GB727472A - Improvements in or relating to salts of formaldehyde sulphoxylic acid - Google Patents

Improvements in or relating to salts of formaldehyde sulphoxylic acid

Info

Publication number
GB727472A
GB727472A GB24146/51A GB2414651A GB727472A GB 727472 A GB727472 A GB 727472A GB 24146/51 A GB24146/51 A GB 24146/51A GB 2414651 A GB2414651 A GB 2414651A GB 727472 A GB727472 A GB 727472A
Authority
GB
United Kingdom
Prior art keywords
formaldehyde
quaternary ammonium
action
groups
sulphoxylates
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB24146/51A
Inventor
Geoffrey Moorhouse Gibson
Walter Cule Davies
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Brotherton & Co Ltd
Original Assignee
Brotherton & Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Brotherton & Co Ltd filed Critical Brotherton & Co Ltd
Priority to GB24146/51A priority Critical patent/GB727472A/en
Publication of GB727472A publication Critical patent/GB727472A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C313/00—Sulfinic acids; Sulfenic acids; Halides, esters or anhydrides thereof; Amides of sulfinic or sulfenic acids, i.e. compounds having singly-bound oxygen atoms of sulfinic or sulfenic groups replaced by nitrogen atoms, not being part of nitro or nitroso groups
    • C07C313/02—Sulfinic acids; Derivatives thereof
    • C07C313/04—Sulfinic acids; Esters thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/06—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom containing only hydrogen and carbon atoms in addition to the ring nitrogen atom
    • C07D213/16—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom containing only hydrogen and carbon atoms in addition to the ring nitrogen atom containing only one pyridine ring
    • C07D213/20—Quaternary compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/02—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms containing only hydrogen and carbon atoms in addition to the ring hetero elements
    • C07D295/037—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms containing only hydrogen and carbon atoms in addition to the ring hetero elements with quaternary ring nitrogen atoms
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/22—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using vat dyestuffs including indigo
    • D06P1/221—Reducing systems; Reducing catalysts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/655—Compounds containing ammonium groups
    • D06P1/66—Compounds containing ammonium groups containing quaternary ammonium groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)

Abstract

The invention comprises quaternary ammonium formaldehyde sulphoxylates, particularly those of the following types:-(1) compounds in which 4 different or the same hydrocarbon groups are attached to the N, including those in which 2 or 3 of the groups are represented by the residue of a heterocyclic ring; (2) compounds in which 2 of the groups on the N are represented by the residue of a heterocyclic ring containing also oxygen, the other two being similar or different hydrocarbon residues; (3) compounds in which one of the groups attached to N is an acidylamino alkyl group, the others being as above; the products may be obtained by the action of a quaternary ammonium hydroxide which is strong enough for the product not to be hydrolysed in aqueous solution, on a basic zinc formaldehyde sulphoxylate with heating, or by the action of normal zinc formaldehyde sulphoxylate, or an aqueous solution or suspension of a normal or basic formaldehyde sulphoxylate of a metal which forms an insoluble hydroxide, carbonate or sulphate, on an aqueous solution of a quaternary ammonium hydroxide, carbonate or sulphate; or by the action of quaternary ammonium salts on metal formaldehyde sulphoxylates, such that in alcoholic solution, a less soluble metal salt is precipitated; or by the reduction of quaternary ammonium formaldehyde bisulphite; or by the action of formaldehyde on a quaternary ammonium hydrosulphite; or by the action of an alcohol soluble quaternary ammonium iodide on tetramethylammonium formaldehyde sulphoxylate in alcoholic solution. In examples the formaldehyde sulphoxylates of tetramethylammonium, the corresponding tetraethyl, phenyl-trimethyl, cetyl-trimethyl, cyclohexyltrimethyl, dicetyldimethyl, phenyl benzyldimethyl, and 2-stearamidoethyltrimethyl, ammonium derivatives and the formaldehyde sulphoxylates of methylpyridinium, N : N-dimethylpiperidinium, N : N-dimethyl-1 : 2 : 3 : 4-tetrahydroquinolinium, N : N - dimethyl morpholinium, and cetyl pyridinium are described; the tetramethyl compound is prepared by each of the methods described above. A table showing the solubilities of several of the products in a number of organic solvents and water is given.
GB24146/51A 1951-10-16 1951-10-16 Improvements in or relating to salts of formaldehyde sulphoxylic acid Expired GB727472A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB24146/51A GB727472A (en) 1951-10-16 1951-10-16 Improvements in or relating to salts of formaldehyde sulphoxylic acid

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB24146/51A GB727472A (en) 1951-10-16 1951-10-16 Improvements in or relating to salts of formaldehyde sulphoxylic acid

Publications (1)

Publication Number Publication Date
GB727472A true GB727472A (en) 1955-04-06

Family

ID=10207125

Family Applications (1)

Application Number Title Priority Date Filing Date
GB24146/51A Expired GB727472A (en) 1951-10-16 1951-10-16 Improvements in or relating to salts of formaldehyde sulphoxylic acid

Country Status (1)

Country Link
GB (1) GB727472A (en)

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