FR2454431A1 - PROCESS FOR THE PRODUCTION OF ALKYLATED DIHYDROXY-DIPHENYLES - Google Patents
PROCESS FOR THE PRODUCTION OF ALKYLATED DIHYDROXY-DIPHENYLESInfo
- Publication number
- FR2454431A1 FR2454431A1 FR7909860A FR7909860A FR2454431A1 FR 2454431 A1 FR2454431 A1 FR 2454431A1 FR 7909860 A FR7909860 A FR 7909860A FR 7909860 A FR7909860 A FR 7909860A FR 2454431 A1 FR2454431 A1 FR 2454431A1
- Authority
- FR
- France
- Prior art keywords
- diphenyles
- production
- formula
- alkylated
- dihydroxy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
- B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/11—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
- C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
- C09K15/06—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing oxygen
- C09K15/08—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing oxygen containing a phenol or quinone moiety
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
- C10L1/183—Organic compounds containing oxygen containing hydroxy groups; Salts thereof at least one hydroxy group bound to an aromatic carbon atom
- C10L1/1835—Organic compounds containing oxygen containing hydroxy groups; Salts thereof at least one hydroxy group bound to an aromatic carbon atom having at least two hydroxy substituted non condensed benzene rings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
- B01J2231/42—Catalytic cross-coupling, i.e. connection of previously not connected C-atoms or C- and X-atoms without rearrangement
- B01J2231/4205—C-C cross-coupling, e.g. metal catalyzed or Friedel-Crafts type
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/842—Iron
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Emergency Medicine (AREA)
- Health & Medical Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Anti-Oxidant Or Stabilizer Compositions (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
CES COMPOSES SONT REPRESENTES PAR LA FORMULE I CI-APRES. POUR LES PREPARER, DES ALCOYL-PHENOLS DE FORMULE II CI-APRES SONT OXYDES AU MOYEN D'EAU OXYGENEE EN PRESENCE D'UN CATALYSEUR CONSTITUE PAR UN COMPOSE P-FERRO-PSEUDOAROMATIQUE TEL QUE LE FERROCENE ET SES DERIVES A UN PH COMPRIS ENTRE 1 ET 7, SELON L'EQUATION III CI-APRES. LE PRODUIT DE REACTION EST UTILISE NOTAMMENT COMME ANTIOXYDANT POUR ESSENCES. (CF DESSIN DANS BOPI) R, SEMBLABLES OU DIFFERENTSRESTES ALCOYLE LINEAIRES OU RAMIFIES EN C-CTHESE COMPOUNDS ARE REPRESENTED BY FORMULA I BELOW. TO PREPARE THEM, ALCOYL-PHENOLS OF FORMULA II BELOW ARE OXIDIZED BY MEANS OF OXYGENATED WATER IN THE PRESENCE OF A CATALYST CONSTITUTED BY A P-FERRO-PSEUDOAROMATIC COMPOUND SUCH AS FERROCENE AND ITS DERIVATIVES AT A PH INCLUDING 1 AND 7, ACCORDING TO EQUATION III BELOW. THE REACTION PRODUCT IS USED IN PARTICULAR AS AN ANTIOXIDANT FOR GASOLINES. (CF DRAWING IN BOPI) R, SIMILAR OR DIFFERENT ALKYL REMAINERS LINEAR OR BRANCHED IN C-C
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7909860A FR2454431A1 (en) | 1979-04-19 | 1979-04-19 | PROCESS FOR THE PRODUCTION OF ALKYLATED DIHYDROXY-DIPHENYLES |
CA000326032A CA1140153A (en) | 1979-04-19 | 1979-04-20 | Process for producing alkylated dihydroxy-diphenyls |
GB7913945A GB2047232B (en) | 1979-04-19 | 1979-04-21 | Alkylated dihydroxy-diphenyls |
CH385479A CH638771A5 (en) | 1979-04-19 | 1979-04-24 | Process for the production of alkylated dihydroxydiphenyls |
BE0/194877A BE875899A (en) | 1979-04-19 | 1979-04-26 | PROCESS FOR THE PRODUCTION OF DIHYDROXY-DIPHENYLESALCOYLS |
JP5354379A JPS55145627A (en) | 1979-04-19 | 1979-05-02 | Manufacture of alkylated dihydroxydiphenyl |
DE19792917927 DE2917927A1 (en) | 1979-04-19 | 1979-05-03 | METHOD FOR PRODUCING ALKYLATED DIHYDROXYDIPHENYLENE AND THE USE THEREOF |
NL7903697A NL7903697A (en) | 1979-04-19 | 1979-05-10 | PROCESS FOR PREPARING ALKYLATED DIHYDROXYDIPHENYL COMPOUNDS AND GASOLINE, CONTAINING PREPARED COMPOUNDS. |
Applications Claiming Priority (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7909860A FR2454431A1 (en) | 1979-04-19 | 1979-04-19 | PROCESS FOR THE PRODUCTION OF ALKYLATED DIHYDROXY-DIPHENYLES |
CA000326032A CA1140153A (en) | 1979-04-19 | 1979-04-20 | Process for producing alkylated dihydroxy-diphenyls |
GB7913945A GB2047232B (en) | 1979-04-19 | 1979-04-21 | Alkylated dihydroxy-diphenyls |
CH385479A CH638771A5 (en) | 1979-04-19 | 1979-04-24 | Process for the production of alkylated dihydroxydiphenyls |
BE0/194877A BE875899A (en) | 1979-04-19 | 1979-04-26 | PROCESS FOR THE PRODUCTION OF DIHYDROXY-DIPHENYLESALCOYLS |
JP5354379A JPS55145627A (en) | 1979-04-19 | 1979-05-02 | Manufacture of alkylated dihydroxydiphenyl |
DE19792917927 DE2917927A1 (en) | 1979-04-19 | 1979-05-03 | METHOD FOR PRODUCING ALKYLATED DIHYDROXYDIPHENYLENE AND THE USE THEREOF |
NL7903697A NL7903697A (en) | 1979-04-19 | 1979-05-10 | PROCESS FOR PREPARING ALKYLATED DIHYDROXYDIPHENYL COMPOUNDS AND GASOLINE, CONTAINING PREPARED COMPOUNDS. |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2454431A1 true FR2454431A1 (en) | 1980-11-14 |
FR2454431B1 FR2454431B1 (en) | 1984-07-13 |
Family
ID=27570158
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7909860A Granted FR2454431A1 (en) | 1979-04-19 | 1979-04-19 | PROCESS FOR THE PRODUCTION OF ALKYLATED DIHYDROXY-DIPHENYLES |
Country Status (8)
Country | Link |
---|---|
JP (1) | JPS55145627A (en) |
BE (1) | BE875899A (en) |
CA (1) | CA1140153A (en) |
CH (1) | CH638771A5 (en) |
DE (1) | DE2917927A1 (en) |
FR (1) | FR2454431A1 (en) |
GB (1) | GB2047232B (en) |
NL (1) | NL7903697A (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2006038893A1 (en) * | 2004-10-06 | 2006-04-13 | Agency For Science, Technology And Research | Oxidation of phenolic compound with hydrogen peroxide generated in the presence of the phenolic compound |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2479948A (en) * | 1947-01-25 | 1949-08-23 | Shell Dev | Stabilized composition |
US2490282A (en) * | 1948-08-31 | 1949-12-06 | Shell Dev | Coupling of aromatic hydroxy compounds |
US2785188A (en) * | 1952-02-04 | 1957-03-12 | Union Oil Co | Method for preparing 3, 3'-5, 5'-tetraalkyl-4, 4'-diphenoquinones |
US2900417A (en) * | 1955-03-21 | 1959-08-18 | Ethyl Corp | 3,3' - diisopropyl - 5,5' - di - tert - butyl-4,4'-dihydroxydiphenyl, its preparation and use |
US3156543A (en) * | 1963-11-21 | 1964-11-10 | Ethyl Corp | Stabilized organic material |
FR2218312A1 (en) * | 1973-02-16 | 1974-09-13 | Brichima Spa | |
FR2332252A1 (en) * | 1975-11-24 | 1977-06-17 | Ici America Inc | OXIDIZING CONDENSATION OF ALKYLPHENOLS CATALYZED BY METAL COMPLEXES OF AMINE COMPOUNDS |
-
1979
- 1979-04-19 FR FR7909860A patent/FR2454431A1/en active Granted
- 1979-04-20 CA CA000326032A patent/CA1140153A/en not_active Expired
- 1979-04-21 GB GB7913945A patent/GB2047232B/en not_active Expired
- 1979-04-24 CH CH385479A patent/CH638771A5/en not_active IP Right Cessation
- 1979-04-26 BE BE0/194877A patent/BE875899A/en not_active IP Right Cessation
- 1979-05-02 JP JP5354379A patent/JPS55145627A/en active Pending
- 1979-05-03 DE DE19792917927 patent/DE2917927A1/en not_active Withdrawn
- 1979-05-10 NL NL7903697A patent/NL7903697A/en not_active Application Discontinuation
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2479948A (en) * | 1947-01-25 | 1949-08-23 | Shell Dev | Stabilized composition |
US2490282A (en) * | 1948-08-31 | 1949-12-06 | Shell Dev | Coupling of aromatic hydroxy compounds |
US2785188A (en) * | 1952-02-04 | 1957-03-12 | Union Oil Co | Method for preparing 3, 3'-5, 5'-tetraalkyl-4, 4'-diphenoquinones |
US2900417A (en) * | 1955-03-21 | 1959-08-18 | Ethyl Corp | 3,3' - diisopropyl - 5,5' - di - tert - butyl-4,4'-dihydroxydiphenyl, its preparation and use |
US3156543A (en) * | 1963-11-21 | 1964-11-10 | Ethyl Corp | Stabilized organic material |
FR2218312A1 (en) * | 1973-02-16 | 1974-09-13 | Brichima Spa | |
US3929913A (en) * | 1973-02-16 | 1975-12-30 | Brichima Spa | Process for preparing diphenols |
FR2332252A1 (en) * | 1975-11-24 | 1977-06-17 | Ici America Inc | OXIDIZING CONDENSATION OF ALKYLPHENOLS CATALYZED BY METAL COMPLEXES OF AMINE COMPOUNDS |
Also Published As
Publication number | Publication date |
---|---|
GB2047232B (en) | 1983-08-03 |
GB2047232A (en) | 1980-11-26 |
FR2454431B1 (en) | 1984-07-13 |
CA1140153A (en) | 1983-01-25 |
JPS55145627A (en) | 1980-11-13 |
NL7903697A (en) | 1980-11-12 |
CH638771A5 (en) | 1983-10-14 |
DE2917927A1 (en) | 1980-11-13 |
BE875899A (en) | 1979-08-16 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |