JPH05272526A - Connecting rod made of titanium alloy - Google Patents

Connecting rod made of titanium alloy

Info

Publication number
JPH05272526A
JPH05272526A JP9724992A JP9724992A JPH05272526A JP H05272526 A JPH05272526 A JP H05272526A JP 9724992 A JP9724992 A JP 9724992A JP 9724992 A JP9724992 A JP 9724992A JP H05272526 A JPH05272526 A JP H05272526A
Authority
JP
Japan
Prior art keywords
connecting rod
titanium alloy
carried out
layer
nitriding
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP9724992A
Other languages
Japanese (ja)
Inventor
Masahiko Kobayashi
雅彦 小林
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suzuki Motor Corp
Original Assignee
Suzuki Motor Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suzuki Motor Corp filed Critical Suzuki Motor Corp
Priority to JP9724992A priority Critical patent/JPH05272526A/en
Publication of JPH05272526A publication Critical patent/JPH05272526A/en
Pending legal-status Critical Current

Links

Landscapes

  • Shafts, Cranks, Connecting Bars, And Related Bearings (AREA)
  • Solid-Phase Diffusion Into Metallic Material Surfaces (AREA)

Abstract

PURPOSE:To improve fatigue strength without deteriorating hardness by remov ing a TiN layer on the surface of a titanium alloy connecting rod on whose surface nitriding is carried out by a specified thickness. CONSTITUTION:A TiN layer on the surface of a Ti alloy connecting rod on which nitriding is carried out is removed by a specified thickness. Al-Ti alloy Ti-6Al-4V is used, for instance, as a material of the connecting rod which is treated under a condition of a temperature at 850 deg.C and an N2 pressure at 0.13MPa, for fifteen hours. Samples are obtained by removing a nitrided layer by 2, 4 and 10mum through electrolytic polishing. Test is performed on each sample repeatedly under a condition of a speed at 57Hz, and R of 0.5 (indicates a load alternate repetition of 500g). Life is remarkably prolonged when the nitrided layer is removed by 4 to 10mum (zero mark indicates the material on whose surface electrilytic polishing is carried out).

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、窒化処理を施したチタ
ン合金製コネクテングロッドに関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a nitriding titanium alloy connecting rod.

【0002】[0002]

【従来の技術】エンジンの駆動系の軽量化の一端とし
て、図4に示すようなコネクテングロッドのチタン合金
化が考えられている。しかし、チタンは高い摩擦係数と
低い摩擦抵抗を示すので、他の金属と接触する摺動部
a,bにおいて焼付を生じ易いという欠点がある。その
ため、コネクテングロッドの摺動部に対しては、ガス窒
化による表面処理をおこない、耐摩耗性を向上させてい
る。
2. Description of the Related Art As one of ways to reduce the weight of an engine drive system, it has been considered to use a titanium alloy for a connecting rod as shown in FIG. However, since titanium has a high coefficient of friction and a low frictional resistance, it has a drawback that seizure is likely to occur in the sliding parts a and b that come into contact with other metals. Therefore, the sliding portion of the connecting rod is subjected to surface treatment by gas nitriding to improve wear resistance.

【0003】[0003]

【発明が解決しようとする課題】このように従来はチタ
ン合金製のコネクテングロッド対して、ガス窒化処理を
施して摺動部の耐摩耗性を向上させているが、窒化処理
の際、表面に生成するTiN層には、微小な亀裂を多く
含むとともに、弾性率が高いため、窒化処理をしない製
品より低い応力で、亀裂が成長進展し、破損に到る場合
があった。
As described above, conventionally, a titanium alloy connecting rod is subjected to a gas nitriding treatment to improve the wear resistance of the sliding portion. Since the TiN layer generated in 1 contains many fine cracks and has a high elastic modulus, the cracks may grow and develop with a lower stress than a product not subjected to the nitriding treatment, resulting in damage.

【0004】本発明は前記事情に鑑みてなされたもの
で、前記問題点を解消したチタン合金製コネクテングロ
ッドを提供することを目的とする。
The present invention has been made in view of the above circumstances, and an object of the present invention is to provide a titanium alloy connecting rod that solves the above problems.

【0005】[0005]

【課題を解決するための手段】前記目的に添い、本発明
は窒化処理を施したチタン合金製コネクテングロッド表
面のTiN層を、所定の厚さ除去することによって、前
記課題を解消した。
In order to solve the above problems, the present invention has solved the above problems by removing a predetermined thickness of the TiN layer on the surface of the connecting rod made of titanium alloy which has been subjected to the nitriding treatment.

【0006】以下、本発明の実施例について詳細に説明
する。コネクテングロッドの材料に、たとえばアルミチ
タン合金Ti−6Al−4Vを用いる。このコネクテン
グロッドを処理時間を変えて、次の処理条件でガス窒化
処理を施した。 処理温度 850℃ N2 圧 0.13MPa 処理時間 5,10,15,20hr
Hereinafter, embodiments of the present invention will be described in detail. Aluminum titanium alloy Ti-6Al-4V, for example, is used as the material of the connecting rod. This connecting rod was subjected to gas nitriding treatment under the following treatment conditions while changing the treatment time. Treatment temperature 850 ° C. N 2 pressure 0.13 MPa Treatment time 5, 10, 15, 20 hr

【0007】その結果、窒化層の深さと処理時間との関
係が図1に示すように得られた。図1から処理時間を1
5時間(hr)以上かけても窒化層の深さは殆ど増加し
ないことが判った。
As a result, the relationship between the depth of the nitrided layer and the processing time was obtained as shown in FIG. 1 processing time from Figure 1
It was found that the depth of the nitride layer hardly increased even after 5 hours (hr) or more.

【0008】次に前記条件で15時間処理したものの窒
化層において、その表面からの深さと、硬度との関係を
図2に示すように得た。なお硬度は、硬度比で示し、こ
の硬度比は、ガス窒化処理を施したものの硬度(Hv)
とガス窒化処理を施さない同じ材質のチタン合金の硬度
(Hvo)との比、即ちHv/Hvoで表わした。
Next, the relationship between the depth from the surface and the hardness of the nitride layer which had been treated under the above conditions for 15 hours was obtained as shown in FIG. The hardness is indicated by a hardness ratio, and the hardness ratio is the hardness (Hv) of the gas-nitrided product.
And the hardness (Hvo) of a titanium alloy of the same material not subjected to the gas nitriding treatment, that is, Hv / Hvo.

【0009】図2から、明らかなように表面からの距離
が大きく(深く)なるにしたがって次第に硬度が低下す
るが、表面より約60μmまでは硬度の上昇が認められ
る。
As is apparent from FIG. 2, the hardness gradually decreases as the distance from the surface becomes larger (deeper), but the hardness increases up to about 60 μm from the surface.

【0010】また、ガス窒化処理時間に対するコネクテ
ングロッド表面に生成するTiN(窒化チタン)層の厚
さの変化が次のように得られた。 処理時間(hr) 4 15 TiN層の厚さ(μm) 2 4 即ち、ガス窒化処理を15時間施したものは、前記のよ
うに窒化層の深さの限界がえられ、この場合のTiN層
の厚さは4μmであることが判る。
The change in the thickness of the TiN (titanium nitride) layer formed on the surface of the connecting rod with respect to the gas nitriding treatment time was obtained as follows. Treatment time (hr) 4 15 Thickness of TiN layer (μm) 2 4 That is, when the gas nitriding treatment was performed for 15 hours, the limit of the depth of the nitride layer was obtained as described above. It can be seen that the thickness is 4 μm.

【0011】次に処理温度850℃、処理時間15時間
で処理した前記チタン合金製コネクテングロッドと、本
発明に係る同様な条件で処理したチタン合金製コネクテ
ングロッドの表面を電解研磨により2,4,10μmの
厚さでそれぞ除去したものについて疲労試験を実施し
た。試験機はコネクテングロッドの大端部と小端部を固
定できるようにした引張圧縮試験機を用い、室温、大気
中で繰り返し速度約57Hz、R=0.5(即ち、負荷
1kg,500gの交互繰り返し)の条件で試験を実施
した。その結果、得られた疲労限度曲線を図3に示す。
図中●印は前記条件で窒化処理を施したコネクテングロ
ッドを、○印は表面を電解研磨したものを示す。
Next, the surface of the titanium alloy connecting rod treated at a treatment temperature of 850 ° C. for a treatment time of 15 hours and the surface of the titanium alloy connecting rod treated under the same conditions according to the present invention are electropolished to 2, Fatigue tests were carried out on the removed products having a thickness of 4, 10 μm. The tester is a tensile compression tester that can fix the big end and the small end of the connecting rod. At room temperature and atmospheric air, the repetition rate is about 57Hz, R = 0.5 (that is, load 1kg, 500g). The test was carried out under the condition of (alternate repetition). The fatigue limit curve obtained as a result is shown in FIG.
In the figure, ● indicates a connecting rod that has been subjected to the nitriding treatment under the above conditions, and ○ indicates that the surface is electrolytically polished.

【0012】図から明らかなように、ガス窒化処理を1
5時間施した場合、表面にはTiN層が形成されている
が、そのコネクテングロッドの表面を厚さ2μm除去し
ても殆ど変化がないが、厚さ4〜10μm除去した場合
に寿命が著しく向上することが判明した。そして図2か
らも、表面をその程度研磨して取り除いても硬度には殆
ど影響しないことが明らかである。
As is apparent from the figure, the gas nitriding treatment
When applied for 5 hours, a TiN layer is formed on the surface, but there is almost no change even if the surface of the connecting rod is removed by a thickness of 2 μm, but when the thickness of 4 to 10 μm is removed, the service life is significantly longer It turned out to improve. Also from FIG. 2, it is clear that even if the surface is polished and removed to that extent, the hardness is hardly affected.

【0013】[0013]

【発明の効果】本発明によれば、ガス窒化処理により耐
摩耗性を向上させたチタン合金製コネクテングロッドに
ついては、その硬度を低下させることなしに、疲労強度
を向上させ、その寿命を長くできる。すなわち、生成し
たTiN膜厚を測定し、そのTiN層の所定量を除去す
ることにより、ガス窒化処理条件に関係なく、疲労強度
を向上させることができる。
According to the present invention, the titanium alloy connecting rod whose wear resistance is improved by the gas nitriding treatment is improved in fatigue strength and extended in life without lowering its hardness. it can. That is, the fatigue strength can be improved regardless of the gas nitriding conditions by measuring the generated TiN film thickness and removing a predetermined amount of the TiN layer.

【図面の簡単な説明】[Brief description of drawings]

【図1】ガス窒化処理における処理時間と窒化層の深さ
との関係を示す図である。
FIG. 1 is a diagram showing a relationship between a processing time and a depth of a nitrided layer in a gas nitriding process.

【図2】ガス窒化処理された窒化材の断面上の硬度の分
布を示す図である。
FIG. 2 is a diagram showing a hardness distribution on a cross section of a gas nitrided nitride material.

【図3】ガス窒化処理されたチタン合金製コネクテング
ロッドに本発明に係る処理を施したものと施さないもの
疲労限度曲線を示す図である。
FIG. 3 is a diagram showing fatigue limit curves of gas-nitrided titanium alloy connecting rods with and without the treatment according to the present invention.

【図4】本発明に係る処理を施すコネクテングロッドの
説明図である。
FIG. 4 is an explanatory diagram of a connecting rod that is subjected to a treatment according to the present invention.

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 窒化処理を施したチタン合金製コネクテ
ングロッド表面のTiN層を、所定の厚さ除去してなる
チタン合金製コネクテングロッド。
1. A titanium alloy connecting rod obtained by removing a predetermined thickness of a TiN layer on the surface of a titanium alloy connecting rod that has been subjected to a nitriding treatment.
【請求項2】 窒化処理を施した前記チタン合金製コネ
クテングロッドの表面を4〜10μmの厚さで除去して
なる請求項1に記載のチタン合金製コネクテングロッ
ド。
2. The titanium alloy connecting rod according to claim 1, wherein the surface of the titanium alloy connecting rod subjected to the nitriding treatment is removed to a thickness of 4 to 10 μm.
JP9724992A 1992-03-24 1992-03-24 Connecting rod made of titanium alloy Pending JPH05272526A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP9724992A JPH05272526A (en) 1992-03-24 1992-03-24 Connecting rod made of titanium alloy

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP9724992A JPH05272526A (en) 1992-03-24 1992-03-24 Connecting rod made of titanium alloy

Publications (1)

Publication Number Publication Date
JPH05272526A true JPH05272526A (en) 1993-10-19

Family

ID=14187307

Family Applications (1)

Application Number Title Priority Date Filing Date
JP9724992A Pending JPH05272526A (en) 1992-03-24 1992-03-24 Connecting rod made of titanium alloy

Country Status (1)

Country Link
JP (1) JPH05272526A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012023620A1 (en) 2010-08-20 2012-02-23 日本発條株式会社 High-strength titanium alloy member and process for production thereof
WO2012169304A1 (en) 2011-06-09 2012-12-13 日本発條株式会社 Titanium alloy member and production method therefor
CN103602946A (en) * 2013-11-21 2014-02-26 沈阳黎明航空发动机(集团)有限责任公司 Method for improving abrasive resistance of surface of titanium alloy bearing pedestal
US10350681B2 (en) 2011-06-07 2019-07-16 Nhk Spring Co., Ltd. Titanium alloy member and production method therefor

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012023620A1 (en) 2010-08-20 2012-02-23 日本発條株式会社 High-strength titanium alloy member and process for production thereof
US10151019B2 (en) 2010-08-20 2018-12-11 Nhk Spring Co., Ltd. High-strength titanium alloy member and production method for same
US10350681B2 (en) 2011-06-07 2019-07-16 Nhk Spring Co., Ltd. Titanium alloy member and production method therefor
WO2012169304A1 (en) 2011-06-09 2012-12-13 日本発條株式会社 Titanium alloy member and production method therefor
US9920399B2 (en) 2011-06-09 2018-03-20 Nhk Spring Co., Ltd. Titanium alloy member and production method therefor
CN103602946A (en) * 2013-11-21 2014-02-26 沈阳黎明航空发动机(集团)有限责任公司 Method for improving abrasive resistance of surface of titanium alloy bearing pedestal

Similar Documents

Publication Publication Date Title
Farokhzadeh et al. Fatigue improvement in low temperature plasma nitrided Ti–6Al–4V alloy
JP2016083704A (en) Method of manufacturing stainless steel product
Jeong et al. Effects of TiN and WC coating on the fatigue characteristics of dental implant
Tokaji et al. The effects of gas nitriding on fatigue behavior in titanium and titanium alloys
CHIANG et al. Influence of a tangential force on the fracture of two contacting elastic bodies
JPH05272526A (en) Connecting rod made of titanium alloy
KR20010040948A (en) Sliding-contact bearings
KR101302051B1 (en) Dining and/or serving cutlery made of ferritic stainless steel with a martensitic boundary layer
Su et al. Influence of single-and multilayer TiN films on the axial tension and fatigue performance of AISI 1045 steel
JP3018804B2 (en) Surface treatment method for titanium alloy members
JP3998733B2 (en) High spring resistance and fatigue resistance coil spring
US5292596A (en) Force-transmitting surfaces of titanium protected from pretting fatigue by a coating of Co-Ni-Fe
Przybilla et al. Growth stresses in the oxide scales on TiAl alloys at 800 and 900 C
JP7448859B2 (en) titanium material
Roven et al. Effects of texture on delamination behavior of a 8090-type Al Li alloy at cryogenic and room temperature
JP3011490B2 (en) Methods for improving corrosion resistance of stainless steel
Jellison et al. Sliding friction of copper alloys in vacuum
JP2002371348A (en) Method for improving fatigue characteristics of titanium alloy component, and titanium alloy component therewith
RU2287146C1 (en) Method for determining type of part processing
JPS61170551A (en) Surface treatment of metallic material and titanium alloy or the like
Bhushan Surface pretreatment of thin Inconel X-750 foils for improved coating adherence
JPS6217168A (en) Sliding contact member having self-lubricity
FR2579997A1 (en) Process for treating the surface of an object and object obtained by this process
JPH0548296B2 (en)
Pape Fretting fatigue damage accumulation and crack nucleation in high-strength steels