EP0349853B1 - Method of producing non-oriented magnetic steel heavy plate having high magnetic flux density - Google Patents
Method of producing non-oriented magnetic steel heavy plate having high magnetic flux density Download PDFInfo
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- EP0349853B1 EP0349853B1 EP89111463A EP89111463A EP0349853B1 EP 0349853 B1 EP0349853 B1 EP 0349853B1 EP 89111463 A EP89111463 A EP 89111463A EP 89111463 A EP89111463 A EP 89111463A EP 0349853 B1 EP0349853 B1 EP 0349853B1
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- steel
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/12—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties
- C21D8/1216—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties the working step(s) being of interest
- C21D8/1222—Hot rolling
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D3/00—Diffusion processes for extraction of non-metals; Furnaces therefor
- C21D3/02—Extraction of non-metals
- C21D3/06—Extraction of hydrogen
Definitions
- the present invention relates to a method of producing non-oriented magnetic steel heavy plate having high magnetic flux density, for magnetic cores used under DC magnetising conditions and for magnetic shielding.
- An object of the present invention is to provide a method of producing non-oriented magnetic steel heavy plate having high magnetic flux density in a low magnetic field.
- Another object of the present invention is to provide a method of producing non-oriented magnetic steel heavy plate having a tensile strength of 40 kg/mm2 or more and a high magnetic flux density in a low magnetic field.
- Another object of the present invention is to provide a method of producing non-oriented magnetic steel heavy plate having a tensile strength of 40 kg/mm2 or more, a high specific resistance and a high magnetic flux density in a low magnetic field.
- Another object of the present invention is to provide a method of producing non-oriented magnetic steel heavy plate having a low coercive force and a high magnetic flux density in a low magnetic field.
- the process of magnetization to raise the magnetic flux density in a low magnetic field consists of placing non-gaussed steel in a magnetic field and changing the orientation of the magnetic domains by increasing the intensity of the magnetic field so that domains oriented substantially in the direction of the magnetic field become preponderant, encroaching on, and amalgamating with, other domains. That is to say, the domain walls are moved. When the magnetic field is further intensified and the moving of the domain walls is completed, the magnetic orientation of all the domains is changed.
- the ease with which the domain walls can be moved decides the magnetic flux density in a low magnetic field. That is, to obtain a high magnetic flux density in a low magnetic field, obstacles to the movement of the domain wall must be reduced as far as possible.
- the inventors carried out detailed investigations relating to crystal grain size, the effects of elements that cause internal stresses and cavity defects.
- AlN has the effect of refining the size of crystal grains, so grain size can be coarsened by reducing the AlN.
- the heating temperature is raised as high as possible to coarsen the size of the austenite grains, and the finish rolling temperature is also raised as high as possible to prevent the crystal grain size being refined by the rolling process, together with which annealing conditions following rolling are used selectively.
- Figure 2 shows that by using high shape ratio rolling to reduce the size of cavity defects to less than 100 micrometers and reducing hydrogen in the steel by dehydrogenation heat treatment, magnetic flux density in a low magnetic field could be markedly raised.
- (0.007 C - 0.01 Si - 0.1 Mn) steel was used.
- the steel is high purity steel comprised of up to 0.01 percent carbon, up to 0.02 percent silicon, up to 0.20 percent manganese, up to 0.015 percent phosphorus, up to 0.010 percent sulfur, up to 0.05 percent chromium, up to 0.01 percent molybdenum, up to 0.01 percent copper, 0.005 to 0.40 percent aluminum, up to 0.004 percent nitrogen, up to 0.005 percent oxygen and up to 0.0002 percent hydrogen and one or more deoxidizing agents, with the remainder being substantially iron.
- Carbon increases internal stresses in steel and is the element most responsible for degradation of magnetic properties, especially magnetic flux density in a low magnetic field, and as such, minimizing the carbon content helps to prevent a drop in the magnetic flux density in a low magnetic field. Also, lowering the carbon content decreases the magnetic aging of the steel, and thereby extends the length of time the steel retains its good magnetic properties. Hence, carbon is limited to a maximum of 0.010 percent. As shown in Figure 1, an even higher magnetic flux density can be obtained by reducing the carbon content to 0.005 percent or less.
- Low silicon and manganese are desirable for achieving high magnetic flux density in a low magnetic field; low manganese is also desirable for reducing MnS inclusions. Therefore 0.01 to 4.0 percent is specified as the limit for silicon and up to 0.20 percent for manganese. To reduce MnS inclusions, a manganese content of no more than 0.10 percent is preferable.
- Phosphorus, sulfur and oxygen produce non-metallic inclusions in the steel, and the segregation of these elements also obstructs the movement of the magnetic domain walls. As such, the higher the content amounts of these elements, the more pronounced the deterioration in the magnetic flux density and other magnetic properties. Therefore, an upper limit of 0.015 percent has been specified for phosphorus, 0.010 percent for sulfur, and 0.005 percent for oxygen.
- chromium, molybdenum and copper have on magnetic flux density in a low magnetic field, preferably the content amounts of these elements are kept as low as possible. Another reason for minimizing these elements is to reduce the degree of segregation. Accordingly, an upper limit of 0.05 percent has been specified for chromium, 0.01 percent for molybdenum and 0.01 percent for copper.
- aluminum is an indispensable element for achieving internal uniformity in materials such as the plate according to the present invention, for which purpose a minimum of 0.001 percent is added. As excessive aluminum will give rise to inclusions, degrading the quality of the steel, an upper limit of 0.40 percent is specified. More preferably, the amount of aluminum should not exceed 0.020 percent in order to reduce the AlN which has the effect of refining the size of the crystal grains.
- the method for producing the steel will now be described.
- the steel is heated to a temperature of 1150°C prior to rolling in order to coarsen the size of the austenite grains and improve the magnetic properties.
- An upper limit of 1350°C, preferably 1300°C is specified to prevent scaling loss and to conserve on energy.
- finish rolling temperature is below 900°C, the rolling will refine the size of the crystal grains, adversely affecting the magnetic properties.
- a temperature of 900°C or more is specified with the aim of achieving an increase in the magnetic flux density as a result of a coarsening of the size of the crystal grains.
- the solidification process will always give rise to cavity defects, although the size of the defects may vary. Rolling has to be used to eliminate such cavity defects, and as such, hot rolling plays an important role.
- An effective means is to increase the amount of deformation per hot rolling, so that the deformation extends to the core of the plate.
- a high shape ratio which includes at least one pass at a shape ratio A of at least 0.7 so that the size of cavity defects is no larger than 100 micrometers is conducive to obtaining desirable magnetic properties. Eliminating cavity defects in the rolling process by using this high shape ratio rolling markedly enhances dehydrogenation efficiency in the subsequent dehydrogenation heat treatment.
- the steel is optionally annealed to coarsen the size of the crystal grains and remove internal stresses.
- a temperature below 750°C will not produce coarsening of the crystal grains, while if the temperature exceeds 950°C, uniformity of the crystal grains in the thickness dimension of the plate cannot be maintained. Therefore an annealing temperature range of 750 to 950°C has been specified.
- Normalizing is optionally carried out to adjust the crystal grains in the thickness dimension of the plate and to remove internal stresses.
- an Ac3 point temperature of below 910°C or over 1000°C, uniformity of the crystal grains in the thickness dimension of the plate cannot be maintained, so a range of 910 to 1000°C has been specified for the normalizing temperature.
- the dehydrogenation heat treatment employed for heavy plates having a gage thickness of 50 mm or more can also be used for the annealing or normalizing. As hydrogen readily disperses in heavy plate that is from 20 mm to less than 50 mm thick, such heavy plate only requires annealing or normalizing, not dehydrogenation heat treatment.
- rolling conditions can be used to coarsen the size of the crystal grains.
- Figure 3 shows the relationship between cold-rolling reduction ratio and ferrite grain size.
- a major coarsening of the size of the crystal grains occurs with a cold-rolling reduction ratio of between 5 percent and 25 percent, with the peak being around 10 percent. Therefore, cold rolling is combined with annealing with the aim of achieving a coarsening of the size of the ferrite grains through abnormal grain growth.
- a suitable cold-rolling reduction ratio for this is 5 to 25 percent.
- the steel is annealed to coarsen the size of the crystal grains and remove internal stresses.
- a temperature below 750°C will not produce a coarsening of the crystal grains, while if the temperature exceeds 950°C, uniformity of the crystal grains in the thickness dimension of the plate cannot be maintained. Therefore an annealing temperature range of 750 to 950°C has been specified.
- AlN has the effect of refining the size of crystal grains, so grain size can be coarsened by reducing the AlN.
- lower aluminum produces an increase in the growth of ferrite grains. Where no aluminum has been added, so there is no more than 0.005 percent aluminum, abnormal growth of crystal grains takes place. However, if aluminum is not added, it becomes necessary to add a different deoxidizing agent.
- silicon, titanium, or calcium are elements that can be used as deoxidizing agents and do not bring about a reduction of the magnetic flux density in a low magnetic field.
- the added amounts are: 0.01 to 4.0, preferably 0.1 to 1.0 percent silicon; 0.005 to 0.20, preferably to 0.03 percent titanium; and 0.0005 to 0.01, preferably 0.005 to 0.01 percent calcium. Titanium and calcium may be added in combination.
- using silicon as a deoxidizing agent where there is no added aluminum can impart to the steel a high tensile strength of 40 kg/mm2 or more, and a high specific resistance of 35 » ⁇ ⁇ cm or more.
- a range of 0.01 to 4.0, preferably 1.0 to 4.0 percent is specified as the amount to be added, because over 4.0 percent will cause a reduction in magnetic flux density in a low magnetic field.
- Nickel is an effective element for reducing coercive force without reducing magnetic flux density in a low magnetic field. As shown in Figure 6, at least 0.1 percent nickel is preferred to reduce the coercive force. A content of more than 2.0 percent nickel produces an increase in the coercive force and reduces the magnetic flux density in a low magnetic field, therefore a range of up to 2.0 percent, preferably 0.1 to 2.0 percent has been specified. This range is also desirable as it enables the strength of the steel to be increased without reducing its magnetic properties.
- titanium is to be used as a deoxidizing agent where there is no added aluminum, i.e., the aluminum content is no more than 0.005 percent, and for achieving a high tensile strength of 40 kg/mm2 or more, as shown in Figure 7, at least 0.04 percent is preferred.
- the magnetic flux density in a low magnetic field will be reduced if there is more than 0.20 percent titanium, a range of 0.005 to 0.20, preferably 0.04 to 0.20 percent is specified.
- Electrical steel heavy plate having the compositions listed in Table 1 were produced using the inventive and comparative conditions listed in Table 2. As shown, steels 1 to 10 are inventive steels and steels 11 to 27 are comparative steels.
- Steels 1 to 5 which were finished to a thickness of 100 mm and had coarse, uniform grains, exhibited good magnetic properties. Compared with steel 1, steel 2, with lower carbon, steels 3 and 4, with lower manganese, and steel 5, with lower aluminum, showed better magnetic properties. Steels 6 to 8, which were finished to a thickness of 500 mm, steel 9, which was finished to a thickness of 40 mm, and steel 10, which was finished to a thickness of 20 mm, each had coarse, uniform grains and exhibited good magnetic properties.
- Comparative steels 5 to 10 which each had coarse, uniform grains, exhibited a high magnetic flux density. Comparative steels 21 and 22 showed poor magnetic properties owing to the heating temperature being too low in the case of the former and the rolling finishing temperature too low in the case of the latter.
- Inventive steels 35 to 40 which each had coarse, uniform grains, exhibited good magnetic properties.
- Inventive steels 49 to 55 which each had coarse, uniform grains, exhibited a tensile strength of 40 kg/mm2 or more, high specific resistance and high magnetic flux density in a low magnetic field.
- Inventive steels 57 to 63 which each had coarse, uniform grains, exhibited a high magnetic flux density in a low magnetic field, and a low coercive force.
- comparative steel 64 exhibited a low magnetic flux density in a low magnetic field together with a high coercive force.
- Inventive steels 65 to 71 which each had coarse, uniform grains, exhibited good tensile strength and magnetic properties.
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Description
- The present invention relates to a method of producing non-oriented magnetic steel heavy plate having high magnetic flux density, for magnetic cores used under DC magnetising conditions and for magnetic shielding.
- With the progress in recent years of elementary particle research and medical instruments, devices using magnets are being used in large structures and there is a demand for improved performance in such structures. Numerous electrical steel sheets having good magnetic flux density have been provided, especially silicon steel sheet and electrical mild steel sheet.
- However, with respect to their use as structural members, there have been problems with the assembly fabrication and strength of such materials, and this has necessitated the use of steel heavy plate. So far, such electrical steel heavy plate has been produced using pure iron components, as in JP-A No. 60(1985)-96749, for example.
- However, with the increase in the size and performance of the devices concerned, there is a strong demand for steel materials with better magnetic properties, especially a high magnetic flux density in a low magnetic field, for instance 80 A/m. With the known steel materials, high magnetic flux density in a low magnetic field of 80 A/m cannot be obtained stably.
- An object of the present invention is to provide a method of producing non-oriented magnetic steel heavy plate having high magnetic flux density in a low magnetic field.
- Another object of the present invention is to provide a method of producing non-oriented magnetic steel heavy plate having a tensile strength of 40 kg/mm² or more and a high magnetic flux density in a low magnetic field.
- Another object of the present invention is to provide a method of producing non-oriented magnetic steel heavy plate having a tensile strength of 40 kg/mm² or more, a high specific resistance and a high magnetic flux density in a low magnetic field.
- Another object of the present invention is to provide a method of producing non-oriented magnetic steel heavy plate having a low coercive force and a high magnetic flux density in a low magnetic field.
- These objects are achieved by the method according to the claims.
- The objects and features of the present invention will become more apparent from a consideration of the following detailed description taken in conjunction with the accompanying drawings in which:
- Figure 1 is a graph showing the effect of the carbon content on magnetic flux density at 80 A/m;
- Figure 2 is a graph showing the effect of cavity defect size and dehydrogenation heat treatment temperature on magnetic flux density at 80 A/m;
- Figure 3 is a graph showing the relationship between cold-rolling reduction ratio and ferrite grain number;
- Figure 4 is a graph showing the relationship between aluminum content and ferrite grain number;
- Figure 5 is a graph showing the effect of silicon on tensile strength and specific resistance;
- Figure 6 is a graph showing the relationship between coercive force and nickel content; and
- Figure 7 is a graph showing the relationship between coercive force and titanium content.
- The process of magnetization to raise the magnetic flux density in a low magnetic field consists of placing non-gaussed steel in a magnetic field and changing the orientation of the magnetic domains by increasing the intensity of the magnetic field so that domains oriented substantially in the direction of the magnetic field become preponderant, encroaching on, and amalgamating with, other domains. That is to say, the domain walls are moved. When the magnetic field is further intensified and the moving of the domain walls is completed, the magnetic orientation of all the domains is changed. In this magnetization process, the ease with which the domain walls can be moved decides the magnetic flux density in a low magnetic field. That is, to obtain a high magnetic flux density in a low magnetic field, obstacles to the movement of the domain wall must be reduced as far as possible.
- As means of obtaining a high magnetic flux density in a low magnetic field, the inventors carried out detailed investigations relating to crystal grain size, the effects of elements that cause internal stresses and cavity defects.
- AlN has the effect of refining the size of crystal grains, so grain size can be coarsened by reducing the AlN. With reference to the production method, the heating temperature is raised as high as possible to coarsen the size of the austenite grains, and the finish rolling temperature is also raised as high as possible to prevent the crystal grain size being refined by the rolling process, together with which annealing conditions following rolling are used selectively.
- Carbon has to be reduced to reduce internal stresses. Figure 1 shows that as the carbon content is increased, magnetic flux density in a low magnetic field of 80 A/m goes down. For the samples, (0.01 Si - 0.1 Mn - 0.01 Al) steel was used.
- With respect to the effect of cavity defects, it was found that there was a large degradation in the magnetic properties when cavity defects measured 100 micrometers or more. It was found that in order to eliminate such harmful cavity defects measuring 100 micrometers or more, a shape ratio A of 0.7 or more is required.
- As shown by Figure 2, the presence of hydrogen in the steel is deleterious, and it was discovered that the magnetic properties could be greatly improved by the use of dehydrogenation heat treatment.
- Figure 2 shows that by using high shape ratio rolling to reduce the size of cavity defects to less than 100 micrometers and reducing hydrogen in the steel by dehydrogenation heat treatment, magnetic flux density in a low magnetic field could be markedly raised. For the samples, (0.007 C - 0.01 Si - 0.1 Mn) steel was used.
- In this invention, preferably the steel is high purity steel comprised of up to 0.01 percent carbon, up to 0.02 percent silicon, up to 0.20 percent manganese, up to 0.015 percent phosphorus, up to 0.010 percent sulfur, up to 0.05 percent chromium, up to 0.01 percent molybdenum, up to 0.01 percent copper, 0.005 to 0.40 percent aluminum, up to 0.004 percent nitrogen, up to 0.005 percent oxygen and up to 0.0002 percent hydrogen and one or more deoxidizing agents, with the remainder being substantially iron.
- The reasons for the component limitations in the high-purity steel referred to with respect to the present invention will now be explained.
- Carbon increases internal stresses in steel and is the element most responsible for degradation of magnetic properties, especially magnetic flux density in a low magnetic field, and as such, minimizing the carbon content helps to prevent a drop in the magnetic flux density in a low magnetic field. Also, lowering the carbon content decreases the magnetic aging of the steel, and thereby extends the length of time the steel retains its good magnetic properties. Hence, carbon is limited to a maximum of 0.010 percent. As shown in Figure 1, an even higher magnetic flux density can be obtained by reducing the carbon content to 0.005 percent or less.
- Low silicon and manganese are desirable for achieving high magnetic flux density in a low magnetic field; low manganese is also desirable for reducing MnS inclusions. Therefore 0.01 to 4.0 percent is specified as the limit for silicon and up to 0.20 percent for manganese. To reduce MnS inclusions, a manganese content of no more than 0.10 percent is preferable.
- Phosphorus, sulfur and oxygen produce non-metallic inclusions in the steel, and the segregation of these elements also obstructs the movement of the magnetic domain walls. As such, the higher the content amounts of these elements, the more pronounced the deterioration in the magnetic flux density and other magnetic properties. Therefore, an upper limit of 0.015 percent has been specified for phosphorus, 0.010 percent for sulfur, and 0.005 percent for oxygen.
- Because of the adverse effect chromium, molybdenum and copper have on magnetic flux density in a low magnetic field, preferably the content amounts of these elements are kept as low as possible. Another reason for minimizing these elements is to reduce the degree of segregation. Accordingly, an upper limit of 0.05 percent has been specified for chromium, 0.01 percent for molybdenum and 0.01 percent for copper.
- In its role as a deoxidizing agent, aluminum is an indispensable element for achieving internal uniformity in materials such as the plate according to the present invention, for which purpose a minimum of 0.001 percent is added. As excessive aluminum will give rise to inclusions, degrading the quality of the steel, an upper limit of 0.40 percent is specified. More preferably, the amount of aluminum should not exceed 0.020 percent in order to reduce the AlN which has the effect of refining the size of the crystal grains.
- Because nitrogen increases internal stresses in the steel and in the form of AlN has the effect of refining the size of the crystal grains, thereby causing a deterioration in magnetic flux density in a low magnetic field, an upper limit of 0.004 percent has been specified.
- To prevent hydrogen having an adverse effect on magnetic properties and preventing reductions in cavity defects, an upper limit of 0.0002 percent hydrogen has been specified.
- The method for producing the steel will now be described. The steel is heated to a temperature of 1150°C prior to rolling in order to coarsen the size of the austenite grains and improve the magnetic properties. An upper limit of 1350°C, preferably 1300°C is specified to prevent scaling loss and to conserve on energy.
- If the finish rolling temperature is below 900°C, the rolling will refine the size of the crystal grains, adversely affecting the magnetic properties. As such, a temperature of 900°C or more is specified with the aim of achieving an increase in the magnetic flux density as a result of a coarsening of the size of the crystal grains.
- Regarding the hot rolling, the solidification process will always give rise to cavity defects, although the size of the defects may vary. Rolling has to be used to eliminate such cavity defects, and as such, hot rolling plays an important role. An effective means is to increase the amount of deformation per hot rolling, so that the deformation extends to the core of the plate.
- Specifically, employing a high shape ratio which includes at least one pass at a shape ratio A of at least 0.7 so that the size of cavity defects is no larger than 100 micrometers is conducive to obtaining desirable magnetic properties. Eliminating cavity defects in the rolling process by using this high shape ratio rolling markedly enhances dehydrogenation efficiency in the subsequent dehydrogenation heat treatment.
-
- A:
- rolling shape ratio
- h₁:
- entry-side plate thickness (mm)
- h₀:
- exit-side plate thickness (mm)
- R:
- radius (mm) of rolling roll
- Because of this, dehydrogenation heat treatment is employed. However, if the temperature of the dehydrogenation heat treatment is below 600°C the dehydrogenation efficiency is poor, while if the temperature exceeds 750°C there is a partial onset of transformation. Therefore, a temperature range of 600 to 750°C is specified. After various studies relating to dehydrogenation time, a time (hours) of [0.6(t - 50) + 6] was found to be suitable (here, t (mm) stands for the thickness of the plate).
- The steel is optionally annealed to coarsen the size of the crystal grains and remove internal stresses. A temperature below 750°C will not produce coarsening of the crystal grains, while if the temperature exceeds 950°C, uniformity of the crystal grains in the thickness dimension of the plate cannot be maintained. Therefore an annealing temperature range of 750 to 950°C has been specified.
- Normalizing is optionally carried out to adjust the crystal grains in the thickness dimension of the plate and to remove internal stresses. However, with an Ac₃ point temperature of below 910°C or over 1000°C, uniformity of the crystal grains in the thickness dimension of the plate cannot be maintained, so a range of 910 to 1000°C has been specified for the normalizing temperature.
- The dehydrogenation heat treatment employed for heavy plates having a gage thickness of 50 mm or more can also be used for the annealing or normalizing. As hydrogen readily disperses in heavy plate that is from 20 mm to less than 50 mm thick, such heavy plate only requires annealing or normalizing, not dehydrogenation heat treatment.
- As another example of the present invention, rolling conditions can be used to coarsen the size of the crystal grains.
- For the present invention, appropriate conditions have been elucidated whereby abnormal grain growth is achieved to coarsen the size of the ferrite grains by the introduction of cold-rolling processing stresses and the use of the following annealing conditions, which was hitherto not possible.
- Figure 3 shows the relationship between cold-rolling reduction ratio and ferrite grain size. A major coarsening of the size of the crystal grains occurs with a cold-rolling reduction ratio of between 5 percent and 25 percent, with the peak being around 10 percent. Therefore, cold rolling is combined with annealing with the aim of achieving a coarsening of the size of the ferrite grains through abnormal grain growth. A suitable cold-rolling reduction ratio for this is 5 to 25 percent.
- The steel is annealed to coarsen the size of the crystal grains and remove internal stresses. A temperature below 750°C will not produce a coarsening of the crystal grains, while if the temperature exceeds 950°C, uniformity of the crystal grains in the thickness dimension of the plate cannot be maintained. Therefore an annealing temperature range of 750 to 950°C has been specified.
- Other examples whereby the size of the crystal grains is coarsened will now be described. AlN has the effect of refining the size of crystal grains, so grain size can be coarsened by reducing the AlN. As shown in Figure 4, lower aluminum produces an increase in the growth of ferrite grains. Where no aluminum has been added, so there is no more than 0.005 percent aluminum, abnormal growth of crystal grains takes place. However, if aluminum is not added, it becomes necessary to add a different deoxidizing agent.
- Instead of aluminum, the inventors found that silicon, titanium, or calcium are elements that can be used as deoxidizing agents and do not bring about a reduction of the magnetic flux density in a low magnetic field. The added amounts are: 0.01 to 4.0, preferably 0.1 to 1.0 percent silicon; 0.005 to 0.20, preferably to 0.03 percent titanium; and 0.0005 to 0.01, preferably 0.005 to 0.01 percent calcium. Titanium and calcium may be added in combination.
- In addition, as shown in Figure 5, using silicon as a deoxidizing agent where there is no added aluminum can impart to the steel a high tensile strength of 40 kg/mm² or more, and a high specific resistance of 35 » Ω · cm or more. A range of 0.01 to 4.0, preferably 1.0 to 4.0 percent is specified as the amount to be added, because over 4.0 percent will cause a reduction in magnetic flux density in a low magnetic field.
- Nickel is an effective element for reducing coercive force without reducing magnetic flux density in a low magnetic field. As shown in Figure 6, at least 0.1 percent nickel is preferred to reduce the coercive force. A content of more than 2.0 percent nickel produces an increase in the coercive force and reduces the magnetic flux density in a low magnetic field, therefore a range of up to 2.0 percent, preferably 0.1 to 2.0 percent has been specified. This range is also desirable as it enables the strength of the steel to be increased without reducing its magnetic properties.
- When titanium is to be used as a deoxidizing agent where there is no added aluminum, i.e., the aluminum content is no more than 0.005 percent, and for achieving a high tensile strength of 40 kg/mm² or more, as shown in Figure 7, at least 0.04 percent is preferred. However, as the magnetic flux density in a low magnetic field will be reduced if there is more than 0.20 percent titanium, a range of 0.005 to 0.20, preferably 0.04 to 0.20 percent is specified.
- Electrical steel heavy plate having the compositions listed in Table 1 were produced using the inventive and comparative conditions listed in Table 2. As shown, steels 1 to 10 are inventive steels and steels 11 to 27 are comparative steels.
- Steels 1 to 5, which were finished to a thickness of 100 mm and had coarse, uniform grains, exhibited good magnetic properties. Compared with steel 1,
steel 2, with lower carbon, steels 3 and 4, with lower manganese, andsteel 5, with lower aluminum, showed better magnetic properties. Steels 6 to 8, which were finished to a thickness of 500 mm, steel 9, which was finished to a thickness of 40 mm, andsteel 10, which was finished to a thickness of 20 mm, each had coarse, uniform grains and exhibited good magnetic properties. - As a result of the upper limit being exceeded for carbon in steel 11, manganese in steel 12, phosphorus in steel 13, sulfur in steel 14, chromium in steel 15, molybdenum in steel 16, copper in steel 17, nitrogen in steel 18, oxygen in steel 19 and hydrogen in
steel 20, each of these steels had poorer magnetic properties. - Poorer magnetic properties were also shown by
steel 21 because the heating temperature used was too low, by steel 22 because the rolling finishing temperature was too low, by steel 23 because the maximum shape ratio was too low, by steel 24 because the dehydrogenation temperature was too low, by steel 25 because the annealing temperature was too low, by steel 26 because the normalizing temperature was too high and by steel 27 because no dehydrogenation was applied. -
Steels 5 to 10 and steels 21 and 22 of Example 1 were used to produce electrical steel heavy plates using the conditions listed in Table 3. -
Inventive steels 5 to 10, which each had coarse, uniform grains, exhibited a high magnetic flux density.Comparative steels 21 and 22 showed poor magnetic properties owing to the heating temperature being too low in the case of the former and the rolling finishing temperature too low in the case of the latter. - Electrical steel heavy plate having the compositions listed in Table 4 were produced using the conditions listed in Table 5.
-
- Electrical steel heavy plate having the compositions listed in Table 6 were produced using the conditions listed in Table 7.
- Inventive steels 35 to 40, which each had coarse, uniform grains, exhibited good magnetic properties.
-
- Electrical steel heavy plate having the compositions listed in Table 8 were produced using the conditions listed in Table 9.
- Inventive steels 42 to 46, which each had coarse, uniform grains, exhibited good magnetic properties.
- Comparative steels 47 and 48, which had high calcium, each showed poor magnetic properties.
- Electrical steel heavy plate having the compositions listed in Table 10 were produced using the conditions listed in Table 11.
- Inventive steels 49 to 55, which each had coarse, uniform grains, exhibited a tensile strength of 40 kg/mm² or more, high specific resistance and high magnetic flux density in a low magnetic field.
-
- Electrical steel heavy plate having the compositions listed in Table 12 were produced using the conditions listed in Table 13.
- Inventive steels 57 to 63, which each had coarse, uniform grains, exhibited a high magnetic flux density in a low magnetic field, and a low coercive force.
-
- Electrical steel heavy plate having the compositions listed in Table 14 were produced using the conditions listed in Table 15.
- Inventive steels 65 to 71, which each had coarse, uniform grains, exhibited good tensile strength and magnetic properties.
-
Claims (10)
- A method of producing non-oriented magnetic steel heavy plate when the gauge thickness is 50 mm or more and having high magnetic flux density, the method comprising the steps of:
preparing a steel slab comprising, by weight, up to 0.01 percent carbon, up to 0.20 percent manganese, up to 0.015 percent phosphorus, up to 0.010 percent sulfur, up to 0.05 percent chromium, up to 2.0 percent nickel, up to 0.01 percent molybdenum, up to 0.01 percent copper, up to 0.004 percent nitrogen, up to 0.005 percent oxygen and up to 0.0002 percent hydrogen, and one or more deoxidizing agents selected from a group consisting of 0.01 to 4.0 percent silicon, 0.005 to 0.20 percent titanium, 0.001 to 0.40 percent aluminum, and 0.0005 to 0.01 percent calcium, with the remainder being iron and unavoidable impurities;
heating the slab to a temperature of 1150 to 1350°C;
carrying out at least one hot-rolling at a shape ratio A of at least 0.7 at a finish rolling temperature of at least 300°C;
applying dehydrogenation heat treatment at between 600 and 750°C;
optionally annealing at a temperature of 750 to 950°C or normalizing at a temperature of 910 to 1000°C, as required;
whereby a magnetic flux density of 0.8 tesla or more at a magnetic field of 80 A/m is imparted to the steel;
wherein:
whereA: rolling shape ratioh₁: entry-side plate thickness (mm)h₀: exit-side plate thickness (mm)R: radius (mm) of rolling roll. - A method of producing non-oriented magnetic steel heavy plate when the gauge thickness is at least 20 mm but less than 50 mm and having high magnetic flux density, the method comprising the steps of:
preparing a steel slab comprising, by weight, up to 0.01 percent carbon, up to 0.20 percent manganese, up to 0.015 percent phosphorus, up to 0.010 percent sulfur, up to 0.05 percent chromium, up to 2.0 percent nickel, up to 0.01 percent molybdenum, up to 0.01 percent copper, up to 0.004 percent nitrogen, up to 0.005 percent oxygen and up to 0.0002 percent hydrogen, and one or more deoxidizing agents selected from a group consisting of 0.01 to 4.0 percent silicon, 0.005 to 0.20 percent titanium, 0.001 to 0.40 percent aluminum, and 0.0005 to 0.01 percent calcium, with the remainder being iron and unavoidable impurities;
heating the slab to a temperature of 1150 to 1350°C;
carrying out at least one hot-rolling at a shape ratio A of at least 0.7 at a finish rolling temperature of at least 900°C;
applying annealing at a temperature of 750 to 950°C or normalizing at a temperature of 910 to 1000°C;
whereby a magnetic flux density of 0.8 tesla or more at a magnetic field of 80 A/m is imparted to the steel;
wherein:
whereA: rolling shape ratioh₁: entry-side plate thickness (mm)h₀: exit-side plate thickness (mm)R: radius (mm) of rolling roll. - The method according to claim 1 or 2 that includes the step of cold-rolling at a reduction ratio of between 5 and 25 percent, prior to the annealing.
- The method according to claims 1 to 3 wherein the slab heating temperature is 1200 to 1350°C.
- The method according to claims 1 to 4 wherein the composition of the steel contains 0.1 to 1.0 percent silicon and up to 0.005 percent aluminum.
- The method according to claims 1 to 4 wherein the composition of the steel contains 0.005 to 0.03 percent titanium and up to 0.005 percent aluminum.
- The method according to claims 1 to 4 wherein the composition of the steel contains up to 0.005 percent aluminum.
- The method according to claims 1 to 4 wherein the composition of the steel contains 1.0 to 4.0 percent silicon and up to 0.040 percent aluminum.
- The method according to claims 1 to 4 wherein the composition of the steel contains 0.01 to 2.0 percent nickel.
- The method according to claims 2 to 4 wherein the composition of the steel contains 0.04 to 0.20 percent titanium and up to 0.040 percent aluminum.
Applications Claiming Priority (20)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP15464388A JPH0689399B2 (en) | 1988-06-24 | 1988-06-24 | Manufacturing method of electromagnetic thick plate for DC magnetization |
JP63154641A JPH0745688B2 (en) | 1988-06-24 | 1988-06-24 | Method for manufacturing high magnetic flux density electromagnetic thick plate |
JP154644/88 | 1988-06-24 | ||
JP15464488A JPH0689400B2 (en) | 1988-06-24 | 1988-06-24 | Method of manufacturing electromagnetic thick plate for non-directional DC magnetization |
JP63154642A JPH06104866B2 (en) | 1988-06-24 | 1988-06-24 | Method for manufacturing electromagnetic thick plate for direct current magnetization |
JP63154640A JPH0711026B2 (en) | 1988-06-24 | 1988-06-24 | Manufacturing method of non-directional electromagnetic thick plate with high magnetic flux density |
JP154640/88 | 1988-06-24 | ||
JP154641/88 | 1988-06-24 | ||
JP154645/88 | 1988-06-24 | ||
JP154643/88 | 1988-06-24 | ||
JP15464588A JPH0689401B2 (en) | 1988-06-24 | 1988-06-24 | Manufacturing method of electromagnetic thick plate for non-directional DC magnetization |
JP154642/88 | 1988-06-24 | ||
JP156722/88 | 1988-06-27 | ||
JP156718/88 | 1988-06-27 | ||
JP15672088A JPH0745691B2 (en) | 1988-06-27 | 1988-06-27 | Non-directional good electromagnetic thick plate manufacturing method |
JP15672288A JPH0745692B2 (en) | 1988-06-27 | 1988-06-27 | Method for manufacturing non-oriented electromagnetic thick plate with high magnetic flux density |
JP156720/88 | 1988-06-27 | ||
JP63156718A JPH0745689B2 (en) | 1988-06-27 | 1988-06-27 | Manufacturing method of good electromagnetic thick plate |
JP15671988A JPH0745690B2 (en) | 1988-06-27 | 1988-06-27 | Manufacturing method of good electromagnetic thick plate |
JP156719/88 | 1988-06-27 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0349853A2 EP0349853A2 (en) | 1990-01-10 |
EP0349853A3 EP0349853A3 (en) | 1991-01-30 |
EP0349853B1 true EP0349853B1 (en) | 1995-03-01 |
Family
ID=27580338
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP89111463A Expired - Lifetime EP0349853B1 (en) | 1988-06-24 | 1989-06-23 | Method of producing non-oriented magnetic steel heavy plate having high magnetic flux density |
Country Status (3)
Country | Link |
---|---|
US (1) | US4950336A (en) |
EP (1) | EP0349853B1 (en) |
DE (1) | DE68921377T2 (en) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5037493A (en) * | 1989-03-16 | 1991-08-06 | Nippon Steel Corporation | Method of producing non-oriented magnetic steel plate having high magnetic flux density and uniform magnetic properties through the thickness direction |
EP0413306B1 (en) * | 1989-08-18 | 1996-04-10 | Nippon Steel Corporation | Method of producing non-oriented magnetic steel plate having high magnetic flux density |
JPH0770715A (en) * | 1993-09-01 | 1995-03-14 | Nkk Corp | Soft magnetic steel excellent in strain resistance and production thereof |
DE19807122C2 (en) * | 1998-02-20 | 2000-03-23 | Thyssenkrupp Stahl Ag | Process for the production of non-grain oriented electrical sheet |
JP4013505B2 (en) | 2000-11-27 | 2007-11-28 | 住友金属工業株式会社 | Ultra-low carbon steel sheet and manufacturing method thereof |
JP4303431B2 (en) * | 2000-12-11 | 2009-07-29 | 新日本製鐵株式会社 | Ultra high magnetic flux density non-oriented electrical steel sheet and manufacturing method thereof |
JP2006501361A (en) * | 2002-05-08 | 2006-01-12 | エイケイ・プロパティーズ・インコーポレイテッド | Continuous casting method of non-oriented electrical steel strip |
US20050000596A1 (en) * | 2003-05-14 | 2005-01-06 | Ak Properties Inc. | Method for production of non-oriented electrical steel strip |
TWI622655B (en) | 2016-01-15 | 2018-05-01 | Jfe Steel Corp | Non-oriented electromagnetic steel plate and manufacturing method thereof |
CN112080695B (en) * | 2020-08-31 | 2021-10-26 | 江苏省沙钢钢铁研究院有限公司 | High-silicon non-oriented electrical steel and production method thereof |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3948691A (en) * | 1970-09-26 | 1976-04-06 | Nippon Steel Corporation | Method for manufacturing cold rolled, non-directional electrical steel sheets and strips having a high magnetic flux density |
JPS5032059B2 (en) * | 1971-12-24 | 1975-10-17 | ||
US4054471A (en) * | 1976-06-17 | 1977-10-18 | Allegheny Ludlum Industries, Inc. | Processing for cube-on-edge oriented silicon steel |
JPS6096749A (en) * | 1983-11-01 | 1985-05-30 | Nippon Steel Corp | Thick plate for dc magnetization and preparation thereof |
JPS60208418A (en) * | 1984-03-30 | 1985-10-21 | Sumitomo Metal Ind Ltd | Production of thick steel plate having high magnetic permeability for structural member |
JPS6169923A (en) * | 1984-09-13 | 1986-04-10 | Kawasaki Steel Corp | Manufacture of non-orientation silicon steel plate of good surface |
JPH0696749A (en) * | 1992-09-16 | 1994-04-08 | Matsushita Electric Ind Co Ltd | Dry battery |
-
1989
- 1989-06-19 US US07/368,031 patent/US4950336A/en not_active Expired - Fee Related
- 1989-06-23 EP EP89111463A patent/EP0349853B1/en not_active Expired - Lifetime
- 1989-06-23 DE DE68921377T patent/DE68921377T2/en not_active Expired - Fee Related
Non-Patent Citations (1)
Title |
---|
PATENT ABSTRACTS OF JAPAN vol. 9, no. 237 (C-305)[1960], 24 September 1985 & JP-A-6096749 (SHIN NIPPON SEITETSU) * |
Also Published As
Publication number | Publication date |
---|---|
EP0349853A2 (en) | 1990-01-10 |
DE68921377T2 (en) | 1995-11-02 |
EP0349853A3 (en) | 1991-01-30 |
DE68921377D1 (en) | 1995-04-06 |
US4950336A (en) | 1990-08-21 |
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