EP0951350A1 - Filter media - Google Patents
Filter mediaInfo
- Publication number
- EP0951350A1 EP0951350A1 EP98900553A EP98900553A EP0951350A1 EP 0951350 A1 EP0951350 A1 EP 0951350A1 EP 98900553 A EP98900553 A EP 98900553A EP 98900553 A EP98900553 A EP 98900553A EP 0951350 A1 EP0951350 A1 EP 0951350A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- filter media
- adsorbent material
- adsorbent
- process according
- substrate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
- B01J20/28028—Particles immobilised within fibres or filaments
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D39/00—Filtering material for liquid or gaseous fluids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D39/00—Filtering material for liquid or gaseous fluids
- B01D39/08—Filter cloth, i.e. woven, knitted or interlaced material
- B01D39/083—Filter cloth, i.e. woven, knitted or interlaced material of organic material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
- B01J20/2803—Sorbents comprising a binder, e.g. for forming aggregated, agglomerated or granulated products
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
- B01J20/28033—Membrane, sheet, cloth, pad, lamellar or mat
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
- B01D2239/04—Additives and treatments of the filtering material
- B01D2239/0407—Additives and treatments of the filtering material comprising particulate additives, e.g. adsorbents
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
- B01D2239/04—Additives and treatments of the filtering material
- B01D2239/0464—Impregnants
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
- B01D2239/06—Filter cloth, e.g. knitted, woven non-woven; self-supported material
- B01D2239/0604—Arrangement of the fibres in the filtering material
- B01D2239/0618—Non-woven
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
- B01D2239/06—Filter cloth, e.g. knitted, woven non-woven; self-supported material
- B01D2239/065—More than one layer present in the filtering material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
- B01D2239/08—Special characteristics of binders
- B01D2239/086—Binders between particles or fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
- B01D2239/12—Special parameters characterising the filtering material
- B01D2239/1233—Fibre diameter
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
- B01D2239/12—Special parameters characterising the filtering material
- B01D2239/1241—Particle diameter
Definitions
- the present invention relates to adsorbent media, particularly of a type formed from a sheet-form carrier substrate incorporating particulate adsorbents therein, and uses thereof in filtration of fluids i.e. by gas/solid liquid/solid interactions wherein the contaminant atom, ion, or molecule of gas or liquid adheres or is otherwise retained by the solid adsorbent particle thereby removing it as a contaminant from the filtered fluid.
- the invention thus finds application in the adsorption of toxic, odiferous, nuisance, radioactive or irritant chemicals from a gaseous or vapour atmosphere, or from a body of liquid, particularly, but not exclusively, in removal of dissolved organic substances from aqueous liquids for example for personal protection.
- adsorbent materials include activated carbon, zeolites, silica and metal oxides including alumina which are often used in particulate form for the purposes of maximising the adsorbent surface.
- EP-A-0 432 438 describes a deodorising unit for air cleaners and air conditioners formed from a moulded mixture of such adsorbent particles, fine plastics particles and a reinforcing fibre.
- a water permeable container filled with a granular adsorbent is described in JP-A-54 105 851, for use in treatment of sewage, industrial effluent etc., containing harmful substances such as heavy metals, N compounds, phosphates etc.
- the granular adsorbents mentioned for that purpose include activated carbon, ion exchange resins, chelate resins, calcium silicate, powdered shell, zeolites, coal, activated alumina, magnesium aluminate, and porous synthetic resins.
- An adsorption filter element comprising a granular adsorbent, such as active carbon, zeolite, silica gel and stone, bonded using a hydrophilic binder e.g. acrylate synthetic resin, covered with a mesh spacer (opening less than 10 mm, thickness 0.2-5 mm) and laminated with filter sheet, e.g. woven cloth and non-woven cloth is described in JP-A-82 94 609.
- a protective mask is described in US-A-4 643 182 which is formed from a porous non-woven sheet material which is made of glass fibres and a suitable binding agent such as polyvinyl alcohol, and which may optionally contain a gas adsorbent substance.
- the mask is intended to protect a wearer from the effects of toxic gases and the like.
- the glass fibres are from about 0.5 microns to 4 microns in diameter and may be from 0.1 inches to 0.25 inches in length.
- the gas adsorbent particles described there include activated carbon particles, crystalline molecular sieve particles or zeolite particles, and the mask may also include anion exchange resin particles.
- an activated carbon filtration medium by a liquid or foam immersion process whereby a substrate is immersed in a liquid or foam containing activated carbon particles.
- This process allows many different types of substrate to be impregnated with activated carbon particles, said substrates being chosen according to the atmosphere to which the filtration medium is to be exposed in use. It also allows for a more even dispersion of activated carbon particles within the matrix of the substrate.
- the activated carbon particles are held generally by entrapment within the matrix of the substrate. Thus, said activated carbon particles are poorly held within the substrate matrix and are easily shed during normal use.
- Activated carbon filtration media can, for example, be employed to adsorb toxic, odoriferous, nuisance, radioactive or irritant chemicals from a gaseous atmosphere or to adsorb dissolved organic compounds from a liquid atmosphere.
- the problem of shedding of the activated carbon particles from the substrate of a filtration medium can lead to the failure of the medium and can in itself represent a hazard particularly where the medium is incorporated in devices or garments for the protection of personnel.
- Shedding is undesirable with any adsorbent material but is a problem which is particularly acute with regard to activated carbon due to the blackening of surfaces contacted by the shed particles.
- handling of filtration media during assembly, maintenance operations etc. is unpleasant and requires clean- up operations and other precautions to avoid contamination with the shed materials.
- binders which can reduce the effective surface available for adsorbent activity.
- An object of the present invention is to obviate or mitigate the aforesaid problems.
- Another object of the invention is to provide improved filtration media suitable for general use in fluid purification by adsorption of impurities from gaseous and/or vapour atmospheres, or from a body of liquid.
- a further object is to provide flexible adsorbent materials which may be readily adopted in protective apparel.
- a still further object is to provide an effective manufacturing process for producing such adsorbent materials and filtration media (hereinafter, simply "filter media”) .
- filter media comprises a fibrous material, preferably a dry laid fibrous web or the like flexible substrate incorporating an adsorbent material in particulate form wherein the adsorbent material is retained within the filter media using a fixing agent whereby in use shedding of the adsorbent material therefrom is inhibited.
- the fibrous material is preferably provided as a non-woven fabric, preferably as a dry laid fibrous web or the like flexible substrate.
- the substrate may comprise a woven fabric, a scrim fabric or any other suitable substrate having a structure capable of retaining adsorbent particles.
- Additional fluid-permeable fabrics may be incorporated in the filter media, and may be of a different structure to the fibrous material incorporating the adsorbent material.
- the additional fluid permeable fabrics may incorporate different adsorbent materials.
- the filter media may be formed as a flat flexible sheet which may be adapted to conform to a surface, e.g. for the purposes of inclusion in a garment, as a laminate, a scroll made up of such a sheet or laminate, or a wadding.
- a process for forming a filter media comprising providing a fluid-permeable carrier substrate containing fibres which are selected from fibres capable of withstanding prolonged contact with a fluid to be filtered, treating the carrier substrate to introduce fixing agents including a binder and a film-former, and particulate adsorbent material (s) to the carrier substrate, wherein the amount of fixing agents, is just sufficient to retain the adsorbent material (s) in the carrier substrate whereby shedding of the adsorbent therefrom is substantially avoided.
- the filter media is formed by selecting a fluid-permeable carrier substrate consisting essentially of fibres and impregnating the substrate with a liquid containing an adsorbent material in particulate form and fixing agents for promoting particle retention in the substrate without occluding the permeability of the substrate, and separating the impregnated substrate and the liquid after a predetermined period sufficient to obtain retention of the particulate adsorbent material in the substrate.
- a preferred liquid for imparting the desired non-shedding characteristics contains a latex binder, such as an acrylics or styrene butadiene latex or natural rubber based binder, especially containing a film former and preferably also an anti-foaming agent.
- a latex binder such as an acrylics or styrene butadiene latex or natural rubber based binder
- film former preferably also an anti-foaming agent.
- film-former means a material capable of forming a film when dry at standard conditions of temperature and pressure (STP) .
- Suitable materials include polyvinyl alcohol, or polyvinyl alcohol/vinyl acetate copolymers, quaternary ammonium salts of polyvinyl pyrolidine/vinyl acetate copolymer amongst other similar film formers, but polyvinyl alcohol is a preferred material.
- Adsorbent materials may be selected according to the intended use from adsorbents which would for the purposes herein involve preferential selection from activated carbon, zeolites, inorganic compounds such as silica and metal oxides e.g. of titanium (Ti0 2 ) , zinc (ZnO), and aluminium in crystalline or micro-crystalline or fine particulate form and mixtures of such adsorbents.
- the activated carbon particles may comprise any one of charcoal, peat, coconut shell, lignite and wood, but preferably comprises charcoal or is lignite based.
- Particle sizes are variable dependent upon the materials selected but a useful working range is from about 0.1 to about
- 300 microns preferably up to about 75 microns, and preferably also not less than about 1 micron, more preferably not less than 25 microns.
- the carrier substrate material may be a non-woven fibre fabric or similar sheet or mat capable of being impregnated with an adsorbent-containing liquid.
- the impregnation may be accomplished by a number of methods which would seek to achieve saturation of the fibres to obtain uniform distribution of the adsorbent and fixing agents (treatment liquor) throughout the fibrous material. These methods would include application to the fibrous material by at least one of the following treatments; saturation by soaking in a convenient manner e.g.
- An immersion treatment such as dip-coating is very flexible in that it allows simple equipment to be adopted even for a continuous production, and permits a wide variety of different substrates to be handled, with the additional advantage of greater certainty of a substantially uniform dispersion of the selected adsorbent throughout the carrier substrate, provided that care is taken to ensure that the period of contact with the chemical treatment liquor is adequate to ensure that the fibrous material is heavily wetted by that liquor.
- a batch dip bath or slow progressive advancement of a web through a dip bath may be preferred for thicker substrates.
- a spray treatment permits quick drying, rapid throughput with an overall fast process rate, and also facilitates presentation of more of the available free surface of the selected adsorbent.
- a spray coating plant can offer economies in plant volume by avoiding the need for the significant space taken up by treatment baths and saturation holding tanks.
- a web of fibrous material of thin to medium thickness suitably suspended between spray nozzles can be saturated quickly by the pressure of the spray jets alone.
- Other ways of saving space for such a treatment plant would include passing a fibrous web under a header tank equipped with means in contact with the web for applying treatment liquor under pressure to forcibly impregnate the web to the desired degree of saturation.
- the forced penetration may be achieved or assisted by reducing ambient pressure on a surface of the web opposite to the liquor receiving surface.
- the fibres to be used are preferably man-made durable materials i.e. synthetic materials of good resilience and impervious to, or at least highly resistant to degradation under contact with the fluid (s) with which it is anticipated normal usage as a filter media would expose the fibres to.
- polyesters Preferably one would use polyester fibres in acidic fluids, nylon or polyvinyl alcohol fibres in alkaline fluids, and rayon viscose fibres for use in contact with vegetable or mineral oil containing fluids.
- polyester fibres may be between 0.5 dtex and 6 dtex but are preferably in the range of 1 dtex to 3 dtex.
- the fibres are synthetic materials formed into a web, mat or similar flexible sheet-form substrate, preferably as a non-woven fabric or as a laminar composite material consisting of layers of woven and/or non-woven fibres.
- Non-woven fabrics suitable for the purposes of this invention are dry-laid fabrics which may be produced using a carding process known in the art such as that process particularly described in GB-A-2 151 667 to which reference is directed.
- non-woven fabrics are also obtainable by entanglement processes, preferably by hydro-entanglement processes known generally in the art of non-woven fabric production.
- Such a fibre entanglement process subjects loose fibres or filaments to a stream or streams of jetted fluid e.g. using air streams (US-A-4 100 324) or using hydraulic fluids (US-A-3 485 706) to intermingle the fibres.
- the filter media contemplated for the purposes of this invention preferably comprises a fibrous web which may contain from 20% to 90% (w/w) , preferably from 30% to 60% by weight, of the filter media sheet-form substrate.
- the amount of fixing agents is suitably in the range of from 5% (w/w) to 45% (w/w) , but preferably is from 15% (w/w) to 30% (w/w) in terms of the finished filter media product.
- a liquid containing the fixing agents which may contain from 5% (w/w) to 95% (w/w) of a latex binder, preferably from 25% (w/w) to 65% (w/w) based on the solids (dry weight as determined at STP) content of the treatment liquid.
- the content thereof in a treatment liquor may be from 0.05% (w/w) and 5% (w/w) , with a preferred range of from 0.4% (w/w) to 1.2% (w/w).
- the amount thereof can be between 0.05% (w/w) and 5.0% (w/w), the preferred range being from 1.5% (w/w) to 3.0% (w/w) .
- adsorbent this would be in the range of from 5% (w/w) and 75% (w/w) , preferably from 15% (w/w) to 65% (w/w) in the finished filter media.
- content of the adsorbent (s) in the treatment liquor again based on the dry weight as determined under STP, this would be from 4% (w/w) to 94% (w/w) , preferably from 1.5% (w/w) to 3.0%(w/w).
- the particle size thereof is in the range of 1 micron to 300 microns, preferably from 25 microns to 75 microns .
- the treatment may be conducted by immersion in a bath of a liquid containing the selected fixing agents and selected adsorbent (s) . This immersion treatment results in impregnation of the carrier substrate.
- the liquid containing the selected fixing agents and selected adsorbent (s) may be applied to a web of the carrier substrate by a spraying process or by a curtain coating (drench or pour- on) type of application.
- an article of apparel such as a protective suit, face mask, industrial glove, apron or article of footwear, including a fabric comprising fibrous materials, preferably as a non-woven (e.g. dry-laid) fabric incorporating an adsorbent material in particulate form which is retained therein by means of a latex binder and a film former present in sufficient quantities to avoid shedding of the particulate adsorbent (s) therefrom but permitting the fabric to retain a high level of fluid permeability.
- a non-woven (e.g. dry-laid) fabric incorporating an adsorbent material in particulate form which is retained therein by means of a latex binder and a film former present in sufficient quantities to avoid shedding of the particulate adsorbent (s) therefrom but permitting the fabric to retain a high level of fluid permeability.
- a filter cartridge for location in a filtration device comprising a non-woven fabric (e.g. dry-laid) incorporating an adsorbent material in particulate form which is retained in the fabric by means of a latex binder and a film former present in sufficient quantities to avoid shedding of the particulate adsorbent (s) therefrom but permitting the fabric to retain a high level of fluid permeability.
- the cartridge may include conventional components in addition to at least one web, or layer, or bundle, or scroll or wadding composed of the said dry-laid non-woven fabric treated in accordance with the invention as hereinbefore described.
- a filter media of polyester fibres having a length in the range of 30 to 50mm and of between 1 and 3 dtex are formed into a sheet which comprises a fibrous web using the carding process detailed in GB-A-2 151 667.
- the sheet may then be impregnated with particles of activated charcoal by a process which involves immersing said sheet for a predetermined period of time in a bath of treatment liquor in which the activated charcoal is suspended.
- the activated charcoal has a particle size in the range of 25 to 75 microns.
- the treatment liquor based on the dry weight as determined under conditions of standard temperature and pressure comprises 25% (w/w) of an acrylic butadiene, 2% (w/w) of a polyvinyl alcohol, and an anti-foaming agent in a suitable organic carrier medium.
- the bulk of the liquor is made up of the particulate activated charcoal.
- the antifoaming agent is a carbon based compound.
- the activated charcoal particles are taken up into the structure of the fibrous web and held in place by the binder and the other fixing agents used.
- the sheet Once the sheet has been immersed for a sufficient period of time it is removed from the bath and the excess liquor allowed to run off and dry.
- the final product is the filter media.
- the activated charcoal remains porous to the gas or liquid passing through the filter media and also is not occluded to any significant degree by the binding agent polyvinyl alcohol/acrylic butadiene which is binding it to the fibres of the filter media.
- a filter media of rayon viscose fibres having a length in the range of 30 to 50mm and of between 1 and 3 dtex are formed into a sheet which comprises a fibrous web using the carding process detailed in GB-A-2 151 667.
- the sheet may then be impregnated with particles of activated charcoal by a process which involves immersing said sheet for a predetermined period of time in a bath of treatment liquor in which the activated charcoal is suspended.
- the activated charcoal has a particle size in the range of 150 to 175 microns.
- the treatment liquor based on the dry weight as determined under conditions of standard temperature and pressure comprises 29% (w/w) of a styrene butadiene, and 1% (w/w) of a polyvinyl acetate/Vinyl acetate copolymer in a suitable organic carrier medium, and in this case no anti- foaming agent is present in this case.
- the bulk of the liquor is made up of the particulate activated charcoal.
- the activated charcoal particles are taken up into the structure of the fibrous web and held in place by the binder and the other fixing agents used.
- the sheet Once the sheet has been immersed for a sufficient period of time it is removed from the bath and the excess liquor allowed to run off and dry.
- the final product is the filter media.
- the activated charcoal remains porous to the gas or liquid passing through the filter media and also is not occluded to any significant degree by the binding agent polyvinyl acetate/vinyl acetate copolymer/styrene butadiene which is binding it to the fibres of the filter media.
- a filter media of nylon fibres having a length in the range of 30 to 50mm and of between 1 and 3 dtex are formed into a sheet which comprises a fibrous web using the carding process detailed in GB-A-2 151 667.
- the sheet may then be impregnated with particles of activated charcoal by a process which involves immersing said sheet for a predetermined period of time in a bath of treatment liquor in which the activated charcoal is suspended.
- the activated charcoal has a particle size in the range of 75 to 125 microns.
- the treatment liquor based on the dry weight as determined under conditions of standard temperature and pressure comprises 35% (w/w) of a natural rubber material, 2% (w/w) of a polyvinyl alcohol, and an anti-foaming agent.
- the bulk of the liquid carrier material is made up of the particulate activated charcoal.
- the anti-foaming agent is silicon based compound.
- the activated charcoal particles are taken up into the structure of the fibrous web and held in place by the binder and the other fixing agents used.
- the filter media is the filter media .
- the activated charcoal remains porous to the gas or liquid passing through the filter media and also is not occluded to any significant degree by the binding agent polyvinyl alcohol/natural rubber material which is binding it to the fibres of the filter media.
- An activated carbon filtration medium not only performs the function of a chemical adsorbate in a gaseous or liquid atmosphere but also acts as a particulate filter by means of physical and/or electrostatic entrapment of particles contained in a flow of gas or liquid passing through the medium, thus providing a means of reducing the amount of impurities in the gas or liquid.
- the activated carbon filtration medium must remain porous to the gas or liquid to be passed therethrough. It must allow easy passage of said gas or liquid through the medium to facilitate contact of activated carbon within the medium and any impurities contained within the gas or liquid thus enabling the activated carbon, through the process of adsorption and aided by particle entrapment by the substrate structure, to reduce the amount of impurities in the gas or liquid.
- An activated carbon filtration medium should exhibit some of the following features: a rapid adsorption of impurities from the gas or liquid passing through the medium; a high free surface area of activated carbon particles available for the adsorption of impurities; good fixation of the activated carbon particles in the filtration substrate in order to prevent shedding of said carbon particles under normal conditions of use; be porous to the gas or liquid to be passed through the medium; and be capable of physical and/or electrostatic entrapment of solid particles in the gas or liquid.
- the present invention enables these functions to be retained yet the shedding problem is solved by providing a substrate which is impregnated with activated carbon particles, wherein said particles are fixed within the structure of the substrate such that the free surface area of the carbon particles is not occluded by more than a minimum amount required for the continued efficacy of the carbon particles as an adsorbate for impurities in gaseous or liquid atmospheres and, in such a manner, that said filtering means does not shed the carbon particles in use.
- a filter media is formed and treated as detailed in Example 1 except in this case the activated charcoal is replaced with a particulate Zeolite.
- a filter media is formed and treated as detailed in Example 2 except in this case the activated charcoal is replaced with particulate Titania.
- a filter media is formed and treated as detailed in Example 1 except in this case the activated charcoal is replaced with a particulate Silica.
- a filter media is formed and treated as detailed in Example 3 except in this case the activated charcoal is replaced with a particulate Zinc Oxide.
- EXAMPLE 8 A filter media is formed and treated as detailed in Example 3 except in this case the activated charcoal is replaced with a particulate Aluminium Oxide.
- a filter media is formed from vinyl acetate fibres as per example 1 and treated as per said example.
- a filter media of polyester fibres having a length in the range of 30 to 50mm and of between 1 and 3 dtex are formed into a sheet which comprises a fibrous web using the carding process detailed in GB-A-2 151 667.
- the sheet may then be impregnated with particles of activated charcoal by a process which involves spraying the sheet a treatment liquor in which the activated charcoal is suspended, so that it is saturated from all sides and in effect immersing said sheet in the treatment liquor.
- the activated charcoal has a particle size in the range of 25 to 75 microns.
- the treatment liquor based on the dry weight as determined under conditions of standard temperature and pressure comprises 25% (w/w) of an acrylic butadiene, 2% (w/w) of a polyvinyl alcohol, and an anti-foaming agent in a suitable organic carrier medium.
- the bulk of the liquor is made up of the particulate activated charcoal.
- the anti- foaming agent is carbon based compound.
- the effective immersion of the sheet in the treatment liquor means that the activated charcoal particles are taken up into the structure of the fibrous web and held in place by the binder and any other fixing agents used.
- the final product is the filter media.
- the activated charcoal remains porous to the gas or liquid passing through the filter media and also is not occluded to any significant degree by the binding agent polyvinyl alcohol/acrylic butadiene which is binding it to the fibres of the filter media.
- a filter media of polyester fibres having a length in the range of 30 to 50mm and of between 1 and 3 dtex are formed into a sheet which comprises a fibrous web using the carding process detailed in GB-A-2 151 667.
- the sheet may then be impregnated with particles of activated charcoal by a process which involves continuously dip coating the sheet in a trough of a treatment liquor in which the activated charcoal is suspended, so that it is saturated from all sides.
- the activated charcoal has a particle size in the range of 25 to 75 microns.
- the treatment liquor based on the dry weight as determined under conditions of standard temperature and pressure comprises 25% (w/w) of an acrylic butadiene, 2% (w/w) of a polyvinyl alcohol, and an anti-foaming agent in a suitable organic carrier medium.
- the bulk of the liquor is made up of the particulate activated charcoal.
- the anti- foaming agent is a silicon based compound.
- the effective immersion of the sheet in the treatment liquor means that the activated charcoal particles are taken up into the structure of the fibrous web and held in place by the binder and any other fixing agents used.
- the sheet is then allowed suspended so that the excess liquor is allowed to run off and the sheet is then allowed to dry.
- the final product is the filter media.
- the activated charcoal remains porous to the gas or liquid passing through the filter media and also is not occluded to any significant degree by the binding agent polyvinyl alcohol/acrylic butadiene which is binding it to the fibres of the filter media.
- This type of mask is useful, for example to workers who are handling radioactive and /or hazardous vapour emitting chemicals such as mercury.
- a filter media as per one aspect of the present invention and as illustrated in Figure 2 of the drawings can be made using the sheets as made and treated in accordance with the present invention.
- the filtering media comprises a plastic casing 10 which is designed to be push-fitted into separate face covering breathing apparatus.
- the casing 10 comprises a sidewall 11, a back-wall 12 having a number of perforations 12a formed therein, and a front-wall 13 formed in a lattice type way and having a series of holes therein. Once fitted in the breathing apparatus the passage of air to the user is via the holes in the front-wall 13 through the filter media 14 and out through the perforations 12a in the back-wall 12.
- the filter media 14 is located and secured in the casing 10 so that any air being drawn through the filtering media has to pass therethrough before it can be breathed in by the user.
- the filter media 14 comprises a wad of material 15 which has a number of individual layers at least one of which layers is a sheet of material as made and treated in accordance with Example 3.
- a filter media as per Example 11 except the wad of material 15 is with a number of layers of material made and treated in accordance with the examples detailed above.
- the wad can include several layers of a sheet made in accordance with one example, for example Example 1, or layers of sheets made and treated in accordance with several of the examples.
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Filtering Materials (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
Description
Claims
Applications Claiming Priority (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GBGB9700339.6A GB9700339D0 (en) | 1997-01-09 | 1997-01-09 | An activated carbon filtering means |
GB9700339 | 1997-01-09 | ||
GBGB9725993.1A GB9725993D0 (en) | 1997-12-09 | 1997-12-09 | A zeolite molecular sieve filtering means |
GB9725991 | 1997-12-09 | ||
GBGB9725991.5A GB9725991D0 (en) | 1997-12-09 | 1997-12-09 | An inorganic oxide filtering means |
GB9725993 | 1997-12-09 | ||
PCT/GB1998/000001 WO1998030326A1 (en) | 1997-01-09 | 1998-01-09 | Filter media |
Publications (1)
Publication Number | Publication Date |
---|---|
EP0951350A1 true EP0951350A1 (en) | 1999-10-27 |
Family
ID=27268660
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP98900553A Withdrawn EP0951350A1 (en) | 1997-01-09 | 1998-01-09 | Filter media |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP0951350A1 (en) |
JP (1) | JP2001507984A (en) |
CN (1) | CN1247485A (en) |
CA (1) | CA2277478A1 (en) |
GB (1) | GB2336793B (en) |
WO (1) | WO1998030326A1 (en) |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU2002239510A1 (en) * | 2000-12-06 | 2002-06-18 | Uop Llc | Adsorbent sheet, process of preparing, and desiccant process for using the sheet |
GB2407327A (en) * | 2003-10-24 | 2005-04-27 | Reckitt Benckiser | Tear-off odour-reducing sheets |
DE102005020076A1 (en) * | 2005-04-29 | 2006-11-09 | W.L. Gore & Associates Gmbh | garment |
BRPI0707753A2 (en) * | 2006-02-13 | 2011-05-10 | Donaldson Co Inc | filter web comprising fine fiber and particulate reactive, adsorptive or absorptive |
JP5470850B2 (en) * | 2007-09-28 | 2014-04-16 | 東レ株式会社 | Filter media and filter unit |
JP5870394B2 (en) * | 2010-07-02 | 2016-03-01 | 文男 前川 | Liquid composition mainly composed of powder ion exchange resin and support containing powder ion exchange resin |
WO2013088260A1 (en) | 2011-12-16 | 2013-06-20 | Helen Of Troy Limited | Gravity filter |
JP2013184149A (en) * | 2012-03-09 | 2013-09-19 | Central Research Institute Of Electric Power Industry | Contaminant adsorption sheet |
CN105983386B (en) * | 2015-02-26 | 2019-04-30 | 天津市四维康环保科技发展有限公司 | A kind of preparation method of non-woven fabrics |
US10543441B2 (en) | 2016-12-15 | 2020-01-28 | Hollingsworth & Vose Company | Filter media including adhesives and/or oleophobic properties |
US10898838B2 (en) | 2016-12-15 | 2021-01-26 | Hollingsworth & Vose Company | Filter media including adhesives |
US10537838B2 (en) * | 2016-12-20 | 2020-01-21 | Kx Technologies Llc | Antimicrobial composite filtering material and method for making the same |
EP3600601A4 (en) * | 2017-03-28 | 2021-01-13 | Hollingsworth & Vose Company | Filter media including adhesives and/or oleophobic properties |
CN107376508A (en) * | 2017-09-19 | 2017-11-24 | 江苏科力特环保科技有限公司 | A kind of new water purification active carbon filter core |
WO2019133543A1 (en) * | 2017-12-31 | 2019-07-04 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Method for manufacturing a solid adsorbent fiber |
MX2020010426A (en) * | 2018-04-04 | 2020-10-28 | Unifrax I Llc | Activated porous fibers and products including same. |
CN114602244B (en) * | 2021-04-14 | 2024-07-05 | 江苏长海复合材料股份有限公司 | Preparation method and application of air filtering material for automobile roof |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3019127A (en) * | 1957-10-07 | 1962-01-30 | American Air Filter Co | Filtering medium and method of making the same |
CA1207736A (en) * | 1983-06-17 | 1986-07-15 | James K. Dix | Paper containing activated carbon |
SE452854B (en) * | 1985-01-17 | 1987-12-21 | Gedevelop Ab | FLUIDUM PERMEABLE FIBER MATRIX AND SET FOR ITS PREPARATION |
US5124177A (en) * | 1988-05-20 | 1992-06-23 | D-Mark, Inc. | Filter and method of making same |
JPH0280696A (en) * | 1988-09-17 | 1990-03-20 | Tokushu Seishi Kk | Neutral paper having moisture-absorbing and-desorbing ability and having excellent gas-adsorbing ability and production thereof |
JPH03258319A (en) * | 1990-03-07 | 1991-11-18 | Kuraray Chem Corp | Air cleaning filter |
JP3728475B2 (en) * | 1996-04-12 | 2005-12-21 | クラレケミカル株式会社 | Adsorbent with dust filter function |
-
1998
- 1998-01-09 CN CN 98802553 patent/CN1247485A/en active Pending
- 1998-01-09 EP EP98900553A patent/EP0951350A1/en not_active Withdrawn
- 1998-01-09 JP JP53061898A patent/JP2001507984A/en active Pending
- 1998-01-09 WO PCT/GB1998/000001 patent/WO1998030326A1/en not_active Application Discontinuation
- 1998-01-09 CA CA002277478A patent/CA2277478A1/en not_active Abandoned
- 1998-01-09 GB GB9915943A patent/GB2336793B/en not_active Expired - Fee Related
Non-Patent Citations (1)
Title |
---|
See references of WO9830326A1 * |
Also Published As
Publication number | Publication date |
---|---|
GB9915943D0 (en) | 1999-09-08 |
GB2336793A (en) | 1999-11-03 |
WO1998030326A1 (en) | 1998-07-16 |
CA2277478A1 (en) | 1998-07-16 |
CN1247485A (en) | 2000-03-15 |
GB2336793B (en) | 2000-11-29 |
JP2001507984A (en) | 2001-06-19 |
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