EP1442109A1 - Polymere für waschanwendungen - Google Patents
Polymere für waschanwendungenInfo
- Publication number
- EP1442109A1 EP1442109A1 EP02774634A EP02774634A EP1442109A1 EP 1442109 A1 EP1442109 A1 EP 1442109A1 EP 02774634 A EP02774634 A EP 02774634A EP 02774634 A EP02774634 A EP 02774634A EP 1442109 A1 EP1442109 A1 EP 1442109A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- alkyl
- group
- groups
- use according
- polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/226—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin esterified
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0036—Soil deposition preventing compositions; Antiredeposition agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/228—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin with phosphorus- or sulfur-containing groups
Definitions
- the present invention relates to substituted polysaccharides which are used in laundry cleaning products, for instance, for incorporation in products for dosing in the wash and/or rinse. These polymers are intended for, but not limited to, soil release benefits in such products.
- soil release polymer is used in the art to cover polymeric materials which assist release of soil from fabrics, e.g. cotton or polyester based fabrics. For example, it is used in relation to polymers which assist release of soil direct from fibres. It is also used to refer to polymers which modify the fibres so that dirt adheres to the polymer-modified fibres rather than to the fibre material itself. Then, when the fabric is washed the next time, the dirt is more easily removed than if it was adhering the fibres. Although not wishing to be bound by any particular theory or explanation, the inventors believe that the soil release polymers utilised in the present invention probably exert their effect mainly by the latter mechanism. The compounds utilised by the present invention have been found, dependent upon the structure of the compound in question, to deliver a soil release, fabric care and/or other laundry cleaning benefit .
- a benefit agent onto a substrate such as a fabric
- a substrate such as a fabric
- typical "benefit agents” include fabric softeners and conditioners, soil release polymers, sunscreens; and the like.
- Deposition of a benefit agent is used, for example, in fabric treatment processes such as fabric softening to impart desirable properties to the fabric substrate.
- the deposition of the benefit agent has had to rely upon the attractive forces between the oppositely charged substrate and the benefit agent.
- this requires the addition of benefit agents during the rinsing step of a treatment process so as to avoid adverse effects from other charged chemical species present in the treatment compositions.
- cationic fabric conditioners are incompatible with anionic surfactants in laundry washing compositions .
- Such adverse charge considerations can place severe limitations upon the inclusion of benefit agents in compositions where an active component thereof is of an opposite charge to that of the benefit agent.
- cotton is negatively charged and thus requires a positively charged benefit agent in order for the benefit agent to be substantive to the cotton, i.e. to have an affinity for the cotton so as to absorb onto it.
- the substantivity of the benefit agent is reduced and/or the deposition rate of the material is reduced because of the presence of incompatible charged species in the compositions.
- the compounds used by the present invention for soil-release and/or other benefits are substituted polysaccharide structures, especially substituted cellulosic structures.
- S-A-4 235 735 discloses cellulose acetates with a defined degree of substitution as anti-redeposition agents in laundry products.
- Cellulosic esters are also known for use in non-laundry applications, as described in O-A-91/16359 and GB-A-1 041 020.
- cellulose based materials adhere to cotton fibres.
- WO 00/18861 and WO 00/18862 disclose cellulosic compounds having a benefit agent attached, so that the benefit agent will be attached to the fibre. See also WO 99/14925.
- polysaccharide, especially cellulose, based materials to adhere has not been fully investigated, and a need exists to find polysaccharide based materials that are of commercial significance.
- a first aspect of the present invention provides use of a compound for promoting soil release during laundering of a textile fabric, the compound being a polymer having the general formula
- each SU represents a sugar unit in a polysaccharide backbone
- a represents the number of unsubstituted sugar units as a percentage of the total number of sugar units and is in the range from 0 to 99.9%, preferably 65 to 99%, more preferably 80 to 99%;
- b represents the number of substituted sugar units as a percentage of the total number of sugar units and is in the range from 0.1 to 100%, preferably 1 to 35%, more preferably 1 to 20%;
- n represents the degree of substitution per sugar unit and is from 1 to 3;
- L represents an ester or ether linkage
- R 1 represents a substituted alkyl group, preferably a hydroxyalkyl, carboxyalkyl or sulfoalkyl group or a salt thereof .
- This aspect of the present invention may also be expressed as a method of promoting soil release during laundering of a textile fabric, the method comprising contacting the fabric with a polymer as defined above, preferably in the form of a laundry cleaning composition comprising said polymer, and most preferably in the form of an aqueous dispersion or solution of said composition, and subsequently washing the fabric after wear or use of the fabric.
- this aspect may be expressed as use of a compound in the manufacture of a laundry cleaning composition for effecting soil release from a laundry item, the compound being a polymer as defined above.
- a second aspect of the invention provides a polymer as defined above for deposition onto a fabric during a laundry cleaning process.
- the second aspect of the invention may also be expressed as a method of depositing a benefit agent onto a fabric, the method comprising applying a polymer or a composition as defined above to the fabric .
- cleaning or “laundering” mean “washing and/or rinsing” .
- group -L-R 1 is a relatively small substituent of relatively low molecular weight compared to many of the groups which have been used as substituents for polysaccharides in the prior art .
- alkyl refers to a branched or unbranched saturated hydrocarbon group which may contain from 1 to 12 carbon atoms, such as methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, t-butyl, octyl, decyl etc. More preferably, an alkyl group contains from 1 to 6, preferably 1 to 4 carbon atoms. "Substituted alkyl” refers to alkyl substituted with one or more substituent groups. Preferably, alkyl and substituted alkyl groups are unbranched.
- alkenyl is a branched or unbranched unsaturated hydrocarbon containing 1 to 12, preferably 1 to 6 and especially 1 to 4 carbon atoms.
- alkenyl and substituted alkenyl groups are unbranched.
- a halogen atom may be a fluorine, chlorine, bromine or iodine atom and any group which contains a halo moiety, such as a haloalkyl group, may thus contain any one or more of these halogen atoms .
- the term "degree of substitution” refers to substitution of the functional groups on the repeating sugar unit.
- DS refers to substitution of the three hydroxyl groups on the repeating anhydroglucose unit .
- the maximum degree of substitution is 3.
- DS values do not generally relate to the uniformity of substitution of chemical groups along the polysaccharide molecule and are not related to the molecular weight of the polysaccharide backbone .
- the average degree of substitution groups is preferably from 0.1 to 3 (eg. from 0.3 to 3), more preferably from 0.1 to 1 (eg. from 0.3 to 1) •
- polysaccharides includes natural polysaccharides, synthetic polysaccharides, polysaccharide derivatives and modified polysaccharides.
- Suitable polysaccharides for use in preparing the compounds of the present invention include, but are not limited to, gums, arabinans, galactans, seeds and mixtures thereof as well as cellulose and derivatives thereof.
- Suitable polysaccharides that are useful in the present invention include polysaccharides with a degree of polymerisation (DP) over 40, preferably from about 50 to about 100,000, more preferably from about 500 to about 50,000.
- DP degree of polymerisation
- Constituent saccharides preferably include, but are not limited to, one or more of the following saccharides: isomaltose, isomaltotriose, isomaltotetraose, isomaltooligosaccharide, fructooligosaccharide, levooligosaccharides, galactooligosaccharide, xylooligosaccharide, gentiooligosaccharides, disaccharides, glucose, fructose, galactose, xylose, mannose, sorbose, arabinose, rhamnose, fucose, maltose, sucrose, lactose, maltulose, ribose, lyxose, allose, altrose, gulose, idose, talose, trehalose, nigerose, kojibiose, lactulose, oligosaccharides, maltooligosaccharides, trisaccharides,
- the polysaccharides can be extracted from plants, produced by organisms, such as bacteria, fungi, prokaryotes, eukaryotes, extracted from animal and/or humans.
- xanthan gum can be produced by Xanthomonas campestris, gellan by Sphingomonas paucimobilis, xyloglucan can be extracted from tamarind seed.
- the polysaccharides can be linear, or branched in a variety of ways, such as 1-2, 1-3, 1-4, 1-6, 2-3 and mixtures thereof. Many naturally occurring polysaccharides have at least some degree of branching, or at any rate, at least some saccharide rings are in the form of pendant side groups on a main polysaccharide backbone. It is desirable that the polysaccharides of the present invention have a molecular weight in the range of from about 10,000 to about 10,000,000, more preferably from about 50,000 to about 1,000,000, most preferably from about 50,000 to about 500, 000.
- the polysaccharide is selected from the group consisting of: tamarind gum (preferably consisting of xyloglucan polymers) , guar gum, locust bean gum (preferably consisting of galactomannan polymers) , and other industrial gums and polymers, which include, but are not limited to,
- Polysaccharides can be used which have an a- or /?-linked backbone. However, more preferred polysaccharides have a ⁇ - linked backbone, preferably a / S-1,4 linked backbone. It is preferred that the ⁇ - 1 , 4-linked polysaccharide is cellulose; a cellulose derivative, particularly cellulose sulphate, cellulose acetate, sulphoethyl cellulose, cyanoethyl cellulose, methyl cellulose, ethyl cellulose, carboxymethylcellulose, hydroxyethylcellulose or hydroxypropylcellulose; a xyloglucan, particularly one derived from Tamarind seed gum; a glucomannan, particularly Konjac glucomannan; a galactomannan, particularly Locust Bean gum and Guar gum; a side chain branched galactomannan, particularly Xanthan gum; chitosan or a chitosan salt.
- the natural polysaccharides can be modified with amines (primary , secondary, tertiary), amides, esters, ethers, urethanes, alcohols, carboxylic acids, tosylates, sulfonates, sulfates, nitrates, phosphates and mixtures thereof. Such a modification can take place in position 2, 3 and/or 6 of the saccharide unit.
- modified or derivatised polysaccharides can be included in the compositions of the present invention in addition to the natural polysaccharides .
- Nonlimiting examples of such modified polysaccharides include: carboxyl and hydroxymethyl substitutions (e.g. glucuronic acid instead of glucose) ; amino polysaccharides
- polysaccharides containing silicone moieties are commercially available from Carbomer and include, but are not limited to, amino alginates, such as hexanediamine alginate, amine functionalised cellulose-like O-methyl- (N-l, 12- dodecanediamine) cellulose, biotin heparin, carboxymethylated dextran, guar polycarboxylic acid, carboxymethylated locust bean gum, carboxymethylated xanthan, chitosan phosphate, chitosan phosphate sulfate, diethylaminoethyl dextran, dodecylamide alginate, sialic acid, glucuronic acid, galacturonic acid, mannuronic acid, guluronic acid, N-acetylgluosamine, N-acetylgalactosamine, and mixtures thereof .
- amino alginates such as hexanediamine alginate, amine functionalised cellulose-like O-methyl- (
- Especially preferred polysaccharides include cellulose, ether, ester and urethane derivatives of cellulose, particularly cellulose monoacetate, xyloglucans and galactomannans, particularly Locust Bean gum.
- the polysaccharide has a total number of sugar units from 10 to 7000, although this figure will be dependent on the type of polysaccharide chosen, at least to some extent.
- the total number of sugar units is preferably from 50 to 1000, more preferably 50 to 750 and especially 200 to 300.
- the preferred molecular weight of such polysaccharides is from 10 000 to 150 000.
- the total number of sugar units is from 10 to 200, preferably 100 to 150.
- the preferred molecular weight is from 10 000 to 20 000.
- the total number of sugar units is preferably from 50 to 7000.
- the preferred molecular weight is from 10 000 to 1000 000.
- the total number of sugar units is preferably from 1000 to 3000.
- the preferred molecular weight is from 250 000 to 600 000.
- the polysaccharide can be linear, like in hydroxyalkyl cellulose, it can have an alternating repeat like in carrageenan, it can have an interrupted repeat like in pectin, it can be a block copolymer like in alginate, it can be branched like in dextran, or it can have a complex repeat like in xanthan. Descriptions of the polysaccharides are given in "An introduction to Polysaccharide Biotechnology", by M. Tombs and S. E. Harding, T.J. Press 1998.
- the polymers utilised in the invention are polysaccharides in which at least one sugar unit of the polysaccharide has been substituted by a group of the general formula
- each SU represents a sugar unit in a polysaccharide backbone
- a represents the number of unsubstituted sugar units as a percentage of the total number of sugar units and is in the range from 0 to 99.9%, preferably 65 to 99%, more preferably 80 to 99% ;
- b represents the number of substituted sugar units as a percentage of the total number of sugar units and is in the range from 0.1 to 100%, preferably 1 to 35%, more preferably 1 to 20%;
- L represents an ester or ether linkage
- R" represents a substituted alkyl group, preferably a hydroxyalkyl, carboxyalkyl or sulfoalkyl group or a salt thereof .
- L represents a group -0-CO- or -0- .
- R 1 is an alkyl group substituted by a group selected from -OH, -C0-OR 2 and -S0 3 -R 2 where R 2 represents a hydrogen atom or an alkali metal, preferably a sodium or potassium, atom.
- R 2 represents a hydrogen atom or an alkali metal, preferably a sodium or potassium, atom.
- the alkyl group is a C ⁇ - 6 alkyl, more preferably a C ⁇ _ 4 alkyl, group.
- Ri represents a hydroxy C ⁇ _ 4 alkyl, preferably a hydroxymethyl group, a carboxy C ⁇ _ 6 alkyl, preferably a carboxy C ⁇ _ 4 alkyl, group or a sulfo C 2 _ 4 alkyl, preferably a sulfoethyl, group or a sodium salt thereof.
- -L-R 1 represents a group selected from -0-CH 2 0H, -0-CH 2 CH 2 S0 3 H, -0-CH 2 -C0 2 H and -0-CO-CH 2 CH 2 C0 2 H and sodium salts thereof.
- polysaccharide backbone in the polymers is ⁇ -linked, preferably ⁇ -1, -linked.
- the polysaccharide backbone is selected from the group consisting of cellulose, cellulose derivatives (preferably cellulose sulphate, cellulose acetate, sulphoethyl cellulose, cyanoethyl cellulose, methyl cellulose, ethyl cellulose, carboxymethylcellulose, hydroxyethylcellulose or hydroxypropylcellulose) , xyloglucans (preferably those derived from Tamarind seed gum) , glucomannans (preferably Konjac glucomannan) , galactomannans (preferably Locust Bean gum, Guar gum and Xanthan gum), chitosan and chitosan salts. It is especially preferred that the polysaccharide backbone is Locust Bean gum or xyloglucan.
- the polymers have the general formula :
- L and R 1 are as defined above and at least one or more R groups are independently selected from groups of formulae : -
- each R 8 is independently selected from C ⁇ _ 2 o
- each R 9 is independently selected from hydrogen and groups R 8 as hereinbefore defined;
- R is a bond or is selected from C ⁇ _ 4 alkylene, C 2 - 4 alkenylene and C 5 _ 7 arylene (e.g. phenylene) groups, the carbon atoms in any of these being optionally substituted by one or more substituents independently selected from C ⁇ - ⁇ 2 (preferably C ⁇ _ ) alkoxy, vinyl, hydroxyl , halo and amine
- each R 11 is independently selected from hydrogen, counter cations such as alkali metal (preferably Na) or 2 Ca or 2 Mg, and groups R 8 as hereinbefore defined;
- R is selected from C ⁇ _ 2 o (preferably C_. 6 ) alkyl, C 2 . 2 o (preferably C 2 - 6 ) alkenyl (e.g. vinyl) and C 5 - 7 aryl (e.g. phenyl) , any of which is optionally substituted by one or more substituents independently selected from C ⁇ _ 4 alkyl, C ⁇ _ ⁇ 2 (preferably C ⁇ _ 4 ) alkoxy, hydroxyl, carboxyl, cyano, sulfonato, vinyl and phenyl groups;
- x is from 1 to 3;
- any remaining R groups being selected from hydrogen and ether substituents.
- R 12 is a methyl, ethyl, phenyl , hydroxyethyl , hydroxypropyl , carboxymethyl , sulphoethyl or cyanoethyl group.
- R groups may optionally have one or more structures, for example as hereinbefore described.
- one or more R groups may simply be hydrogen or an alkyl group .
- Preferred groups may for example be independently selected from one or more of acetate, propanoate, trifluoroacetate, 2- (2-hydroxy-l-oxopropoxy) propanoate, lactate, glycolate, pyruvate, crotonate, isovalerate cinna ate, formate, salicylate, carbamate, methylcarbamate, benzoate, gluconate, methanesulphonate, toluene, sulphonate, groups and hemiester groups of fumaric, malonic, itaconic, oxalic, maleic, succinic, tartaric, aspartic, glutamic, and malic acids.
- cellulose monoacetate refers to a molecule that has acetate esters in a degree of substitution of about 1.1 or less, preferably about 1.1 to about 0.5.
- Cellulose triacetate refers to a molecule that has acetate esters in a degree of substitution of about 2.7 to 3.
- Cellulose esters of hydroxyacids can be obtained using the acid anhydride in acetic acid solution at 20-30°C and in any case below 50°C. When the product has dissolved the liquid is poured into water. Tri-esters can be converted to secondary products as with the triacetate. Glycollic and lactic ester are most common. Cellulose glycollate may also be obtained from cellulose chloracetate (GB-A-320 842) by treating 100 parts with 32 parts of NaOH in alcohol added in small portions.
- An alternative method of preparing cellulose esters consists in the partial displacement of the acid radical in a cellulose ester by treatment with another acid of higher ionisation constant (FR-A-702 116) .
- the ester is heated at about 100°C with the acid which, preferably, should be a solvent for the ester.
- the acid which, preferably, should be a solvent for the ester.
- cellulose acetate- oxalate, tartrate, maleate, pyruvate, salicylate and phenylglycollate have been obtained, and from cellulose tribenzoate a cellulose benzoate-pyruvate .
- a cellulose acetate-lactate or acetate-glycollate could be made in this way also.
- cellulose acetate (10 g.) in dioxan (75 ml.) containing oxalic acid (10 g.) is heated at 100°C for 2 hours under reflux.
- esters are prepared by variations of this process.
- a simple ester of cellulose e.g. the acetate, is dissolved in a mixture of two (or three) organic acids, each of which has an ionisation constant greater than that of acetic acid
- a cellulose acetate-lactate-pyruvate is prepared from cellulose acetate, 40 per cent, acetyl (100 g.), in a bath of 125 ml. pyruvic acid and 125 ml. of 85 per cent, lactic acid by heating at 100 °C for 18 hours. The product is soluble in water and is precipitated and washed with ether- acetone. M.p. 230-250°C.
- m is from 1 to 2, preferably 1.
- polymers used in the present invention may be synthesised by a variety of routes which are well known to those skilled in the art of polymer chemistry.
- carboxyalkyl ether-linked polymers can be made by reacting a polysaccharide with a suitable haloalkanoic acid
- carboxyalkyl ester-linked polymers can be made by reacting a polysaccharide with a suitable anhydride, such as succinic anhydride
- sulfoalkyl ether-linked polymers can be made by reacting a polysaccharide with a suitable alkenyl sulphonic acid.
- the substituted polysaccharide according to the first aspect of the present invention may be incorporated into compositions containing only a diluent (which may comprise solid and/or liquid) and/or also comprising an active ingredient.
- the compound is typically included in said compositions at levels of from 0.01% to 25% by weight, preferably from 0.05% to 15%, more preferably from 0.1% to 10%, especially from 0.1% to 5% and most preferably from 0.5% to 3%.
- the active ingredient in the compositions is preferably a surface active agent or a fabric conditioning agent. More than one active ingredient may be included. For some applications a mixture of active ingredients may be used.
- compositions of the invention may be in any physical form e.g. a solid such as a powder or granules, a tablet, a solid bar, a paste, gel or liquid, especially, an aqueous based liquid.
- a solid such as a powder or granules, a tablet, a solid bar, a paste, gel or liquid, especially, an aqueous based liquid.
- the compositions may be used in laundry compositions, especially in liquid, powder or tablet laundry composition.
- compositions of the present invention are preferably laundry compositions, especially main wash (fabric washing) compositions or rinse-added softening compositions.
- the main wash compositions may include a fabric softening agent and rinse-added fabric softening compositions may include surface-active compounds, particularly non-ionic surface- active compounds, if appropriate.
- the detergent compositions of the invention may contain a surface-active compound (surfactant) which may be chosen from soap and non-soap anionic, cationic, non-ionic, amphoteric and zwitterionic surface-active compounds and mixtures thereof.
- surfactant may be chosen from soap and non-soap anionic, cationic, non-ionic, amphoteric and zwitterionic surface-active compounds and mixtures thereof.
- surface-active compound surfactant
- surfactant may be chosen from soap and non-soap anionic, cationic, non-ionic, amphoteric and zwitterionic surface-active compounds and mixtures thereof.
- the preferred detergent-active compounds that can be used are soaps and synthetic non-soap anionic and non-ionic compounds.
- compositions of the invention may contain linear alkylbenzene sulphonate, particularly linear alkylbenzene sulphonates having an alkyl chain length of C 8 -C ⁇ 5 . It is preferred if the level of linear alkylbenzene sulphonate is from 0 wt% to 30 wt%, more preferably 1 wt% to 25 wt%, most preferably from 2 wt% to 15 wt%.
- compositions of the invention may contain other anionic surfactants in amounts additional to the percentages quoted above.
- Suitable anionic surfactants are well-known to those skilled in the art. Examples include primary and secondary alkyl sulphates, particularly C 8 -C 15 primary alkyl sulphates; alkyl ether sulphates; olefin sulphonates; alkyl xylene sulphonates; dialkyl sulphosuccinates; and fatty acid ester sulphonates. Sodium salts are generally preferred.
- the compositions of the invention may also contain non-ionic surfactant.
- Nonionic surfactants that may be used include the primary and secondary alcohol ethoxylates, especially the C 8 -C 2 o aliphatic alcohols ethoxylated with an average of from 1 to 20 moles of ethylene oxide per mole of alcohol, and more especially the C ⁇ 0 -C ⁇ 5 primary and secondary aliphatic alcohols ethoxylated with an average of from 1 to 10 moles of ethylene oxide per mole of alcohol .
- Non-ethoxylated nonionic surfactants include alkylpolyglycosides, glycerol monoethers, and polyhydroxyamides (glucamide) .
- the level of non-ionic surfactant is from 0 wt% to 30 wt%, preferably from 1 wt% to 25 wt%, most preferably from 2 wt% to 15 wt%.
- any conventional fabric conditioning agent may be used in the compositions of the present invention.
- the conditioning agents may be cationic or non-ionic. If the fabric conditioning compound is to be employed in a main wash detergent composition the compound will typically be nonionic. For use in the rinse phase, typically they will be cationic. They may for example be used in amounts from 0.5% to 35%, preferably from 1% to 30% more preferably from 3% to 25% by weight of the composition.
- the fabric conditioning agent (s) have two long chain alkyl or alkenyl chains each having an average chain length greater than or equal to C 1S . Most preferably at least 50% of the long chain alkyl or alkenyl groups have a chain length of C ⁇ 8 or above. It is preferred if the long chain alkyl or alkenyl groups of the fabric conditioning agents are predominantly linear.
- the fabric conditioning agents are preferably compounds that provide excellent softening, and are characterised by a chain melting L ⁇ to L ⁇ transition temperature greater than 25°C, preferably greater than 35°C, most preferably greater than 45°C.
- This L ⁇ to L ⁇ transition can be measured by DSC as defined in " Handbook of Lipid Bilayers, D Marsh, CRC Press, Boca Raton, Florida, 1990 (pages 137 and 337) .
- Substantially insoluble fabric conditioning compounds in the context of this invention are defined as fabric conditioning compounds having a solubility less than 1 x 10 "3 wt % in deminerailised water at 20°C.
- the fabric softening compounds have a solubility less than 1 x 10 ⁇ 4 wt %, most preferably less than 1 x 10 "8 to 1 x 10 " ⁇ .
- Preferred cationic fabric softening agents comprise a substantially water insoluble quaternary ammonium material comprising a single alkyl or alkenyl long chain having an average chain length greater than or equal to C 2 o or, more preferably, a compound comprising a polar head group and two alkyl or alkenyl chains having an average chain length greater than or equal to C 14 .
- the cationic fabric softening agent is a quaternary ammonium material or a quaternary ammonium material containing at least one ester group.
- the quaternary ammonium compounds containing at least one ester group are referred to herein as ester-linked quaternary ammonium compounds .
- ester-linked quaternary ammonium compounds As used in the context of the quarternary ammonium cationic fabric softening agents, the term 'ester group', includes an ester group which is a linking group in the molecule.
- ester-linked quaternary ammonium compounds it is preferred for the ester-linked quaternary ammonium compounds to contain two or more ester groups .
- the ester group (s) is a linking group between the nitrogen atom and an alkyl group.
- the ester groups (s) are preferably attached to the nitrogen atom via another hydrocarbyl group .
- quaternary ammonium compounds containing at least one ester group, preferably two, wherein at least one higher molecular weight group containing at least one ester group and two or three lower molecular weight groups are linked to a common nitrogen atom to produce a cation and wherein the electrically balancing anion is a halide, acetate or lower alkosulphate ion, such as chloride or methosulphate .
- the higher molecular weight substituent on the nitrogen is preferably a higher alkyl group, containing 12 to 28, preferably 12 to 22, e.g.
- the lower molecular weight substituents are preferably lower alkyl of 1 to 4 carbon atoms, such as methyl or ethyl, or substituted lower alkyl.
- One or more of the said lower molecular weight substituents may include an aryl moiety or may be replaced by an aryl, such as benzyl, phenyl or other suitable substituents.
- the quaternary ammonium material is a compound having two C 12 -C 22 alkyl or alkenyl groups connected to a quaternary ammonium head group via at least one ester link, preferably two ester links or a compound comprising a single long chain with an average chain length equal to or greater than C 2 o ⁇
- the quaternary ammonium material comprises a compound having two long chain alkyl or alkenyl chains with an average chain length equal to or greater than C i4 .
- each chain has an average chain length equal to or greater than C 16 .
- Most preferably at least 50% of each long chain alkyl or alkenyl group has a chain length of Cis . It is preferred if the long chain alkyl or alkenyl groups are predominantly linear.
- ester-linked quaternary ammonium material that can be used in laundry rinse compositions according to the invention is represented by the formula (A) :
- T is -O-C- or -C-O- ; each R 20 group is independently selected from C ⁇ _ 4 alkyl, hydroxyalkyl or C 2 - alkenyl groups; and wherein each R 21 group is independently selected from C 8 _ 28 alkyl or alkenyl groups;
- Y " is any suitable counter-ion, i.e. a halide, acetate or lower alkosulphate ion, such as chloride or methosulphate;
- w is an integer from 1-5 or is 0; and y is an integer from 1-5.
- each R group is methyl and w is 1 or 2.
- the quaternary ammonium material is biologically degradable.
- Preferred materials of this class such as 1,2 bis [hardened tallowoyloxy] -3-trimethylammonium propane chloride and their method of preparation are, for example, described in US-A-4 137 180.
- these materials comprise small amounts of the corresponding monoester as described in US-A-4 137 180 for example 1-hardened tallowoyloxy-2 -hydroxy-3- trimethylammonium propane chloride.
- Another class of preferred ester-linked quaternary ammonium materials for use in laundry rinse compositions according to the invention can be represented by the formula:
- T is -O-C- or -C-O- ;
- R 20 , R 21 , w, and Y " are as defined above.
- di- (tallowyloxyethyl) - dimethyl ammonium chloride available from Hoechst, is the most preferred.
- Di- (hardened tallowyloxyethyl) dimethyl ammonium chloride, ex Hoechst and di- (tallowyloxyethyl) - methyl hydroxyethyl methosulphate are also preferred.
- Another preferred class of quaternary ammonium cationic fabric softening agent is defined by formula (C) : -
- R 20 , R 21 and Y " are as hereinbefore defined.
- a preferred material of formula (C) is di-hardened tallow- diethyl ammonium chloride, sold under the Trademark Arquad 2HT.
- the optionally ester-linked quaternary ammonium material may contain optional additional components, as known in the art, in particular, low molecular weight solvents, for instance isopropanol and/or ethanol, and co-actives such as nonionic softeners, for example fatty acid or sorbitan esters.
- low molecular weight solvents for instance isopropanol and/or ethanol
- co-actives such as nonionic softeners, for example fatty acid or sorbitan esters.
- compositions of the invention when used as main wash fabric washing compositions, will generally also contain one or more detergency builders.
- the total amount of detergency builder in the compositions will typically range from 5 to 80 wt%, preferably from 10 to 60 wt%.
- Cationic surfactants which can be used in main-wash compositions for fabrics.
- Cationic surfactants that may be used include quaternary ammonium salts of the general formula R ⁇ R 2 R 3 R 4 N + X " wherein the R groups are long or short hydrocarbon chains, typically alkyl, hydroxyalkyl or ethoxylated alkyl groups, and X is a counter-ion (for example, compounds in which R_ is a C 8 -C 2 2 alkyl group, preferably a C 8 -C ⁇ 0 or C ⁇ 2 -C ⁇ alkyl group, R 2 is a methyl group, and R 3 and R 4 , which may be the same or different, are methyl or hydroxyethyl groups) ; and cationic esters (for example, choline esters) .
- surfactant surface-active compound
- amount present will depend on the intended use of the detergent composition.
- surfactant systems may be chosen, as is well known to the skilled formulator, for handwashing products and for products intended for use in different types of washing machine .
- the total amount of surfactant present will also depend on the intended end use and may be as high as 60 wt%, for example, in a composition for washing fabrics by hand. In compositions for machine washing of fabrics, an amount of from 5 to 40 wt% is generally appropriate. Typically the compositions will comprise at least 2 wt% surfactant e.g. 2- 60%, preferably 15-40% most preferably 25-35%.
- Detergent compositions suitable for use in most automatic fabric washing machines generally contain anionic non-soap surfactant, or non-ionic surfactant, or combinations of the two in any suitable ratio, optionally together with soap.
- compositions of the invention when used as main wash fabric washing compositions, will generally also contain one or more detergency builders.
- the total amount of detergency builder in the compositions will typically range from 5 to 80 wt%, preferably from 10 to 60 wt%.
- Inorganic builders that may be present include sodium carbonate, if desired in combination with a crystallisation seed for calcium carbonate, as disclosed in GB 1 437 950 (Unilever) ; crystalline and amorphous aluminosilicates, for example, zeolites as disclosed in GB 1 473 201 (Henkel) , amorphous aluminosilicates as disclosed in GB 1 473 202
- Inorganic phosphate builders for example, sodium orthophosphate, pyrophosphate and tripolyphosphate are also suitable for use with this invention.
- compositions of the invention preferably contain an alkali metal, preferably sodium, aluminosilicate builder.
- Sodium aluminosilicates may generally be incorporated in amounts of from 10 to 70% by weight (anhydrous basis) , preferably from 25 to 50 wt%.
- the alkali metal aluminosilicate may be either crystalline or amorphous or mixtures thereof, having the general formula: 0.8-1.5 Na 2 0. A1 2 0 3 . 0.8-6 Si0 2
- the preferred sodium aluminosilicates contain 1.5-3.5 Si0 2 units (in the formula above) . Both the amorphous and the crystalline materials can be prepared readily by reaction between sodium silicate and sodium aluminate, as amply described in the literature. Suitable crystalline sodium aluminosilicate ion-exchange detergency builders are described, for example, in GB 1 429 143 (Procter & Gamble) .
- the preferred sodium aluminosilicates of this type are the well-known commercially available zeolites A and X, and mixtures thereof .
- the zeolite may be the commercially available zeolite 4A now widely used in laundry detergent powders. However, according to a preferred embodiment of the invention, the zeolite 32 -
- zeolite MAP maximum aluminium zeolite P as described and claimed in EP 384 070A (Unilever) .
- Zeolite MAP is defined as an alkali metal aluminosilicate of the zeolite P type having a silicon to aluminium ratio not exceeding 1.33, preferably within the range of from 0.90 to 1.33, and more preferably within the range of from 0.90 to 1.20.
- zeolite MAP having a silicon to aluminium ratio not exceeding 1.07, more preferably about 1.00.
- the calcium binding capacity of zeolite MAP is generally at least 150 mg CaO per g of anhydrous material.
- Organic builders that may be present include polycarboxylate polymers such as polyacrylates, acrylic/maleic copolymers, and acrylic phosphinates; monomeric polycarboxylates such as citrates, gluconates, oxydisuccinates, glycerol mono-, di and trisuccinates, carboxymethyloxy succinates, carboxymethyloxymalonates, dipicolinates, hydroxyethyliminodiacetates, alkyl- and alkenylmalonates and succinates; and sulphonated fatty acid salts. This list is not intended to be exhaustive.
- polycarboxylate polymers such as polyacrylates, acrylic/maleic copolymers, and acrylic phosphinates
- monomeric polycarboxylates such as citrates, gluconates, oxydisuccinates, glycerol mono-, di and trisuccinates, carboxymethyloxy succinates, carboxymethyloxymalonates, dipicolinates, hydroxyethy
- Especially preferred organic builders are citrates, suitably used in amounts of from 5 to 30 wt%, preferably from 10 to 25 wt%; and acrylic polymers, more especially acrylic/maleic copolymers, suitably used in amounts of from 0.5 to 15 wt%, preferably from 1 to 10 wt%.
- Builders both inorganic and organic, are preferably present in alkali metal salt, especially sodium salt, form. 33
- compositions according to the invention may also suitably contain a bleach system.
- Fabric washing compositions may desirably contain peroxy bleach compounds, for example, inorganic persalts or organic peroxyacids, capable of yielding hydrogen peroxide in aqueous solution.
- Suitable peroxy bleach compounds include organic peroxides such as urea peroxide, and inorganic persalts such as the alkali metal perborates, percarbonates, perphosphates, persilicates and persulphates .
- organic peroxides such as urea peroxide
- inorganic persalts such as the alkali metal perborates, percarbonates, perphosphates, persilicates and persulphates .
- Preferred inorganic persalts are sodium perborate monohydrate and tetrahydrate, and sodium percarbonate .
- sodium percarbonate having a protective coating against destabilisation by moisture Especially preferred is sodium percarbonate having a protective coating against destabilisation by moisture.
- Sodium percarbonate having a protective coating comprising sodium metaborate and sodium silicate is disclosed in GB 2 123 044B (Kao) .
- the peroxy bleach compound is suitably present in an amount of from 0.1 to 35 wt%, preferably from 0.5 to 25 wt%.
- the peroxy bleach compound may be used in conjunction with a bleach activator (bleach precursor) to improve bleaching action at low wash temperatures.
- the bleach precursor is suitably present in an amount of from 0.1 to 8 wt%, preferably from 0.5 to 5 wt%.
- Preferred bleach precursors are peroxycarboxylic acid precursors, more especially peracetic acid precursors and pernoanoic acid precursors. Especially preferred bleach 34
- N,N,N' ,N' , -tetracetyl ethylenediamine (TAED) and sodium nonanoyloxybenzene sulphonate (SNOBS) are also of interest.
- TAED N,N,N' ,N' , -tetracetyl ethylenediamine
- SNOBS sodium nonanoyloxybenzene sulphonate
- the bleach system can be either supplemented with or replaced by a peroxyacid.
- peracids can be found in US 4 686 063 and US 5 397 501 (Unilever) .
- a preferred example is the imido peroxycarboxylic class of peracids described in EP A 325 288, EP A 349 940, DE 382 3172 and EP 325 289.
- a particularly preferred example is phthalimido peroxy caproic acid (PAP).
- PAP phthalimido peroxy caproic acid
- Such peracids are suitably present at 0.1 - 12%, preferably 0.5 - 10%.
- a bleach stabiliser may also be present.
- Suitable bleach stabilisers include ethylenediamine tetra-acetate (EDTA) , the polyphosphonates such as Dequest (Trade Mark) and non-phosphate stabilisers such as EDDS (ethylene diamine di-succinic acid) . These bleach stabilisers are also useful for stain removal especially in products containing low levels of bleaching species or no bleaching species.
- An especially preferred bleach system comprises a peroxy bleach compound (preferably sodium percarbonate optionally together with a bleach activator) , and a transition metal bleach catalyst as described and claimed in EP 458 397A ,EP 458 398A and EP 509 787A (Unilever) . 35
- a peroxy bleach compound preferably sodium percarbonate optionally together with a bleach activator
- a transition metal bleach catalyst as described and claimed in EP 458 397A ,EP 458 398A and EP 509 787A (Unilever) .
- compositions according to the invention may also contain one or more enzyme (s) .
- Suitable enzymes include the proteases, amylases, cellulases, oxidases, peroxidases and lipases usable for incorporation in detergent compositions.
- Preferred proteolytic enzymes are, catalytically active protein materials which degrade or alter protein types of stains when present as in fabric stains in a hydrolysis reaction. They may be of any suitable origin, such as vegetable, animal, bacterial or yeast origin.
- proteolytic enzymes or proteases of various qualities and origins and having activity in various pH ranges of from 4-12 are available and can be used in the instant invention.
- suitable proteolytic enzymes are the subtilins which are obtained from particular strains of B. Subtilis B. licheniformis , such as the commercially available subtilisins Maxatase (Trade Mark) , as supplied by Gist Brocades N.V. ,
- protease obtained from a strain of Bacillus having maximum activity throughout the pH range of 8-12, being commercially available, e.g. from Novo Industri A/S under the registered trade-names Esperase (Trade Mark) and Savinase (Trade-Mark) .
- Esperase Trade Mark
- Savinase Trade-Mark
- the preparation of these and analogous enzymes is described in GB 1 243 785.
- Other commercial proteases are Kazusase (Trade Mark obtainable from
- Detergency enzymes are commonly employed in granular form in amounts of from about 0.1 to about 3.0 wt%. However, any suitable physical form of enzyme may be used.
- compositions of the invention may contain alkali metal, preferably sodium carbonate, in order to increase detergency and ease processing.
- Sodium carbonate may suitably be present in amounts ranging from 1 to 60 wt%, preferably from 2 to 40 wt%.
- compositions containing little or no sodium carbonate are also within the scope of the invention.
- Powder flow may be improved by the incorporation of a small amount of a powder structurant, for example, a fatty acid (or fatty acid soap) , a sugar, an acrylate or acrylate/maleate copolymer, or sodium silicate.
- a powder structurant for example, a fatty acid (or fatty acid soap) , a sugar, an acrylate or acrylate/maleate copolymer, or sodium silicate.
- a powder structurant for example, a fatty acid (or fatty acid soap) , a sugar, an acrylate or acrylate/maleate copolymer, or sodium silicate.
- fatty acid soap suitably present in an amount of from 1 to 5 wt%.
- detergent compositions of the invention include sodium silicate; antiredeposition agents such as cellulosic polymers; soil release polymers; inorganic salts such as sodium sulphate; lather control agents or lather boosters as appropriate; proteolytic and lipolytic enzymes; dyes; coloured speckles; foam controllers and decoupling polymers.
- Further additional ingredients include surfactants, detergency builders, bleaches, transition metal sequestrants, enzymes, fabric softening and/or conditioning agents, lubricants for inhibition of 37 -
- UV absorbers such as fluorescers and photofading inhibitors, for example sunscreens/UV inhibitors and/or anti-oxidants, fungicides, insect repellents and/or insecticides, perfumes, dye fixatives, waterproofing agents, deposition aids, flocculants, anti-redeposition agents and soil release agents.
- Particulate detergent compositions are suitably prepared by spray-drying a slurry of compatible heat-insensitive ingredients, and then spraying on or post-dosing those ingredients unsuitable for processing via the slurry.
- the skilled detergent formulator will have no difficulty in deciding which ingredients should be included in the slurry and which should not .
- Particulate detergent compositions of the invention preferably have a bulk density of at least 400 g/llitre, more preferably at least 500 g/litre. Especially preferred compositions have bulk densities of at least 650 g/litre, more preferably at least 700 g/litre. 38
- Such powders may be prepared either by post-tower densification of spray-dried powder, or by wholly non-tower methods such as dry mixing and granulation; in both cases a high-speed mixer/granulator may advantageously be used. Processes using high-speed mixer/granulators are disclosed, for example, in EP 340 013A, EP 367 339A, EP 390 251A and EP 420 317A (Unilever) .
- Liquid detergent compositions can be prepared by admixing the essential and optional ingredients thereof in any desired order to provide compositions containing components in the requisite concentrations.
- Liquid compositions according to the present invention can also be in compact form which means it will contain a lower level of water compared to a conventional liquid detergent.
- the substrate may be any substrate onto which it is desirable to deposit a polymer and which is subjected to treatment such as a washing or rinsing process.
- the substrate may be a textile fabric, fabric, preferably of cotton.
- the treatment of the substrate with the material of the invention can be made by any suitable method such as washing, soaking or rinsing of the substrate.
- the treatment will involve a washing or rinsing method such as treatment in the main wash or rinse cycle of a washing machine and involves contacting the substrate with an aqueous medium comprising the material of the invention.
- Locust Bean Gum (MUD 246B, ex Rhodia) (5g, 30.84 mmol of anhydrosugar units) was dispersed in a mixture of demineralised water (12 ml) and propan-2-ol (30 ml) with vigorous stirring in a 2-necked 100ml round bottom flask fitted with a mechanical stirrer. After heating the solution to 70 °C, sodium hydroxide (0.625g, 15.6 mmol) was added and the mixture stirred for 15 minutes at the reaction temperature. Sodium chloroacetate (1.8g, 15 mmol) was then added as a solution in demineralised water (2 ml) and the reaction mixture vigorously stirred for 15 minutes at 70 °C.
- Locust Bean Gum (MUD 246B, ex Rhodia) (5g, 30.84 mmol of anhydrosugar units) was dispersed in a mixture of demineralised water (12 ml) and propan-2-ol (30 ml) with vigorous stirring in a 2 -necked 100ml round bottom flask fitted with a mechanical stirrer. After heating the solution to 70 °C, sodium hydroxide (0.625g, 15.6 mmol) was added as a solution in water (2 ml) and the mixture stirred for 15 minutes at the reaction temperature. Vinyl sulfonic acid (8 ml of a 25% aqueous solution, 15.6 mmol) was added and the - 41 -
- reaction mixture vigorously stirred for 15 minutes at 70 °C.
- the same protocol of adding both reagents was repeated three times and the reaction mixture stirred for 6 hours whilst maintaining the temperature at 70 °C.
- the reaction mixture was then poured into methanol (200ml) and the resultant white precipitate collected on a sinter funnel .
- the product was washed repeatedly with methanol and then re-dispersed into hot demineralised water. This was freeze dried resulting in 6.25g of creamy coloured material.
- a 9% w/v solution of lithium chloride in anhydrous dimethylsulfoxide (DMSO) was prepared by heating 100 ml of the solvent to 150 °C in a 2 -necked round bottom flask fitted with a mechanical stirrer.
- Locust Bean Gum (MUD 246B, ex Rhodia ) (5g, 30.84 mmol of anhydrosugar units) was added whilst maintaining the temperature until a highly viscous, homogeneous solution had formed.
- succinic anhydride (4.5g, 45 mmol) was added as a solution in anhydrous dimethyl sulphoxide (DMSO) (10ml) followed by the addition of 4- (dimethylamino) pyridine (1.15g, 9.4 mmol), also as a solution in DMSO (10ml) .
- DMSO dimethyl sulphoxide
- 4- (dimethylamino) pyridine (1.15g, 9.4 mmol
- the reaction mixture was then poured into methanol (300ml) and the resultant white precipitate collected on a sinter funnel After repeated - 42 -
- Locust Bean Gum-succinate as prepared above (1.355g) was added to a conical flask, to which 25ml of 1M sodium hydroxide solution was added. This was repeated with a sample of the unmodified Locust Bean Gum (0.5g) as a blank. The flasks were stoppered and left at ambient temperature overnight. Each flask was then titrated with 1M hydrochloric acid solution using phenolphthalein as indicator. The amount of acid required for neutralisation allows the number of the succinic acid molecules present to be calculated. For this example, the Locust Bean Gum derivative was found to be 53% succinoylated.
- Locust bean gum copolymer with a backbone of (1,4) -linked ⁇ -D-mannose units having side stubs of (1,6) -linked a-D- galactose groups in a ratio of mannose to galactose 4 :1
- LAS linear alkylbenzene sulphonate
- NaTPP Sodium tripolyphosphate Detergency used 0.5% w/w polymer
- CM-XG carboxymethylated xyloglucan
- CM-LBG carboxymethylated Locust Bean Gum
- SU-XG succinoylated xyloglucan
- SU-LBG succinoylated Locust Bean Gum
- Su-Et XG sulfoethylated xyloglucan
- Su-Et XG sulfoethylated Locust Bean Gum
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Molecular Biology (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP10183587.4A EP2330178A3 (de) | 2001-11-09 | 2002-09-20 | Polymere für Waschanwendungen |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB0127036A GB0127036D0 (en) | 2001-11-09 | 2001-11-09 | Polymers for laundry applications |
GB0127036 | 2001-11-09 | ||
PCT/EP2002/010586 WO2003040279A1 (en) | 2001-11-09 | 2002-09-20 | Polymers for laundry applications |
Related Child Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP10183587.4A Division EP2330178A3 (de) | 2001-11-09 | 2002-09-20 | Polymere für Waschanwendungen |
EP10183587.4A Division-Into EP2330178A3 (de) | 2001-11-09 | 2002-09-20 | Polymere für Waschanwendungen |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1442109A1 true EP1442109A1 (de) | 2004-08-04 |
EP1442109B1 EP1442109B1 (de) | 2018-04-25 |
Family
ID=9925546
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP10183587.4A Withdrawn EP2330178A3 (de) | 2001-11-09 | 2002-09-20 | Polymere für Waschanwendungen |
EP02774634.6A Expired - Lifetime EP1442109B1 (de) | 2001-11-09 | 2002-09-20 | Polymere für waschanwendungen |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP10183587.4A Withdrawn EP2330178A3 (de) | 2001-11-09 | 2002-09-20 | Polymere für Waschanwendungen |
Country Status (5)
Country | Link |
---|---|
EP (2) | EP2330178A3 (de) |
BR (1) | BR0213709B1 (de) |
ES (1) | ES2675289T3 (de) |
GB (1) | GB0127036D0 (de) |
WO (1) | WO2003040279A1 (de) |
Families Citing this family (206)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB0313900D0 (en) | 2003-06-16 | 2003-07-23 | Unilever Plc | Laundry treatment compositions |
GB0508883D0 (en) | 2005-04-29 | 2005-06-08 | Unilever Plc | Polymers for laundry applications |
GB0508882D0 (en) * | 2005-04-29 | 2005-06-08 | Unilever Plc | Polymers for laundry applications |
SE529259C2 (sv) | 2005-08-31 | 2007-06-12 | Ge Healthcare Bio Sciences Ab | Tillverkning av kromarografimatriser, en kromarografimatris, en vätskekromatografikolonn, prcess för att isolera målföreningar och användning av en kromarografimatris för vätskekromatografi |
JP2009511656A (ja) | 2005-10-28 | 2009-03-19 | ザ プロクター アンド ギャンブル カンパニー | 陰イオン修飾カテコール、および汚れ懸濁ポリマー類を含有する組成物 |
EP1867708B1 (de) * | 2006-06-16 | 2017-05-03 | The Procter and Gamble Company | Waschmittelzusammensetzungen |
US9376648B2 (en) | 2008-04-07 | 2016-06-28 | The Procter & Gamble Company | Foam manipulation compositions containing fine particles |
ES2568457T3 (es) | 2009-03-20 | 2016-04-29 | Henkel Ag & Co. Kgaa | Uso de polímeros con grupos carboxilo en combinación con cationes divalentes para la formación de una capa protectora |
DE102009001803A1 (de) | 2009-03-24 | 2010-09-30 | Henkel Ag & Co. Kgaa | Verwendung von Polymeren mit Carboxylgruppen in Kombination mit zweiwertigen Kationen zur Ausbildung einer Schutzschicht |
EP2501792A2 (de) | 2009-12-29 | 2012-09-26 | Novozymes A/S | Gh61-polypeptide mit waschmittelverstärkendem effekt |
WO2011104339A1 (en) | 2010-02-25 | 2011-09-01 | Novozymes A/S | Variants of a lysozyme and polynucleotides encoding same |
WO2012035103A1 (en) | 2010-09-16 | 2012-03-22 | Novozymes A/S | Lysozymes |
JP2014508830A (ja) | 2011-02-16 | 2014-04-10 | ノボザイムス アクティーゼルスカブ | 金属プロテアーゼを含む洗剤組成物 |
WO2012110563A1 (en) | 2011-02-16 | 2012-08-23 | Novozymes A/S | Detergent compositions comprising metalloproteases |
WO2012110564A1 (en) | 2011-02-16 | 2012-08-23 | Novozymes A/S | Detergent compositions comprising m7 or m35 metalloproteases |
GB201103974D0 (en) | 2011-03-09 | 2011-04-20 | Reckitt Benckiser Nv | Composition |
JP6126086B2 (ja) | 2011-06-24 | 2017-05-10 | ノボザイムス アクティーゼルスカブ | プロテアーゼ活性を有するポリペプチドおよびこれをコードするポリヌクレオチド |
CN112662734A (zh) | 2011-06-30 | 2021-04-16 | 诺维信公司 | 用于筛选α-淀粉酶的方法 |
MX2014001594A (es) | 2011-08-15 | 2014-04-25 | Novozymes As | Polipeptidos que tienen actividad de celulasa y polinucleotidos que los codifican. |
WO2013041689A1 (en) | 2011-09-22 | 2013-03-28 | Novozymes A/S | Polypeptides having protease activity and polynucleotides encoding same |
JP2015500006A (ja) | 2011-11-25 | 2015-01-05 | ノボザイムス アクティーゼルスカブ | サブチラーゼ変異体およびこれをコードするポリヌクレオチド |
BR112014012170A2 (pt) | 2011-11-25 | 2020-06-23 | Novozymes A/S | polipetídeo isolado, composição, aditivo de ração animal, uso de um polipetídeo, métodos de isolamento de dna de bastérias, e de produção de um poliptídeo, polinucleotídeo isolado, constructo de ácido nucleico ou vetor de expressão, célula hospedeira recombinante, e, planta, parte de planta ou célula de planta |
CN107267489A (zh) | 2011-12-20 | 2017-10-20 | 诺维信公司 | 枯草杆菌酶变体和编码它们的多核苷酸 |
US9809787B2 (en) | 2011-12-29 | 2017-11-07 | Novozymes A/S | Detergent compositions comprising lipase |
ES2644007T3 (es) | 2012-01-26 | 2017-11-27 | Novozymes A/S | Uso de polipéptidos con actividad de proteasa en piensos para animales y en detergentes |
JP2015509364A (ja) | 2012-02-17 | 2015-03-30 | ノボザイムス アクティーゼルスカブ | サブチリシン変異体およびそれをコードするポリヌクレオチド |
US20150064773A1 (en) | 2012-03-07 | 2015-03-05 | Novozymes A/S | Detergent Composition and Substitution of Optical Brighteners in Detergent Composition |
CN117904080A (zh) | 2012-05-07 | 2024-04-19 | 诺维信公司 | 具有黄原胶降解活性的多肽以及编码其的核苷酸 |
EP2861749A1 (de) | 2012-06-19 | 2015-04-22 | Novozymes Bioag A/S | Enzymatische reduktion von hydroperoxiden |
EP2863759A2 (de) | 2012-06-20 | 2015-04-29 | Novozymes Biopolymer A/S | Verwendung von polypeptiden mit proteasewirkung in tierfutter und reinigungsmitteln |
BR112015003724A2 (pt) | 2012-08-22 | 2017-08-08 | Novozymes As | polipeptídeo isolado, composição, uso de uma composição, polinucleotídeo isolado, constructo de ácido nucleico ou vetor de expressão, célula hospedeira recombinante, e, métodos de produção de um polipeptídeo e de produção de uma proteína. |
EP2888360B1 (de) | 2012-08-22 | 2017-10-25 | Novozymes A/S | Metalloproteasen aus alicyclobacillus sp. |
BR112015003726A2 (pt) | 2012-08-22 | 2019-09-24 | Novozymes As | composição detergente, uso de uma composição e de um polipeptídeo, e, método para remoção de uma nódoa de uma superfície. |
WO2014090940A1 (en) | 2012-12-14 | 2014-06-19 | Novozymes A/S | Removal of skin-derived body soils |
US9551042B2 (en) | 2012-12-21 | 2017-01-24 | Novozymes A/S | Polypeptides having protease activity and polynucleotides encoding same |
CN104903443A (zh) | 2013-01-03 | 2015-09-09 | 诺维信公司 | α-淀粉酶变体以及对其进行编码的多核苷酸 |
EP2970830B1 (de) | 2013-03-14 | 2017-12-13 | Novozymes A/S | Protease und hemmer enthaltend in wasserlöslichen filmen |
EP3461881A1 (de) | 2013-05-03 | 2019-04-03 | Novozymes A/S | Mikroverkapselung von wasch- und reinigungsmittelenzymen |
WO2014183921A1 (en) | 2013-05-17 | 2014-11-20 | Novozymes A/S | Polypeptides having alpha amylase activity |
US10538751B2 (en) | 2013-06-06 | 2020-01-21 | Novozymes A/S | Alpha-amylase variants and polynucleotides encoding same |
WO2014207224A1 (en) | 2013-06-27 | 2014-12-31 | Novozymes A/S | Subtilase variants and polynucleotides encoding same |
CN105874067A (zh) | 2013-06-27 | 2016-08-17 | 诺维信公司 | 枯草杆菌酶变体以及编码它们的多核苷酸 |
WO2015001017A2 (en) | 2013-07-04 | 2015-01-08 | Novozymes A/S | Polypeptides having anti-redeposition effect and polynucleotides encoding same |
EP3613853A1 (de) | 2013-07-29 | 2020-02-26 | Novozymes A/S | Proteasevarianten und polynukleotide zur codierung davon |
RU2670946C9 (ru) | 2013-07-29 | 2018-11-26 | Новозимс А/С | Варианты протеазы и кодирующие их полинуклеотиды |
WO2015049370A1 (en) | 2013-10-03 | 2015-04-09 | Novozymes A/S | Detergent composition and use of detergent composition |
EP3083954B1 (de) | 2013-12-20 | 2018-09-26 | Novozymes A/S | Polypeptide mit proteaseaktivität und polynukleotide, die für diese kodieren |
EP3114219A1 (de) | 2014-03-05 | 2017-01-11 | Novozymes A/S | Zusammensetzungen und verfahren zur verbesserung der eigenschaften von nichtcellulosischen textilmaterialien mit xyloglucan-endotransglycosylase |
CN106062271A (zh) | 2014-03-05 | 2016-10-26 | 诺维信公司 | 用于改进具有木葡聚糖内糖基转移酶的纤维素纺织材料的性质的组合物和方法 |
US20170015950A1 (en) | 2014-04-01 | 2017-01-19 | Novozymes A/S | Polypeptides having alpha amylase activity |
WO2015155350A1 (en) | 2014-04-11 | 2015-10-15 | Novozymes A/S | Detergent composition |
US20170121695A1 (en) | 2014-06-12 | 2017-05-04 | Novozymes A/S | Alpha-amylase variants and polynucleotides encoding same |
WO2016001319A1 (en) | 2014-07-03 | 2016-01-07 | Novozymes A/S | Improved stabilization of non-protease enzyme |
EP3739029A1 (de) | 2014-07-04 | 2020-11-18 | Novozymes A/S | Subtilasevarianten und polynukleotide zur codierung davon |
WO2016001449A1 (en) | 2014-07-04 | 2016-01-07 | Novozymes A/S | Subtilase variants and polynucleotides encoding same |
US10287562B2 (en) | 2014-11-20 | 2019-05-14 | Novoszymes A/S | Alicyclobacillus variants and polynucleotides encoding same |
US10683491B2 (en) | 2014-12-04 | 2020-06-16 | Novozymes A/S | Subtilase variants and polynucleotides encoding same |
WO2016087619A1 (en) | 2014-12-04 | 2016-06-09 | Novozymes A/S | Liquid cleaning compositions comprising protease variants |
WO2016096714A1 (en) | 2014-12-15 | 2016-06-23 | Henkel Ag & Co. Kgaa | Detergent composition comprising subtilase variants |
WO2016096996A1 (en) | 2014-12-16 | 2016-06-23 | Novozymes A/S | Polypeptides having n-acetyl glucosamine oxidase activity |
US11518987B2 (en) | 2014-12-19 | 2022-12-06 | Novozymes A/S | Protease variants and polynucleotides encoding same |
CN107109388A (zh) | 2014-12-19 | 2017-08-29 | 诺维信公司 | 蛋白酶变体以及对其进行编码的多核苷酸 |
EP3280791A1 (de) | 2015-04-10 | 2018-02-14 | Novozymes A/S | Waschverfahren, verwendung von dnase und waschmittelzusammensetzung |
EP3106508B1 (de) | 2015-06-18 | 2019-11-20 | Henkel AG & Co. KGaA | Reinigungsmittelzusammensetzung mit subtilasevarianten |
EP3310912B1 (de) | 2015-06-18 | 2021-01-27 | Novozymes A/S | Subtilasevarianten und polynukleotide zur codierung davon |
US20180171271A1 (en) | 2015-06-30 | 2018-06-21 | Novozymes A/S | Laundry detergent composition, method for washing and use of composition |
WO2017046260A1 (en) | 2015-09-17 | 2017-03-23 | Novozymes A/S | Polypeptides having xanthan degrading activity and polynucleotides encoding same |
MX2018002831A (es) | 2015-10-07 | 2018-09-28 | Novozymes As | Polipeptidos. |
EP3362556B1 (de) | 2015-10-14 | 2024-07-10 | Novozymes A/S | Polypeptidvarianten |
CN108291215A (zh) | 2015-10-14 | 2018-07-17 | 诺维信公司 | 具有蛋白酶活性的多肽以及编码它们的多核苷酸 |
WO2016203064A2 (en) | 2015-10-28 | 2016-12-22 | Novozymes A/S | Detergent composition comprising protease and amylase variants |
EP3380608A1 (de) | 2015-11-24 | 2018-10-03 | Novozymes A/S | Polypeptide mit proteaseaktivität und dafür codierende polynukleotide |
WO2017097866A1 (en) | 2015-12-07 | 2017-06-15 | Novozymes A/S | Polypeptides having beta-glucanase activity, polynucleotides encoding same and uses thereof in cleaning and detergent compositions |
US20210171927A1 (en) | 2016-01-29 | 2021-06-10 | Novozymes A/S | Beta-glucanase variants and polynucleotides encoding same |
EP3715442A1 (de) | 2016-03-23 | 2020-09-30 | Novozymes A/S | Verwendung eines polypeptids mit dnase-aktivität zur behandlung von geweben |
CN109312270B (zh) | 2016-04-08 | 2022-01-28 | 诺维信公司 | 洗涤剂组合物及其用途 |
EP3448978B1 (de) | 2016-04-29 | 2020-03-11 | Novozymes A/S | Reinigungsmittelzusammensetzungen und verwendungen davon |
WO2017210188A1 (en) | 2016-05-31 | 2017-12-07 | Novozymes A/S | Stabilized liquid peroxide compositions |
WO2017207762A1 (en) | 2016-06-03 | 2017-12-07 | Novozymes A/S | Subtilase variants and polynucleotides encoding same |
CN109563495A (zh) | 2016-06-30 | 2019-04-02 | 诺维信公司 | 脂肪酶变体及包含表面活性剂和脂肪酶变体的组合物 |
WO2018002261A1 (en) | 2016-07-01 | 2018-01-04 | Novozymes A/S | Detergent compositions |
CN109715794A (zh) | 2016-07-05 | 2019-05-03 | 诺维信公司 | 果胶裂解酶变体以及编码它们的多核苷酸 |
WO2018007573A1 (en) | 2016-07-08 | 2018-01-11 | Novozymes A/S | Detergent compositions with galactanase |
CN109642222A (zh) | 2016-07-13 | 2019-04-16 | 诺维信公司 | 食物芽孢杆菌dna酶变体 |
US11512300B2 (en) | 2016-08-24 | 2022-11-29 | Novozymes A/S | Xanthan lyase variants and polynucleotides encoding same |
CN109563498A (zh) | 2016-08-24 | 2019-04-02 | 汉高股份有限及两合公司 | 包含黄原胶裂解酶变体i的洗涤剂组合物 |
CA3031609A1 (en) | 2016-08-24 | 2018-03-01 | Novozymes A/S | Gh9 endoglucanase variants and polynucleotides encoding same |
EP3504313A1 (de) | 2016-08-24 | 2019-07-03 | Henkel AG & Co. KGaA | Waschmittelzusammensetzung mit gh9-endoglucanasevarianten i |
CN109996859B (zh) | 2016-09-29 | 2021-11-30 | 诺维信公司 | 含孢子的颗粒 |
EP3532592A1 (de) | 2016-10-25 | 2019-09-04 | Novozymes A/S | Waschmittelzusammensetzungen |
US11753605B2 (en) | 2016-11-01 | 2023-09-12 | Novozymes A/S | Multi-core granules |
WO2018108865A1 (en) | 2016-12-12 | 2018-06-21 | Novozymes A/S | Use of polypeptides |
WO2018177938A1 (en) | 2017-03-31 | 2018-10-04 | Novozymes A/S | Polypeptides having dnase activity |
WO2018177936A1 (en) | 2017-03-31 | 2018-10-04 | Novozymes A/S | Polypeptides having dnase activity |
US11149233B2 (en) | 2017-03-31 | 2021-10-19 | Novozymes A/S | Polypeptides having RNase activity |
US20200109352A1 (en) | 2017-04-04 | 2020-04-09 | Novozymes A/S | Polypeptide compositions and uses thereof |
US20200109354A1 (en) | 2017-04-04 | 2020-04-09 | Novozymes A/S | Polypeptides |
CN110651029B (zh) | 2017-04-04 | 2022-02-15 | 诺维信公司 | 糖基水解酶 |
ES2728758T3 (es) | 2017-04-05 | 2019-10-28 | Henkel Ag & Co Kgaa | Composiciones de detergente que comprenden mananasas bacterianas |
EP3385362A1 (de) | 2017-04-05 | 2018-10-10 | Henkel AG & Co. KGaA | Waschmittelzusammensetzungen mit pilzmannanasen |
WO2018185285A1 (en) | 2017-04-06 | 2018-10-11 | Novozymes A/S | Cleaning compositions and uses thereof |
WO2018184818A1 (en) | 2017-04-06 | 2018-10-11 | Novozymes A/S | Cleaning compositions and uses thereof |
US11407964B2 (en) | 2017-04-06 | 2022-08-09 | Novozymes A/S | Cleaning compositions and uses thereof |
US10968416B2 (en) | 2017-04-06 | 2021-04-06 | Novozymes A/S | Cleaning compositions and uses thereof |
EP3607042A1 (de) | 2017-04-06 | 2020-02-12 | Novozymes A/S | Reinigungszusammensetzungen und verwendungen davon |
CA3058519A1 (en) | 2017-04-06 | 2018-10-11 | Novozymes A/S | Cleaning compositions comprosing a dnase and a protease |
WO2018184873A1 (en) | 2017-04-06 | 2018-10-11 | Novozymes A/S | Detergent compositions and uses thereof |
WO2018185280A1 (en) | 2017-04-06 | 2018-10-11 | Novozymes A/S | Cleaning compositions and uses thereof |
EP3401385A1 (de) | 2017-05-08 | 2018-11-14 | Henkel AG & Co. KGaA | Tensidzusammensetzungen enthaltend polypeptide enthaltend eine carbohydrate binding domain |
WO2018206535A1 (en) | 2017-05-08 | 2018-11-15 | Novozymes A/S | Carbohydrate-binding domain and polynucleotides encoding the same |
WO2018224544A1 (en) | 2017-06-08 | 2018-12-13 | Novozymes A/S | Compositions comprising polypeptides having cellulase activity and amylase activity, and uses thereof in cleaning and detergent compositions |
US20200181542A1 (en) | 2017-06-30 | 2020-06-11 | Novozymes A/S | Enzyme Slurry Composition |
WO2019038058A1 (en) | 2017-08-24 | 2019-02-28 | Novozymes A/S | GH9 ENDOGLUCANASE VARIANTS AND POLYNUCLEOTIDES ENCODING SUCH VARIANTS |
EP3673060A1 (de) | 2017-08-24 | 2020-07-01 | Henkel AG & Co. KGaA | Reinigungsmittelzusammensetzung mit xanthanlyasevarianten ii |
CN111344404A (zh) | 2017-08-24 | 2020-06-26 | 诺维信公司 | 黄原胶裂解酶变体以及编码其的多核苷酸 |
US11624059B2 (en) | 2017-08-24 | 2023-04-11 | Henkel Ag & Co. Kgaa | Detergent compositions comprising GH9 endoglucanase variants II |
US11414814B2 (en) | 2017-09-22 | 2022-08-16 | Novozymes A/S | Polypeptides |
WO2019067390A1 (en) | 2017-09-27 | 2019-04-04 | The Procter & Gamble Company | DETERGENT COMPOSITIONS CONTAINING LIPASES |
WO2019068713A1 (en) | 2017-10-02 | 2019-04-11 | Novozymes A/S | POLYPEPTIDES HAVING MANNANASE ACTIVITY AND POLYNUCLEOTIDES ENCODING THESE POLYPEPTIDES |
CN111373036A (zh) | 2017-10-02 | 2020-07-03 | 诺维信公司 | 具有甘露聚糖酶活性的多肽和编码它们的多核苷酸 |
WO2019076800A1 (en) | 2017-10-16 | 2019-04-25 | Novozymes A/S | CLEANING COMPOSITIONS AND USES THEREOF |
CN111448302A (zh) | 2017-10-16 | 2020-07-24 | 诺维信公司 | 低粉化颗粒 |
WO2019076834A1 (en) | 2017-10-16 | 2019-04-25 | Novozymes A/S | PELLETS WITH LOW DUST CONTENT |
WO2019081515A1 (en) | 2017-10-24 | 2019-05-02 | Novozymes A/S | COMPOSITIONS COMPRISING POLYPEPTIDES HAVING MANNANASE ACTIVITY |
EP3701017A1 (de) | 2017-10-27 | 2020-09-02 | Novozymes A/S | Dnase-varianten |
CN111386340B (zh) | 2017-10-27 | 2024-05-24 | 宝洁公司 | 包含多肽变体的洗涤剂组合物 |
BR112020008737A2 (pt) | 2017-11-01 | 2020-10-13 | Novozymes A/S | polipeptídeos e composições que compreendam tais polipeptídeos |
DE102017125558A1 (de) | 2017-11-01 | 2019-05-02 | Henkel Ag & Co. Kgaa | Reinigungszusammensetzungen, die dispersine i enthalten |
EP3704220A1 (de) | 2017-11-01 | 2020-09-09 | Novozymes A/S | Verfahren zur reinigung von medizinischen vorrichtungen |
DE102017125559A1 (de) | 2017-11-01 | 2019-05-02 | Henkel Ag & Co. Kgaa | Reinigungszusammensetzungen, die dispersine ii enthalten |
CN111479919A (zh) | 2017-11-01 | 2020-07-31 | 诺维信公司 | 多肽以及包含此类多肽的组合物 |
DE102017125560A1 (de) | 2017-11-01 | 2019-05-02 | Henkel Ag & Co. Kgaa | Reinigungszusammensetzungen, die dispersine iii enthalten |
KR20200124258A (ko) | 2018-02-23 | 2020-11-02 | 헨켈 아게 운트 코. 카게아아 | 크산탄 리아제 및 엔도글루카나제 변이체를 포함하는 세제 조성물 |
CN111770788B (zh) | 2018-03-13 | 2023-07-25 | 诺维信公司 | 使用氨基糖低聚物进行微囊化 |
WO2019180111A1 (en) | 2018-03-23 | 2019-09-26 | Novozymes A/S | Subtilase variants and compositions comprising same |
WO2019201793A1 (en) | 2018-04-17 | 2019-10-24 | Novozymes A/S | Polypeptides comprising carbohydrate binding activity in detergent compositions and their use in reducing wrinkles in textile or fabric. |
WO2019201785A1 (en) | 2018-04-19 | 2019-10-24 | Novozymes A/S | Stabilized cellulase variants |
US11661592B2 (en) | 2018-04-19 | 2023-05-30 | Novozymes A/S | Stabilized endoglucanase variants |
CN112368363A (zh) | 2018-06-28 | 2021-02-12 | 诺维信公司 | 洗涤剂组合物及其用途 |
EP3814473A1 (de) | 2018-06-29 | 2021-05-05 | Novozymes A/S | Reinigungsmittelzusammensetzungen und verwendungen davon |
WO2020002255A1 (en) | 2018-06-29 | 2020-01-02 | Novozymes A/S | Subtilase variants and compositions comprising same |
WO2020007863A1 (en) | 2018-07-02 | 2020-01-09 | Novozymes A/S | Cleaning compositions and uses thereof |
WO2020007875A1 (en) | 2018-07-03 | 2020-01-09 | Novozymes A/S | Cleaning compositions and uses thereof |
WO2020008024A1 (en) | 2018-07-06 | 2020-01-09 | Novozymes A/S | Cleaning compositions and uses thereof |
WO2020008043A1 (en) | 2018-07-06 | 2020-01-09 | Novozymes A/S | Cleaning compositions and uses thereof |
US20210340466A1 (en) | 2018-10-01 | 2021-11-04 | Novozymes A/S | Detergent compositions and uses thereof |
WO2020070209A1 (en) | 2018-10-02 | 2020-04-09 | Novozymes A/S | Cleaning composition |
WO2020070011A1 (en) | 2018-10-02 | 2020-04-09 | Novozymes A/S | Cleaning composition |
WO2020070014A1 (en) | 2018-10-02 | 2020-04-09 | Novozymes A/S | Cleaning composition comprising anionic surfactant and a polypeptide having rnase activity |
WO2020070249A1 (en) | 2018-10-03 | 2020-04-09 | Novozymes A/S | Cleaning compositions |
US11993762B2 (en) | 2018-10-03 | 2024-05-28 | Novozymes A/S | Polypeptides having alpha-mannan degrading activity and polynucleotides encoding same |
WO2020074498A1 (en) | 2018-10-09 | 2020-04-16 | Novozymes A/S | Cleaning compositions and uses thereof |
WO2020074499A1 (en) | 2018-10-09 | 2020-04-16 | Novozymes A/S | Cleaning compositions and uses thereof |
EP3864124A1 (de) | 2018-10-11 | 2021-08-18 | Novozymes A/S | Reinigungszusammensetzungen und verwendungen davon |
EP3647397A1 (de) | 2018-10-31 | 2020-05-06 | Henkel AG & Co. KGaA | Reinigungsmittel mit dispersins iv |
EP3647398B1 (de) | 2018-10-31 | 2024-05-15 | Henkel AG & Co. KGaA | Reinigungszusammensetzungen mit dispersinen v |
US20220056379A1 (en) | 2018-12-03 | 2022-02-24 | Novozymes A/S | Powder Detergent Compositions |
EP3891264A1 (de) | 2018-12-03 | 2021-10-13 | Novozymes A/S | Waschmittelpulverzusammensetzung mit niedrigem ph-wert |
US11959111B2 (en) | 2018-12-21 | 2024-04-16 | Novozymes A/S | Polypeptides having peptidoglycan degrading activity and polynucleotides encoding same |
CN113330101A (zh) | 2018-12-21 | 2021-08-31 | 诺维信公司 | 包含金属蛋白酶的洗涤剂袋 |
EP3702452A1 (de) | 2019-03-01 | 2020-09-02 | Novozymes A/S | Waschmittelzusammensetzungen mit zwei proteasen |
BR112021018731A2 (pt) | 2019-03-21 | 2021-12-21 | Novozymes As | Variantes de alfa-amilase e polinucleotídeos codificando as mesmas |
US20220169953A1 (en) | 2019-04-03 | 2022-06-02 | Novozymes A/S | Polypeptides having beta-glucanase activity, polynucleotides encoding same and uses thereof in cleaning and detergent compositions |
WO2020207944A1 (en) | 2019-04-10 | 2020-10-15 | Novozymes A/S | Polypeptide variants |
US20220186151A1 (en) | 2019-04-12 | 2022-06-16 | Novozymes A/S | Stabilized glycoside hydrolase variants |
WO2021009067A1 (en) | 2019-07-12 | 2021-01-21 | Novozymes A/S | Enzymatic emulsions for detergents |
US20220325204A1 (en) | 2019-08-27 | 2022-10-13 | Novozymes A/S | Detergent composition |
US20220315866A1 (en) | 2019-09-19 | 2022-10-06 | Novozymes A/S | Detergent Composition |
WO2021064068A1 (en) | 2019-10-03 | 2021-04-08 | Novozymes A/S | Polypeptides comprising at least two carbohydrate binding domains |
KR20220119608A (ko) | 2019-12-20 | 2022-08-30 | 헨켈 아게 운트 코. 카게아아 | 디스페르신 viii을 포함하는 세정 조성물 |
WO2021122117A1 (en) | 2019-12-20 | 2021-06-24 | Henkel Ag & Co. Kgaa | Cleaning composition coprising a dispersin and a carbohydrase |
WO2021122118A1 (en) | 2019-12-20 | 2021-06-24 | Henkel Ag & Co. Kgaa | Cleaning compositions comprising dispersins vi |
AU2020405786A1 (en) | 2019-12-20 | 2022-08-11 | Henkel Ag & Co. Kgaa | Cleaning compositions comprising dispersins IX |
CN114929848A (zh) | 2019-12-20 | 2022-08-19 | 诺维信公司 | 稳定的液体无硼酶组合物 |
EP4077656A2 (de) | 2019-12-20 | 2022-10-26 | Novozymes A/S | Polypeptide mit proteolytischer aktivität und verwendung davon |
WO2021130167A1 (en) | 2019-12-23 | 2021-07-01 | Novozymes A/S | Enzyme compositions and uses thereof |
EP4093842A1 (de) | 2020-01-23 | 2022-11-30 | Novozymes A/S | Enzymzusammensetzungen und verwendungen davon |
WO2021152120A1 (en) | 2020-01-31 | 2021-08-05 | Novozymes A/S | Mannanase variants and polynucleotides encoding same |
BR112022014946A2 (pt) | 2020-01-31 | 2022-10-04 | Novozymes As | Variantes de mananase e polinucleotídeos codificando as mesmas |
DE102020201317A1 (de) | 2020-02-04 | 2021-08-05 | Henkel Ag & Co. Kgaa | Chitosanderivate als schmutzablösevermögende Wirkstoffe |
EP3892708A1 (de) | 2020-04-06 | 2021-10-13 | Henkel AG & Co. KGaA | Reinigungszusammensetzungen mit dispersinvarianten |
CN115210371A (zh) | 2020-04-08 | 2022-10-18 | 诺维信公司 | 碳水化合物结合模块变体 |
EP4139431A1 (de) | 2020-04-21 | 2023-03-01 | Novozymes A/S | Reinigungszusammensetzungen mit polypeptiden mit fructanabbauender aktivität |
WO2021239818A1 (en) | 2020-05-26 | 2021-12-02 | Novozymes A/S | Subtilase variants and compositions comprising same |
EP3936593A1 (de) | 2020-07-08 | 2022-01-12 | Henkel AG & Co. KGaA | Reinigungszusammensetzungen und verwendungen davon |
WO2022043321A2 (en) | 2020-08-25 | 2022-03-03 | Novozymes A/S | Variants of a family 44 xyloglucanase |
US20230323330A1 (en) | 2020-08-28 | 2023-10-12 | Novozymes A/S | Polyester degrading protease variants |
WO2022074037A2 (en) | 2020-10-07 | 2022-04-14 | Novozymes A/S | Alpha-amylase variants |
EP4232539A2 (de) | 2020-10-20 | 2023-08-30 | Novozymes A/S | Verwendung von polypeptiden mit dnase-aktivität |
EP4032966A1 (de) | 2021-01-22 | 2022-07-27 | Novozymes A/S | Flüssige enzymzusammensetzung mit sulfitabfänger |
EP4039806A1 (de) | 2021-02-04 | 2022-08-10 | Henkel AG & Co. KGaA | Reinigungsmittelzusammensetzung mit xanthan-lyase- und endoglucanase-varianten mit verbesserter stabilität |
WO2022171780A2 (en) | 2021-02-12 | 2022-08-18 | Novozymes A/S | Alpha-amylase variants |
WO2022171872A1 (en) | 2021-02-12 | 2022-08-18 | Novozymes A/S | Stabilized biological detergents |
EP4305146A1 (de) | 2021-03-12 | 2024-01-17 | Novozymes A/S | Polypeptidvarianten |
EP4060036A1 (de) | 2021-03-15 | 2022-09-21 | Novozymes A/S | Polypeptidvarianten |
WO2022194673A1 (en) | 2021-03-15 | 2022-09-22 | Novozymes A/S | Dnase variants |
EP4359518A1 (de) | 2021-06-23 | 2024-05-01 | Novozymes A/S | Alpha-amylase-polypeptide |
WO2023061928A1 (en) | 2021-10-12 | 2023-04-20 | Novozymes A/S | Endoglucanase with improved stability |
EP4206309A1 (de) | 2021-12-30 | 2023-07-05 | Novozymes A/S | Proteinpartikel mit verbesserter weisse |
WO2023165950A1 (en) | 2022-03-04 | 2023-09-07 | Novozymes A/S | Dnase variants and compositions |
WO2023194204A1 (en) | 2022-04-08 | 2023-10-12 | Novozymes A/S | Hexosaminidase variants and compositions |
WO2023247348A1 (en) | 2022-06-21 | 2023-12-28 | Novozymes A/S | Mannanase variants and polynucleotides encoding same |
WO2024083819A1 (en) | 2022-10-20 | 2024-04-25 | Novozymes A/S | Lipid removal in detergents |
WO2024110541A1 (en) | 2022-11-22 | 2024-05-30 | Novozymes A/S | Colored granules having improved colorant stability |
WO2024121070A1 (en) | 2022-12-05 | 2024-06-13 | Novozymes A/S | Protease variants and polynucleotides encoding same |
WO2024131880A2 (en) | 2022-12-23 | 2024-06-27 | Novozymes A/S | Detergent composition comprising catalase and amylase |
Family Cites Families (47)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB320842A (en) | 1928-04-18 | 1929-10-18 | Henry Dreyfus | The manufacture and treatment of cellulose derivatives |
FR702116A (fr) | 1929-08-02 | 1931-03-30 | Kodak Pathe Soc | Procédé de fabrication d'esters mixtes de cellulose |
SE1061757A (de) * | 1957-11-22 | |||
US3303051A (en) | 1963-04-05 | 1967-02-07 | United Merchants & Mfg | Process of conditioning cellulose acetate with hydroxyethylcellulose |
GB1243785A (en) | 1967-10-12 | 1971-08-25 | De La Rue Instr | Improvements in sheet counting apparatus |
US3756966A (en) * | 1971-09-28 | 1973-09-04 | Lever Brothers Ltd | Compositions sulfosuccinate derivatives of carbohydrates as builders for detergent |
US4020015A (en) * | 1971-10-12 | 1977-04-26 | Lever Brothers Company | Detergent compositions |
GB1437950A (en) | 1972-08-22 | 1976-06-03 | Unilever Ltd | Detergent compositions |
AT330930B (de) | 1973-04-13 | 1976-07-26 | Henkel & Cie Gmbh | Verfahren zur herstellung von festen, schuttfahigen wasch- oder reinigungsmitteln mit einem gehalt an calcium bindenden substanzen |
US4605509A (en) | 1973-05-11 | 1986-08-12 | The Procter & Gamble Company | Detergent compositions containing sodium aluminosilicate builders |
DE2433485A1 (de) | 1973-07-16 | 1975-02-06 | Procter & Gamble | Zur verwendung in waschmitteln geeignete aluminosilikat-ionenaustauscher |
DE2613791A1 (de) * | 1975-04-02 | 1976-10-21 | Procter & Gamble | Waschmittel |
GB1567947A (en) | 1976-07-02 | 1980-05-21 | Unilever Ltd | Esters of quaternised amino-alcohols for treating fabrics |
US4235735A (en) * | 1979-07-30 | 1980-11-25 | Milliken Research Corporation | Laundry detergent containing cellulose acetate anti-redeposition agent |
ATE7044T1 (de) * | 1980-12-17 | 1984-04-15 | Unilever Nv | Detergenszusammensetzung mit antiwiederablagerungseigenschaften. |
GB2123044B (en) | 1982-06-10 | 1986-02-05 | Kao Corp | Bleaching detergent composition |
DE3413571A1 (de) | 1984-04-11 | 1985-10-24 | Hoechst Ag, 6230 Frankfurt | Verwendung von kristallinen schichtfoermigen natriumsilikaten zur wasserenthaertung und verfahren zur wasserenthaertung |
GB8519046D0 (en) * | 1985-07-29 | 1985-09-04 | Unilever Plc | Detergent compositions |
US4686063A (en) | 1986-09-12 | 1987-08-11 | The Procter & Gamble Company | Fatty peroxyacids or salts thereof having amide moieties in the fatty chain and low levels of exotherm control agents |
US4751015A (en) | 1987-03-17 | 1988-06-14 | Lever Brothers Company | Quaternary ammonium or phosphonium substituted peroxy carbonic acid precursors and their use in detergent bleach compositions |
US4818426A (en) | 1987-03-17 | 1989-04-04 | Lever Brothers Company | Quaternary ammonium or phosphonium substituted peroxy carbonic acid precursors and their use in detergent bleach compositions |
US4933103A (en) | 1987-03-23 | 1990-06-12 | Kao Corporation | Bleaching composition |
US4915863A (en) | 1987-08-14 | 1990-04-10 | Kao Corporation | Bleaching composition |
IT1233846B (it) | 1988-01-20 | 1992-04-21 | Ausimont Spa | Perossiacidi immido aromatici |
IT1215739B (it) | 1988-01-20 | 1990-02-22 | Ausimont Spa | Perossiacidi immido aromatici come agenti sbiancanti. |
GB8810193D0 (en) | 1988-04-29 | 1988-06-02 | Unilever Plc | Detergent compositions & process for preparing them |
DE3823172C2 (de) | 1988-07-08 | 1998-01-22 | Hoechst Ag | omega-Phthalimidoperoxihexansäure, Verfahren zu dessen Herstellung und dessen Verwendung |
ES2085273T3 (es) | 1988-11-02 | 1996-06-01 | Unilever Nv | Procedimiento para preparar una composicion detergente granular de alta densidad aparente. |
CA2001927C (en) | 1988-11-03 | 1999-12-21 | Graham Thomas Brown | Aluminosilicates and detergent compositions |
GB8907187D0 (en) | 1989-03-30 | 1989-05-10 | Unilever Plc | Detergent compositions and process for preparing them |
US4988451A (en) | 1989-06-14 | 1991-01-29 | Lever Brothers Company, Division Of Conopco, Inc. | Stabilization of particles containing quaternary ammonium bleach precursors |
GB8922018D0 (en) | 1989-09-29 | 1989-11-15 | Unilever Plc | Detergent compositions and process for preparing them |
US5142034A (en) | 1990-04-16 | 1992-08-25 | Eastman Kodak Company | Cellulose ester compositions and process for the preparation thereof |
ES2100925T3 (es) | 1990-05-21 | 1997-07-01 | Unilever Nv | Activacion de blanqueador. |
GB9108136D0 (en) | 1991-04-17 | 1991-06-05 | Unilever Plc | Concentrated detergent powder compositions |
US5397501A (en) | 1993-07-26 | 1995-03-14 | Lever Brothers Company, Division Of Conopco, Inc. | Amido peroxycarboxylic acids for bleaching |
EP0874802A1 (de) * | 1995-10-27 | 1998-11-04 | Basf Aktiengesellschaft | Fettsäurederivate und ihre verwendung als tenside in wasch- und reinigungsmitteln |
DE69723575T2 (de) | 1996-12-26 | 2004-05-13 | The Procter & Gamble Company, Cincinnati | Waschmittelzusammensetzungen enthaltend zellulosepolymere |
AU746433B2 (en) * | 1997-09-15 | 2002-05-02 | Procter & Gamble Company, The | Laundry detergent compositions with cellulosic based polymers to provide appearance and integrity benefits to fabrics laundered therewith |
DE19740558C2 (de) | 1997-09-15 | 2003-01-09 | Siemens Ag | Verfahren zum Übertragen von "MWI-Dienst"-spezifischen Nachrichten in Telekommunikationsnetzen, insbesondere in hybriden DECT/ISDN-spezifischen Telekommunikationsnetzen |
GB9821218D0 (en) | 1998-09-30 | 1998-11-25 | Unilever Plc | Treatment for fabrics |
GB9821217D0 (en) * | 1998-09-30 | 1998-11-25 | Unilever Plc | Treatment for substrates |
GB9900151D0 (en) | 1999-01-05 | 1999-02-24 | Unilever Plc | Treatment for fabrics |
GB9900150D0 (en) * | 1999-01-05 | 1999-02-24 | Unilever Plc | Treatment for fabrics |
JP2002534592A (ja) * | 1999-01-13 | 2002-10-15 | ザ、プロクター、エンド、ギャンブル、カンパニー | セルロースポリマーを有する洗剤組成物 |
WO2000065015A2 (en) * | 1999-04-27 | 2000-11-02 | The Procter & Gamble Company | Surface care compositions and methods for treating surfaces |
GB0117768D0 (en) * | 2001-07-20 | 2001-09-12 | Unilever Plc | Use of polymers in fabrics cleaning |
-
2001
- 2001-11-09 GB GB0127036A patent/GB0127036D0/en not_active Ceased
-
2002
- 2002-09-20 EP EP10183587.4A patent/EP2330178A3/de not_active Withdrawn
- 2002-09-20 BR BRPI0213709-7A patent/BR0213709B1/pt active IP Right Grant
- 2002-09-20 ES ES02774634.6T patent/ES2675289T3/es not_active Expired - Lifetime
- 2002-09-20 EP EP02774634.6A patent/EP1442109B1/de not_active Expired - Lifetime
- 2002-09-20 WO PCT/EP2002/010586 patent/WO2003040279A1/en not_active Application Discontinuation
Non-Patent Citations (1)
Title |
---|
See references of WO03040279A1 * |
Also Published As
Publication number | Publication date |
---|---|
BR0213709A (pt) | 2004-10-26 |
EP2330178A3 (de) | 2014-05-14 |
EP1442109B1 (de) | 2018-04-25 |
WO2003040279A1 (en) | 2003-05-15 |
EP2330178A2 (de) | 2011-06-08 |
BR0213709B1 (pt) | 2014-11-18 |
GB0127036D0 (en) | 2002-01-02 |
ES2675289T3 (es) | 2018-07-10 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP1442109B1 (de) | Polymere für waschanwendungen | |
US7967871B2 (en) | Polymers for laundry applications | |
WO2006117056A1 (en) | Polymers for laundry applications | |
US6288022B1 (en) | Treatment for fabrics | |
EP1409629B1 (de) | Verwendung von pfropfpolymeren für textilwaschen | |
CA2402469C (en) | Laundry treatment for fabrics | |
US6869452B2 (en) | Laundry treatment for fabrics | |
AU2002333459B2 (en) | Polymers and their use | |
EP1902121A1 (de) | Wäschebehandlungsmittel | |
US20010036908A1 (en) | Laundry treatment for fabrics | |
CA2403435C (en) | Laundry treatment granule and detergent composition containing same | |
GB2360791A (en) | Softening treatment for fabrics | |
GB2360792A (en) | Laundry treatment composition containing a rebuild agent |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
17P | Request for examination filed |
Effective date: 20040326 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR IE IT LI LU MC NL PT SE SK TR |
|
AX | Request for extension of the european patent |
Extension state: AL LT LV MK RO SI |
|
RAP1 | Party data changed (applicant data changed or rights of an application transferred) |
Owner name: UNILEVER N.V. Owner name: UNILEVER PLC |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: EXAMINATION IS IN PROGRESS |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R079 Ref document number: 60249393 Country of ref document: DE Free format text: PREVIOUS MAIN CLASS: C11D0003220000 Ipc: C11D0003000000 |
|
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: GRANT OF PATENT IS INTENDED |
|
RIC1 | Information provided on ipc code assigned before grant |
Ipc: C11D 3/00 20060101AFI20180118BHEP Ipc: C11D 3/22 20060101ALI20180118BHEP |
|
INTG | Intention to grant announced |
Effective date: 20180202 |
|
GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE PATENT HAS BEEN GRANTED |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R081 Ref document number: 60249393 Country of ref document: DE Owner name: UNILEVER GLOBAL IP LIMITED, WIRRAL, GB Free format text: FORMER OWNERS: UNILEVER N.V., ROTTERDAM, NL; UNILEVER PLC, LONDON, GB |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR IE IT LI LU MC NL PT SE SK TR |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: FG4D |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: EP |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: REF Ref document number: 992917 Country of ref document: AT Kind code of ref document: T Effective date: 20180515 |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R096 Ref document number: 60249393 Country of ref document: DE |
|
REG | Reference to a national code |
Ref country code: ES Ref legal event code: FG2A Ref document number: 2675289 Country of ref document: ES Kind code of ref document: T3 Effective date: 20180710 |
|
REG | Reference to a national code |
Ref country code: NL Ref legal event code: MP Effective date: 20180425 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: PLFP Year of fee payment: 17 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: NL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180425 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: BG Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180725 Ref country code: FI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180425 Ref country code: SE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180425 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180726 |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: MK05 Ref document number: 992917 Country of ref document: AT Kind code of ref document: T Effective date: 20180425 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: PT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180827 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R097 Ref document number: 60249393 Country of ref document: DE |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: EE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180425 Ref country code: AT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180425 Ref country code: DK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180425 Ref country code: SK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180425 Ref country code: CZ Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180425 |
|
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
26N | No opposition filed |
Effective date: 20190128 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MC Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180425 |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
REG | Reference to a national code |
Ref country code: BE Ref legal event code: MM Effective date: 20180930 |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: MM4A |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20180920 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20180920 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: CH Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20180930 Ref country code: LI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20180930 Ref country code: BE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20180930 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: TR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180425 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: CY Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180425 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R081 Ref document number: 60249393 Country of ref document: DE Owner name: UNILEVER GLOBAL IP LIMITED, WIRRAL, GB Free format text: FORMER OWNER: UNILEVER N.V., ROTTERDAM, NL |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: IT Payment date: 20210927 Year of fee payment: 20 Ref country code: FR Payment date: 20210921 Year of fee payment: 20 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: DE Payment date: 20210920 Year of fee payment: 20 Ref country code: GB Payment date: 20210920 Year of fee payment: 20 |
|
REG | Reference to a national code |
Ref country code: ES Ref legal event code: PC2A Owner name: UNILEVER IP HOLDINGS B.V. Effective date: 20211228 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: ES Payment date: 20211119 Year of fee payment: 20 |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: 732E Free format text: REGISTERED BETWEEN 20220203 AND 20220209 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R071 Ref document number: 60249393 Country of ref document: DE |
|
REG | Reference to a national code |
Ref country code: ES Ref legal event code: FD2A Effective date: 20220927 |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: PE20 Expiry date: 20220919 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GB Free format text: LAPSE BECAUSE OF EXPIRATION OF PROTECTION Effective date: 20220919 Ref country code: ES Free format text: LAPSE BECAUSE OF EXPIRATION OF PROTECTION Effective date: 20220921 |