GB1136699A - Electrolytic polymerization of aromatic compounds - Google Patents

Electrolytic polymerization of aromatic compounds

Info

Publication number
GB1136699A
GB1136699A GB36513/67A GB3651367A GB1136699A GB 1136699 A GB1136699 A GB 1136699A GB 36513/67 A GB36513/67 A GB 36513/67A GB 3651367 A GB3651367 A GB 3651367A GB 1136699 A GB1136699 A GB 1136699A
Authority
GB
United Kingdom
Prior art keywords
aromatic compound
benzene
biphenyl
metal
naphthalene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB36513/67A
Inventor
David George Walker
Norvell Edwin Wisdom
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Esso Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Research and Engineering Co, Esso Research and Engineering Co filed Critical Exxon Research and Engineering Co
Publication of GB1136699A publication Critical patent/GB1136699A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/20—Processes
    • C25B3/29—Coupling reactions

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

1,136,699. Polycyclic aromatic hydrocarbons. ESSO RESEARCH & ENG. CO. 9 Aug., 1967, No. 36513/67. Heading C5E. [Also in Divison C7] Polymeric aromatic compounds are prepared by electrolysing a solution comprising a C 6 - C 20 aromatic compound and a ternary complex having the formula R : HX : 2AlX 3 wherein R is a C 6 -C 20 aromatic compound at least as basic as the aromatic compound to be polymerized and X is Cl or Br. The aromatic compound to be polymerized may be benzene, biphenyl, naphthalene, an alkyl, e.g. methyl substituted benzene, a naphthalene, or a biphenyl; thus R may be the same or more basic, e.g. benzene, biphenyl, toluene, xylene, pseudocumene, hemimellitene, (iso)durene, mesitylene, prehnitene, pentamethylbenzene, hexamethylbenzene, isopropyl benzene, (1,3,5-dimethyl)- ethylbenzene, ethyl toluene or (di)methylnaphthalene. Many polymeric products are specified including p-poly- or sexi-phenyl (C 36 H 26 ). The electrolysis cell may be divided by a diffusion hindering membrane, e.g. of fritted or sintered glass, asbestos, porous ceramics or plastics, paper or perforated metal, wherein the ternary complex is preferably employed only in the anode compartment. A Ptgroup metal or Ta anode, and a Pt-group metal, Al, Cu, Hg, W, Ti, Zr, Hf, Ta, ferrous metal or C cathode may be used.
GB36513/67A 1967-07-26 1967-08-09 Electrolytic polymerization of aromatic compounds Expired GB1136699A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEE0034469 1967-07-26

Publications (1)

Publication Number Publication Date
GB1136699A true GB1136699A (en) 1968-12-11

Family

ID=7076798

Family Applications (1)

Application Number Title Priority Date Filing Date
GB36513/67A Expired GB1136699A (en) 1967-07-26 1967-08-09 Electrolytic polymerization of aromatic compounds

Country Status (2)

Country Link
DE (1) DE1643931A1 (en)
GB (1) GB1136699A (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3034988A1 (en) * 1980-09-17 1982-04-29 Basf Ag, 6700 Ludwigshafen METHOD FOR THE PRODUCTION OF ELECTRICALLY CONDUCTIVE POLYAROMATS AND THEIR USE IN ELECTROTECHNICS AND FOR THE ANTISTATIC EQUIPMENT OF PLASTICS

Also Published As

Publication number Publication date
DE1643931A1 (en) 1971-05-19

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