EP2252721A1 - Hartstoffbeschichteter körper - Google Patents
Hartstoffbeschichteter körperInfo
- Publication number
- EP2252721A1 EP2252721A1 EP09718954A EP09718954A EP2252721A1 EP 2252721 A1 EP2252721 A1 EP 2252721A1 EP 09718954 A EP09718954 A EP 09718954A EP 09718954 A EP09718954 A EP 09718954A EP 2252721 A1 EP2252721 A1 EP 2252721A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- layer
- tii
- layers
- hard material
- hard
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000463 material Substances 0.000 title claims abstract description 21
- 229910052719 titanium Inorganic materials 0.000 claims description 10
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 9
- 239000000758 substrate Substances 0.000 claims description 9
- 229910052751 metal Inorganic materials 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 6
- 239000011195 cermet Substances 0.000 claims description 5
- 239000000919 ceramic Substances 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 2
- 239000010410 layer Substances 0.000 description 78
- 239000010936 titanium Substances 0.000 description 14
- 238000000576 coating method Methods 0.000 description 10
- 229910052782 aluminium Inorganic materials 0.000 description 8
- 239000011248 coating agent Substances 0.000 description 8
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 7
- 238000005520 cutting process Methods 0.000 description 7
- 238000000034 method Methods 0.000 description 6
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 5
- 239000000460 chlorine Substances 0.000 description 5
- 229910052801 chlorine Inorganic materials 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 3
- 230000001965 increasing effect Effects 0.000 description 3
- 238000003754 machining Methods 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 229910052984 zinc sulfide Inorganic materials 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical group [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- 238000005268 plasma chemical vapour deposition Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000002347 wear-protection layer Substances 0.000 description 2
- 229910018509 Al—N Inorganic materials 0.000 description 1
- 108020005544 Antisense RNA Proteins 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 229910010038 TiAl Inorganic materials 0.000 description 1
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical class Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 1
- -1 aluminum halides Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical compound Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
- 150000002830 nitrogen compounds Chemical class 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000002230 thermal chemical vapour deposition Methods 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical class Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C30/00—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
- C23C30/005—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process on hard metal substrates
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
- Y10T428/2495—Thickness [relative or absolute]
- Y10T428/24967—Absolute thicknesses specified
- Y10T428/24975—No layer or component greater than 5 mils thick
Definitions
- the invention relates to a hard-coated body with a plurality of CVD applied hard material layers.
- the cutting material should in particular be resistant to abrasion, which already led early to hard metal or cermet substrate bodies having been provided with surface coatings, wherein first carbides, nitrides or carbonitrides of titanium and later also aluminum oxide layers have been used as wear protection layers.
- first carbides, nitrides or carbonitrides of titanium and later also aluminum oxide layers have been used as wear protection layers.
- multi-layer wear protection layers of different hard materials are also known.
- wear-reducing layers for example, aluminum oxide layers are known, which are arranged on one or more intermediate layers such as titanium carbonitride or titanium nitride.
- WO 03/085152 A2 discloses the use of a Ti-Al-N layer which can be produced as a monophase layer with aluminum contents of up to 60% by means of PVD. At higher aluminum contents, however, a mixture of cubic and hexagonal TiAIN is formed, and with even higher proportions of aluminum only the softer and not wear-resistant hexagonal wurtzite structure is produced.
- WO 2007/003648 A1 in order to improve the wear resistance and the oxidation resistance, it is proposed to produce a hard-coated body with a single- or multilayer coating system by means of CVD, which contains at least one Tii- X Al x N-hard material layer, to which the body in a reactor is coated at temperatures in the range of 700 ° C to 900 0 C by CVD without plasma excitation and should be used as precursors titanium hallogenides, aluminum halides and reactive nitrogen compounds, which are mixed at elevated temperature.
- the chlorine content is in the range between 0.05 to 0.9 at%.
- the Tii- X Al X N hard-material layer or layers can contain up to 30% by mass of amorphous layer constituents.
- the hardness value of the layers obtained is in the range of 2,500 HV to 3,800 HV.
- the layer system applied to a substrate body consists of a titanium nitride, titanium carbonitride or titanium carbide bonding layer applied to the body followed by a phase gradient layer followed and finally an outer layer of a single- or multi-phase Tii -x Al ⁇ N hard material layer.
- the phase gradient layer consists of a TiN / h-AlN phase mixture on its side facing the connection layer and, with increasing layer thickness, has an increasing phase fraction of fcc-TiAIN with a proportion of more than 50% and, concomitantly, a simultaneous decrease in the phase proportions of TiN and h- AIN on.
- the thermal resistance of the coating is of great importance for the application of this material during machining operations, in particular at high cutting speeds.
- temperatures that are significantly above 1000 ° C. are produced.
- different coefficients of expansion that exist for the substrates between the individual layers, significantly. This leads to the formation of stresses between the individual layers and, if the high temperature is transported by heat conduction from the outer layer to the substrate body, in the worst case to a detachment of the coating, making the cutting insert is unusable.
- T ⁇ i -X Al X N, Tii- X Al X C or Ti 1-X Al X CN layer instead of a commonly used in the prior art TiCN layer has the advantage that the thermal conductivity in the below
- the Al 2 O 3 layer arranged layer is about 80% lower, so that the T ⁇ 1-X AI X N, Tii -X AI X C or CN layer proves to significantly improve thermal insulation to the substrate body.
- the outer AbOa layer is also more resistant to oxidation and harder by about 50% compared to a TiCN outer layer, resulting in a higher wear resistance.
- the Ti- X Al X CN, Tii -x Al ⁇ C or Tii- X Al X N layer may be single-phase and have a cubic structure or be multi-phase and have a further phase in wurtzite structure and / or TiN in addition to a main cubic phase , Up to 30 mass% may contain amorphous layer constituents.
- the chlorine content is between 0.01 to 3 At%.
- a TiN and / or TiCN layer can be used as a bonding layer to the substrate body, which consists of a hard metal, a cermet or a ceramic, so that the sequence of layers from the inside to the outside TiN or TiCN TiAIC (N) -Al 2 O 3 is.
- TiCN layers are also possible between the Al 2 O 3 outer layer and the Tii- X Al x N layer, Ti 1-x Al x C layer or the Tii- x Al x CN layer.
- the aluminum content as metal content is preferably between 70% and 90%.
- the layer thickness of a Ti 1-X Al x N layer, Tii -X AI x C layer or a Ti 1-X AI x CN layer may vary between 2 .mu.m to 10 .mu.m, preferably 3 .mu.m to 7 .mu.m.
- the aforementioned layer may also contain proportions of hexagonal aluminum nitride, at most 25%.
- the TiAIN / TiAICN / TiAIC alternating layer then has a total thickness resulting from the sum of the thicknesses of each individual layer, which is between 1 nm to 5 nm.
- the total thickness should be at least 1 micron to 5 microns.
- the TiAIN, TiAIC or TiAICN layer can contain up to 30% amorphous and chlorine levels up to 3 at%.
- a cermet or a ceramic substrate body is subjected to a CVD coating at coating temperatures between 650 0 C and 900 0 C, wherein in the gas atmosphere titanium and aluminum chlorides and ammonia are introduced to produce a TiAIN layer.
- a first between 2 .mu.m and 10 .mu.m, preferably 3 .mu.m to 7 .mu.m thick layer is applied in a conventional manner by means of the CVD method at least 2 microns maximum 10 microns thick Al 2 ⁇ 3 layer.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Vapour Deposition (AREA)
- Cutting Tools, Boring Holders, And Turrets (AREA)
- Carbon And Carbon Compounds (AREA)
Abstract
Description
Claims
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP15185878.4A EP3031948B1 (de) | 2008-03-12 | 2009-01-20 | Hartstoffbeschichteter körper |
PL09718954T PL2252721T3 (pl) | 2008-03-12 | 2009-01-20 | Korpus powlekany twardym materiałem |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102008013965A DE102008013965A1 (de) | 2008-03-12 | 2008-03-12 | Hartstoffbeschichteter Körper |
PCT/EP2009/000309 WO2009112115A1 (de) | 2008-03-12 | 2009-01-20 | Hartstoffbeschichteter körper |
Related Child Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP15185878.4A Division EP3031948B1 (de) | 2008-03-12 | 2009-01-20 | Hartstoffbeschichteter körper |
EP15185878.4A Division-Into EP3031948B1 (de) | 2008-03-12 | 2009-01-20 | Hartstoffbeschichteter körper |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2252721A1 true EP2252721A1 (de) | 2010-11-24 |
EP2252721B1 EP2252721B1 (de) | 2015-11-04 |
Family
ID=40586932
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP09718954.2A Active EP2252721B1 (de) | 2008-03-12 | 2009-01-20 | Hartstoffbeschichteter körper |
EP15185878.4A Revoked EP3031948B1 (de) | 2008-03-12 | 2009-01-20 | Hartstoffbeschichteter körper |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP15185878.4A Revoked EP3031948B1 (de) | 2008-03-12 | 2009-01-20 | Hartstoffbeschichteter körper |
Country Status (13)
Country | Link |
---|---|
US (1) | US8389134B2 (de) |
EP (2) | EP2252721B1 (de) |
JP (1) | JP5863241B2 (de) |
KR (1) | KR20100122918A (de) |
CN (2) | CN103834928B (de) |
BR (1) | BRPI0908924B1 (de) |
CA (1) | CA2717187C (de) |
DE (1) | DE102008013965A1 (de) |
ES (2) | ES2628524T3 (de) |
MX (1) | MX2010009890A (de) |
PL (2) | PL3031948T3 (de) |
RU (1) | RU2491368C2 (de) |
WO (1) | WO2009112115A1 (de) |
Families Citing this family (51)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102009046667B4 (de) * | 2009-11-12 | 2016-01-28 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Beschichtete Körper aus Metall, Hartmetal, Cermet oder Keramik sowie Verfahren zur Beschichtung derartiger Körper |
AT510981B1 (de) * | 2011-03-18 | 2012-08-15 | Boehlerit Gmbh & Co Kg | Beschichteter körper, verwendung desselben und verfahren zu dessen herstellung |
AT510963B1 (de) † | 2011-03-18 | 2012-08-15 | Boehlerit Gmbh & Co Kg | Beschichteter körper und verfahren zu dessen herstellung |
WO2013031915A1 (ja) * | 2011-08-30 | 2013-03-07 | 京セラ株式会社 | 切削工具 |
JP6024981B2 (ja) | 2012-03-09 | 2016-11-16 | 三菱マテリアル株式会社 | 高速断続切削加工で硬質被覆層がすぐれた耐チッピング性を発揮する表面被覆切削工具 |
JP5935479B2 (ja) * | 2012-04-20 | 2016-06-15 | 三菱マテリアル株式会社 | 高速ミーリング切削加工、高速断続切削加工で硬質被覆層がすぐれた耐チッピング性を発揮する表面被覆切削工具 |
JP6044401B2 (ja) * | 2012-04-20 | 2016-12-14 | 三菱マテリアル株式会社 | 高速断続切削加工で硬質被覆層がすぐれた耐チッピング性を発揮する表面被覆切削工具 |
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US9103036B2 (en) | 2013-03-15 | 2015-08-11 | Kennametal Inc. | Hard coatings comprising cubic phase forming compositions |
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US9168664B2 (en) | 2013-08-16 | 2015-10-27 | Kennametal Inc. | Low stress hard coatings and applications thereof |
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CA2922827C (en) * | 2013-08-21 | 2017-01-31 | Tungaloy Corporation | Coated cutting tool |
JP6391045B2 (ja) * | 2014-01-29 | 2018-09-19 | 三菱マテリアル株式会社 | 高速断続切削加工で硬質被覆層がすぐれた耐チッピング性を発揮する表面被覆切削工具 |
DE102014103220A1 (de) | 2014-03-11 | 2015-09-17 | Walter Ag | TiAIN-Schichten mit Lamellenstruktur |
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JP7253153B2 (ja) | 2021-04-30 | 2023-04-06 | 株式会社タンガロイ | 被覆切削工具 |
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2008
- 2008-03-12 DE DE102008013965A patent/DE102008013965A1/de not_active Ceased
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2009
- 2009-01-20 CA CA2717187A patent/CA2717187C/en active Active
- 2009-01-20 CN CN201410055196.4A patent/CN103834928B/zh active Active
- 2009-01-20 BR BRPI0908924-1A patent/BRPI0908924B1/pt active IP Right Grant
- 2009-01-20 MX MX2010009890A patent/MX2010009890A/es active IP Right Grant
- 2009-01-20 RU RU2010141746/02A patent/RU2491368C2/ru active
- 2009-01-20 US US12/866,151 patent/US8389134B2/en active Active
- 2009-01-20 ES ES15185878.4T patent/ES2628524T3/es active Active
- 2009-01-20 KR KR1020107020052A patent/KR20100122918A/ko active Search and Examination
- 2009-01-20 PL PL15185878T patent/PL3031948T3/pl unknown
- 2009-01-20 ES ES09718954.2T patent/ES2561597T3/es active Active
- 2009-01-20 CN CN2009801085019A patent/CN101970717A/zh active Pending
- 2009-01-20 WO PCT/EP2009/000309 patent/WO2009112115A1/de active Application Filing
- 2009-01-20 EP EP09718954.2A patent/EP2252721B1/de active Active
- 2009-01-20 PL PL09718954T patent/PL2252721T3/pl unknown
- 2009-01-20 JP JP2010550049A patent/JP5863241B2/ja active Active
- 2009-01-20 EP EP15185878.4A patent/EP3031948B1/de not_active Revoked
Non-Patent Citations (1)
Title |
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See references of WO2009112115A1 * |
Also Published As
Publication number | Publication date |
---|---|
ES2561597T3 (es) | 2016-02-29 |
CA2717187C (en) | 2015-11-17 |
EP3031948B1 (de) | 2017-03-15 |
RU2010141746A (ru) | 2012-04-20 |
PL2252721T3 (pl) | 2016-02-29 |
BRPI0908924A2 (pt) | 2015-08-18 |
JP2011516722A (ja) | 2011-05-26 |
ES2628524T3 (es) | 2017-08-03 |
CN103834928B (zh) | 2016-11-02 |
PL3031948T3 (pl) | 2017-07-31 |
RU2491368C2 (ru) | 2013-08-27 |
DE102008013965A1 (de) | 2009-09-17 |
EP3031948A1 (de) | 2016-06-15 |
CN103834928A (zh) | 2014-06-04 |
MX2010009890A (es) | 2010-09-30 |
US8389134B2 (en) | 2013-03-05 |
EP2252721B1 (de) | 2015-11-04 |
KR20100122918A (ko) | 2010-11-23 |
US20100323176A1 (en) | 2010-12-23 |
WO2009112115A1 (de) | 2009-09-17 |
BRPI0908924B1 (pt) | 2024-01-23 |
CN101970717A (zh) | 2011-02-09 |
CA2717187A1 (en) | 2009-09-17 |
JP5863241B2 (ja) | 2016-02-16 |
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