EP0969810A1 - Film-forming cosmetic composition - Google Patents

Film-forming cosmetic composition

Info

Publication number
EP0969810A1
EP0969810A1 EP98963620A EP98963620A EP0969810A1 EP 0969810 A1 EP0969810 A1 EP 0969810A1 EP 98963620 A EP98963620 A EP 98963620A EP 98963620 A EP98963620 A EP 98963620A EP 0969810 A1 EP0969810 A1 EP 0969810A1
Authority
EP
European Patent Office
Prior art keywords
composition according
composition
film
agents
proportion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP98963620A
Other languages
German (de)
French (fr)
Inventor
Roland Ramin
Chris Frankfurt
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LOreal SA
Original Assignee
LOreal SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by LOreal SA filed Critical LOreal SA
Publication of EP0969810A1 publication Critical patent/EP0969810A1/en
Withdrawn legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A61Q1/10—Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/731—Cellulose; Quaternized cellulose derivatives
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q3/00—Manicure or pedicure preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q3/00—Manicure or pedicure preparations
    • A61Q3/02—Nail coatings

Definitions

  • the subject of the present invention is a new film-forming composition containing, in a cosmetically suitable vehicle, a film-forming substance derived from cellulose and a new thickening agent.
  • the present invention also relates to the use of this new composition for making up, treating and / or caring for keratin materials such as the nails, the eyelashes, the eyebrows and the hair.
  • the present invention further relates to a process for making up, treating and / or caring for keratin fibers such as the nails, the eyelashes, the eyebrows and the hair.
  • thickening agents in film-forming cosmetic compositions are well known.
  • compositions when the compositions are thickened, this facilitates the taking of the product out of its packaging in an amount sufficient for the desired effect and without significant loss, and this also allows a regular distribution of the product on the keratin materials.
  • compositions have improved properties compared to the prior art, in particular, great ease of application and good homogeneity of the film, while retaining the qualities of gloss and resistance of the film obtained after application.
  • the present invention therefore relates to a film-forming composition containing, in a cosmetically suitable vehicle, a film-forming substance derived from cellulose and, as thickening agent, an effective amount of at least one alkali metal tetraborate.
  • the alkali metal tetraborate is preferably potassium, sodium or lithium tetraborate and is present in a proportion of between 0.01 and 0.1% by weight relative to the total weight of the film-forming substance .
  • the potassium tetraborate is either in the form of pentahydrate or octahydrate
  • the sodium tetraborate is in the form of decahydrate or borax
  • the lithium tetraborate is in the form of pentahydrate.
  • the film-forming substance derived from cellulose is preferably nitrocellulose, cellulose ethers, nonionic cellulose esters and anionic cellulose esters.
  • compositions of the invention are in the form of a product for the nails such as a nail varnish or a product for the care of the nails.
  • a product for the nails such as a nail varnish or a product for the care of the nails.
  • an alkali metal tetraborate not only makes it possible to obtain an appropriate thickening of the varnish compositions, but also has a stabilizing action on certain unstable substances generally present in nail varnishes , in particular of compounds comprising at least one amine or amide function.
  • the film-forming substance preferably used according to this first embodiment is nitrocellulose, generally present in a proportion of between approximately 5 and 20%, and preferably between 10 and 16% by weight relative to the total weight of the composition.
  • nitrocelluloses of the "RS" or "SS” type there may be mentioned nitrocelluloses of the "RS" or "SS” type, and in particular nitrocellulose type V * second RS, nitrocellulose type Vi second RS, nitrocellulose type 14 second SS and nitrocellulose type V second RS.
  • these contain, in a solvent system for varnishes, in addition to the film-forming substance derived from cellulose as described above, at least one plasticizing agent and at least one resin.
  • the solvent system for varnishes is in the form of a mixture of solvents volatile organic and is generally present in a proportion of between 55 and 90% by weight relative to the total weight of the composition.
  • the use of a mixture of volatile organic solvents makes it possible to obtain relatively short drying times.
  • the solvent mixture can also comprise a diluent which is preferably a saturated linear or branched hydrocarbon, such as hexane or octane or also an aromatic hydrocarbon such as toluene or xylene in a proportion generally between 10 and 35% relative to the total weight of the varnish.
  • the solvent mixture can also include other volatile solvents such as ethanol, n-propanol, isopropanol, n-butanol or their mixtures.
  • the plasticizing agent is present in a proportion of between 2 and 12%, and preferably between 5 and 10% by weight relative to the total weight of the composition.
  • Plasticizers allow the flexibility of the film to be adjusted without weakening its strength or physical strength.
  • plasticizing agents capable of being used in cosmetic varnish compositions
  • plasticizing agents capable of being used in cosmetic varnish compositions
  • the resin is present in particular: tricresyl phosphate, benzyl benzoate, tributyl phosphate, butyl acetyl-ricinoleate, acetyl-ricinoleate of glyceryl, dibutyl phthalate, butyl giycolate, dioctyl phthalate, butyl stearate, tributoxyethyl phosphate, triphenyl phosphate, triethyl citrate, tributyl citrate, acetyl citrate tributyl, 2-triethylhexyl acetyl citrate, dibutyl tartrate, dimethoxyethyl phthalate, di-isobutyl phthalate, diamyl phthalate, camphor, glycerol triacetate and their mixtures.
  • resins of the aryl-sulfonamide formaldehyde or aryl-sulfonamide epoxy type in particular the toluene sulfonamide formaldehyde resin, more commonly known under the trade names of "SANTOLITE MHP®", “SANTOLITE MS 80 % ® ", and” KETJENFLEX MS 80® ", or alternatively alkyd resins such as those sold by the company DAINIPPON under the name of" BECKOSOL ODE 230-70® ".
  • the nail varnishes according to this particular embodiment can be colorless or colored.
  • organic and inorganic pigments and / or dyes generally present in a proportion of between 0.01 and 5% by weight and preferably between 0.1 and 2% by weight. relative to the total weight of the composition.
  • organic pigments mention may be made of R&C Red No. 10, 11, 12 and 13, D&C Red No. 7, D&C Red No. 5 and 6, D&C Red No. 34, lacquers such as D&C lacquer Yellow No. 5, D&C Red No. 2 hairspray and guanine.
  • inorganic pigments mention may be made of titanium dioxide, bismuth oxychloride, brown iron oxide and red iron oxides.
  • certain thixotropic agents can be used, such as for example "BENTONE 27®” or "BENTONE 38®”.
  • the nail varnish compositions according to this particular embodiment can also contain a conventional adjuvant such as UVA and / or UVB sun filters, dispersing and wetting agents, matting agents, agents adhesion agents, spreading agents, rheological agents, thixotropic agents, preservatives, antioxidants, and active agents treating the nail.
  • a conventional adjuvant such as UVA and / or UVB sun filters, dispersing and wetting agents, matting agents, agents adhesion agents, spreading agents, rheological agents, thixotropic agents, preservatives, antioxidants, and active agents treating the nail.
  • the varnishes according to the invention apply, because of their consistency conferred by the presence of the thickening agent, in a particularly convenient manner on the surface of the nails and leave, after drying, a shiny film.
  • compositions according to the invention are in the form of make-up and / or care products for the eyelashes, the eyebrows and the hair such as mascaras.
  • the film-forming substance in the film-forming cosmetic compositions according to this particular embodiment is preferably chosen from nonionic cellulose esters, anionic cellulose esters and cellulose ethers and is present in a proportion of between 5 and 50 %, and preferably between 10 and 25% by weight relative to the total weight of the composition.
  • nonionic cellulose esters which can be used as film-forming substance according to the invention, mention may be made of cellulose acetates, cellulose propionates, cellulose butyrates, cellulose aceto-propionates and cellulose aceto-butyrates.
  • anionic cellulose esters mention may be made of cellulose esters with carboxylic acid functions, such as cellulose acetophthalate, cellulose acetate succinate, cellulose propionate succinate, cellulose butyrate succinate, succinate cellulose acetate propionate, cellulose acetate butyrate succinate, cellulose acetate trimellilate, cellulose butyrate trimellilate, cellulose propionate trimellilate, cellulose acetate propionate trimellilate and acetobutyrate trimellilate cellulose, the said carboxylic acid functions being neutralized at a neutralization rate between 10 and 80% using a basic non-volatile agent.
  • carboxylic acid functions being neutralized at a neutralization rate between 10 and 80% using a basic non-volatile agent.
  • cellulose ethers which can be used as film-forming substance according to the invention, mention may in particular be made of ethylicelluloses and in particular those marketed under the names of "ETHOCEL" by the company DOW CHEMICAL.
  • compositions according to this embodiment can be in the form of an oil-in-water or water-in-oil emulsion, in the form of a suspension in a solvent medium, or also in the form of a block or a anhydrous solid paste, these makeup compositions more particularly being mascaras.
  • the mascaras according to the invention are preferably in the form of an emulsion consisting of an aqueous phase and a fatty phase, and at least one surfactant.
  • the surfactant is present in a proportion of between 0.01 and 30% by weight relative to the total weight of the composition.
  • the surfactant is preferably anionic or nonionic and is present in a proportion preferably of between 2 and 30% by weight relative to the total weight of the composition.
  • Such surfactants are well known in the state of the art and are, among other things, described in application FR-2 715 063.
  • the fatty phase is preferably present in a proportion of approximately 0.1 and 40% by weight relative to the total weight of the composition, and consists of at least one liquid, solid or semi-solid fatty substance.
  • the fatty substances can be chosen from oils, waxes, gums and / or so-called pasty fatty substances of mineral, animal, vegetable or synthetic origin. These fatty substances are well known from the state of the art and are described in particular in application FR-2 687 569.
  • the mascaras according to this particular embodiment of the invention may also contain pigments present in a proportion of between 3 and 25% by weight relative to the total weight of the composition according to the coloring and the intensity of coloring sought.
  • pigments can be organic or mineral or can also be pearlescent pigments. Such pigments are well known and are described in particular in application FR-2 528 699.
  • the mascaras can also contain a conventional additive chosen from softeners, preservatives, sequestering agents, perfumes, oils, silicones, cohesion agents, plasticizers, moisturizers, treating active agents, alkalizing or acidifying agents. .
  • the mascaras according to the invention are applied to keratin fibers such as eyelashes, eyebrows and the hair using a brush or a paintbrush and form a smooth and regular film.

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention concerns a film-forming cosmetic composition containing, in an appropriate cosmetic vehicle, a film-forming substance derived from cellulose and, as thickening agent, an efficient amount of alkaline metal tetraborate. The invention is used for making nail varnish, for nail make-up and/or nail care, or for making products for make-up and/or care of eyelashes, eyebrows or hair.

Description

Composition cosmétique filmogèneFilm-forming cosmetic composition
La présente invention a pour objet une nouvelle composition filmogène contenant, dans un véhicule cosmétiquement approprié, une substance filmogène dérivée de la cellulose et un nouvel agent épaississant.The subject of the present invention is a new film-forming composition containing, in a cosmetically suitable vehicle, a film-forming substance derived from cellulose and a new thickening agent.
La présente invention a également pour objet l'utilisation de cette nouvelle composition pour le maquillage, le traitement et/ou le soin des matières kératiniques telles que les ongles, les cils, les sourcils et les cheveux. La présente invention a en outre pour objet un procédé de maquillage, de traitement et/ou de soin des fibres kératiniques telles que les ongles, les cils, les sourcils et les cheveux.The present invention also relates to the use of this new composition for making up, treating and / or caring for keratin materials such as the nails, the eyelashes, the eyebrows and the hair. The present invention further relates to a process for making up, treating and / or caring for keratin fibers such as the nails, the eyelashes, the eyebrows and the hair.
Les différents avantages apportés par les agents épaississants dans les composi- tions cosmétiques filmogènes sont bien connus.The various advantages provided by thickening agents in film-forming cosmetic compositions are well known.
En effet, lorsque les compositions sont épaissies, ceci facilite la prise du produit hors de son conditionnement en une quantité suffisante pour l'effet recherché et sans perte significative, et ceci permet par ailleurs une répartition régulière du produit sur les matières kératiniques.Indeed, when the compositions are thickened, this facilitates the taking of the product out of its packaging in an amount sufficient for the desired effect and without significant loss, and this also allows a regular distribution of the product on the keratin materials.
Il est de plus connu que dans des compositions filmogènes liquides tels que des vernis à ongles contenant des pigments, l'utilisation d'un agent épaississant permet d'en éviter la sédimentation lors du stockage des compositions. Il a été proposé à cet effet dans la demande GB-A-2 021 411 , d'utiliser des argiles notamment des montmorriiionites organomodifiées en tant qu'agent épaississant. Toutefois, la préparation de telles compositions nécessite une étape supplémentaire de mise en dispersion de l'argile à l'aide d'un homogénéisateur haute pression "Gaulin" rendant ainsi la fabrication de ces compositions longues et coûteuses. De plus, les argiles telles que les montmorriiionites organomodifiées modifient les propriétés de résistance du film après application. Il a été également proposé dans la demande FR-A-1 453 089 de réaliser des compositions de vernis à ongles en utilisant des silices hydrophiles et hydropho- bes en tant qu'agent épaississant. L'utilisation de ces silices nécessite également une étape de mise en dispersion supplémentaire et elles ont tendance à modifier les propriétés de brillance du film. L'emploi de ces silices n'est donc pas préconisé pour la préparation de compositions filmogènes transparentes ou pour l'obtention de films brillants.It is moreover known that in liquid film-forming compositions such as nail varnishes containing pigments, the use of a thickening agent makes it possible to avoid sedimentation during storage of the compositions. It has been proposed for this purpose in application GB-A-2 021 411, to use clays, in particular organomodified montmorriiionites as thickening agent. However, the preparation of such compositions requires an additional step of dispersing the clay using a "Gaulin" high pressure homogenizer, thus making the manufacture of these compositions long and expensive. In addition, clays such as organomodified montmorriiionites modify the resistance properties of the film after application. It has also been proposed in application FR-A-1 453 089 to produce nail varnish compositions using hydrophilic and hydrophobic silicas as thickening agent. The use of these silicas also requires an additional dispersing step and they tend to modify the gloss properties of the film. The use of these silicas is therefore not recommended for the preparation of transparent film-forming compositions or for obtaining glossy films.
A la suite d'études sur divers composés, on a constaté de façon surprenante et in- attendue que l'association d'au moins une substance filmogène dérivée de la cellulose avec un tétraborate de métal alcalin, en tant qu'agent épaississant, permettait de remédier aux inconvénients de mise en dispersion sans modification des propriétés du film.Following studies on various compounds, it has been found, surprisingly and unexpectedly, that the combination of at least one film-forming substance derived from cellulose with an alkali metal tetraborate, as a thickening agent, makes it possible to overcome the disadvantages of dispersing without modifying the properties of the film.
Ces nouvelles compositions présentent des propriétés améliorées par rapport à l'art antérieur, en particulier, une grande facilité d'application et une bonne homogénéité du film, tout en conservant les qualités de brillance et de résistance du film obtenu après application.These new compositions have improved properties compared to the prior art, in particular, great ease of application and good homogeneity of the film, while retaining the qualities of gloss and resistance of the film obtained after application.
La présente invention a donc pour objet une composition filmogène contenant, dans un véhicule cosmétiquement approprié, une substance filmogène dérivée de la cellulose et, en tant qu'agent épaississant, une quantité efficace d'au moins un tétraborate de métal alcalin.The present invention therefore relates to a film-forming composition containing, in a cosmetically suitable vehicle, a film-forming substance derived from cellulose and, as thickening agent, an effective amount of at least one alkali metal tetraborate.
Selon l'invention, le tétraborate de métal alcalin est de préférence le tétraborate de potassium, de sodium ou de lithium et est présent en une proportion comprise entre 0,01 et 0,1 % en poids par rapport au poids total de la substance filmogène. Le tétraborate de potassium est soit sous forme de pentahydrate soit d'octahy- drate, le tétraborate de sodium est sous forme de décahydrate ou borax et le té- traborate de lithium est sous forme de pentahydrate. Selon l'invention, la substance filmogène dérivée de la cellulose est de préférence la nitrocellulose, les éthers de cellulose, les esters de cellulose non-ioniques et les esters de cellulose anioniques.According to the invention, the alkali metal tetraborate is preferably potassium, sodium or lithium tetraborate and is present in a proportion of between 0.01 and 0.1% by weight relative to the total weight of the film-forming substance . The potassium tetraborate is either in the form of pentahydrate or octahydrate, the sodium tetraborate is in the form of decahydrate or borax and the lithium tetraborate is in the form of pentahydrate. According to the invention, the film-forming substance derived from cellulose is preferably nitrocellulose, cellulose ethers, nonionic cellulose esters and anionic cellulose esters.
Selon un premier mode de réalisation des compositions de l'invention, celles-ci se présentent sous forme d'un produit pour les ongles tel qu'un vernis à ongles ou un produit pour le soin des ongles. Selon ce mode de réalisation, on a constaté que la présence d'un tétraborate de métal alcalin permettait non seulement d'obtenir un épaississement approprié des compositions de vernis, mais avait également une action stabilisante de certaines substances instables généralement présentes dans les vernis à ongles, en particulier de composés comportant au moins une fonction aminé ou amide.According to a first embodiment of the compositions of the invention, these are in the form of a product for the nails such as a nail varnish or a product for the care of the nails. According to this embodiment, it has been found that the presence of an alkali metal tetraborate not only makes it possible to obtain an appropriate thickening of the varnish compositions, but also has a stabilizing action on certain unstable substances generally present in nail varnishes , in particular of compounds comprising at least one amine or amide function.
Parmi ces composés, on peut notamment mentionner des colorants et pigments, ainsi que certaines substances actives traitantes de la kératine des ongles.Among these compounds, mention may in particular be made of dyes and pigments, as well as certain active substances which treat nail keratin.
La substance filmogène utilisée de préférence selon ce premier mode de réalisation est la nitrocellulose, généralement présente en une proportion comprise entre environ 5 et 20 %, et de préférence entre 10 et 16 % en poids par rapport au poids total de la composition.The film-forming substance preferably used according to this first embodiment is nitrocellulose, generally present in a proportion of between approximately 5 and 20%, and preferably between 10 and 16% by weight relative to the total weight of the composition.
Parmi les nitrocelluloses particulièrement préférées, on peut citer les nitrocellulo- ses du type "RS" ou "SS", et en particulier la nitrocellulose type V* seconde RS, la nitrocellulose type Vi seconde RS, la nitrocellulose type 14 seconde SS et la nitrocellulose type V seconde RS.Among the particularly preferred nitrocelluloses, there may be mentioned nitrocelluloses of the "RS" or "SS" type, and in particular nitrocellulose type V * second RS, nitrocellulose type Vi second RS, nitrocellulose type 14 second SS and nitrocellulose type V second RS.
Selon ce mode particulier de réalisation des compositions filmogènes de l'invention, celles-ci contiennent dans un système solvant pour vernis, outre la substance filmogène dérivée de la cellulose telle que décrite précédemment, au moins un agent plastifiant et au moins une résine.According to this particular embodiment of the film-forming compositions of the invention, these contain, in a solvent system for varnishes, in addition to the film-forming substance derived from cellulose as described above, at least one plasticizing agent and at least one resin.
Le système solvant pour vernis se présente sous forme d'un mélange de solvants organiques volatils et est généralement présent en une proportion comprise entre 55 et 90 % en poids par rapport au poids total de la composition. L'utilisation d'un mélange de solvants organiques volatils permet d'obtenir des temps de séchage relativement courts.The solvent system for varnishes is in the form of a mixture of solvents volatile organic and is generally present in a proportion of between 55 and 90% by weight relative to the total weight of the composition. The use of a mixture of volatile organic solvents makes it possible to obtain relatively short drying times.
Parmi ces solvants on peut citer l'acétone, la méthyl-éthyl cétone, la méthyl- isobutyl cétone, l'acétate de méthyle, l'acétate d'éthyle, l'acétate d'isopropyle, l'acétate de butyle, l'acétate d'amyle et l'acétate de méthoxy-2 éthyle. Le mélange solvant peut comprendre également un diluant qui est de préférence un hydrocarbure, linéaire ou ramifié, saturé, tel que l'hexane ou l'octane ou encore un hydrocarbure aromatique tel que le toluène ou le xylène en une proportion généralement comprise entre 10 et 35 % par rapport au poids total du vernis. Le mélange solvant peut également inclure d'autres solvants volatils tels que de l'éthanol, du n-propanol, de l'isopropanol, du n-butanol ou leurs mélanges.Among these solvents, mention may be made of acetone, methyl ethyl ketone, methyl isobutyl ketone, methyl acetate, ethyl acetate, isopropyl acetate, butyl acetate, amyl acetate and 2-methoxy ethyl acetate. The solvent mixture can also comprise a diluent which is preferably a saturated linear or branched hydrocarbon, such as hexane or octane or also an aromatic hydrocarbon such as toluene or xylene in a proportion generally between 10 and 35% relative to the total weight of the varnish. The solvent mixture can also include other volatile solvents such as ethanol, n-propanol, isopropanol, n-butanol or their mixtures.
Selon ce mode particulier de réalisation, l'agent plastifiant est présent en une proportion comprise entre 2 et 12 %, et de préférence entre 5 et 10 % en poids par rapport au poids total de la composition. Les agents plastifiants permettent de régler la flexibilité du film sans affaiblir sa résistance ou sa force physique.According to this particular embodiment, the plasticizing agent is present in a proportion of between 2 and 12%, and preferably between 5 and 10% by weight relative to the total weight of the composition. Plasticizers allow the flexibility of the film to be adjusted without weakening its strength or physical strength.
Parmi les agents plastifiants susceptibles d'être utilisés dans les compositions cosmétiques de vernis, on peut notamment citer : le phosphate de tricrésyle, le benzoate de benzyle, le phosphate de tributyle, l'acétyl-ricinoléate de butyle, l'acétyl-ricinoléate de glycéryle, le phtalate de dibutyle, le giycolate de butyle, le phtalate de dioctyle, le stéarate de butyle, le phosphate de tributoxy-éthyle, le phosphate de triphényle, le citrate de triéthyle, le citrate de tributyle, l'acétyl-citrate de tributyle, l'acétyl-citrate de triéthyl-2 hexyle, le tartrate de dibutyle, le phtalate de diméthoxyéthyle, le phtalate de di-isobutyle, le phtalate de diamyle, le camphre, le triacétate de glycérol et leurs mélanges. Selon ce mode de réalisation particulier de l'invention, la résine est présente en une proportion comprise entre 0,5 et 15 %, mais de préférence entre 5 et 10 % en poids par rapport au poids total de la composition. Les résines permettent d'améliorer le brillant et l'adhérence du film.Among the plasticizing agents capable of being used in cosmetic varnish compositions, there may be mentioned in particular: tricresyl phosphate, benzyl benzoate, tributyl phosphate, butyl acetyl-ricinoleate, acetyl-ricinoleate of glyceryl, dibutyl phthalate, butyl giycolate, dioctyl phthalate, butyl stearate, tributoxyethyl phosphate, triphenyl phosphate, triethyl citrate, tributyl citrate, acetyl citrate tributyl, 2-triethylhexyl acetyl citrate, dibutyl tartrate, dimethoxyethyl phthalate, di-isobutyl phthalate, diamyl phthalate, camphor, glycerol triacetate and their mixtures. According to this particular embodiment of the invention, the resin is present in a proportion of between 0.5 and 15%, but preferably between 5 and 10% by weight relative to the total weight of the composition. The resins improve the gloss and the adhesion of the film.
Parmi les nombreuses résines utilisables, on préfère employer selon l'invention des résines du type aryl-sulfonamide formaldéhyde ou aryl-sulfonamide époxy, notamment la résine toluène sulfonamide formaldéhyde plus connue sous les dénominations commerciales de "SANTOLITE MHP®", "SANTOLITE MS 80 %®", et "KETJENFLEX MS 80®", ou encore des résines alkydes telles que celles vendues par la Société DAINIPPON sous la dénomination de "BECKOSOL ODE 230-70®". Les vernis à ongles selon ce mode particulier de réalisation peuvent être incolores ou colorés.Among the numerous resins which can be used, it is preferred to use, according to the invention, resins of the aryl-sulfonamide formaldehyde or aryl-sulfonamide epoxy type, in particular the toluene sulfonamide formaldehyde resin, more commonly known under the trade names of "SANTOLITE MHP®", "SANTOLITE MS 80 % ® ", and" KETJENFLEX MS 80® ", or alternatively alkyd resins such as those sold by the company DAINIPPON under the name of" BECKOSOL ODE 230-70® ". The nail varnishes according to this particular embodiment can be colorless or colored.
Lorsqu'ils se présentent sous forme colorée, ils contiennent alors des pigments et/ou des colorants organiques ou inorganiques généralement présents en une proportion comprise entre 0,01 et 5 % en poids et de préférence entre 0,1 et 2 % en poids par rapport au poids total de la composition.When they are in colored form, they then contain organic and inorganic pigments and / or dyes generally present in a proportion of between 0.01 and 5% by weight and preferably between 0.1 and 2% by weight. relative to the total weight of the composition.
Parmi les pigments organiques, on peut citer le R&C Red No. 10, 11 , 12 et 13, le D&C Red No. 7 les D&C Red No. 5 et 6, les D&C Red No. 34, des laques tel que la laque D&C Yellow No. 5, la laque D&C Red No. 2 et la guanine.Among the organic pigments, mention may be made of R&C Red No. 10, 11, 12 and 13, D&C Red No. 7, D&C Red No. 5 and 6, D&C Red No. 34, lacquers such as D&C lacquer Yellow No. 5, D&C Red No. 2 hairspray and guanine.
Parmi les pigments inorganiques, on peut citer le dioxyde de titane, l'oxychlorure de bismuth, l'oxyde de fer brun et les oxydes de fer rouge.Among the inorganic pigments, mention may be made of titanium dioxide, bismuth oxychloride, brown iron oxide and red iron oxides.
Si nécessaire, en vue d'améliorer l'effet d'anti-sédimentation des pigments, on peut utiliser certains agents thixotropes, tels que par exemple la "BENTONE 27®" ou la "BENTONE 38®".If necessary, in order to improve the anti-sedimentation effect of the pigments, certain thixotropic agents can be used, such as for example "BENTONE 27®" or "BENTONE 38®".
Les compositions de vernis à ongles selon ce mode particulier de réalisation, peuvent également contenir un adjuvant conventionnel tels que les filtres solaires UVA et/ou UVB, les agents dispersants et mouillants, les agents matifiants, les agents d'adhérence, les agents d'étalement, les agents rhéologiques, les agents thixotro- pes, les conservateurs, les antioxydants, et les agents actifs traitants de l'ongle.The nail varnish compositions according to this particular embodiment, can also contain a conventional adjuvant such as UVA and / or UVB sun filters, dispersing and wetting agents, matting agents, agents adhesion agents, spreading agents, rheological agents, thixotropic agents, preservatives, antioxidants, and active agents treating the nail.
Selon ce mode de réalisation, les vernis selon l'invention s'appliquent, du fait de leur consistance conférée par la présence de l'agent épaississant, de façon particulièrement commode sur la surface des ongles et laissent après séchage, un film brillant.According to this embodiment, the varnishes according to the invention apply, because of their consistency conferred by the presence of the thickening agent, in a particularly convenient manner on the surface of the nails and leave, after drying, a shiny film.
Selon un deuxième mode de réalisation particulier des compositions selon l'inven- tion, celles-ci se présentent sous la forme de produits de maquillage et/ou de soin des cils, des sourcils et des cheveux tels que les mascaras.According to a second particular embodiment of the compositions according to the invention, these are in the form of make-up and / or care products for the eyelashes, the eyebrows and the hair such as mascaras.
La substance filmogène dans les compositions cosmétiques filmogènes selon ce mode particulier de réalisation est choisie de préférence parmi les esters de cellu- lose non-ioniques, les esters de cellulose anioniques et les éthers de cellulose et est présente en une proportion comprise entre 5 et 50 %, et de préférence entre 10 et 25 % en poids par rapport au poids total de la composition.The film-forming substance in the film-forming cosmetic compositions according to this particular embodiment is preferably chosen from nonionic cellulose esters, anionic cellulose esters and cellulose ethers and is present in a proportion of between 5 and 50 %, and preferably between 10 and 25% by weight relative to the total weight of the composition.
Parmi les esters de cellulose non-ioniques utilisables comme substance filmogène selon l'invention, on peut citer les acétates de cellulose, les propionates de cellulose, les butyrates de cellulose, les acéto-propionates de cellulose et les acéto- butyrates de cellulose.Among the nonionic cellulose esters which can be used as film-forming substance according to the invention, mention may be made of cellulose acetates, cellulose propionates, cellulose butyrates, cellulose aceto-propionates and cellulose aceto-butyrates.
Parmi les esters de cellulose anioniques on peut citer les esters de cellulose à fonctions acides carboxyliques, tels que l'acétophtalate de cellulose, le succinate d'acétate de cellulose, le succinate de propionate de cellulose, le succinate de butyrate de cellulose, le succinate d'acétopropionate de cellulose, le succinate d'acétobutyrate de cellulose, le trimellilate d'acétate de cellulose, le trimellilate de butyrate de cellulose, le trimellilate de propionate de cellulose, le trimellilate d'acétopropionate de cellulose et le trimellilate d'acétobutyrate de cellulose, lesdi- tes fonctions acides carboxyliques étant neutralisées à un taux de neutralisation compris entre 10 et 80 % à l'aide d'un agent basique non volatil. Parmi les éthers de cellulose utilisables comme substance filmogène selon l'invention, on peut citer notamment les éthyicelluloses et en particulier celles commercialisées sous les dénominations de "ETHOCEL" par la Société DOW CHEMICAL.Among the anionic cellulose esters, mention may be made of cellulose esters with carboxylic acid functions, such as cellulose acetophthalate, cellulose acetate succinate, cellulose propionate succinate, cellulose butyrate succinate, succinate cellulose acetate propionate, cellulose acetate butyrate succinate, cellulose acetate trimellilate, cellulose butyrate trimellilate, cellulose propionate trimellilate, cellulose acetate propionate trimellilate and acetobutyrate trimellilate cellulose, the said carboxylic acid functions being neutralized at a neutralization rate between 10 and 80% using a basic non-volatile agent. Among the cellulose ethers which can be used as film-forming substance according to the invention, mention may in particular be made of ethylicelluloses and in particular those marketed under the names of "ETHOCEL" by the company DOW CHEMICAL.
Les compositions selon ce mode de réalisation, peuvent se présenter sous forme d'une émulsion huile-dans-eau ou eau-dans-huile, sous forme de suspension dans un milieu solvant, ou encore sous forme d'un bloc ou d'une pâte solide anhydre, ces compositions de maquillage étant plus particulièrement des mascaras.The compositions according to this embodiment can be in the form of an oil-in-water or water-in-oil emulsion, in the form of a suspension in a solvent medium, or also in the form of a block or a anhydrous solid paste, these makeup compositions more particularly being mascaras.
Les modes opératoires pour la préparation de ces différentes formes de produits de maquillage et/ou de soin sont bien connus de l'homme du métier.The procedures for the preparation of these different forms of makeup and / or care products are well known to those skilled in the art.
Les mascaras selon l'invention se présentent de préférence sous forme d'une émulsion constituée d'une phase aqueuse et d'une phase grasse, et d'au moins un agent tensioactif.The mascaras according to the invention are preferably in the form of an emulsion consisting of an aqueous phase and a fatty phase, and at least one surfactant.
Selon ce mode particulier de réalisation de l'invention, l'agent tensioactif est présent en une proportion comprise entre 0,01 à 30 % en poids par rapport au poids total de la composition. L'agent tensioactif est de préférence anionique ou non- ionique et est présent en une proportion de préférence comprise entre 2 et 30 % en poids par rapport au poids total de la composition. De tels agents tensioactifs sont bien connus de l'état de la technique et sont entre autres décrits dans la demande FR-2 715 063.According to this particular embodiment of the invention, the surfactant is present in a proportion of between 0.01 and 30% by weight relative to the total weight of the composition. The surfactant is preferably anionic or nonionic and is present in a proportion preferably of between 2 and 30% by weight relative to the total weight of the composition. Such surfactants are well known in the state of the art and are, among other things, described in application FR-2 715 063.
La phase grasse est de préférence présente en une proportion d'environ 0,1 et 40 % en poids par rapport au poids total de la composition, et est constituée d'au moins un corps gras liquide, solide ou semi-solide.The fatty phase is preferably present in a proportion of approximately 0.1 and 40% by weight relative to the total weight of the composition, and consists of at least one liquid, solid or semi-solid fatty substance.
Les corps gras peuvent être choisis parmi les huiles, les cires, les gommes et/ou les corps gras dits pâteux d'origine minérale, animale, végétale ou de synthèse. Ces corps gras sont bien connus de l'état de la technique et sont notamment décrits dans la demande FR-2 687 569.The fatty substances can be chosen from oils, waxes, gums and / or so-called pasty fatty substances of mineral, animal, vegetable or synthetic origin. These fatty substances are well known from the state of the art and are described in particular in application FR-2 687 569.
Les mascaras selon ce mode particulier de réalisation de l'invention, peuvent en outre contenir des pigments présents en une proportion comprise entre 3 et 25 % en poids par rapport au poids total de la composition suivant la coloration et l'intensité de coloration recherchée.The mascaras according to this particular embodiment of the invention may also contain pigments present in a proportion of between 3 and 25% by weight relative to the total weight of the composition according to the coloring and the intensity of coloring sought.
Ces pigments peuvent être organiques ou minéraux ou peuvent être également des pigments nacrés. De tels pigments sont bien connus et sont en particulier dé- crits dans la demande FR-2 528 699.These pigments can be organic or mineral or can also be pearlescent pigments. Such pigments are well known and are described in particular in application FR-2 528 699.
Les mascaras peuvent également contenir un additif conventionnel choisi parmi les adoucissants, les conservateurs, les agents séquestrants, les parfums, les huiles, les silicones, les agents de cohésion, les plastifiants, les hydratants, les agents actifs traitants, les agents alcalinisants ou acidifiants.The mascaras can also contain a conventional additive chosen from softeners, preservatives, sequestering agents, perfumes, oils, silicones, cohesion agents, plasticizers, moisturizers, treating active agents, alkalizing or acidifying agents. .
Selon ce mode de réalisation, les mascaras selon l'invention sont appliqués sur les fibres kératiniques telles que cils, sourcils et les cheveux à l'aide d'une brosse ou d'un pinceau et forment un film lisse et régulier.According to this embodiment, the mascaras according to the invention are applied to keratin fibers such as eyelashes, eyebrows and the hair using a brush or a paintbrush and form a smooth and regular film.
On va maintenant donner à titre d'illustration, plusieurs exemples de préparation des compositions filmogènes selon l'invention.We will now give by way of illustration, several examples of preparation of the film-forming compositions according to the invention.
EXEMPLES DE PREPARATIONPREPARATION EXAMPLES
EXEMPLE 1 : Vernis à onglesEXAMPLE 1 Nail Polish
Nitrocellulose 20 gNitrocellulose 20 g
Acétylcitrate de tributyle 6 gTributyl acetyl citrate 6 g
Résine toluène sulfonamide formaldéhyde 4 g - Tétraborate de potassium 0,4 gToluene sulfonamide formaldehyde resin 4 g - Potassium tetraborate 0.4 g
Argile 1 g Alcool isopropylique 6 gClay 1 g Isopropyl alcohol 6 g
Pigments organiques 0,5 g0.5 g organic pigments
Solvants(Acétate d'éthyle, acétate de butyle 50/50) q.s.p. 100 gSolvents (Ethyl acetate, butyl acetate 50/50) q.s.p. 100g
EXEMPLE 2 : Produit pour le soin des onglesEXAMPLE 2 Product for nail care
Nitrocellulose 20 gNitrocellulose 20 g
Acétylcitrate de tributyle 6 g - Résine alkyde 12 gTributyl acetyl citrate 6 g - Alkyd resin 12 g
Tétraborate de Potassium 0,01 g d-panthénol 1 gPotassium tetraborate 0.01 g d-panthenol 1 g
Alcool isopropylique 6 gIsopropyl alcohol 6 g
D-panthénol 0,5 g - Solvants(Acétate d'éthyle, acétate de butyle 50/50) q.s.p. 100 g D-panthenol 0.5 g - Solvents (Ethyl acetate, butyl acetate 50/50) q.s.p. 100g

Claims

REVENDICATIONS
1. Composition cosmétique filmogène, caractérisée par le fait qu'elle contient, dans un véhicule cosmétiquement approprié, une substance filmogène dérivée de la cellulose et, en tant qu'agent épaississant, une quantité efficace d'un tétraborate de métal alcalin.1. Cosmetic film-forming composition, characterized in that it contains, in a cosmetically suitable vehicle, a film-forming substance derived from cellulose and, as thickening agent, an effective amount of an alkali metal tetraborate.
2. Composition selon la revendication 1 , caractérisée par le fait que le tétraborate de métal alcalin est choisi parmi le tétraborate de potassium, de sodium et de li- thium.2. Composition according to claim 1, characterized in that the alkali metal tetraborate is chosen from potassium, sodium and lithium tetraborate.
3. Composition selon les revendications 1 à 2, caractérisée par le fait que le tétraborate de métal alcalin est présent en une proportion comprise entre 0,01 et 0,1 % en poids par rapport au poids total de la substance filmogène.3. Composition according to Claims 1 to 2, characterized in that the alkali metal tetraborate is present in a proportion of between 0.01 and 0.1% by weight relative to the total weight of the film-forming substance.
4. Composition selon l'une quelconque des revendications précédentes, caractérisée par le fait que ledit véhicule est un mélange de solvants organiques volatils, ladite composition contenant en outre au moins une résine et au moins un agent plastifiant.4. Composition according to any one of the preceding claims, characterized in that the said vehicle is a mixture of volatile organic solvents, the said composition also containing at least one resin and at least one plasticizing agent.
5. Composition selon les revendications 1 à 4, caractérisée par le fait que ladite substance filmogène est la nitrocellulose.5. Composition according to Claims 1 to 4, characterized in that the said film-forming substance is nitrocellulose.
6. Composition selon la revendication 5, caractérisée par le fait que la nitrocellu- lose est présente en une proportion comprise entre 5 et 20 % en poids par rapport au poids total de la composition.6. Composition according to claim 5, characterized in that the nitrocellulose is present in a proportion of between 5 and 20% by weight relative to the total weight of the composition.
7. Composition selon les revendications 4 à 6, caractérisée par le fait que le mélange de solvants organiques volatils est présent en une proportion comprise entre 55 et 90 % en poids par rapport au poids total de la composition. 7. Composition according to Claims 4 to 6, characterized in that the mixture of volatile organic solvents is present in a proportion of between 55 and 90% by weight relative to the total weight of the composition.
8. Composition selon les revendications 4 à 7, caractérisée par le fait que l'agent plastifiant est présent en une proportion comprise entre 2 et 12 % en poids par rapport au poids total de la composition.8. Composition according to Claims 4 to 7, characterized in that the plasticizing agent is present in a proportion of between 2 and 12% by weight relative to the total weight of the composition.
9. Composition selon les revendications 4 à 8, caractérisée par le fait que la résine est présente en une proportion comprise entre 0,5 et 15 % en poids par rapport au poids total de la composition.9. Composition according to Claims 4 to 8, characterized in that the resin is present in a proportion of between 0.5 and 15% by weight relative to the total weight of the composition.
10. Composition selon l'une quelconque des revendications 1 à 9, caractérisée par le fait qu'elle comprend également un pigment de nature organique ou inorganique présent en une proportion comprise entre 0,01 et 5 % en poids par rapport au poids total de la composition.10. Composition according to any one of claims 1 to 9, characterized in that it also comprises an organic or inorganic pigment present in a proportion of between 0.01 and 5% by weight relative to the total weight of the composition.
11. Composition selon l'une quelconque des revendications 1 à 10, caractérisée par le fait qu'elle contient en outre un adjuvant conventionnel choisi dans un groupe constitué par les filtres solaires UVA et/ou UVB, les agents dispersants et mouillants, les agents matifiants, les agents d'adhérence, les agents d'étalement, les agents rhéologiques, les agents thixotropes, les conservateurs, les antioxydants, et les agents actifs traitants de l'ongle.11. Composition according to any one of claims 1 to 10, characterized in that it also contains a conventional adjuvant chosen from a group consisting of UVA and / or UVB sunscreens, dispersing and wetting agents, agents matifiers, adhesion agents, spreading agents, rheological agents, thixotropic agents, preservatives, antioxidants, and active agents treating the nail.
12. Composition selon l'une quelconque des revendications 1 à 11 , caractérisée par le fait qu'elle se présente sous forme d'un vernis à ongles.12. Composition according to any one of claims 1 to 11, characterized in that it is in the form of a nail varnish.
13. Composition selon les revendications 1 à 3, caractérisée par le fait que ladite composition à base d'une substance filmogène dérivée de la cellulose se présente sous forme d'une émulsion huile-dans-eau, d'une émulsion eau-dans-huile, d'une suspension dans un milieu solvant, d'un bloc ou d'une pâte anhydre.13. Composition according to claims 1 to 3, characterized in that said composition based on a film-forming substance derived from cellulose is in the form of an oil-in-water emulsion, a water-in-emulsion oil, a suspension in a solvent medium, a block or an anhydrous paste.
14. Composition selon la revendication 13, caractérisée par le fait qu'elle se pré- sente sous forme d'une émulsion constituée d'une phase aqueuse et d'une phase grasse et d'au moins un agent tensioactif. 14. Composition according to claim 13, characterized in that it is in the form of an emulsion consisting of an aqueous phase and a fatty phase and at least one surfactant.
15. Composition selon les revendications 13 et 14, caractérisée par le fait que la substance filmogène est choisie parmi les esters de cellulose non-ioniques, les esters de cellulose anioniques, et les éthers de cellulose.15. Composition according to Claims 13 and 14, characterized in that the film-forming substance is chosen from non-ionic cellulose esters, anionic cellulose esters, and cellulose ethers.
16. Composition selon les revendications 13 à 15, caractérisée par le fait que la substance filmogène est présente en une proportion comprise entre 5 et 50 % en poids par rapport au poids total de la composition.16. Composition according to Claims 13 to 15, characterized in that the film-forming substance is present in a proportion of between 5 and 50% by weight relative to the total weight of the composition.
17. Composition selon les revendications 13 à 16, caractérisée par le fait que ladite phase grasse est présente en une proportion comprise entre 0,1 et 40 % en poids par rapport au poids total de la composition.17. Composition according to Claims 13 to 16, characterized in that the said fatty phase is present in a proportion of between 0.1 and 40% by weight relative to the total weight of the composition.
18. Composition selon les revendications 13 à 17, caractérisée par le fait que ledit agent tensioactif est présent en une proportion comprise entre 2 et 30 % en poids par rapport au poids total de la composition.18. Composition according to Claims 13 to 17, characterized in that the said surfactant is present in a proportion of between 2 and 30% by weight relative to the total weight of the composition.
19. Composition selon les revendications 13 à 18, caractérisée par le fait qu'elle comprend en outre des pigments présents en une proportion comprise entre 3 et 25 % en poids par rapport au poids total de la composition.19. Composition according to Claims 13 to 18, characterized in that it also comprises pigments present in a proportion of between 3 and 25% by weight relative to the total weight of the composition.
20. Composition selon les revendications 13 à 19, caractérisée par le fait qu'elle contient également au moins un adjuvant conventionnel choisi parmi les adoucissants les conservateurs, les agents séquestrants, les parfums, les huiles, les sili- cônes, les agents de cohésion, les plastifiants, les agents actifs traitants et les agents alkalinisants ou acidifiants.20. Composition according to claims 13 to 19, characterized in that it also contains at least one conventional adjuvant chosen from softeners preservatives, sequestering agents, perfumes, oils, silicones, cohesion agents , plasticizers, active treating agents and alkalinizing or acidifying agents.
21. Composition selon l'une quelconque des revendications 13 à 20, caractérisée par le fait qu'elle se présente sous forme d'un produit de maquillage des cils, sour- cils ou cheveux. 21. Composition according to any one of claims 13 to 20, characterized in that it is in the form of a makeup product for eyelashes, eyelashes or hair.
22. Utilisation d'une composition filmogène selon l'une quelconque des revendications 1 à 12 pour le maquillage et/ou le traitement des ongles.22. Use of a film-forming composition according to any one of claims 1 to 12 for making up and / or treating the nails.
23. Utilisation d'une composition filmogène selon l'une quelconque des revendica- tions 1 à 3 et 13 à 21 pour le maquillage et/ou le soin des cils, des sourcils et des cheveux.23. Use of a film-forming composition according to any one of claims 1 to 3 and 13 to 21 for making up and / or caring for the eyelashes, the eyebrows and the hair.
24. Procédé de maquillage et/ou de traitement des ongles, caractérisé par le fait que l'on applique sur les ongles, une composition selon l'une quelconque des re- vendications 1 à 12.24. Method for making up and / or treating the nails, characterized in that a composition according to any one of claims 1 to 12 is applied to the nails.
25. Procédé de maquillage et/ou de soin des cils, sourcils et cheveux, caractérisé par le fait que l'on applique sur les cils, sourcils et cheveux, une composition selon l'une quelconque des revendications 1 à 3 et 13 à 21. 25. Process for making up and / or caring for eyelashes, eyebrows and hair, characterized in that a composition according to any one of claims 1 to 3 and 13 to 21 is applied to the eyelashes, eyebrows and hair. .
EP98963620A 1997-12-29 1998-12-23 Film-forming cosmetic composition Withdrawn EP0969810A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR9716627A FR2773068B1 (en) 1997-12-29 1997-12-29 FILM-FORMING COSMETIC COMPOSITION BASED ON A CELLULOSE DERIVATIVE CONTAINING, AS A THICKENING AGENT, AN ALKALI METAL TETRABORATE
FR9716627 1997-12-29
PCT/FR1998/002861 WO1999033442A1 (en) 1997-12-29 1998-12-23 Film-forming cosmetic composition

Publications (1)

Publication Number Publication Date
EP0969810A1 true EP0969810A1 (en) 2000-01-12

Family

ID=9515235

Family Applications (1)

Application Number Title Priority Date Filing Date
EP98963620A Withdrawn EP0969810A1 (en) 1997-12-29 1998-12-23 Film-forming cosmetic composition

Country Status (7)

Country Link
EP (1) EP0969810A1 (en)
JP (1) JP2000510876A (en)
KR (1) KR20000075726A (en)
BR (1) BR9807320A (en)
CA (1) CA2281597A1 (en)
FR (1) FR2773068B1 (en)
WO (1) WO1999033442A1 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10252816B4 (en) * 2002-11-13 2008-02-14 Schwan-Stabilo Cosmetics Gmbh & Co. Kg Cosmetic preparation, and a process for its preparation and its use
JP2006045141A (en) * 2004-08-06 2006-02-16 Asanuma Corporation Liquid cosmetic
FR2973389B1 (en) * 2011-03-31 2013-04-19 Lvmh Rech BLACK COLOR MIXTURE AND COMPOSITIONS CONTAINING SAME

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IE42162B1 (en) * 1974-10-11 1980-06-18 Lingner & Fischer Gmbh Thickening solutions of film-forming polymer
NL7711287A (en) * 1977-10-05 1979-04-09 Unilever Nv PROCEDURE TO IMPROVE A LIQUID SOAP PRODUCT.
AU2252388A (en) * 1988-05-02 1989-11-29 Zila Pharmaceuticals Compositions and in situ methods for forming films on body tissue
FR2681782B1 (en) * 1991-09-26 1993-12-17 Oreal COMPOSITION FOR THE TREATMENT OF NAILS CONTAINING A SULFUR AMINOACID.
US5254161A (en) * 1991-10-24 1993-10-19 Aqualon Company Thermally stable nitrocellulose emulsions, solutions and coatings

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO9933442A1 *

Also Published As

Publication number Publication date
JP2000510876A (en) 2000-08-22
BR9807320A (en) 2000-03-21
KR20000075726A (en) 2000-12-26
CA2281597A1 (en) 1999-07-08
FR2773068B1 (en) 2000-09-01
FR2773068A1 (en) 1999-07-02
WO1999033442A1 (en) 1999-07-08

Similar Documents

Publication Publication Date Title
EP0745372B1 (en) Use of colloidal silicic acid to reinforce keratineous fibres
EP0898958B1 (en) Thickened film-forming composition
CH676243A5 (en)
FR2785528A1 (en) COSMETIC COMPOSITION WITH CONTINUOUS LIPOPHILIC PHASE CONTAINING A NEW PIGMENT
FR2737407A1 (en) USE OF HYDROXYLATED CARBOXYLIC ACIDS FOR THE TREATMENT OF KERATINIC MATERIALS
EP0894490A1 (en) Cosmetic compositions comprising a film-forming polymer
EP0620723B1 (en) Film-forming cosmetic composition based on a grafted chlorinated copolymer resulting from the grafting of a chlorinated polyolefin and acrylic, styrene and/or vinyl type unsaturated monomers
EP1000609A1 (en) Use of a cellulose ester for decreasing the drying time of a nail varnish composition containing nitrocellulose
EP0931538B1 (en) Nail varnish composition based on nitrocellulose containing a stabilizing agent
CH678270A5 (en)
EP0755676B1 (en) Use of monocarboxylic acids for the care of keratineous matters
EP0969810A1 (en) Film-forming cosmetic composition
FR2780276A1 (en) Drying accelerators for nail varnishes
EP0758006B1 (en) Process for passivating a photoreactive mineral pigment by an organic cold plasma treatment and lightfast cosmetic or pharmaceutical composition containing at least one thus passivated pigment
FR2819176A1 (en) Peelable film-forming cosmetic composition, e.g. nail varnish, comprises an organic solvent, nitrocellulose, a resin and a polymer capable of forming a peelable film
EP1475072A1 (en) Use of dialkylsulphones in cosmetic compositions for nail care and nail growth promotion
EP1749515B1 (en) Nail coating comprising a polyoxyethylene/polyoxypropylene block polymer
CA2145751C (en) Composition useful for the make up of eyes
FR2785531A1 (en) Nail varnish composition comprising a film-forming polymer, solvent and a fluorinated citric acid ester plasticizer
CA2274941A1 (en) Cosmetic composition in the form of an organic solution or dispersion containing at least a polymeric colouring agent
FR2734718A1 (en) Use of colloidal silica to strengthen keratinic material
FR2734722A1 (en) Use of colloidal silica to strengthen keratinic material
FR2734719A1 (en) Use of colloidal silica to strengthen keratinic material
FR2707493A1 (en) Product based on coloured mineral particles containing a pyrrolic pigment, process for preparing it and its use in cosmetics
FR2907337A1 (en) Nail varnish useful to form a glossy and long lasting film after applying on the nails, comprises an organic solvent medium, film forming polymer and a gelifying agent

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): DE ES FR GB IT

17P Request for examination filed

Effective date: 20000110

17Q First examination report despatched

Effective date: 20021004

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN

18D Application deemed to be withdrawn

Effective date: 20030217