EP1736438A3 - Use of complex metal oxides in the autothermal generation of hydrogen - Google Patents
Use of complex metal oxides in the autothermal generation of hydrogen Download PDFInfo
- Publication number
- EP1736438A3 EP1736438A3 EP06012910A EP06012910A EP1736438A3 EP 1736438 A3 EP1736438 A3 EP 1736438A3 EP 06012910 A EP06012910 A EP 06012910A EP 06012910 A EP06012910 A EP 06012910A EP 1736438 A3 EP1736438 A3 EP 1736438A3
- Authority
- EP
- European Patent Office
- Prior art keywords
- complex metal
- metal oxide
- hydrogen
- group
- metal oxides
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
- C01B3/56—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0244—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/042—Purification by adsorption on solids
- C01B2203/0425—In-situ adsorption process during hydrogen production
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/0475—Composition of the impurity the impurity being carbon dioxide
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Catalysts (AREA)
Abstract
(A'xCax'Mgx")x(B'yMny'Fey")yOn
where A' represents at least one element selected from the group consisting of Sr, Ba, a Group 1 element, and an element of the Lanthanide series according to the IUPAC Periodic Table of the Elements; B' represents at least one element selected from the group consisting of Cu, Ni, Co, Cr, and V;
0≤x≤1, 0≤x'≤1, 0≤x"≤1 wherein x + x' + x" = x;
0≤y≤1, 0≤y'≤1, 0≤y"≤1 wherein y + y' + y" = y;
1≤x≤10;
1≤y≤10;
and n represents a value such that the complex metal oxide is rendered electrically neutral. The metal oxide adsorbs carbon dioxide.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US11/165,720 US7438889B2 (en) | 2005-06-24 | 2005-06-24 | Use of complex metal oxides in the autothermal generation of hydrogen |
Publications (3)
Publication Number | Publication Date |
---|---|
EP1736438A2 EP1736438A2 (en) | 2006-12-27 |
EP1736438A3 true EP1736438A3 (en) | 2008-02-27 |
EP1736438B1 EP1736438B1 (en) | 2012-02-08 |
Family
ID=37026959
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP06012910A Not-in-force EP1736438B1 (en) | 2005-06-24 | 2006-06-22 | Use of complex metal oxides in the autothermal generation of hydrogen |
Country Status (6)
Country | Link |
---|---|
US (1) | US7438889B2 (en) |
EP (1) | EP1736438B1 (en) |
CN (1) | CN1982205B (en) |
AT (1) | ATE544729T1 (en) |
CA (1) | CA2550701C (en) |
ES (1) | ES2382202T3 (en) |
Families Citing this family (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7438889B2 (en) | 2005-06-24 | 2008-10-21 | University Of South Carolina | Use of complex metal oxides in the autothermal generation of hydrogen |
US7429373B2 (en) * | 2005-06-24 | 2008-09-30 | Air Products And Chemicals, Inc. | Process for autothermal generation of hydrogen |
US7824655B2 (en) * | 2006-01-25 | 2010-11-02 | Air Products And Chemicals, Inc. | Regeneration of complex metal oxides for the production of hydrogen |
US7591992B2 (en) | 2006-01-25 | 2009-09-22 | Air Products And Chemicals, Inc. | Hydrogen production process with regenerant recycle |
US7951349B2 (en) * | 2006-05-08 | 2011-05-31 | The California Institute Of Technology | Method and system for storing and generating hydrogen |
US7700005B2 (en) * | 2006-12-26 | 2010-04-20 | Saudi Arabian Oil Company | Oil-based thermo-neutral reforming with a multi-component catalyst |
US7695708B2 (en) * | 2007-03-26 | 2010-04-13 | Air Products And Chemicals, Inc. | Catalytic steam reforming with recycle |
US7897128B2 (en) | 2007-04-20 | 2011-03-01 | Air Products And Chemicals, Inc. | Preparation of complex metal oxides |
US20090162268A1 (en) * | 2007-12-19 | 2009-06-25 | Air Products And Chemicals, Inc. | Carbon Dioxide Separation Via Partial Pressure Swing Cyclic Chemical Reaction |
US8038981B2 (en) * | 2008-02-05 | 2011-10-18 | Air Products And Chemicals, Inc. | Hydrogen production using complex metal oxide pellets |
US20100196259A1 (en) * | 2009-02-05 | 2010-08-05 | Air Products And Chemicals, Inc. | CO2-Sorptive Pellets and Uses Thereof |
EA030740B1 (en) * | 2011-07-26 | 2018-09-28 | СТАМИКАРБОН Б.В. ЭКТИНГ АНДЕР ДЗЕ НЕЙМ ОФ ЭмТи ИННОВЕЙШН СЕНТЕР | Process for production of hydrogen rich gas mixtures |
CN103373704B (en) * | 2012-04-12 | 2015-08-12 | 中国石油化工股份有限公司 | The application of a kind of composite metal oxide oxygen carrier in recycle chemistry chain hydrogen production and preparation |
JP5972678B2 (en) * | 2012-06-14 | 2016-08-17 | 三菱化学株式会社 | Synthesis gas production catalyst and synthesis gas production method |
US9303867B2 (en) * | 2012-07-16 | 2016-04-05 | Conocophillips Company | Dual-pressure fixed bed chemical looping process for enhanced oil recovery |
CN105188917B (en) | 2013-05-09 | 2019-04-26 | 沙特基础工业全球技术公司 | Clay mineral loaded catalyst |
US9499403B2 (en) | 2013-07-10 | 2016-11-22 | Saudi Arabian Oil Company | Catalyst and process for thermo-neutral reforming of liquid hydrocarbons |
AU2018249486B2 (en) * | 2017-04-03 | 2022-09-15 | Qatar Foundation For Education, Science And Community Development | System and method for carbon and syngas production |
FR3086282B1 (en) * | 2018-09-20 | 2020-09-25 | Saint Gobain Ct Recherches | BROWNMILLERITE MELTED POLYCRYSTALLINE PRODUCT |
CN109607477B (en) * | 2018-12-07 | 2022-05-06 | 昆明理工大学 | La-Cu-Mn oxygen storage-release material and preparation method and application thereof |
US11827521B2 (en) | 2021-12-14 | 2023-11-28 | Industrial Technology Research Institute | Method for selectively chemically reducing CO2 to form CO |
CN114408864A (en) * | 2021-12-31 | 2022-04-29 | 江苏嘉宇特种装备股份有限公司 | Hydrogen production equipment with automatic control pressure regulation function |
Citations (5)
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WO1999002471A1 (en) * | 1997-07-07 | 1999-01-21 | Mobil Oil Corporation | Process for heat integration of an autothermal reformer and cogeneration power plant |
EP1134187A2 (en) * | 2000-03-17 | 2001-09-19 | SNAMPROGETTI S.p.A. | Process for the production of hydrogen |
US20030150163A1 (en) * | 2002-01-25 | 2003-08-14 | Keiji Murata | Fuel reforming method and system |
US6682838B2 (en) * | 2001-04-18 | 2004-01-27 | Texaco Inc. | Integrated fuel processor, fuel cell stack, and tail gas oxidizer with carbon dioxide removal |
EP1736437A2 (en) * | 2005-06-24 | 2006-12-27 | Air Products and Chemicals, Inc. | Process for autothermal generation of hydrogen |
Family Cites Families (20)
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AU571615B2 (en) * | 1983-12-15 | 1988-04-21 | Bergwerksverband Gmbh | Pressure swing adsorbtion of highly adsorbable components |
EP0411506A2 (en) | 1989-08-02 | 1991-02-06 | Air Products And Chemicals, Inc. | Production of hydrogen, carbon monoxide and mixtures thereof |
US5055441A (en) * | 1990-02-01 | 1991-10-08 | E. I. Du Pont De Nemours And Company | Process for preparation of metal oxides of molybdenum or mlybdenum and tungsten |
US5827496A (en) * | 1992-12-11 | 1998-10-27 | Energy And Environmental Research Corp. | Methods and systems for heat transfer by unmixed combustion |
CN1047103C (en) * | 1994-04-05 | 1999-12-08 | 中国科学院兰州化学物理研究所 | Catalyst for converting methane into synthetic gas and its process |
US6303092B1 (en) | 1995-04-10 | 2001-10-16 | Air Products And Chemicals, Inc. | Process for operating equilibrium controlled reactions |
US6007699A (en) * | 1996-08-21 | 1999-12-28 | Energy And Environmental Research Corporation | Autothermal methods and systems for fuels conversion |
US6238816B1 (en) * | 1996-12-30 | 2001-05-29 | Technology Management, Inc. | Method for steam reforming hydrocarbons using a sulfur-tolerant catalyst |
US6379586B1 (en) * | 1998-10-20 | 2002-04-30 | The Boc Group, Inc. | Hydrocarbon partial oxidation process |
DE19903616A1 (en) * | 1999-01-29 | 2000-08-03 | Basf Ag | Process for the production of nitrogen oxides with a low degree of oxidation |
CA2421157A1 (en) * | 2000-09-05 | 2002-03-14 | Altair Technologies, Inc. | Method for producing mixed metal oxides and metal oxide compounds |
US6506510B1 (en) * | 2000-12-15 | 2003-01-14 | Uop Llc | Hydrogen generation via methane cracking for integrated heat and electricity production using a fuel cell |
US20020179887A1 (en) * | 2001-05-01 | 2002-12-05 | Yongxian Zeng | Supported perovskite-type oxides and methods for preparation thereof |
US6667022B2 (en) * | 2001-08-14 | 2003-12-23 | General Electric Co. | Process for separating synthesis gas into fuel cell quality hydrogen and sequestration ready carbon dioxide |
US6767530B2 (en) * | 2001-12-14 | 2004-07-27 | Praxair Technology, Inc. | Method for producing hydrogen |
US6972301B2 (en) * | 2002-06-06 | 2005-12-06 | Sasol North America Inc. | Process for producing organically modified metal oxides and products thereof |
US7914764B2 (en) * | 2003-02-28 | 2011-03-29 | Exxonmobil Research And Engineering Company | Hydrogen manufacture using pressure swing reforming |
US7267811B2 (en) * | 2003-11-26 | 2007-09-11 | Cabot Corporation | Fuel reformer catalyst and absorbent materials |
US7438889B2 (en) | 2005-06-24 | 2008-10-21 | University Of South Carolina | Use of complex metal oxides in the autothermal generation of hydrogen |
US7824655B2 (en) * | 2006-01-25 | 2010-11-02 | Air Products And Chemicals, Inc. | Regeneration of complex metal oxides for the production of hydrogen |
-
2005
- 2005-06-24 US US11/165,720 patent/US7438889B2/en active Active
-
2006
- 2006-06-19 CA CA2550701A patent/CA2550701C/en not_active Expired - Fee Related
- 2006-06-22 EP EP06012910A patent/EP1736438B1/en not_active Not-in-force
- 2006-06-22 AT AT06012910T patent/ATE544729T1/en active
- 2006-06-22 ES ES06012910T patent/ES2382202T3/en active Active
- 2006-06-23 CN CN2006101719703A patent/CN1982205B/en not_active Expired - Fee Related
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1999002471A1 (en) * | 1997-07-07 | 1999-01-21 | Mobil Oil Corporation | Process for heat integration of an autothermal reformer and cogeneration power plant |
EP1134187A2 (en) * | 2000-03-17 | 2001-09-19 | SNAMPROGETTI S.p.A. | Process for the production of hydrogen |
US6682838B2 (en) * | 2001-04-18 | 2004-01-27 | Texaco Inc. | Integrated fuel processor, fuel cell stack, and tail gas oxidizer with carbon dioxide removal |
US20030150163A1 (en) * | 2002-01-25 | 2003-08-14 | Keiji Murata | Fuel reforming method and system |
EP1736437A2 (en) * | 2005-06-24 | 2006-12-27 | Air Products and Chemicals, Inc. | Process for autothermal generation of hydrogen |
Non-Patent Citations (2)
Title |
---|
BALASUBRAMANIAN B ET AL: "Hydrogen from methane in a single-step process", CHEMICAL ENGINEERING SCIENCE, OXFORD, GB, vol. 54, 1999, pages 3543 - 3552, XP002212892, ISSN: 0009-2509 * |
J. HUTON ET AL.: "Sorption Enhanced Reaction Process (SERP) for the production of hydrogen", PROCEEDINGS OF THE 2000 HYDROGEN PROGRAM REVIEW NREL/CP-570-28890, 2000, XP008087160 * |
Also Published As
Publication number | Publication date |
---|---|
CA2550701A1 (en) | 2006-12-24 |
US20060292066A1 (en) | 2006-12-28 |
CA2550701C (en) | 2010-07-06 |
US7438889B2 (en) | 2008-10-21 |
CN1982205B (en) | 2013-03-13 |
EP1736438B1 (en) | 2012-02-08 |
ATE544729T1 (en) | 2012-02-15 |
CN1982205A (en) | 2007-06-20 |
EP1736438A2 (en) | 2006-12-27 |
ES2382202T3 (en) | 2012-06-06 |
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