CN1300250C - Antifoulant for vitreous polished floor tile and its preparing method - Google Patents
Antifoulant for vitreous polished floor tile and its preparing method Download PDFInfo
- Publication number
- CN1300250C CN1300250C CNB2004100688959A CN200410068895A CN1300250C CN 1300250 C CN1300250 C CN 1300250C CN B2004100688959 A CNB2004100688959 A CN B2004100688959A CN 200410068895 A CN200410068895 A CN 200410068895A CN 1300250 C CN1300250 C CN 1300250C
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- CN
- China
- Prior art keywords
- floor tile
- vitreous
- alkyd resin
- rosin
- antifoulant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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Abstract
The present invention provides an antifoulant of a vitreous polished floor tile, which has a good antifouling effect and increases the gloss degree of the tile face. The present invention mainly comprises 4 to 7% of paraffin wax, 40 to 60% of naphthalene, 20 to 40% of rosin modified alkyd resin, 8 to 15% of penetrating agent, 0.1 to 1% of essence and 0.1 to 1% of toner, wherein the paraffin wax is from 54 degrees to 60 degrees; a proportion of rosin to alkyd resin is from 1:1 to 1:3. The antifoulant can be penetrated into a superfine hole in the vitreous polished floor tile and firmly combined to the surface of the vitreous polished floor tile after being crystallized and dried, and the superfine hole is sealed and blocked so that filth can not enter the vitreous polished floor tile. The present invention has good antifouling property, water scrub resistance and good endurance. Additionally, the gloss degree of the tile face can be enhanced by more than 10 degrees.
Description
Technical field
The application relates to a kind of antifoulant for vitreous polished floor tile.
Background technology
Though glazed polishing floor tile surface-brightening, rich color as the building decoration surface lining; but there is the relatively poor problem of antifouling ability; easily by pollutions such as cement, footwear seal, colors, this is because a large amount of minute aperture that glazed polishing brick surface exists causes during use.
Antifoulant for vitreous polished floor tile mainly comprises liquid wax, hydrophobic surface promoting agent and organic coating etc. at present.Though liquid wax is cheap and can increase the surface brightness of glazed polishing floor tile, its antifouling time is short, and anti-fouling effect is also bad; The hydrophobic surface promoting agent can form the very thin water-repellent layer of one deck on the glazed polishing floor tile surface and reach certain anti-fouling effect, but because it just is adsorbed on the glazed polishing floor tile surface, lose anti-fouling effect so come off under external force easily, thereby cause its antifouling poor durability; In addition, though the anti-fouling effect of organic coating is pretty good, it can reduce the glossiness on glazed polishing floor tile surface, generally can reduce about its glossiness 5 degree.
Summary of the invention
The application aims to provide a kind of good antifouling effect and can increase antifoulant for vitreous polished floor tile of brick face glossiness and preparation method thereof.
The stain control agent that the application provides mainly comprises: the paraffin of 4-7%, and wherein the paraffin number of degrees are the 54-60 degree; The sodium-chlor of 0-1%; The naphthalene of 40-60%; The rosin modified alkyd resin of 20-40%, wherein the ratio of rosin and Synolac is 1: 1-1: 3; The permeate agent of 8-15%; The essence of 0.1-1%; The toner of 0.1-1%.
The stain control agent preparation method that the application provides is: naphthalene and the 20-40% rosin modified alkyd resin with 40-60% mixes earlier, normal temperature condition reacts after 50-90 hour down, again 4-7% paraffin and 0.1-1% sodium-chlor are mixed and heated to about 55-65 ℃, add the 8-15% permeate agent then, be poured on reacted naphthalene and the mixed liquid of rosin modified alkyd resin, add 0.1-1% essence and 0.1-1% toner at last, normal temperature condition reacted 50-90 hour down, and wherein: rosin and alkyd ratio are 1 in the rosin modified alkyd resin: 1-1: 3; Paraffin is 54-60 degree paraffin.
Permeate agent in the application's stain control agent is not particularly limited, as adopting kerosene, penetrant t etc.; Toner in the application's stain control agent also is not particularly limited in addition, as adopting titanium dioxide or other mill base that needs etc.
The application's stain control agent can penetrate into the minute aperture of glazed polishing floor tile inside, and in glazed polishing floor tile surface mortise, minute aperture is stopped up in sealing after the crystallization mummification, and making dirt not have sky can go into, and antifouling property is good, water-proof and good endurance; In addition, the application's stain control agent can also increase the glazed polishing floor tile surface gloss, generally can improve more than 10 degree.
Embodiment
Embodiment 1
Earlier 40% naphthalene and 40% rosin modified alkyd resin (rosin is 1: 1 with the Synolac ratio) are mixed, normal temperature condition was placed 50 hours down, again 4% 54 degree paraffin and 0.1% sodium-chlor are mixed and heated to about 55 ℃, add 15% deodorized kerosine (another name takes off virtue oil) then, be poured on reacted naphthalene and the mixed liquid of rosin modified alkyd resin, the titanium dioxide toner that adds 0.1% essence and 0.8% at last, normal temperature condition was placed 50 hours down.
Embodiment 2
Earlier 50% naphthalene and 30% rosin modified alkyd resin (rosin is 1: 2 with the Synolac ratio) are mixed, normal temperature condition was placed 72 hours down, again 7% 60 degree paraffin and 0.5% sodium-chlor are mixed and heated to about 60 ℃, add 12% illuminating kerosene then, be poured on reacted naphthalene and the mixed liquid of rosin modified alkyd resin, the titanium dioxide toner that adds 0.25% essence and 0.25% at last, normal temperature condition was placed 72 hours down.
Embodiment 3
Earlier 60% naphthalene and 24% rosin modified alkyd resin (rosin is 1: 3 with the Synolac ratio) are mixed, normal temperature condition was placed 90 hours down, again 6% 58 degree paraffin and 1% sodium-chlor are mixed and heated to about 65 ℃, add 8% penetrant t then, be poured on reacted naphthalene and the mixed liquid of rosin modified alkyd resin, the white colorant that adds 0.9% essence and 0.1% at last, normal temperature condition was placed 90 hours down.
After the stain control agent that the foregoing description 1-3 is prepared is coated on the glazed polishing floor tile surface, carry out antifouling experiment, after ten minutes the brick face is cleaned up, still do not see the variable color of brick face this moment with ink; The same terms adopts other commercially available stain control agent down, and the brick face just has metachromatism after 1-2 minute.In addition, above-mentioned stain control agent can also increase the glazed polishing floor tile surface gloss, generally can improve more than 10 degree.
It will be understood by those skilled in the art that above-mentioned stain control agent not only limits to is used in glazed polishing floor tile, and it also is feasible being used in other building decoration surface lining.
Claims (4)
1, a kind of preparation method of antifoulant for vitreous polished floor tile the steps include: naphthalene and the 20-40% rosin modified alkyd resin of 40-60% are mixed, and reacts 50-90 hour; 4-7% paraffin and 0.1-1% sodium-chlor are mixed and heated to about 55-65 ℃, add the 8-15% permeate agent then, be poured on reacted naphthalene and the mixed liquid of rosin modified alkyd resin, add 0.1-1% essence and 0.1-1% toner at last, reacted 50-90 hour, wherein: rosin and alkyd ratio are 1 in the rosin modified alkyd resin: 1-1: 3; Paraffin is 54-60 degree paraffin.
2, the preparation method of stain control agent as claimed in claim 1 is characterized in that: the ratio of rosin and Synolac is 1: 2 in the rosin modified alkyd resin.
3, the preparation method of stain control agent as claimed in claim 1 or 2 is characterized in that: adopt kerosene as permeate agent.
4, the preparation method of stain control agent as claimed in claim 3 is characterized in that: adopt titanium dioxide as toner.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2004100688959A CN1300250C (en) | 2004-07-14 | 2004-07-14 | Antifoulant for vitreous polished floor tile and its preparing method |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2004100688959A CN1300250C (en) | 2004-07-14 | 2004-07-14 | Antifoulant for vitreous polished floor tile and its preparing method |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1587318A CN1587318A (en) | 2005-03-02 |
CN1300250C true CN1300250C (en) | 2007-02-14 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CNB2004100688959A Expired - Fee Related CN1300250C (en) | 2004-07-14 | 2004-07-14 | Antifoulant for vitreous polished floor tile and its preparing method |
Country Status (1)
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CN (1) | CN1300250C (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7993713B2 (en) | 2006-02-16 | 2011-08-09 | Kureha Corporation | Heat shrinkable multilayer film and packaging material using the same |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104016725A (en) * | 2014-05-04 | 2014-09-03 | 姚燕春 | Colored polished brick brightening technique |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS63258972A (en) * | 1987-04-16 | 1988-10-26 | Mitsubishi Motors Corp | Rust-proofing agent |
JPH04270204A (en) * | 1991-02-25 | 1992-09-25 | Yoshitomi Pharmaceut Ind Ltd | Underwater adhesive organism-control ling agent controlled in its elution |
-
2004
- 2004-07-14 CN CNB2004100688959A patent/CN1300250C/en not_active Expired - Fee Related
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS63258972A (en) * | 1987-04-16 | 1988-10-26 | Mitsubishi Motors Corp | Rust-proofing agent |
JPH04270204A (en) * | 1991-02-25 | 1992-09-25 | Yoshitomi Pharmaceut Ind Ltd | Underwater adhesive organism-control ling agent controlled in its elution |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7993713B2 (en) | 2006-02-16 | 2011-08-09 | Kureha Corporation | Heat shrinkable multilayer film and packaging material using the same |
Also Published As
Publication number | Publication date |
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CN1587318A (en) | 2005-03-02 |
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