JP6463757B2 - ガラスおよびガラスセラミック - Google Patents
ガラスおよびガラスセラミック Download PDFInfo
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- JP6463757B2 JP6463757B2 JP2016535425A JP2016535425A JP6463757B2 JP 6463757 B2 JP6463757 B2 JP 6463757B2 JP 2016535425 A JP2016535425 A JP 2016535425A JP 2016535425 A JP2016535425 A JP 2016535425A JP 6463757 B2 JP6463757 B2 JP 6463757B2
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- 239000002241 glass-ceramic Substances 0.000 title claims description 72
- 239000011521 glass Substances 0.000 claims description 71
- 239000013078 crystal Substances 0.000 claims description 29
- 229910006404 SnO 2 Inorganic materials 0.000 claims description 26
- 238000004519 manufacturing process Methods 0.000 claims description 17
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 14
- 239000010453 quartz Substances 0.000 claims description 13
- 229910008556 Li2O—Al2O3—SiO2 Inorganic materials 0.000 claims description 9
- 229910017493 Nd 2 O 3 Inorganic materials 0.000 claims description 5
- 238000000034 method Methods 0.000 description 75
- 230000008569 process Effects 0.000 description 64
- 239000000203 mixture Substances 0.000 description 28
- 238000002468 ceramisation Methods 0.000 description 27
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 22
- 230000006911 nucleation Effects 0.000 description 21
- 238000010899 nucleation Methods 0.000 description 21
- 230000000052 comparative effect Effects 0.000 description 16
- 239000002667 nucleating agent Substances 0.000 description 14
- 230000008018 melting Effects 0.000 description 13
- 238000002844 melting Methods 0.000 description 13
- 229910010413 TiO 2 Inorganic materials 0.000 description 12
- 238000010438 heat treatment Methods 0.000 description 10
- 229910000413 arsenic oxide Inorganic materials 0.000 description 9
- 229960002594 arsenic trioxide Drugs 0.000 description 9
- 238000004031 devitrification Methods 0.000 description 9
- KTTMEOWBIWLMSE-UHFFFAOYSA-N diarsenic trioxide Chemical compound O1[As](O2)O[As]3O[As]1O[As]2O3 KTTMEOWBIWLMSE-UHFFFAOYSA-N 0.000 description 9
- 239000006025 fining agent Substances 0.000 description 9
- 238000005259 measurement Methods 0.000 description 9
- 238000000465 moulding Methods 0.000 description 9
- 239000012535 impurity Substances 0.000 description 8
- 239000002994 raw material Substances 0.000 description 8
- 238000002425 crystallisation Methods 0.000 description 7
- 230000008025 crystallization Effects 0.000 description 7
- 238000010521 absorption reaction Methods 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- 238000004040 coloring Methods 0.000 description 6
- 229910004298 SiO 2 Inorganic materials 0.000 description 5
- 230000007613 environmental effect Effects 0.000 description 5
- 238000000149 argon plasma sintering Methods 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000002834 transmittance Methods 0.000 description 4
- 229910018068 Li 2 O Inorganic materials 0.000 description 3
- 230000002411 adverse Effects 0.000 description 3
- 229910000410 antimony oxide Inorganic materials 0.000 description 3
- 230000005540 biological transmission Effects 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 230000002349 favourable effect Effects 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 229910021495 keatite Inorganic materials 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 3
- 230000035699 permeability Effects 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000013016 damping Methods 0.000 description 2
- 238000004042 decolorization Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000000691 measurement method Methods 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 238000005457 optimization Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000002344 surface layer Substances 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 238000000441 X-ray spectroscopy Methods 0.000 description 1
- GEIAQOFPUVMAGM-UHFFFAOYSA-N ZrO Inorganic materials [Zr]=O GEIAQOFPUVMAGM-UHFFFAOYSA-N 0.000 description 1
- JFBZPFYRPYOZCQ-UHFFFAOYSA-N [Li].[Al] Chemical compound [Li].[Al] JFBZPFYRPYOZCQ-UHFFFAOYSA-N 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000003279 ceramming Methods 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 239000006103 coloring component Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 1
- 230000005274 electronic transitions Effects 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 238000013467 fragmentation Methods 0.000 description 1
- 238000006062 fragmentation reaction Methods 0.000 description 1
- 239000000156 glass melt Substances 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910052863 mullite Inorganic materials 0.000 description 1
- 239000002159 nanocrystal Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000011002 quantification Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000006017 silicate glass-ceramic Substances 0.000 description 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Inorganic materials [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000007704 wet chemistry method Methods 0.000 description 1
- 229910000500 β-quartz Inorganic materials 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C10/00—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition
- C03C10/0018—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition containing SiO2, Al2O3 and monovalent metal oxide as main constituents
- C03C10/0027—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition containing SiO2, Al2O3 and monovalent metal oxide as main constituents containing SiO2, Al2O3, Li2O as main constituents
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/097—Glass compositions containing silica with 40% to 90% silica, by weight containing phosphorus, niobium or tantalum
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Glass Compositions (AREA)
Description
CoO、Cr2O3、Cs2O3、CuO、MoO3、NiO、PbO、Rb2O3、V2O5。
比較例の場合、aの値は小さく、パラメーターbの値は大きいことが明らかである。第二項の減衰挙動を決定するパラメーターcは、比較例の場合比較的小さい、つまり、第二項は、長い時間tKBAに対して有効的である。
本発明によるガラスの場合、パラメーターaは比較的大きく、bの値はきわめて小さいことを特徴としている。比較例の場合、その反対に、aの値は小さく、パラメーターbの値は大きいことが明らかである。第二項の減衰挙動を決定するパラメーターcは、比較例の場合、比較的小さい、つまり、第二項は、長いtKBAに対して有効的である。
Claims (8)
- SnO2が0.05質量%から0.5質量%までであることを特徴とする、請求項1、2、4又は5に記載のガラスまたはガラスセラミック。
- Nd2O3が0.01質量%から0.1質量%までであることを特徴とする、請求項1、2、4、5又は6に記載のガラスまたはガラスセラミック。
- SrOが0.05質量%から0.7質量%までであることを特徴とする、請求項1、2、4、5、6又は7に記載のガラスまたはガラスセラミック。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102013216736.9 | 2013-08-22 | ||
DE102013216736.9A DE102013216736B9 (de) | 2013-08-22 | 2013-08-22 | Verfahren zur Ermittlung eines Prozessfensters sowie Verfahren zur Herstellung einer Glaskeramik |
PCT/EP2014/067427 WO2015024858A1 (de) | 2013-08-22 | 2014-08-14 | Glas und glaskeramik |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2016531075A JP2016531075A (ja) | 2016-10-06 |
JP6463757B2 true JP6463757B2 (ja) | 2019-02-06 |
Family
ID=51352506
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2016535425A Active JP6463757B2 (ja) | 2013-08-22 | 2014-08-14 | ガラスおよびガラスセラミック |
Country Status (6)
Country | Link |
---|---|
US (1) | US10106456B2 (ja) |
EP (1) | EP3010865B9 (ja) |
JP (1) | JP6463757B2 (ja) |
CN (2) | CN105612132A (ja) |
DE (1) | DE102013216736B9 (ja) |
WO (2) | WO2015024858A1 (ja) |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102012105576B4 (de) * | 2012-06-26 | 2016-12-15 | Schott Ag | Glaskeramik und Verfahren zu deren Herstellung sowie Glaskeramik-Kochfeld |
EP2805829A1 (de) | 2013-04-15 | 2014-11-26 | Schott AG | Glaskeramik-Kochfläche mit lokal erhöhter Transmission und Verfahren zur Herstellung einer solchen Glaskeramik-Kochfläche |
JP6312805B2 (ja) | 2013-04-15 | 2018-04-18 | ショット アクチエンゲゼルシャフトSchott AG | ガラス及びガラスセラミックの透過率を変化させるための方法及び該方法により製造可能なガラス又はガラスセラミック物品 |
DE102013216736B9 (de) * | 2013-08-22 | 2016-12-15 | Schott Ag | Verfahren zur Ermittlung eines Prozessfensters sowie Verfahren zur Herstellung einer Glaskeramik |
DE102015111490A1 (de) | 2015-07-15 | 2017-01-19 | Schott Ag | Verfahren und Vorrichtung zum lasergestützten Abtrennen eines Teilstücks von einem flächigen Glaselement |
US10550029B2 (en) | 2015-12-17 | 2020-02-04 | Corning Incorporated | Ion exchangeable glass with fast diffusion |
DE202018102533U1 (de) | 2017-12-22 | 2018-06-12 | Schott Ag | Einrichtungs- und Ausstattungsgegenstände für Küchen oder Labore mit Anzeigeeinrichtung |
DE202018102537U1 (de) | 2017-12-22 | 2018-05-22 | Schott Ag | Einrichtungs- und Ausstattungsgegenstände für Küchen oder Labore mit Leuchtelement |
DE202018102514U1 (de) | 2017-12-22 | 2018-05-22 | Schott Ag | Glaskeramik mit reduziertem Lithium-Gehalt |
DE102018110908A1 (de) * | 2017-12-22 | 2018-06-21 | Schott Ag | Transparente, eingefärbte Lithiumaluminiumsilikat-Glaskeramik sowie Verfahren zur Herstellung und Verwendung der Glaskeramik |
EP3502072B1 (de) * | 2017-12-22 | 2021-10-27 | Schott AG | Eingefärbte kaminsichtscheibe mit farbneutraler transmissionscharakteristik |
DE102018110909A1 (de) | 2017-12-22 | 2018-06-21 | Schott Ag | Abdeckplatte mit farbneutraler Beschichtung |
US20210403370A1 (en) | 2018-11-12 | 2021-12-30 | Nippon Electric Glass Co., Ltd. | Li2O-Al2O3-SiO2-BASED CRYSTALLIZED GLASS |
DE102019216441A1 (de) * | 2019-10-25 | 2021-04-29 | BSH Hausgeräte GmbH | Haushaltsgerät mit einer Sende-/ Empfangseinheit |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3997593B2 (ja) * | 1998-02-19 | 2007-10-24 | 日本電気硝子株式会社 | Li2 O−Al2 O3 −SiO2 系結晶化ガラス |
JPH11228181A (ja) * | 1998-02-19 | 1999-08-24 | Nippon Electric Glass Co Ltd | Li2 O−Al2 O3 −SiO2 系結晶化ガラス |
DE10017701C2 (de) * | 2000-04-08 | 2002-03-07 | Schott Glas | Gefloatetes Flachglas |
DE202004009227U1 (de) * | 2004-05-13 | 2005-09-29 | Schott Ag | Leuchtvorrichtung mit einer Glas-Metall-Durchführung sowie Glas-Metall-Durchführung |
DE102004001176A1 (de) * | 2004-01-05 | 2005-08-04 | Schott Ag | Verwendungen von Glaskeramiken |
DE502006004506D1 (de) * | 2006-03-20 | 2009-09-24 | Schott Ag | Transparente, farblose Lithium-Aluminosilikat-Glaskeramikplatte mit blickdichter, farbiger Unterseitenbeschichtung |
DE502006007025D1 (de) * | 2006-03-20 | 2010-07-08 | Schott Ag | Lithium-Aluminium-Silikatglas mit kurzen Keramisierungszeiten |
FR2909374B1 (fr) * | 2006-11-30 | 2016-11-25 | Soc En Nom Collectif Dite : Eurokera | Vitroceramiques de beta-quartz, transparentes et incolores, a faible teneur en tio2; articles en lesdites vitroceramiques ; verres precurseurs, procedes d'elaboration |
FR2909373B1 (fr) * | 2006-11-30 | 2009-02-27 | Snc Eurokera Soc En Nom Collec | Vitroceramiques de beta-quartz, transparentes et incolores, exemptes de tio2 ; articles en lesdites vitroceramiques ; verres precurseurs, procedes d'elaboration. |
DE102008043718B9 (de) | 2008-11-13 | 2012-05-31 | Schott Ag | Hochtransparentes wuchteinwirkungsfestes Scheibenlaminat umfassend wenigstens eine Scheibe einer Lithium-Alumino-Silicat-Glaskeramik und dessen Verwendung |
DE102010032113B9 (de) * | 2010-07-23 | 2017-06-22 | Schott Ag | Transparente oder transparente eingefärbte Lithiumaluminiumsilikat-Glaskeramik mit einstellbarer thermischer Ausdehnung und deren Verwendung |
JP6202775B2 (ja) * | 2010-08-11 | 2017-09-27 | 日本電気硝子株式会社 | Li2O−Al2O3−SiO2系結晶化ガラス |
DE102012202697A1 (de) * | 2012-02-22 | 2013-08-22 | Schott Ag | Transparente farbarme Lithiumaluminiumsilikat-Glaskeramik und deren Verwendung |
FR2990690B1 (fr) * | 2012-05-15 | 2016-01-01 | Eurokera | Vitroceramiques de quartz-beta, transparentes, essentiellement incolores et non diffusantes; articles en lesdites vitroceramiques; verres precurseurs |
DE102013216736B9 (de) * | 2013-08-22 | 2016-12-15 | Schott Ag | Verfahren zur Ermittlung eines Prozessfensters sowie Verfahren zur Herstellung einer Glaskeramik |
-
2013
- 2013-08-22 DE DE102013216736.9A patent/DE102013216736B9/de active Active
-
2014
- 2014-08-14 CN CN201480046357.1A patent/CN105612132A/zh active Pending
- 2014-08-14 CN CN201911128810.4A patent/CN110698060A/zh active Pending
- 2014-08-14 EP EP14753234.5A patent/EP3010865B9/de active Active
- 2014-08-14 WO PCT/EP2014/067427 patent/WO2015024858A1/de active Application Filing
- 2014-08-14 JP JP2016535425A patent/JP6463757B2/ja active Active
- 2014-08-14 WO PCT/EP2014/067426 patent/WO2015024857A1/de active Application Filing
-
2016
- 2016-02-22 US US15/049,261 patent/US10106456B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
EP3010865B9 (de) | 2017-02-22 |
WO2015024857A1 (de) | 2015-02-26 |
JP2016531075A (ja) | 2016-10-06 |
US10106456B2 (en) | 2018-10-23 |
CN110698060A (zh) | 2020-01-17 |
CN105612132A (zh) | 2016-05-25 |
DE102013216736B9 (de) | 2016-12-15 |
US20160168018A1 (en) | 2016-06-16 |
DE102013216736B4 (de) | 2016-07-28 |
WO2015024858A1 (de) | 2015-02-26 |
DE102013216736A1 (de) | 2015-02-26 |
EP3010865A1 (de) | 2016-04-27 |
EP3010865B1 (de) | 2016-11-09 |
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