EP0899325B1 - Weichspülmittelzusammemsetzung - Google Patents
Weichspülmittelzusammemsetzung Download PDFInfo
- Publication number
- EP0899325B1 EP0899325B1 EP98810753A EP98810753A EP0899325B1 EP 0899325 B1 EP0899325 B1 EP 0899325B1 EP 98810753 A EP98810753 A EP 98810753A EP 98810753 A EP98810753 A EP 98810753A EP 0899325 B1 EP0899325 B1 EP 0899325B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- alkyl
- formula
- alkoxy
- independently
- phthalocyanine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title claims description 68
- 239000002979 fabric softener Substances 0.000 title claims description 31
- -1 alkoxide carboxylate Chemical class 0.000 claims description 52
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 claims description 31
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 30
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 27
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 23
- 229910052739 hydrogen Inorganic materials 0.000 claims description 21
- 239000001257 hydrogen Substances 0.000 claims description 21
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims description 20
- 229910052736 halogen Inorganic materials 0.000 claims description 20
- 150000003856 quaternary ammonium compounds Chemical class 0.000 claims description 19
- 150000002367 halogens Chemical group 0.000 claims description 16
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 16
- 150000001450 anions Chemical class 0.000 claims description 15
- 239000004753 textile Substances 0.000 claims description 15
- 229910052757 nitrogen Inorganic materials 0.000 claims description 14
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 claims description 14
- 229910052725 zinc Inorganic materials 0.000 claims description 14
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 13
- 229910052700 potassium Inorganic materials 0.000 claims description 13
- 229910052708 sodium Inorganic materials 0.000 claims description 13
- 229910052749 magnesium Inorganic materials 0.000 claims description 12
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 11
- 239000000194 fatty acid Substances 0.000 claims description 11
- 229930195729 fatty acid Natural products 0.000 claims description 11
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 10
- 229910052791 calcium Inorganic materials 0.000 claims description 10
- 150000004665 fatty acids Chemical class 0.000 claims description 10
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims description 9
- 229910002651 NO3 Inorganic materials 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- 150000002431 hydrogen Chemical class 0.000 claims description 9
- 229910052760 oxygen Inorganic materials 0.000 claims description 9
- 239000001301 oxygen Substances 0.000 claims description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 8
- 238000004061 bleaching Methods 0.000 claims description 8
- JOPOVCBBYLSVDA-UHFFFAOYSA-N chromium(6+) Chemical compound [Cr+6] JOPOVCBBYLSVDA-UHFFFAOYSA-N 0.000 claims description 8
- 150000004820 halides Chemical class 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 7
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 7
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 7
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 7
- 150000003839 salts Chemical class 0.000 claims description 7
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- CKHJYUSOUQDYEN-UHFFFAOYSA-N gallium(3+) Chemical compound [Ga+3] CKHJYUSOUQDYEN-UHFFFAOYSA-N 0.000 claims description 6
- 125000005843 halogen group Chemical group 0.000 claims description 6
- 229910052710 silicon Inorganic materials 0.000 claims description 6
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims description 5
- NFGODEMQGQNUKK-UHFFFAOYSA-M [6-(diethylamino)-9-(2-octadecoxycarbonylphenyl)xanthen-3-ylidene]-diethylazanium;chloride Chemical group [Cl-].CCCCCCCCCCCCCCCCCCOC(=O)C1=CC=CC=C1C1=C2C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C21 NFGODEMQGQNUKK-UHFFFAOYSA-M 0.000 claims description 5
- 150000002148 esters Chemical class 0.000 claims description 5
- 239000000835 fiber Substances 0.000 claims description 5
- 239000003760 tallow Substances 0.000 claims description 5
- 125000000229 (C1-C4)alkoxy group Chemical group 0.000 claims description 4
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 4
- 150000008051 alkyl sulfates Chemical class 0.000 claims description 4
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 4
- 125000001624 naphthyl group Chemical group 0.000 claims description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 3
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052794 bromium Inorganic materials 0.000 claims description 3
- 239000000460 chlorine Substances 0.000 claims description 3
- 229910052801 chlorine Inorganic materials 0.000 claims description 3
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 3
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 3
- 229920006395 saturated elastomer Polymers 0.000 claims description 3
- NAWXUBYGYWOOIX-SFHVURJKSA-N (2s)-2-[[4-[2-(2,4-diaminoquinazolin-6-yl)ethyl]benzoyl]amino]-4-methylidenepentanedioic acid Chemical compound C1=CC2=NC(N)=NC(N)=C2C=C1CCC1=CC=C(C(=O)N[C@@H](CC(=C)C(O)=O)C(O)=O)C=C1 NAWXUBYGYWOOIX-SFHVURJKSA-N 0.000 claims description 2
- 125000001140 1,4-phenylene group Chemical group [H]C1=C([H])C([*:2])=C([H])C([H])=C1[*:1] 0.000 claims description 2
- 125000002373 5 membered heterocyclic group Chemical group 0.000 claims description 2
- 125000004070 6 membered heterocyclic group Chemical group 0.000 claims description 2
- 150000001449 anionic compounds Chemical class 0.000 claims description 2
- 125000003118 aryl group Chemical group 0.000 claims description 2
- 150000001768 cations Chemical class 0.000 claims description 2
- 229910001412 inorganic anion Inorganic materials 0.000 claims description 2
- 239000000463 material Substances 0.000 claims description 2
- 150000002891 organic anions Chemical class 0.000 claims description 2
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 2
- 125000004076 pyridyl group Chemical group 0.000 claims description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 claims description 2
- 125000004434 sulfur atom Chemical group 0.000 claims description 2
- 229910001413 alkali metal ion Inorganic materials 0.000 claims 3
- ORTFAQDWJHRMNX-UHFFFAOYSA-M oxidooxomethyl Chemical compound [O-][C]=O ORTFAQDWJHRMNX-UHFFFAOYSA-M 0.000 claims 2
- JYNZIOFUHBJABQ-UHFFFAOYSA-N allyl-{6-[3-(4-bromo-phenyl)-benzofuran-6-yloxy]-hexyl-}-methyl-amin Chemical group C=1OC2=CC(OCCCCCCN(C)CC=C)=CC=C2C=1C1=CC=C(Br)C=C1 JYNZIOFUHBJABQ-UHFFFAOYSA-N 0.000 claims 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 1
- 150000002500 ions Chemical class 0.000 claims 1
- 238000009472 formulation Methods 0.000 description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 19
- 239000004744 fabric Substances 0.000 description 14
- 238000005406 washing Methods 0.000 description 14
- 125000000217 alkyl group Chemical group 0.000 description 13
- 229920000742 Cotton Polymers 0.000 description 12
- 150000001875 compounds Chemical class 0.000 description 11
- 239000003599 detergent Substances 0.000 description 10
- 239000011734 sodium Substances 0.000 description 10
- 125000003342 alkenyl group Chemical group 0.000 description 8
- 239000011575 calcium Substances 0.000 description 8
- 239000011777 magnesium Substances 0.000 description 8
- 125000001424 substituent group Chemical group 0.000 description 7
- 0 CC1*CCC1 Chemical compound CC1*CCC1 0.000 description 6
- 244000269722 Thea sinensis Species 0.000 description 6
- 229940077464 ammonium ion Drugs 0.000 description 6
- 239000007844 bleaching agent Substances 0.000 description 6
- 239000013543 active substance Substances 0.000 description 5
- 125000003545 alkoxy group Chemical group 0.000 description 5
- 239000002657 fibrous material Substances 0.000 description 5
- 125000006527 (C1-C5) alkyl group Chemical group 0.000 description 4
- 229910052783 alkali metal Inorganic materials 0.000 description 4
- 150000001340 alkali metals Chemical class 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 235000020095 red wine Nutrition 0.000 description 4
- 125000004191 (C1-C6) alkoxy group Chemical group 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 150000007942 carboxylates Chemical class 0.000 description 3
- CTYRPMDGLDAWRQ-UHFFFAOYSA-N phenyl hydrogen sulfate Chemical compound OS(=O)(=O)OC1=CC=CC=C1 CTYRPMDGLDAWRQ-UHFFFAOYSA-N 0.000 description 3
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical group C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 2
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 230000001678 irradiating effect Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N palmitic acid group Chemical group C(CCCCCCCCCCCCCCC)(=O)O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 125000000923 (C1-C30) alkyl group Chemical group 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- RHQQHZQUAMFINJ-GKWSUJDHSA-N 1-[(3s,5s,8s,9s,10s,11s,13s,14s,17s)-3,11-dihydroxy-10,13-dimethyl-2,3,4,5,6,7,8,9,11,12,14,15,16,17-tetradecahydro-1h-cyclopenta[a]phenanthren-17-yl]-2-hydroxyethanone Chemical compound C1[C@@H](O)CC[C@]2(C)[C@H]3[C@@H](O)C[C@](C)([C@H](CC4)C(=O)CO)[C@@H]4[C@@H]3CC[C@H]21 RHQQHZQUAMFINJ-GKWSUJDHSA-N 0.000 description 1
- GQEZCXVZFLOKMC-UHFFFAOYSA-N 1-hexadecene Chemical compound CCCCCCCCCCCCCCC=C GQEZCXVZFLOKMC-UHFFFAOYSA-N 0.000 description 1
- 125000004974 2-butenyl group Chemical group C(C=CC)* 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- 125000004975 3-butenyl group Chemical group C(CC=C)* 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- GESFNQOJVBMNHY-UHFFFAOYSA-N C1C2N(C3)C3CC12 Chemical compound C1C2N(C3)C3CC12 GESFNQOJVBMNHY-UHFFFAOYSA-N 0.000 description 1
- NZZNMDNKJVUJAL-UHFFFAOYSA-N CCC1NCC1 Chemical compound CCC1NCC1 NZZNMDNKJVUJAL-UHFFFAOYSA-N 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 240000000491 Corchorus aestuans Species 0.000 description 1
- 235000011777 Corchorus aestuans Nutrition 0.000 description 1
- 235000010862 Corchorus capsularis Nutrition 0.000 description 1
- 229920000727 Decyl polyglucose Polymers 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- YITMLDIGEJSENC-UHFFFAOYSA-N Hexadecen Natural products CCCCCCCCCCCCCC=CC YITMLDIGEJSENC-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 1
- JVTAAEKCZFNVCJ-UHFFFAOYSA-M Lactate Chemical compound CC(O)C([O-])=O JVTAAEKCZFNVCJ-UHFFFAOYSA-M 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000013011 aqueous formulation Substances 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-M benzenesulfonate Chemical compound [O-]S(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-M 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 235000005607 chanvre indien Nutrition 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 239000007920 enema Substances 0.000 description 1
- 229940095399 enema Drugs 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 230000002070 germicidal effect Effects 0.000 description 1
- 125000005456 glyceride group Chemical group 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000003707 hexyloxy group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])O* 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000000555 isopropenyl group Chemical group [H]\C([H])=C(\*)C([H])([H])[H] 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000005394 methallyl group Chemical group 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000006174 pH buffer Substances 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002958 pentadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000005956 quaternization reaction Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000004627 regenerated cellulose Substances 0.000 description 1
- WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical compound CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 description 1
- 229960003656 ricinoleic acid Drugs 0.000 description 1
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000011550 stock solution Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 235000014101 wine Nutrition 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/395—Bleaching agents
- C11D3/3951—Bleaching agents combined with specific additives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
- C11D3/0015—Softening compositions liquid
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0063—Photo- activating compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/168—Organometallic compounds or orgometallic complexes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/12—Soft surfaces, e.g. textile
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/40—Specific cleaning or washing processes
- C11D2111/46—Specific cleaning or washing processes applying energy, e.g. irradiation
Definitions
- the present invention relates to a fabric softener composition and a Process for bleaching textile fiber materials using this fabric softener composition.
- the object of the present invention is to provide water-soluble phthalocyanine compounds as a photo bleach in certain fabric softener compositions to use, which contain so-called "esterquats" as active substance, these are quaternary Ammonium compounds, at least one interrupted by carboxy groups have long chain hydrophobic alkyl or alkenyl group. Containing esterquats Fabric softeners are described, for example, in EP-A-0,239,910 or WO 95/24460.
- the number of substituents Q 1 and Q 2 in formulas (2a) and (2b), which may be the same or different, is between 1 and 8, and, as is customary for phthalocyanines, does not have to be an integer (degree of substitution) . If other non-cationic substituents are also present, the sum of the latter and the cationic substituents is between 1 and 4.
- the minimum number of substituents that must be present in the molecule depends on the water solubility of the resulting molecule. Sufficient water solubility is given when enough phthalocyanine compound goes into solution to cause photodynamically catalyzed oxidation on the fiber. A solubility of 0.01 mg / l may be sufficient, in general that of 0.001 to 1 g / l is appropriate.
- Halogen means fluorine, bromine or especially chlorine.
- the group is preferred
- heterocyclic rings in the group the groups mentioned above are also suitable, with only the binding to the residual substituents taking place via a carbon atom.
- phenyl, naphthyl and aromatic hetero rings can be substituted by one or two further radicals, for example by C 1 -C 6 alkyl, C 1 -C 6 alkoxy, halogen carboxy, carb-C 1 -C 6 - Alkoxy, hydroxy, amino, cyano, sulfo, sulfonamido etc.
- All of the nitrogen heterocycles mentioned above can still be by alkyl groups be substituted, either on a carbon atom or on another in the ring located nitrogen atom.
- Preferred as the alkyl group is the methyl group.
- a - s in formula (2a) means any anion as a counterion to the positive charge of the residual molecule. It is generally introduced through the manufacturing process (quaternization). It then preferably means a halogen ion, an alkyl sulfate or an aryl sulfate ion. Of the aryl sulfate ions, the phenyl sulfonate, p-tolyl sulfonate and p-chlorophenyl sulfonate ions are mentioned.
- any other anion can also act as the anion, since the anions can be easily exchanged in a known manner;
- a s - can also represent a sulfate, sulfite, carbonate, phosphate, nitrate, acetate, oxalate, citrate, lactate or other anion of an organic carboxylic acid.
- the index s is r for monovalent anions.
- s assumes a value ⁇ r, which, depending on the conditions, must be such that it just compensates for the positive charge of the residual molecule.
- C 1 -C 6 -alkyl and C 1 -C 6 -alkoxy are straight-chain or branched alkyl or alkoxy radicals such as methyl, ethyl, n-propyl, isopropyl, n-butyl, sec-butyl, tert-butyl, amyl, Isoamyl, tert-amyl or hexyl or methoxy, ethoxy, n-propoxy, isopropoxy, n-butoxy, sec-butoxy, tert-butoxy, amyloxy, isoamyloxy, tert-amyloxy or hexyloxy.
- C 2 -C 22 alkenyl means, for example, allyl, methallyl, isopropenyl, 2-butenyl, 3-butenyl, isobutenyl, n-penta-2,4-dienyl, 3-methyl-but-2-enyl, n-oct-2 -enyl, n-dodec-2-enyl, iso-dodecenyl, n-dodec-2-enyl or n-octadec-4-enyl.
- the C 8 -C 20 fatty acid residues defined for the quaternary ammonium compounds of the formula (1) are derived from saturated or unsaturated fatty acids, such as, for example, capric, lauric, myristic, palmitic, stearic, dodecyl; Pentadecyl; Hexadecyl or oleic acid; or decen, dodecen, tetradecen, hexadecen, oleic, linoleic, linolenic, ricinoleic acid, coconut fatty acid, or preferably tallow fatty acid.
- saturated or unsaturated fatty acids such as, for example, capric, lauric, myristic, palmitic, stearic, dodecyl; Pentadecyl; Hexadecyl or oleic acid; or decen, dodecen, tetradecen, hexadecen, oleic
- R 16 , R 17 , R 18 , R 19 , R 20 , R 21 , R 22 , R 23 , B 2 , B 3 , M, M 1 , Q 1 , Q 2 , A s , T 1 , X 1 , Y 2 , Z 2 a, b, c, d, e, r, v, w have the meaning given in the formulas (2a) and (2b).
- Quaternary ammonium compounds which can be used according to the invention are particularly preferred are those of formula (1), wherein A and B represent the rest of the formula (1b).
- the photobleaches used according to the invention are in the fabric softener composition used in only small amounts and therefore have catalytic Effect.
- the fabric softener compositions according to the invention preferably contain 0.0001 to 0.05, preferably 0.001 to 0.005% by weight of component (a) and 1 to 20, preferably 5 to 20% by weight of component (b).
- the fabric softener composition according to the invention can also be that for commercially available Contain conventional additives such as alcohols, e.g. Ethanol, n-propanol, i-propanol, polyhydric alcohols, e.g.
- Glycerin and propylene glycol amphoteric and nonionic surfactants such as Carboxyl derivatives of imidazole, ethoxylated fatty alcohols, hydrogenated and ethoxylated castor oil, alkyl polyglycosides, for example decyl polyglucose and dodecyl polyglucose, fatty alcohols, fatty acid esters, fatty acids, ethoxylated Fatty acid glycerides or fatty acid partial glycerides; still smaller amounts of dyes, Perfumes, buffer substances, inorganic or organic salts, e.g.
- amphoteric and nonionic surfactants such as Carboxyl derivatives of imidazole, ethoxylated fatty alcohols, hydrogenated and ethoxylated castor oil, alkyl polyglycosides, for example decyl polyglucose and dodecyl polyglucose, fatty alcohols, fatty acid est
- water soluble Potassium, sodium or magnesium salts non-aqueous solvents, pH buffers, perfumes, Dyes, hydrotroping agents, anti-foaming agents, corrosion inhibitors, anti-redeposition agents, Viscosity regulators, in particular polymeric or other thickeners, stabilizers, Enzymes, optical brighteners, anti-enema agents, anti-stain agents, antimicrobials, germicides, Fungicides, antioxidants, corrosion inhibitors and wrinkle free agents.
- the fabric softener composition according to the invention is usually liquid.
- the one in it Active ingredients contained are preferably emulsified in water.
- the production takes place usually in such a way that the active substance, i.e. the quaternary ammonium compound of the formula (1) stirred in water in the molten state, then optionally Add further desired additives and finally, after cooling, the Add phthalocyanine compound as a dilute stock solution.
- the composition according to the invention is used in the for known Fabric softener usual way, the photobleaching agent only by irradiation with Light takes effect, e.g. in US-A-4,166,718.
- the photobleaching agent only by irradiation with Light takes effect, e.g. in US-A-4,166,718.
- a washing cycle in a liquor containing an inventive
- Contains fabric softener composition aftertreated in one rinse cycle.
- Irradiation with visible and / or infrared light or in daylight can take place directly in the fabric softener liquor, for example by means of a corresponding artificial light source in the washing machine.
- the radiation can also be preferred after removing the textiles from the rinsing bath in a damp state, whereby sunlight is preferably used as the light source.
- the exposure can be in this case expediently take place while the textiles are drying.
- the textiles are not on the line, but dried in a tumble dryer, for example, the exposure also take place during this drying process, for example by a suitable one artificial light source, which is attached to or in the dryer.
- a suitable one artificial light source which is attached to or in the dryer.
- oxygen is also required for the effectiveness of the photobleaching agent.
- the (dissolved) oxygen present in the wash liquor is sufficient (the liquor should if possible contain no reducing agent) or the oxygen dissolved in the moisture and atmospheric oxygen if the exposure is outside the bath.
- textile fiber materials with the inventive fabric softener composition can be treated, e.g. Silk, wool, polyamide materials or polyurethanes, and in particular cellulose-containing fiber materials of all kinds in Consideration.
- Such fiber materials are, for example, the natural cellulose fiber, such as Cotton, linen, jute and hemp, as well as cellulose and regenerated cellulose.
- Prefers are textile fiber materials made of cotton.
- the fabric softener compositions according to the invention are also suitable for fibers containing hydroxyl groups in mixed fabrics are included, e.g. Mixtures of cotton with polyester fibers or polyamide fibers.
- the effect of the photo bleaching agent will remove stains from the treated Tissue significantly improved. This also allows color transfers between individual pieces of tissue can be prevented or reduced.
- composition according to the invention has the advantage that the essential components in their effect do not influence each other, that is Bleaching action of the photo bleaching agent through the quaternary ammonium compound and conversely is not affected.
- Bleaching agent compositions are already known from US-A-4,240,920 and US-A-4,255,273 known, which is a metal phthalocyanine and a surface-active quaternary ammonium compound contain.
- the quaternary ammonium compound used is significantly different from the compounds used in the present application.
- a viscous, homogeneous liquid is created.
- Example 5 (comparative example )
- Y brightness values
- Table 2 Formulation from example without exposure with 2 h exposure Y [%] ⁇ Y Y [%] ⁇ Y 1 68.1 71.1 2 67.9 -0.2 74 2.9 3rd 67.3 -0.8 75.9 4.8 4th 67.6 -0.5 77.8 6.7
- Example 6 (Comparative example ) The procedure is as described in Example 5, with the difference that cotton fabric soiled with tea is used.
- Example 7 (Comparative example ) The procedure is as described in Example 5, with the difference that cotton fabric soiled with coffee is used.
- the fabric After washing, the fabric is rinsed under running water.
- 1 part of the fabric is ironed dry. 1 part of the fabric soiled with wine and coffee is exposed for 4 hours under Osram lamps and then ironed dry.
- the tissue soiled with tea is exposed to moisture under Osram lamps for 2 hours and subsequently ironed dry.
- results of the washing test of the tea soiled tissue tissue soiled with tea Y (start) 35.5 after 1 wash cycle after 3 washing cycles after 5 washing cycles exposure without 2 hours without 2 hours without 2 hours Y ⁇ Y Y ⁇ Y Y ⁇ Y Y ⁇ Y Y ⁇ Y Y ⁇ Y Formulation 8a) 40.6 40.7 41.2 44.7 41.3 49.9 Formulation 8b) 40.2 -0.4 43.4 2.7 41.6 0.4 53.4 8.7 41.6 0.3 63.5 13.6
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
Description
- R1 und R2 unabhängig voneinander C1-C5-Alkyl; oder Hydroxy-C1-C5-Alkyl;
- A und B unabhängig voneinander je den Rest der Formel
- R3, R4 und R5 unabhängig voneinander einen C8-C20-Fettsäurerest;
- X1 -
- ein für Weichmacher kompatibles Anion;
- m, n und p eine Zahl von 0 bis 5;
- PC
- das Phthalocyaninringsystem;
- Me
- Zn, Fe(II), Ca, Mg, Na, K, Al-Z1, Si(IV), P(V), Ti(IV), Ge(IV), Cr(VI), Ga(III), Zr(IV), In(III), Sn(IV) oder Hf(VI);
- Z1
- ein Halogenid-, Sulfat-, Nitrat-, Acetat-, Alkoholat-, Carboxylat- oder Hydroxy-Ion;
- q
- 0,1 oder 2;
- r
- 1 bis 4;
- Q1
- eine Sulfo- oder Carboxylgruppe; oder einen Rest der Formel -SO2X2-R6-X3 +, -O-R6-X3 +; oder -(CH2)t-Y1 +;
- R6
- verzweigtes oder unverzweigtes C1-C8-Alkylen; oder 1,3- oder 1,4-Phenylen;
- X2
- -NH-; oder -N-C1-C5-Alkyl-;
- X3 +
- eine Gruppe der Formel
- t
- 0 oder 1;
- R7 und R8
- unabhängig voneinander C1-C6-Alkyl;
- R9
- C1-C6Alkyl; C5-C7-Cycloalkyl; oder NR11R12;
- R10 und R11
- unabhängig voneinander, C1-C5-Alkyl;
- R12 und R13
- unabhängig voneinander Wasserstoff oder C1-C5-Alkyl;
- R14 und R15
- unabhängig voneinander nicht substituiertes oder durch Hydroxy, Cyano, Carboxy, Carb-C1-C6-Akoxy, C1-C6-Alkoxy, Phenyl, Naphthyl oder Pyridyl substituiertes C1-C6-Alkyl;
- u
- 1 bis 6;
- A1
- die Ergänzung zu einem aromatischen 5- bis 7-gliedrigen Stickstoffheterocyclus, der gegebenenfalls noch ein oder zwei weitere Stickstoffatome als Ringglieder enthalten kann, und
- B1
- die Ergänzung zu einem gesättigten 5- bis 7-gliedrigen Stickstoffheterocyclus, der gegebenenfalls noch 1 bis 2 Stickstoff-, Sauerstoff- und/oder Schwefelatome als Ringglieder enthalten kann;
- Q2
- Hydroxy; C1-C22-Alkyl; verzweigtes C4-C22-Alkyl; C2-C22-Alkenyl; verzweigtes C4-C22-Alkenyl und Mischungen davon; C1-C22-Alkoxy; einen Sulfo- oder Carboxylrest; einen Rest der Formel -SO2(CH2)v-OSO3M; -SO2(CH2)v-SO3M; einen verzweigten Alkoxyrest der Formel eine Alkylethylenoxyeinheit der Formel -(T1)d-(CH2)b(OCH2CH2)a-B3 oder einen Ester der Formel COOR23
- B2
- Wasserstoff; Hydroxy; C1-C30-Alkyl; C1-C30-Alkoxy; -CO2H; -CH2COOH; SO3 -M1 +; -OSO3 -M1 +; -PO3 2-; M1; -OPO3 2-M1; und Mischungen davon;
- B3
- Wasserstoff; Hydroxy; -COOH; -SO3 -M1 +; -OSO3 -M1 +; C1-C6-Alkoxy;
- M1
- ein wasserlösliches Kation;
- T1
- -O-; oder -NH-;
- X1 und X4
- unabhängig voneinander -O-; -NH-; oder -N-C1-C5-Alkyl;
- R16 und R17
- unabhängig voneinander Wasserstoff, die Sulfogruppe und deren Salze, die Carboxylgruppe und deren Salze oder die Hydroxylgruppe bedeuten, wobei mindestens einer der Reste R16 und R17 für eine Sulfo- oder Carboxylgruppe oder deren Salze steht,
- Y2
- -O-, -S-, -NH- oder -N-C1-C5-Alkyl;
- R18 und R19
- unabhängig voneinander Wasserstoff, C1-C6-Alkyl, Hydroxy-C1-C6-Alkyl, Cyano-C1-C6-Alkyl, Sulfo- C1-C6-Alkyl, Carboxy oder Halogen-C1-C6-Alkyl; nicht substituiertes oder durch Halogen, C1-C4-Alkyl oder C1-C4-Alkoxy, Sulfo oder Carboxy substituiertes Phenyl; oder R18 und R19 zusammen mit dem Stickstoffatom, an das sie gebunden sind, einen gesättigten 5- oder 6-gliedrigen heterocyclischen Ring, der zusätzlich noch ein Stickstoff- oder Sauerstoffatom als Ringglied enthalten kann;
- R20 und R21
- unabhängig voneinander einen C1-C6-Alkyl- oder Aryl-C1-C6-Alkylrest;
- R22
- Wasserstoff; oder nicht substituiertes oder durch Halogen, Hydroxy, Cyano, Phenyl, Carboxy, Carb-C1-C6-Alkoxy oder C1-C6-Alkoxy substituiertes C1-C6-Alkyl;
- R23
- C1-C22-Alkyl, verzweigtes C4-C22-Alkyl, C1-C22-Alkenyl oder verzweigtes C4-C22-Alkenyl; C3-C22-Glykol; C1-C22-Alkoxy; verzweigtes C4-C22-Alkoxy; und Mischungen davon;
- M
- Wasserstoff; oder ein Alkalimetall- oder Ammoniumion,
- Z2
- ein Chlor-, Brom, Alkyl- oder Aralkylsulfation;
- a
- 0 oder 1;
- b
- 0 bis 6;
- c
- 0 bis 100;
- d
- 0; oder 1;
- e
- 0 bis 22;
- V
- eine ganze Zahl von 2 bis 12;
- w
- o oder 1; und
- A
- ein organisches oder anorganisches Anion
- s
- im Falle einwertiger Anionen A gleich r und im Falle mehrwertiger Anionen ≤ r ist, wobei As - die positive Ladung kompensieren muss; wobei, wenn r ≠ 1, die Reste Q1 gleich oder verschieden sein können,
- PC, X2, X3 und R6
- die oben angegebene Bedeutung haben,
- M
- Wasserstoff, ein Alkalimetall-, Ammonium- oder Aminsalzion; bedeutet, und die Summe der Zahlen r1 und r2 von 1 bis 4 reicht und
- As -
- die positive Ladung des Restmoleküls genau kompensiert,
- PC
- wie in Formel (2a) definiert ist,
- R6'
- C2-C6-Alkylen;
- r1
- eine Zahl von 1 bis 4;
- X3'
- eine Gruppe der Formel oder bedeuten,
- R7 und R8
- unabhängig voneinander unsubstituiertes oder durch Hydroxy, Cyano, Halogen oder Phenyl substituiertes C1-C4-Alkyl;
- R9
- R7; Cyclohexyl oder Amino;
- R11
- C1-C4-Alkyl;
- R21
- C1-C4-Alkyl; C1-C4-Alkoxy; Halogen, Carboxy, Carb-C1-C4-Alkoxy oder Hydroxy; und
- A'
- ein Halogenid-, Alkylsulfat- oder Arylsulfation;
- PC
- das Phthalocyaninringsystem;
- Me
- Zn, Fe(ll), Ca, Mg, Na, K, Al-Z1, Si(lV), P(V), Ti(lV), Ge(lV), Cr(VI), Ga(III), Zr(IV), In(lll), Sn(lV) oder Hf(VI);
- Z1
- ein Halogenid-, Sulfat-, Nitrat-, Acetat-, Alkoholat-, Carboxylat- oder Hydroxy-lon;
- q
- 0; 1; oder 2;
- Y3'
- Wasserstoff; ein Alkalimetall- oder Ammoniumion; und
- r
- eine beliebige Zahl von 1 bis 4;
- Me
- Zn oder Al-Z1; und
- Z1
- ein Halogenid-, Sulfat-, Nitrat-, Acetat-, Alkoholat-, Carboxylat- oder Hydroxy-lon;
- PC, Me und q
- die in Formel (5) angegebene Bedeutung haben;
- R17' und R18'
- unabhängig voneinander Wasserstoff, Phenyl, Sulfophenyl, Carboxyphenyl, C1-C6-Alkyl, Hydroxy-C1-C6-Alkyl, Cyano-C1-C6-Alkyl, Sulfo-C1-C6-Alkyl, Carboxy-C1-C6-Alkyl oder Halogen C1-C6-Alkyl oder zusammen mit dem Stickstoffatom den Morpholinring;
- q'
- eine ganze Zahl von 2 bis 6; und
- r
- eine Zahl von 1 bis 4;
- PC, Me und q
- die in Formel (5) angegebenen Bedeutung haben,
- Y'3
- Wasserstoff, ein Alkalimetall- oder Ammoniumion,
- q'
- eine ganze Zahl von 2 bis 6;
- R17' und R18'
- unabhängig voneinander Wasserstoff, Phenyl, Sulfophenyl, Carboxyphenyl, C1-C6-Alkyl, Hydroxy C1-C6-Alkyl, Cyano C1-C6-Alkyl, Sulfo C1-C6-Alkyl, Carboxy C1-C6-Alkyl oder Halogen C1-C6-Alkyl oder zusammen mit dem Stickstoffatom den Morpholinring,
- m'
- 0 oder 1; und
- r und r1
- unabhängig voneinander eine beliebige Zahl von 0,5 und 3 bedeuten, wobei die Summe r +r1 mindestens 1, jedoch höchstens 4 beträgt.
- R24
- Hydroxy; C1-C22-Alkyl; verzweigtes C4-C22-Alkyl; C1-C22-Alkenyl; verzweigtes C4-C22-Alkenyl und Mischungen davon; C1-C22-Alkoxy; einen Sulfo- oder Carboxylrest; einen
- U
- [Q1]r +As -; oder Q2; bedeuten.
- X1
- ein Halogenatom; -CH3SO4 -; -C2H5SO4 -; oder -NO3 -;
- R1 und R2
- C1-C5-Alkyl;
- R3
- den aliphatischen Rest der Talgfettsäure und
- X3 -
- ein Halogenatom;
Beispiel | Konzentration der Formulierung von (102) [%] | Menge der eingesetzten Formulierung von (102) [g] | eingesetztes Wasser [g] | Menge der Verbindung d. F. (102) [mg] | Verbindung d. F. (102) bezogen auf Spülmittel-Formulierung [%] |
1 | 0 | 0,0 | 0,9 | 0,0 | 0,0 |
2 | 0,038 | 0,9 | 0,0 | 0,345 | 0,00115 |
3 | 0,23 | 0,45 | 0,45 | 1,035 | 0,00345 |
4 | 0,23 | 0,9 | 0,0 | 2,074 | 0,00690 |
Formulierung aus Beispiel | ohne Belichtung | mit 2 h Belichtung | ||
Y[%] | ΔY | Y [%] | ΔY | |
1 | 68,1 | 71,1 | ||
2 | 67,9 | -0,2 | 74 | 2,9 |
3 | 67,3 | -0,8 | 75,9 | 4,8 |
4 | 67,6 | -0,5 | 77,8 | 6,7 |
Formulierung aus Beispiel | ohne Belichtung | mit 2 h Belichtung | ||
Y[%] | ΔY | Y [%] | ΔY | |
1 | 58,1 | 59,1 | ||
2 | 58,2 | 0,1 | 60,5 | 1,4 |
3 | 58 | -0,1 | 61,2 | 2,1 |
4 | 57,9 | -0,2 | 63,3 | 4,2 |
Formulierung aus Beispiel | ohne Belichtung | mit 2 Stunden Belichtung | mit 4 Stunden Belichtung | |||
Y [%] | ΔY | Y[%] | ΔY | Y[%] | ΔY | |
1 | 79,4 | 81,2 | 83,4 | |||
2 | 78,6 | -0,8 | 84,5 | 3,3 | 87 | 3,6 |
3 | 78,6 | -0,8 | 86,3 | 5,1 | 88,7 | 5,3 |
4 | 78,7 | -07 | 86,5 | 5,3 | 89 | 5,6 |
1 Teil des mit Wein und Kaffee angeschmutzten Gewebes wird 4 Stunden feucht unter Osram-Lampen belichtet und nachträglich trockengebügelt.
Ergebnisse der Waschtests der mit Rotwein bzw. Kaffee angeschmutztem Gewebe | ||||||||
mit Rotwein angeschmutztes Gewebe Y(Start) = 52,3 | mit Kaffee angeschmutztes Gewebe Y(Start) = 73,7 | |||||||
ohne Belichtung | mit 4 Stunden Belichtung | ohne Belichtung | mit 4 Stunden Belichtung | |||||
Y | ΔY | Y | ΔY | Y | ΔY | Y | ΔY | |
Formulierung 8a) | 66,1 | 66,2 | 77,9 | 80,2 | ||||
Formulierung 8b) | 65,0 | 1,1 | 71,5 | 5,3 | 79,4 | 1,5 | 86,9 | 6,7 |
Ergebnisse der Waschtests des mit Tee angeschmutzten Gewebes | ||||||||||||
mit Tee angeschmutztes Gewebe Y(Start) = 35,5 | ||||||||||||
nach 1 Waschzyklus | nach 3 Waschzyklen | nach 5 Waschzyklen | ||||||||||
Belichtung | ohne | 2 Stunden | ohne | 2 Stunden | ohne | 2Stunden | ||||||
Y | ΔY | Y | ΔY | Y | ΔY | Y | ΔY | Y | ΔY | Y | ΔY | |
Formulierung 8a) | 40,6 | 40,7 | 41,2 | 44,7 | 41,3 | 49,9 | ||||||
Formulierung 8b) | 40,2 | -0,4 | 43,4 | 2,7 | 41,6 | 0,4 | 53,4 | 8,7 | 41,6 | 0,3 | 63,5 | 13,6 |
Claims (14)
- Weichspülmittelzusammensetzung, enthaltend(a) ein wasserlösliches Zn, Fe(ll), Ca, Mg, Na, K, Al, Si(lV), P(V), Ti(lV), Ge(lV), Cr(VI), Ga(lll), Zr(lV), In(lll), Sn(lV) oder Hf(VI) Phthalocyanin; und
- Zusammensetzung nach Anspruch 1, dadurch gekennzeichnet, dass sie ein Phthalocyanin der Formel enthält, worin
- PC
- das Phthalocyaninringsystem;
- Me
- Zn, Fe(ll), Ca, Mg, Na, K, Al-Z1, Si(lV), P(V), Ti(lV), Ge(lV), Cr(VI), Ga(lll), Zr(IV), In(lll), Sn(lV) oder Hf(VI);
- Z1
- ein Halogenid-, Sulfat-, Nitrat-, Acetat-, Alkoholat-, Carboxylat- oder Hydroxy-Ion;
- q
- 0,1 oder 2;
- r
- 1 bis 4;
- Q1
- eine Sulfo- oder Carboxylgruppe; oder einen Rest der Formel -SO2X2-R6-X3 +, -O-R6-X3 +; oder -(CH2)t-Y1 +;
- R6
- verzweigtes oder unverzweigtes C1-C8-Alkylen; oder 1,3- oder 1,4-Phenylen;
- X2
- -NH-; oder -N-C1-C5-Alkyl-;
- X3 +
- eine Gruppe der Formel
- Y1 +
- eine Gruppe der Formel
- t
- 0 oder 1;
- R7 und R8
- unabhängig voneinander C1-C6-Alkyl;
- R9
- C1-C6Alkyl; C5-C7-Cycloalkyl; oder NR11R12;
- R10 und R11
- unabhängig voneinander, C1-C5-Alkyl;
- R12 und R13
- unabhängig voneinander Wasserstoff oder C1-C5-Alkyl;
- R14 und R15
- unabhängig voneinander nicht substituiertes oder durch Hydroxy, Cyano, Carboxy, Carb-C1-C6-Akoxy, C1-C6-Alkoxy, Phenyl, Naphthyl oder Pyridyl substituiertes C1-C6-Alkyl;
- u
- 1 bis 6;
- A1
- die Ergänzung zu einem aromatischen 5- bis 7-gliedrigen Stickstoffheterocyclus, der gegebenenfalls noch ein oder zwei weitere Stickstoffatome als Ringglieder enthalten kann, und
- B1
- die Ergänzung zu einem gesättigten 5- bis 7-gliedrigen Stickstoffheterocyclus, der gegebenenfalls noch 1 bis 2 Stickstoff-, Sauerstoff- und/oder Schwefelatome als Ringglieder enthalten kann;
- Q2
- Hydroxy; C1-C22-Alkyl; verzweigtes C4-C22-Alkyl; C2-C22-Alkenyl; verzweigtes C4-C22-Alkenyl und Mischungen davon; C1-C22-Alkoxy; einen Sulfo- oder Carboxylrest; einen Rest der Formel -SO2(CH2)v-OSO3M; -SO2(CH2)v-SO3M; einen verzweigten Alkoxyrest der Formel eine Alkylethylenoxyeinheit der Formel -(T1)d-(CH2)b(OCH2CH2)a-B3 oder einen Ester der Formel COOR23
- B2
- Wasserstoff; Hydroxy; C1-C30-Alkyl; C1-C30-Alkoxy; -CO2H; -CH2COOH; SO3 -M1 +; -OSO3 -M1 +; -PO3 2-; M1; -OPO3 2-M1; und Mischungen davon;
- B3
- Wasserstoff; Hydroxy; -COOH; -SO3 -M1 +; -OSO3 -M1 +; C1-C6-Alkoxy;
- M1
- ein wasserlösliches Kation;
- T1
- -O-; oder -NH-;
- X1 und X4
- unabhängig voneinander -O-; -NH-; oder -N-C1-C5-Alkyl;
- R16 und R17
- unabhängig voneinander Wasserstoff, die Sulfogruppe und deren Salze, die Carboxylgruppe und deren Salze oder die Hydroxylgruppe bedeuten, wobei mindestens einer der Reste R16 und R17 für eine Sulfo- oder Carboxylgruppe oder deren Salze steht,
- Y2
- -O-, -S-, -NH- oder -N-C1-C5-Alkyl;
- R18 und R19
- unabhängig voneinander Wasserstoff, C1-C6-Alkyl, Hydroxy-C1-C6-Alkyl, Cyano-C1-C6-Alkyl, Sulfo- C1-C6-Alkyl, Carboxy oder Halogen-C1-C6-Alkyl; nicht substituiertes oder durch Halogen, C1-C4-Alkyl oder C1-C4-Alkoxy, Sulfo oder Carboxy substituiertes Phenyl; oder R18 und R19 zusammen mit dem Stickstoffatom, an das sie gebunden sind, einen gesättigten 5- oder 6-gliedrigen heterocyclischen Ring, der zusätzlich noch ein Stickstoff- oder Sauerstoffatom als Ringglied enthalten kann;
- R20 und R21
- unabhängig voneinander einen C1-C6-Alkyl- oder Aryl-C1-C6-Alkylrest;
- R22
- Wasserstoff; oder nicht substituiertes oder durch Halogen, Hydroxy, Cyano, Phenyl, Carboxy, Carb-C1-C6-Alkoxy oder C1-C6-Alkoxy substituiertes C1-C6-Alkyl;
- R23
- C1-C22-Alkyl, verzweigtes C4-C22-Alkyl, C1-C22-Alkenyl oder verzweigtes C4-C22-Alkenyl; C3-C22-Glykol; C1-C22-Alkoxy; verzweigtes C4-C22-Alkoxy; und Mischungen davon;
- M
- Wasserstoff; oder ein Alkalimetall- oder Ammoniumion,
- Z2
- ein Chlor-, Brom, Alkyl- oder Aralkylsulfation;
- a
- 0 oder 1;
- b
- 0 bis 6;
- c
- 0 bis 100;
- d
- 0; oder 1;
- e
- 0 bis 22;
- v
- eine ganze Zahl von 2 bis 12;
- w
- o oder 1; und
- A
- ein organisches oder anorganisches Anion
- s
- im Falle einwertiger Anionen A- gleich r und im Falle mehrwertiger Anionen ≤ r ist, wobei As - die positive Ladung kompensieren muss; wobei, wenn r ≠ 1, die Reste Q1 gleich oder verschieden sein können,
- Zusammensetzung nach Anspruch 1 oder 2, dadurch gekennzeichnet, dass sie ein Phthalocyanin der Formel enthält, worin
PC, X2, X3, R6 die in Anspruch 2 angegebene Bedeutung haben;- M
- Wasserstoff, ein Alkalimetall-, Ammonium- oder Aminsalzion;
- As
- die positive Ladung des Restmoleküls genau kompensiert.
- Zusammensetzung nach Anspruch 1 oder 2, dadurch gekennzeichnet, dass es ein Phthalocyanin der Formel enthält, worin
- PC
- wie in Anspruch 2 definiert ist,
- R6'
- C2-C6-Alkylen;
- r1
- eine Zahl von 1 bis 4;
- X3 '+
- eine Gruppe der Formel
- R7 und R8
- unabhängig voneinander unsubstituiertes oder durch Hydroxy, Cyano, Halogen oder Phenyl substituiertes C1-C4-Alkyl;
- R9 R7;
- Cyclohexyl oder Amino;
- R11
- C1-C4-Alkyl;
- R21
- C1-C4-Alkyl; C1-C4-Alkoxy; Halogen, Carboxy, Carb-C1-C4-Alkoxy oder Hydroxy; und
- A'
- ein Halogenid-, Alkylsulfat- oder Arylsulfation;
- Zusammensetzung nach Anspruch 1 oder 2, dadurch gekennzeichnet, dass die Zusammensetzung Phthalocyanine der Formel enthält, worin
- PC
- das Phthalocyaninringsystem;
- Me
- Zn, Fe(II), Ca, Mg, Na, K, Al-Z1, Si(IV), P(V), Ti(IV), Ge(IV), Cr(VI), Ga(III), Zr(IV), In(III), Sn(IV) oder Hf(VI);
- Z1
- ein Halogenid-, Sulfat-, Nitrat-, Acetat-, Alkoholat-, Carboxylat- oder Hydroxy-lon;
- q
- 0; 1; oder 2;
- Y3'
- Wasserstoff; ein Alkalimetall- oder Ammoniumion; und
- r
- eine beliebige Zahl von 1 bis 4;
- Zusammensetzung nach Anspruch 5, dadurch gekennzeichnet, dass in Formel (5)
- Me
- Zn oder Al-Z1; und
- Z1
- ein Halogenid-, Sulfat-, Nitrat-, Acetat-, Alkoholat-, Carboxylat- oder Hydroxy-lon;
- Zusammensetzung nach Anspruch 1,2 oder 5, dadurch gekennzeichnet, dass die Zusammensetzung ein Phthalocyanin der Formel enthält, worin
- R24
- Hydroxy; C1-C22-Alkyl; verzweigtes C4-C22-Alkyl; C1-C22-Alkenyl; verzweigtes C4-C22-Alkenyl und Mischungen davon; C1-C22-Alkoxy; einen Sulfo- oder Carboxylrest; einen Rest der Formel -SO2(CH2)v-OSO3M; -SO2(CH2)v-SO3M; einen verzweigten Alkoxyrest der Formel eine Alkylethylenoxyeinheit der Formel -(T1)d-(CH2)b(OCH2CH2)a-B3 oder einen Ester der Formel COOR23; und
- u
- [Q1]r +As -; oder Q2; bedeuten; und
- Zusammensetzung nach einem der Ansprüche 1 bis 7, dadurch gekennzeichnet, dass die quaternäre Ammoniumverbindung der Formel (1) entspricht, worin
- X1
- ein Halogenatom; -CH3SO4 -; -C2H5SO4 -; oder -NO3 -;
- Zusammensetzung nach einem der Ansprüche 1 bis 8, dadurch gekennzeichnet, dass in Formel (1)
A und B den Rest der Formel (1b) bedeuten. - Zusammensetzung nach Anspruch 1, enthaltend(a) ein wasserlösliches Phthalocyanin der Formel (5) nach Anspruch 5 und(b) eine quaternäre Ammoniumverbindung der Formel (8) nach Anspruch 10.
- Zusammensetzung nach Anspruch 1, enthaltend(a) ein wasserlösliches Phthalocyanin der Formel (10) nach Anspruch 7 und(b) eine quaternäre Ammoniumverbindung der Formel (8) nach Anspruch 10.
- Zusammensetzung nach Anspruch 1, dadurch gekennzeichnet, dass sie 0,0001 bis 0,05 Gew.% der Komponente (a) und
1 bis 20 Gew.% der Komponente (b) enthält. - Verfahren zum Bleichen von textilen Fasermaterialien mit einem Photobleichmittel, dadurch gekennzeichnet, dass man angeschmutzte Textilien in einem Bad, das Weichspülmittelzusammensetzung, enthaltend(a) ein wasserlösliches Zn, Fe(ll), Ca, Mg, Na, K, Al, Si(lV), P(V), Ti(lV), Ge(lV), Cr(VI), Ga(lll), Zr(lV), In(lll), Sn(lV) oder Hf(VI) Phthalocyanin; und(b) eine quaternäre Ammoniumverbindung der Formel (1),
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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EP98810753A EP0899325B1 (de) | 1997-08-15 | 1998-08-06 | Weichspülmittelzusammemsetzung |
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Application Number | Priority Date | Filing Date | Title |
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EP97810573 | 1997-08-15 | ||
EP97810573 | 1997-08-15 | ||
EP98810753A EP0899325B1 (de) | 1997-08-15 | 1998-08-06 | Weichspülmittelzusammemsetzung |
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Publication Number | Publication Date |
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EP0899325A2 EP0899325A2 (de) | 1999-03-03 |
EP0899325A3 EP0899325A3 (de) | 1999-07-21 |
EP0899325B1 true EP0899325B1 (de) | 2001-12-19 |
Family
ID=8230344
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EP98810753A Expired - Lifetime EP0899325B1 (de) | 1997-08-15 | 1998-08-06 | Weichspülmittelzusammemsetzung |
Country Status (11)
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---|---|
US (1) | US6583105B1 (de) |
EP (1) | EP0899325B1 (de) |
JP (1) | JPH11172575A (de) |
KR (1) | KR100505528B1 (de) |
AU (1) | AU747856B2 (de) |
BR (1) | BR9803753A (de) |
DE (1) | DE59802506D1 (de) |
ES (1) | ES2169492T3 (de) |
ID (1) | ID20699A (de) |
NZ (1) | NZ331196A (de) |
ZA (1) | ZA987302B (de) |
Cited By (1)
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CN1320090C (zh) * | 2002-09-04 | 2007-06-06 | 西巴特殊化学品控股有限公司 | 包含水溶性颗粒的制剂 |
Families Citing this family (12)
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ATE272104T1 (de) | 1998-05-18 | 2004-08-15 | Ciba Sc Holding Ag | Wasserlösliche granulate von phthalocyaninverbindungen |
EP0959123B1 (de) * | 1998-05-18 | 2004-07-28 | Ciba SC Holding AG | Wasserlösliche Granulate von Phthalocyaninverbindungen |
AU3507900A (en) * | 1999-03-05 | 2000-09-21 | Case Western Reserve University | Hydrophobic liquid photobleaches |
KR100554479B1 (ko) * | 2002-09-11 | 2006-03-03 | 씨제이라이온 주식회사 | 염착 얼룩 방지 세탁용 착염 |
KR100502955B1 (ko) * | 2002-10-11 | 2005-07-21 | 씨제이라이온 주식회사 | 염착얼룩방지 세탁용 과립조성물 |
US7345016B2 (en) * | 2003-06-27 | 2008-03-18 | The Procter & Gamble Company | Photo bleach lipophilic fluid cleaning compositions |
ES2317370T3 (es) * | 2005-09-06 | 2009-04-16 | Clariant (Brazil) S.A. | Composiciones acuosas estables de esteres cuates. |
GB0717485D0 (en) * | 2007-09-08 | 2007-10-17 | Unilever Plc | Improvements relating to fabric conditioners |
ATE504643T1 (de) * | 2007-09-08 | 2011-04-15 | Unilever Nv | Verbesserungen im zusammenhang mit wäscheweichmachern |
CN103147267B (zh) * | 2013-03-06 | 2015-07-15 | 浙江传化股份有限公司 | 一种低温练漂剂及其制备方法 |
BR112017015471A2 (pt) | 2015-01-19 | 2018-01-30 | Diversey, Inc. | auxiliar de secagem para produtos têxteis |
EP3805346A1 (de) * | 2019-10-08 | 2021-04-14 | The Procter & Gamble Company | Verfahren zum waschen von stoffen |
Family Cites Families (15)
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GB1408144A (en) | 1972-06-02 | 1975-10-01 | Procter & Gamble Ltd | Bleaching process |
US4033718A (en) * | 1973-11-27 | 1977-07-05 | The Procter & Gamble Company | Photoactivated bleaching process |
CA1064797A (en) | 1975-04-03 | 1979-10-23 | Brandon H. Wiers | Photoactivated bleach-compositions and process |
CH630127A5 (de) | 1977-03-25 | 1982-05-28 | Ciba Geigy Ag | Verfahren zum bleichen von textilien. |
EP0003371A1 (de) | 1978-01-11 | 1979-08-08 | THE PROCTER & GAMBLE COMPANY | Einen Photoaktivator und eine kationische Verbindung enthaltendes Mittel zum verbesserten Bleichen und Waschen von Textilien |
CA1104451A (en) * | 1978-02-28 | 1981-07-07 | Manuel Juan De Luque | Detergent bleach composition and process |
MX155643A (es) * | 1980-02-29 | 1988-04-11 | Ciba Geigy Ag | Composicion blanqueadora de telas |
ATE12254T1 (de) * | 1980-12-22 | 1985-04-15 | Unilever Nv | Einen photoaktivator enthaltende zusammensetzung mit verbesserter bleichwirkung. |
JP2855287B2 (ja) | 1990-08-22 | 1999-02-10 | ライオン株式会社 | 柔軟剤組成物 |
EP0484027B1 (de) * | 1990-11-02 | 1996-12-18 | Zeneca Limited | Polysubstituierte Phthalocyanine |
JP3330200B2 (ja) | 1993-09-14 | 2002-09-30 | 花王株式会社 | 液体漂白剤組成物 |
WO1996002625A1 (en) * | 1994-07-19 | 1996-02-01 | The Procter & Gamble Company | Perfumes for laundry and cleaning compositions |
IL116638A0 (en) | 1995-01-12 | 1996-05-14 | Procter & Gamble | Method and compositions for laundering fabrics |
US5916481A (en) * | 1995-07-25 | 1999-06-29 | The Procter & Gamble Company | Low hue photobleaches |
US5679661A (en) | 1995-07-25 | 1997-10-21 | The Procter & Gamble Company | Low hue photodisinfectants |
-
1998
- 1998-07-31 NZ NZ331196A patent/NZ331196A/xx unknown
- 1998-08-06 DE DE59802506T patent/DE59802506D1/de not_active Expired - Lifetime
- 1998-08-06 EP EP98810753A patent/EP0899325B1/de not_active Expired - Lifetime
- 1998-08-06 ES ES98810753T patent/ES2169492T3/es not_active Expired - Lifetime
- 1998-08-10 ID IDP981114A patent/ID20699A/id unknown
- 1998-08-13 KR KR10-1998-0032821A patent/KR100505528B1/ko not_active IP Right Cessation
- 1998-08-14 ZA ZA987302A patent/ZA987302B/xx unknown
- 1998-08-14 AU AU80006/98A patent/AU747856B2/en not_active Ceased
- 1998-08-14 BR BR9803753-6A patent/BR9803753A/pt not_active IP Right Cessation
- 1998-08-17 JP JP10230444A patent/JPH11172575A/ja active Pending
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Cited By (1)
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CN1320090C (zh) * | 2002-09-04 | 2007-06-06 | 西巴特殊化学品控股有限公司 | 包含水溶性颗粒的制剂 |
Also Published As
Publication number | Publication date |
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KR19990023559A (ko) | 1999-03-25 |
BR9803753A (pt) | 1999-12-07 |
DE59802506D1 (de) | 2002-01-31 |
ZA987302B (en) | 1999-02-15 |
NZ331196A (en) | 2000-01-28 |
KR100505528B1 (ko) | 2005-11-09 |
ID20699A (id) | 1999-02-18 |
US6583105B1 (en) | 2003-06-24 |
ES2169492T3 (es) | 2002-07-01 |
JPH11172575A (ja) | 1999-06-29 |
AU8000698A (en) | 1999-02-25 |
AU747856B2 (en) | 2002-05-23 |
EP0899325A3 (de) | 1999-07-21 |
EP0899325A2 (de) | 1999-03-03 |
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