EA200600431A1 - Способ переработки угля в моторные топлива - Google Patents

Способ переработки угля в моторные топлива

Info

Publication number
EA200600431A1
EA200600431A1 EA200600431A EA200600431A EA200600431A1 EA 200600431 A1 EA200600431 A1 EA 200600431A1 EA 200600431 A EA200600431 A EA 200600431A EA 200600431 A EA200600431 A EA 200600431A EA 200600431 A1 EA200600431 A1 EA 200600431A1
Authority
EA
Eurasian Patent Office
Prior art keywords
synthesis gas
stage
gas
reactor
gasification
Prior art date
Application number
EA200600431A
Other languages
English (en)
Other versions
EA008269B1 (ru
Inventor
Чавдар Ангелов Ангелов
Original Assignee
Чавдар Ангелов Ангелов
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Чавдар Ангелов Ангелов filed Critical Чавдар Ангелов Ангелов
Publication of EA200600431A1 publication Critical patent/EA200600431A1/ru
Publication of EA008269B1 publication Critical patent/EA008269B1/ru

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/721—Multistage gasification, e.g. plural parallel or serial gasification stages
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/02—Fixed-bed gasification of lump fuel
    • C10J3/06—Continuous processes
    • C10J3/18—Continuous processes using electricity
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/78—High-pressure apparatus
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/093—Coal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0973—Water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/12—Heating the gasifier
    • C10J2300/123—Heating the gasifier by electromagnetic waves, e.g. microwaves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/12—Heating the gasifier
    • C10J2300/123—Heating the gasifier by electromagnetic waves, e.g. microwaves
    • C10J2300/1238—Heating the gasifier by electromagnetic waves, e.g. microwaves by plasma
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1625—Integration of gasification processes with another plant or parts within the plant with solids treatment
    • C10J2300/1628—Ash post-treatment
    • C10J2300/1634—Ash vitrification
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/164—Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
    • C10J2300/1656—Conversion of synthesis gas to chemicals
    • C10J2300/1659—Conversion of synthesis gas to chemicals to liquid hydrocarbons

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Industrial Gases (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

Способ может быть использован в химической и нефтехимической промышленности для производства синтез-газа - сырья для получения разных видов химической продукции и синтетических моторных топлив. Он отличается повышенной эффективностью процесса получения синтез-газа из сильновязкого водоугольного топлива. Способ включает стадию приготовления водоугольной смеси и ее газификацию в две стадии. Первую стадию проводят в вертикальном проточном трубчатом теплообменнике газификационной колонны, а вторую стадию - в нагреваемом реакторе с получением синтез-газа и твердых отходов. Далее способ включает стадию каталитической переработки синтез-газа в моторные топлива. Характерно то, что парогазоугольную смесь в теплообменнике подвергают воздействию модулированными высокочастотными полями в частотном диапазоне от 1 до 50 МГц при частотах модуляции в диапазоне от 1 до 200 кГц. В реакторе парогазоугольную смесь подвергают воздействию плазмой одноэлектродных высокочастотных разрядов при температуре 600-800°С. Полученный синтез-газ подвергают электрохимической очистке от соединений серы и азота, очистке от химических примесей, компримируют и подвергают превращению на полифункциональном катализаторе, содержащем оксиды железа, цинка и молибдена в комбинации с носителем - алюминием, его оксидами и фосфатом алюминия. Процесс газификации парогазоугольной смеси в реакторе можно проводить в присутствии катализаторов паровой конверсии углерода, нанесенных на теплоизолирующие покрытия внутренних стенок реактора.
EA200600431A 2005-07-29 2006-03-16 Способ переработки угля в моторные топлива EA008269B1 (ru)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
BG109247A BG109247A (bg) 2005-07-29 2005-07-29 Метод за преработка на въглища в горива

Publications (2)

Publication Number Publication Date
EA200600431A1 true EA200600431A1 (ru) 2007-02-27
EA008269B1 EA008269B1 (ru) 2007-04-27

Family

ID=35614578

Family Applications (1)

Application Number Title Priority Date Filing Date
EA200600431A EA008269B1 (ru) 2005-07-29 2006-03-16 Способ переработки угля в моторные топлива

Country Status (5)

Country Link
EP (1) EP1996679A1 (ru)
BG (1) BG109247A (ru)
EA (1) EA008269B1 (ru)
UA (1) UA79216C2 (ru)
WO (1) WO2007012151A1 (ru)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2423079B (en) 2005-06-29 2008-11-12 Tetronics Ltd Waste treatment process and apparatus
UA78474C2 (en) * 2006-08-17 2007-03-15 Private Entpr Radical Plus Method for intensification of solid fuel burning
US20130074396A1 (en) 2008-06-30 2013-03-28 Gustavo A. Núñez Nano-dispersions of carbonaceous material in water as the basis of fuel related technologies and methods of making same
WO2010039315A2 (en) 2008-06-30 2010-04-08 Nano Dispersions Technology, Inc. Nano-dispersions of coal in water as the basis of fuel related tecfinologies and methods of making same
CN101671576B (zh) * 2009-09-22 2013-04-24 武汉凯迪控股投资有限公司 利用合成气返烧的辅助气化工艺及其设备
CN101671578B (zh) * 2009-09-22 2012-11-21 武汉凯迪控股投资有限公司 可燃物料等离子体高温气化工艺及其设备
GB2478797B (en) 2010-03-19 2015-11-04 Advanced Plasma Power Ltd Waste treatment
US8667914B2 (en) 2010-05-07 2014-03-11 Advanced Plasma Power Limited Waste treatment
WO2015151028A1 (en) * 2014-04-01 2015-10-08 Ugra S.R.L. Apparatus and method for the processing of waste material
RU2688614C1 (ru) * 2018-08-24 2019-05-21 Федеральное государственное бюджетное образовательное учреждение высшего образования "Кубанский государственный технологический университет" (ФГБОУ ВО "КубГТУ") Способ получения синтез-газа
CN112745961B (zh) * 2019-10-31 2021-08-06 中国石油化工股份有限公司 一种立式微波加热生物质气化反应器

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4435374A (en) * 1981-07-09 1984-03-06 Helm Jr John L Method of producing carbon monoxide and hydrogen by gasification of solid carbonaceous material involving microwave irradiation
RU2047650C1 (ru) * 1993-09-28 1995-11-10 Акционерное общество "Трансрегион" Плазмотермический способ переработки угля в синтез-газ
US6533945B2 (en) * 2000-04-28 2003-03-18 Texaco Inc. Fischer-Tropsch wastewater utilization
US7622693B2 (en) * 2001-07-16 2009-11-24 Foret Plasma Labs, Llc Plasma whirl reactor apparatus and methods of use
US6664302B2 (en) * 2002-04-12 2003-12-16 Gtl Energy Method of forming a feed for coal gasification
WO2004044492A1 (en) * 2002-11-14 2004-05-27 David Systems Technology, S.L. Method and device for integrated plasma-melt treatment of wastes
RU2233312C1 (ru) * 2002-12-16 2004-07-27 Государственное унитарное предприятие Научно-производственное объединение "Гидротрубопровод" Способ получения синтез-газа из водоугольной суспензии
NZ523665A (en) * 2003-01-15 2004-02-27 Rajeev Prasad Gupta Use of microwave energy for the combustion of organic material
ITVI20030030A1 (it) * 2003-02-13 2004-08-14 Xarox Group Ltd Procedimento ed impianto per la conversione di rifiuti

Also Published As

Publication number Publication date
UA79216C2 (en) 2007-05-25
EP1996679A1 (en) 2008-12-03
BG109247A (bg) 2005-11-30
EA008269B1 (ru) 2007-04-27
WO2007012151A1 (en) 2007-02-01

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Legal Events

Date Code Title Description
MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

Designated state(s): AZ BY KZ RU