WO1995021057A1 - Polymeric sheet having oriented multilayer interference thin flakes therein - Google Patents
Polymeric sheet having oriented multilayer interference thin flakes therein Download PDFInfo
- Publication number
- WO1995021057A1 WO1995021057A1 PCT/US1995/001014 US9501014W WO9521057A1 WO 1995021057 A1 WO1995021057 A1 WO 1995021057A1 US 9501014 W US9501014 W US 9501014W WO 9521057 A1 WO9521057 A1 WO 9521057A1
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- WO
- WIPO (PCT)
- Prior art keywords
- layer
- flakes
- sheet
- polymeric material
- polymeric
- Prior art date
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C41/00—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
- B29C41/24—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor for making articles of indefinite length
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/07—Flat, e.g. panels
- B29C48/08—Flat, e.g. panels flexible, e.g. films
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/16—Articles comprising two or more components, e.g. co-extruded layers
- B29C48/18—Articles comprising two or more components, e.g. co-extruded layers the components being layers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/16—Articles comprising two or more components, e.g. co-extruded layers
- B29C48/18—Articles comprising two or more components, e.g. co-extruded layers the components being layers
- B29C48/19—Articles comprising two or more components, e.g. co-extruded layers the components being layers the layers being joined at their edges
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C55/00—Shaping by stretching, e.g. drawing through a die; Apparatus therefor
- B29C55/02—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets
- B29C55/10—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets multiaxial
- B29C55/12—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets multiaxial biaxial
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/58—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising fillers only, e.g. particles, powder, beads, flakes, spheres
- B29C70/62—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising fillers only, e.g. particles, powder, beads, flakes, spheres the filler being oriented during moulding
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D7/00—Producing flat articles, e.g. films or sheets
- B29D7/01—Films or sheets
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
- B32B37/15—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state
- B32B37/153—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state at least one layer is extruded and immediately laminated while in semi-molten state
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M3/00—Printing processes to produce particular kinds of printed work, e.g. patterns
- B41M3/14—Security printing
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/355—Security threads
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/0005—Condition, form or state of moulded material or of the material to be shaped containing compounding ingredients
- B29K2105/0032—Pigments, colouring agents or opacifiyng agents
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/06—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
- B29K2105/16—Fillers
- B29K2105/18—Fillers oriented
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
- B29K2995/0018—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds having particular optical properties, e.g. fluorescent or phosphorescent
- B29K2995/002—Coloured
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
- B29K2995/0018—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds having particular optical properties, e.g. fluorescent or phosphorescent
- B29K2995/003—Reflective
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
- B29K2995/0037—Other properties
- B29K2995/005—Oriented
- B29K2995/0053—Oriented bi-axially
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/514—Oriented
- B32B2307/518—Oriented bi-axially
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/916—Fraud or tamper detecting
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24058—Structurally defined web or sheet [e.g., overall dimension, etc.] including grain, strips, or filamentary elements in respective layers or components in angular relation
- Y10T428/24124—Fibers
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
- Y10T428/256—Heavy metal or aluminum or compound thereof
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
- Y10T428/256—Heavy metal or aluminum or compound thereof
- Y10T428/257—Iron oxide or aluminum oxide
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
- Y10T428/258—Alkali metal or alkaline earth metal or compound thereof
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
- Y10T428/259—Silicic material
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2991—Coated
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2991—Coated
- Y10T428/2993—Silicic or refractory material containing [e.g., tungsten oxide, glass, cement, etc.]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31507—Of polycarbonate
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31786—Of polyester [e.g., alkyd, etc.]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31786—Of polyester [e.g., alkyd, etc.]
- Y10T428/31797—Next to addition polymer from unsaturated monomers
Definitions
- This invention relates to a polymeric sheet multilayer interference thin film having oriented flakes disposed therein, a product using the same and a method.
- Patent No. 5,135,812 there is disclosed optically variable multilayer interference thin film flakes of various types and how such flakes can be incorporated into inks and paints. There is a need to find more uses for such flakes so as to broaden their application, as for example, encapsulating the same in plastic and in particular with extruded, coextruded and cast plastic sheets.
- Another object of the invention is to provide a plastic sheet of the above character which can be extruded or cast.
- Another object of the invention is to provide a plastic sheet of the above character which the flakes are biaxially oriented.
- Another object of the invention is to provide a plastic sheet of the above character which can be coated onto a plastic web serving as a substrate web with a weak bond between the plastic sheet and the plastic web.
- Another object of the invention is to provide a plastic sheet of the above character which has a plastic substrate which can be white or colored.
- Another object of the invention is to provide a plastic sheet of the above character in which flakes can be provided in one or more of the layers.
- Another object of the invention is to provide a plastic sheet of the above character in which the flakes in different layers can have different colors.
- Another object of the invention is to provide a plastic sheet of the above character in which the flakes are optically variable with a color shift in one layer which is different from the color shift in another layer.
- Another object of the invention is to provide a plastic sheet of the above character which can be slit into narrow strips and incorporated as threads to be utilized in security papers such as bank notes.
- Another object of the invention is to provide a plastic sheet of the above character in which relatively low amounts of flakes can be provided in the sheet while still achieving the desired optical effects.
- Another object of the invention is to provide a plastic sheet of the above character which has smooth outer surfaces.
- Another object of the invention is to provide a method for making the plastic sheet of the above character in which a mechanical flow is utilized to induce laminar flow orientation of the pigment flakes in the film optical product.
- Another object of the invention is to provide a method of the above character which stabilizes the color characteristics of the flakes in the plastic sheet.
- FIG. 1 is an isometric view partially in cross section of a polymeric sheet having oriented multilayer interference thin film flakes therein incorporating the present invention.
- FIG. 2 is a cross-sectional view of a coextruded polymeric sheet incorporating the present invention carried by a plastic substrate.
- FIG. 3 is a cross-sectional view of a coextruded polymeric sheet incorporating the present invention having flakes in layers on opposite sides of a plastic substrate.
- FIG. 4 is a cross-sectional view of a polymeric sheet having a substrate having flakes therein incorporating the present invention with plastic layers disposed on each side which can be clear or dyed with a color.
- FIG. 5 is a cross sectional view of a polymeric sheet having a thick clear polymeric base upon which is a thin layer of polymeric material containing optically variable flakes plus additional materials such as dyes, pigments, aluminum flake, etc., with a clear overlacguer.
- FIG. 6 is a plan view of a bank note having embedded therein a thread made from polymeric sheet incorporating the present invention visible on one side of the bank note.
- FIG. 7 is a cross-sectional view taken along the line 6-6 of FIG. 5.
- FIG. 8 is a view similar to FIG. 6 but showing the manner in which the thread is woven into the bank note so that it is visible on both sides of the bank note.
- FIG. 9 is an isometric view partially in cross section of a security document incorporating a polymeric sheet of the present invention.
- the polymeric sheet of the present invention is comprised of a layer of polymeric material having first and second parallel surfaces.
- a plurality of multilayer interference thin film flakes are disposed within the layer of polymeric material.
- the flakes have first and second spaced apart parallel surfaces and have a width and a thickness with an aspect ratio of at least 2:1 for the width with respect to the thickness.
- the flakes lie in planes with the first and second surfaces of the flakes being substantially parallel to the first and second surfaces of the layer of polymeric material.
- the plastic or polymeric sheet 11 which has upper and lower planar spaced-apart parallel surfaces 12 and 13.
- the polymeric sheet 11 can be formed by casting or by extrusion. Also, as hereinafter described, it can be formed by coextruding films in which the sheet 11 forms one of the layers in the coextruded film.
- the film forming the sheet 11 should have a thickness of at least two times the thickness of the multilayer interference thin film flakes which typically have a thickness of approximately 1 micron so that the sheet 11 should have a thickness of approximately two times the thickness of the flakes, or in other words, 2 microns if the flakes have a thickness of 1 micron.
- various types of polymers can be used, for example with an aqueous polymer, a polyvi ⁇ yl alcohol, polyvinyl acetate polyvinylpyrrolidone, poly (ethoxyethylene) , poly (methoxyethylene) , poly (acrylic) acid, poly(acryla ide) , poly(oxyethylene) , poly(maleic anhydride) , hydroxyethyl cellulose, cellulose acetate and poly(sacchrides) such as gum arabic and pectin may be used. If an organic solvent base is to be utilized, almost any polymer system that is dissolvable may be used.
- poly(acetals) such as polyvinylbutyral, poly(vinyl halides) , such as polyvinyl chloride and polyvinylene chloride, poly(dienes) such as polybutadiene, poly(alkenes) such as polyethylene, poly(aerylates) such as polymethyl aerylate, poly(methacrylates) such as poly methylmethacrylate, poly(carbonates) such as poly(oxycarbonyl oxyhexamethylene, poly(esters) such as polyethylene terephthalate, poly (urethanes) , poly(siloxanes) , poly(suphides) , poly(sulphones) , poly(vinylnitriles) , poly(acrylonitriles) , poly(styrene) , poly(phenylenes) such as poly (2,5 dihydroxy-1,4- phenyleneethylene
- a plurality of multilayer interference thin film flakes or platelets 16 are disposed in the sheet 11 between the top and bottom surfaces 12 and 13.
- the flakes 16 have upper and lower parallel surfaces 17 and 18 and have a maximum dimension or width along the surfaces 17 and 18 and a thickness measured in the direction perpendicular to the surfaces 17 and 18 so that the flakes have an aspect ratio of at least 2:1 with respect to the width versus the thickness.
- the flakes can be of a single color or can be optically variable. They can be manufactured in accordance with the teaching of Patent No. 5,135,812.
- the optically variable pigments can be produced by all dielectric thin film layers or metal dielectric layers as described in Patent No. 5,135,812.
- the metal dielectric multilayer interference thin film coating making up the optically variable flakes can be in the form of an opaque metallic layer having first and second surfaces with a dielectric layer of a low index of refraction on each side of the first and second surfaces and a thin absorbing layer having an n/k ratio of near unity where n is the refractive index and k is the absorption constant.
- the low index material can be magnesium fluoride whereas the absorbed layer can be chromium.
- the thick substantially opaque metal layer can be formed of aluminum.
- the pigment flakes 16 which are to be introduced into the polymeric sheet to be manufactured can be introduced into the dry polymer and mixed therewith immediately prior to being fed into the extruder hopper feed system.
- the amount of pigment flakes that can be added in the ratio desired can range from more than 30% to less than 0.1% by weight with respect to the polymer.
- the polymer With the pigment flakes mixed therein, the polymer is heated to fully melt the same.
- the molten polymer with the pigment flakes therein is passed through a die which is extruded onto a cooled casting drum so that the molten polymer is quenched rapidly to an amorphous film.
- the molten polymer is cooled from the melt temperature of about 275°C to below 120°C within 20 seconds.
- a forward draw is then carried out for uniaxial orientation of the polymer by heating the film to its draw temperature, above 90°C and stretching it between two sets of nip rollers, the second set running faster than the first set to cause stretching in one direction of the film to cause molecular chains within the film to align in the draw direction which in turn causes uniaxial orientation of the film.
- the film After, the film has been uniaxially oriented, it is passed through a sidewise draw to create biaxial orientation or orientation in a direction perpendicular to a uniaxial orientation.
- the sidewise draw is carried out in a conventional stentor (not shown) which preheats the film to 80-90°C and draws at a temperature ranging from 100-120°C by gripping the edges of the film as it is being drawn forwardly in the stentor.
- the biaxiall oriented film is passed through a conventional crystallization oven (not shown) having a temperature ranging from 200-230°C to firstly cause the film to become more crystalline with the molecular chains packing together in regular arrangements giving a density increase, secondly to cause the amorphous regions to relax and act as stress-relieving zones and thirdly to cause the crystalline regions to become disoriented out of the plane of the film. These changes give rise to identifiable properties of the film.
- the relaxation of strains plus the crystallization give a very dimensionally stable film.
- the biaxial orientation of the film has additional advantages with respect to orienting the pigment flakes 16 in the film. It has been found that when the film is going through the forward direction draw, the pigment flakes having their first and second surfaces 17 and 18 disposed perpendicular to the direction of the draw will be caused to tip over so that their first and second surfaces 17 and 18 lie in planes which are parallel to the first and second surfaces of the film. Similarly when the film is subjected to the sidewise draw, the pigment flakes 16 which have their surfaces lying in directions which are perpendicular to the direction of the sidewise draw will be tipped over so that their first and second surfaces 17 and 18 also lie in planes which are parallel to the first and second surfaces of the film 11.
- FIG. 1 The results of this biaxial orientation of the film 11 are shown in FIG. 1 in which as shown in cross section in Figure 1 transverse of the film 11, the pigment flakes 16 lie in planes parallel to the surfaces 12 and 13 of the film. Similarly, looking in cross section longitudinal of the film as also shown in FIG. 1, the flakes 16 also lie in planes parallel to the surfaces 12 and 13 of the film. It has been found that it is very important that this mechanical movement during biaxial orientation of the film causes the appropriate alignment of the pigment flakes in the film hereinbefore described and so that the flakes are disposed below the surfaces of the film to provide the film with smooth first and second surfaces 12 and 13.
- a film 11 can have a thickness of 2-5 microns with the pigment flakes having a thickness of 1-2 microns.
- the film 11 after it is passed through the crystallization oven can be cooled and then can be slit to desired widths by trimming off the edges and trimming the same to suitable sizes, as for example widths of 1-3 millimeters.
- the uses of the film shown in FIG. 1 will be described hereinafter in conjunction with the additional embodiments of the invention disclosed herein.
- a substrate or substrate layer 21 can be provided to form a composite structure 22 shown in FIG. 2.
- This substrate or substrate layer 21 has upper and lower spaced-apart parallel surfaces 26 and 27.
- This substrate or primary layer 21 can be formed from any synthetic, film-forming polymeric material. Suitable polymeric materials include thermoplastic materials.
- This substrate layer or primary layer 21 may be biaxially oriented in the same manner as the film 11 to cause sequential biaxial stretching by stretching in the forward direction first and thereafter in a sidewise direction.
- simultaneous biaxial orientation can be affected by extruding a thermoplastic polymeric tube which is subsequently quenched, reheated and then expanded by internal gas pressure to induce transverse orientation in one direction and to cause axial orientation in the opposite direction. This can be accomplished by withdrawing the polymeric tube at a rate which will induce longitudinal orientation at right angles to the first direction of orientation caused by the gas expansion.
- both the secondary layer 11 and primary layer 21 can be formed substantially simultaneously by simultaneous coextrusion of the respective film-forming layers through independent orifices of a multi-orifice die and thereafter uniting the still molten layers, or preferably by a single channel of coextrusion in which molten streams of the respective polymers are first united within a channel leading to a die manifold and thereafter extruded together from the die orifice under conditions of streamlined flow without intermixing thereby to produce a composite sheet.
- the coextruded sheet can be then stretched to effect molecular orientation in a forward direction of both layers simultaneously and thereafter sidewise stretched to produce the biaxial orientation of both layers and thereafter inducing partial crystallization of the secondary layer 11.
- the secondary layer 11 containing the multilayer interference thin film flakes is provided on one surface, as for example on the top or first surface 26 of the substrate 21.
- the sheet can be formed by casting, as for example through a conventional slot applicator.
- the multilayer interference thin film flakes can be introduced and mixed with the solvent dissolved polymer and then passed through the slot applicator. This casting process also causes orientation of the flakes 16 so that they lie flat or in parallel planes with respect to the top and bottom surfaces 12 and 13 of the sheet 11.
- the movement of the flakes or platelets 16 so that they lie on their wider sides is accomplished by three effects.
- gravitational forces have a large impact on having the flakes 16 lie down on their wide sides.
- This lying down is enhanced by the surface tension which is created during drying of the cast film which is akin to the biaxial stretch hereinbefore described.
- the surface tension effect as the polymer dries and the solvent evaporates, the polymer tends to shrink and pull the flakes flat. In the direction of flow during the casting process, the flow will tend to orient the flakes along the direction of flow while permitting the flakes to settle under the force of gravity so that they will lie flat.
- the polymer is a hot melt material
- the shear forces present at the coating slot die also cause the flakes to lie flat.
- the flakes are oriented in much the same manner as during biaxial stretching of an extruded film.
- one of the layers 11 is also provided on the second surface 27 so that the same or a different color effect can be achieved on the other side of the substrate 21.
- the multilayer interference thin film flakes 16 of the present invention can be utilized to provide a pigment of a single color or one that is optically variable.
- the two different layers 11 on opposite sides of the substrate can have different colors or can have the same or different optically variable characteristics.
- the substrate 21 can be provided with a black dye or alternatively can be colored to achieve different color effects. Also it can be white.
- FIG. 4 there is shown a composite structure 32 in which the center layer 11 is the layer carrying the flakes and the outer layers 21 are clear or dyed with a color to provided different or the same color effects on opposite sides of the layer 11.
- FIGS. 3 and 4 can be coextruded in the manner hereinbefore described. It should be appreciated that if desired, additional layers can be provided which also can be simultaneously coextruded and biaxially stretched in the manner hereinbefore described.
- a polymer sheet composite incorporating the present invention can range in thickness from 12-500 microns, 3-175 microns and preferably from 3-30 microns.
- the secondary layers 11 can constitute from 1-50% and typically from 1-20% of the total composite thickness.
- the secondary layers 11 preferably have a thickness of up to 20 microns and more preferably from 0.5-10 microns.
- the multilayer interference thin film flakes suitable for use as pigments in the layer 11 comprise multilayer optical coatings, typically of three and five layers and greater to produce strongly dichroic optical effects.
- five layer optically variable flakes are preferably of a symmetrical design as described in Patent No.
- 5,135,812 are comprised a first thin semi-opaque metal layer followed in sequence by a first dielectric layer, a thick metal reflecting layer, a second layer of dielectric material and a second thin semi-opaque metal layer.
- the first semi-opaque metal layer and the dielectric layer are formed of an optical coating substructure which is an inverted version of the optical coating substructure of the second semi-opaque metal and dielectric layers.
- Each of the semi-opaque thin metal layers preferably comprise a nominal 5 nanometer thick layer of chromium.
- Each of the dielectric layers are formed from a dielectric material such as silicon dioxide or magnesium fluoride to form an optical thickness of a plurality of half waves at a particularly design wavelength.
- the thick metal reflecting layer may comprise a layer of aluminum formed to a thickness of about 40 or more nanometers to provide high opacity and high reflection.
- a material such as nickel and stainless steel can be utilized.
- silicon dioxide having an index or refraction of 1.46 for the dielectric layers
- other inorganic materials having a refractive index of 1.65 or less such as magnesium fluoride (1.38) and aluminum oxide (1.65) also can be used.
- aluminum materials such as gold, copper and silver as well as cobalt-nickel magnetic alloys may be used.
- Three layer optically variable flakes similar in design to the five-layer structure can be used but the optical coating substructure of the second semi-opaque metal and dielectric layers can be eliminated. Furthermore, three-layer optical designs as described in U.S. Patent 5,278,590 can be used as the interference flakes.
- a preferred example of a five layer optically variable flake exhibits deep green and purple hues with changes of angle of incidence light.
- the deep green optically variable flake comprises a plurality of half waves for a silicon dioxide layer at a wavelength at approximately 515 nanometers. This produces an optically variable flake with a sixth order reflectance maximum at 515 nanometers.
- a narrow band reflectance spike with about 60% or greater reflectance at the 515 nanometer wavelength results with nearly zero reflectance at nearby wavelengths.
- fourth and eighth order reflectance maxima occur in the near infrared region and the short wavelength blue regions, the flake still produces a very saturated green color.
- the sixth order peak shifts into the blue region, and the fourth order peak shifts downscale into the red, leaving a low reflectance in the 515 nanometer green region.
- the apparent color of the coating changes from a deep green to a purple as the angle of viewing increases.
- a second preferred example of a five layer optically variable flake comprises a silicon dioxide layer of a plurality of half waves at about 450 nanometers.
- This coating had a fourth order reflectance peak in the red part of the spectrum and a sixth order peak in the blue part of the spectrum which produced a deep purple color when viewed at normal incidence. When viewed at larger angles, the fourth order peak moved into the green region with low reflectance in the blue and red. This causes the apparent color of the coating to shift from purple to green at large viewing angles.
- the optically variable flakes utilized in the present invention for inclusion in the secondary layer or layer 11 of a polymeric film exhibit two distinct colors, one color when viewed in a direction normal to the surface of the flake and another color when viewed at a substantial angle such as 45° with respect to the surface of the flake.
- This dramatic color shift is achieved because of the use of at least one dielectric layer having a low refractive index, preferably at 1.65 and below.
- the flakes 16 suitable for use in the secondary layer or layer 11 of a polymeric film according to the present invention preferably have a particle size by which is meant the size of the maximum width of the flake of 0.5-200 microns, and preferably in the range of 1-20 microns.
- the mean particle size, i.e. the maximum width of the flakes, of the flakes is preferably, 1-20 microns.
- the aspect ratio by which is meant the ratio of the maximum width to the thickness, of the optical variable flakes is suitably greater than 2:1, preferably in the range of 5-10:1.
- the concentration of the optically variable flakes present in the layer 11 was suitably in the range of 1-50% by weight and preferably 2-30% by weight with respect to the weight of the polymer in the layer 11.
- it is desirable to bake the pigment flakes at a relatively high temperature as for example at 250°C or above for a period of time ranging from 2-4 hours to make the pigment flakes more durable.
- baking at a high temperature in air or in oxygen improves the durability of the flakes.
- Substantially the same effects are achieved by placing the pigment flakes in the polymeric film during extrusion of the same and during biaxial orientation of the polymeric film because of the high temperatures utilized.
- the pigment flakes 16 could be added to the polymeric material prior to extrusion of the same, it should be appreciated that the flakes 16 if desired may be added during monomer transfer or in the autoclave. It has been found, however, that it is preferred to incorporate the flakes as a glycol dispersion during the esterification reaction stage of the polyester synthesis. Alternatively, the pigment flakes may be added directly to the polymer chip prior to extrusion. Thus, the flakes may be added as a dry powder into the polymer melt extruded therefrom.
- the layers of film made in accordance with the present invention may contain any of the additives conventionally employed in the manufacture of polymeric films.
- agents such as dyes, pigments, lubricants, anti-oxidants, anti-blocking agents, surface active agents, ultra-violet light stabilizers, viscosity modifiers and dispersion stabilizers may be incorporated in the primary and/or secondary layer(s) , as appropriate.
- the dichroic optical effects of the optically variable flakes can be combined with certain matching or contrasting dye colors and/or pigments added to the polymeric material of the secondary layer in order to produce other colors with other color-shifting effects.
- Transparent pigments and dyes can be used to block out unwanted colors, for example as disclosed in Patent No. 5,135,812.
- the composite construction herein disclosed can also be formed of materials which will seal onto themselves or alternatively additional layers can be provided so that sealing can be accomplished.
- a polymeric film made in accordance with the present invention may be coated on one or both surfaces with one or more additional coatings such as ink, lacquer and/or metal layers to form a laminate or composite which exhibits improved properties, such as antistatic, adhesion promoting or release, compared with the component materials.
- the biaxial orientation typically can be carried out by stretching in the forward and sideways directions in suitable amounts to accomplish the production of a film having the desired thickness.
- one film was stretched 3.6 times its original dimension in the forward direction and 4.2 times its original dimension in a sideways or a transverse direction.
- the film composite was finally heat-set under dimensional restraint in a stentor oven at a temperature of about 225°C.
- the biaxially oriented polymeric film optical product made in accordance with the present invention as hereinbefore described and having oriented multilayer interference thin film flakes therein can be utilized in many different products. Particularly novel and desirable color effects can be obtained which can be utilized for various decorative purposes.
- the flakes are in the form of optically variable pigments, they are particularly useful in providing security capabilities in security documents such as bank notes, certificates, credit cards and security type identification documents, such as drivers licenses and the like.
- security documents such as bank notes, certificates, credit cards and security type identification documents, such as drivers licenses and the like.
- small portions of the polymeric film can be incorporated into the security documents. They also can be incorporated in labels or packaging of articles which may be subject to counterfeiting. The presence of even a small amount of the polymeric sheet in the security document makes it possible for one, as for example, a man on the street, to readily distinguish between a genuine article and a counterfeited article by observing the presence or absence of a color shift.
- FIG. 5 there is provided another composite polymeric sheet construction 34 in which the polymeric sheet is provided with a base or substrate 36 having upper and lower surfaces 37 and 38.
- the base substrate 36 in comparison to the substrate of the hereinbefore described embodiments can be relatively thick as for example from 5 mils to 3/8 inch and can be clear.
- the center layer 11 provided on the surface 37 can be of the type hereinbefore described and can be in the form of a thin layer of polymeric material containing the optically variable flakes 16 hereinbefore described.
- other materials such as dyes, pigments, aluminum flakes and the like can be incorporated into the layer 11.
- These dyes, pigments and the like can be used for various purposes well known to those skilled in the art. For example, they can be used to block out an undesired color at various angles. They also can be used to subtract a color.
- An overlayer 39 can be provided over the layer 11 and can be formed of suitable relatively hard material such as a lacquer.
- Such a composite structure 34 as shown in FIG. 5 can be utilized in a number of applications as for example for flooring and other decorative effects.
- FIG. 6 An example of the manner in which the invention can be practiced in utilizing the polymeric film of the present invention in a security document 41 is shown in FIG. 6 in which the security document is in the form of a sheet of material such as a bank note formed of paper having a thickness ranging from 2-3 mils and having first and second surfaces 42 and 43 which are spaced apart and parallel with a thread 46 is at least partially embedded in the paper of the note.
- the thread 46 extends transversely across the note adjacent one edge of the same as shown in FIG. 6 with spaced-apart portions 46a of the thread being exposed on one or the top surface 42 with intermediate portions 46b being embedded within the paper of the bank note as shown in FIG. 7.
- FIG. 6 An example of the manner in which the invention can be practiced in utilizing the polymeric film of the present invention in a security document 41 is shown in FIG. 6 in which the security document is in the form of a sheet of material such as a bank note formed of paper having a thickness ranging from 2-3 mils and having first and second surfaces 42
- the thread 46 can be embedded in the paper of the bank note by having spaced-apart portions 46a being visible from the surface 42, intermediate portions 46b being buried within the paper of the note and additional spaced-apart portions 46c visible from the other surface 43 of the bank note.
- the thread 46 can be formed from the biaxially oriented polymeric sheet 11 or the cast film hereinbefore described by slitting the sheet 11 to appropriate widths, as for example 1.5-3 mils and with a thickness of .5 mil to provide an elongate strip serving as the thread 46. Such a thread would have a rectangular cross section.
- the thread could be incorporated into the bank note as shown in FIG. 6 to remove a one color or provide a one color or one optically variable effect from one side of the bank note. If it is incorporated into the bank note as shown in FIG. 7 so that portions of the same are visible on opposite sides of the note, two different color effects or optically variable effects can be achieved on opposite sides of the note.
- a gold-to-green shifter could be incorporated on one side and a green-to-blue shifter could be incorporated on the other side.
- one side could just be a metalized reflector, as for example having aluminum flakes incorporated therein with the other side having an optically variable effect.
- FIG. 9 An example of a security document is shown in FIG. 9 which as shown therein can be in the form of a California driver's license 51 of a suitable size so that it can readily fit into a conventional billfold, as for example 2" x 3-;".
- I is provided with a relatively rigid substrate 52 formed of a suitable plastic of the type hereinbefore described. It can have a suitable thickness, as for example 2-10 mils. It has upper and lower planar spaced-apart parallel surfaces 53 and 54.
- a sheet 56 of a suitable material such as paper can be laminated to the surface 53 by the application of heat and pressure and the use of an adhesive (not shown) .
- the sheet 56 depending upon the application for the security document can carry a picture or a photograph 57 and printed information 58 as shown in FIG. 8.
- the photograph by example may be a color photograph and the printed information can be in different colors. In such an application, the sheet 56 can be opaque. However, it should be appreciated that if desired, the sheet 56 can be formed of a semi-
- a polymer sheet 61 incorporating the present invention is adhered to the sheet 56 by laminating it thereto by the use of a clear adhesive (not shown) and by the application of suitable heat and pressure to complete the security document.
- the polymer sheet contains multilayer interference thin film flakes 62 of the type hereinbefore described.
- the polymer sheet 61 in this application can be relatively thin, as for example 2-3 microns.
- the flakes can be in relatively low concentration, as for example in the lower ranges hereinbefore set forth so that the polymer sheet 61 is semi-transparent to permit viewing of the information on the sheet 56, as for example the photograph 57 and the printed information 58 by the human eye.
- the flakes 62, in such an application can be of the optically variable type to provide a relatively low color concentration upon which a color shift still exists to the human eye to thereby provide an additional level of security to the security document 51.
- the multilayer interference thin film flakes into the polymeric film, it is possible to maximize the optical effect from the optical flakes and to minimize the amount of flakes which is required. This is important because the pigment flakes are relatively expensive in comparison to the cost of the polymeric film.
- the best optical performance can be achieved by having a single plane of the flakes with the flakes touching each other so that they are in effect a monolayer with minimum use of flakes. In practice, this optimum arrangement of the flakes is difficult to achieve because the polymeric sheet has a third dimension and thus the flakes may not lie in any single plane. Also there may be some overlapping of the flakes and some gaps in between the flakes.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Composite Materials (AREA)
- Laminated Bodies (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Cosmetics (AREA)
- Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
Abstract
Description
Claims
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1019960704248A KR100215144B1 (en) | 1994-02-04 | 1995-01-24 | Polymeric sheet having oriented multilayer interference thin flakes therein |
AU16910/95A AU684146B2 (en) | 1994-02-04 | 1995-01-24 | Polymeric sheet having oriented multilayer interference thin flakes therein |
DE69535073T DE69535073T2 (en) | 1994-02-04 | 1995-01-24 | AMORPHOUS PLASTIC LAYER CONTAINING ORIENTED, MULTILAYERED DARK INTERFERENCE PIGMENTS |
AT95908680T ATE306389T1 (en) | 1994-02-04 | 1995-01-24 | AMORPHOUS PLASTIC LAYER CONTAINING ORIENTED, MULTI-LAYER SCALE-SHAPED INTERFERENCE PIGMENTS |
EP95908680A EP0741639B1 (en) | 1994-02-04 | 1995-01-24 | Amorphous polymeric sheet having oriented multilayer interference thin flakes therein |
CA002181588A CA2181588C (en) | 1994-02-04 | 1995-01-24 | Polymeric sheet having oriented multilayer interference thin flakes therein |
JP7520650A JPH09508593A (en) | 1994-02-04 | 1995-01-24 | Polymer sheets with oriented multilayer interference flakes |
HK98112883A HK1011640A1 (en) | 1994-02-04 | 1998-12-07 | Amorphous polymeric sheet having oriented multilayer interference thin flakes therein |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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US08/191,992 US5424119A (en) | 1994-02-04 | 1994-02-04 | Polymeric sheet having oriented multilayer interference thin film flakes therein, product using the same and method |
US08/191,992 | 1994-02-04 |
Publications (1)
Publication Number | Publication Date |
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WO1995021057A1 true WO1995021057A1 (en) | 1995-08-10 |
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PCT/US1995/001014 WO1995021057A1 (en) | 1994-02-04 | 1995-01-24 | Polymeric sheet having oriented multilayer interference thin flakes therein |
Country Status (12)
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US (1) | US5424119A (en) |
EP (1) | EP0741639B1 (en) |
JP (1) | JPH09508593A (en) |
CN (1) | CN1081984C (en) |
AT (1) | ATE306389T1 (en) |
AU (1) | AU684146B2 (en) |
CA (1) | CA2181588C (en) |
DE (1) | DE69535073T2 (en) |
DK (1) | DK0741639T3 (en) |
ES (1) | ES2250968T3 (en) |
HK (1) | HK1011640A1 (en) |
WO (1) | WO1995021057A1 (en) |
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- 1995-01-24 ES ES95908680T patent/ES2250968T3/en not_active Expired - Lifetime
- 1995-01-24 EP EP95908680A patent/EP0741639B1/en not_active Expired - Lifetime
- 1995-01-24 DE DE69535073T patent/DE69535073T2/en not_active Expired - Lifetime
- 1995-01-24 CN CN95191497A patent/CN1081984C/en not_active Expired - Lifetime
- 1995-01-24 DK DK95908680T patent/DK0741639T3/en active
- 1995-01-24 JP JP7520650A patent/JPH09508593A/en active Pending
- 1995-01-24 CA CA002181588A patent/CA2181588C/en not_active Expired - Lifetime
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- 1995-01-24 AT AT95908680T patent/ATE306389T1/en active
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1998
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Also Published As
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CA2181588C (en) | 2007-03-27 |
AU1691095A (en) | 1995-08-21 |
CN1140432A (en) | 1997-01-15 |
CN1081984C (en) | 2002-04-03 |
EP0741639A1 (en) | 1996-11-13 |
JPH09508593A (en) | 1997-09-02 |
ES2250968T3 (en) | 2006-04-16 |
ATE306389T1 (en) | 2005-10-15 |
CA2181588A1 (en) | 1995-08-10 |
EP0741639B1 (en) | 2005-10-12 |
HK1011640A1 (en) | 1999-07-16 |
US5424119A (en) | 1995-06-13 |
EP0741639A4 (en) | 1998-01-28 |
DK0741639T3 (en) | 2006-01-16 |
DE69535073T2 (en) | 2006-12-14 |
AU684146B2 (en) | 1997-12-04 |
DE69535073D1 (en) | 2006-08-03 |
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