JPH0571052B2 - - Google Patents
Info
- Publication number
- JPH0571052B2 JPH0571052B2 JP61070024A JP7002486A JPH0571052B2 JP H0571052 B2 JPH0571052 B2 JP H0571052B2 JP 61070024 A JP61070024 A JP 61070024A JP 7002486 A JP7002486 A JP 7002486A JP H0571052 B2 JPH0571052 B2 JP H0571052B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- evoh
- polyamide
- gas barrier
- barrier properties
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920000219 Ethylene vinyl alcohol Polymers 0.000 claims description 61
- 239000004952 Polyamide Substances 0.000 claims description 42
- 229920002647 polyamide Polymers 0.000 claims description 42
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical group O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 claims description 14
- ALBYIUDWACNRRB-UHFFFAOYSA-N hexanamide Chemical group CCCCCC(N)=O ALBYIUDWACNRRB-UHFFFAOYSA-N 0.000 claims description 12
- 238000002844 melting Methods 0.000 claims description 11
- 230000008018 melting Effects 0.000 claims description 11
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 7
- 239000005977 Ethylene Substances 0.000 claims description 7
- 239000011342 resin composition Substances 0.000 claims description 4
- UFRKOOWSQGXVKV-UHFFFAOYSA-N ethene;ethenol Chemical compound C=C.OC=C UFRKOOWSQGXVKV-UHFFFAOYSA-N 0.000 description 59
- 239000004715 ethylene vinyl alcohol Substances 0.000 description 59
- 230000004888 barrier function Effects 0.000 description 58
- 239000007789 gas Substances 0.000 description 49
- 239000004677 Nylon Substances 0.000 description 29
- 229920001778 nylon Polymers 0.000 description 29
- 239000000203 mixture Substances 0.000 description 25
- 238000000034 method Methods 0.000 description 21
- 238000000465 moulding Methods 0.000 description 15
- 229920005992 thermoplastic resin Polymers 0.000 description 13
- 239000000499 gel Substances 0.000 description 12
- 238000010438 heat treatment Methods 0.000 description 12
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 11
- 239000001301 oxygen Substances 0.000 description 11
- 229910052760 oxygen Inorganic materials 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 9
- -1 polypropylene Polymers 0.000 description 9
- 229920005989 resin Polymers 0.000 description 9
- 239000011347 resin Substances 0.000 description 9
- 239000004840 adhesive resin Substances 0.000 description 8
- 229920006223 adhesive resin Polymers 0.000 description 8
- 238000005259 measurement Methods 0.000 description 8
- 230000035699 permeability Effects 0.000 description 8
- 238000002156 mixing Methods 0.000 description 7
- 239000004743 Polypropylene Substances 0.000 description 6
- 229920001155 polypropylene Polymers 0.000 description 6
- 239000000155 melt Substances 0.000 description 5
- 239000004014 plasticizer Substances 0.000 description 5
- 229920000570 polyether Polymers 0.000 description 5
- 238000007127 saponification reaction Methods 0.000 description 5
- 239000002253 acid Substances 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000001125 extrusion Methods 0.000 description 4
- 235000013305 food Nutrition 0.000 description 4
- 239000008188 pellet Substances 0.000 description 4
- 229920006122 polyamide resin Polymers 0.000 description 4
- 239000004721 Polyphenylene oxide Substances 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- DJZKNOVUNYPPEE-UHFFFAOYSA-N tetradecane-1,4,11,14-tetracarboxamide Chemical compound NC(=O)CCCC(C(N)=O)CCCCCCC(C(N)=O)CCCC(N)=O DJZKNOVUNYPPEE-UHFFFAOYSA-N 0.000 description 3
- MXAOILAHPVJWBS-UHFFFAOYSA-N 10-(azepan-1-yl)-10-oxodecanamide Chemical compound NC(=O)CCCCCCCCC(=O)N1CCCCCC1 MXAOILAHPVJWBS-UHFFFAOYSA-N 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- 230000005856 abnormality Effects 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 239000000806 elastomer Substances 0.000 description 2
- 239000005038 ethylene vinyl acetate Substances 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 238000003475 lamination Methods 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 238000003303 reheating Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- XDOLZJYETYVRKV-UHFFFAOYSA-N 7-Aminoheptanoic acid Chemical compound NCCCCCCC(O)=O XDOLZJYETYVRKV-UHFFFAOYSA-N 0.000 description 1
- 239000004230 Fast Yellow AB Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical class C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000000641 cold extrusion Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000009820 dry lamination Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 125000004494 ethyl ester group Chemical group 0.000 description 1
- 229920006226 ethylene-acrylic acid Polymers 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- 229960001545 hydrotalcite Drugs 0.000 description 1
- 229910001701 hydrotalcite Inorganic materials 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 229920000554 ionomer Polymers 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 235000013372 meat Nutrition 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- 229920006280 packaging film Polymers 0.000 description 1
- 239000012785 packaging film Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920005990 polystyrene resin Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229940124530 sulfonamide Drugs 0.000 description 1
- 238000003856 thermoforming Methods 0.000 description 1
- FKVMWDZRDMCIAJ-UHFFFAOYSA-N undecanamide Chemical compound CCCCCCCCCCC(N)=O FKVMWDZRDMCIAJ-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
- Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
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Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ ãšãã¬ã³å«æé25ã60ã¢ã«ïŒ ãããå床90ïŒ
以äžã®ãšãã¬ã³âããã«ã¢ã«ã³ãŒã«å ±éåäœ100
éééšããã³ããªã¢ããïŒã30éééšãããªãã
ãã€è©²ããªã¢ãããã«ããã¢ããåäœãïŒã50é
éïŒ å«æããããªã¢ãã(a)ãšã©ãŠãªã³ã©ã¯ã¿ã å
äœãïŒã49ééïŒ å«æããããªã¢ãã(b)ãšãããª
ãããã€è©²ããªã¢ãã(a)ããã³(b)ã®ééæ¯ã ïœïŒïœïŒïŒïŒ95ä¹è³95ïŒïŒ ã§ãããããã«è©²ããªã¢ãã(a)ããã³(b)ã®ããã
ãã®èç¹ã110ã180âã溶èç²æ§ææ°ã®æ¯ãïœïŒ
ïœïŒ0.1ã10ã§ããæš¹èçµæç©ã ïŒ (a)ããã³(b)ã®ããããã®èç¹ã120ã170âã§
ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®æš¹èçµæç©ã ïŒ ããªã¢ããã®æº¶èç²æ§ææ°ã0.5ãïŒïœïŒ10
åã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®æš¹èçµæ
ç©ã
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP7002486A JPS62225543A (ja) | 1986-03-27 | 1986-03-27 | æš¹èçµæç© |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP7002486A JPS62225543A (ja) | 1986-03-27 | 1986-03-27 | æš¹èçµæç© |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS62225543A JPS62225543A (ja) | 1987-10-03 |
JPH0571052B2 true JPH0571052B2 (ja) | 1993-10-06 |
Family
ID=13419617
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP7002486A Granted JPS62225543A (ja) | 1986-03-27 | 1986-03-27 | æš¹èçµæç© |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS62225543A (ja) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH01301243A (ja) * | 1988-05-30 | 1989-12-05 | Tokai Rubber Ind Ltd | å·åªèŒžéçšããŒã¹ |
JPH072403B2 (ja) * | 1988-06-06 | 1995-01-18 | æ±æµ·ãŽã å·¥æ¥æ ªåŒäŒç€Ÿ | å·åªèŒžéçšããŒã¹ |
JPH01308455A (ja) * | 1988-06-06 | 1989-12-13 | Tokai Rubber Ind Ltd | ã¬ã¹äžééæ§æš¹èçµæç© |
JP2002338767A (ja) * | 2001-05-16 | 2002-11-27 | Nippon Synthetic Chem Ind Co Ltd:The | ããŒãã·ãŒã«æ |
JP2003026887A (ja) * | 2001-07-17 | 2003-01-29 | Nippon Synthetic Chem Ind Co Ltd:The | åå±€å°åºæ圢å |
JP4353996B2 (ja) * | 2006-01-17 | 2009-10-28 | 暪æµãŽã æ ªåŒäŒç€Ÿ | äœééæ§ãŽã ç©å±€äœåã³ãããçšãã空æ°å ¥ãã¿ã€ã€ |
ES2908375T3 (es) * | 2015-05-20 | 2022-04-28 | Hakko Corp | Tubo de suministro de tinta |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5232944A (en) * | 1975-09-10 | 1977-03-12 | Toray Ind Inc | Polyamide composition |
JPS5478750A (en) * | 1977-12-06 | 1979-06-23 | Toray Ind Inc | Resin composition |
JPS5478749A (en) * | 1977-12-06 | 1979-06-23 | Toray Ind Inc | Resin composition |
JPS60174626A (ja) * | 1983-10-28 | 1985-09-07 | ã¹ã¿ãã«âãã³ã»ãã¹ãâãã ã»ãã³ãããã·ã€ãã | åäžå±€åã¯å€å±€ãã€ã«ã ã®è£œæ³ |
-
1986
- 1986-03-27 JP JP7002486A patent/JPS62225543A/ja active Granted
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5232944A (en) * | 1975-09-10 | 1977-03-12 | Toray Ind Inc | Polyamide composition |
JPS5478750A (en) * | 1977-12-06 | 1979-06-23 | Toray Ind Inc | Resin composition |
JPS5478749A (en) * | 1977-12-06 | 1979-06-23 | Toray Ind Inc | Resin composition |
JPS60174626A (ja) * | 1983-10-28 | 1985-09-07 | ã¹ã¿ãã«âãã³ã»ãã¹ãâãã ã»ãã³ãããã·ã€ãã | åäžå±€åã¯å€å±€ãã€ã«ã ã®è£œæ³ |
Also Published As
Publication number | Publication date |
---|---|
JPS62225543A (ja) | 1987-10-03 |
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