GB1136699A - Electrolytic polymerization of aromatic compounds - Google Patents
Electrolytic polymerization of aromatic compoundsInfo
- Publication number
- GB1136699A GB1136699A GB36513/67A GB3651367A GB1136699A GB 1136699 A GB1136699 A GB 1136699A GB 36513/67 A GB36513/67 A GB 36513/67A GB 3651367 A GB3651367 A GB 3651367A GB 1136699 A GB1136699 A GB 1136699A
- Authority
- GB
- United Kingdom
- Prior art keywords
- aromatic compound
- benzene
- biphenyl
- metal
- naphthalene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B3/00—Electrolytic production of organic compounds
- C25B3/20—Processes
- C25B3/29—Coupling reactions
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Abstract
1,136,699. Polycyclic aromatic hydrocarbons. ESSO RESEARCH & ENG. CO. 9 Aug., 1967, No. 36513/67. Heading C5E. [Also in Divison C7] Polymeric aromatic compounds are prepared by electrolysing a solution comprising a C 6 - C 20 aromatic compound and a ternary complex having the formula R : HX : 2AlX 3 wherein R is a C 6 -C 20 aromatic compound at least as basic as the aromatic compound to be polymerized and X is Cl or Br. The aromatic compound to be polymerized may be benzene, biphenyl, naphthalene, an alkyl, e.g. methyl substituted benzene, a naphthalene, or a biphenyl; thus R may be the same or more basic, e.g. benzene, biphenyl, toluene, xylene, pseudocumene, hemimellitene, (iso)durene, mesitylene, prehnitene, pentamethylbenzene, hexamethylbenzene, isopropyl benzene, (1,3,5-dimethyl)- ethylbenzene, ethyl toluene or (di)methylnaphthalene. Many polymeric products are specified including p-poly- or sexi-phenyl (C 36 H 26 ). The electrolysis cell may be divided by a diffusion hindering membrane, e.g. of fritted or sintered glass, asbestos, porous ceramics or plastics, paper or perforated metal, wherein the ternary complex is preferably employed only in the anode compartment. A Ptgroup metal or Ta anode, and a Pt-group metal, Al, Cu, Hg, W, Ti, Zr, Hf, Ta, ferrous metal or C cathode may be used.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEE0034469 | 1967-07-26 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1136699A true GB1136699A (en) | 1968-12-11 |
Family
ID=7076798
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB36513/67A Expired GB1136699A (en) | 1967-07-26 | 1967-08-09 | Electrolytic polymerization of aromatic compounds |
Country Status (2)
Country | Link |
---|---|
DE (1) | DE1643931A1 (en) |
GB (1) | GB1136699A (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3034988A1 (en) * | 1980-09-17 | 1982-04-29 | Basf Ag, 6700 Ludwigshafen | METHOD FOR THE PRODUCTION OF ELECTRICALLY CONDUCTIVE POLYAROMATS AND THEIR USE IN ELECTROTECHNICS AND FOR THE ANTISTATIC EQUIPMENT OF PLASTICS |
-
1967
- 1967-07-26 DE DE19671643931 patent/DE1643931A1/en active Pending
- 1967-08-09 GB GB36513/67A patent/GB1136699A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
DE1643931A1 (en) | 1971-05-19 |
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