JP6794311B2 - 超電導コイル装置及びその製造方法 - Google Patents
超電導コイル装置及びその製造方法 Download PDFInfo
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- JP6794311B2 JP6794311B2 JP2017094442A JP2017094442A JP6794311B2 JP 6794311 B2 JP6794311 B2 JP 6794311B2 JP 2017094442 A JP2017094442 A JP 2017094442A JP 2017094442 A JP2017094442 A JP 2017094442A JP 6794311 B2 JP6794311 B2 JP 6794311B2
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- superconducting coil
- polymerizable composition
- coil device
- monomer
- superconducting
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- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
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- 229910000859 α-Fe Inorganic materials 0.000 description 1
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Description
で示される化合物の1種以上よりなるものであってもよく、ノルボルネン、テトラシクロドデセン、5−エチリデンノルボルネン及び8−エチリデンテトラシクロドデセンからなる群から選択された1種以上よりなるものであってもよい。
<超電導コイル装置>
初めに、本発明の一実施形態である実施の形態の超電導コイル装置について説明する。図1は、実施の形態の超電導コイル装置の斜視図である。図2は、実施の形態の超電導コイル装置の分解斜視図である。図3は、実施の形態の超電導コイル装置の正面図である。図4は、実施の形態の超電導コイル装置の要部断面図である。図5は、実施の形態の超電導コイル装置の他の例の正面図である。図6は、実施の形態の超電導コイル装置の他の例の要部断面図である。なお、図3乃至図6は、コイルケースの蓋部を外した状態を示し、図4は、図3のA−A線に沿った断面図であり、図6は、図5のA−A線に沿った断面図である。さらに、図2では、理解を簡単にするために、樹脂部を形成する前の状態を示している。
次に、本実施の形態の超電導コイル装置において、コイルケースの内壁と超電導コイルとの間に充填されている重合体、及び、その重合体を形成するための原料としての重合性組成物、の好適な組成について説明する。
次に、本実施の形態の超電導コイル装置の製造方法について説明する。図7は、実施の形態の超電導コイル装置の製造工程の一部を示すプロセスフロー図である。図8乃至図10は、実施の形態の超電導コイル装置の製造工程中の要部断面図である。なお、図8乃至図10に示す要部断面は、図4に示す要部断面に対応している。
(製造例1)
製造例1では、ジシクロペンタジエンよりなる第1モノマーと、前記化合物(8)よりなるメタセシス重合触媒と、を含有する重合性組成物を準備した。得られた重合性組成物は20℃に維持した。メタセシス重合触媒の使用量は、使用した全モノマー1モルに対して0.055ミリモルであった。また、重合性組成物の25℃での粘度は、B型粘度計による測定で10mPa・s以下であった。
製造例2では、ジシクロペンタジエンよりなる第1モノマーと、5−エチリデンノルボルネンよりなる第2モノマーと、前記化合物(8)よりなるメタセシス重合触媒と、を含有する重合性組成物を準備した。得られた重合性組成物は20℃に維持した。ここで、重合性組成物における第1モノマーの含有量と重合性組成物における第2モノマーの含有量との合計を100質量部としたとき、重合性組成物における第2モノマーの含有量は6.4質量部であった。また、重合性組成物の25℃での粘度は、B型粘度計による測定で10mPa・s以下であった。メタセシス重合触媒の使用量は、使用した全モノマー1モルに対して0.055ミリモルであった。
次に、製造例1及び製造例2の重合性組成物を、20℃の環境下、コイルケースを模擬した模擬ケース内に注入、樹脂流動がなくなるまで放置(予備硬化)した後、80℃の加熱温度及び1時間の加熱時間の条件で熱処理して重合硬化させることにより、製造例1及び製造例2の重合性組成物の重合硬化の評価を視認により行った。この製造例1及び製造例2のうち、製造例2の重合性組成物を重合した重合体の写真を、図14に示す。
(実施例1)
コイルケース20内に超電導コイル30を収容し、製造例2の重合性組成物52を注入した後、重合性組成物52の重合硬化の評価の際の条件と同一の条件で熱処理して重合硬化させることにより樹脂部50を形成し、形成された樹脂部50によりコイルケース20の内壁と超電導コイル30との間を充填した。これにより、図1に示したように、実施例1の超電導コイル装置10を作製した。
次に、実施例1の超電導コイル装置について、加振試験装置を用いた加振試験を行い、超電導コイル装置10における振動による発熱の有無の評価を行った。
20 コイルケース
21 容器本体部
22 蓋部
23 凹部
24 主面
25、26 開口部
30 超電導コイル
31 パンケーキコイル
32 内側電極
33〜35 外側電極
40 電流リード
41〜43 接続部材
50 樹脂部
51 重合体
52 重合性組成物
60 加振試験装置
61 真空容器
62 冷凍機
63 伝熱板
64 支持部材
65 加振機
66 加振ロッド
67 天板
AX1 軸
CP1〜CP4 曲線部
EP11、EP12、EP21、EP22 端部
EP31、EP32、EP41、EP42 端部
LP1〜LP4 直線部
Claims (16)
- 超電導コイルを収容する収容部と、
前記収容部内に収容された前記超電導コイルと、
前記収容部の内壁と前記超電導コイルとの間に充填された樹脂部と、
を有し、
前記樹脂部は、ノルボルネン環構造を有する第1モノマーを含む重合性組成物を重合した重合体からなる、超電導コイル装置。 - 請求項2に記載の超電導コイル装置において、
前記第2モノマーが、ノルボルネン、テトラシクロドデセン、5−エチリデンノルボルネン及び8−エチリデンテトラシクロドデセンからなる群から選択された1種以上よりなる、超電導コイル装置。 - 請求項2又は3に記載の超電導コイル装置において、
前記重合性組成物における前記第1モノマーの含有量と前記重合性組成物における前記第2モノマーの含有量との合計を100質量部としたとき、前記重合性組成物における前記第2モノマーの含有量が4質量部以上である、超電導コイル装置。 - 請求項1乃至4のいずれか一項に記載の超電導コイル装置において、
前記超電導コイルは、第1方向に沿った巻回軸の周りに超電導線材がそれぞれ渦巻き状に巻回され、前記収容部内で前記第1方向に積層され、且つ、直列に接続された複数のパンケーキコイルを含む、超電導コイル装置。 - 請求項5に記載の超電導コイル装置において、
前記収容部は、
凹部を有する容器本体部と、
前記凹部を塞ぐ蓋部と、
を含み、
前記容器本体部は、前記第1方向と交差する主面を有し、
前記凹部は、前記主面に形成され、
前記複数のパンケーキコイルは、前記凹部内で積層されている、超電導コイル装置。 - 請求項1乃至6のいずれか一項に記載の超電導コイル装置において、
前記収容部は、アルミニウム合金、ステンレス鋼又はGFRPよりなる、超電導コイル装置。 - (a)超電導コイルを収容する収容部内に前記超電導コイルを収容する工程、
(b)前記(a)工程の後、前記収容部内に重合性組成物を注入する工程、
(c)前記(b)工程の後、前記重合性組成物を重合し、前記収容部の内壁と前記超電導コイルとの間を、前記重合性組成物の重合体からなる樹脂部により充填する工程、
を有し、
前記重合性組成物は、ノルボルネン環構造を有する第1モノマーを含む、超電導コイル装置の製造方法。 - 請求項9に記載の超電導コイル装置の製造方法において、
前記第2モノマーが、ノルボルネン、テトラシクロドデセン、5−エチリデンノルボルネン及び8−エチリデンテトラシクロドデセンからなる群から選択された1種以上よりなる、超電導コイル装置の製造方法。 - 請求項9又は10に記載の超電導コイル装置の製造方法において、
前記重合性組成物における前記第1モノマーの含有量と前記重合性組成物における前記第2モノマーの含有量との合計を100質量部としたとき、前記重合性組成物における前記第2モノマーの含有量が4質量部以上である、超電導コイル装置の製造方法。 - 請求項8乃至11のいずれか一項に記載の超電導コイル装置の製造方法において、
前記(b)工程では、25℃で100mPa・s以下の粘度を有する前記重合性組成物を注入し、
前記(c)工程では、前記重合性組成物を、250℃以下の温度で重合させる、超電導コイル装置の製造方法。 - 請求項8乃至12のいずれか一項に記載の超電導コイル装置の製造方法において、
前記(a)工程は、
(a1)超電導線材がそれぞれ渦巻き状に巻回されてなる複数のパンケーキコイルを前記収容部内に収容する工程、
を含み、
前記(a1)工程では、直前に収容されたパンケーキコイルを、前記直前に収容されたパンケーキコイルよりも1つ前に収容されたパンケーキコイルと電気的に接続した後、次のパンケーキコイルを収容し、
前記(a)工程では、前記複数のパンケーキコイルの各々の巻回軸が第1方向に沿った状態で、前記(a1)工程を行うことにより、前記第1方向に沿った前記巻回軸の周りに前記超電導線材がそれぞれ渦巻き状に巻回され、前記第1方向に積層され、且つ、直列に接続された前記複数のパンケーキコイルを含む前記超電導コイルを収容する、超電導コイル装置の製造方法。 - 請求項13に記載の超電導コイル装置の製造方法において、
前記収容部は、
凹部を有する容器本体部と、
前記凹部を塞ぐ蓋部と、
を含み、
前記容器本体部は、前記第1方向と交差する主面を有し、
前記凹部は、前記主面に形成され、
前記(a1)工程では、前記複数のパンケーキコイルを前記凹部内に収容する、超電導コイル装置の製造方法。 - 請求項14に記載の超電導コイル装置の製造方法において、
前記容器本体部は、
前記主面に形成され、前記凹部よりも前記第1方向と交差する第2方向における第1の側に配置され、且つ、前記凹部と連通する第1開口部と、
前記主面に形成され、前記凹部よりも前記第2方向における前記第1の側と反対側に配置され、且つ、前記凹部と連通する第2開口部と、
を有し、
前記(b)工程は、
(b1)前記凹部を前記蓋部により塞ぐ工程、
(b2)前記(b1)工程の後、前記第1開口部が前記第2開口部よりも高くなるように前記主面を水平面に対して傾斜させた状態で、前記第1開口部から前記凹部内への前記重合性組成物の注入を開始する工程、
(b3)前記(b2)工程の後、前記主面の水平面に対する傾斜角度を減少させながら、前記第1開口部から前記凹部内に前記重合性組成物を注入する工程、
を含む、超電導コイル装置の製造方法。 - 請求項8乃至15のいずれか一項に記載の超電導コイル装置の製造方法において、
前記収容部は、アルミニウム合金、ステンレス鋼又はGFRPよりなる、超電導コイル装置の製造方法。
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
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JP2017094442A JP6794311B2 (ja) | 2017-05-11 | 2017-05-11 | 超電導コイル装置及びその製造方法 |
CN201880028861.7A CN110574130B (zh) | 2017-05-11 | 2018-05-10 | 聚合性组合物的用途 |
US16/609,375 US11710590B2 (en) | 2017-05-11 | 2018-05-10 | Superconducting coil device and method for producing same |
PCT/JP2018/018067 WO2018207861A1 (ja) | 2017-05-11 | 2018-05-10 | 超電導コイル装置及びその製造方法 |
EP18797850.7A EP3624146B1 (en) | 2017-05-11 | 2018-05-10 | Superconducting coil device and method for producing same |
CN202210161289.XA CN114512296A (zh) | 2017-05-11 | 2018-05-10 | 超导线圈装置及其制造方法 |
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JP2982346B2 (ja) | 1991-04-02 | 1999-11-22 | 住友電気工業株式会社 | 高温超電導コイル |
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