JPH02128843A - Decorative material - Google Patents
Decorative materialInfo
- Publication number
- JPH02128843A JPH02128843A JP28439288A JP28439288A JPH02128843A JP H02128843 A JPH02128843 A JP H02128843A JP 28439288 A JP28439288 A JP 28439288A JP 28439288 A JP28439288 A JP 28439288A JP H02128843 A JPH02128843 A JP H02128843A
- Authority
- JP
- Japan
- Prior art keywords
- layer
- paper
- synthetic resin
- printing layer
- gloss
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000463 material Substances 0.000 title claims abstract description 48
- 238000007639 printing Methods 0.000 claims abstract description 50
- 229920003002 synthetic resin Polymers 0.000 claims abstract description 29
- 239000000057 synthetic resin Substances 0.000 claims abstract description 29
- 239000007787 solid Substances 0.000 claims abstract description 16
- 229920000178 Acrylic resin Polymers 0.000 claims description 4
- 239000004925 Acrylic resin Substances 0.000 claims description 4
- 239000000123 paper Substances 0.000 abstract description 20
- -1 for example Polymers 0.000 abstract description 14
- 239000004698 Polyethylene Substances 0.000 abstract description 7
- 229920000573 polyethylene Polymers 0.000 abstract description 7
- 239000004744 fabric Substances 0.000 abstract description 5
- 239000010440 gypsum Substances 0.000 abstract description 5
- 229910052602 gypsum Inorganic materials 0.000 abstract description 5
- 229920005672 polyolefin resin Polymers 0.000 abstract description 4
- 239000000835 fiber Substances 0.000 abstract description 3
- 239000004575 stone Substances 0.000 abstract description 3
- 239000004743 Polypropylene Substances 0.000 abstract description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract description 2
- 229920000554 ionomer Polymers 0.000 abstract description 2
- 238000010030 laminating Methods 0.000 abstract description 2
- 230000000704 physical effect Effects 0.000 abstract description 2
- 229920001155 polypropylene Polymers 0.000 abstract description 2
- 229920005992 thermoplastic resin Polymers 0.000 abstract description 2
- 239000010936 titanium Substances 0.000 abstract description 2
- 229910052719 titanium Inorganic materials 0.000 abstract description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- 239000011111 cardboard Substances 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 239000004816 latex Substances 0.000 abstract 1
- 229920000126 latex Polymers 0.000 abstract 1
- 238000010422 painting Methods 0.000 abstract 1
- 238000010186 staining Methods 0.000 abstract 1
- 238000004049 embossing Methods 0.000 description 18
- 239000002023 wood Substances 0.000 description 12
- 238000000034 method Methods 0.000 description 10
- 238000000576 coating method Methods 0.000 description 7
- 229920005989 resin Polymers 0.000 description 7
- 239000011347 resin Substances 0.000 description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 239000000049 pigment Substances 0.000 description 5
- 239000004800 polyvinyl chloride Substances 0.000 description 5
- 229920000915 polyvinyl chloride Polymers 0.000 description 5
- 241000218645 Cedrus Species 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 239000004568 cement Substances 0.000 description 4
- 239000003973 paint Substances 0.000 description 4
- 229920000728 polyester Polymers 0.000 description 4
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 3
- 239000004793 Polystyrene Substances 0.000 description 3
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- 229920001903 high density polyethylene Polymers 0.000 description 3
- 239000004700 high-density polyethylene Substances 0.000 description 3
- 239000002932 luster Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000002985 plastic film Substances 0.000 description 3
- 229920006255 plastic film Polymers 0.000 description 3
- 229920002223 polystyrene Polymers 0.000 description 3
- 229920002635 polyurethane Polymers 0.000 description 3
- 239000004814 polyurethane Substances 0.000 description 3
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 3
- 239000002966 varnish Substances 0.000 description 3
- 238000009736 wetting Methods 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- 229920002301 cellulose acetate Polymers 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 229920006026 co-polymeric resin Polymers 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 238000003851 corona treatment Methods 0.000 description 2
- 239000005038 ethylene vinyl acetate Substances 0.000 description 2
- 238000007756 gravure coating Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000010985 leather Substances 0.000 description 2
- 239000006224 matting agent Substances 0.000 description 2
- 239000010445 mica Substances 0.000 description 2
- 229910052618 mica group Inorganic materials 0.000 description 2
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 229920002689 polyvinyl acetate Polymers 0.000 description 2
- 239000011118 polyvinyl acetate Substances 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- IANQTJSKSUMEQM-UHFFFAOYSA-N 1-benzofuran Chemical compound C1=CC=C2OC=CC2=C1 IANQTJSKSUMEQM-UHFFFAOYSA-N 0.000 description 1
- 229910001369 Brass Inorganic materials 0.000 description 1
- 229910000906 Bronze Inorganic materials 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920008347 Cellulose acetate propionate Polymers 0.000 description 1
- 241000238366 Cephalopoda Species 0.000 description 1
- 229920000896 Ethulose Polymers 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical class CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- 239000001859 Ethyl hydroxyethyl cellulose Substances 0.000 description 1
- 229920012753 Ethylene Ionomers Polymers 0.000 description 1
- 229920000219 Ethylene vinyl alcohol Polymers 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 229920002873 Polyethylenimine Polymers 0.000 description 1
- 241000975357 Salangichthys microdon Species 0.000 description 1
- 229920002522 Wood fibre Polymers 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000007754 air knife coating Methods 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229920003180 amino resin Polymers 0.000 description 1
- 238000004873 anchoring Methods 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- 239000010974 bronze Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229920002678 cellulose Chemical class 0.000 description 1
- 239000001913 cellulose Chemical class 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 208000028659 discharge Diseases 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 235000019326 ethyl hydroxyethyl cellulose Nutrition 0.000 description 1
- 238000007765 extrusion coating Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 238000007646 gravure printing Methods 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 150000002688 maleic acid derivatives Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000011087 paperboard Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 239000011120 plywood Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920001483 poly(ethyl methacrylate) polymer Polymers 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920000120 polyethyl acrylate Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 229920002620 polyvinyl fluoride Polymers 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 235000015170 shellfish Nutrition 0.000 description 1
- 229910021487 silica fume Inorganic materials 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 229920006337 unsaturated polyester resin Polymers 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 239000002025 wood fiber Substances 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
Abstract
Description
[産業上の利用分野]
本発明は、立体感をもつ化粧材の改良に関する。
[従来の技術]
化粧材の製造において、ツヤ消しインキとツヤ出しイン
キとを併用して立体的な感じを出す手法があるが、その
製品は依然として立体的な深みが乏しい。 立体的な深
みを出すため、基材に絵柄を印刷した上に透明な合成樹
脂層を形成してエンボスを施す手法があり、これによっ
て一応の立体感は出せるが、エンボスによりツヤが決め
られてしまい、好みどおりの意匠感を得ることは難しい
。
出願人は、これらの課題を解決した化粧材として、基材
上に、合成樹脂層、隠蔽ベタ印刷層、絵柄印刷層および
ツヤ調整層を順に積層し、エンボスを施してなる化粧材
を提案した(特開昭61−293854号)。 この化
粧材は、天然物に近い感じをもった美麗なものである。
出願人はまた、上記の化粧材の表面のエンボス凹部へ着
色インキのワイピング加工を行なった化粧材も開示した
く特開昭63−147135号)。
しかしながら、これらの化粧材は、長期間にわたる使用
により絵柄が薄くなったり、スクラッチによりインキが
剥落してキズができることが経験された。[Industrial Field of Application] The present invention relates to the improvement of decorative materials with a three-dimensional effect. [Prior Art] In the production of decorative materials, there is a method of using a combination of matte ink and gloss ink to create a three-dimensional feel, but the product still lacks three-dimensional depth. In order to create three-dimensional depth, there is a method of printing a pattern on a base material and then forming a transparent synthetic resin layer and embossing it. Although this creates a certain three-dimensional effect, the embossing does not determine the gloss. Therefore, it is difficult to obtain the desired design feel. The applicant has proposed a decorative material that solves these problems by sequentially laminating a synthetic resin layer, a concealing solid printing layer, a pattern printing layer, and a gloss adjustment layer on a base material, and then applying embossing. (Unexamined Japanese Patent Publication No. 61-293854). This decorative material is beautiful and has a feel similar to natural products. The applicant also wishes to disclose a decorative material in which colored ink is wiped onto the embossed recesses on the surface of the decorative material (Japanese Patent Application Laid-Open No. 147135/1983). However, it has been experienced that when these decorative materials are used for a long period of time, the patterns become thinner and the ink peels off due to scratches, resulting in scratches.
本発明の目的は、上記したざきの発明による化粧材と同
様に美麗な外観をもち、耐スクラッチ性、耐候性および
耐汚染性などの表面物性を向上させた化粧材を提供する
ことにある。
(課題を解決するための手段]
本発明の化粧材は、基本的には第1図に示すように、基
材(1)上に、隠蔽ベタ印刷層(2)、絵柄印刷層(3
)、透明な合成樹脂層(4)およびツヤ調整層(5)を
順に積層し、エンボス(6)を施してなることを特徴と
する。
第2図に示すように、透明な合成樹脂層(4)とツヤ調
整層(5)との間に、第二の絵柄印刷層(3B>および
第二の透明な合成樹脂層(4B)を設けてもよい。 こ
うすると、絵柄印刷層(3)と第二の絵柄印刷層(3B
)との視差および隠蔽ベタ印刷層(2)に投影される第
二の絵柄印刷層(3B)の影により、立体感が増すから
、これは推奨できる態様である。
基材として代表的なものは各種の紙類であって、その例
は、薄葉紙、晒または未晒のクラフト紙、上質紙、紙間
強化紙(ラテックス含浸紙)、合成樹脂を混抄した混抄
紙、チタン紙、リンター紙、板紙、石こうボード紙など
である。 プラスチックのフィルムも使用できる。 た
とえば、ポリエチレン、ポリプロピレン、ポリ塩化ビニ
ル、ポリビニルアルコール、ポリエチレンテレフタレー
ト、ポリカーボネート、ナイロン、ポリスチレン、エチ
レン−酢酸ビニル共重合体、エチレン−ビニルアルコー
ル共重合体、アイオノマーなとのプラスチックのフィル
ムである。 そのほか、木、合板、パーチクルボードな
どの木質基材、石こうボード、石こうスラグボードなど
の石こう系基材、パルプセメント板、石綿セメント板、
木片セメント板などの繊維セメント板、GRCおよびコ
ンクリート、鉄、アルミニウム、銅などの金属箔または
シートも使用可能である。 上記の各種材料を複合した
基材も、もちろん使用できる。
絵柄印刷層、第二の絵柄印刷層および隠蔽ベタ印刷層を
設けるインキまたは塗料組成物としては、ベヒクルに顔
料または染料である着色剤、可塑剤、安定剤、その他の
添加剤、溶剤または希釈剤を混練してなるものを用いる
。 ベヒクルとして適当な材料は、エチルセルロース、
エチルヒドロキシエチルセルロース、セルロースアセテ
ートプロピオネート、酢酸セルロースなどのセルロース
誘導体、ポリスチレン、ポリ−α−メチルスチレンなど
のスチレン樹脂およびスチレン共重合体樹脂、ポリメタ
クリル酸エチル、ポリアクリル酸エチル、ポリアクリル
ブチルなどのアクリルまたはメタクリル酸エステルの単
独または共重合体樹脂、ロジン、ロジン変性マレイン酸
樹脂、ロジン変性フェノール樹脂、重合ロジンなどのロ
ジンエステル樹脂、ポリ酢酸ビニル、クマロン樹脂、ビ
ニルトルエン樹脂、ポリ塩化ビニル、ポリエステル、ポ
リウレタン、ブチラール樹脂などである。 これらの二
種以上を併用してもよい。 ベタ印刷には隠蔽性能に富
んだ二酸化チタンなどの無機顔料を主体としたものを用
い、絵柄印刷には適宜の着色剤を用いる。
絵柄印刷層および第二の絵柄印刷層の上に設ける透明な
合成樹脂層は、ポリエチレン、ポリプロピレン、エチレ
ン−酢酸ビニル共重合体、アイオノマーなとのポリオレ
フィン樹脂、飽和ポリエステルやポリ塩化ビニルのよう
なそれ以外の熱可塑性樹脂、不飽和ポリエステル樹脂や
ポリウレタン樹脂などの熱硬化性樹脂から選択したもの
を使用すればよい。 化粧材の表面物性を向上させると
いう観点からは、ポリフッ化ビニル、ポリフッ化ビニリ
レン、ポリフルオロオレフィンなどのフッ素樹脂のフィ
ルム、またはポリメタクリル酸メチルのようなアクリル
樹脂のフィルム、あるいはそれらの積層体を使用するこ
とが、とくに好ましい。
これらの合成樹脂は、透明であれば、無色のものでも着
色したものでも、任意にえらんで使用できる。
合成樹脂の層を形成するには、使用する合成樹脂の物性
に合わせてエクストルージョン、Tダイ、ロールコート
、グラビアコートなどの塗布手段を選択して塗布する。
合成樹脂層として接着性のよくないポリオレフィン樹脂
を使用する場合は、エクストルージョンコーティング法
の採用が好ましく、かつコーティングに先立って、アル
キルチタネートやポリエチレンイミンなどのアンカー剤
をコートqでおくとよい。 同様に、合成樹脂層の上に
も接着性向上のための処理を施こすとよい。 たとえば
ポリオレフィン樹脂で合成樹脂層を形成したときは、コ
ロナ放電処理して合成樹脂層の表面の「ぬれ指数」を3
8 dyne/ crit以上とすることが望ましく、
それにより印刷インキの接着性が向上する。
ツヤ調整層は、化粧材の表面に好ましいツヤを与えるも
のであって、適宜のベヒクルを用いた塗料を塗布するこ
とにより形成できる。 ベヒクルとしては、ポリウレタ
ン、アクリル樹脂、アミノ樹脂、ニトロセルロース、ア
ルキッド樹脂、ポリエステル、ポリビニルブチラール、
メラミン樹脂、酢酸セルロース、ポリ塩化ビニル、ポリ
酢酸ビニル、ポリスチレン、ポリビニルアルコールなど
の樹脂を単独または複合して使用することができる。
ツヤ調整層を形成する塗料には通常、適量のツヤ消し剤
を分散させて所望のツヤ消し度を与えるが、ツヤ消し剤
を全く含まないクロス(光沢)タイプの塗料を用いるこ
ともある。 使用できるツヤ)肖し剤は、マイカ、シリ
カ、アルミナ、炭酸カルシウム、ケイソウ土、ケイ砂、
シラスバルーンのような無機質中空体などである。
ツヤ調整層を絵柄印刷層上に一様に形成するときは、グ
ラビアコート、ロールコート、エアーナイフコート、ス
プレーコート、フローコートなどの方式によればよく、
パターン状に形成するときは、絵柄印刷層を形成すると
きと同様の印刷方式によればよい。 ツヤ調整層は、異
なるツヤ消し度の塗料を2種以上組み合わせて形成する
こともできる。 この場合、ツヤ消し層上にツヤ出し層
を設けるほか、ツヤ出し層を設けた上にツヤ消し層を設
けたり、ツヤ消し層とツヤ出し層とを同一面上に区分し
て設けたりすることもあるし、第2図に示すように、ツ
ヤ消し層またはツヤ出し層のいずれか一方(5)をベタ
で、他方(5A)をパターン状に設けてもよい。 ツヤ
調整層を下の絵柄模様と同調するパターンで設けると、
視覚的な立体感が増す。
所望により、隠蔽ベタ印刷層または絵柄印刷層上に、光
輝性着色層を設ける。 木の照り、皮の光沢、石の輝き
、おるいは布の光沢などが、それによってよく再現され
る。
光輝性着色層を形成する顔料の例をめげれば、次のとお
りである。 (イ)パール顔料と称するもの、具体的
には貝からの内側の部分や真球を砕粉したもの、マイカ
、マ、イカの微粒子にTiO2または酸化鉄を焼き付け
たもの、(ロ)金属粉、具体的には銅、アルミニウム、
真ちゅう、青銅、金、銀などの、好ましくは1〜120
μの微粒子、(ハ)蒸着されたプラスチックフィルムの
砕片、たとえばポリエチレンテレフタレートフィルムに
上記のような金属、通常はアルミニウムを蒸着し、粉砕
したもの(銀色粉)、蒸着ののち透明な黄色塗装を行な
って粉砕したちのく金色粉)。 これらの光輝性顔料は
、再現しようとするものの光沢、照り、輝きに応じて選
択し、必要に応じて2種以上併用することができる。
エンボスは、木目の導管溝を表現したもの、塗装版のツ
ヤ状態を再現したもの、およびそれらを組み合わせたも
のが多く使われている。 木の繊維感を表現したい場合
には、木目の方向に沿ったヘアーライン状のエンボスを
用いるとよい。 ヘアーライン状のエンボスで天然木の
繊維感を表現するためには、ヘアーラインのピッチを3
00μ以下にすることが好ましい。 ヘアーライン状の
エンボスと、導管溝なとのエンボスが共存してもよいこ
とはもちろんであって、たとえば「うづくり」の感じを
表現したもの、ツヤを出すための鏡面に近いもの、ツヤ
を消すための梨地のものなどが、木目模様を印刷したと
きに適合する。 皮の感じを表現したい場合には、皮の
表面の凹凸である皮紋を模したものや、梨地、ときによ
り鏡面に近いものが適合し、自然石の場合には、石の表
面の状態すなわち凹凸や割れ目を模したもの、磨いた石
を表現するときは鏡面のものがそれぞれ適合する。 布
の場合には、平織、斜文織もしくは朱子織、またはこれ
らの組合わせからなる布目の凹凸が適合する。
意匠効果をより高くするのに有効な手法として、エンボ
スの凹部に着色インキを充填することが行なわれる。
充填の方法としては、エンボス加工で設けた凹部を含む
全面に着色インキを塗り、凹部以外のインキをドクター
ブレード、ロール、布などでかき取る、いわゆるワイピ
ング法が望ましい。 この手法は、とくに木目導管エン
ボスの凹部を忠実に再現するのに有効であり、この場合
に使用するインキの色は、黒や茶系統が最適である。
充填するインキは、ポリウレタン、アクリル樹脂、ポリ
エステル、ポリ塩化ビニルなど常用のビヒクルに、カー
ボン、ベンガラ、シアンブル−のような既知の顔料を含
むものを用い、その中でも、密着性と耐摩耗性の高い点
で、イソシアネートやアミンで架橋する二液硬化型のも
のがとくに良好な結果を与える。
[作 用]
本発明の化粧材は、さきに提案した化粧材の構成に加え
て、絵柄印刷層の上でツヤ調整層の下に透明な合成樹脂
層を設けたものである。 透明な合成樹脂層が絵柄印刷
層を保護し、絵柄印刷層の汚染や摩耗、スクラッチによ
る剥離を防止し、全体として表面物性が向上する。
[実施例11
坪量40g/mの薄葉紙に高密度ポリエチレン「ミラソ
ン14」 (三井ポリケミカル)を、20μの厚さにコ
ートした。 ポリエチレン層の表面をコロナ放電処理し
、「ぬれ指数」を38 dyn[3/crA以上になる
ようにして基材を用意した。
この基材のコロナ放電処理面に隠蔽ベタ印刷用インキr
sP] (昭和インク工業製)でグラビアベタ印刷し
、その上に絵柄印刷用インキrsAM](同)で杉の板
目模様をグラビア印刷した。 絵柄印刷層の上に、高密
度ポリエチレン(同)を20μの厚さにエクストルージ
ョンコートし、その上に75°グロス値20の、マイク
ロシリカ3重量%を含有するイソシアネート硬化型ウレ
タン系ツヤ消し用ニス(昭和インク工業製)を、版深3
0μmのグラビア版を用いてグラビア印刷し、全面にツ
ヤ消し層を形成した。 次に、75°グロス値80のウ
レタン系ツヤ出し用ニス(同)を、杉の板目模様のうち
秋材部に相当する部分にグラビア印刷して、ツヤ出し層
を形成した。
このようにして得られた印刷紙を120’Cに加熱して
ポリエチレン層を軟化させ、表面温度20℃のへアーラ
イン状エンボスロール(幅方向ピッチ100〜200μ
)を設置したエンボス機にかけ、杉の板目模様の繊維方
向(木の成長方向)にヘアーラインの方向を一致させて
エンボスを行ない、本発明の化粧材を得た。An object of the present invention is to provide a decorative material that has a beautiful appearance similar to the decorative material according to Zaki's invention described above and has improved surface properties such as scratch resistance, weather resistance, and stain resistance. (Means for Solving the Problems) The decorative material of the present invention basically consists of a base material (1), a concealing solid printing layer (2), a pattern printing layer (3), as shown in FIG.
), a transparent synthetic resin layer (4) and a gloss adjustment layer (5) are laminated in this order, and embossing (6) is applied. As shown in Figure 2, a second pattern printing layer (3B> and a second transparent synthetic resin layer (4B) are provided between the transparent synthetic resin layer (4) and the gloss adjustment layer (5). In this way, the pattern printing layer (3) and the second pattern printing layer (3B
) and the shadow of the second pattern printing layer (3B) projected onto the concealment solid printing layer (2) increases the three-dimensional effect, so this is a recommended mode. Typical base materials are various types of paper, such as tissue paper, bleached or unbleached kraft paper, high-quality paper, reinforced paper (latex-impregnated paper), and mixed paper mixed with synthetic resin. , titanium paper, linter paper, paperboard, gypsum board paper, etc. Plastic film can also be used. Examples include plastic films such as polyethylene, polypropylene, polyvinyl chloride, polyvinyl alcohol, polyethylene terephthalate, polycarbonate, nylon, polystyrene, ethylene-vinyl acetate copolymer, ethylene-vinyl alcohol copolymer, and ionomer. In addition, wood base materials such as wood, plywood, and particle board, gypsum base materials such as gypsum board and gypsum slag board, pulp cement board, asbestos cement board,
Fiber cement boards such as wood chip cement boards, GRC and concrete, metal foils or sheets such as iron, aluminum, copper etc. can also be used. Of course, base materials made of composites of the various materials listed above can also be used. The ink or coating composition for providing the pattern printing layer, the second pattern printing layer and the concealing solid printing layer includes a vehicle containing a colorant such as a pigment or dye, a plasticizer, a stabilizer, other additives, a solvent or a diluent. Use a product made by kneading. Suitable materials for the vehicle include ethyl cellulose,
Cellulose derivatives such as ethyl hydroxyethyl cellulose, cellulose acetate propionate, cellulose acetate, styrene resins and styrene copolymer resins such as polystyrene, poly-α-methylstyrene, polyethyl methacrylate, polyethyl acrylate, polyacrylbutyl, etc. Single or copolymer resins of acrylic or methacrylic acid esters, rosin, rosin-modified maleic acid resins, rosin-modified phenolic resins, rosin ester resins such as polymerized rosin, polyvinyl acetate, coumaron resins, vinyl toluene resins, polyvinyl chloride, These include polyester, polyurethane, butyral resin, etc. Two or more of these may be used in combination. For solid printing, an inorganic pigment such as titanium dioxide with excellent hiding performance is used as the main ingredient, and for pattern printing, an appropriate coloring agent is used. The transparent synthetic resin layer provided on the pattern printing layer and the second pattern printing layer is made of polyolefin resin such as polyethylene, polypropylene, ethylene-vinyl acetate copolymer, ionomer, saturated polyester or polyvinyl chloride. Thermoplastic resins other than those listed above, thermosetting resins such as unsaturated polyester resins and polyurethane resins may be used. From the perspective of improving the surface properties of decorative materials, films of fluororesins such as polyvinyl fluoride, polyvinylylene fluoride, and polyfluoroolefins, films of acrylic resins such as polymethyl methacrylate, or laminates thereof are recommended. It is particularly preferred to use These synthetic resins may be colorless or colored, as long as they are transparent, and can be used as desired. To form a synthetic resin layer, a coating method such as extrusion, T-die, roll coating, or gravure coating is selected depending on the physical properties of the synthetic resin used. When a polyolefin resin with poor adhesion is used as the synthetic resin layer, it is preferable to employ an extrusion coating method, and it is preferable to apply an anchoring agent such as alkyl titanate or polyethyleneimine as a coat q prior to coating. Similarly, the synthetic resin layer may also be treated to improve adhesion. For example, when a synthetic resin layer is formed using polyolefin resin, corona discharge treatment is performed to reduce the "wetting index" of the surface of the synthetic resin layer to 3.
It is desirable to set it to 8 dyne/crit or more,
This improves the adhesion of the printing ink. The gloss adjustment layer imparts a desirable gloss to the surface of the decorative material, and can be formed by applying a paint using an appropriate vehicle. Vehicles include polyurethane, acrylic resin, amino resin, nitrocellulose, alkyd resin, polyester, polyvinyl butyral,
Resins such as melamine resin, cellulose acetate, polyvinyl chloride, polyvinyl acetate, polystyrene, and polyvinyl alcohol can be used alone or in combination. Usually, a suitable amount of a matting agent is dispersed in the paint forming the gloss adjustment layer to give the desired degree of matting, but a cloth (glossy) type paint that does not contain any matting agent is sometimes used. The polishing agents that can be used are mica, silica, alumina, calcium carbonate, diatomaceous earth, silica sand,
These include inorganic hollow bodies such as whitebait balloons. When uniformly forming the gloss adjustment layer on the pattern printing layer, methods such as gravure coating, roll coating, air knife coating, spray coating, flow coating, etc. may be used.
When forming a pattern, the same printing method as when forming a pattern printing layer may be used. The gloss adjustment layer can also be formed by combining two or more types of paints with different matte degrees. In this case, in addition to providing a gloss layer on a matte layer, a matte layer may be provided on top of a gloss layer, or a matte layer and a gloss layer may be separately provided on the same surface. Alternatively, as shown in FIG. 2, either the matte layer or the gloss layer (5) may be provided solidly, and the other layer (5A) may be provided in a pattern. When the gloss adjustment layer is provided in a pattern that matches the pattern below,
Increases visual three-dimensionality. If desired, a glittering colored layer is provided on the concealing solid printing layer or the pattern printing layer. The shine of wood, the luster of leather, the brilliance of stones, and the luster of cloth are well reproduced by this technique. Examples of pigments that form the glitter colored layer are as follows. (a) Pearl pigments, specifically those made by crushing the inner parts of shellfish or true spheres, fine particles of mica, ma, and squid baked with TiO2 or iron oxide, and (b) metal powders. , specifically copper, aluminum,
Brass, bronze, gold, silver, etc., preferably 1 to 120
(c) Fragments of vapor-deposited plastic film, such as polyethylene terephthalate film on which the above-mentioned metal, usually aluminum, is vapor-deposited and crushed (silver powder), which is coated with a transparent yellow coating after vapor deposition. (Crushed into powder). These glitter pigments are selected depending on the gloss, luster, and brilliance of the object to be reproduced, and two or more kinds can be used in combination as necessary. Embossing is often used to express the conduit grooves in the wood grain, to reproduce the glossy state of the painted version, or to combine these. If you want to express the feel of wood fibers, it is best to use hairline embossing along the direction of the wood grain. In order to express the texture of natural wood with hairline embossing, the pitch of the hairline should be set to 3.
It is preferable to make it 00μ or less. It goes without saying that hairline-like embossing and conduit groove-like embossing can coexist; for example, embossing that expresses the feeling of ``Uzukuri'', mirror-like embossing to create a shine, and embossing that eliminates gloss. Materials such as those made of satin material are suitable when printed with wood grain patterns. If you want to express the feel of leather, a material that imitates the roughness of the surface of the skin, a satin finish, or a surface that is almost mirror-like is suitable. Items that imitate unevenness and cracks, and mirror surfaces are suitable for expressing polished stones. In the case of cloth, plain weave, diagonal weave, satin weave, or a combination of these, with uneven texture, is suitable. An effective method for increasing the design effect is to fill the recesses of the embossing with colored ink.
As a filling method, a so-called wiping method is preferable, in which colored ink is applied to the entire surface including the recesses provided by embossing, and ink other than the recesses is scraped off with a doctor blade, roll, cloth, or the like. This method is particularly effective in faithfully reproducing the concave portion of the wood grain conduit embossing, and the optimal ink color used in this case is black or brown. The ink to be filled is a commonly used vehicle such as polyurethane, acrylic resin, polyester, or polyvinyl chloride, containing known pigments such as carbon, red iron, or cyan blue. In this respect, a two-component curing type that is crosslinked with isocyanate or amine gives particularly good results. [Function] In addition to the structure of the decorative material proposed above, the decorative material of the present invention has a transparent synthetic resin layer provided above the pattern printing layer and below the gloss adjustment layer. The transparent synthetic resin layer protects the pattern printing layer, prevents the pattern printing layer from being contaminated, abraded, and peeled off by scratches, and improves the surface properties as a whole. [Example 11 A thin paper with a basis weight of 40 g/m was coated with high-density polyethylene "Mirason 14" (Mitsui Polychemicals) to a thickness of 20 μm. A base material was prepared by subjecting the surface of the polyethylene layer to corona discharge treatment so that the "wetting index" was 38 dyn[3/crA or more. Ink for concealed solid printing is applied to the corona discharge treated surface of this base material.
sP] (manufactured by Showa Ink Kogyo), and a cedar grain pattern was gravure printed thereon using pattern printing ink rsAM] (manufactured by Showa Ink Industries). On the pattern printing layer, extrusion coat high-density polyethylene (same) to a thickness of 20μ, and then apply an isocyanate-curing urethane matte coating containing 3% by weight of microsilica and having a 75° gloss value of 20. Apply varnish (manufactured by Showa Ink Industries) to a plate depth of 3.
Gravure printing was performed using a 0 μm gravure plate to form a matte layer over the entire surface. Next, a urethane-based gloss varnish (same as the same) with a 75° gloss value of 80 was gravure printed on a portion of the cedar grain pattern corresponding to the autumn wood portion to form a gloss layer. The thus obtained printing paper was heated to 120'C to soften the polyethylene layer, and a hairline embossing roll (widthwise pitch 100-200μ) with a surface temperature of 20°C was used.
) and embossing was performed by matching the hairline direction to the fiber direction of the cedar grain pattern (tree growth direction) to obtain the decorative material of the present invention.
【実施例2】
実施例1と同じ基材を用意し、それにやはり実施例1と
同じ隠蔽ベタ印刷用インキでグラビアベタ印刷した。
その上に絵柄印1り用インキrsAMJ (前記)で
杉の板目模様の一部をグラビア印刷し、高密度ポリエチ
レンを20μの厚さにエクストルージョンコートした。
ポリエチレン層の表面をコロナ敢電処理して「ぬれ指
数」を38 dyne/ crd以上にし、そこに別の
絵柄印刷用インキrG&MJ (昭和インキ工業製)
で模様の残りをグラビア印刷し、上記と同じポリエチレ
ン層を形成した。
実施例1と同様の操作で木目導管エンボスを設け、エン
ボス凹凸面上に着色インキrW−141J(昭和インク
工業製)を全面に塗ってから、ドクターブレードで凹部
以外の着色インキをかき取ってワイピング加工した。
インキを乾燥硬化させた債、実施例1と同じニスでツヤ
消し層を形成し、天然木の導管模様を忠実に再現するこ
とによって、本発明の化粧材を得た。
【発明の効果1
本発明の化粧材は、さきに開示した化粧材と同様に奥行
き感があり、あるいはワイビングカロエしたものに固有
の意匠感がおって美麗な外観をもち、そのうえ、耐スク
ラッチ性、耐候性および耐汚染性などの表面物性が向上
したものである。 従って、長期間使用しても、またあ
る程度乱暴な使い方をしても、絵柄が薄くなったり、剥
れてキズが見えるようなことはない。[Example 2] The same base material as in Example 1 was prepared, and gravure solid printing was performed on it using the same concealing solid printing ink as in Example 1. A part of the cedar grain pattern was gravure printed on it using the ink rsAMJ (described above) for pattern stamps, and extrusion coated with high-density polyethylene to a thickness of 20 μm. The surface of the polyethylene layer is treated with corona electrolysis to make the "wetting index" 38 dyne/crd or higher, and then another pattern printing ink rG&MJ (manufactured by Showa Ink Industries) is added thereto.
The remainder of the pattern was gravure printed to form the same polyethylene layer as above. A wood grain conduit embossing was created in the same manner as in Example 1, and the colored ink rW-141J (manufactured by Showa Ink Industries) was applied to the entire surface of the embossed uneven surface, and then the colored ink was scraped off except for the concave areas with a doctor blade and wiped. processed.
The decorative material of the present invention was obtained by forming a matte layer with the same varnish as in Example 1 and faithfully reproducing the conduit pattern of natural wood. Effects of the Invention 1 The decorative material of the present invention has a sense of depth similar to the previously disclosed decorative material, or has a beautiful appearance with a design unique to the weaving color, and has scratch resistance and It has improved surface properties such as weather resistance and stain resistance. Therefore, even if it is used for a long period of time or even if it is used roughly to a certain extent, the pattern will not fade or peel off to show any scratches.
第1図は、本発明の化粧材の基本的な態様を示す模式的
な断面図でおる。
第2図は、本発明の化粧材の好ましい態様を示す第1図
と同様な図である。
1・・・基 材
2・・・ベタ印刷層
3・・・絵柄印刷層
3B・・・第二の絵柄印刷層
4・・・透明合成樹脂層
4B・・・第二の透明合成樹脂層
5.5A・・・ツヤ調整層
6・・・エンボス
f!IIJ1図
第2wAFIG. 1 is a schematic sectional view showing a basic aspect of the decorative material of the present invention. FIG. 2 is a diagram similar to FIG. 1 showing a preferred embodiment of the decorative material of the present invention. 1... Base material 2... Solid printing layer 3... Pattern printing layer 3B... Second pattern printing layer 4... Transparent synthetic resin layer 4B... Second transparent synthetic resin layer 5 .5A...Gloss adjustment layer 6...Emboss f! IIJ1 Figure 2wA
Claims (7)
合成樹脂層およびツヤ調整層を順に積層し、エンボスを
施してなることを特徴とする化粧材。(1) A decorative material characterized in that a concealing solid printing layer, a pattern printing layer, a transparent synthetic resin layer and a gloss adjustment layer are laminated in this order on a base material and embossed.
絵柄印刷層および第二の透明な合成樹脂層を設けた請求
項1の化粧材。(2) The decorative material according to claim 1, wherein a second pattern printing layer and a second transparent synthetic resin layer are provided between the transparent synthetic resin layer and the gloss adjustment layer.
の材料として、フッ素樹脂またはアクリル樹脂を用いた
請求項1または2の化粧材。(3) The decorative material according to claim 1 or 2, wherein a fluororesin or an acrylic resin is used as the material for the transparent synthetic resin layer or the second transparent synthetic resin layer.
他方がツヤ出し層である請求項1または2の化粧材。(4) The gloss adjustment layer consists of two layers, one of which is a matte layer,
The decorative material according to claim 1 or 2, wherein the other layer is a glossy layer.
ベタ印刷層の上に、光輝性着色層を設けた請求項1また
は2の化粧材。(5) The decorative material according to claim 1 or 2, wherein a glitter colored layer is provided on the pattern printing layer, the second pattern printing layer, or the concealing solid printing layer.
を設けた請求項1または2の化粧材。(6) The decorative material according to claim 1 or 2, wherein another synthetic resin layer is provided between the base material and the concealing solid printing layer.
とツヤ調整層との間のエンボスの凹部に着色インキを充
填した請求項1ないし6のいずれかの化粧板。(7) The decorative board according to any one of claims 1 to 6, wherein the embossed recesses between the transparent synthetic resin layer or the second transparent synthetic resin layer and the gloss adjustment layer are filled with colored ink.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP63284392A JP2707651B2 (en) | 1988-11-10 | 1988-11-10 | Cosmetic material |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP63284392A JP2707651B2 (en) | 1988-11-10 | 1988-11-10 | Cosmetic material |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH02128843A true JPH02128843A (en) | 1990-05-17 |
JP2707651B2 JP2707651B2 (en) | 1998-02-04 |
Family
ID=17677982
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP63284392A Expired - Fee Related JP2707651B2 (en) | 1988-11-10 | 1988-11-10 | Cosmetic material |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP2707651B2 (en) |
Cited By (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0494440U (en) * | 1990-12-28 | 1992-08-17 | ||
JPH04337345A (en) * | 1991-05-13 | 1992-11-25 | Achilles Corp | Gloss-controlling resin composition |
JPH05154977A (en) * | 1991-12-10 | 1993-06-22 | Dainichiseika Color & Chem Mfg Co Ltd | Method for forming pattern of sheet and pattern formed sheet |
JPH0671814A (en) * | 1992-08-27 | 1994-03-15 | Riken Viny Kogyo Kk | Decorative sheet with feeling of paint even though unpainted and manufacture thereof |
JPH07137221A (en) * | 1993-06-29 | 1995-05-30 | Dainippon Printing Co Ltd | Decorative sheet |
JPH09174794A (en) * | 1995-12-22 | 1997-07-08 | Nippon Dekoole Kk | Synthetic resin decorative material and manufacture thereof |
JPH09216327A (en) * | 1996-02-08 | 1997-08-19 | Nippon Dekoole Kk | Laminated synthetic resin decorative material and its manufacture |
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Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
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JPS6391243A (en) * | 1986-10-03 | 1988-04-21 | 大日本印刷株式会社 | Decorative material |
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- 1988-11-10 JP JP63284392A patent/JP2707651B2/en not_active Expired - Fee Related
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
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JPS6391243A (en) * | 1986-10-03 | 1988-04-21 | 大日本印刷株式会社 | Decorative material |
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