CN1949062A - Liquid crystal display panel and mfg. method thereof - Google Patents

Liquid crystal display panel and mfg. method thereof Download PDF

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CN1949062A
CN1949062A CN 200510113470 CN200510113470A CN1949062A CN 1949062 A CN1949062 A CN 1949062A CN 200510113470 CN200510113470 CN 200510113470 CN 200510113470 A CN200510113470 A CN 200510113470A CN 1949062 A CN1949062 A CN 1949062A
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liquid crystal
substrate
display panels
resistant strata
panels according
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CN1949062B (en
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高振宽
蔡玉婷
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Chi Mei Optoelectronics Corp
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Abstract

The invention supplies one liquid crystal display panel. It includes one base plate, one opposite base plate, one liquid crystal stationary layer, and one liquid crystal layer. The liquid crystal stationary layer is set at the base plate. Its surface has many convex matters of which height is between 10nm and 200nm; maximum breadth is almost between 150nm and 600nm. In addition, the liquid crystal layer is sealed between the base plate and the opposite base plate. The invention also supplies the liquid crystal display panel manufacturing method.

Description

Display panels and manufacture method thereof
[technical field]
The invention relates to a kind of display panel and manufacture method thereof, and particularly relevant for a kind of display panels and manufacture method thereof.
[prior art]
Along with the significantly progressive and internet of computing power, the high development of multimedia technology, the transmission of image information at present transfers digital transmission to by simulation mostly.In addition, in order to cooperate modern life pattern, it is frivolous that the volume of video signal or device for image also day by day is tending towards.Traditional cathode-ray tube (CRT) though still have its advantage, because the structure in internal electron chamber, makes that display is bulky and takes up space, and it still has radiant rays to hinder problems such as eye when showing.Therefore, the plane formula display panel (flat panel display) that cooperates photoelectric technology and semiconductor fabrication to be developed, for example LCD (liquid crystal display), organic light emitting display (Organic light-emittingdisplay) or plasma scope (Plasma Display Panel, PDP) etc., become the main flow of display product gradually.
Fig. 1 illustrates the diagrammatic cross-section into existing display panels.Please refer to Fig. 1, aspect LCD, available liquid crystal display panel 100 mainly comprises a subtend substrate 110, a substrate 120, a both alignment layers 130, a both alignment layers 140 and a liquid crystal layer 150.In addition, both alignment layers 130 is to be disposed on the subtend substrate 110, and both alignment layers 140 then is disposed on the substrate 120, and wherein both alignment layers 130 and 140 material are the material of polyamide class (polyimide).In addition, 150 of liquid crystal layers are sealed between subtend substrate 110 and the substrate 120.
When an electrical potential energy is formed between subtend substrate 110 and the substrate 120, the liquid crystal molecule of liquid crystal layer 150 just can be subjected to this electrical potential energy intensity influence and produce deflection, make display panels 100 have light penetration rate corresponding to this voltage.Thus, display panels 100 just can be according to the electrical potential energy size between subtend substrate 110 and the substrate 120, and shows different grey menu.
Effect that it should be noted that both alignment layers 130 and 140 mainly is to provide the stable boundary condition of liquid crystal molecule of liquid crystal layer 150 so that liquid crystal molecule along specific preface to arrangement.But because existing both alignment layers 130 and 140 has its material and structural restriction, so the both alignment layers 130 of prior art and 140 can't surely be positioned at the liquid crystal molecule of liquid crystal layer 150 boundaries effectively.
Be with when applying an electrical potential energy between substrate 120 and subtend substrate 110 time, such phenomenon just causes the reaction velocity of liquid crystal molecule comparatively slow easily.Thus, when display panels 100 when showing a continuous pictures, just be easy to generate the discontinuous or slack situation of other display effect of picture.In addition, except the problem of reaction velocity, liquid crystal molecule is also easy of the boundary condition instability, and the situation of yawing moment mistake takes place under the influence of electrical potential energy, and then causes the reduction of display panels 100 picture qualities.At this problem, in United States Patent (USP) case numbers 6,043,860, a kind of method that reduces the stabilization time of liquid crystal molecule is proposed just.The method mainly is via the mode of adding monomer (monomer) in liquid crystal layer 150, surely is positioned at the liquid crystal molecule of liquid crystal layer 150 boundaries, and accelerates the reaction velocity of liquid crystal molecule.
In addition, except the slow partially problem of the reaction rate of above-mentioned liquid crystal molecule, aspect the angle of visibility scope that promotes display panels 100, prior art also faces technical bottleneck.For example, both alignment layers 130 and 140 needs to handle via friction (rubbing) repeatedly usually, just can make the liquid crystal molecule of liquid crystal layer 150 produce multidirectional orientation effect.Yet so not only orientation effect of the practice is limited, and its manufacturing process is also comparatively complicated, and the manufacturing process yield is also on the low side.
Except making the liquid crystal molecule of liquid crystal layer 150 produce outside multidirectional orientation effect via friction treatment repeatedly, prior art can also directly change the daylighting alignment materials with the material of both alignment layers 130 and 140.Yet such practice not only needs to consider outside the stability of light alignment materials, and the required exposure sources of manufacturing process is also expensive and complicated completely.
Moreover, prior art more can through because form projection (protrusion) on the both alignment layers 130,140, above-mentioned projection and slit were gone up or adopted simultaneously to the slit (slit) that forms patterning at the pixel electrode (not illustrating) of substrate 120 design so that the liquid crystal molecule of liquid crystal layer 150 produces multidirectional orientation effect.Yet such practice but needs to increase extra light shield manufacturing process, and then causes the increase of manufacturing process cost, and the decline of yield.
[summary of the invention]
In view of this, purpose of the present invention is exactly that a kind of display panels and liquid crystal indicator with comparatively stable and preferable LCD alignment effect is being provided.
Another object of the present invention is that a kind of manufacture method of display panels is being provided, in order to provide the liquid crystal molecule in the liquid crystal layer comparatively stable and preferable orientation effect.
The present invention proposes a kind of manufacture method of display panels, and its step comprises provides 1 substrate earlier, forms a liquid crystal afterwards and stablize material layer on this substrate.Then, this liquid crystal is stablized material layer shine a light, become a liquid crystal resistant strata so that liquid crystal is stablized material layer, wherein the top layer of liquid crystal resistant strata has a plurality of protrusions, and the geometry external form (profile) of these protrusions is the exposure intensity corresponding to light.Then, provide a subtend substrate, and a liquid crystal layer is sealed between substrate and the subtend substrate.
The present invention more proposes the manufacture method of another kind of display panels, and its step comprises provides a substrate earlier, forms a liquid crystal afterwards and stablize material layer on this substrate.Then, provide a subtend substrate, and on this subtend substrate, form a both alignment layers.Then, a liquid crystal layer is sealed between substrate and the subtend substrate.And, liquid crystal is stablized material layer shine a light, so that stablizing material layer, liquid crystal becomes a liquid crystal resistant strata, wherein the top layer of liquid crystal resistant strata has a plurality of protrusions, and the geometry external form of these protrusions system is corresponding to the exposure intensity of light.
In the manufacture method of above-mentioned display panels, after forming a liquid crystal on the substrate and stablizing material layer, and before liquid crystal is stablized the material layer irradiation light, for example comprise more that dry liquid crystal stablizes material layer.In addition, after the formation liquid crystal is stablized material layer, and before liquid crystal is stablized the material layer irradiation light, for example comprise more a pressing mold is provided that wherein the top layer of pressing mold has a raised design, stablizes material layer and raised design is needed on liquid crystal.
In the manufacture method of above-mentioned display panels, for example more be included on the subtend substrate and form liquid crystal and stablize material layer.
In the manufacture method of above-mentioned display panels, the method that the formation liquid crystal is stablized material layer for example is to utilize a scraper or transfer printing wheel that liquid crystal is stablized coated materials on substrate.
In addition, the present invention proposes the manufacture method of another kind of display panels again, and its step comprises provides a substrate and a subtend substrate earlier.Afterwards, provide a liquid crystal compound, it comprises a liquid crystal material and a liquid crystal stabilizing material.Then, liquid crystal compound is sealed between substrate and the subtend substrate, and liquid crystal compound is shone a light, with intersection at liquid crystal compound and substrate, and at the intersection of liquid crystal compound and subtend substrate, form a liquid crystal resistant strata respectively, wherein the top layer of liquid crystal resistant strata has a plurality of protrusions, and the geometry external form of these protrusions system is corresponding to the exposure intensity of light.
In the manufacture method of above-mentioned display panels, before forming the liquid crystal resistant strata, for example can on substrate or subtend substrate, form a both alignment layers respectively.
In the manufacture method of above-mentioned display panels, the height of protrusion for example be between 10 how rice to 200 how between the rice.In addition, the breadth extreme of protrusion for example be between 150 how rice to 600 how between the rice.
In the manufacture method of above-mentioned display panels, employed light for example is ultraviolet light.
In the manufacture method of above-mentioned display panels, the material that liquid crystal is stablized material layer for example as the formula (1).
Formula (1):
Wherein,
B, B ' comprise aromatic series (aromatic) or saturated rings alkane (saturated ring core);
X, Y comprise terminal base (terminal group) or reactive group (reactive group);
R, R ', R " be crosslinked (linkage) between the loop systems (ring system); And
Z, Z ' are side chain substituents (lateral substituent).
In the manufacture method of above-mentioned display panels, reactive group for example is a reactive group of drawing together acrylic acid (acrylic), epoxy resin (epoxy) or other kind, and crosslinked between loop systems for example is alkyl structure (alkyl structure).
In the manufacture method of above-mentioned display panels, the material that this liquid crystal is stablized material layer for example is:
Figure A20051011347000091
Or
Figure A20051011347000092
The present invention reintroduces a kind of display panels, and it comprises a substrate, a subtend substrate, a liquid crystal resistant strata and a liquid crystal layer.The liquid crystal resistant strata is disposed on the substrate, and wherein the surface of liquid crystal resistant strata has a plurality of protrusions.Liquid crystal layer is sealed between substrate and the subtend substrate.
The present invention more proposes to comply with kind of liquid crystal indicator, and it comprises a display panels and a backlight assembly.Wherein display panels comprises a substrate, a subtend substrate, a liquid crystal resistant strata and a liquid crystal layer.The liquid crystal resistant strata is disposed on the substrate, and wherein the surface of liquid crystal resistant strata has a plurality of protrusions.Liquid crystal layer is sealed between substrate and the subtend substrate.And backlight assembly is adjacent to the substrate configuration.
In display panels of the present invention and liquid crystal indicator, the height of protrusion for example be in 10 how rice to 200 how between the rice.In addition, the breadth extreme of protrusion for example be between 150 how rice to 600 how between the rice.
In display panels of the present invention and liquid crystal indicator, the material that liquid crystal is stablized material layer for example as the formula (1).
Formula (1):
Figure A20051011347000093
Wherein,
B, B ' comprise aromatic series or saturated rings alkane (saturated ring core);
X, Y comprise terminal base or reactive group;
R, R ', R " be crosslinked between the loop systems; And
Z, Z ' are side chain substituents.
In display panels of the present invention and liquid crystal indicator, reactive group for example is the reactive group of acrylic acid, epoxy resin or other kind, and crosslinked between loop systems for example is alkyl structure.
In display panels of the present invention and liquid crystal indicator, the material that liquid crystal is stablized material layer for example is:
Or
Figure A20051011347000102
In display panels of the present invention and liquid crystal indicator, for example optionally be formed with another a liquid crystal resistant strata or a both alignment layers on the subtend substrate.Certainly, also can have both alignment layers and liquid crystal resistant strata simultaneously on the subtend substrate, wherein these orientation series of strata are between liquid crystal resistant strata and subtend substrate.
In display panels of the present invention and liquid crystal indicator, for example optionally dispose a both alignment layers on the substrate, it is between substrate and liquid crystal resistant strata.
In display panels of the present invention and liquid crystal indicator, the liquid crystal resistant strata for example has a raised design.
The present invention surely is positioned at the liquid crystal molecule of liquid crystal layer and liquid crystal resistant strata intersection because of adopting the liquid crystal resistant strata, comes the stabilizing liquid crystal molecule with the protrusion by the how meter level on the liquid crystal resistant strata, and preferable orientation effect is provided.Therefore, compared to knowing technology, the liquid crystal molecule in the liquid crystal layer of the present invention has the short response time.In addition, the present invention more can look actual the geometry external form that demand is adjusted protrusion, makes liquid crystal molecule have different tilt angle (pre-tilt angle).
For above and other objects of the present invention, feature and advantage can be become apparent, preferred embodiment cited below particularly, and cooperate appended graphicly, be described in detail below.
[description of drawings]
Fig. 1 illustrates the diagrammatic cross-section into existing display panels.
Fig. 2 A~2D illustrates the schematic flow sheet into the manufacture method of the display panels of preferred embodiment of the present invention.
Fig. 2 E illustrates to forming the synoptic diagram that liquid crystal is stablized material layer by scraper on substrate.
Fig. 3 illustrates the enlarged diagram into a preferred embodiment protrusions thing of the present invention.
Fig. 4 illustrates the enlarged diagram into the intersection of Fig. 2 D protrusions thing and liquid crystal layer.
Fig. 5 A~5B illustrates the synoptic diagram that is subjected to the protrusion influence of different geometry external forms for the tilt angle of liquid crystal molecule.
Fig. 6 A~Fig. 6 B illustrates to form the synoptic diagram of the protrusion of different external forms by the composition that changes protrusion.
Fig. 6 C illustrates to form the synoptic diagram of the protrusion of different external forms by the exposure intensity that changes light.
Fig. 7 A~Fig. 7 C illustrates the schematic diagram of fabrication technology that forms raised design in the display panels manufacturing process on the liquid crystal resistant strata.
Fig. 8 A~Fig. 8 C illustrates the synoptic diagram into the display panels of other multiple different kenels of preferred embodiment of the present invention.
Fig. 9 A~9C illustrates the manufacturing process synoptic diagram into another kind of display panels of the present invention.
Figure 10 A and Figure 10 B illustrate the synoptic diagram into the display panels by formed multiple other the different kenels of another way.
Figure 11 illustrates the synoptic diagram into the liquid crystal indicator of preferred embodiment of the present invention.
[embodiment]
Fig. 2 A~2D illustrates the schematic flow sheet into the manufacture method of the display panels of preferred embodiment of the present invention.At first, please refer to Fig. 2 A, a substrate 210 is provided, and a liquid crystal is stablized material layer 220 be formed on the substrate 210.In the present embodiment, the mode that the formation liquid crystal is stablized material layer 220 for example is earlier liquid crystal to be stablized droplets of material on transfer printing wheel 300, and then utilize relatively move (shown in direction 350) between transfer printing wheel 300 and the substrate 210, and the liquid crystal that formation has a suitable thickness on substrate 210 is stablized material layer 220.
In addition, utilize transfer printing wheel 300 to form liquid crystal to stablize the material layer 220, in other embodiments of the invention, more can form above-mentioned liquid crystal and stablize material layer 220 except above-mentioned by alternate manner.For example, Fig. 2 E promptly illustrates to forming the synoptic diagram that liquid crystal is stablized material layer 220 by scraper 310 on substrate 210, it for example is by a scraper 310, makes it along direction 355 and substrate 210 relative motions, stablizes material layer 220 on substrate 210 and form the liquid crystal with suitable thickness.
Then, shown in Fig. 2 B, after liquid crystal being stablized material layer 220 and being formed at substrate 210, for example can stablize material layer 220 and carry out drying liquid crystal.In a preferred implementation, for example can be formed with liquid crystal stablize the substrate 210 of material layer 220 insert a temperature between Celsius 50~200 the degree between environment in toast (baking), stablize material layer 220 with dry liquid crystal.
Then, please refer to Fig. 2 C, with a light 320 irradiating liquid crystal stabilizing material layers 220, make liquid crystal stablize material layer 220 and change the liquid crystal resistant strata into that wherein light 320 for example can be ultraviolet light, and liquid crystal is stablized the material of material layer 220 and formed as the formula (1).
Formula (1):
Figure A20051011347000121
Wherein,
B, B ' for example comprise aromatic series or saturated rings alkane (saturated ring core);
X, Y for example comprise terminal base or reactive group, and wherein reactive group can be the reactive group of acrylic acid, epoxy resin or other kind;
R, R ', R " for example be crosslinked between the loop systems, the crosslinked alkyl structure that comprises between loop systems wherein; And
Z, Z ' are side chain substituents.
For example, liquid crystal stablize material layer 220 material for example can for:
Figure A20051011347000122
Or
Figure A20051011347000123
After liquid crystal was stablized material layer 220 and changed liquid crystal resistant strata 230 into, how meter-sized the surface of liquid crystal resistant strata 230 can form a plurality of protrusion 230a, its physical dimension about tens of how rice between hundreds of how rice.Please refer to Fig. 3, it illustrates in the preferred embodiment of the present invention, the enlarged diagram of protrusion 230a.As shown in Figure 3, protrusion 230a for example is taper, its height h for example between 10 how rice to 100 how between the rice, and the breadth extreme w of protrusion 230a for example between 150 how rice to 600 how between the rice.
Though it should be noted that the geometry external form of protrusion 230a is a taper in the present embodiment, those who are familiar with this art should stablize the material of material layer 220 according to different liquid crystal, and form the protrusion 230a of different how much external forms.
Afterwards, please refer to Fig. 2 D, a subtend substrate 240 is provided, and form a both alignment layers 250 on subtend substrate 240, wherein the material of both alignment layers for example is the material of polyamide class.Afterwards, one liquid crystal layer 260 is sealed between substrate 210 and the subtend substrate 240, to form display panels 200a, wherein the material of liquid crystal layer 260 for example is the liquid crystal material of nematic (nematic) liquid crystal, twist nemaatic mode (cholesteric) liquid crystal or other kind.
In addition, though the foregoing description is before 240 groups of substrate 210 and subtend substrates are stood, just the liquid crystal on the substrate 210 is stablized material layer 220 irradiations, to form liquid crystal resistant strata 230 (shown in Fig. 2 C).Yet, in another better embodiment, for example more can after be stood, 240 groups of substrate 210 and subtend substrates liquid crystal material layer 220 be shone establish light 320 again, so that stablizing material layer 220, liquid crystal changes liquid crystal resistant strata 230 into.
Fig. 4 illustrates the enlarged diagram into the intersection of Fig. 2 D protrusions thing 230a and liquid crystal layer 260.Please refer to Fig. 4, because the physical dimension of protrusion 230a is the size of meter level how, and intersection at protrusion 230a and liquid crystal layer 260, the molecular structure on protrusion 230a surface can form stable structure jointly with near liquid crystal molecule, so the protrusion 230a of present embodiment has the function of stabilizing liquid crystal molecule and stabilizing liquid crystal molecule rotation direction.
What deserves to be mentioned is that the protrusion 230a on the above-mentioned liquid crystal resistant strata 230 more can provide liquid crystal molecule one tilt angle, to reach wide-visual angle effect except can the stabilizing liquid crystal molecule.Please refer to Fig. 5 A and 5B, it illustrates the synoptic diagram that is subjected to the protrusion influence of different geometry external forms for the tilt angle of liquid crystal molecule respectively.The h/w value system of the protrusion 230a that Fig. 5 A is illustrated is less than the h '/w ' value of the protrusion 230a ' shown in Fig. 5 B.Thus, if when the tilt angle of liquid crystal molecule 262 is defined as the main shaft of liquid crystal molecule and the angle of horizontal direction (shown in Fig. 5 A), just then the tilt angle of liquid crystal molecule 262 can be greater than the tilt angle of liquid crystal molecule 262 ' among Fig. 5 B among Fig. 5 D '.In other words, just present embodiment can be by utilize adjusting geometry external form (profile) (as the h/w value) of protrusion 230a, provide different liquid crystal to stablize and the effect of orientation.
The method of the geometry external form of above-mentioned change protrusion 230a will be in hereinafter being illustrated.
Fig. 6 A~Fig. 6 B illustrates to form the synoptic diagram of the protrusion of different external forms by the composition that changes protrusion.Please refer to Fig. 6 A, present embodiment for example can be adjusted the geometry external form of protrusion 230a by whether removing the reactive group X in the liquid crystal stabilizing material as the formula (1).For example, when the liquid crystal stabilizing material shown in the formula (1) did not have reactive group X, the h/w value of formed protrusion 230a can be less than the h '/w ' value with formed protrusion 230a in the reactive group X.In addition, please refer to Fig. 6 B, present embodiment for example can also be by adjusting crosslinked R ' or the R between the loop systems in the liquid crystal stabilizing material as the formula (1) " chain length, adjust the geometry external form of protrusion 230a.For example, crosslinked R ' and the R in the liquid crystal stabilizing material shown in the formula (1) " be-(CH 2) 6In-time, the h/w value meeting of formed protrusion 230a is less than crosslinked R ' and R " be short-(CH of chain length 2) 3In-time,, h '/w ' of pairing protrusion 230a was worth.
Certainly, except the composition structure of adjusting the liquid crystal stabilizing material shown in (1), present embodiment can also be adjusted the geometry external form of protrusion 230a by changing the composition of liquid crystal stabilizing material.For example, when the reactive group X of the liquid crystal stabilizing material shown in the formula (1) or Y were acrylic acid, when reactive group X or Y were epoxy resin in formula (1), its formed protrusion 230a will have different geometry external forms respectively.
In addition, if come irradiating liquid crystal stabilizing material layer 220 with the light of varying strength, the protrusion 230a on the then formed liquid crystal resistant strata 230 also with different geometry external forms arranged.Fig. 6 C illustrates to form the synoptic diagram of the protrusion of different external forms by the exposure intensity that changes light.Shown in Fig. 6 C, when the intensity of the light 320 that is shone was strong, the h/w value of formed protrusion 230a will be less than the h/w value of shining formed protrusion 230a by the more weak light 320 of intensity.
Based on above-mentioned, the present invention for example can adjust the geometry external form of protrusion 230a (as the h/w value) by the modes such as composition that change irradiation intensity, liquid crystal stabilizing material.Certainly, in other embodiments of the invention, more for example can reach identical purpose by the variation of manufacturing process temperature or other fabrication process parameters, give unnecessary details no longer one by one at this.
In addition, in order to strengthen the orientation effect of liquid crystal resistant strata 230, the present invention more can form a raised design on liquid crystal resistant strata 230 except the geometry external form that can adjust protrusion 230a.Please refer to Fig. 7 A~Fig. 7 C, it illustrates in the display panels manufacturing process, forms the schematic diagram of fabrication technology of raised design on the liquid crystal resistant strata.In the manufacturing process of aforesaid display panels 200a, liquid crystal is stablized material layer 220 be formed at substrate 210 after (Fig. 2 B), and liquid crystal is being stablized before material layer 220 irradiation light 320, present embodiment for example more can be shown in Fig. 7 A, one pressing mold 330 is provided earlier, and pressing mold 330 is moved along direction 360, and wherein the surface of pressing mold 330 has a raised design 332.Afterwards, shown in Fig. 7 B,, pressing mold 332 is pressed on liquid crystal stablizes on the material layer 220, stablize on the material layer 220 so that the raised design on the pressing mold 330 332 is transferred to liquid crystal with a predetermined pressure.Then, shown in Fig. 7 C, remove pressing mold 330, and with light 320 irradiating liquid crystal stabilizing material layers 220, and obtain having the liquid crystal resistant strata 230 of raised design 332.This liquid crystal resistant strata 230 with raised design 332 can provide better LCD alignment effect, and further improve the angle of visibility scope of display panels 200a.
In addition, the display panels 200a of present embodiment is except forming liquid crystal resistant strata 230 on substrate 210, and forming on the subtend substrate 240 outside the both alignment layers 250, more for example can pass through the collocation of liquid crystal resistant strata and both alignment layers, and form the display panels of multiple different kenels.Fig. 8 A~Fig. 8 C illustrates the synoptic diagram into the display panels of other multiple different kenels of preferred embodiment of the present invention.
Please refer to Fig. 8 A, in the manufacturing process of above-mentioned manufacturing display panels 200a, the configuration of both alignment layers 250 is except can be shown in Fig. 2 D, more another liquid crystal resistant strata 235 can be formed on the subtend substrate 240, to replace the both alignment layers 250 among Fig. 2 D, make display panels 200b on substrate 210, have liquid crystal resistant strata 230, on subtend substrate 240, have liquid crystal resistant strata 235.
In addition, please refer to Fig. 8 B, present embodiment more can be before the formation liquid crystal be stablized material layer 230, form another both alignment layers 255 on substrate 210, so that display panels 200c has both alignment layers 255 and liquid crystal resistant strata 230 on substrate 210, have both alignment layers 250 on subtend substrate 240, wherein both alignment layers 255 is disposed between liquid crystal resistant strata 230 and the substrate 210.200c
In addition, please refer to Fig. 8 C, present embodiment more for example can be earlier respectively at forming both alignment layers 255 and 250 respectively on substrate 210 and the subtend substrate 240, form liquid crystal resistant strata 230 and 235 afterwards more respectively on these two both alignment layers 250, so that display panels 200d has both alignment layers 255 and liquid crystal resistant strata 230 on substrate 210, on subtend substrate 240, have both alignment layers and liquid crystal resistant strata 235, wherein both alignment layers 255 is between liquid crystal resistant strata 230 and substrate 210, and both alignment layers 250 is between liquid crystal resistant strata 235 and subtend substrate 240.
It should be noted that, though in Fig. 2 D and Fig. 8 A, the liquid crystal resistant strata 230 of individualism and 255 can make the liquid crystal molecule of liquid crystal layer 230 reach stable orientation state, but the display panels of working as present embodiment is shown in Fig. 8 B, when being disposed at both alignment layers 255 between liquid crystal resistant strata 230 and the substrate 210, or shown in Fig. 8 C, both alignment layers 255 is disposed between liquid crystal resistant strata 230 and the substrate 210, and when being disposed at both alignment layers 250 between liquid crystal resistant strata 235 and the subtend substrate 240, the liquid crystal resistant strata of Fig. 8 B and Fig. 8 C and the iterative structure of both alignment layers can make the liquid crystal molecule of liquid crystal layer 230 reach stable orientation state more quickly.
In addition, though the display panels 200a of Fig. 2 D and the display panels 200b of Fig. 8 A can't shorten the time that liquid crystal molecule reaches steady state (SS) via the iterative structure of liquid crystal resistant strata and both alignment layers, but present embodiment can apply an electrical potential energy between the substrate 210 of Fig. 2 D and Fig. 8 A and subtend substrate 240, so that the liquid crystal molecule of liquid crystal layer 230 can reach stable orientation state more quickly.Certainly, present embodiment more can be in Fig. 8 B and Fig. 8 C, between substrate 210 and subtend substrate 240, apply an electrical potential energy, make the liquid crystal molecule of liquid crystal layer 230 be subjected to simultaneously this electrical potential energy and liquid crystal resistant strata and both alignment layers iterative structure influence and reach stable orientation state more quickly.
Except the above-mentioned liquid crystal stabilizing material that on substrate or subtend substrate, applies, outside the mode that forms the liquid crystal resistant strata, the present invention more for example can directly mix the liquid crystal stabilizing material in liquid crystal layer, treat panel sets upright after again in the intersection formation liquid crystal resistant strata of liquid crystal layer and substrate (or subtend substrate).
Fig. 9 A~9C illustrates the manufacturing process synoptic diagram into another kind of display panels of the present invention.Please refer to Fig. 9 A, a substrate 210 and liquid crystal compound 270 at first are provided, wherein liquid crystal compound 270 is mixed by liquid crystal material and liquid crystal stabilizing material, and wherein the material of liquid crystal stabilizing material as the formula (1).Afterwards, (one drop fill ODF) is formed at liquid crystal compound 270 on the substrate 210 for example to utilize the liquid crystal drop laxative remedy.
Please refer to Fig. 7 B, a subtend substrate 240 is provided, and liquid crystal compound 270 is sealed between substrate 210 and the subtend substrate 240.Afterwards, shown in Fig. 7 C, utilize the liquid crystal compound 270 of light 320 irradiations between substrate 210 and subtend substrate 240, with the intersection between liquid crystal compound 270 and substrate 210, and the intersection between liquid crystal compound 270 and the subtend substrate 240 forms liquid crystal resistant strata 230 and 235 respectively, and obtains a display panels 200e.
In above-mentioned display panels 200e, on substrate 210 and the subtend substrate 240 except can having liquid crystal resistant strata 230 and 235, more for example can have both alignment layers respectively, it is to be disposed between substrate 210 and the liquid crystal resistant strata 230 or between subtend substrate 240 and the liquid crystal resistant strata 235, and Figure 10 A and Figure 10 B illustrate the synoptic diagram into the display panels by formed multiple other the different kenels of this mode.
Please refer to Figure 10 A, in the manufacturing process of above-mentioned display panels 200f, present embodiment for example more can with 270 of liquid crystal compounds before on the substrate 210, on substrate 210, form a both alignment layers 255, so that display panels 200f is when finishing, have both alignment layers 255 and liquid crystal resistant strata on the substrate 210, and have liquid crystal resistant strata 235 on the subtend substrate 240, wherein both alignment layers 255 is disposed between liquid crystal resistant strata 230 and the substrate 210.
In addition, please refer to Figure 10 B, present embodiment for example can also with 270 of liquid crystal compounds before on the substrate 210, on substrate 210 and subtend substrate 240, form both alignment layers 250 and 255, so that display panels 200g is when finishing, have both alignment layers 255 and liquid crystal resistant strata 230 on the substrate 210, have both alignment layers 250 and liquid crystal resistant strata 235 on the subtend substrate 240, wherein both alignment layers 255 is disposed between liquid crystal resistant strata 230 and the substrate 210, and both alignment layers 250 is disposed between liquid crystal resistant strata 235 and the subtend substrate 240.
It should be noted that, though in Fig. 9 C, the liquid crystal resistant strata 230 of individualism and 235 can make the liquid crystal molecule of liquid crystal layer 230 reach stable orientation state, but the display panels of working as present embodiment is shown in Figure 10 A, when being disposed at both alignment layers 255 between liquid crystal resistant strata 230 and the substrate 210, or shown in Fig. 8 C, both alignment layers 255 is disposed between liquid crystal resistant strata 230 and the substrate 210, and when being disposed at both alignment layers 250 between liquid crystal resistant strata 235 and the subtend substrate 240, the liquid crystal resistant strata of Figure 10 A and Figure 10 B and the iterative structure of both alignment layers can make the liquid crystal molecule of liquid crystal layer 230 reach stable orientation state more quickly.
In addition, though the display panels 200e of Fig. 9 C can't shorten the time that liquid crystal molecule reaches steady state (SS) via the iterative structure of liquid crystal resistant strata and both alignment layers, but present embodiment can apply an electrical potential energy between the substrate 210 of Fig. 9 C and subtend substrate 240, so that the liquid crystal molecule of liquid crystal layer 230 can reach stable orientation state more quickly.Certainly, present embodiment more can be in Figure 10 A and Figure 10 B, between substrate 210 and subtend substrate 240, apply an electrical potential energy, make the liquid crystal molecule of liquid crystal layer 230 be subjected to simultaneously this electrical potential energy and liquid crystal resistant strata and both alignment layers iterative structure influence and reach stable orientation state more quickly.
After finishing above-mentioned display panels 200, present embodiment more can be as shown in figure 11, backlight assembly 600 is adjacent to substrate 210 configurations, and to form liquid crystal indicator 50, wherein backlight assembly 600 is in order to display panels 200a to be provided suitable intensity backlight.
In sum, liquid crystal resistant strata of the present invention can by how the protrusion of meter level, come stabilizing liquid crystal molecule, stabilizing liquid crystal molecule rotation direction and make the orientation effect of liquid crystal molecule more good.Therefore, compared to existing technologies, display panels proposed by the invention can have the response time than advantages such as short and wide viewing angles.In addition, the present invention more can adjust the geometry external form of the protrusion on the liquid crystal resistant strata by the composition, manufacturing process temperature or other fabrication process parameters that change irradiation intensity, liquid crystal stabilizing material, therefore the present invention can look actual needs, adjust the response time and the tilt angle of liquid crystal molecule, make display panels have preferable display effect.
Though the present invention discloses as above with preferred embodiment; right its is not in order to limit the present invention; anyly have the knack of this skill person; without departing from the spirit and scope of the present invention; when can doing a little change and retouching, so protection scope of the present invention is as the criterion when looking accompanying the claim person of defining.

Claims (20)

1. liquid crystal indicator, it comprises:
One display panels, it comprises:
One substrate;
One subtend substrate;
One liquid crystal resistant strata is disposed on this substrate, and wherein the surface of this liquid crystal resistant strata has
A most protrusion; And
One liquid crystal layer is sealed between this substrate and this subtend substrate; And
One backlight assembly is adjacent to this substrate.
2. display panels according to claim 1 is characterized in that, the height of this protrusion between 10 how rice to 200 how between the rice.
3. display panels according to claim 1 is characterized in that, the breadth extreme of this protrusion between 150 how rice to 600 how between the rice.
4. display panels according to claim 1 is characterized in that, the material of this liquid crystal resistant strata as the formula (1),
Formula (1):
Wherein,
B, B ' comprise aromatic series or saturated rings alkane (saturated ring core);
X, Y comprise terminal base or reactive group;
R, R ', R " be crosslinked between the loop systems; And
Z, Z ' are side chain substituents.
5. display panels according to claim 4 is characterized in that reactive group comprises the reactive group of acrylic acid, epoxy resin or other kind.
6. display panels according to claim 4 is characterized in that, the crosslinked alkyl structure that comprises between loop systems.
7. the manufacture method of display panels according to claim 4 is characterized in that, the material that this liquid crystal is stablized material layer is:
8. the manufacture method of display panels according to claim 4 is characterized in that, the material that this liquid crystal is stablized material layer is:
9. display panels according to claim 4 is characterized in that, more comprises a both alignment layers, and it is disposed on this subtend substrate.
10. display panels according to claim 9 is characterized in that, more comprises another both alignment layers, and it is disposed between this substrate and this liquid crystal resistant strata.
11. display panels according to claim 1 is characterized in that, more comprises another liquid crystal resistant strata, is disposed on this substrate and this subtend substrate.
12. display panels according to claim 11 is characterized in that, comprise that more a both alignment layers is disposed between this substrate and this liquid crystal resistant strata, and another both alignment layers is disposed between this subtend substrate and another this liquid crystal resistant strata.
13. display panels according to claim 1 is characterized in that, this liquid crystal resistant strata has a raised design.
14. the manufacture method of a display panels, its step comprises:
One substrate is provided;
On this substrate, form a liquid crystal and stablize material layer;
This liquid crystal is stablized material layer shine a light, become a liquid crystal resistant strata so that this liquid crystal is stablized material layer, wherein the top layer of this liquid crystal resistant strata has most protrusions, and the geometry external form of those protrusions system is corresponding to the exposure intensity of this light;
One subtend substrate is provided; And
One liquid crystal layer is sealed between this substrate and this subtend substrate.
15. the manufacture method of display panels according to claim 14 is characterized in that, after forming this liquid crystal and stablizing material layer, and this liquid crystal is stablized material layer shines before this light, more comprises:
One pressing mold is provided, and wherein the top layer of this pressing mold has a raised design; And
Utilize this pressing mold, this raised design is needed on this liquid crystal stablizes material layer.
16. the manufacture method of display panels according to claim 14 is characterized in that, forms this liquid crystal and stablizes the method for material layer and comprise and utilize a scraper that liquid crystal is stablized coated materials on this substrate.
17. the manufacture method of display panels according to claim 14 is characterized in that, forms this liquid crystal and stablizes the method for material layer and comprise and utilize transfer printing wheel that liquid crystal is stablized coated materials on this substrate.
18. the manufacture method of a display panels, its step comprises:
One substrate and a subtend substrate are provided;
One liquid crystal compound is provided, and it comprises a liquid crystal material and a liquid crystal stabilizing material;
This liquid crystal compound is sealed between this substrate and this subtend substrate; And
This liquid crystal compound is shone a light, with in the intersection of this liquid crystal compound and this substrate, and in the intersection of this liquid crystal compound and this subtend substrate, form a liquid crystal resistant strata respectively, wherein the top layer of this liquid crystal resistant strata has most protrusions, and the geometry external form of those protrusions system is corresponding to the exposure intensity of this light.
19. the manufacture method of display panels according to claim 18 is characterized in that, more is included in and forms a both alignment layers on this subtend substrate.
20. the manufacture method of display panels according to claim 19 is characterized in that, before forming this liquid crystal resistant strata, more comprises forming another both alignment layers on this substrate.
CN200510113470XA 2005-10-12 2005-10-12 Liquid crystal display panel and manufacture method thereof Active CN1949062B (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8269935B2 (en) 2008-07-08 2012-09-18 Chimei Innolux Corporation Liquid crystal display
CN102326121B (en) * 2009-01-30 2015-07-01 索尼公司 Liquid crystal display device and method for manufacturing same
CN105093620A (en) * 2015-08-07 2015-11-25 深圳市华星光电技术有限公司 Public advertisement display screen and manufacture method thereof
CN111025775A (en) * 2019-12-16 2020-04-17 深圳市华星光电半导体显示技术有限公司 Curved surface screen

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8269935B2 (en) 2008-07-08 2012-09-18 Chimei Innolux Corporation Liquid crystal display
CN102326121B (en) * 2009-01-30 2015-07-01 索尼公司 Liquid crystal display device and method for manufacturing same
CN105093620A (en) * 2015-08-07 2015-11-25 深圳市华星光电技术有限公司 Public advertisement display screen and manufacture method thereof
CN105093620B (en) * 2015-08-07 2018-03-06 深圳市华星光电技术有限公司 Public advertising display screen and preparation method thereof
CN111025775A (en) * 2019-12-16 2020-04-17 深圳市华星光电半导体显示技术有限公司 Curved surface screen
US11391972B2 (en) 2019-12-16 2022-07-19 Shenzhen China Star Optoelectronics Semiconductor Display Technology Co., Ltd. Curved panel and display device

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