FR2454431A1 - PROCESS FOR THE PRODUCTION OF ALKYLATED DIHYDROXY-DIPHENYLES - Google Patents

PROCESS FOR THE PRODUCTION OF ALKYLATED DIHYDROXY-DIPHENYLES

Info

Publication number
FR2454431A1
FR2454431A1 FR7909860A FR7909860A FR2454431A1 FR 2454431 A1 FR2454431 A1 FR 2454431A1 FR 7909860 A FR7909860 A FR 7909860A FR 7909860 A FR7909860 A FR 7909860A FR 2454431 A1 FR2454431 A1 FR 2454431A1
Authority
FR
France
Prior art keywords
diphenyles
production
formula
alkylated
dihydroxy
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7909860A
Other languages
French (fr)
Other versions
FR2454431B1 (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Brichima SpA
Original Assignee
Brichima SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Brichima SpA filed Critical Brichima SpA
Priority to FR7909860A priority Critical patent/FR2454431A1/en
Priority to CA000326032A priority patent/CA1140153A/en
Priority to GB7913945A priority patent/GB2047232B/en
Priority to CH385479A priority patent/CH638771A5/en
Priority to BE0/194877A priority patent/BE875899A/en
Priority to JP5354379A priority patent/JPS55145627A/en
Priority to DE19792917927 priority patent/DE2917927A1/en
Priority to NL7903697A priority patent/NL7903697A/en
Publication of FR2454431A1 publication Critical patent/FR2454431A1/en
Application granted granted Critical
Publication of FR2454431B1 publication Critical patent/FR2454431B1/fr
Granted legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/11—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
    • C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
    • C09K15/06—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing oxygen
    • C09K15/08—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing oxygen containing a phenol or quinone moiety
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/183—Organic compounds containing oxygen containing hydroxy groups; Salts thereof at least one hydroxy group bound to an aromatic carbon atom
    • C10L1/1835—Organic compounds containing oxygen containing hydroxy groups; Salts thereof at least one hydroxy group bound to an aromatic carbon atom having at least two hydroxy substituted non condensed benzene rings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
    • B01J2231/42—Catalytic cross-coupling, i.e. connection of previously not connected C-atoms or C- and X-atoms without rearrangement
    • B01J2231/4205—C-C cross-coupling, e.g. metal catalyzed or Friedel-Crafts type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/842—Iron

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Emergency Medicine (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Anti-Oxidant Or Stabilizer Compositions (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

CES COMPOSES SONT REPRESENTES PAR LA FORMULE I CI-APRES. POUR LES PREPARER, DES ALCOYL-PHENOLS DE FORMULE II CI-APRES SONT OXYDES AU MOYEN D'EAU OXYGENEE EN PRESENCE D'UN CATALYSEUR CONSTITUE PAR UN COMPOSE P-FERRO-PSEUDOAROMATIQUE TEL QUE LE FERROCENE ET SES DERIVES A UN PH COMPRIS ENTRE 1 ET 7, SELON L'EQUATION III CI-APRES. LE PRODUIT DE REACTION EST UTILISE NOTAMMENT COMME ANTIOXYDANT POUR ESSENCES. (CF DESSIN DANS BOPI) R, SEMBLABLES OU DIFFERENTSRESTES ALCOYLE LINEAIRES OU RAMIFIES EN C-CTHESE COMPOUNDS ARE REPRESENTED BY FORMULA I BELOW. TO PREPARE THEM, ALCOYL-PHENOLS OF FORMULA II BELOW ARE OXIDIZED BY MEANS OF OXYGENATED WATER IN THE PRESENCE OF A CATALYST CONSTITUTED BY A P-FERRO-PSEUDOAROMATIC COMPOUND SUCH AS FERROCENE AND ITS DERIVATIVES AT A PH INCLUDING 1 AND 7, ACCORDING TO EQUATION III BELOW. THE REACTION PRODUCT IS USED IN PARTICULAR AS AN ANTIOXIDANT FOR GASOLINES. (CF DRAWING IN BOPI) R, SIMILAR OR DIFFERENT ALKYL REMAINERS LINEAR OR BRANCHED IN C-C

FR7909860A 1979-04-19 1979-04-19 PROCESS FOR THE PRODUCTION OF ALKYLATED DIHYDROXY-DIPHENYLES Granted FR2454431A1 (en)

Priority Applications (8)

Application Number Priority Date Filing Date Title
FR7909860A FR2454431A1 (en) 1979-04-19 1979-04-19 PROCESS FOR THE PRODUCTION OF ALKYLATED DIHYDROXY-DIPHENYLES
CA000326032A CA1140153A (en) 1979-04-19 1979-04-20 Process for producing alkylated dihydroxy-diphenyls
GB7913945A GB2047232B (en) 1979-04-19 1979-04-21 Alkylated dihydroxy-diphenyls
CH385479A CH638771A5 (en) 1979-04-19 1979-04-24 Process for the production of alkylated dihydroxydiphenyls
BE0/194877A BE875899A (en) 1979-04-19 1979-04-26 PROCESS FOR THE PRODUCTION OF DIHYDROXY-DIPHENYLESALCOYLS
JP5354379A JPS55145627A (en) 1979-04-19 1979-05-02 Manufacture of alkylated dihydroxydiphenyl
DE19792917927 DE2917927A1 (en) 1979-04-19 1979-05-03 METHOD FOR PRODUCING ALKYLATED DIHYDROXYDIPHENYLENE AND THE USE THEREOF
NL7903697A NL7903697A (en) 1979-04-19 1979-05-10 PROCESS FOR PREPARING ALKYLATED DIHYDROXYDIPHENYL COMPOUNDS AND GASOLINE, CONTAINING PREPARED COMPOUNDS.

Applications Claiming Priority (8)

Application Number Priority Date Filing Date Title
FR7909860A FR2454431A1 (en) 1979-04-19 1979-04-19 PROCESS FOR THE PRODUCTION OF ALKYLATED DIHYDROXY-DIPHENYLES
CA000326032A CA1140153A (en) 1979-04-19 1979-04-20 Process for producing alkylated dihydroxy-diphenyls
GB7913945A GB2047232B (en) 1979-04-19 1979-04-21 Alkylated dihydroxy-diphenyls
CH385479A CH638771A5 (en) 1979-04-19 1979-04-24 Process for the production of alkylated dihydroxydiphenyls
BE0/194877A BE875899A (en) 1979-04-19 1979-04-26 PROCESS FOR THE PRODUCTION OF DIHYDROXY-DIPHENYLESALCOYLS
JP5354379A JPS55145627A (en) 1979-04-19 1979-05-02 Manufacture of alkylated dihydroxydiphenyl
DE19792917927 DE2917927A1 (en) 1979-04-19 1979-05-03 METHOD FOR PRODUCING ALKYLATED DIHYDROXYDIPHENYLENE AND THE USE THEREOF
NL7903697A NL7903697A (en) 1979-04-19 1979-05-10 PROCESS FOR PREPARING ALKYLATED DIHYDROXYDIPHENYL COMPOUNDS AND GASOLINE, CONTAINING PREPARED COMPOUNDS.

Publications (2)

Publication Number Publication Date
FR2454431A1 true FR2454431A1 (en) 1980-11-14
FR2454431B1 FR2454431B1 (en) 1984-07-13

Family

ID=27570158

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7909860A Granted FR2454431A1 (en) 1979-04-19 1979-04-19 PROCESS FOR THE PRODUCTION OF ALKYLATED DIHYDROXY-DIPHENYLES

Country Status (8)

Country Link
JP (1) JPS55145627A (en)
BE (1) BE875899A (en)
CA (1) CA1140153A (en)
CH (1) CH638771A5 (en)
DE (1) DE2917927A1 (en)
FR (1) FR2454431A1 (en)
GB (1) GB2047232B (en)
NL (1) NL7903697A (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006038893A1 (en) * 2004-10-06 2006-04-13 Agency For Science, Technology And Research Oxidation of phenolic compound with hydrogen peroxide generated in the presence of the phenolic compound

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2479948A (en) * 1947-01-25 1949-08-23 Shell Dev Stabilized composition
US2490282A (en) * 1948-08-31 1949-12-06 Shell Dev Coupling of aromatic hydroxy compounds
US2785188A (en) * 1952-02-04 1957-03-12 Union Oil Co Method for preparing 3, 3'-5, 5'-tetraalkyl-4, 4'-diphenoquinones
US2900417A (en) * 1955-03-21 1959-08-18 Ethyl Corp 3,3' - diisopropyl - 5,5' - di - tert - butyl-4,4'-dihydroxydiphenyl, its preparation and use
US3156543A (en) * 1963-11-21 1964-11-10 Ethyl Corp Stabilized organic material
FR2218312A1 (en) * 1973-02-16 1974-09-13 Brichima Spa
FR2332252A1 (en) * 1975-11-24 1977-06-17 Ici America Inc OXIDIZING CONDENSATION OF ALKYLPHENOLS CATALYZED BY METAL COMPLEXES OF AMINE COMPOUNDS

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2479948A (en) * 1947-01-25 1949-08-23 Shell Dev Stabilized composition
US2490282A (en) * 1948-08-31 1949-12-06 Shell Dev Coupling of aromatic hydroxy compounds
US2785188A (en) * 1952-02-04 1957-03-12 Union Oil Co Method for preparing 3, 3'-5, 5'-tetraalkyl-4, 4'-diphenoquinones
US2900417A (en) * 1955-03-21 1959-08-18 Ethyl Corp 3,3' - diisopropyl - 5,5' - di - tert - butyl-4,4'-dihydroxydiphenyl, its preparation and use
US3156543A (en) * 1963-11-21 1964-11-10 Ethyl Corp Stabilized organic material
FR2218312A1 (en) * 1973-02-16 1974-09-13 Brichima Spa
US3929913A (en) * 1973-02-16 1975-12-30 Brichima Spa Process for preparing diphenols
FR2332252A1 (en) * 1975-11-24 1977-06-17 Ici America Inc OXIDIZING CONDENSATION OF ALKYLPHENOLS CATALYZED BY METAL COMPLEXES OF AMINE COMPOUNDS

Also Published As

Publication number Publication date
GB2047232B (en) 1983-08-03
GB2047232A (en) 1980-11-26
FR2454431B1 (en) 1984-07-13
CA1140153A (en) 1983-01-25
JPS55145627A (en) 1980-11-13
NL7903697A (en) 1980-11-12
CH638771A5 (en) 1983-10-14
DE2917927A1 (en) 1980-11-13
BE875899A (en) 1979-08-16

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