GB874618A - Organo manganese pentacarbonyl compounds - Google Patents
Organo manganese pentacarbonyl compoundsInfo
- Publication number
- GB874618A GB874618A GB6893/58A GB689358A GB874618A GB 874618 A GB874618 A GB 874618A GB 6893/58 A GB6893/58 A GB 6893/58A GB 689358 A GB689358 A GB 689358A GB 874618 A GB874618 A GB 874618A
- Authority
- GB
- United Kingdom
- Prior art keywords
- manganese
- pentacarbonyls
- pentacarbonyl
- compounds
- alkali metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 Organo manganese Chemical compound 0.000 title abstract 15
- 229910052748 manganese Inorganic materials 0.000 title abstract 8
- 239000011572 manganese Substances 0.000 title abstract 8
- 150000001875 compounds Chemical class 0.000 title abstract 4
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 abstract 4
- 229910052783 alkali metal Inorganic materials 0.000 abstract 3
- 150000001340 alkali metals Chemical class 0.000 abstract 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 abstract 2
- 150000004820 halides Chemical class 0.000 abstract 2
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 2
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 abstract 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical group [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 abstract 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 abstract 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 1
- JCDPDJUOJWVVAR-UHFFFAOYSA-N FC(F)(F)[Mn] Chemical compound FC(F)(F)[Mn] JCDPDJUOJWVVAR-UHFFFAOYSA-N 0.000 abstract 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 abstract 1
- 229910018385 Mn(CO)5 Inorganic materials 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 1
- IBXNLBMOIVUEMJ-UHFFFAOYSA-N [Mn]C Chemical compound [Mn]C IBXNLBMOIVUEMJ-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 150000008065 acid anhydrides Chemical class 0.000 abstract 1
- 125000002252 acyl group Chemical group 0.000 abstract 1
- 239000006079 antiknock agent Substances 0.000 abstract 1
- 238000009835 boiling Methods 0.000 abstract 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052794 bromium Inorganic materials 0.000 abstract 1
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 1
- VPLUIUJZLFXMCF-UHFFFAOYSA-N carbon monoxide;manganese Chemical compound [Mn].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-] VPLUIUJZLFXMCF-UHFFFAOYSA-N 0.000 abstract 1
- 125000004181 carboxyalkyl group Chemical group 0.000 abstract 1
- 125000005026 carboxyaryl group Chemical group 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 239000000460 chlorine Substances 0.000 abstract 1
- 150000004292 cyclic ethers Chemical class 0.000 abstract 1
- 150000002170 ethers Chemical class 0.000 abstract 1
- 229910052731 fluorine Inorganic materials 0.000 abstract 1
- 239000011737 fluorine Substances 0.000 abstract 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 abstract 1
- 239000000446 fuel Substances 0.000 abstract 1
- 239000002816 fuel additive Substances 0.000 abstract 1
- 238000011065 in-situ storage Methods 0.000 abstract 1
- 238000002955 isolation Methods 0.000 abstract 1
- 150000002825 nitriles Chemical class 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
- 229910021653 sulphate ion Inorganic materials 0.000 abstract 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F13/00—Compounds containing elements of Groups 7 or 17 of the Periodic Table
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/30—Organic compounds compounds not mentioned before (complexes)
- C10L1/305—Organic compounds compounds not mentioned before (complexes) organo-metallic compounds (containing a metal to carbon bond)
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Pyridine Compounds (AREA)
Abstract
The invention comprises organo manganese pentacarbonyls of formula R(CO)xMn (CO)5 where R is a univalent hydrocarbon group which may be substituted with nonreactive, non-hydrocarbyl substituents and x is 0 or 1. Typical substituents include fluorine, chlorine, bromine and iodine atoms, nitro, hydroxyl, aldehyde, nitrile and carboxyalkyl or carboxyaryl groups such as carboxyethyl, carboxybutyl and carboxyphenyl. Specified compounds include benzoyl-, benzyl-, phenyl-, methyl-, acetyl-, stearoyl-, trifluoroacetyl-, and trifluoromethyl manganese pentacarbonyls. They may be prepared by reacting an alkali metal manganese pentacarbonyl with an organic halide, organic sulphate, acid halide or acid anhydride. The alkali metal manganese pentacarbonyl may be prepared by reacting an alkali metal with manganese pentacarbonyl in an ether medium and may be used in situ without isolation in the preparation of the compounds of the invention. Suitable ethers are those with a boiling point above 25 DEG C., especially cyclic ethers such as tetrahydrofuran and dioxane. The acy manganese pentacarbonyls so prepared may be pyrolysed to give the corresponding hydrocarbyl manganese pentacarbonyl, which in its turn may be reconverted into the acyl derivative by reaction with carbon monoxide under pressure at a temperature between 20 DEG C. and 200 DEG C. The compounds of the invention may be used as anti-knock fuel additives (see Group III).ALSO:Organo manganese pentacarbonyls of formula R(CO)xMn(CO)5 where R is an unsubstituted or substituted univalent hydrocarbon group and x is 0 or 1-in particular, methyl manganese pentacarbonyl CH3.Mn(CO)5 -may be added as antiknock agents for gasoline fuels.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US874618XA | 1957-03-13 | 1957-03-13 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB874618A true GB874618A (en) | 1961-08-10 |
Family
ID=22205326
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB6893/58A Expired GB874618A (en) | 1957-03-13 | 1958-03-04 | Organo manganese pentacarbonyl compounds |
Country Status (3)
| Country | Link |
|---|---|
| BE (1) | BE558947A (en) |
| DE (1) | DE1116661B (en) |
| GB (1) | GB874618A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3290343A (en) * | 1961-09-01 | 1966-12-06 | Ethyl Corp | Organometallic compounds containing fluorocarbon radicals |
-
0
- BE BE558947D patent/BE558947A/xx unknown
-
1958
- 1958-03-04 GB GB6893/58A patent/GB874618A/en not_active Expired
- 1958-03-12 DE DEE15515A patent/DE1116661B/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3290343A (en) * | 1961-09-01 | 1966-12-06 | Ethyl Corp | Organometallic compounds containing fluorocarbon radicals |
Also Published As
| Publication number | Publication date |
|---|---|
| BE558947A (en) | |
| DE1116661B (en) | 1961-11-09 |
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