WO1984003770A1 - A method and an apparatus for assaying sulphur trioxide - Google Patents

A method and an apparatus for assaying sulphur trioxide Download PDF

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Publication number
WO1984003770A1
WO1984003770A1 PCT/SE1984/000088 SE8400088W WO8403770A1 WO 1984003770 A1 WO1984003770 A1 WO 1984003770A1 SE 8400088 W SE8400088 W SE 8400088W WO 8403770 A1 WO8403770 A1 WO 8403770A1
Authority
WO
WIPO (PCT)
Prior art keywords
gas
light
mist
gases
sulphur trioxide
Prior art date
Application number
PCT/SE1984/000088
Other languages
French (fr)
Inventor
Sven Goeran Wennlid
Original Assignee
Boliden Ab
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Boliden Ab filed Critical Boliden Ab
Priority to DE8484901127T priority Critical patent/DE3472457D1/en
Priority to AT84901127T priority patent/ATE35461T1/en
Publication of WO1984003770A1 publication Critical patent/WO1984003770A1/en
Priority to DK507984A priority patent/DK507984D0/en
Priority to NO844348A priority patent/NO162437C/en
Priority to FI844433A priority patent/FI80149C/en

Links

Classifications

    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/75—Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated
    • G01N21/77—Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated by observing the effect on a chemical indicator
    • G01N21/82—Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated by observing the effect on a chemical indicator producing a precipitate or turbidity
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/01—Arrangements or apparatus for facilitating the optical investigation
    • G01N21/03—Cuvette constructions
    • G01N21/031—Multipass arrangements
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T436/00—Chemistry: analytical and immunological testing
    • Y10T436/18—Sulfur containing

Definitions

  • the present invention relates to a method for assaying sulphur trioxide and to apparatus for carrying out the method.
  • the object of the present invention is to provide a method and apparatus for assaying sulphur trioxide which is capable of forming a mist, and particularly for monitoring industrial emission process gases containing sulphur trioxide, for controlling the recycling of such gases and/or the emission of said gases to the surroundings, with the view of protecting the environment.
  • Such emission can be tolerated in itself, provided that it is on such a small scale as to have no cronic effect on the environment.
  • the emission of such gases must not be continuous, however, and consequently it is necessary to monitor gases which derive from industrial processes and which are liable to create emission problems.
  • gases comprising sulphur trioxide in an amount down to 35 mg SO3 per m ⁇ can be determined using ordinary air having a normal humidity, i.e. a water content of 15 to 20 g of H2O per m 3 . It has been noted that the water content should not be less than about 15 g of H O per m 3 , although the amount of sulphur trioxide is low and that thereby not all water is needed.
  • Fig 1 is a sectional view of a preferred first embodiment of an assaying appa ⁇ ratus according to the invention, placed in a residual gas conduit; and . /- ⁇
  • a cylindrical tube 1 suitably made of an acid-proof material such as acid-proof steel or polypropylene. Arranged
  • OMPI « ⁇ °o on one end 2 of the tube is a housing 3 which contains a mirror 4.
  • a gas inlet pipe 5 Arranged in the vicinity of the mirror 4 is a second inlet pipe 6, said pipe being intended to conduct air and/or an inert gas.
  • a second housing ⁇ Arranged on the other end 7 of the tube 1 is a second housing ⁇ which contains a photodiode 9 and a receiver, photocell, 10.
  • the receiver 10 is coupled to a transmitter 11, which transfers incoming signals to a writer and/or display instrument (not shown).
  • a supply pipe 12 Coupled to the housing 8 is a supply pipe 12, which is arranged to transfer said air and/or inert gas.
  • the pipe 12 communicates with the pipe 6 and also with a connector 13 arranged around the photodiode 9 and receiver 10, for the introduction of said air/inert gas to the region around said diode and receiver. Also arranged at said other end 7 of the tube 1 is an outlet pipe 14, which is connected to a suction source, for example a vacuum pump (not shown).
  • a suction source for example a vacuum pump (not shown).
  • the embodiment illustrated i Fig 2 comprises a cylindrical tube 1, made of polypropylene for example.
  • a housing 3 which accomodates a photodiode 9.
  • the embodiment also includes a pipe 16 through which air for flushing out the interior of the tube can be introduced thereinto.
  • two inlet pipes 5 and 6 Arranged at the end 2 of the tube 1 are two inlet pipes 5 and 6, the first mentioned pipe being connected to a residual-gas line (not shown) and the latter being connected to an air source.
  • the other end 7 of the tube 1 is provided with a further housing 8, which accomodates a receiver 10 and a transmitter 11.
  • Connected to the housing 8 is a further air-flush inlet pipe 12.
  • an outlet pipe 14 which is connected to a suction source not shown.
  • the apparatus have the following mode of operation:
  • the outlet pipe 14 to the vacuum source is opened, whereupon gas is drawn from the residual gas conduit into the tube' 1.
  • the * gas may comprise a gas leaving an absorption tower in a sulphuric-fteid plapt, andaat is thus desired to measure the residual quantities of sulphur trioxide in the gas.
  • moist air is passed through the pipe 6, this air being intended to flush clean the area around the mirror 4 and the photodiode 9 respectively, and to react with any sulphur trioxide
  • the humidity of the air is that normally present in ambient air under ordinary climate conditions.
  • air is also drawn in through the piping 12/13 and through the housing 8 so as to flush around the photodiode 9/receiver 10 and the receiver 10 respectively.
  • the photodiode 9 emits a beam of light which, if there is no mist in the tube 1, passes to the receiver 10, at full strength, optionally via the mirror 4 when the embodiment according to Fig 1 is used.
  • the light transmitted is obliterated, either totally or partially, the extent to which said light is blotted being proportional to the amount of sulphur trioxide present.
  • the gas in the residual gas conduit can be returned to the absorption tower in the sulphuric-acid plant, or can be rendered innocuous in some other way, for example by scrubbing.
  • a residual gas is introduced through the pipe 5, at the same time as air with normal humidi ⁇ ty is drawn in through the pipe 6 and cleaning dry, air is passed through the pipe 16. If any sulphur trioxide is present it will react with the water to form a mist whose ability to extinguish light transmitted from the photodiode can be readily measured in the aforementioned manner.
  • All gases are withdrawn by suction through the outlet pipe 14, thereby maintain ⁇ ing the light source 9 and receiver 10 free from coatings, for example coatings of sulphuric acid, and continuous assaying can be effected, since fresh gas/gases can constantly be introduced into the apparatus.
  • the instrument By using a mirror/reflector arrangement in accordance with Fig 1, it is possible to double the length of the light beam, or the instrument can be correspondingly shortened to half its length, such an embodiment being of interest when the apparatus is to be inserted in a residual gas conduit 21.
  • the tube 1 When the tube 1 is also located in the residual gas conduit, it will be heated to the same tempera- ture?_£s the gas, thereby eliminating risk of ⁇ condensation.
  • the interior surfaces of the tube 1 and the houses 3 and 8 are so formed as to prevent any condensate which may form from reaching the light source/receiver units, for example as illustrated in Fig 2.
  • the content range may be 35-1000 mg SO3 pei* m 3 of gas, this range fully covering all current operational conditions.
  • combustion gases can be assayed and controlled in a similar manner, particularly when the combustion gases are substantially free from soot and other particles, as is the case with large combustion plants.

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  • Physics & Mathematics (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Plasma & Fusion (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Investigating Or Analysing Materials By Optical Means (AREA)
  • Sampling And Sample Adjustment (AREA)
  • Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
  • Investigating Or Analysing Materials By The Use Of Chemical Reactions (AREA)
  • Investigating Or Analysing Biological Materials (AREA)

Abstract

A method for assaying dry gases comprising sulphur trioxide capable of forming a mist, and particularly to apparatus for monitoring and controlling gases discharged for process industries and combustion plants. The gas to be assayed is introduced into a closed space and contacted therein with air comprising normal humidity which reacts with the gas to form a mist, whereafter the light-extinction properties of the mist are measured. The apparatus for carrying out the method comprises a closed space (1) wherein there is arranged a light source (9) and a receiver (10) for receiving a beam of light emitted from said light source (9), said light beam being arranged to pass through said close space (1); an inlet line (5) for gas to be assayed; at least one inlet line (6) for at least one further gas; an outlet line (14) for removal of said gases, said outlet and inlet lines (5, 6, 14) being arranged in spaced apart relationship.

Description

"A method and an apparatus for assaying sulphur trioxide"
Description
Technical Field
The present invention relates to a method for assaying sulphur trioxide and to apparatus for carrying out the method.
The object of the present invention is to provide a method and apparatus for assaying sulphur trioxide which is capable of forming a mist, and particularly for monitoring industrial emission process gases containing sulphur trioxide, for controlling the recycling of such gases and/or the emission of said gases to the surroundings, with the view of protecting the environment.
Background Art
When producing sulphuric acid problems relating to the undesirable emission of sulphur trioxide constantly occur, such occurrence being particularly evident when process equipment becomes overloaded and/or break downs in operation occur and/or production is re-started after such break downs.
Such emission can be tolerated in itself, provided that it is on such a small scale as to have no cronic effect on the environment. The emission of such gases must not be continuous, however, and consequently it is necessary to monitor gases which derive from industrial processes and which are liable to create emission problems.
Although with respect to certain gases, it is possible to assay the gas in the actual chimney stack, using light-absorption assaying methods herefor, the gas has either already been discharged from the system to the surroundings, or is in the process of being discharged, thereby rendering it impossible to recycle the gas, should such prove desirable.
OMPI_ S ~rf Thus, there is a demand for a method by which the sulphur trioxide content of a dry exhaust gas can be measured downstream of an absorption tower in a sulphuric acid plant, so that the gas can be checked and controlled in a rapid fashion.
Disclosure of the Invention
It has now surprisingly been found possible, in accordance with the present invention, to assay gases containing sulphur trioxide which is able to form a mist, the invention being characterized by drawing the dry gas into a closed space by suction; contacting the gas with air comprising normal humidity which reacts therewith to form a mist; and measuring the light extinction properties of the gas.
By means of the present invention gases comprising sulphur trioxide in an amount down to 35 mg SO3 per m^ can be determined using ordinary air having a normal humidity, i.e. a water content of 15 to 20 g of H2O per m3. It has been noted that the water content should not be less than about 15 g of H O per m3, although the amount of sulphur trioxide is low and that thereby not all water is needed.
Further characterizing features of the invention are set forth in the following claims.
The present invention will now be described with reference to the accompanying drawing, in which
Fig 1 is a sectional view of a preferred first embodiment of an assaying appa¬ ratus according to the invention, placed in a residual gas conduit; and . /- ■
1?ϊg 2 is a cross-sectional view^f a second preferred embodiment of an assaying apparatus according to the invention. ? f * ~
Referring first to Fig 1, there is illustrated a cylindrical tube 1, suitably made of an acid-proof material such as acid-proof steel or polypropylene. Arranged
OMPI « τ°o on one end 2 of the tube is a housing 3 which contains a mirror 4. Immediately in front of the housing 3 is a gas inlet pipe 5. Arranged in the vicinity of the mirror 4 is a second inlet pipe 6, said pipe being intended to conduct air and/or an inert gas. Arranged on the other end 7 of the tube 1 is a second housing δ which contains a photodiode 9 and a receiver, photocell, 10. The receiver 10 is coupled to a transmitter 11, which transfers incoming signals to a writer and/or display instrument (not shown). Coupled to the housing 8 is a supply pipe 12, which is arranged to transfer said air and/or inert gas. The pipe 12 communicates with the pipe 6 and also with a connector 13 arranged around the photodiode 9 and receiver 10, for the introduction of said air/inert gas to the region around said diode and receiver. Also arranged at said other end 7 of the tube 1 is an outlet pipe 14, which is connected to a suction source, for example a vacuum pump (not shown).
The embodiment illustrated i Fig 2 comprises a cylindrical tube 1, made of polypropylene for example. Arranged at one end 2 of the tube 1 is a housing 3, which accomodates a photodiode 9. The embodiment also includes a pipe 16 through which air for flushing out the interior of the tube can be introduced thereinto. Arranged at the end 2 of the tube 1 are two inlet pipes 5 and 6, the first mentioned pipe being connected to a residual-gas line (not shown) and the latter being connected to an air source. The other end 7 of the tube 1 is provided with a further housing 8, which accomodates a receiver 10 and a transmitter 11. Connected to the housing 8 is a further air-flush inlet pipe 12. Also connected to said other end 7 of the pipe 1 is an outlet pipe 14, which is connected to a suction source not shown.
The apparatus have the following mode of operation:
When using the apparatus illustrated in Figs 1-2, the outlet pipe 14 to the vacuum source is opened, whereupon gas is drawn from the residual gas conduit into the tube' 1. The* gas may comprise a gas leaving an absorption tower in a sulphuric-fteid plapt, andaat is thus desired to measure the residual quantities of sulphur trioxide in the gas. At the same time, moist air is passed through the pipe 6, this air being intended to flush clean the area around the mirror 4 and the photodiode 9 respectively, and to react with any sulphur trioxide
"YΠPO"
« o present, to form a sulphuric-acid mist. The humidity of the air is that normally present in ambient air under ordinary climate conditions. At the same time as air is drawn in through the pipe 6, air is also drawn in through the piping 12/13 and through the housing 8 so as to flush around the photodiode 9/receiver 10 and the receiver 10 respectively. The photodiode 9 emits a beam of light which, if there is no mist in the tube 1, passes to the receiver 10, at full strength, optionally via the mirror 4 when the embodiment according to Fig 1 is used. When a mist is formed, due to presence of sulphur trioxide, the light transmitted is obliterated, either totally or partially, the extent to which said light is blotted being proportional to the amount of sulphur trioxide present.
When the amount of sulphur trioxide present is found to be highly excessive, the gas in the residual gas conduit can be returned to the absorption tower in the sulphuric-acid plant, or can be rendered innocuous in some other way, for example by scrubbing. In the Fig 2 embodiment it is assumed that a residual gas is introduced through the pipe 5, at the same time as air with normal humidi¬ ty is drawn in through the pipe 6 and cleaning dry, air is passed through the pipe 16. If any sulphur trioxide is present it will react with the water to form a mist whose ability to extinguish light transmitted from the photodiode can be readily measured in the aforementioned manner.
All gases are withdrawn by suction through the outlet pipe 14, thereby maintain¬ ing the light source 9 and receiver 10 free from coatings, for example coatings of sulphuric acid, and continuous assaying can be effected, since fresh gas/gases can constantly be introduced into the apparatus.
By using a mirror/reflector arrangement in accordance with Fig 1, it is possible to double the length of the light beam, or the instrument can be correspondingly shortened to half its length, such an embodiment being of interest when the apparatus is to be inserted in a residual gas conduit 21. When the tube 1 is also located in the residual gas conduit, it will be heated to the same tempera- ture?_£s the gas, thereby eliminating risk of ^condensation. Suitably, the interior surfaces of the tube 1 and the houses 3 and 8 are so formed as to prevent any condensate which may form from reaching the light source/receiver units, for example as illustrated in Fig 2. When assaying sulphur trioxide, the content range may be 35-1000 mg SO3 pei* m3 of gas, this range fully covering all current operational conditions.
The above description has been made with reference to gases discharged from process industries. It will be understood, however, that combustion gases can be assayed and controlled in a similar manner, particularly when the combustion gases are substantially free from soot and other particles, as is the case with large combustion plants.
fr* - . *

Claims

1. A method for assaying gases comprising sulphur trioxide capable of forming a mist, characterized by drawing the gas to be assayed into a closed space; by contacting said gas with air comprising normal humidity which reacts with the sulphur trioxide to form a mist; and measuring the extent to which the mist extinguishes light.
2. A method according to claim 1, characterized by introducing the gas into a measuring cell, and by passing a further gas into light-measuring units arranged in the measuring cell.
3. A method according to claim 2, characterized in that the further gas is air comprising humidity which is to react with the first mentioned gas to form said mist.
4. A method according to claims 1-3, characterized in that the air comprises at least about 15 g of H2O per m3.
5. Apparatus for carrying out the method according to claims 1-4, characte¬ rized in that said apparatus includes a closed space in which there is arranged a light source and a receiver for receiving a beam of light emitted from said light source, said light beam being arranged to pass through said closed space; an inlet line for gas to be assayed; at least one inlet line for at least one further gas; and an outlet line for removal of said gases, said outlet and inlet lines being arranged in spaced apart relationship.
6. An apparatus according to claim 5, characterized in that the light souce and a mirror are arranged so that a beam of light emitted from the light source is able to pass through the closed space in two diametrically opposed directions.
7. An apparatus according to claim 5, characterized in that inlet lines for further gas are so arranged that gas supplied therethrough passes into assay¬ ing units arranged in said space.
^z**
PCT/SE1984/000088 1983-03-18 1984-03-12 A method and an apparatus for assaying sulphur trioxide WO1984003770A1 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
DE8484901127T DE3472457D1 (en) 1983-03-18 1984-03-12 A method and an apparatus for assaying sulphur trioxide
AT84901127T ATE35461T1 (en) 1983-03-18 1984-03-12 METHOD AND DEVICE FOR DETECTING SULFUR TRIOXIDE.
DK507984A DK507984D0 (en) 1983-03-18 1984-10-24 METHOD AND APPARATUS FOR DETERMINING SULFUR TRYOXIDE
NO844348A NO162437C (en) 1983-03-18 1984-11-01 PROCEDURE AND APPARATUS FOR AA DETERMINE SULFUR TRYOXYD.
FI844433A FI80149C (en) 1983-03-18 1984-11-12 FOERFARANDE OCH APPARATUR FOER ANALYSERING AV SVAVELTRIOXID.

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
SE8301488A SE8301488L (en) 1983-03-18 1983-03-18 Saturation and device for saturation of gases forming a fog

Publications (1)

Publication Number Publication Date
WO1984003770A1 true WO1984003770A1 (en) 1984-09-27

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/SE1984/000088 WO1984003770A1 (en) 1983-03-18 1984-03-12 A method and an apparatus for assaying sulphur trioxide

Country Status (7)

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US (1) US4629704A (en)
EP (1) EP0138879B1 (en)
DE (1) DE3472457D1 (en)
DK (1) DK507984D0 (en)
FI (1) FI80149C (en)
SE (1) SE8301488L (en)
WO (1) WO1984003770A1 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10488258B2 (en) * 2012-12-12 2019-11-26 Spectrasensors, Inc. Optical reflectors for spectrometer gas cells
CN103472061B (en) * 2013-08-27 2016-05-04 浙江大学 The on-line measuring device of sulfur trioxide and method in a kind of flue gas

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US3945801A (en) * 1974-11-07 1976-03-23 The United States Of America As Represented By The United States National Aeronautics And Space Administration Office Of General Counsel Code-Gp Indicator providing continuous indication of the presence of a specific pollutant in air
US4078896A (en) * 1977-01-21 1978-03-14 International Telephone And Telegraph Corporation Photometric analyzer
US4272249A (en) * 1980-01-28 1981-06-09 E. I. Du Pont De Nemours And Company Method of monitoring oxygen concentrations in gas streams

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Patent Citations (4)

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Publication number Priority date Publication date Assignee Title
DE2340747A1 (en) * 1972-10-26 1974-05-09 Bailey Meter Co GAS ANALYZER
US3945801A (en) * 1974-11-07 1976-03-23 The United States Of America As Represented By The United States National Aeronautics And Space Administration Office Of General Counsel Code-Gp Indicator providing continuous indication of the presence of a specific pollutant in air
US4078896A (en) * 1977-01-21 1978-03-14 International Telephone And Telegraph Corporation Photometric analyzer
US4272249A (en) * 1980-01-28 1981-06-09 E. I. Du Pont De Nemours And Company Method of monitoring oxygen concentrations in gas streams

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Also Published As

Publication number Publication date
FI844433L (en) 1984-11-12
FI80149C (en) 1990-04-10
DK507984A (en) 1984-10-24
DK507984D0 (en) 1984-10-24
SE8301488L (en) 1984-09-19
FI80149B (en) 1989-12-29
US4629704A (en) 1986-12-16
SE8301488D0 (en) 1983-03-18
FI844433A0 (en) 1984-11-12
DE3472457D1 (en) 1988-08-04
EP0138879A1 (en) 1985-05-02
EP0138879B1 (en) 1988-06-29

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