KR890009831A - 비스페놀 a의 제조방법 - Google Patents
비스페놀 a의 제조방법 Download PDFInfo
- Publication number
- KR890009831A KR890009831A KR1019880016077A KR880016077A KR890009831A KR 890009831 A KR890009831 A KR 890009831A KR 1019880016077 A KR1019880016077 A KR 1019880016077A KR 880016077 A KR880016077 A KR 880016077A KR 890009831 A KR890009831 A KR 890009831A
- Authority
- KR
- South Korea
- Prior art keywords
- reaction
- acetone
- exchange resin
- cation exchange
- bisphenol
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C39/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring
- C07C39/12—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring polycyclic with no unsaturation outside the aromatic rings
- C07C39/15—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring polycyclic with no unsaturation outside the aromatic rings with all hydroxy groups on non-condensed rings, e.g. phenylphenol
- C07C39/16—Bis-(hydroxyphenyl) alkanes; Tris-(hydroxyphenyl)alkanes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/11—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms
- C07C37/20—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms using aldehydes or ketones
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제 1도는 비스페놀 A의 제조에 대한 본 발명의 실시예를 설명하는 흐름도.
* 도면의 주요부분에 대한 부호의 설명
1 : 페놀 2 : 혼합용기
3 : 아세톤 5 : 제1반응기
6 : 반응생성혼합물 7 : 반응생성혼합물의 일부
8 : 반응생성혼합물의 나머지 9 : 염화수소 흡수관
10 : 염화수소 11 : 진한염산
14 : 제2반응기 15 : 반응생성물
Claims (7)
- 아세톤과 페놀의 반응으로 비스페놀 A를 제조하는 방법은, (a) 반응내에 20∼60%의 아세톤을 전환시키기 위해 메르캅토기 함유화합물로 변성된 술폰산형태의 양이온 교환수지의 존재하에 아세톤과 페놀의 반응을 실행하는 단계와 (b) 염산촉매의 존재하에 반응안된 아세톤을 함유하는 결과의 반응혼합물을 더욱 반응시키는 단계를 포함하는 것을 특징으로 하는 비스페놀 A의 제조방법.
- 제1항에 있어서, 여기서 아세톤대 페놀의 몰비는 1 : 4∼12인 것을 특징으로 하는 비스페놀 A의 제조 방법.
- 제1항에 있어서, 여기서 상기 양이온 교환수지내에 술폰산기의 5∼35몰%는 메르캅토기 함유화합물로 변성되는 것을 특징으로 하는 비스페놀 A의 제조방법.
- 제1항에 있어서, 여기서 상기 양이온 교환수지내에 술폰산기의 12몰%는 메르캅토에틸아민으로 변성되는 것을 특징으로 하는 비스페놀 A의 제조방법.
- 제1항에 있어서, 여기서 양이온 교환수지 존재하의 상기 반응은 30∼120℃의 온도에서 실행하는 것을 특징으로 하는 비스페놀 A의 제조방법.
- 제1항에 있어서, 여기서 염산촉매존재하의 상기 반응은 30-85℃의 온도에서 실행하는 것을 특징으로 하는 비스페놀 A의 제조방법.
- 제1항에 있어서, 여기서 양이온 교환수지 존재하의 반응과 염산촉매존재하의 반응은 배치방식으로 실행되는 것을 특징으로 하는 비스페놀 A의 제조방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP62305942A JPH07103058B2 (ja) | 1987-12-04 | 1987-12-04 | ビスフェノールaの製造方法 |
JP62-305942 | 1987-12-04 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR890009831A true KR890009831A (ko) | 1989-08-04 |
KR910003252B1 KR910003252B1 (ko) | 1991-05-25 |
Family
ID=17951153
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019880016077A KR910003252B1 (ko) | 1987-12-04 | 1988-12-02 | 비스페놀 a의 제조방법 |
Country Status (8)
Country | Link |
---|---|
US (1) | US4918245A (ko) |
EP (1) | EP0319327B1 (ko) |
JP (1) | JPH07103058B2 (ko) |
KR (1) | KR910003252B1 (ko) |
CN (1) | CN1013364B (ko) |
CA (1) | CA1282797C (ko) |
DE (1) | DE3870172D1 (ko) |
ES (1) | ES2030874T3 (ko) |
Families Citing this family (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2658814B1 (fr) * | 1990-02-28 | 1993-12-31 | Rhone Poulenc Chimie | Procede de fabrication du bisphenol-a. |
US5336813A (en) * | 1990-11-13 | 1994-08-09 | General Electric Company | Process for low color bisphenol |
WO1994019079A1 (en) * | 1993-02-17 | 1994-09-01 | China Petro-Chemical Corporation | A multiple stage suspended reactive stripping process and apparatus |
CN1080914A (zh) * | 1993-02-17 | 1994-01-19 | 中国石油化工总公司 | 一种2,2-二(4-羟基苯基)丙烷的制造方法 |
US5315042A (en) * | 1993-03-22 | 1994-05-24 | General Electric Company | Use of partial acetone conversion for capacity increase and quality/yield improvement in the bisphenol-A reaction |
US5414151A (en) * | 1994-05-02 | 1995-05-09 | General Electric Company | Method for making bisphenol |
DE19540497A1 (de) * | 1995-10-31 | 1997-05-07 | Degussa | Sulfonat- und mercaptogruppenhaltige anorganische Trägermaterialien, Verfahren zu ihrer Herstellung und Verwendung als Katalysatoren |
DE19640710A1 (de) * | 1996-10-02 | 1998-04-09 | Phenolchemie Gmbh | Verfahren zum Transport und zur Lagerung von Phenol |
ID30168A (id) * | 2000-01-07 | 2001-11-08 | Idemitsu Petrochemical Co | Proses pembuatan bisfenol a |
ES2320322T3 (es) | 2000-09-19 | 2009-05-21 | Dow Global Technologies Inc. | Procedimiento para producir una resina de intercambio cationico fuertemente acida. |
US6703530B2 (en) | 2002-02-28 | 2004-03-09 | General Electric Company | Chemical reactor system and process |
US7112702B2 (en) * | 2002-12-12 | 2006-09-26 | General Electric Company | Process for the synthesis of bisphenol |
US6635788B1 (en) * | 2002-12-20 | 2003-10-21 | General Electric Company | Process for manufacture of bisphenols |
US6858759B2 (en) * | 2002-12-20 | 2005-02-22 | General Electric Company | Process for manufacture of bisphenols |
US7132575B2 (en) * | 2003-07-01 | 2006-11-07 | General Electric Company | Process for the synthesis of bisphenol |
US7041774B2 (en) | 2003-09-30 | 2006-05-09 | General Electric Company | Functionalized zeolite compositions and methods for their preparation and use |
US8735634B2 (en) | 2011-05-02 | 2014-05-27 | Sabic Innovative Plastics Ip B.V. | Promoter catalyst system with solvent purification |
US9290618B2 (en) | 2011-08-05 | 2016-03-22 | Sabic Global Technologies B.V. | Polycarbonate compositions having enhanced optical properties, methods of making and articles comprising the polycarbonate compositions |
CN104205376B (zh) | 2012-02-03 | 2018-04-27 | 沙特基础全球技术有限公司 | 发光二极管器件及用于生产其的包括转换材料化学的方法 |
CN104145001A (zh) | 2012-02-29 | 2014-11-12 | 沙特基础创新塑料Ip私人有限责任公司 | 含转换材料化学物质并具有增强的光学特性的聚碳酸酯组合物、其制造方法及包含其的制品 |
EP2819981B1 (en) | 2012-02-29 | 2016-12-21 | SABIC Global Technologies B.V. | Process for producing low sulfur bisphenol a, processes for producing polycarbonate, articles made from polycarbonate |
US9346949B2 (en) | 2013-02-12 | 2016-05-24 | Sabic Global Technologies B.V. | High reflectance polycarbonate |
KR101961312B1 (ko) | 2012-10-25 | 2019-03-22 | 사빅 글로벌 테크놀러지스 비.브이. | 발광 다이오드 장치, 이의 제조 방법 및 용도 |
KR102229148B1 (ko) | 2013-05-29 | 2021-03-23 | 사빅 글로벌 테크놀러지스 비.브이. | 색 안정한 열가소성 광투과 물품을 갖는 조명 장치 |
CN106563502B (zh) * | 2016-11-04 | 2019-01-25 | 凯瑞环保科技股份有限公司 | 一种双酚a合成树脂催化剂及其制备方法 |
US11260378B2 (en) * | 2017-04-24 | 2022-03-01 | Badger Licensing Llc | Catalyst system and process for producing bisphenol-A |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3172916A (en) * | 1965-03-09 | Bisphenol axpreparation u using ion ex- change resin containing mercapto and sulfonic acid groups | ||
US2359242A (en) * | 1941-08-23 | 1944-09-26 | Dow Chemical Co | Preparation of phenol-ketone condensation products |
US3221061A (en) * | 1961-08-01 | 1965-11-30 | Union Carbide Corp | Process for the production of 2,2-bis-(4-hydroxyphenyl) propane |
FR1342760A (fr) * | 1962-02-16 | 1963-11-15 | Progil | Fabrication d'aryl-alcanes |
DE1518321A1 (ko) * | 1964-07-24 | 1972-03-09 | ||
GB1578225A (en) * | 1977-07-11 | 1980-11-05 | Shell Int Research | Preparation of bisphenols |
US4188496A (en) * | 1977-12-23 | 1980-02-12 | General Electric Company | Process for preparing 2,2-bis(4-hydroxy-phenyl) propane from distillation by-products thereof |
US4308405A (en) * | 1978-07-05 | 1981-12-29 | Shell Oil Company | Preparation of bisphenols |
US4584416A (en) * | 1983-11-14 | 1986-04-22 | General Electric Company | Method and catalyst for making bisphenol |
-
1987
- 1987-12-04 JP JP62305942A patent/JPH07103058B2/ja not_active Expired - Lifetime
-
1988
- 1988-11-28 US US07/276,658 patent/US4918245A/en not_active Expired - Fee Related
- 1988-12-02 DE DE8888311465T patent/DE3870172D1/de not_active Expired - Fee Related
- 1988-12-02 EP EP88311465A patent/EP0319327B1/en not_active Expired - Lifetime
- 1988-12-02 ES ES198888311465T patent/ES2030874T3/es not_active Expired - Lifetime
- 1988-12-02 CA CA000584934A patent/CA1282797C/en not_active Expired - Fee Related
- 1988-12-02 KR KR1019880016077A patent/KR910003252B1/ko not_active IP Right Cessation
- 1988-12-03 CN CN88108296A patent/CN1013364B/zh not_active Expired
Also Published As
Publication number | Publication date |
---|---|
ES2030874T3 (es) | 1992-11-16 |
US4918245A (en) | 1990-04-17 |
JPH01149746A (ja) | 1989-06-12 |
CN1034360A (zh) | 1989-08-02 |
EP0319327B1 (en) | 1992-04-15 |
CN1013364B (zh) | 1991-07-31 |
EP0319327A1 (en) | 1989-06-07 |
JPH07103058B2 (ja) | 1995-11-08 |
KR910003252B1 (ko) | 1991-05-25 |
CA1282797C (en) | 1991-04-09 |
DE3870172D1 (de) | 1992-05-21 |
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