WO1998012292A1 - Fabric softeners having increased performance - Google Patents
Fabric softeners having increased performance Download PDFInfo
- Publication number
- WO1998012292A1 WO1998012292A1 PCT/US1997/016688 US9716688W WO9812292A1 WO 1998012292 A1 WO1998012292 A1 WO 1998012292A1 US 9716688 W US9716688 W US 9716688W WO 9812292 A1 WO9812292 A1 WO 9812292A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- mixtures
- formula
- alkyl
- cationic charge
- weight
- Prior art date
Links
- 239000002979 fabric softener Substances 0.000 title claims abstract description 27
- 230000001965 increasing effect Effects 0.000 title description 5
- 239000000203 mixture Substances 0.000 claims abstract description 114
- 125000002091 cationic group Chemical group 0.000 claims abstract description 44
- 150000001875 compounds Chemical class 0.000 claims abstract description 12
- 239000004744 fabric Substances 0.000 claims description 37
- 239000003795 chemical substances by application Substances 0.000 claims description 34
- 239000002304 perfume Substances 0.000 claims description 25
- -1 C1-C4 alkyi Substances 0.000 claims description 19
- 229910052739 hydrogen Inorganic materials 0.000 claims description 18
- 239000001257 hydrogen Substances 0.000 claims description 18
- 125000000217 alkyl group Chemical group 0.000 claims description 17
- 150000001450 anions Chemical class 0.000 claims description 17
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 14
- 239000004615 ingredient Substances 0.000 claims description 13
- 150000002431 hydrogen Chemical group 0.000 claims description 12
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims description 11
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 11
- 239000002689 soil Substances 0.000 claims description 10
- 125000005529 alkyleneoxy group Chemical group 0.000 claims description 8
- 239000003760 tallow Substances 0.000 claims description 7
- 239000003381 stabilizer Substances 0.000 claims description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 5
- 239000000828 canola oil Substances 0.000 claims description 5
- 235000019519 canola oil Nutrition 0.000 claims description 5
- 230000003750 conditioning effect Effects 0.000 claims description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 4
- 239000003755 preservative agent Substances 0.000 claims description 4
- 239000012753 anti-shrinkage agent Substances 0.000 claims description 3
- 230000001153 anti-wrinkle effect Effects 0.000 claims description 3
- 239000002518 antifoaming agent Substances 0.000 claims description 3
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 3
- 239000000969 carrier Substances 0.000 claims description 3
- 239000003086 colorant Substances 0.000 claims description 3
- 238000005260 corrosion Methods 0.000 claims description 3
- 230000007797 corrosion Effects 0.000 claims description 3
- 239000000417 fungicide Substances 0.000 claims description 3
- 230000002070 germicidal effect Effects 0.000 claims description 3
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 3
- 239000003605 opacifier Substances 0.000 claims description 3
- 230000003287 optical effect Effects 0.000 claims description 3
- 125000001453 quaternary ammonium group Chemical group 0.000 claims description 3
- 125000002853 C1-C4 hydroxyalkyl group Chemical group 0.000 claims description 2
- 239000004902 Softening Agent Substances 0.000 claims description 2
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 claims 2
- 125000001309 chloro group Chemical group Cl* 0.000 claims 1
- 230000008901 benefit Effects 0.000 abstract description 7
- 150000005690 diesters Chemical class 0.000 abstract description 4
- 150000001412 amines Chemical class 0.000 description 19
- 229920000768 polyamine Polymers 0.000 description 13
- 229920002873 Polyethylenimine Polymers 0.000 description 11
- 125000001924 fatty-acyl group Chemical group 0.000 description 11
- 239000000126 substance Substances 0.000 description 10
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 229920002554 vinyl polymer Polymers 0.000 description 8
- 125000004432 carbon atom Chemical group C* 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- 235000015112 vegetable and seed oil Nutrition 0.000 description 6
- 239000008158 vegetable oil Substances 0.000 description 6
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 5
- 239000005977 Ethylene Substances 0.000 description 5
- 125000003342 alkenyl group Chemical group 0.000 description 5
- 235000014113 dietary fatty acids Nutrition 0.000 description 5
- 239000000194 fatty acid Substances 0.000 description 5
- 229930195729 fatty acid Natural products 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 239000004255 Butylated hydroxyanisole Substances 0.000 description 4
- 239000004322 Butylated hydroxytoluene Substances 0.000 description 4
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 4
- 229920000858 Cyclodextrin Polymers 0.000 description 4
- ZTHYODDOHIVTJV-UHFFFAOYSA-N Propyl gallate Chemical compound CCCOC(=O)C1=CC(O)=C(O)C(O)=C1 ZTHYODDOHIVTJV-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 239000003963 antioxidant agent Substances 0.000 description 4
- 235000006708 antioxidants Nutrition 0.000 description 4
- 235000019282 butylated hydroxyanisole Nutrition 0.000 description 4
- CZBZUDVBLSSABA-UHFFFAOYSA-N butylated hydroxyanisole Chemical compound COC1=CC=C(O)C(C(C)(C)C)=C1.COC1=CC=C(O)C=C1C(C)(C)C CZBZUDVBLSSABA-UHFFFAOYSA-N 0.000 description 4
- 229940043253 butylated hydroxyanisole Drugs 0.000 description 4
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 4
- 229940095259 butylated hydroxytoluene Drugs 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- HZAXFHJVJLSVMW-UHFFFAOYSA-N monoethanolamine hydrochloride Natural products NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical compound O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 description 4
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 3
- KIWBPDUYBMNFTB-UHFFFAOYSA-N Ethyl hydrogen sulfate Chemical compound CCOS(O)(=O)=O KIWBPDUYBMNFTB-UHFFFAOYSA-N 0.000 description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- 229910002651 NO3 Inorganic materials 0.000 description 3
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 3
- 235000019483 Peanut oil Nutrition 0.000 description 3
- 235000019774 Rice Bran oil Nutrition 0.000 description 3
- 235000019485 Safflower oil Nutrition 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- 235000019486 Sunflower oil Nutrition 0.000 description 3
- SEQDDYPDSLOBDC-UHFFFAOYSA-N Temazepam Chemical compound N=1C(O)C(=O)N(C)C2=CC=C(Cl)C=C2C=1C1=CC=CC=C1 SEQDDYPDSLOBDC-UHFFFAOYSA-N 0.000 description 3
- BGNXCDMCOKJUMV-UHFFFAOYSA-N Tert-Butylhydroquinone Chemical compound CC(C)(C)C1=CC(O)=CC=C1O BGNXCDMCOKJUMV-UHFFFAOYSA-N 0.000 description 3
- 125000002252 acyl group Chemical group 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 239000008172 hydrogenated vegetable oil Substances 0.000 description 3
- 230000002209 hydrophobic effect Effects 0.000 description 3
- 229910052740 iodine Inorganic materials 0.000 description 3
- 239000011630 iodine Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 235000019198 oils Nutrition 0.000 description 3
- 239000000312 peanut oil Substances 0.000 description 3
- 230000002829 reductive effect Effects 0.000 description 3
- 239000008165 rice bran oil Substances 0.000 description 3
- 235000005713 safflower oil Nutrition 0.000 description 3
- 239000003813 safflower oil Substances 0.000 description 3
- 239000003549 soybean oil Substances 0.000 description 3
- 235000012424 soybean oil Nutrition 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- 239000002600 sunflower oil Substances 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- 239000003784 tall oil Substances 0.000 description 3
- 238000011282 treatment Methods 0.000 description 3
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 3
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 description 2
- UOQYWMZLTNEIFI-UHFFFAOYSA-N 2-[3-aminopropyl(methyl)amino]ethanol Chemical compound OCCN(C)CCCN UOQYWMZLTNEIFI-UHFFFAOYSA-N 0.000 description 2
- PMUNIMVZCACZBB-UHFFFAOYSA-N 2-hydroxyethylazanium;chloride Chemical compound Cl.NCCO PMUNIMVZCACZBB-UHFFFAOYSA-N 0.000 description 2
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 150000003868 ammonium compounds Chemical class 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000004665 cationic fabric softener Substances 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 2
- 125000004433 nitrogen atom Chemical group N* 0.000 description 2
- 125000002811 oleoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 2
- 239000000473 propyl gallate Substances 0.000 description 2
- 235000010388 propyl gallate Nutrition 0.000 description 2
- 229940075579 propyl gallate Drugs 0.000 description 2
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 2
- 238000005956 quaternization reaction Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- VKZRWSNIWNFCIQ-WDSKDSINSA-N (2s)-2-[2-[[(1s)-1,2-dicarboxyethyl]amino]ethylamino]butanedioic acid Chemical compound OC(=O)C[C@@H](C(O)=O)NCCN[C@H](C(O)=O)CC(O)=O VKZRWSNIWNFCIQ-WDSKDSINSA-N 0.000 description 1
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
- 229940015975 1,2-hexanediol Drugs 0.000 description 1
- XKQMKMVTDKYWOX-UHFFFAOYSA-N 1-[2-hydroxypropyl(methyl)amino]propan-2-ol Chemical compound CC(O)CN(C)CC(C)O XKQMKMVTDKYWOX-UHFFFAOYSA-N 0.000 description 1
- VZYDKJOUEPFKMW-UHFFFAOYSA-N 2,3-dihydroxybenzenesulfonic acid Chemical class OC1=CC=CC(S(O)(=O)=O)=C1O VZYDKJOUEPFKMW-UHFFFAOYSA-N 0.000 description 1
- WUXYGKZSOBYDPP-UHFFFAOYSA-N 2-[bis(2-aminoethyl)amino]ethanol Chemical compound NCCN(CCN)CCO WUXYGKZSOBYDPP-UHFFFAOYSA-N 0.000 description 1
- MPNXSZJPSVBLHP-UHFFFAOYSA-N 2-chloro-n-phenylpyridine-3-carboxamide Chemical compound ClC1=NC=CC=C1C(=O)NC1=CC=CC=C1 MPNXSZJPSVBLHP-UHFFFAOYSA-N 0.000 description 1
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 1
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- 150000003626 triacylglycerols Chemical class 0.000 description 1
- 229960004418 trolamine Drugs 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- QUEDXNHFTDJVIY-UHFFFAOYSA-N γ-tocopherol Chemical class OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/227—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin with nitrogen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/645—Mixtures of compounds all of which are cationic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/0094—Process for making liquid detergent compositions, e.g. slurries, pastes or gels
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
- C11D3/0015—Softening compositions liquid
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3723—Polyamines or polyalkyleneimines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
- C11D3/3773—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
- C11D3/3776—Heterocyclic compounds, e.g. lactam
Definitions
- fabric softener compositions which have an increased or "boosted” fabric softening capacity.
- fabric softener compositions which comprise fabric softener actives having suitable properties other than sufficient cationic charge density, need a means to boost the overall charge density thereby providing to the consumer a better fabric care benefit.
- the cationic charge enhancing agents of the present invention have the effect of increasing the net cationic charge concentration independent of the intrinsic properties of the softener active. Therefore, the formulator may combine fabric softener actives having low cationic charge capacity, but which have other desirable properties inter alia good dispensability, low melting point, with cationic charge boosters thereby obtaining a composition which overcomes the lack of cationic charge density of the fabric softener active.
- X is a softener compatible anion; m is from 1 to 3; n is from 1 to 4; at least one cationic charge booster selected from the group consisting of: i) at least about 0.2%, preferably from about 0.2% to about 10%, more preferably from about 0.2% to about 6% by weight, of a cationic charge booster having the formula:
- R 1 , R-, R 3 . and R 4 are each independently C 1 -C22 alkyl, C3-C22 alkenyl.
- R 5 -Q-(CH ) m - wherein R 5 is Cj - C22 alkyl, C3-C22 alkenyl, and mixtures thereof, m is from 1 to about 6;
- Q is a carbonyl unit as defined hereinabove;
- X is a softener compatible anion; ii) at least about 0.2%, preferably from about 0.2% to about 5%, more preferably from about 0.2% to about 2% by weight, of a cationic charge booster having the formula:
- the preferred fabric softening actives according to the present invention have the formula:
- each R is independently Cj-C ⁇ alkyl, C ⁇ -C hydroxyalkyl, benzyl, and mixtures thereof;
- Rl is preferably C ⁇ 1-C22 alkyl, C ⁇ 1-C22 alkenyl, and mixtures thereof;
- Q is a carbonyl moiety having the formula:
- O — O— C-Rl is a fatty acyl moiety.
- Suitable fatty acyl moieties for use in the softener actives of the present invention are derived from sources of triglycerides including tallow, vegetable oils and/or partially hydrogenated vegetable oils including inter alia canola oil, safflower oil, peanut oil, sunflower oil, corn oil, soybean oil, tall oil, rice bran oil.
- mixed chain fatty acyl units is defined as "a mixture of fatty acyl units comprising alkyl and alkenyl chains having from 10 carbons to 22 carbon atoms including the carbonyl carbon atom, and in the case of alkenyl chains, from one to three double bonds, preferably all double bonds in the cis configuration".
- R units of the present invention it is preferred that at least a substantial percentage of the fatty acyl groups are unsaturated, e.g., from about 25%, preferably from about 50% to about 70%, preferably to about 65%.
- the total level of fabric softening active containing polyunsaturated fatty acyl groups can be from about 3%, preferably from about 5%, more preferably from about 10% to about 30%, preferably to about 25%, more preferably to about 18%.
- cis and trans isomers can be used, preferably with a cis/ trans ratio is of from 1 : 1, preferably at least 3:1, and more preferably from about 4:1 to about 50:1, more preferably about 20:1, however, the minimum being 1 :1.
- the R units suitable for use in the present invention can be further characterized by the Iodine Value (IV) of the parent fatty acid, said IV is preferably from about 20, more preferably from about 50, most preferably from about 70, to a value of about 140, preferably to about 130, more preferably to about 115.
- IV is preferably from about 20, more preferably from about 50, most preferably from about 70, to a value of about 140, preferably to about 130, more preferably to about 115.
- formulators may wish to add an amount of fatty acyl units which have Iodine Values outside the range listed herein above.
- "hardened stock" (IV less than or equal to about 10) may be combined with the source of fatty acid admixture to adjust the properties of the final softener active.
- a further preferred embodiment of the present invention comprises DEQA's wherein the average Iodine Value for Rl is approximately 45.
- R moieties which are introduced during the quaternization step are preferably methyl.
- R moieties which are introduced during the quaternization step are preferably methyl.
- R is preferably the same moiety (i.e. methyl) which is introduced during the quaternization step.
- a methyl amine having the formula:
- Gte '3-m-N-KCHzfo-Z m wherein not all of the Z units are fully reacted with a fatty acyl moiety thereby leaving an amount of ami ⁇ e and/or quatemized ammonium compound in the final fabric softener active admixture having one or more Z units unreacted and thereby not transformed into an ester or amide.
- N,N-di(tallowoyl-oxy-ethyl)-N,N-dimethyl ammonium chloride where the tallow chains are at least partially unsaturated and N,N-di(canoloyl-oxy-ethyl)-N,N-dimethyl ammonium chloride.
- the amount of fabric softening active present in the compositions of the present invention is at least about 2%, preferably from about 2%, more preferably from about 5% to about 60%, more preferably to about 40% by weight, of the composition.
- Cationic Charge Boosters The preferred cationic charge boosters of the present invention are described herein below. i) Quaternary Ammonium Compounds
- Rl, R2, R3, and R ⁇ are each independently C1-C22 alkyl, C3-C22 alkenyl, R5-Q-(CH2) m -, wherein R- ⁇ is C1-C22 alkyl, and mixtures thereof, m is from 1 to about 6;
- X is an anion.
- R is C6-C22 alkyl, Cg-C22 alkenyl, and mixtures thereof, more preferably C ⁇ J -CJ S lkyl > j-Cjg alkenyl, and mixtures thereof;
- R 2 , R 3 , and R 4 are each preferably C1-C4 alkyl, more preferably each R2, R3 ? and R 4 are methyl.
- the formulator may similarly choose R to be a R5-Q-(CH2) m - moiety wherein R$ is an alkyl or alkenyl moiety having from 1 to 22 carbon atoms, preferably the alkyl or alkenyl moiety when taken together with the Q unit is an acyl unit derived preferably derived from a source of triglyceride selected from the group consisting of tallow, partially hydrogenated tallow, lard, partially hydrogenated lard, vegetable oils and/or partially hydrogenated vegetable oils, such as, canola oil, safflower oil, peanut oil, sunflower oil, co oil, soybean oil, tall oil, rice bran oil, etc. and mixtures thereof.
- R$ is an alkyl or alkenyl moiety having from 1 to 22 carbon atoms, preferably the alkyl or alkenyl moiety when taken together with the Q unit is an acyl unit derived preferably derived from a source of triglyceride selected from the group consisting of
- X is a softener compatible anion, preferably the anion of a strong acid, for example, chloride, bromide, methylsulfate, ethylsulfate, sulfate, nitrate and mixtures thereof, more preferably chloride and methyl sulfate.
- a strong acid for example, chloride, bromide, methylsulfate, ethylsulfate, sulfate, nitrate and mixtures thereof, more preferably chloride and methyl sulfate.
- a preferred composition according to the present invention contains at least about 0.2%, preferably from about 0.2% to about 5%, more preferably from about 0.2% to about 2% by weight, of one or more poly vinyl amines having the formula
- y is from about 3 to about 10,000, preferably from about 10 to about 5,000, more preferably from about 20 to about 500.
- Polyvinyl amines suitable for use in the present invention are available from BASF.
- one or more of the polyvinyl amine backbone -NH2 unit hydrogens can be substituted by an alkyleneoxy unit having the formula:
- Rl is C2-C4 alkyiene
- R is hydrogen, C1-C4 alkyl, and mixtures thereof
- x is from 1 to 50.
- the polyvinyl amine is reacted first with a substrate which places a 2-propyleneoxy unit directly on the nitrogen followed by reaction of one or more moles of ethylene oxide to form a unit having the general formula:
- x has the value of from 1 to about 50. Substitutions such as the above are represented by the abbreviated formula PO-EO x -. However, more than one propyleneoxy unit can be incorporated into the alkyleneoxy substituent.
- the compounds of the present invention comprise polyamines having a ratio of m : n that is at least 1:1 but may include linear polymers (n equal to 0) as well as a range as high as 10:1, preferably the ratio is 2:1.
- the ratio of m:n is 2:1, the ratio of primary secondary :tertary amine moieties, that is the ratio of -RNH2, -RNH, and -RN moieties, is 1 :2:1.
- R units are C2 ⁇ C alkyiene, C -Cg alkyl substituted alkyiene, and mixtures thereof, preferably ethylene, 1 ,2-propylene, 1 ,3-propylene, and mixtures thereof, more preferably ethylene.
- R units serve to connect the amine nitrogens of the backbone.
- one or more of the polyvinyl amine backbone -NH2 unit hydrogens can be substituted by an alkyleneoxy unit having the formula: — (RlO) x R2 wherein Rl is C2-C4 alkyiene, R is hydrogen, C1-C4 alkyl, and mixtures thereof; x is from 1 to 50.
- the polyvinyl amine is reacted first with a substrate which places a 2-propyleneoxy unit directly on the nitrogen followed by reaction of one or more moles of ethylene oxide to form a unit having the general formula:
- ethanolamine may be used as an "initiator" in the synthesis of polyethyleneimines, therefore a sample of polyethyleneimine that comprises one hydroxyethyl moiety resulting from the polymerization "initiator” would be considered to comprise a homogeneous polyamine backbone for the purposes of the present invention.
- the PEI's which comprise the preferred backbones of the polyamines of the present invention can be prepared, for example, by polymerizing ethyleneimine in the presence of a catalyst such as carbon dioxide, sodium bisulfite, sulfuric acid, hydrogen peroxide, hydrochloric acid, acetic acid, etc.
- a catalyst such as carbon dioxide, sodium bisulfite, sulfuric acid, hydrogen peroxide, hydrochloric acid, acetic acid, etc.
- a catalyst such as carbon dioxide, sodium bisulfite, sulfuric acid, hydrogen peroxide, hydrochloric acid, acetic acid, etc.
- Specific methods for preparing PEI's are disclosed in U.S. Patent 2,182,306, Ulrich et al., issued December 5, 1939; U.S. Patent 3,033,746, Mayle et al., issued May 8, 1962; U.S. Patent 2,208,095, Esselmann et al., issued July 16, 1940; U.S. Patent 2,806,839, Crowther, issued September
- the present invention also includes the cyclic amines that are typically formed as artifacts of synthesis. The presence of these materials may be increased or decreased depending on the conditions chosen by the formulator. iv) Polv-Quaternarv Ammonium Compounds
- R is substituted or unsubstituted C2-C12 alkyiene, substituted or unsubstituted C2-C12 hydroxyalkylene; each R is independently C1-C4 ⁇ lkyl, each R 2 is independently C i -C22 alkyl, C3-C22 alkenyl, R 5 -Q-(CH2) m -, wherein R 5 is CJ-C22 alkyl, C3-C22 alkenyl, and mixtures thereof; m is from 1 to about 6; Q is a carbonyl unit as defined hereinabove; and mixtures thereof; X is an anion.
- R is ethylene; R is methyl or ethyl, more preferably methyl; at least one R2 is preferably C1-C4 alkyl, more preferably methyl. Preferably at least one R is C ⁇ 1-C22 alkyl, Cj 1-C22 alkenyl, and mixtures thereof.
- the formulator may similarly choose R2 to be a R5-Q-(CH2) m - moiety wherein Rp is an alkyl moiety having from 1 to 22 carbon atoms, preferably the alkyl moiety when taken together with the Q unit is an acyl unit derived preferably derived from a source of triglyceride selected from the group consisting of tallow, partially hydrogenated tallow, lard, partially hydrogenated lard, vegetable oils and/or partially hydrogenated vegetable oils, such as, canola oil, safflower oil, peanut oil, sunflower oil, com oil, soybean oil, tall oil, rice bran oil, etc. and mixtures thereof.
- Rl is methyl, one R units is methyl and the other R2 unit is R ⁇ -Q- (CH2) m -wherein R- ⁇ -Q- is an oleoyl unit and m is equal to 2.
- X is a softener compatible anion, preferably the anion of a strong acid, for example, chloride, bromide, methylsulfate, ethylsulfate, sulfate, nitrate and mixtures thereof, more preferably chloride and methyl sulfate.
- a strong acid for example, chloride, bromide, methylsulfate, ethylsulfate, sulfate, nitrate and mixtures thereof, more preferably chloride and methyl sulfate.
- soil release agents will generally comprise from about 0.01% to about 10.0%, by weight, of the detergent compositions herein, typically from about 0.1% to about 5%, preferably from about 0.2% to about 3.0%.
- soil release agents include the METOLOSE SMI 00, METOLOSE SM200 manufactured by Shin-etsu Kagaku Kogyo K.K., SOKALAN type of material, e.g., SOKALAN HP-22, available from BASF (Germany), ZELCON 5126 (from Dupont) and MILEASE T (from ICI).
- Perfumes The products herein can also contain from about 0.5% to about 60%, preferably from about 1% to about 50%, cyclodextrin/perfume inclusion complexes and/or free perfume, as disclosed in U.S. Pat. Nos. 5,139,687, Borcher et al., issued Aug. 18, 1992; and 5,234,610, Gardlik et al., to issue Aug. 10, 1993, which are incorporated herein by reference.
- Perfumes are highly desirable, can usually benefit from protection, and can be complexed with cyclodextrin.
- Fabric softening products typically contain perfume to provide an olfactory aesthetic benefit and/or to serve as a signal that the product is effective.
- perfume ingredients and compositions of this invention are the conventional ones known in the art. Selection of any perfume component, or amount of perfume, is based solely on aesthetic considerations. Suitable perfume compounds and compositions can be found in the art including U.S. Pat. Nos.: 4,145,184, Brain and Cummins, issued Mar. 20, 1979; 4,209,417, Whyte, issued June 24, 1980; 4,515,705, Moeddel, issued May 7, 1985; and 4,152,272, Young, issued May 1, 1979, all of said patents being incorporated herein by reference. Many of the art recognized perfume compositions are relatively substantive to maximize their odor effect on substrates. However, it is a special advantage of perfume delivery via the perfume/cyclodextrin complexes that nonsubstantive perfumes are also effective.
- Stabilizers can be present in the compositions of the present invention.
- the term "stabilizer,” as used herein, includes antioxidants and reductive agents. These agents are present at a level of from 0% to about 2%, preferably from about 0.01% to about 0.2%, more preferably from about 0.035% to about 0.1% for antioxidants, and more preferably from about 0.01% to about 0.2% for reductive agents. These assure good odor stability under long term storage conditions for the compositions and compounds stored in molten form.
- the use of antioxidants and reductive agent stabilizers is especially critical for low scent products (low perfume).
- antioxidants examples include a mixture of ascorbic acid, ascorbic palmitate, propyl gallate, available from Eastman Chemical Products, Inc., under the trade names Tenox® PG and Tenox S-l; a mixture of BHT (butylated hydroxytoluene), BHA (butylated hydroxyanisole), propyl gallate, and citric acid, available from Eastman Chemical Products, Inc., under the trade name Tenox-6; butylated hydroxytoluene, available from UOP Process Division under the trade name Sustane® BHT; tertiary butylhydroquinone, Eastman Chemical Products, Inc., as Tenox TBHQ; natural tocopherols, Eastman Chemical Products, Inc., as Tenox GT-l/GT-2; and butylated hydroxyanisole, Eastman Chemical Products, Inc., as BHA; long chain esters (Cs- C22) of gallic acid, e.g., dodecyl
- Tiron® available from Kodak with a chemical name of 4,5-dihydroxy-m-benzene- sulfonic acid/sodium salt, EDDS, and DTP A®, available from Aldrich with a chemical name of diethylenetriaminepentaacetic acid. Concentration aids
- Inorganic viscosity/dispersibility control agents which can also act like or augment the effect of the surfactant concentration aids, include water-soluble, ionizable salts which can also optionally be incorporated into the compositions of the present invention.
- ionizable salts can be used. Examples of suitable salts are the halides of the Group IA and IIA metals of the Periodic Table of the Elements, e.g., calcium chloride, magnesium chloride, sodium chloride, potassium bromide, and lithium chloride.
- the ionizable salts are particularly useful during the process of mixing the ingredients to make the compositions herein, and later to obtain the desired viscosity.
- the amount of ionizable salts used depends on the amount of active ingredients used in the compositions and can be adjusted according to the desires of the formulator. Typical levels of salts used to control the composition viscosity are from about 20 to about 20,000 parts per million (ppm), preferably from about 20 to about 11,000 ppm, by weight of the composition.
- the present invention can include other adjunct components (minor components) conventionally used in textile treatment compositions, for example, colorants, preservatives, optical brighteners, opacifiers, anti-shrinkage agents, anti- wrinkle agents, fabric crisping agents, spotting agents, germicides, fungicides, anti- corrosion agents, antifoam agents, and the like.
- adjunct components for example, colorants, preservatives, optical brighteners, opacifiers, anti-shrinkage agents, anti- wrinkle agents, fabric crisping agents, spotting agents, germicides, fungicides, anti- corrosion agents, antifoam agents, and the like.
- suitable ingredients useful in fabric softener containing compositions see WO 97/03169 included herein by reference.
- the following compositions illustrate the present invention.
- N,N-di(canoyloxyethyl)-N-2-hydroxyethyl-N-methyl ammonium methyl sulfate available from Witco.
- Polyvinylamine having a MW 23,000 available from BASF.
- Polyvinylamine having a MW 1,500 available from BASF.
- Minors can include perfume, dye, acid, preservatives, etc.
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Abstract
Description
Claims
Priority Applications (10)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU43562/97A AU734821B2 (en) | 1996-09-19 | 1997-09-19 | Fabric softeners having increased performance |
CA002265731A CA2265731A1 (en) | 1996-09-19 | 1997-09-19 | Fabric softeners having increased performance |
JP51491198A JP3190357B2 (en) | 1996-09-19 | 1997-09-19 | Fabric softener with enhanced performance |
DE69728778T DE69728778D1 (en) | 1996-09-19 | 1997-09-19 | SOFTENER WITH IMPROVED PERFORMANCE |
CZ99945A CZ94599A3 (en) | 1996-09-19 | 1997-09-19 | Brightening agent for fabrics |
EP97941708A EP0931131B1 (en) | 1996-09-19 | 1997-09-19 | Fabric softeners having increased performance |
AT97941708T ATE264903T1 (en) | 1996-09-19 | 1997-09-19 | FABRIC SOFTENER WITH IMPROVED PERFORMANCE |
BR9712068A BR9712068A (en) | 1996-09-19 | 1997-09-19 | Fabric softeners having improved performance |
US09/269,087 US6083899A (en) | 1996-09-19 | 1997-09-19 | Fabric softeners having increased performance |
NO991201A NO991201L (en) | 1996-09-19 | 1999-03-11 | Textile softener with improved effect |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US2644296P | 1996-09-19 | 1996-09-19 | |
US60/026,442 | 1996-09-19 |
Publications (1)
Publication Number | Publication Date |
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WO1998012292A1 true WO1998012292A1 (en) | 1998-03-26 |
Family
ID=21831841
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1997/016690 WO1998012293A1 (en) | 1996-09-19 | 1997-09-19 | Concentrated quaternary ammonium fabric softener compositions containing cationic polymers |
PCT/US1997/016688 WO1998012292A1 (en) | 1996-09-19 | 1997-09-19 | Fabric softeners having increased performance |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
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PCT/US1997/016690 WO1998012293A1 (en) | 1996-09-19 | 1997-09-19 | Concentrated quaternary ammonium fabric softener compositions containing cationic polymers |
Country Status (14)
Country | Link |
---|---|
US (4) | US6492322B1 (en) |
EP (2) | EP0931132B1 (en) |
JP (2) | JP3190357B2 (en) |
KR (1) | KR100367905B1 (en) |
CN (2) | CN1238000A (en) |
AR (1) | AR008469A1 (en) |
AT (2) | ATE264903T1 (en) |
AU (2) | AU734821B2 (en) |
BR (2) | BR9713213A (en) |
CA (2) | CA2265769C (en) |
CZ (1) | CZ94599A3 (en) |
DE (2) | DE69725994T2 (en) |
NO (2) | NO991201L (en) |
WO (2) | WO1998012293A1 (en) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2000056849A1 (en) * | 1999-03-25 | 2000-09-28 | The Procter & Gamble Company | Laundry detergent compositions with certain cationically charged dye maintenance polymers |
WO2001000161A1 (en) * | 1999-06-28 | 2001-01-04 | The Procter & Gamble Company | Cosmetic compositions |
WO2001007548A1 (en) * | 1999-07-26 | 2001-02-01 | The Procter & Gamble Company | Cationic charge boosting systems |
EP1096055A1 (en) * | 1998-06-11 | 2001-05-02 | Kao Corporation | Softener composition |
EP1149890A2 (en) * | 2000-04-26 | 2001-10-31 | Goldschmidt Chemical Company | Polyquaternary ammonium anionic scavengers for rinse cycle fabric softeners |
EP1149891A1 (en) * | 2000-04-26 | 2001-10-31 | Goldschmidt Chemical Company | Low cost fabric softeners for rinse cycle using triglyceride-based ester quats |
US6733538B1 (en) | 1999-03-25 | 2004-05-11 | The Procter & Gamble Company | Laundry detergent compositions with certain cationically charged dye maintenance polymers |
Families Citing this family (127)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
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JPH10316951A (en) | 1997-05-20 | 1998-12-02 | Lion Corp | Liquid cationic paste composition |
JPH10316949A (en) | 1997-05-20 | 1998-12-02 | Lion Corp | Liquid cationic paste composition |
US6617446B1 (en) | 1999-06-03 | 2003-09-09 | National Starch And Chemical Investment Holding Corporation | Cold water swellable starches exhibiting delayed viscosity development, preparation and use thereof |
DE60111513D1 (en) | 2000-04-20 | 2005-07-21 | Procter & Gamble | Woven fabric composition with modified starch polymer |
-
1997
- 1997-09-19 AU AU43562/97A patent/AU734821B2/en not_active Ceased
- 1997-09-19 CN CN97199836A patent/CN1238000A/en active Pending
- 1997-09-19 US US09/269,086 patent/US6492322B1/en not_active Expired - Fee Related
- 1997-09-19 CN CN97199584A patent/CN1237199A/en active Pending
- 1997-09-19 DE DE69725994T patent/DE69725994T2/en not_active Revoked
- 1997-09-19 CA CA002265769A patent/CA2265769C/en not_active Expired - Fee Related
- 1997-09-19 JP JP51491198A patent/JP3190357B2/en not_active Expired - Fee Related
- 1997-09-19 AT AT97941708T patent/ATE264903T1/en not_active IP Right Cessation
- 1997-09-19 WO PCT/US1997/016690 patent/WO1998012293A1/en not_active Application Discontinuation
- 1997-09-19 BR BR9713213-6A patent/BR9713213A/en not_active Application Discontinuation
- 1997-09-19 AR ARP970104332A patent/AR008469A1/en unknown
- 1997-09-19 AT AT97941709T patent/ATE253626T1/en not_active IP Right Cessation
- 1997-09-19 DE DE69728778T patent/DE69728778D1/en not_active Expired - Lifetime
- 1997-09-19 AU AU43563/97A patent/AU4356397A/en not_active Abandoned
- 1997-09-19 BR BR9712068A patent/BR9712068A/en not_active Application Discontinuation
- 1997-09-19 KR KR10-1999-7002276A patent/KR100367905B1/en not_active IP Right Cessation
- 1997-09-19 JP JP51491398A patent/JP4219407B2/en not_active Expired - Fee Related
- 1997-09-19 EP EP97941709A patent/EP0931132B1/en not_active Revoked
- 1997-09-19 WO PCT/US1997/016688 patent/WO1998012292A1/en not_active Application Discontinuation
- 1997-09-19 EP EP97941708A patent/EP0931131B1/en not_active Expired - Lifetime
- 1997-09-19 CA CA002265731A patent/CA2265731A1/en not_active Abandoned
- 1997-09-19 CZ CZ99945A patent/CZ94599A3/en unknown
-
1999
- 1999-03-11 NO NO991201A patent/NO991201L/en not_active Application Discontinuation
- 1999-03-11 NO NO991203A patent/NO991203L/en unknown
-
2002
- 2002-12-02 US US10/307,634 patent/US6797688B2/en not_active Expired - Lifetime
-
2004
- 2004-06-22 US US10/873,913 patent/US6939844B2/en not_active Expired - Fee Related
-
2005
- 2005-01-13 US US11/034,478 patent/US20050130872A1/en not_active Abandoned
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Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
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EP1096055A1 (en) * | 1998-06-11 | 2001-05-02 | Kao Corporation | Softener composition |
EP1096055A4 (en) * | 1998-06-11 | 2002-06-26 | Kao Corp | Softener composition |
US6521588B1 (en) | 1998-06-11 | 2003-02-18 | Kao Corporation | Softener composition |
WO2000056849A1 (en) * | 1999-03-25 | 2000-09-28 | The Procter & Gamble Company | Laundry detergent compositions with certain cationically charged dye maintenance polymers |
US6733538B1 (en) | 1999-03-25 | 2004-05-11 | The Procter & Gamble Company | Laundry detergent compositions with certain cationically charged dye maintenance polymers |
WO2001000161A1 (en) * | 1999-06-28 | 2001-01-04 | The Procter & Gamble Company | Cosmetic compositions |
WO2001007548A1 (en) * | 1999-07-26 | 2001-02-01 | The Procter & Gamble Company | Cationic charge boosting systems |
US6211140B1 (en) | 1999-07-26 | 2001-04-03 | The Procter & Gamble Company | Cationic charge boosting systems |
EP1149890A2 (en) * | 2000-04-26 | 2001-10-31 | Goldschmidt Chemical Company | Polyquaternary ammonium anionic scavengers for rinse cycle fabric softeners |
EP1149891A1 (en) * | 2000-04-26 | 2001-10-31 | Goldschmidt Chemical Company | Low cost fabric softeners for rinse cycle using triglyceride-based ester quats |
EP1149890A3 (en) * | 2000-04-26 | 2003-04-23 | Goldschmidt Chemical Company | Polyquaternary ammonium anionic scavengers for rinse cycle fabric softeners |
US6784152B2 (en) | 2000-04-26 | 2004-08-31 | Goldschmidt Chemical Corporation | Polyquat anionic scavengers for rinse cycle fabric softeners |
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