1981-07-07 | Sumitomo Electric Industries, Ltd. | Sintered hard metal and the method for producing the same |
US4548786A (en) * | 1983-04-28 | 1985-10-22 | General Electric Company | Coated carbide cutting tool insert |
US4649084A (en) * | 1985-05-06 | 1987-03-10 | General Electric Company | Process for adhering an oxide coating on a cobalt-enriched zone, and articles made from said process |
WO1993017140A1 (en) * | 1992-02-21 | 1993-09-02 | Sandvik Ab | Cemented carbide with binder phase enriched surface zone |
US5484468A (en) * | 1993-02-05 | 1996-01-16 | Sandvik Ab | Cemented carbide with binder phase enriched surface zone and enhanced edge toughness behavior and process for making same |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
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US4610931A (en) | 1981-03-27 | 1986-09-09 | Kennametal Inc. | Preferentially binder enriched cemented carbide bodies and method of manufacture |
JPS63169356A (en) | 1987-01-05 | 1988-07-13 | Toshiba Tungaloy Co Ltd | Surface-tempered sintered alloy and its production |
SE467716B (en) | 1991-07-31 | 1992-08-31 | Leif Holmlid | COLLECTOR DRIVES THERMOJONIC ENERGY CONVERTER |
CA2092932C (en) | 1992-04-17 | 1996-12-31 | Katsuya Uchino | Coated cemented carbide member and method of manufacturing the same |
SE514283C2 (en) | 1995-04-12 | 2001-02-05 | Sandvik Ab | Coated carbide inserts with binder facade-enriched surface zone and methods for its manufacture |
-
1996
- 1996-10-11 SE SE9603758A patent/SE517474C2/en not_active IP Right Cessation
-
1997
- 1997-10-09 DE DE69718805T patent/DE69718805T2/en not_active Expired - Lifetime
- 1997-10-09 EP EP97945149A patent/EP0931171B1/en not_active Expired - Lifetime
- 1997-10-09 WO PCT/SE1997/001690 patent/WO1998016665A1/en active IP Right Grant
- 1997-10-09 JP JP51825998A patent/JP3934160B2/en not_active Expired - Fee Related
- 1997-10-09 US US09/242,683 patent/US6299992B1/en not_active Expired - Lifetime
- 1997-10-09 AT AT97945149T patent/ATE231930T1/en active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
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US4277283A (en) * | 1977-12-23 | 1981-07-07 | Sumitomo Electric Industries, Ltd. | Sintered hard metal and the method for producing the same |
US4548786A (en) * | 1983-04-28 | 1985-10-22 | General Electric Company | Coated carbide cutting tool insert |
US4649084A (en) * | 1985-05-06 | 1987-03-10 | General Electric Company | Process for adhering an oxide coating on a cobalt-enriched zone, and articles made from said process |
WO1993017140A1 (en) * | 1992-02-21 | 1993-09-02 | Sandvik Ab | Cemented carbide with binder phase enriched surface zone |
US5484468A (en) * | 1993-02-05 | 1996-01-16 | Sandvik Ab | Cemented carbide with binder phase enriched surface zone and enhanced edge toughness behavior and process for making same |
Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002520484A (en) * | 1998-07-09 | 2002-07-09 | サンドビック アクティエボラーグ(プブル) | Cemented carbide insert with bonded phase enriched surface zone |
US6699526B2 (en) | 1999-02-05 | 2004-03-02 | Sandvik Ab | Method of making cemented carbide insert |
US6333100B1 (en) | 1999-02-05 | 2001-12-25 | Sandvik Ab | Cemented carbide insert |
USRE41248E1 (en) | 1999-02-05 | 2010-04-20 | Sanvik Intellectual Property Aktiebolag | Method of making cemented carbide insert |
USRE39894E1 (en) | 1999-02-05 | 2007-10-23 | Sandvik Intellectual Property Ab | Cemented carbide insert |
EP1026271A1 (en) * | 1999-02-05 | 2000-08-09 | Sandvik Aktiebolag | Cemented carbide insert |
US6998173B2 (en) | 2000-03-24 | 2006-02-14 | Kennametal Inc. | Cemented carbide tool and method of making |
US6638474B2 (en) | 2000-03-24 | 2003-10-28 | Kennametal Inc. | method of making cemented carbide tool |
JP2003528743A (en) * | 2000-03-24 | 2003-09-30 | ケンナメタル インコーポレイテッド | Cemented carbide tool and method of making the same |
JP4965047B2 (en) * | 2000-03-24 | 2012-07-04 | ケンナメタル インコーポレイテッド | Cemented carbide tool and method for producing the same |
US6884496B2 (en) | 2001-03-27 | 2005-04-26 | Widia Gmbh | Method for increasing compression stress or reducing internal tension stress of a CVD, PCVD or PVD layer and cutting insert for machining |
WO2002077312A3 (en) * | 2001-03-27 | 2003-01-03 | Widia Gmbh | Method for increasing compression stress or reducing internal tension stress of a layer |
WO2002077312A2 (en) * | 2001-03-27 | 2002-10-03 | Widia Gmbh | Method for increasing compression stress or reducing internal tension stress of a layer |
US8101291B2 (en) | 2006-12-27 | 2012-01-24 | Sandvik Intellectual Property Ab | Coated cemented carbide insert particularly useful for heavy duty operations |
US11858049B2 (en) | 2022-01-19 | 2024-01-02 | Sumitomo Electric Industries, Ltd. | Cemented carbide and tool containing the same |
Also Published As
Publication number | Publication date |
---|---|
SE517474C2 (en) | 2002-06-11 |
JP3934160B2 (en) | 2007-06-20 |
ATE231930T1 (en) | 2003-02-15 |
EP0931171B1 (en) | 2003-01-29 |
SE9603758L (en) | 1998-04-12 |
US6299992B1 (en) | 2001-10-09 |
JP2001502249A (en) | 2001-02-20 |
EP0931171A1 (en) | 1999-07-28 |
DE69718805D1 (en) | 2003-03-06 |
DE69718805T2 (en) | 2003-08-07 |
SE9603758D0 (en) | 1996-10-11 |
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