CN204198864U - A kind of Integrated Processing Unit of hydro-electrolytic hydrogen production device - Google Patents
A kind of Integrated Processing Unit of hydro-electrolytic hydrogen production device Download PDFInfo
- Publication number
- CN204198864U CN204198864U CN201420612176.8U CN201420612176U CN204198864U CN 204198864 U CN204198864 U CN 204198864U CN 201420612176 U CN201420612176 U CN 201420612176U CN 204198864 U CN204198864 U CN 204198864U
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- gas
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- integrated processing
- hydrogen production
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
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- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Abstract
The utility model relates to a kind of Integrated Processing Unit of hydro-electrolytic hydrogen production device, belongs to the brine electrolysis technical field of hydrogen or oxygen.Gas feed is arranged at the bottom of this device tank body, and the outlet of moisturizing upflow tube reaches bottom gas-liquid separator; The bottom of tank body is provided with the moisturizing import with ft connection; The middle part of tank body is provided with reflux assembly; The top of tank body is provided with to catch drips net.The Integrated Processing Unit of this hydro-electrolytic hydrogen production device carries out integrating for prior art and supplements, multistep in water electrolysis hydrogen producing process is concentrated, propose a kind ofly to wash gas in water electrolysis hydrogen producing gas process simultaneously, cool, Integrated Processing Unit to system water supplement, realize multifunctional all, reduce total floor space of hydro-electrolytic hydrogen production device, cost-saving and improve device integral space utilization ratio.
Description
Technical field
The utility model relates to a kind for the treatment of unit of hydrogen manufacturing, belongs to the brine electrolysis technical field of hydrogen or oxygen.
Background technology
The general technology flow process of water electrolysis hydrogen producing is: adopt 25 ~ 30% potassium hydroxide or aqueous sodium hydroxide solution to be electrolytic solution, electrolyzer works under 80 ~ 90 DEG C of conditions.When electrolytic system normally runs, industrial soft water through pure water device Pure-water Making, and sends into pure water water tank, through small pump input alkali lye system, supplements the water consumed because of electrolysis.Water is electrolyzed to produce H in a cell
2with O
2, and with do not enter in gas-liquid processing device together with the alkali lye of electrolysis, then carry out gas-liquid separation at gas-liquid separator, the gas separated is again through gas scrubber, gas cooler.In the process, the gas water content after gas-liquid separation and alkalinity are comparatively large, and gas temperature is high, need multi step strategy progressively to reduce alkaline matter content in gas, to reduce alkaline matter in gas to the impact of overall hydro-electrolytic hydrogen production device.
Relative, contain alkali in gas so the alkaline matter in electrolytic solution is in continuous minimizing, electrolysis work can be affected because the concentration of alkali lye reduces, and alkali lye does to shut down and supplements by prior art, can reduce hydrogen output capacity.The more loaded down with trivial details concentration of lye of technique floats comparatively large, and hydrogen output capacity is unstable.
And in order to reduce alkaline matter corrosion hydro-electrolytic hydrogen production device, dealkalize can be realized by washing plant through overcooled gas.
In addition, often moisturizing will be carried out, because the normal working temperature in electrolyzer is at about 85 DEG C, so add again in electrolyzer after needing to carry out preheat process to moisturizing in electrolyzer operational process, otherwise electric tank working temperature can be affected, reduce the quality of output hydrogen.
Thus on the whole, hydro-electrolytic hydrogen production device is must be obligato for techniques such as gas cooling, dealkalize and moisturizings, but these equipment disperses and disunity in prior art, cause the complicated of hydro-electrolytic hydrogen production device and maximize, bringing the series of problems such as occupation of land, maintenance, economic benefit.
Utility model content
First technical problem to be solved in the utility model is: ensure while hydro-electrolytic hydrogen production device normally runs, total floor space of hydro-electrolytic hydrogen production device can be reduced again,, not enough for prior art, a kind of Integrated Processing Unit each technical process being concentrated one is proposed.
Second technical problem to be solved in the utility model is: solution the first technical problem while, reduces the volume of this Integrated Processing Unit self.
The utility model is the first technical scheme that solution first technical problem proposes: a kind of Integrated Processing Unit of hydro-electrolytic hydrogen production device, the gas-liquid separator of described hydro-electrolytic hydrogen production device is communicated with below this Integrated Processing Unit, this Integrated Processing Unit comprises tank body, the bottom of described tank body is provided with the moisturizing import with ft connection, middle part in described tank body is provided with backflow mechanism, and the top in described tank body is provided with to catch drips net; Described backflow mechanism comprises at least two-layer fining air bubbles net be arranged in described tank body and the reflux assembly be arranged in the middle part of described fining air bubbles net; Described reflux assembly comprises substrate and is fixed in three layers of sleeve pipe below described substrate, and described substrate has through hole, and described three layers of sleeve pipe are followed successively by moisturizing upflow tube, inlet pipe and gas return line from inside to outside, and described through hole is communicated with described moisturizing upflow tube.
The beneficial effect of the first technical scheme is: again through refinement net dispersing and disintegrating after entering this device containing the high-temperature gas of alkaline matter from inlet pipe, gas is fully contacted, by soluble in water for the alkaline matter entrained by it while gas and water carry out heat exchange with water in tank.
Consider the problems such as the consumption of water in the saturation ratio of alkaline aqueous solution in tank, the mistake of electrolyzer neutral and alkali Commodity flow speed and electrolyzer, so be provided with moisturizing import in the below of tank body, for device provides water, and when in tank body water level reach a certain height Shi Huicong be arranged on tank body center moisturizing upflow tube be back to gas-liquid separator, withdrawing fluid is the basic solution with certain temperature, and this solution is for electrolyzer provides the solution of real moisturizing.
This device is while the normal work that ensure that hydro-electrolytic hydrogen production device thus, namely gas is tentatively cooled, gas is carried out to lixiviating process and moisturizing is carried out to hydro-electrolytic hydrogen production device, the device originally processed used by these operations carried out integrated concentrating, total floor space of hydro-electrolytic hydrogen production device is reduced greatly.
On the basis of the first technical scheme the utility model be solution second technical problem propose the second technical scheme be: described inlet pipe has some ventilating pits on the tube wall of edge of substrate, described moisturizing upflow tube extends downwardly in described gas-liquid separator, described inlet pipe is docked with the air outlet of described gas-liquid separator downwards, and described gas backstreaming pipe also passes the lowest layer of described fining air bubbles net to downward-extension.
The beneficial effect of the second technical scheme is: by the design by the lowest layer of gas backstreaming pipe to downward-extension and through described fining air bubbles net, the movement travel of gas in tank body of coming in from inlet pipe is strengthened, gas is once cooled, gas is transported to tank body bottom afterwards, and floated by natural buoyancy effect, by fining air bubbles net dispersing and disintegrating in floating-upward process, small bubbles after disperseing fully are contacted with water, contained alkaline matter is water-soluble, at utmost to reduce the alkaline matter of going out contained by gas from this device, decrease the corrosion of gas to hydro-electrolytic hydrogen production device of conveying, extend the work-ing life of whole plant.
State is normally run at guarantee hydro-electrolytic hydrogen production device, under carrying out each technique integrating the major premise concentrating on a device, this device reasonably make use of limited space by above-mentioned relating to, reduce the volume of this device self to the full extent, device itself can not be made because function is too many to become too complicated.
The improvement of above-mentioned first technical scheme is: described gas backstreaming pipe periphery wall dish is provided with cooling water coil.
The beneficial effect of technique scheme is: establish cooling water coil at the periphery wall dish of three layers of outermost gas backstreaming pipe of sleeve pipe, to be reduced in the temperature of the gas flowed in pipeline further, to slow down the cooling pressure of this device and exports the cooling temperature of gas.
The improvement of technique scheme is: first bubble refinement net sets firmly on the substrate, and the second fining air bubbles net is positioned at the bottom of described backflow mechanism, and the order number of described first bubble refinement net is greater than the order number of described second fining air bubbles net.
The improvement of technique scheme is: be also provided with order number between described first bubble refinement net and described second fining air bubbles and be less than described first bubble refinement mesh number and the some fining air bubbles nets being greater than described second fining air bubbles mesh number.
The beneficial effect of technique scheme is: the second fining air bubbles mesh number is greater than first bubble refinement mesh number, carrys out further dispersing and disintegrating gas with this; MLV refinement net is set, can maximum attenuating gas in the scope that practical situation allow, be dissolved completely in water in the hope of the incidental alkaline matter of gas.
The improvement of technique scheme is: described moisturizing ingress is provided with T-way water valve, and the outlet of described cooling water coil is by the water inlet of pipeline communication to described T-way water valve.
The beneficial effect of technique scheme is: the outlet of cooling water coil, by the water inlet of pipeline communication to T-way water valve, makes water coolant can be passed into tank body interior as moisturizing for subsequent use, carrys out water saving, more environmental protection with this.
Accompanying drawing explanation
Below in conjunction with accompanying drawing, the utility model is described in further detail:
Fig. 1 is the structural representation of the Integrated Processing Unit of the hydro-electrolytic hydrogen production device of the utility model embodiment.
Embodiment
Embodiment
The Integrated Processing Unit of a kind of hydro-electrolytic hydrogen production device of the present embodiment, as shown in Figure 1, the bottom import of this Integrated Processing Unit inlet pipe 14 is communicated with the air outlet 1 of gas-liquid separator below it 2, and connected by flange seal, gas is got rid of from the top gas outlet 10 of the Integrated Processing Unit of this hydro-electrolytic hydrogen production device, the Integrated Processing Unit of this hydro-electrolytic hydrogen production device comprises tank body 9, the bottom of tank body 9 is provided with the moisturizing import 4 with ft connection, the middle part of tank body 9 is provided with backflow mechanism, the top of tank body 9 is provided with and is arranged at catching in tank body 9 along tank body 9 radial direction and drips a net 11, backflow mechanism comprises first bubble refinement net 12, the second fining air bubbles net 13 be arranged in described tank body and the reflux assembly be arranged in the middle part of fining air bubbles net, three layers of sleeve pipe that reflux assembly comprises substrate 8 and is welded in below substrate 8, the center of substrate 8 has through hole, first bubble refinement net 12 just sets firmly on the substrate 8, and three layers of sleeve pipe are followed successively by moisturizing upflow tube 3, inlet pipe 14 and gas return line 6 from inside to outside, and through hole is communicated with moisturizing upflow tube 3.
Have some ventilating pits in inlet pipe 14 near substrate 8 end, the other end of moisturizing upflow tube 3 extends to below the liquid level of gas-liquid separator 2, to prevent gas from entering into this Integrated Processing Unit from moisturizing upflow tube 3 adverse current, affects the normal operation of device.Return line 6 the other end extends to the below of backflow mechanism, also namely extends to the below of the second fining air bubbles net 13, gas is fully washed by fining air bubbles net dispersing and disintegrating, farthest eliminate in gas with alkaline matter; The periphery wall of gas backstreaming pipe 6, namely the outermost layer of reflux assembly is arranged with cooling water coil 15.
The order number of the first layer fining air bubbles net 12 of the present embodiment is greater than the order number of described second layer fining air bubbles net 13.
MLV refinement net can also can also be added in the present embodiment between first bubble refinement net 12 and the second fining air bubbles net 13, and the order number of refinement net can by lower from upper increasing successively also can be that the order number of each fining air bubbles net is consistent, to reach better gas refinement dispersion effect.Import 7 and the outlet 5 of cooling water coil 15 are all arranged on the outside of tank body 9, control opening and closing by water valve.
Moisturizing import 4 place of the present embodiment is provided with T-way water valve, and the outlet of cooling water coil 15 is by the water inlet of pipeline communication to T-way water valve.
Opening on the substrate 8 of the present embodiment is arranged on the center of substrate 8.Can certainly according to needing to be opened on other positions of substrate 8, but open better effects if center relatively other positions, its can make gas dissipates heat evenly, also comparatively close with water temperature in each position in timer.
The integration unit of the present embodiment is by the apparatus integration of the cooling in hydrogen production process by water electrolysis, washing and moisturizing, total floor space of hydro-electrolytic hydrogen production device is reduced with this, reasonably designed by some simultaneously, while guarantee water power hydrogen producer normally runs, at utmost reduce the cumulative volume of equipment, so need not worry because overconcentration of power in the managerial system function causes equipment enlarging and complicated problem.
It is worth mentioning that, this device can not only ensure the normal operation of hydro-electrolytic hydrogen production device, in some details, also notes how Appropriate application electric energy, heat energy and water resources, to adapt to country to the efficient requirement of energy-saving, emission-reducing, environment friendly.Such as high-temperature gas is used for preheating moisturizing, gets back in tank body and the measure such as washing liq backflow by logical for water coolant.
Water electrolysis hydrogen producing obtain gas be a kind of high humidity, temperature high, containing the gas of alkaline matter, general step first washs after gas cooling again, and constantly carrying out along with electrolysis, the solute of electrolytic solution and the amount of solvent are all in minimizing, namely alkaline matter and water are all in loss, so will supplement, and the working temperature of electrolytic solution is general all very high, cold water directly injection can affect normally carrying out of electrolysis, therefore needs to carry out preheat process to reduce impact.
And by the appropriate design of some structures in this case, avoid and occur the problems referred to above, wash after first having carried out preliminary cooling, the solution return of alkaline matter is contained in electrolyzer after by washing, and the high-temperature gas directly passing into this device heats the water in tank body, so the problem worrying backflow water temperature need not be gone again.
In use, need first by pre-mounted part water in tank body 9, it is not highly higher than first bubble refinement net 12.The gas that the electrolysis of the present embodiment obtains enters into the neutralizing treatment device of the present embodiment from inlet pipe 14, now in gas, alkalinity, water content and gas temperature are all higher, and general processing mode first cools to wash except alkali performs some follow-up processing steps more again, and after using this device, the gas of high temperature height alkali content high water content is directly delivered into this device, gas is through cooling for reflux, and the below gas temperature that now gas temperature has more just been carried into being transported to the second fining air bubbles net 13 has compared obvious decline.Gas floats by fining air bubbles net dispersing and disintegrating in water, the alkaline matter contained in bubble is soluble in water, gas is after passing through first bubble refinement net 12, alkaline matter content in gas has obvious reduction, but still have higher water content, therefore the Integrated Processing Unit of the present embodiment is also provided with one and catches a net 11 on the top of tank body 9, and this measure reduces to a certain extent finally by the water content of pneumatic outlet 10 expellant gas.
As can be seen from foregoing description we, the Integrated Processing Unit of the present embodiment completes the washing, the cooling that electrolysis are obtained to gas, and the present embodiment can also solve as Problems existing in this technique of electrolyzer moisturizing.
Integrated Processing Unit in the present embodiment, there is a set of water charging system that can carry out heat exchange, the temperature of the water that will fill in electrolyzer is heated while cooling gas, these water are exactly for gas carries out washing the water except alkali, therefore there is certain alkalinity in these water, the loss of the alkaline matter in electrolyzer can well be slowed down.
The utility model is not limited to above-described embodiment.All employings are equal to the technical scheme of replacing and being formed, and all drop on the protection domain of the utility model requirement.
Claims (6)
1. the Integrated Processing Unit of a hydro-electrolytic hydrogen production device, the gas-liquid separator of described hydro-electrolytic hydrogen production device is communicated with below this Integrated Processing Unit, it is characterized in that: this Integrated Processing Unit comprises tank body, the bottom of described tank body is provided with the moisturizing import with ft connection, middle part in described tank body is provided with backflow mechanism, and the top in described tank body is provided with to catch drips net; Described backflow mechanism comprises at least two-layer fining air bubbles net be arranged in described tank body and the reflux assembly be arranged in the middle part of described fining air bubbles net; Described reflux assembly comprises substrate and is fixed in three layers of sleeve pipe below described substrate, and described substrate has through hole, and described three layers of sleeve pipe are followed successively by moisturizing upflow tube, inlet pipe and gas return line from inside to outside, and described through hole is communicated with described moisturizing upflow tube.
2. the Integrated Processing Unit of hydro-electrolytic hydrogen production device as claimed in claim 1, it is characterized in that: described inlet pipe has some ventilating pits on the tube wall of edge of substrate, described moisturizing upflow tube extends downwardly in described gas-liquid separator, described inlet pipe is docked with the air outlet of described gas-liquid separator downwards, and described gas backstreaming pipe also passes the lowest layer of described fining air bubbles net to downward-extension.
3. the Integrated Processing Unit of hydro-electrolytic hydrogen production device as claimed in claim 1, is characterized in that: described gas backstreaming pipe periphery wall dish is provided with cooling water coil.
4. the Integrated Processing Unit of the hydro-electrolytic hydrogen production device as described in claim 1,2 or 3, it is characterized in that: first bubble refinement net sets firmly on the substrate, second fining air bubbles net is positioned at the bottom of described backflow mechanism, and the order number of described first bubble refinement net is greater than the order number of described second fining air bubbles net.
5. the Integrated Processing Unit of hydro-electrolytic hydrogen production device as claimed in claim 4, is characterized in that: be also provided with order number between described first bubble refinement net and described second fining air bubbles and be less than described first bubble refinement mesh number and some fining air bubbles nets of being greater than described second fining air bubbles mesh number.
6. the Integrated Processing Unit of hydro-electrolytic hydrogen production device as claimed in claim 3, it is characterized in that: described moisturizing ingress is provided with T-way water valve, the outlet of described cooling water coil is by the water inlet of pipeline communication to described T-way water valve.
Priority Applications (1)
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CN201420612176.8U CN204198864U (en) | 2014-10-22 | 2014-10-22 | A kind of Integrated Processing Unit of hydro-electrolytic hydrogen production device |
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CN201420612176.8U CN204198864U (en) | 2014-10-22 | 2014-10-22 | A kind of Integrated Processing Unit of hydro-electrolytic hydrogen production device |
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CN204198864U true CN204198864U (en) | 2015-03-11 |
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CN201420612176.8U Withdrawn - After Issue CN204198864U (en) | 2014-10-22 | 2014-10-22 | A kind of Integrated Processing Unit of hydro-electrolytic hydrogen production device |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104388971A (en) * | 2014-10-22 | 2015-03-04 | 苏州竞立制氢设备有限公司 | Comprehensive treatment device for hydrogen manufacturing equipment through water electrolysis |
CN107452432A (en) * | 2017-08-01 | 2017-12-08 | 福建宁德核电有限公司 | Washer |
-
2014
- 2014-10-22 CN CN201420612176.8U patent/CN204198864U/en not_active Withdrawn - After Issue
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104388971A (en) * | 2014-10-22 | 2015-03-04 | 苏州竞立制氢设备有限公司 | Comprehensive treatment device for hydrogen manufacturing equipment through water electrolysis |
CN104388971B (en) * | 2014-10-22 | 2017-07-04 | 苏州竞立制氢设备有限公司 | The Integrated Processing Unit of hydro-electrolytic hydrogen production device |
CN107452432A (en) * | 2017-08-01 | 2017-12-08 | 福建宁德核电有限公司 | Washer |
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Legal Events
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C14 | Grant of patent or utility model | ||
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AV01 | Patent right actively abandoned |
Granted publication date: 20150311 Effective date of abandoning: 20170704 |
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AV01 | Patent right actively abandoned |