US20050170177A1

US20050170177A1 - Conductive filament

Info

Publication number: US20050170177A1
Application number: US10/767,668
Authority: US
Inventors: Julian Crawford; Frederico Traetz
Original assignee: Individual
Current assignee: TS CABOS IND COM LTDA; Teijin Monofilament US Inc
Priority date: 2004-01-29
Filing date: 2004-01-29
Publication date: 2005-08-04
Also published as: EP1559815A2; ES2308098T3; JP2005213718A; EP1559815A3; DE602004014587D1; PT1559815E; EP1559815B1; PL1559815T3; ATE399222T1

Abstract

A multi-component conductive yarn which includes a primary component and a secondary component. The primary component consists of at least one elongated filament formed of polymeric material while the secondary component consists of a blend of polymeric material and carbon nanotubes. The secondary component is bonded with the primary component along its length. The carbon nanotubes comprise up to 20% of the secondary component. The conductive yarn comprises no more than 10% carbon nanotubes.

Description

DEFINITION OF TERMS

Filament—a shaped body, usually formed of polymeric material, of relatively small cross section and of indefinite length.
Yarn—here: A product formed of at least one filament (=monofilament) or an assembly of filaments (=multifilament)
Multi-Component Yarn—A yarn formed of two or more different materials and/or of two or more different yarns.
Conductivity—definition of what is considered to be conductive

BACKGROUND OF THE INVENTION

It has long been known to produce conductive yarns from thermoplastic polymers which are combined with a conductive material such as carbon. In many instances the carbon is combined with the yarn as a coating. This is not wholly acceptable because carbon or carbon loaded polymeric resin does not adhere well which causes flaking or peeling. Another concern is the mass of carbon required in order to generate an acceptable level of conductivity. Because relatively large percentages of carbon must be combined with the polymer resin to make it conductive, the yarn properties are severely compromised. Historically, the carbon content necessary to provide adequate conductivity is more than 25% by weight. The technical properties of yarns containing this level of carbon content is severely affected.
Carbon nanotubes, which have recently been developed, are essentially very fine carbon fibers. This nano size allows the use of a low percentage of carbon in a polymeric composition while providing for the requisite conductive properties.
It is the primary object of the instant invention to provide a multi-component yarn which is conductive, does not flake, is not brittle and has good physical properties.
Another object of the invention is a multi-component conductive yarn in which no component includes more than 20% carbon by weight.
Another object of the invention is a multi-component conductive yarn which contains less than 10% carbon by weight.
Another object of the invention is a multi-component conductive yarn which includes a plurality of components, at least one of which is a conductive filament.
Another object of the invention is the provision of a multi-component yarn with a conductive sheath secured to a non-conductive core.
Another object of the invention is a multi-component conductive yarn in which one component includes carbon nanotubes which form the electrical conductor.
Another object of the invention is a multi-component conductive yarn in which multiple components include carbon nanotubes which form the electrical conductor.
Another object of the invention is a multi-component conductive yarn which is physically resilient.
The invention is intended for use in a variety of applications including, but not limited to, lay belts, conveyor belts, braiding, industrial textiles, filtration, paper machine clothing, IFBC shipping bags, upholstery, home furnishings, hook and loop, carpets, apparel, nonwovens, brushes and process forming belts.

SUMMARY OF THE INVENTION

The invention is directed to a multi-component conductive yarn and the method of forming. The yarn comprises a primary component and a secondary component. The primary component consists of an elongated filament formed from polymeric material. The secondary component consists of a fiber of a polymeric material and carbon nanotubes which is bonded with the primary component along its length. The carbon included in the secondary component includes up to 20% by mass of carbon nanotubes. The secondary component when combined with the first component provides a conductive yarn which comprises no more than 10% carbon nanotubes by weight.
The polymeric material forming the primary component may be one of any melt-spinnable polymer, preferred is one of or a blend of polyester (such as PET, PTT, PBT, PCTA, Polycarbonate, etc.), polyamide, PPS, polypropylene, polyethylene and/or PEEK. The polymeric material of said secondary component includes at least 80% of one of polyester, polyamide, PTT, PBT, PPS, polypropylene, polyethylene and PEEK while carbon nanotubes comprise the remainder of the makings of the component.
The secondary component may comprise a sheath surrounding the filament of the primary component. Alternatively, the secondary component may comprise an elongated filament bonded with the filament of the primary component along its length.
The secondary component may wrap around the primary component as it extends along its length.
The secondary component may comprise between 0.5% and 50% by weight of the multi-component yarn while the carbon nanotubes may comprise up to 20% by weight, preferred no more than 15% by weight, of the secondary component.
The primary component may be a yarn which has been stretched and heat set prior to being combined with the secondary component. Alternatively, the first and second components may be extruded simultaneously and joined forming the multi-component yarn. The so formed yarn may then be stretched and heat set. Such a yarn is called a heterofilament yarn.
The invention further includes a method of forming a conductive multi-component yarn. The method includes the steps of providing at least a first component consisting of at least one elongated filament of polymeric material. Also, providing at least a second component consisting of a composition including a polymeric resin and carbon nanotubes. Limiting the carbon nanotubes to between 0.5% to 20% of the composition of the second component. Passing the first component through a crosshead extruder in the form of a filament while the second component is extruded onto the first component causing it to bond therewith forming the composite yarn as a core filament comprised of the first component with a conductive sheath formed there about. This type of yarn is called a coated yarn. Alternately, the method may comprise simultaneously extruding the first and second components forming multiple filaments and causing the filaments to bond together along their length. This type of yarn is called bonded filaments.

DESCRIPTION OF THE DRAWINGS

The construction designed to carry out the invention will hereinafter be described, together with other features thereof.
The invention will be more readily understood from a reading of the following specification and by reference to the accompanying drawings forming a part thereof, wherein an example of the invention is shown and wherein:
FIG. 1 is a schematic view showing a process forming a multi-component yarn of the invention. It is the coating process of the first component with a second component by a crosshead extruder.
FIG. 2 is a schematic view showing another process for forming a multi-component yarn of the invention.
FIG. 3A is a cross sectional view of a multi-component yarn of the invention.
FIG. 3B is a cross sectional view of another multi-component yarn of the invention.
FIG. 3C is a cross sectional view of another multi-component yarn of the invention.
FIG. 3D is a cross sectional view of another multi-component yarn of the invention.
FIG. 3E is a cross-sectional view of another multi-component yarn of the invention.
FIG. 3F is a cross-sectional view of another multi-component yarn of the invention.
FIG. 3G is a cross-sectional view of another multi-component yarn of the invention.
FIG. 4 is a diagrammatic view showing aligned nanotubes.

DESCRIPTION OF A PREFERRED EMBODIMENT

Referring now in more detail to the drawings, the invention will now be described in more detail.
Carbon nanotubes are extremely small conductive elements which have found use with polymers as a conductive additive. A primary advantage of carbon nanotubes is that they possess a higher aspect ratio than carbon black particles or chopped carbon which allows for a lower additive loading while maintaining adequate levels of conductivity.
Carbon nanotubes comprise elongated particles which tend to intertwine and have a low sensitivity to shear fields. This provides the capability of elongating the polymeric resin containing carbon nanotubes without entirely severing the carbon nanotube agglomerates which are formed within the polymer. FIG. 4 schematically shows generally the manner in which carbon nanotubes can be distributed in a polymeric resin.
In a conductive yarn it has been most difficult to produce a yarn which retains most of the desired fiber characteristics normally achieved from the original polymer resin due to the negative impact of the carbon. A major contributor to this problem is the amount of carbon necessary to provide for the fiber to be sufficiently conductive. If the carbon additive is combined with the polymer in the form of a coating, the coating has the tendency to peel and crack.
The instant invention provides to overcome these drawbacks by providing a conductive multi-component yarn which retains the desired physical characteristics, is flexible and does not peel or crack.
Turning now to FIG. 1, a supply 10 comprising a set filament 12 is seen being passed through at least one but preferably a plurality of extruder dies which extrude a coating or adhering resin compound 14 onto the filament 12 as it passes. Resin compound 14, in this instance, forms a sheath 16 about filament 12. Also, in this instance, as filament 12 is already stretched and heat set, sheath 16 is allowed to solidify and the multi-component yarn 18 is simply rewound for shipment. Alternatively, the multi-component yarn could be passed between draw rolls and through an oven where the yarn is stretched, relaxed, or both and then heat set.
The multi-component yarn 18 may comprise a core usually formed of a polyester (such as PET, PTT, PBT, PCTA, etc) or a polyamide fiber. The core could alternatively be polypropylene, polyethylene, PPS, PEEK or other melt-spinnable polymers or a blend of these polymers. The core may comprise one or a plurality of filaments. It can also be a yarn made of natural fibers and staple fibers.
The sheath comprises a polymer, again usually a polyester or a polyamide combined with carbon nanotubes. Again, the above listed resins could also comprise the polymer forming the sheath.
Resin compound 14 comprises between 0.5% to 20% carbon nanotubes and between 80% to 99.5% polyester or other polymer or blend of polymers. Sheath 16 comprises between 0.5% to 50% of the mass of the multi-component yarn while core 12 forms between 50% to 99.5% of the multi-component yarn.
The nanotubes within resin 14 are interspersed along the length of the sheath and about the core providing a conductive artery along the length of the multi-component yarn. The percentage of the multi-component yarn consisting of carbon nanotubes is between 0.5% and 15%. Such a low percentage of carbon allows the resins forming the compound 14 to maintain substantially all of their normal features such as elasticity, strength and elongation. Normally the core of the multi-component yarn retains all of its usual characteristics as it is formed of 100% polymer.
In a second arrangement for forming the multi-component yarn, yarn 12 is pre-formed but not set. Yarn 12 is drawn from supply 10 and passes through the extruders extruding compound 14 producing yarn 18 as earlier described. In the alternative arrangement, the just formed multi-component yarn is passed between draw rolls and through an oven where the yarn is stretched, relaxed, or both and then heat set. Both the core 12 and sheath 16 are treated and then set. This is possible due to the innate characteristics of carbon nanotubes which are not so easily separated but remain substantially in contact and because of the limited percentage of nanotubes present in the sheath 16.
Other arrangements are shown in FIG. 2. In a first arrangement a pair of extruders 20, 22 are shown. Extruder 20 extrudes the core yarn 12 while extruder 22 extrudes the second component 24. The extruders are controlled in known manner which allows the second component 24 to adhere to core 12 along its length in the form of an elongated filament 28. FIG. 2 also represents the heterofilament process. In this case both components are molten in their extruders 20 and 22 and pressed into a special designed spinhead in which both components are simultaneously spun into a multi-component yarn 28.
The multi-component yarn 28 shown in FIG. 3 is passed between draw rolls 30, stretched and/or relaxed and then heat set by heater 32.
It is noted that component 24 may be dispensed in the form of sheath 16 as shown in FIG. 3A which encases the core along its length. The extruded compound 24 can be controlled to attach to the core 12 in the form of a wedge shaped filament 26 or an additional filament 26 which extends along the length and is wrapped about its axis of core 12 as shown in FIGS. 3B and 3E. Another arrangement could be for core 12 to be arranged on opposed sides of compound 24 which assumes the form of a conductive strip 26′ which extends along the length of core 12 as shown in FIG. 3C. The extruded compound 24 could form a plurality of wedge shaped filaments 26 or additional filaments 26 which are arranged along the length of core 12 as shown in FIGS. 3D and 3F. Another arrangement could be for core 12 to be first coated by sheath 36 and then by conductive sheath 16. Sheath 36, which is preferably a low melt polymer, adhesive type polymer, co-polyester or other suitable material, provides an intermediate layer which provides increased adhesion between the core 12 and the conductive sheath 16. In each of the arrangements sheath 16, filaments 26 and strips 26′ form a conductive filament which is adhered with core 12 along its length.
In all arrangements, the percentage of the first component or core polymer and the percentage of the second component or conductive polymer+carbon nanotubes remains within the set forth limits.
It is noted that the core could consist of a plurality of filaments which are preferably but not necessarily of the same polymer. The core could consist of a blend of polymers. Also the sheath or conductive filament could consist of a blend of polymers combined with the carbon nanotubes.
The multi-component conductive yarn of the invention is intended for use with a multiple of fabric types such as woven fabrics, knitted fabrics, braided fabrics, non-woven fabrics, interlaid fabrics and composite fabrics. The yarn is intended to comprise varying selected percents of yarns forming these fabrics. Also, the yarn is intended for use with any combination of the above fabric types.
While a preferred embodiment of the invention has been described using specific terms, such description is for illustrative purposes only, and it is to be understood that changes and variations may be made without departing from the spirit or scope of the following claims.

Claims

1. A multi-component conductive yarn comprising a primary component and a secondary component:

said primary component consists of at least one elongated filament formed of polymeric material;

said secondary component consists of a blend of polymeric material and carbon bonded with said primary component along its length;

said carbon material of said secondary component comprises carbon nanotubes which constitute up to 20% of said secondary component; wherein,

said conductive yarn comprises no more than 10% carbon nanotubes.

2. The yarn of claim 1 wherein said polymeric material of said primary component is formed of at least one of polyester, polyamide, polypropylene, polyethylene, PPS and PEEK.

3. The yarn of claim 1 wherein said polymeric material of said secondary component includes at least 80% of at least one of polyester, polyamide, polypropylene, polyethylene, PPS and PEEK.

4. The yarn of claim 1 wherein said secondary component comprises a sheath bonded with and surrounding said filament of said primary component.

5. The yarn of claim 1 wherein said secondary component comprises an elongated filament bonded with said filament of said primary component along its length.

6. The yarn of claim 1 wherein said secondary component comprises between 0.5% and 50% of said multi-component yarn.

7. The yarn of claim 5 wherein said carbon nanotubes comprise up to 20% of said secondary component.

8. The conductive yarn of claim 1 wherein said primary component is set prior to bonding with said secondary component.

9. The conductive yarn of claim 1 wherein said multi-component yarn is set.

10. The conductive yarn of claim 1 wherein said primary component comprises a plurality of elongated filaments of synthetic material.

11. The conductive yarn of claim 10 wherein at least two of said plurality of filaments are formed of different polymers.

12. The conductive yarn of claim 10 wherein said filaments are set prior to bonding with said secondary components.

13. A method of forming a conductive multi-component yarn including:

providing a first component comprising at least one elongated filament of synthetic material and setting said filament;

providing a second component consisting of a composition including polymeric resin and carbon nanotubes and further providing that the carbon nanotubes comprise between 0.1% to 25% of the composition;

passing said first component through an extruder die and extruding said second component onto said first component forming a conductive filament along said first component; and,

curing said multi-component yarn.

14. The method of claim 13 including setting said elongated filament of said first component prior to passing said first component through said extruder.

15-16. (canceled)

17. A method of forming a multi-component conductive yarn including the steps:

providing a first component comprising at least one resin of polymer resin;

providing a second component including a composition including a polymeric resin and carbon nanotubes with the carbon nanotubes comprising between 0.1% to 25% of the composition;

providing two extruders and extruding simultaneously said first and second components forming said first and second filaments;

causing said first and second filaments to bond along their length forming a conductive multi-component yarn; and

curing said conductive multi-component yarn.

18. The method of claim 17 wherein said curing Includes passing said bonded first and second filaments between draw rolls and a heater causing said multi-component yarn to be heat set.

19-20. (canceled)

21. A method of fanning a conductive multi-component yarn including:

providing a first component comprising at least one polymeric resin;

providing a second component consisting of a composition including polymeric resin and carbon nanotubes with the carbon nanotube comprising no more than 25% of the composition;

extruding said first and second components and causing said first and second components to be engaged longitudinally;

curing said extruded and engaged components forming said multi-component yarn.